WO2008001588A1 - Boiled egg yolk-like food - Google Patents

Boiled egg yolk-like food Download PDF

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Publication number
WO2008001588A1
WO2008001588A1 PCT/JP2007/061417 JP2007061417W WO2008001588A1 WO 2008001588 A1 WO2008001588 A1 WO 2008001588A1 JP 2007061417 W JP2007061417 W JP 2007061417W WO 2008001588 A1 WO2008001588 A1 WO 2008001588A1
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WIPO (PCT)
Prior art keywords
egg yolk
egg
food
soybean protein
boiled
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PCT/JP2007/061417
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French (fr)
Japanese (ja)
Inventor
Atsushi Ohno
Original Assignee
Fuji Oil Company, Limited
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Publication date
Application filed by Fuji Oil Company, Limited filed Critical Fuji Oil Company, Limited
Priority to JP2008522378A priority Critical patent/JPWO2008001588A1/en
Publication of WO2008001588A1 publication Critical patent/WO2008001588A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L15/00Egg products; Preparation or treatment thereof
    • A23L15/30Addition of substances other than those covered by A23L15/20 – A23L15/25
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L15/00Egg products; Preparation or treatment thereof
    • A23L15/20Addition of proteins, e.g. hydrolysates, fats, carbohydrates, natural plant hydrocolloids; Addition of animal or vegetable substances containing proteins, fats, or carbohydrates

Definitions

  • fine sense of the present invention is boiled egg yolk, c related to egg yolk-like food boiled with a texture that was Hokuhoku
  • the texture of the egg yolk which is obtained by heating the egg while it is shelled, is divided into egg yolk without breaking the yolk membrane at the time of cleavage, and the egg yolk is heated.
  • the ones that have been sliced or shredded and seasoned with mayonnaise are popular ingredients and are used in various foods such as sandwiches and salads.
  • Patent Document 1 discloses a method in which an egg liquid and a water-insoluble protein are mixed and then heated to obtain a heated coagulated egg having a texture like egg yolk. In this method, however, it is necessary to prepare a water-insoluble protein in advance. In addition, it is not easy to make soy protein water-insoluble by heating under severe conditions such as high concentration, high temperature and high pressure. Also, it is not practical because it involves a complicated process of grinding the gel or aggregated structure thus obtained to 50-500 m.
  • Patent Document 2 Patent Publication No. 2531745
  • Patent Document 2 JP-A-11-089518
  • An object of the present invention is to provide a boiled egg yolk-like food having a fine grain texture unique to boiled egg yolk and a chewy texture.
  • soybean protein solution is agglomerated in advance under severe heating conditions such as high temperature and high pressure, and then pulverized, so that a complicated process is required. I need to go through.
  • a method for producing boiled egg yolk-like food characterized by mixing one or more of a soy protein material, a calcium compound and a magnesium compound, and a raw material containing an egg material, followed by heat coagulation and stirring.
  • Boiled egg yolk-like food consisting of a block obtained by mixing soybean protein material, one or more of calcium compound and magnesium compound, and raw materials containing egg material, heat coagulation and stirring,
  • the present invention aims to produce and supply boiled egg yolk-like food that uses a soy protein material in combination with an egg material, and is a soy protein material that is a plant-based material that can be stably supplied at low cost. To reduce production costs, reduce risks related to raw material storage, stable production, etc. There is an effect. Secondarily, in addition to nutrients derived from egg materials, it is possible to ingest nutrients contained in soybean protein materials and various physiologically active substances.
  • the boiled egg yolk-like food according to the present invention contains one or more of soybean protein material, egg material, calcium compound and magnesium compound as essential components.
  • the soy protein material in the present invention is isolated soy protein, its emulsion, concentrated soy protein, defatted soy milk, soy milk and the like.
  • the soy protein material is contained in an egg yolk-like food in home potatoes in an amount of 5 to 25% by weight, preferably 9 to 20% by weight in terms of crude protein. If it is too much, the egg flavor will be dilute. On the other hand, if the amount is too little, the rubbery texture of the heat-coagulated material of the egg material becomes strong, and a boiled egg yolk-like texture cannot be obtained.
  • the calcium compound and magnesium compound in the present invention are magnesium chloride, calcium sulfate, calcium chloride, calcium hydroxide and the like. Also included are bitterns containing magnesium chloride and calcium chloride. Use these alone or in combination of two or more.
  • the amount of calcium compound and magnesium compound in the production of egg yolk-like foods on the main rice cake is 16 to 71 mmol, preferably 20 to 65 mmol in terms of calcium or magnesium per 100 g of crude protein mass (CP) of soybean protein material. It is. If both are acceptable, make sure that the total amount of both is within the above range! Calcium compounds and magnesium compounds agglomerate soybean protein, and the agglomerated soybean protein has a fine grain feeling similar to egg yolk. In order to weaken soy protein gellica, the cohesive strength of soy protein aggregates is reduced, and boiled egg yolk-like foods are given a boiled egg yolk-like food texture.
  • the soy protein agglomerate inhibits the egg material from coagulating to form a rubbery texture tissue, so that an egg yolk-like texture can be obtained by boiling. Therefore, if there is too little calcium compound or magnesium compound, the fine grain feeling and hokuhoku feeling of boiled egg yolk-like food will be poor.
  • soy protein material and the calcium compound or magnesium compound may be mixed in the manufacturing process of boiled egg yolk-like food, or may be mixed in advance during the manufacturing process of the soy protein material.
  • Mixing can be done by adding and adding a ruthenium compound or a magnesium compound.
  • the soybean protein material is sufficiently hydrated in advance, or it is good to disperse. Suppresses the occurrence of lumps during mixing and can be quickly finished into an egg yolk-like food.
  • the latter case is also preferable because the dispersibility of the soy protein material is improved, and it is not necessary to add a calcium compound or the like.
  • the calcium compound and magnesium compound added during the manufacturing process should be taken into account, and if necessary, supplemented with the manufacturing process of the boiled egg yolk-like food within the above mixing range. May be.
  • the upper limit of the calcium compound corresponding to the food additive is 1% by weight as the calcium content in the food. Therefore, adjust the amount of soy protein material, egg material, and auxiliary material so that the boiled egg yolk-like food does not contain any calcium compounds that correspond to food additives.
  • egg material in the present invention whole egg, egg yolk, or a mixed egg in which egg yolk and egg white are mixed at a desired ratio can be used.
  • the whole egg, egg yolk, and egg white used here may be in any form, for example, liquid or dry matter.
  • Egg white is not essential, but egg yolk is essential because it is boiled and preferable in terms of flavor of egg yolk-like food, and the weight ratio of egg yolk to egg white is preferably 4.5: 1 or more in terms of dry solids.
  • the blended amount of egg material in boiled egg yolk-like food is 8 to 25% by weight, more preferably 12 to 25% by weight in terms of solid content (DM). If the amount of egg material is large, the yolk flavor of egg yolk-like food becomes stronger with boil, but if the ratio of egg material is too high, the feeling of hokuhoku and fine grain will be poor, making it meaningless as a substitute for egg yolk. .
  • Egg yolk-like foods are also preferred, and include starchy compositions, fats and oils, seasonings, pH adjusters, dietary fibers such as porridge, flavors, and pigments as sub-materials without any particular limitations. it can . Egg yolk-like foods tend to flicker when the amount of soy protein material is high, but the fats and oils suppress this to give a moist texture and make the tongue and the throat feel more authentic.
  • As fats and oils conventionally known vegetable fats, animal fats and other edible fats and oils can be used without particular limitation. When fats and oils are blended, 5 to 20% by weight, preferably 8 to 15% by weight is appropriate.
  • a malon paste that is also a flavoring agent
  • pumpkin paste can impart a favorable texture and egg yolk-like color to egg yolk-like foods.
  • Boiled egg yolk-like food is a mixture of one or more of soy protein material, calcium compound and magnesium compound, egg material, and water, fats and oils as necessary. Mix and homogenize all ingredients thoroughly.
  • the mixing order of each raw material is not limited.
  • the mixture is solidified by heating and made into blocks (chopped) by stirring. If the block (chopped material) is too rough, a foreign body sensation will be felt, so the diameter of the block should be 7 mm or less, preferably 5 mm or less.
  • the size of the block need not be uniform, and may vary as long as the diameter is 7 mm or less.
  • the number of blocks can be adjusted according to the shape of the blades, the number of stirring, and the stirring time, which is a simple method. Moreover, block formation by heat coagulation and stirring may be performed simultaneously. The smaller the block, the better.
  • a continuous type heat exchanger it can be easily performed from mixing to blocking by heating and stirring, and the burning can be suppressed by stirring during heating.
  • Some of the continuous heat exchangers with lids have a lid and can suppress the evaporation of moisture during heating.
  • the heating conditions are not particularly limited, and it is sufficient if the egg yolk-like food is not burnt and is sufficiently solidified and sterilized, for example, 70 to 80 ° C. Heating also involves sterilization.
  • the boiled egg yolk-like food in the present invention may be eaten as it is, it may be further eaten by mixing with other foods. For example, it may be mixed with egg boiled or shredded eggs, mayonnaise, dressing, etc.
  • the solution was sufficiently stirred with a homomixer and spray-dried with an atomizer to obtain a dry powder.
  • the CP content of the obtained dry powder was 83% by weight (30 mmol in terms of calcium per CPlOOg of soybean protein).
  • Put 500g of this dry powder and 700g of pasteurized liquid egg yolk (Kupie Corporation, DM 51%), lkg of water, 250g of rapeseed white tightening oil into a continuous heat exchanger with a lid, and stir at 80 ° C for 8 minutes. (500 rpm) was heated. After heating, stirring was continued in a continuous heat exchanger with a scraper to obtain an egg yolk-like food consisting of a block having a size of 5 mm or less.
  • the eggs with shells were heated in 90 ° C hot water for 20 minutes and then cooled to remove the shells and egg whites to obtain egg yolks by boiling.
  • Table 1 shows the evaluation by 10 panelists.
  • Test plot 1 Test plot 2 Control plot 2 Equivalent to egg yolk 0% 0% 100%

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Nutrition Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Botany (AREA)
  • Molecular Biology (AREA)
  • Meat, Egg Or Seafood Products (AREA)

Abstract

It is intended to produce and provide a boiled egg yolk-like food, which has a granular touch and a tender-crisp texture similar to boiled egg yolk, by using an egg material together with a soybean protein material. It is also intended to reduce the production cost, reduce the risk during the storage of the starting materials, stably produce the product and so on. It is secondarily intended to enable the intake of nutrients and various physiologically active substances contained in the soybean protein material in addition to the nutrients originating in the egg material. By blending a soybean protein material with a calcium compound, a magnesium compound and an egg material and coagulating the obtained mixture under heating followed by agitation, it is possible to prepare a food having a granular touch and a tender-crisp texture similar to boiled egg yolk without resorting to a complicated process. According to the above-described method, it is unnecessary to preliminarily coagulate a soybean protein solution under severe conditions (for example, at a high temperature or a high pressure) and ground the coagulated matter so as to obtain insolubilized soybean protein particles.

Description

明 細 書  Specification
茹で卵黄様食品  Boiled egg yolk-like food
技術分野  Technical field
[0001] 本発明は茹で卵黄の細粒感、ホクホクした食感を持つ茹で卵黄様食品に関する c [0001] fine sense of the present invention is boiled egg yolk, c related to egg yolk-like food boiled with a texture that was Hokuhoku
背景技術 Background art
[0002] 卵を殻付のまま加熱して得られるかた茹で卵の卵黄や、割卵時に卵黄膜を破らずに 卵白と分け、加熱した卵黄のホクホクとした食感は独特である。これを裏ごしまたは細 断しマヨネーズ等で調味したものはポピュラーな食材であり、サンドイッチやサラダ等 さまざまな食品に使われている。  [0002] The texture of the egg yolk, which is obtained by heating the egg while it is shelled, is divided into egg yolk without breaking the yolk membrane at the time of cleavage, and the egg yolk is heated. The ones that have been sliced or shredded and seasoned with mayonnaise are popular ingredients and are used in various foods such as sandwiches and salads.
[0003] こうした茹で卵黄独特の食感は、卵黄膜を破壊することなく加熱しないと得られない。  [0003] Such a texture unique to egg yolk cannot be obtained without heating without destroying the yolk membrane.
卵黄膜が破れた卵黄液を加熱しても、弾力に富むゴム様の食感となってしまうからで ある。しかし茹で卵を作りこれの卵黄部分だけを取り出すのは手間である。或いは割 卵し卵黄膜を壊さな 、ように卵黄のみを取り出し、これを加熱するのも技術を要する。 このため卵黄膜が無傷のままで加熱した卵黄を作らずともできる、茹で卵黄様食感を 持つ食品の製造法が検討されてきた。それらは他のたん白を加工し、茹で卵黄様食 感を出そうとする技術である。  This is because even when the yolk liquid with a broken yolk membrane is heated, it becomes a rubber-like texture rich in elasticity. However, it is troublesome to make eggs with boil and take out only the yolk portion. Alternatively, it is necessary to take out only the yolk and heat it so that the egg yolk membrane is not broken and broken. For this reason, methods have been investigated for producing foods with a boiled egg yolk-like texture that can be used without producing egg yolks that are heated with the yolk membrane intact. They are technologies that process other proteins and try to give them an egg yolk-like texture with rice cakes.
[0004] 特許文献 1には、卵液と水不溶性たん白質を混合した後加熱し、茹で卵黄の様な食 感を持つ加熱凝固卵を得る方法が開示されている。し力しこの方法では、予め水不 溶性たん白質を調製する必要がある。また加熱によって大豆たん白質を水不溶性に するには、高濃度且つ高温、高圧といった過酷な条件での加熱を要し容易ではない 。またこうして得られるゲルまたは凝集状の構造体を 50-500 mに粉砕する煩雑なェ 程を伴うため実用的ではな!/、。  [0004] Patent Document 1 discloses a method in which an egg liquid and a water-insoluble protein are mixed and then heated to obtain a heated coagulated egg having a texture like egg yolk. In this method, however, it is necessary to prepare a water-insoluble protein in advance. In addition, it is not easy to make soy protein water-insoluble by heating under severe conditions such as high concentration, high temperature and high pressure. Also, it is not practical because it involves a complicated process of grinding the gel or aggregated structure thus obtained to 50-500 m.
[0005] 一方、個々に分離した壊れて 、な 、細胞壁に囲まれた植物性の粒子を結着剤で結 着させた、かた茹で卵の卵黄部の様な細粒感とホクホクした食感を持つ食品がある( 特許文献 2)。し力しこれは大豆たん白、卵液、カルシウム化合物やマグネシウム化合 物を混合したものを加熱凝固させて得られる茹で卵黄様食品とは異なる。 [0006] 特許文献 1:特許公報第 2531745 [0005] On the other hand, broken, individually separated, plant-like particles surrounded by cell walls are bound with a binder. There is a food with a feeling (Patent Document 2). This is different from egg yolk-like foods that are obtained by heating and coagulating a mixture of soybean protein, egg liquid, calcium compounds and magnesium compounds. [0006] Patent Document 1: Patent Publication No. 2531745
特許文献 2 :特開平 11-089518  Patent Document 2: JP-A-11-089518
発明の開示  Disclosure of the invention
発明が解決しょうとする課題  Problems to be solved by the invention
[0007] 本発明は、茹で卵黄独特の細粒感とホクホクした食感を持つ茹で卵黄様食品を提 供することを課題とする。 [0007] An object of the present invention is to provide a boiled egg yolk-like food having a fine grain texture unique to boiled egg yolk and a chewy texture.
課題を解決するための手段  Means for solving the problem
[0008] 本発明者らは上記課題に対して鋭意検討を行った結果、大豆たん白、カルシウム 化合物やマグネシウム化合物、卵素材を混合'加熱したものは、カルシウム化合物や マグネシウム化合物により凝集した大豆たん白のために細粒感、ホクホク感を有する ことを見出し、本発明を完成させた。本発明によれば、不溶化された大豆たん白の粒 子を得るために、予め大豆たん白溶液を高温、高圧等の過酷な加熱条件で凝集さ せ、これを粉砕すると 、つた煩雑な工程を経る必要がな 、。 [0008] As a result of intensive studies on the above problems, the inventors of the present invention have mixed and heated soybean protein, calcium compound, magnesium compound, and egg material, soy protein agglomerated with calcium compound or magnesium compound. As a result of white, it was found that it had a fine grained feeling and a feeling of tingling, and the present invention was completed. According to the present invention, in order to obtain insolubilized soybean protein particles, the soybean protein solution is agglomerated in advance under severe heating conditions such as high temperature and high pressure, and then pulverized, so that a complicated process is required. I need to go through.
すなわち本発明は、  That is, the present invention
1.大豆たん白素材、カルシウム化合物及びマグネシウム化合物の 1種または 2種以 上、並びに卵素材を含む原料を混合し、加熱凝固'攪拌することを特徴とする茹で卵 黄様食品の製造方法、  1. A method for producing boiled egg yolk-like food, characterized by mixing one or more of a soy protein material, a calcium compound and a magnesium compound, and a raw material containing an egg material, followed by heat coagulation and stirring.
2.茹で卵黄様食品中の大豆たん白素材の混合量が粗たん白質換算で 5〜25重量 %である 1記載の製造方法、  2. The production method according to 1, wherein the amount of the soy protein material in the boiled egg yolk-like food is 5 to 25% by weight in terms of crude protein,
3.大豆たん白素材、カルシウム化合物及びマグネシウム化合物の 1種または 2種以 上、並びに卵素材を含む原料を混合し、加熱凝固'攪拌して得られるブロックからな る茹で卵黄様食品、  3. Boiled egg yolk-like food consisting of a block obtained by mixing soybean protein material, one or more of calcium compound and magnesium compound, and raw materials containing egg material, heat coagulation and stirring,
を提供するものである。  Is to provide.
発明の効果  The invention's effect
[0009] 本発明は、卵素材に大豆たん白素材を併用した茹で卵黄様食品の生産、供給を 目的とするものであり、安価且つ安定に供給可能な植物系原料である大豆たん白素 材を用いることで、生産コストの低減、原料保管に関するリスク低減、安定な生産など の効果がある。副次的には卵素材由来の栄養素に加え、大豆たん白素材に含まれ る栄養素、各種生理活性物質の摂取が可能となる。 [0009] The present invention aims to produce and supply boiled egg yolk-like food that uses a soy protein material in combination with an egg material, and is a soy protein material that is a plant-based material that can be stably supplied at low cost. To reduce production costs, reduce risks related to raw material storage, stable production, etc. There is an effect. Secondarily, in addition to nutrients derived from egg materials, it is possible to ingest nutrients contained in soybean protein materials and various physiologically active substances.
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0010] 本発明における茹で卵黄様食品は、大豆たん白素材、卵素材、カルシウム化合物及 びマグネシウム化合物の 1種または 2種以上を必須の成分として含む。本発明におけ る大豆たん白素材とは、分離大豆たん白、そのェマルジヨン、濃縮大豆たん白、脱脂 豆乳、豆乳等である。  [0010] The boiled egg yolk-like food according to the present invention contains one or more of soybean protein material, egg material, calcium compound and magnesium compound as essential components. The soy protein material in the present invention is isolated soy protein, its emulsion, concentrated soy protein, defatted soy milk, soy milk and the like.
[0011] 大豆たん白素材は、本茹で卵黄様食品中に粗たん白質換算で 5〜25重量%含まれ 、好ましくは 9〜20重量%である。多すぎると卵の風味が希薄となる。また少なすぎる と卵素材の加熱凝固物のゴム状の食感が強くなり、茹で卵黄様のホクホクした食感が 得られない。  [0011] The soy protein material is contained in an egg yolk-like food in home potatoes in an amount of 5 to 25% by weight, preferably 9 to 20% by weight in terms of crude protein. If it is too much, the egg flavor will be dilute. On the other hand, if the amount is too little, the rubbery texture of the heat-coagulated material of the egg material becomes strong, and a boiled egg yolk-like texture cannot be obtained.
[0012] 本発明におけるカルシウム化合物やマグネシウム化合物は、塩化マグネシウム、硫 酸カルシウム、塩化カルシウム、水酸化カルシウム等である。また塩化マグネシウムや 塩ィ匕カルシウムを含有するにがり等も含まれる。これらを単独で、あるいは 2つ以上を 組み合わせて用いる。  [0012] The calcium compound and magnesium compound in the present invention are magnesium chloride, calcium sulfate, calcium chloride, calcium hydroxide and the like. Also included are bitterns containing magnesium chloride and calcium chloride. Use these alone or in combination of two or more.
[0013] 本茹で卵黄様食品の製造におけるカルシウム化合物やマグネシウム化合物の混合 量は、大豆たん白素材の粗たん白質量 (CP) 100g当たりカルシウムまたはマグネシゥ ム換算で 16〜71mmol、好ましくは 20〜65mmolである。両者を併用してもよぐその 場合は両者の総混合量が上記範囲に収まるようにすればよ!、。カルシウム化合物や マグネシウム化合物は大豆たん白を凝集させ、凝集した大豆たん白は茹で卵黄に似 た細粒感を有する。また大豆たん白のゲルィ匕カを弱めるために、大豆たん白の凝集 物同士の決着力を減少させ、茹で卵黄様食品に茹で卵黄様のホクホクした食感を与 える。また大豆たん白の凝集物は、卵素材が凝固してゴム状食感の組織を形成する のを阻害するため、茹で卵黄様食感が得られる。従ってカルシウム化合物やマグネ シゥム化合物が少なすぎると茹で卵黄様食品の細粒感、ホクホク感が乏しくなるため 好ましくなぐ多すぎると風味的に好ましくない。  [0013] The amount of calcium compound and magnesium compound in the production of egg yolk-like foods on the main rice cake is 16 to 71 mmol, preferably 20 to 65 mmol in terms of calcium or magnesium per 100 g of crude protein mass (CP) of soybean protein material. It is. If both are acceptable, make sure that the total amount of both is within the above range! Calcium compounds and magnesium compounds agglomerate soybean protein, and the agglomerated soybean protein has a fine grain feeling similar to egg yolk. In order to weaken soy protein gellica, the cohesive strength of soy protein aggregates is reduced, and boiled egg yolk-like foods are given a boiled egg yolk-like food texture. The soy protein agglomerate inhibits the egg material from coagulating to form a rubbery texture tissue, so that an egg yolk-like texture can be obtained by boiling. Therefore, if there is too little calcium compound or magnesium compound, the fine grain feeling and hokuhoku feeling of boiled egg yolk-like food will be poor.
[0014] 尚、大豆たん白素材と上記カルシウム化合物やマグネシウム化合物は、茹で卵黄様 食品の製造工程で混合しても良いし、予め大豆たん白素材の製造工程中に上記力 ルシゥム化合物やマグネシウム化合物を添加し含有させることで混合しても良 、。前 者の場合、予め大豆たん白素材の水和を充分に行えば良ぐ或いは分散性の良い 顆粒状のゃェマルジヨンタイプの大豆たん白素材を使用することで水、卵素材などと の混合時にダマの発生を抑え速やかに卵黄様食品に仕上げることができる。後者の 場合も、大豆たん白素材の分散性が改善されており、新たにカルシウム化合物等を 加える必要がなく好ましい。し力し後者の場合であっても製造工程中に添加したカル シゥム化合物やマグネシウム化合物を考慮し、必要に応じて上記混合量の範囲でさ らに茹で卵黄様食品の製造工程で補ってやっても良い。 [0014] It should be noted that the soy protein material and the calcium compound or magnesium compound may be mixed in the manufacturing process of boiled egg yolk-like food, or may be mixed in advance during the manufacturing process of the soy protein material. Mixing can be done by adding and adding a ruthenium compound or a magnesium compound. In the former case, it is sufficient if the soybean protein material is sufficiently hydrated in advance, or it is good to disperse. Suppresses the occurrence of lumps during mixing and can be quickly finished into an egg yolk-like food. The latter case is also preferable because the dispersibility of the soy protein material is improved, and it is not necessary to add a calcium compound or the like. However, even in the latter case, the calcium compound and magnesium compound added during the manufacturing process should be taken into account, and if necessary, supplemented with the manufacturing process of the boiled egg yolk-like food within the above mixing range. May be.
[0015] 尚、食品添加物に該当するカルシウム化合物は、その食品中の含有量がカルシウム として 1重量%が上限である。したがって茹で卵黄様食品中に、これを超えて食品添 加物に該当するカルシウム化合物が含まれない様に、大豆たん白素材、卵素材や副 素材の量を調整すればよ!、。  [0015] The upper limit of the calcium compound corresponding to the food additive is 1% by weight as the calcium content in the food. Therefore, adjust the amount of soy protein material, egg material, and auxiliary material so that the boiled egg yolk-like food does not contain any calcium compounds that correspond to food additives.
[0016] 本発明における卵素材は、全卵、卵黄、及び卵黄と卵白を好みの割合で混合した混 合卵等を用いることができる。尚、ここで用いる全卵、卵黄及び卵白は形態を問わず 、例えば液体乃至乾燥物のいずれであってもよい。卵白は必須ではないが、卵黄は 茹で卵黄様食品の風味の点において好ましいため必須であり、卵黄と卵白の重量比 は乾燥固形分で 4.5 : 1以上が好ましい。卵素材の茹で卵黄様食品への配合量は固 形分 (DM)換算で、 8から 25重量%が好ましぐさらに好ましくは 12から 25重量%で ある。卵素材の配合量が多いと茹で卵黄様食品の卵黄の風味が強くなるが、卵素材 の配合率が高すぎるとホクホク感、細粒感が乏しくなり、茹で卵黄の代替食品として の意味もなくなる。  [0016] As the egg material in the present invention, whole egg, egg yolk, or a mixed egg in which egg yolk and egg white are mixed at a desired ratio can be used. The whole egg, egg yolk, and egg white used here may be in any form, for example, liquid or dry matter. Egg white is not essential, but egg yolk is essential because it is boiled and preferable in terms of flavor of egg yolk-like food, and the weight ratio of egg yolk to egg white is preferably 4.5: 1 or more in terms of dry solids. The blended amount of egg material in boiled egg yolk-like food is 8 to 25% by weight, more preferably 12 to 25% by weight in terms of solid content (DM). If the amount of egg material is large, the yolk flavor of egg yolk-like food becomes stronger with boil, but if the ratio of egg material is too high, the feeling of hokuhoku and fine grain will be poor, making it meaningless as a substitute for egg yolk. .
[0017] 本茹で卵黄様食品はまた好みで、澱粉性組成物、油脂、調味料、 pH調整剤、おカゝら 等の食物繊維、フレーバー及び色素等を副素材として特に制限なく含むことができる 。本茹で卵黄様食品は大豆たん白素材の配合量が多いとばさつく傾向があるが、油 脂はこれを抑えてしっとりとした食感を与え、舌触り、喉越しをより本物らしくする。油 脂は従来公知の植物脂、動物脂、その他食用油脂を特に制限なく用いることができ る。油脂を配合する場合、 5から 20重量%、好ましくは 8から 15重量%が適当である 。澱粉性組成物としては従来公知の澱粉類に加え、風味剤でもあるマロンペースト、 さつま芋のペースト等のペースト類が例示される力 なかでもかぼちゃペーストは、本 茹で卵黄様食品に好ましい食感と茹で卵黄様の色を付与することができる。 [0017] Egg yolk-like foods are also preferred, and include starchy compositions, fats and oils, seasonings, pH adjusters, dietary fibers such as porridge, flavors, and pigments as sub-materials without any particular limitations. it can . Egg yolk-like foods tend to flicker when the amount of soy protein material is high, but the fats and oils suppress this to give a moist texture and make the tongue and the throat feel more authentic. As fats and oils, conventionally known vegetable fats, animal fats and other edible fats and oils can be used without particular limitation. When fats and oils are blended, 5 to 20% by weight, preferably 8 to 15% by weight is appropriate. As a starch composition, in addition to conventionally known starches, a malon paste that is also a flavoring agent, Among the powers exemplified by pastes such as sweet potato paste, among others, pumpkin paste can impart a favorable texture and egg yolk-like color to egg yolk-like foods.
[0018] 茹で卵黄様食品は、大豆たん白素材、カルシウム化合物及びマグネシウム化合物の 1種または 2種以上、卵素材、必要に応じて水、油脂類の副素材を混合し、大豆たん 白質を水和させると共に、全原料を十分に混ぜ合わせ均質にする。各原料の混合順 序は問わない。混合物は加熱により凝固させ、攪拌によってブロック状 (細断化)にす る。ブロック (細断物)は粗すぎると異物感が感じられてしまうため、ブロックの直径の 大きさは 7mm以下、好ましくは 5mm以下にする。ブロックの大きさは均一である必要は なぐ直径が 7mm以下であればばらつきがあって良い。羽根の形や攪拌数、攪拌時 間によりブロックの多きさは調節可能であり、簡便な方法である。また加熱凝固と攪拌 によるブロック化を同時に行ってもよい。ブロックは細かいほど好ましぐ特に下限は ない。  [0018] Boiled egg yolk-like food is a mixture of one or more of soy protein material, calcium compound and magnesium compound, egg material, and water, fats and oils as necessary. Mix and homogenize all ingredients thoroughly. The mixing order of each raw material is not limited. The mixture is solidified by heating and made into blocks (chopped) by stirring. If the block (chopped material) is too rough, a foreign body sensation will be felt, so the diameter of the block should be 7 mm or less, preferably 5 mm or less. The size of the block need not be uniform, and may vary as long as the diameter is 7 mm or less. The number of blocks can be adjusted according to the shape of the blades, the number of stirring, and the stirring time, which is a simple method. Moreover, block formation by heat coagulation and stirring may be performed simultaneously. The smaller the block, the better.
[0019] 例えば搔きとり式連続熱交換機を用いれば、混合から加熱、攪拌によるブロック化ま で行え簡便であるし、加熱時の攪拌によって焦げ付きを抑えることができる。搔きとり 式連続熱交換機は蓋が付いたものがあり、加熱中の水分の蒸散を抑えることができ る。加熱条件は特に限定されず、卵黄様食品の焦げ付きが生じず且つ凝固、殺菌が 充分であれば良ぐ例えば 70〜80°Cにて行う。また加熱は殺菌も伴う。  [0019] For example, if a continuous type heat exchanger is used, it can be easily performed from mixing to blocking by heating and stirring, and the burning can be suppressed by stirring during heating. Some of the continuous heat exchangers with lids have a lid and can suppress the evaporation of moisture during heating. The heating conditions are not particularly limited, and it is sufficient if the egg yolk-like food is not burnt and is sufficiently solidified and sterilized, for example, 70 to 80 ° C. Heating also involves sterilization.
[0020] 本発明における茹で卵黄様食品はそのまま食しても良いが、他の食品と混合するな どしてさらに力卩ェし食しても良い。たとえば茹で卵を裏ごし又は細断したもの、マヨネ ーズ、ドレッシング等と混合しても良い。  [0020] Although the boiled egg yolk-like food in the present invention may be eaten as it is, it may be further eaten by mixing with other foods. For example, it may be mixed with egg boiled or shredded eggs, mayonnaise, dressing, etc.
実施例 1  Example 1
[0021] 脱脂大豆に 15倍加水し、 50°C、 pH7. 0において 30分間抽出後、遠心分離し、脱 脂豆乳を得た。その脱脂豆乳に塩酸を加え、 pH4. 5とした後、遠心分離し、カードを 得た。そのカードに 10%濃度になるように加水した後、対乾物量当たり 0. 8%のカル シゥムになるように水酸化カルシウムを添カ卩し、更に水酸化ナトリウムをカ卩え、 pH6. 5 もしくは 6. 7とした。その分離大豆蛋白溶液を 140°Cで 15秒間加熱後、 60°Cまで冷 却し、ホモミキサーで攪拌しながら、対固形分で 0. 2%のカルシウムになるように塩ィ匕 カルシウム溶液を添加し、終濃度が対固形分で 1. 0%のカルシウムになるようにした 。その溶液をホモミキサーで十分攪拌後、アトマイザ一により噴霧乾燥して乾燥粉末 を得た。得られた乾燥粉末の CP含量は 83重量%であった(大豆たん白の CPlOOg当 たりカルシウム換算で 30mmol)。この乾燥粉末 500gと殺菌液状卵黄 (キューピー株 式会社、 DM = 51%) 700g、水 lkg、菜種白締油 250gを蓋つきの搔きとり式連続熱 交換機に投入し、 80°Cで 8分間攪拌 (500r.p.m)加熱をした。加熱後、搔きとり式連 続熱交換機内で攪拌を続け 5mm以下の大きさのブロックからなる茹で卵黄様食品を 得た。 [0021] Water was added 15 times to defatted soybeans, extracted at 50 ° C and pH 7.0 for 30 minutes, and then centrifuged to obtain defatted soymilk. Hydrochloric acid was added to the defatted soymilk to adjust the pH to 4.5, followed by centrifugation to obtain a curd. Add water to the curd to a concentration of 10%, add calcium hydroxide to 0.8% calcium to dry matter, add sodium hydroxide, and add pH 6.5. Or 6.7. The separated soy protein solution is heated at 140 ° C for 15 seconds, then cooled to 60 ° C, and stirred with a homomixer, the salted calcium solution is added to a solid content of 0.2% calcium. Added to a final concentration of 1.0% calcium to solids . The solution was sufficiently stirred with a homomixer and spray-dried with an atomizer to obtain a dry powder. The CP content of the obtained dry powder was 83% by weight (30 mmol in terms of calcium per CPlOOg of soybean protein). Put 500g of this dry powder and 700g of pasteurized liquid egg yolk (Kupie Corporation, DM = 51%), lkg of water, 250g of rapeseed white tightening oil into a continuous heat exchanger with a lid, and stir at 80 ° C for 8 minutes. (500 rpm) was heated. After heating, stirring was continued in a continuous heat exchanger with a scraper to obtain an egg yolk-like food consisting of a block having a size of 5 mm or less.
実施例 2  Example 2
[0022] 粉末状大豆たん白サンラバー 10 (不二製油株式会社製、 CP含量 59重量%)を 500g と殺菌液状卵黄 (キューピー株式会社製、 DM = 51%) 700g、水 lkg、硫酸カルシ ゥム 25g、菜種白締油 250gを蓋つきの搔きとり式連続熱交 に投入し、 80°Cで 8 分間攪拌(500r.p.m)加熱をした。カルシウム化合物の混合量は、大豆たん白の CP1 00g当たりカルシウム換算で 62mmolであった。加熱後、搔きとり式連続熱交換機内で 攪拌を続け 5mm以下の大きさのブロックカゝらなる茹で卵黄様食品を得た。  [0022] 500 g powdered soybean protein sun rubber 10 (manufactured by Fuji Oil Co., Ltd., CP content 59% by weight) and 700 g sterilized liquid egg yolk (manufactured by Kewpie Co., Ltd., DM = 51%), lkg water, calcium sulfate 25 g and 250 g of rapeseed white fastening oil were placed in a continuous continuous heat exchanger with a lid, and heated at 80 ° C for 8 minutes with stirring (500 rpm). The mixing amount of the calcium compound was 62 mmol in terms of calcium per 100 g of CP of soybean protein. After heating, stirring was continued in a continuous heat exchanger, and egg yolk-like food was obtained in a bowl of 5 mm or less in size.
(比較例 1)  (Comparative Example 1)
粉末状大豆たん白サンラバー 10 (不二製油株式会社製、 CP含量 59重量%)を 500g と殺菌液状卵黄 (キューピー株式会社製、 DM = 51%) 700g、水 lkg、菜種白締油 250gを蓋つきの搔きとり式連続熱交換機に投入し、 80°Cで 8分間攪拌 (500r.p.m) 加熱をした。加熱後、搔きとり式連続熱交換機内で攪拌を続け 5mm以下の大きさの ブロックは得られた力 加熱凝固した卵液のような食感であり、茹で卵黄様の細粒感 、ホクホク感に乏しいものであった。  500g powdered soybean protein sun rubber 10 (manufactured by Fuji Oil Co., Ltd., CP content 59% by weight) and 700g pasteurized liquid egg yolk (manufactured by Kewpie Co., Ltd., DM = 51%), lkg water, 250g rapeseed white tightening oil It was put into a Tsukihitori type continuous heat exchanger and heated at 80 ° C for 8 minutes with stirring (500 rpm). After heating, stirring is continued in a continuous heat exchanger with a scraper. Blocks with a size of 5 mm or less are obtained. The texture is like heat-coagulated egg liquid. It was poor.
(対照区 1)  (Control 1)
[0023] 殻付鶏卵を 90°Cの湯中で 20分間加熱後冷却し、殻と卵白部を除去して茹で卵黄を 得た。  [0023] The eggs with shells were heated in 90 ° C hot water for 20 minutes and then cooled to remove the shells and egg whites to obtain egg yolks by boiling.
(テスト区 1)  (Test Zone 1)
[0024] 実施例 1で得た茹で卵黄様食品を 150g、対象区 1で得た茹で卵黄を 150g、茹でた 卵白 200gを 3mm角程度に細断したもの、みじん切りした生玉葱 100g、マヨネーズ 4 OOgをよく混合して卵フィリングを得た。 (テスト区 2) [0024] 150 g of boiled egg yolk-like food obtained in Example 1, 150 g of boiled egg yolk obtained in target area 1, 200 g of boiled egg white chopped to about 3 mm square, 100 g of chopped raw onion cake, mayonnaise 4 OOg Were mixed well to obtain an egg filling. (Test Zone 2)
[0025] 実施例 2で得た茹で卵黄様食品を 150g、対象区で得た茹で卵黄を 150g、茹でた卵 白 200gを 3mm角程度に細断したもの、みじん切りした生玉葱 100g、マヨネーズ 40 Ogをよく混合して卵フイリングを得た。  [0025] 150 g of boiled egg yolk-like food obtained in Example 2, 150 g of boiled egg yolk obtained in the target area, 200 g of boiled egg white chopped to about 3 mm square, 100 g of chopped raw onion, mayonnaise 40 Og The egg filling was obtained by mixing well.
(対照区 2)  (Control 2)
[0026] 対照区 1で得た茹で卵黄を 300g、茹でた卵白 200gを 3mm角程度に細断したもの、 みじん切りみじん生玉葱 lOOg、マヨネーズ 400gをよく混合して卵フィリングを得た。 以上の各サンプルについて共食して食感、風味を評価したところ表 1の結果が得ら れた。  [0026] 300 g of boiled egg yolk obtained in control group 1, 200 g of boiled egg white, chopped to about 3 mm square, finely chopped raw onion lOOg and mayonnaise 400 g were mixed well to obtain an egg filling. When the above samples were eaten together and the texture and flavor were evaluated, the results shown in Table 1 were obtained.
尚、表 1はパネラー 10名による評価である。  Table 1 shows the evaluation by 10 panelists.
<茹で卵黄様食品の評価結果: 5段階評価にて実施 >  <Evaluation results of boiled egg yolk-like food: implemented in a 5-level evaluation>
テスト区 1 テスト区 2 対照区 2 卵黄と全く同等 0% 0% 100%  Test plot 1 Test plot 2 Control plot 2 Equivalent to egg yolk 0% 0% 100%
近似許容範囲 80% 80% 0%  Approximate tolerance 80% 80% 0%
やや卵黄的 20% 20% 0%  Slightly yolk 20% 20% 0%
わずかに卵黄的 0% 0% 0%  Slightly yolk 0% 0% 0%
全く異なる 0% 0% 0%  Completely different 0% 0% 0%

Claims

請求の範囲 The scope of the claims
[1] 大豆たん白素材、カルシウム化合物及びマグネシウム化合物の 1種または 2種以上、 並びに卵素材を含む原料を混合し、加熱凝固'攪拌することを特徴とする茹で卵黄 様食品の製造方法。  [1] A method for producing a boiled egg yolk-like food comprising mixing a soybean protein material, one or more of a calcium compound and a magnesium compound, and a raw material containing an egg material, followed by heat coagulation and stirring.
[2] 茹で卵黄様食品中の大豆たん白素材の混合量が粗たん白質換算で 5〜25重量%で ある請求項 1記載の製造方法。  [2] The method according to claim 1, wherein the amount of the soy protein material in the boiled egg yolk-like food is 5 to 25% by weight in terms of crude protein.
[3] 大豆たん白素材、カルシウム化合物及びマグネシウム化合物の 1種または 2種以上、 並びに卵素材を含む原料を混合し、加熱凝固'攪拌して得られるブロックからなる茹 で卵黄様食品。 [3] Boiled egg yolk-like food comprising a block obtained by mixing one or more of a soy protein material, a calcium compound and a magnesium compound, and a raw material containing an egg material, followed by heat coagulation and stirring.
PCT/JP2007/061417 2006-06-28 2007-06-06 Boiled egg yolk-like food WO2008001588A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010110285A (en) * 2008-11-07 2010-05-20 Marudai Food Co Ltd Method for producing egg processed food and egg processed food produced by the method
JP2010161939A (en) * 2009-01-13 2010-07-29 Marudai Food Co Ltd Method for producing egg processed food and the egg processed food produced by the same
CN108157841A (en) * 2018-01-04 2018-06-15 邬惠林 The method that the egg that salts down is made of high-pressure bottle
CN113040342A (en) * 2021-04-15 2021-06-29 北京都丰年生态农业科技有限公司 Preparation method of natural plant egg product with curry flavor

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5836347A (en) * 1981-08-10 1983-03-03 エ−・イ−・ステ−リ−・マニユフアクチユアリング・カンパニ− Thermally gellable and gas bubble stable enzyme modified vegetable isolate
JPS59146565A (en) * 1983-02-08 1984-08-22 Riyuushiyoubou:Kk Preparation of yolk-containing membranous food
JPH01304866A (en) * 1988-05-31 1989-12-08 Q P Corp Heat-coagulated egg, preparation thereof and egg product obtained using above-mentioned egg
US5192566A (en) * 1988-05-06 1993-03-09 Cox James P Whole poultry egg analogue composition and method
JPH1189518A (en) * 1997-09-19 1999-04-06 Fuji Oil Co Ltd Food having egg yolky texture
JP2003038127A (en) * 2001-07-26 2003-02-12 Kanegafuchi Chem Ind Co Ltd Processed food of egg
US20050196513A1 (en) * 2004-02-27 2005-09-08 Lewis David A. Egg-like food product
US20060003080A1 (en) * 2004-06-28 2006-01-05 Grusby Alan H Composition and method for enhancing eggs

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2548949Y2 (en) * 1990-06-15 1997-09-24 株式会社品川工業所 Stirrer
JPH11308968A (en) * 1998-02-06 1999-11-09 Fuji Oil Co Ltd Food material having palate feeling like boiled yolk and food utilizing the same

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5836347A (en) * 1981-08-10 1983-03-03 エ−・イ−・ステ−リ−・マニユフアクチユアリング・カンパニ− Thermally gellable and gas bubble stable enzyme modified vegetable isolate
JPS59146565A (en) * 1983-02-08 1984-08-22 Riyuushiyoubou:Kk Preparation of yolk-containing membranous food
US5192566A (en) * 1988-05-06 1993-03-09 Cox James P Whole poultry egg analogue composition and method
JPH01304866A (en) * 1988-05-31 1989-12-08 Q P Corp Heat-coagulated egg, preparation thereof and egg product obtained using above-mentioned egg
JPH1189518A (en) * 1997-09-19 1999-04-06 Fuji Oil Co Ltd Food having egg yolky texture
JP2003038127A (en) * 2001-07-26 2003-02-12 Kanegafuchi Chem Ind Co Ltd Processed food of egg
US20050196513A1 (en) * 2004-02-27 2005-09-08 Lewis David A. Egg-like food product
US20060003080A1 (en) * 2004-06-28 2006-01-05 Grusby Alan H Composition and method for enhancing eggs

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SUGITA K.: "Chori no Kagaku Dai 17 Kai Tamago no Chori Netsugyoko no Riyo no Samazama", KIKKOMAN GIJUTSU JOHO, no. 129, 2001, pages 10 - 13, XP003020320 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010110285A (en) * 2008-11-07 2010-05-20 Marudai Food Co Ltd Method for producing egg processed food and egg processed food produced by the method
JP2010161939A (en) * 2009-01-13 2010-07-29 Marudai Food Co Ltd Method for producing egg processed food and the egg processed food produced by the same
CN108157841A (en) * 2018-01-04 2018-06-15 邬惠林 The method that the egg that salts down is made of high-pressure bottle
CN113040342A (en) * 2021-04-15 2021-06-29 北京都丰年生态农业科技有限公司 Preparation method of natural plant egg product with curry flavor

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