JP2002317071A - Method for recycling hybrid-type plastic - Google Patents

Method for recycling hybrid-type plastic

Info

Publication number
JP2002317071A
JP2002317071A JP2001123689A JP2001123689A JP2002317071A JP 2002317071 A JP2002317071 A JP 2002317071A JP 2001123689 A JP2001123689 A JP 2001123689A JP 2001123689 A JP2001123689 A JP 2001123689A JP 2002317071 A JP2002317071 A JP 2002317071A
Authority
JP
Japan
Prior art keywords
recycling
oil
plastics
crushing
materials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001123689A
Other languages
Japanese (ja)
Inventor
Kazuhiko Tada
和彦 多田
Yuji Nishioka
祐二 西岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kubota Corp
Original Assignee
Kubota Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kubota Corp filed Critical Kubota Corp
Priority to JP2001123689A priority Critical patent/JP2002317071A/en
Publication of JP2002317071A publication Critical patent/JP2002317071A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/52Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Landscapes

  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Disintegrating Or Milling (AREA)
  • Separation Of Solids By Using Liquids Or Pneumatic Power (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a method for recycling hybrid-type plastics by which the recycling rate of a material of nonindustrial waste-based plastics disposed from a household is heightened, the plastics can be reused as a reclaimed material having a high additional value, the amount of a residue discharged to the outside of the system can be reduced, and the amount of the recovered formed oil can be increased. SOLUTION: This method for recycling the hybrid-type plastics comprises manually selecting the waste plastics to recycling raw materials of each separated polyethylene, polypropylene, polystyrene and polyethylene terephthalate, and oil-forming raw materials comprising other mixed plastics in a step for sorting mixed various kinds of the waste plastics received in an installation, removing foreign matters from the product at a wet gravity selecting step 8 after crushing each material of the recycling raw materials at a crushing step 7, granulating each crushed material at a granulating step 11 after removing the foreign matters to provide material-recycling products, crushing the oil-forming raw materials 4 at the crushing step 7, removing iron materials and aluminum materials from the crushed product at a magnetic selecting step 13 and an aluminum-selecting step 14, subjecting the iron materials and aluminum materials-removed product to a vinyl chloride-removing treatment at the wet gravity selecting step 8, and forming the product obtained at the foregoing step 8 into the oil at a thermal cracking and oil-forming step 18.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明はハイブリッド型プラ
スチックリサイクル方法に関し、プラスチック廃棄物の
リサイクル技術に係るものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hybrid plastic recycling method, and more particularly to a technique for recycling plastic waste.

【0002】[0002]

【従来の技術】従来、家庭から排出される一般廃棄物系
プラスッチクは、破袋、粉砕、風力選別などの各工程を
経て異物を除去し、造粒後に油化設備において油化して
生成油を得ている。この油化技術には特開平3−867
91号に開示するものがある。これはポリオレフィン系
プラスチックを粉砕した後に押出機で加熱により軟化も
しくは溶融化して溶融混合槽に導入し、溶融混合槽で原
料を均一な溶融物とし、溶融物を熱分解槽において分解
するものであり、熱分解槽では溶融物を加熱炉で所定温
度に加熱して循環させ、熱分解槽で発生する蒸気状生成
物は分離器でミストを除去した後にゼオライト触媒槽に
おいて接触分解させる。
2. Description of the Related Art Conventionally, general waste plastics discharged from homes are subjected to various processes such as bag breaking, crushing, and wind separation to remove foreign substances. It has gained. This oil technology is disclosed in Japanese Patent Application Laid-Open No. 3-867.
No. 91 discloses this. This is to pulverize a polyolefin plastic, then soften or melt it by heating with an extruder, introduce it into a melting and mixing tank, make the raw material uniform in the melting and mixing tank, and decompose the melt in a pyrolysis tank. In the pyrolysis tank, the melt is heated to a predetermined temperature in a heating furnace and circulated, and the vaporous product generated in the pyrolysis tank is catalytically decomposed in a zeolite catalyst tank after removing mist in a separator.

【0003】[0003]

【発明が解決しようとする課題】ところで、上記した従
来の構成では、受け入れた全てのもを破砕して風力選別
機に通しているが、一般廃棄物系プラスチックのなかで
も材料リサイクルに適するプラスチックが多く含まれて
おり、これらを破砕後に風力選別機に通すとかなりの量
の異物として残渣側に選別される。
By the way, in the above-mentioned conventional configuration, all the received materials are crushed and passed through a wind separator, but plastics suitable for material recycling among general waste plastics are used. When they are crushed and passed through a wind separator, they are sorted to the residue side as a considerable amount of foreign matter.

【0004】この問題の解決法として自動選別機の使用
が考えられるが、一般廃棄物系プラスチックの種類は非
常に多く、種類によって少量しかないものがあるので、
その選別精度を高めると費用対効果において採算が取り
難く、まして破砕物を選別するとさらに困難性が増す。
[0004] As a solution to this problem, the use of an automatic sorter is conceivable. However, the types of general waste plastics are very large, and some of them have only a small amount.
Increasing the sorting accuracy makes it harder to make profits in cost-effectiveness, and even more so when sorting crushed materials.

【0005】また、塩素等が0.5WT%以上含まれる
廃棄プラスチックはダイオキシンの発生、設備機器の腐
食等の問題があり、燃料化、高炉還元材料化に適さない
ものになり、埋立処理となる。このように、材料リサイ
クルされずに廃棄される雑プラスチックは受入量の50
〜60%にも達し、これらは産業廃棄物として埋立処分
されるが、その費用と埋立スペースの確保が大きな問題
となっている。
[0005] Waste plastics containing 0.5 WT% or more of chlorine and the like have problems such as generation of dioxin and corrosion of equipment, and are not suitable for use as fuel or blast furnace reduction material, and require landfill treatment. . Thus, the amount of miscellaneous plastic discarded without recycling is 50% of the amount received.
They reach up to 60% and are landfilled as industrial waste. However, the cost and landfill space are serious problems.

【0006】本発明は上記した課題を解決するものであ
り、家庭から排出する一般廃棄物系プラスチックの材料
リサイクル率を高めるとともに付加価値の高い再生原料
とし、系外へ排出する残渣量を低減するとともに回収す
る生成油量を増加させることができるハイブリッド型プ
ラスチックリサイクル方法を提供することを目的とす
る。
SUMMARY OF THE INVENTION The present invention solves the above-mentioned problems, and increases the material recycling rate of general waste plastics discharged from homes, makes it a recycled material with high added value, and reduces the amount of residues discharged outside the system. Another object of the present invention is to provide a hybrid plastic recycling method capable of increasing the amount of generated oil to be recovered.

【0007】[0007]

【課題を解決するための手段】上記課題を解決するため
に、本発明のハイブリッド型プラスチックリサイクル方
法は、施設内に受け入れた多種混合の廃棄プラスチック
をポリエチレン/ポリプロピレン/ポリスチレン/ポリ
エチレンテレフタレートの各材質ごとの材料リサイクル
原料とその他の混合プラスチックからなる油化原料とに
人手で手選別し、材料リサイクル原料は各材質ごとに破
砕して後に湿式比重選別して異質物を除去し、その後に
造粒して材料リサイクル製品となし、油化原料は破砕し
て後に磁力選別、アルミ選別して鉄類およびアルミ類を
除去し、その後に湿式比重選別にて脱塩化ビニル処理し
たものを熱分解処理して油化するものである。
In order to solve the above-mentioned problems, a hybrid plastic recycling method according to the present invention is a method of recycling a mixed plastic waste received in a facility for each material of polyethylene / polypropylene / polystyrene / polyethylene terephthalate. Material is manually separated into raw materials made from recycled materials and oiled raw materials made of other mixed plastics.The material recycled materials are crushed for each material, then wet-specific gravity sorted to remove foreign substances, and then granulated. Recycled material is crushed, and the liquefied raw material is crushed, then magnetically separated, and then aluminum is separated to remove irons and aluminums. It turns into oil.

【0008】上記した構成により、手選別によってポリ
エチレン/ポリプロピレン/ポリスチレン/ポリエチレ
ンテレフタレートの各材質の廃棄プラスチックを確保す
ることにより高精度で安価に材料リサイクル原料を回収
することができ、選別できなかった混合プラスチックは
油化不適合物である塩化ビニルを除去した後に油化する
ことで、ダイオキシンの発生、設備機器の腐食等を伴な
うことなく油化でき、埋立処理する残渣量を低減でき、
廃棄プラスチックの材料リサイクルラインと油化処理ラ
インとを兼ね備えることで廃棄プラスチックの処理に要
する消費エネルギーを低減することができるとともに廃
棄プラスチックリサイクルの収率が向上する。
[0008] With the above-mentioned configuration, by securing waste plastics of each material of polyethylene / polypropylene / polystyrene / polyethylene terephthalate by manual selection, it is possible to recover material recycled materials with high precision and at low cost, and to obtain a mixture that cannot be selected. By removing vinyl chloride, which is incompatible with oil, the plastic can be converted to oil without the generation of dioxin and corrosion of equipment and equipment, reducing the amount of landfill waste.
By providing both a waste plastic material recycling line and an oil treatment line, energy consumption required for waste plastic processing can be reduced, and the yield of waste plastic recycling can be improved.

【0009】[0009]

【発明の実施の形態】以下、本発明の実施の形態を図面
に基づいて説明する。図1において、家庭から排出する
一般廃棄物系プラスチックは複数種類のプラスチックを
含み、袋に入れられた状態にある。
Embodiments of the present invention will be described below with reference to the drawings. In FIG. 1, general waste plastics discharged from homes include a plurality of types of plastics and are in a bag.

【0010】施設内に受け入れた多種混合の廃棄プラス
チックは解砕工程1において袋を破って後に異物除去・
仕分け工程2に供給する。異物除去・仕分け工程2では
手選別により廃棄プラスチックをポリエチレン/ポリプ
ロピレン/ポリスチレン/ポリエチレンテレフタレート
の各材質ごとの材料リサイクル原料3と、その他の混合
プラスチックからなる油化原料4と、金属類5と、異物
・不適物6とに選別する。
[0010] The mixed plastic waste received in the facility breaks the bag in the crushing step 1 and then removes foreign matter.
It is supplied to the sorting step 2. In the foreign matter removal / sorting step 2, waste plastics are manually sorted to recycle raw materials 3 for each material of polyethylene / polypropylene / polystyrene / polyethylene terephthalate, oily raw materials 4 made of other mixed plastics, metals 5, foreign substances・ Sorting to unsuitable 6

【0011】材料リサイクル原料3は各材質ごとに破砕
(細破砕)工程7で破砕して後に湿式比重選別・粗洗浄
工程8で異質物を除去するとともに粗洗浄し、二次洗浄
工程9を経て乾燥工程10で乾燥させ、その後に造粒工
程11で所定粒径に造粒するか、またはそのままフレー
ク状として材料リサイクル製品(ペレット、フレーク)
12となす。
The material recycled material 3 is crushed in a crushing (fine crushing) step 7 for each material, and thereafter, a foreign substance is removed and coarsely cleaned in a wet specific gravity sorting / rough cleaning step 8, followed by a secondary cleaning step 9. It is dried in a drying step 10, and then granulated to a predetermined particle size in a granulation step 11, or is made into flakes as they are, and recycled materials (pellets, flakes)
Make 12

【0012】油化原料4は破砕(細破砕)工程7で破砕
して後に磁力選別工程13、アルミ選別工程14で鉄類
15およびアルミ類16を除去し、その後に湿式比重選
別工程8にて塩化ビニル(フレーク状)17を除去し、
さらに乾燥工程10で乾燥させた後に熱分解・油化工程
18で処理して油化し、生成油19、生成ガス20を得
るとともに、残渣物を固形燃料21とする。破砕(細破
砕)工程7、湿式比重選別工程8、乾燥工程10は廃棄
プラスチック材料リサイクルラインと油化処理ラインと
で兼用する。
The liquefied raw material 4 is crushed in a crushing (fine crushing) step 7, after which irons 15 and aluminums 16 are removed in a magnetic separation step 13 and an aluminum selection step 14, and then in a wet specific gravity separation step 8. Remove vinyl chloride (flakes) 17,
Further, after being dried in the drying step 10, it is treated and oiled in the thermal decomposition / oiling step 18 to obtain the product oil 19 and the product gas 20, and the residue is used as the solid fuel 21. The crushing (fine crushing) step 7, the wet-type specific gravity sorting step 8, and the drying step 10 are shared by the waste plastic material recycling line and the oil treatment line.

【0013】以下、上記した構成における作用を説明す
る。異物除去・仕分け工程2における手選別は人的作業
によって行うので、ポリエチレン/ポリプロピレン/ポ
リスチレン/ポリエチレンテレフタレートの各材質の廃
棄プラスチックを高精度で安価に材料リサイクル原料と
して回収することができ、湿式比重選別・粗洗浄工程8
および二次洗浄工程9の各工程で異物を除去することに
より、付加価値の高い再生原料となる。
The operation of the above configuration will be described below. Since the manual sorting in the foreign matter removal / sorting process 2 is performed by human work, waste plastics of each material of polyethylene / polypropylene / polystyrene / polyethylene terephthalate can be collected with high precision at low cost as a raw material for material recycling, and wet specific gravity sorting.・ Rough cleaning process 8
In addition, by removing foreign matter in each step of the secondary washing step 9, a recycled material having high added value can be obtained.

【0014】ポリエチレン/ポリプロピレン/ポリスチ
レン/ポリエチレンテレフタレート以外の材質の混合プ
ラスチックは湿式比重選別・粗洗浄工程8で油化不適合
物である塩化ビニルを除去した後に油化することで、ダ
イオキシンの発生、設備機器の腐食等を伴なうことなく
油化でき、埋立処理する残渣量を低減でき、結果として
廃棄プラスチックリサイクルの収率が向上する。
The mixed plastic of materials other than polyethylene / polypropylene / polystyrene / polyethylene terephthalate removes vinyl chloride which is incompatible with oil in a wet specific gravity sorting / rough washing step 8 and then oils it, thereby generating dioxin and equipment. The oil can be turned into oil without causing corrosion of the equipment, and the amount of residues to be landfilled can be reduced. As a result, the yield of waste plastic recycling can be improved.

【0015】図2に本発明における物質収支を示し、図
3に従来の構成における物質収支を示す。両者の比較に
より明らかなように、投入した廃棄プラスチックから4
0%程度のペレット/フレークを回収することができる
ので材料リサイクルの率が高まる。
FIG. 2 shows a material balance in the present invention, and FIG. 3 shows a material balance in a conventional configuration. As is clear from the comparison between the two, 4
Since about 0% of pellets / flakes can be recovered, the rate of material recycling is increased.

【0016】[0016]

【発明の効果】以上のように本発明によれば、手選別に
よってポリエチレン/ポリプロピレン/ポリスチレン/
ポリエチレンテレフタレートの各材質の廃棄プラスチッ
クを除去することにより高精度で安価に材料リサイクル
原料を回収することができ、選別できなかった混合プラ
スチックは油化不適合物である塩化ビニルを除去した後
に油化することで、ダイオキシンの発生、設備機器の腐
食等を伴なうことなく油化でき、埋立処理する残渣量を
低減でき、廃棄プラスチックの材料リサイクルラインと
油化処理ラインとを兼ね備えることで廃棄プラスチック
の処理に要する消費エネルギーを低減することができる
とともに廃棄プラスチックリサイクルの収率が向上す
る。
As described above, according to the present invention, polyethylene / polypropylene / polystyrene /
By removing waste plastics of each material of polyethylene terephthalate, material recycling raw materials can be recovered with high precision and at low cost. Mixed plastics that could not be sorted are turned into oil after removing vinyl chloride, which is an incompatible oil. In this way, oil can be turned into oil without the generation of dioxins and corrosion of equipment, etc., the amount of residues to be landfilled can be reduced, and by combining a waste plastic material recycling line with an oil treatment line, waste plastic Energy consumption required for processing can be reduced, and the yield of waste plastic recycling is improved.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施の形態におけるリサイクル方法を
示すフローシートである。
FIG. 1 is a flow sheet showing a recycling method according to an embodiment of the present invention.

【図2】本実施の形態における物質収支を示す図であ
る。
FIG. 2 is a diagram showing a material balance in the present embodiment.

【図3】従来の構成における物質収支を示す図である。FIG. 3 is a diagram showing a material balance in a conventional configuration.

【符号の説明】[Explanation of symbols]

1 解砕工程 2 異物除去・仕分け工程 3 材料リサイクル原料 4 油化原料 5 金属類 6 異物・不適物 7 破砕(細破砕)工程 8 湿式比重選別・粗洗浄工程 9 二次洗浄工程 10 乾燥工程 11 造粒工程 12 材料リサイクル製品(ペレット、フレーク) 13 磁力選別工程 14 アルミ選別工程 15 鉄類 16 アルミ類 17 塩化ビニル(フレーク) 18 熱分解・油化工程 19 生成油 20 生成ガス 21 固形燃料 DESCRIPTION OF REFERENCE NUMERALS 1 Crushing process 2 Foreign material removal / sorting process 3 Material recycling raw material 4 Oiling raw material 5 Metals 6 Foreign material / unsuitable material 7 Crushing (fine crushing) process 8 Wet specific gravity sorting / rough cleaning process 9 Secondary washing process 10 Drying process 11 Granulation process 12 Material recycling products (pellets, flakes) 13 Magnetic sorting process 14 Aluminum sorting process 15 Irons 16 Aluminums 17 Vinyl chloride (flakes) 18 Thermal decomposition / oiling process 19 Generated oil 20 Generated gas 21 Solid fuel

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) B03C 1/00 B03C 1/00 B B29B 17/02 B29B 17/02 C10G 1/10 ZAB C10G 1/10 ZAB // C08L 23:06 C08L 23:06 23:10 23:10 25:06 25:06 67:00 67:00 Fターム(参考) 4D067 DD02 DD07 DD10 DD19 GA16 GB05 4D071 AA41 AB14 AB23 AB24 AB49 CA03 CA05 DA15 4F301 AA13 AA14 AA15 AA25 BD05 BF09 BF11 BF20 BF31 CA07 CA24 4H029 CA01 CA16 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification code FI Theme coat ゛ (Reference) B03C 1/00 B03C 1/00 B B29B 17/02 B29B 17/02 C10G 1/10 ZAB C10G 1/10 ZAB // C08L 23:06 C08L 23:06 23:10 23:10 25:06 25:06 67:00 67:00 F term (reference) 4D067 DD02 DD07 DD10 DD19 GA16 GB05 4D071 AA41 AB14 AB23 AB24 AB49 CA03 CA05 DA15 4F301 AA13 AA14 AA15 AA25 BD05 BF09 BF11 BF20 BF31 CA07 CA24 4H029 CA01 CA16

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 施設内に受け入れた多種混合の廃棄プラ
スチックをポリエチレン/ポリプロピレン/ポリスチレ
ン/ポリエチレンテレフタレートの各材質ごとの材料リ
サイクル原料とその他の混合プラスチックからなる油化
原料とに人手で手選別し、材料リサイクル原料は各材質
ごとに破砕して後に湿式比重選別して異質物を除去し、
その後に造粒して材料リサイクル製品となし、油化原料
は破砕して後に磁力選別、アルミ選別して鉄類およびア
ルミ類を除去し、その後に湿式比重選別にて脱塩化ビニ
ル処理したものを熱分解処理して油化することを特徴と
するハイブリッド型プラスチックリサイクル方法。
1. A multi-mixed waste plastic received in a facility is manually and manually separated into a material recycling raw material for each material of polyethylene / polypropylene / polystyrene / polyethylene terephthalate and an oiling raw material composed of other mixed plastics, Material recycling raw materials are crushed for each material, and then wet specific gravity sorting is performed to remove foreign substances,
After that, it is granulated and made into a material recycled product, and the liquefied raw material is crushed, then magnetically separated, aluminum is separated to remove irons and aluminums, and then wet-gravity separated and dechlorinated. A hybrid plastic recycling method characterized in that it is thermally decomposed and converted to oil.
JP2001123689A 2001-04-23 2001-04-23 Method for recycling hybrid-type plastic Pending JP2002317071A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005154313A (en) * 2003-11-21 2005-06-16 Ishikawajima Harima Heavy Ind Co Ltd Method for chemically recycling waste plastic
CN104309027A (en) * 2014-10-08 2015-01-28 四川塑金科技有限公司 System integrating automatic feeding, crushing and cleaning functions and implementation method of system
CN104369286A (en) * 2014-10-08 2015-02-25 四川塑金科技有限公司 Device and method for automatic cleaning of PS and ABS waste and old plastic
JP2018503734A (en) * 2014-11-28 2018-02-08 ヴァーレ、ソシエダージ、アノニマVale S.A. Method for obtaining ore dust control resin, ore dust control resin, method for controlling ore particle emission and use of resin
KR102318626B1 (en) * 2021-02-23 2021-10-29 주식회사 포우천개발 Recycling method of waste vinyl, and recycled products manufactured by the same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005154313A (en) * 2003-11-21 2005-06-16 Ishikawajima Harima Heavy Ind Co Ltd Method for chemically recycling waste plastic
CN104309027A (en) * 2014-10-08 2015-01-28 四川塑金科技有限公司 System integrating automatic feeding, crushing and cleaning functions and implementation method of system
CN104369286A (en) * 2014-10-08 2015-02-25 四川塑金科技有限公司 Device and method for automatic cleaning of PS and ABS waste and old plastic
JP2018503734A (en) * 2014-11-28 2018-02-08 ヴァーレ、ソシエダージ、アノニマVale S.A. Method for obtaining ore dust control resin, ore dust control resin, method for controlling ore particle emission and use of resin
KR102318626B1 (en) * 2021-02-23 2021-10-29 주식회사 포우천개발 Recycling method of waste vinyl, and recycled products manufactured by the same

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