JP2002362529A - Synthetic resin thin container - Google Patents

Synthetic resin thin container

Info

Publication number
JP2002362529A
JP2002362529A JP2002105559A JP2002105559A JP2002362529A JP 2002362529 A JP2002362529 A JP 2002362529A JP 2002105559 A JP2002105559 A JP 2002105559A JP 2002105559 A JP2002105559 A JP 2002105559A JP 2002362529 A JP2002362529 A JP 2002362529A
Authority
JP
Japan
Prior art keywords
synthetic resin
container
thin
outermost layer
label
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2002105559A
Other languages
Japanese (ja)
Other versions
JP4077233B2 (en
Inventor
Takao Kurosawa
孝雄 黒沢
Hiroaki Tokuda
博昭 徳田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yoshino Kogyosho Co Ltd
Original Assignee
Yoshino Kogyosho Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yoshino Kogyosho Co Ltd filed Critical Yoshino Kogyosho Co Ltd
Priority to JP2002105559A priority Critical patent/JP4077233B2/en
Publication of JP2002362529A publication Critical patent/JP2002362529A/en
Application granted granted Critical
Publication of JP4077233B2 publication Critical patent/JP4077233B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To prevent, as a technical target, an extremely thin region from being formed on a peripheral surface due to a label edge getting into the peripheral surface of a container body, in a synthetic resin thin container formed by welding and fixing a label as an insert material to an outer peripheral surface of the molded container body, thereby preventing the peripheral wall from cracking and improving a commercial value. SOLUTION: The synthetic resin thin container comprises the synthetic resin container body which has been molded to be sufficiently thin and the label 2 welded and fixed to the outer peripheral surface of the body 1 as an insert material. The container body 1 comprises a laminate structure having its outermost layer 1c formed of a synthetic resin material with a high flexural modulus, thereby preventing the label edge 2a from getting into the peripheral wall 1a of the container body 1.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、ブロー成形される
容器本体の外周面に、インサート材であるラベルを溶着
固定して構成される合成樹脂製肉薄容器に関するもので
ある。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a thin synthetic resin container formed by welding and fixing a label as an insert material to an outer peripheral surface of a container body to be blow-molded.

【0002】[0002]

【従来の技術】各種の液状内容物の詰め替え用容器とし
て、省資源および廃棄処理の簡易化を満たすべく、胴部
の肉厚を0.1〜0.7mm程度まで薄くした、ブロー
成形等の延伸成形や射出成形手段等により成形された合
成樹脂製の肉薄容器が多用されている。
2. Description of the Related Art As containers for refilling various liquid contents, in order to satisfy resource saving and simplification of disposal processing, the thickness of a body portion is reduced to about 0.1 to 0.7 mm, such as blow molding. Thin-walled containers made of synthetic resin formed by stretch molding, injection molding means or the like are frequently used.

【0003】この肉薄容器は、基本的には従来からのブ
ロー成形容器または延伸ブロー成形容器さらには真空成
形や圧空成形等の延伸成形容器と同じ構成であるので、
従来からの延伸成形技術(特には、ブロー成形技術)を
そのまま利用し、単に、延伸量を増大させるか、容器に
延伸成形されるプリフォームまたはパリソンの寸法およ
び肉厚を小さくするだけで、簡単にかつ好適に成形する
ことができる。
[0003] Since this thin container has basically the same structure as a conventional blow-molded container or stretch blow-molded container, and also a stretch-formed container such as vacuum forming or pressure forming,
Using conventional stretch molding technology (especially blow molding technology) as it is, simply increasing the amount of stretching or reducing the size and thickness of the preform or parison stretch-molded into the container And can be suitably molded.

【0004】この合成樹脂製肉薄容器の外周面にラベル
を装着する方法として、成形金型内に合成樹脂製ラベル
をインサート材として組付けた状態で、容器本体の成形
を行なうことによって、この容器本体の外周面にラベル
を溶着固定する方法が知られている。
As a method of attaching a label to the outer peripheral surface of the thin synthetic resin container, the container main body is molded in a state where the synthetic resin label is attached as an insert material in a molding die. A method of welding and fixing a label to an outer peripheral surface of a main body is known.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、上記し
た従来技術にあっては、図3に示すように、冷却状態に
ある金型3およびラベル2に対して、容器本体1に成形
されるプリフォームまたはパリソンは加熱されて延伸成
形されるので、ラベル2の周端面の内側エッジ部2a
が、容器本体1の肉薄に成形された軟化状態の周壁1a
に食い込み、これにより周壁1aに極端に肉薄となった
極肉薄部1bが形成される。
However, in the above-mentioned prior art, as shown in FIG. 3, a preform formed in a container body 1 for a mold 3 and a label 2 in a cooled state. Alternatively, since the parison is heated and stretch-formed, the inner edge 2a of the peripheral end face of the label 2 is formed.
Is a thin peripheral wall 1a of the container body 1 in a softened state.
, Thereby forming an extremely thin portion 1b which is extremely thin on the peripheral wall 1a.

【0006】そして、この極肉薄部1bへの応力集中に
より、この極肉薄部1bから周壁1aの割れが発生し易
くなり、容器としての商品価値が損なわれてしまう、と
云う問題があった。
[0006] Then, the stress concentration on the extremely thin portion 1b tends to cause cracks in the peripheral wall 1a from the extremely thin portion 1b, thereby causing a problem that the commercial value of the container is impaired.

【0007】そこで、本発明は、上記した従来技術にお
ける問題点を解消すべく創案されたもので、延伸成形や
射出成形等で成形される容器本体の外周面に、インサー
ト材としてのラベルを溶着固定して構成される合成樹脂
製肉薄容器において、容器本体の周壁に対するラベルエ
ッジ部の食い込みにより、周壁に極肉薄部が形成される
ことを防止することを技術的課題とし、もって周壁の割
れの発生を防止し、商品価値を向上させることを目的と
する。
Therefore, the present invention has been made to solve the above-mentioned problems in the prior art, and a label as an insert material is welded to the outer peripheral surface of a container body formed by stretch molding, injection molding or the like. In a synthetic resin thin-walled container configured to be fixed, the technical problem is to prevent the formation of an extremely thin portion on the peripheral wall due to the bite of the label edge portion with respect to the peripheral wall of the container main body. The purpose is to prevent the occurrence and improve the commercial value.

【0008】[0008]

【課題を解決するための手段】上記技術的課題を解決す
る本発明のうち請求項1記載の発明の手段は、充分に肉
薄に成形された合成樹脂製容器本体と、この容器本体の
外周面にインサート材として溶着固定されたラベルとか
ら構成される容器であること、容器本体は、その最外層
を曲げ弾性の高い合成樹脂材料で形成した積層構造とさ
れていること、にある。
Means for Solving the Problems According to the first aspect of the present invention for solving the above technical problems, a synthetic resin container body formed sufficiently thin and an outer peripheral surface of the container body are provided. And a label which is welded and fixed as an insert material. The container body has a laminated structure in which the outermost layer is formed of a synthetic resin material having high bending elasticity.

【0009】ラベルをインサート材として成形される容
器本体の最外層は、曲げ弾性率の高い合成樹脂材料で形
成されているので、容器本体の周壁は曲げ変形しにくく
なり、成形性が低くなるため、ラベルの内側エッジ部
の、周壁への食い込みが防止され、従って、周壁に極肉
薄部が形成されることは全く無く、よって、その極肉薄
部への応力集中により周壁に割れが発生することが防止
される。
Since the outermost layer of the container body molded using the label as an insert material is formed of a synthetic resin material having a high flexural modulus, the peripheral wall of the container body is less likely to be bent and deformed, and the moldability is reduced. Therefore, the inner edge of the label is prevented from biting into the peripheral wall, so that the peripheral wall is never formed with an extremely thin portion, and therefore, cracks are generated on the peripheral wall due to stress concentration on the extremely thin portion. Is prevented.

【0010】請求項2記載の発明の手段は請求項1記載
の発明において、最外層を3000kg/cm以上の
曲げ弾性率を有する合成樹脂材料で形成すること、にあ
る。
A second aspect of the present invention is that, in the first aspect, the outermost layer is formed of a synthetic resin material having a flexural modulus of 3000 kg / cm 2 or more.

【0011】曲げ弾性率が3000kg/cm以上の
合成樹脂を使用することにより、ラベルの内側エッジ部
の、周壁への食い込みが防止され、従って、周壁に極肉
薄部が形成されることを無くすことができる。
By using a synthetic resin having a flexural modulus of not less than 3000 kg / cm 2 , the inner edge of the label is prevented from biting into the peripheral wall, so that an extremely thin portion is not formed on the peripheral wall. be able to.

【0012】請求項3、4、5、6、7、8、9または
10記載の発明の手段は請求項2記載の発明において、
最外層を形成する合成樹脂材料がそれぞれ請求項3は低
密度ポリエチレン樹脂、請求項4は高密度ポリエチレン
樹脂、請求項5はポリプロピレン樹脂、請求項6はナイ
ロン樹脂、請求項7はPETG、請求項8はエチレンビ
ニルアルコール共重合樹脂、請求項9は環状ポリオレフ
ィン樹脂、請求項10はポリアクリロニトリル樹脂であ
ること、にある。ここでPETGはイーストマンケミカ
ル社製の非晶性PETである。
The means of the invention described in claim 3, 4, 5, 6, 7, 8, 9 or 10 is the same as that of claim 2,
Claim 3 is a low-density polyethylene resin, Claim 4 is a high-density polyethylene resin, Claim 5 is a polypropylene resin, Claim 6 is a nylon resin, and Claim 7 is PETG. 8 is an ethylene vinyl alcohol copolymer resin, claim 9 is a cyclic polyolefin resin, and claim 10 is a polyacrylonitrile resin. Here, PETG is amorphous PET manufactured by Eastman Chemical Company.

【0013】それぞれの樹脂を用いて最外層を形成する
ことにより、ラベルの内側エッジ部の、周壁への食い込
みが防止され、従って、周壁に極肉薄部が形成されるこ
とを無くすことができる。
By forming the outermost layer using each resin, the inner edge portion of the label is prevented from biting into the peripheral wall, and therefore, the formation of an extremely thin portion on the peripheral wall can be eliminated.

【0014】[0014]

【発明の実施の形態】以下、本発明の一実施例を、図
1、2を参照しながら説明する。本発明の合成樹脂製肉
薄容器は、充分に肉薄に、好ましくは0.3〜0.5m
mの厚さにブロー成形された合成樹脂製容器本体1と、
この容器本体1の外周面にインサート材として溶着固定
された合成樹脂製ラベル2とから構成し、かつ容器本体
1は、その最外層1cを、エチレンビニルアルコール共
重合体(EVOH)、ダイレクトブロー用のポリエチレ
ンテレフタレート(PETG・商品名)や、ポリプロピ
レン(PP)、さらにはナイロン66等の曲げ弾性率の
高い合成樹脂材料で形成した積層構造としたものであ
る。
DESCRIPTION OF THE PREFERRED EMBODIMENTS One embodiment of the present invention will be described below with reference to FIGS. The thin synthetic resin container of the present invention is sufficiently thin, preferably 0.3 to 0.5 m
m, a synthetic resin container body 1 blow-molded to a thickness of m
The container body 1 is composed of a synthetic resin label 2 welded and fixed as an insert material to the outer peripheral surface of the container body 1, and the outermost layer 1c of the container body 1 is made of ethylene vinyl alcohol copolymer (EVOH), Of polyethylene terephthalate (trade name of PETG), polypropylene (PP), and a synthetic resin material having a high flexural modulus such as nylon 66.

【0015】この肉薄容器を成形するには、まず、図1
に示すように、ブロー成形金型3(図1には、割金型の
一方を示した)の内面の所定位置に、インサート材とし
てのラベル2を挿入組付けし、次いで、最外層を曲げ弾
性率の高い合成樹脂材料で形成した積層構造のパリソン
から、通常のブロー成形手段により壜体状の容器本体1
をブロー成形し、これにより肉薄に成形された周壁1a
の外周面にラベル2を溶着固定する。なお、図1中、3
aは金型3を冷却するための冷却孔である。
To form the thin container, first, FIG.
As shown in FIG. 1, a label 2 as an insert material is inserted into a predetermined position on the inner surface of a blow molding die 3 (one of the split dies is shown in FIG. 1), and then the outermost layer is bent. From a parison having a laminated structure formed of a synthetic resin material having a high elastic modulus, a bottle-shaped container main body 1 is formed by ordinary blow molding.
Is blow-molded, and thereby the peripheral wall 1a formed thin.
The label 2 is fixed to the outer peripheral surface by welding. In FIG. 1, 3
a is a cooling hole for cooling the mold 3.

【0016】その場合において、周壁1aの最外層1c
は、曲げ弾性率の高い合成樹脂材料で形成されているの
で、ラベル2の内側エッジ部2aの、周壁1aへの食い
込みは防止され、従って、周壁1aに極肉薄部1b(図
3参照)が形成されることは全く無く、全体的に略均一
な厚さの周壁1aに成形される(図2参照)ので、割れ
の発生が全く無い。
In this case, the outermost layer 1c of the peripheral wall 1a
Is formed of a synthetic resin material having a high flexural modulus, so that the inner edge portion 2a of the label 2 is prevented from biting into the peripheral wall 1a. Therefore, the extremely thin portion 1b (see FIG. 3) is formed on the peripheral wall 1a. It is not formed at all, and is formed on the peripheral wall 1a having a substantially uniform thickness as a whole (see FIG. 2), so that no crack is generated.

【0017】肉薄容器の成形手法としては、ブロー成
形、2軸延伸ブロー成形、射出成形、真空成形、圧空成
形等の利用が可能である。
As a method for forming a thin container, use can be made of blow molding, biaxial stretch blow molding, injection molding, vacuum molding, compressed air molding and the like.

【0018】また、インサート材として使用されるラベ
ルとしては、合成樹脂製ラベルの他に、金属箔層を有す
るラミネートシート製のラベルの使用が可能である。
As a label used as an insert material, a label made of a laminate sheet having a metal foil layer can be used in addition to a synthetic resin label.

【0019】さらに、容器本体1の最外層1cの成形材
料に要求される曲げ弾性率の実測結果としては、低密度
ポリエチレンの場合2.2×10(kg/cm2)で
割れが発生してしまったが、他の低密度ポリエチレンの
場合3.3×10、高密度ポリエチレンの場合5.5
×10、他の高密度ポリエチレンの場合1.4×10
、ポリプロピレンの場合8.2×10、ナイロン6
6の場合(2.9〜8.8)×10、ダイレクトブロ
ー用PETGの場合2.9×10、EVOHの場合
2.5×10、環状ポリオレフィン(日本ゼオン社製
ゼオノア)の場合(2.1〜2.6)×10、ポリア
クリルニトリルの場合(2.8〜3.3)×10で割
れが発生しなかった。
Further, as a result of actual measurement of the flexural modulus required for the molding material of the outermost layer 1c of the container body 1, cracks occur at 2.2 × 10 3 (kg / cm 2 ) in the case of low-density polyethylene. It was 3.3 × 10 3 for other low-density polyethylene, and 5.5 for high-density polyethylene.
× 10 3 , 1.4 × 10 for other high density polyethylene
4 , 8.2 × 10 3 for polypropylene, nylon 6
6 (2.9-8.8) × 10 4 , PETG for direct blow 2.9 × 10 4 , EVOH 2.5 × 10 4 , cyclic polyolefin (Zeonor, manufactured by Zeon Corporation) (2.1 to 2.6) × 10 4 , and in the case of polyacrylonitrile, (2.8 to 3.3) × 10 4 , no crack was generated.

【0020】[0020]

【発明の効果】本発明は、上記した構成となっているの
で、以下に示す効果を奏する。ラベルをインサート材と
して成形される容器本体の最外層は、曲げ弾性率の高い
合成樹脂材料で成形されているので、容器本体の周壁は
曲げ変形しにくくなり成形性が低くなるため、ラベルの
裏面側エッジ部の、周壁への食い込みが防止され、従っ
て、周壁に極肉薄部が形成されることは全く無く、よっ
て、その極肉薄部への応力集中により周壁に割れが発生
することが防止され、肉薄容器としての商品価値が向上
する。
Since the present invention has the above-described structure, the following effects can be obtained. Since the outermost layer of the container body molded using the label as the insert material is formed of a synthetic resin material having a high flexural modulus, the peripheral wall of the container body is hardly deformed by bending, and the moldability is reduced, so the back surface of the label is used. The side edge portion is prevented from biting into the peripheral wall, so that no extremely thin portion is formed on the peripheral wall, so that cracks are prevented from being generated on the peripheral wall due to stress concentration on the extremely thin portion. In addition, the commercial value as a thin container is improved.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明容器の成形例を示す、割金型の一方の金
型の平断面図。
FIG. 1 is a plan sectional view of one mold of a split mold, showing a molding example of the container of the present invention.

【図2】図1に示した成形例の、ブロー成形後の状態を
示す要部拡大平断面図。
FIG. 2 is an enlarged plan sectional view of a main part showing a state after blow molding of the molding example shown in FIG. 1;

【図3】従来の成形方法による、ブロー成形後の状態を
示す要部拡大平断面図。
FIG. 3 is an enlarged plan sectional view of a main part showing a state after blow molding by a conventional molding method.

【符号の説明】[Explanation of symbols]

1 ; 容器本体 1a ; 周壁 1b ; 極肉薄部 1c ; 最外層 2 ; ラベル 2a ; 内側エッジ部 3 ; 金型 3a ; 冷却孔 DESCRIPTION OF SYMBOLS 1; Container main body 1a; Peripheral wall 1b; Extra-thin part 1c; Outermost layer 2; Label 2a; Inside edge part 3;

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 3E033 AA01 BA14 BA15 BA16 BA18 BA21 BA23 BB08 CA20 EA20 FA03 3E062 AA09 AB01 AC02 DA02 DA07 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 3E033 AA01 BA14 BA15 BA16 BA18 BA21 BA23 BB08 CA20 EA20 FA03 3E062 AA09 AB01 AC02 DA02 DA07

Claims (10)

【特許請求の範囲】[Claims] 【請求項1】 充分に肉薄に成形された合成樹脂製容器
本体(1)と、該容器本体(1)の外周面にインサート材とし
て溶着固定されたラベル(2)とから構成される容器であ
って、前記容器本体(1)は、その最外層(1c)を曲げ弾性
率の高い合成樹脂材料で形成した積層構造とされて成る
合成樹脂製肉薄容器。
A container comprising a synthetic resin container main body (1) formed sufficiently thin and a label (2) welded and fixed as an insert material to an outer peripheral surface of the container main body (1). The container body (1) is a thin synthetic resin container having a laminated structure in which the outermost layer (1c) is formed of a synthetic resin material having a high flexural modulus.
【請求項2】 最外層(1c)を3000kg/cm以上
の曲げ弾性率を有する合成樹脂材料で形成した請求項1
記載の合成樹脂製肉薄容器。
2. An outermost layer (1c) formed of a synthetic resin material having a flexural modulus of 3000 kg / cm 2 or more.
A thin container made of the synthetic resin described in the above.
【請求項3】 最外層(1c)を形成する合成樹脂材料が低
密度ポリエチレン樹脂である請求項2記載の合成樹脂製
肉薄容器。
3. A thin container made of synthetic resin according to claim 2, wherein the synthetic resin material forming the outermost layer (1c) is a low-density polyethylene resin.
【請求項4】 最外層(1c)を形成する合成樹脂材料が高
密度ポリエチレン樹脂である請求項2記載の合成樹脂製
肉薄容器。
4. The thin synthetic resin container according to claim 2, wherein the synthetic resin material forming the outermost layer (1c) is a high-density polyethylene resin.
【請求項5】 最外層(1c)を形成する合成樹脂材料がポ
リプロピレン樹脂である請求項2記載の合成樹脂製肉薄
容器。
5. The thin container made of a synthetic resin according to claim 2, wherein the synthetic resin material forming the outermost layer (1c) is a polypropylene resin.
【請求項6】 最外層(1c)を形成する合成樹脂材料がナ
イロン樹脂である請求項2記載の合成樹脂製肉薄容器。
6. The thin synthetic resin container according to claim 2, wherein the synthetic resin material forming the outermost layer (1c) is a nylon resin.
【請求項7】 最外層(1c)を形成する合成樹脂材料がP
ETGである請求項2記載の合成樹脂製肉薄容器。
7. The synthetic resin material forming the outermost layer (1c) is P
The thin container made of a synthetic resin according to claim 2, which is ETG.
【請求項8】 最外層(1c)を形成する合成樹脂材料がエ
チレンビニルアルコール共重合樹脂である請求項2記載
の合成樹脂製肉薄容器。
8. The thin container made of a synthetic resin according to claim 2, wherein the synthetic resin material forming the outermost layer (1c) is an ethylene vinyl alcohol copolymer resin.
【請求項9】 最外層(1c)を形成する合成樹脂材料が環
状ポリオレフィン樹脂である請求項2記載の合成樹脂製
肉薄容器。
9. The thin synthetic resin container according to claim 2, wherein the synthetic resin material forming the outermost layer (1c) is a cyclic polyolefin resin.
【請求項10】 最外層(1c)を形成する合成樹脂材料が
ポリアクリロニトリル樹脂である請求項2記載の合成樹
脂製肉薄容器。
10. The thin container made of a synthetic resin according to claim 2, wherein the synthetic resin material forming the outermost layer (1c) is a polyacrylonitrile resin.
JP2002105559A 2001-04-06 2002-04-08 Synthetic resin thin container Expired - Fee Related JP4077233B2 (en)

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JPH04284223A (en) * 1991-03-14 1992-10-08 Toppan Printing Co Ltd Hollow molded container and molding method for hollow molded container
JPH0560837U (en) * 1991-12-20 1993-08-10 釜屋化学工業株式会社 Multi-layer container
JPH06190990A (en) * 1992-10-09 1994-07-12 Otsuka Pharmaceut Factory Inc Multi-layer film and vessel
JPH07267234A (en) * 1994-03-31 1995-10-17 Toyo Seikan Kaisha Ltd Foldable blow-molded bottle
JPH0811855A (en) * 1994-06-23 1996-01-16 Yoshino Kogyosho Co Ltd Bottle body and molding thereof
JPH0899395A (en) * 1994-09-30 1996-04-16 Toppan Printing Co Ltd Multilayered resin container
JPH08309836A (en) * 1995-05-18 1996-11-26 Yoshino Kogyosho Co Ltd Multilayer plastic hollow molding vessel
JPH1035720A (en) * 1996-05-23 1998-02-10 Kureha Chem Ind Co Ltd Packing laminated film having aliphatic polyamide resin as outermost layer
JPH10235760A (en) * 1997-02-24 1998-09-08 Toyo Seikan Kaisha Ltd Blow bag and its manufacture
JPH10236453A (en) * 1997-02-24 1998-09-08 Toyo Seikan Kaisha Ltd Blow molding container excellent in heat resistance
JP3063963U (en) * 1999-05-18 1999-12-10 富田製薬株式会社 Moisture-proof container for food
JP2000319407A (en) * 1999-05-14 2000-11-21 Nippon Polyolefin Kk Insert molded body

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04284223A (en) * 1991-03-14 1992-10-08 Toppan Printing Co Ltd Hollow molded container and molding method for hollow molded container
JPH0560837U (en) * 1991-12-20 1993-08-10 釜屋化学工業株式会社 Multi-layer container
JPH06190990A (en) * 1992-10-09 1994-07-12 Otsuka Pharmaceut Factory Inc Multi-layer film and vessel
JPH07267234A (en) * 1994-03-31 1995-10-17 Toyo Seikan Kaisha Ltd Foldable blow-molded bottle
JPH0811855A (en) * 1994-06-23 1996-01-16 Yoshino Kogyosho Co Ltd Bottle body and molding thereof
JPH0899395A (en) * 1994-09-30 1996-04-16 Toppan Printing Co Ltd Multilayered resin container
JPH08309836A (en) * 1995-05-18 1996-11-26 Yoshino Kogyosho Co Ltd Multilayer plastic hollow molding vessel
JPH1035720A (en) * 1996-05-23 1998-02-10 Kureha Chem Ind Co Ltd Packing laminated film having aliphatic polyamide resin as outermost layer
JPH10235760A (en) * 1997-02-24 1998-09-08 Toyo Seikan Kaisha Ltd Blow bag and its manufacture
JPH10236453A (en) * 1997-02-24 1998-09-08 Toyo Seikan Kaisha Ltd Blow molding container excellent in heat resistance
JP2000319407A (en) * 1999-05-14 2000-11-21 Nippon Polyolefin Kk Insert molded body
JP3063963U (en) * 1999-05-18 1999-12-10 富田製薬株式会社 Moisture-proof container for food

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