JP2002241237A - Deodorant perfume composition for hair cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a deodorant perfume composition for hair cosmetics, having a reduced smell and/or a reduced smell emitted during use. SOLUTION: This deodorant perfume composition comprises one or more kinds selected from the group consisting of (1) a chemical deodorant component such as an aldehyde, a formic acid ester or a tiglic acid derivative and (2) a vapor pressure control component such as tetrahydromethyl abietate, dihydromethyl abietate, methyl abietate or a polymer of an ester of adipic acid and oxybis (dipropylene glycol) as active ingredients.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a deodorant perfume composition for hair cosmetics and a deodorant perfume composition capable of reducing the odor of hair cosmetics and / or the odor generated during use of hair cosmetics. It relates to the hair cosmetics used.

[0002]

2. Description of the Related Art In recent years, with changes in consciousness of living environment, there is a strong demand for more effective deodorization of odors around us. For example, in homes, odors from toilets and kitchens, pet odors, cigarette odors, etc. pose a problem, but as main odorants, ammonia, trimethylamine, hydrogen sulfide, etc. are known and cause discomfort The main cause.

Conventionally, the following four methods (1) to (4) have been proposed as methods for eliminating such malodors. (1) Sensory deodorization: A method of masking bad odors with a strong odor (2) Physical deodorization: Adsorption of bad odor components by activated carbon, zeolite, cyclodextrin, etc., interaction by inclusion or intermolecular force ( (3) Chemical deodorization: A method of chemically reacting (neutralization, addition, condensation, oxidation, etc.) with malodorous components to deodorize (4) Biological deodorization Odor: Biological deodorization using microorganisms such as activated sludge

[0004] Although such methods have a certain deodorizing effect, they each have disadvantages, and the deodorizing effects have not always been satisfactory. In addition, such bad smell,
It is also emitted in hair cosmetics such as perms, hair straighteners, hair dyes, hair removers, etc. Odor components such as ammonia originally present in hair cosmetics, and the actual use of hair cosmetics Occasionally generated reaction odors such as dimethyl disulfide and methyl mercaptan cause odors. Therefore, when these hair cosmetics are used, they often feel uncomfortable, and there has been a demand for a deodorant fragrance composition that can effectively deodorize these malodors.

[0005] The present invention has been made in view of the above-mentioned conventional circumstances, and is a hair cosmetic which can effectively reduce the odor of hair cosmetics such as perm agents, hair straighteners, hair dyes, and hair removers. It is an object of the present invention to provide a food deodorant fragrance composition.

[0006]

Means for Solving the Problems The present inventors have conducted intensive studies to solve the above problems, and as a result, using a chemical deodorant component or a vapor pressure suppressing component, the deodorization of hair cosmetics. The present inventors have found that a deodorant fragrance composition for hair cosmetics having excellent effects and excellent safety can be obtained, and based on this, the present invention has been completed.

[0007] That is, the present invention is a deodorant fragrance composition for hair cosmetics, characterized by containing one or more selected from the group consisting of the following (1) and (2) as an active ingredient. . (1) Chemical deodorant component (2) Vapor pressure suppressing component

Further, according to the present invention, the odor component in the hair cosmetic and / or a part of the odor component generated during the use of the hair cosmetic is chemically changed by the chemical deodorant component to deodorize the cosmetic. The present invention also provides a hair cosmetic deodorizing method characterized in that the odor during the use of the hair cosmetic is reduced by suppressing the evaporation of the odor component by the vapor pressure suppressing component.

Hereinafter, the present invention will be described in detail. Of the (1) chemical deodorant component and (2) vapor pressure suppressing component used in the present invention, (1) the chemical deodorant component has an aroma and is recognized as a fragrance. Many are used with other fragrances. In addition, (2) the vapor pressure suppressing component does not have a fragrance by itself, but is used as a fragrance retaining agent. In the present invention, it is often used together with a fragrance. Therefore, in the present invention, a deodorant fragrance composition for hair cosmetics is referred to as a fragrance composition for hair cosmetics and deodorant. However, the fragrance composition of the present invention does not exclude (1) a chemical deodorant component alone or (2) a component composed of a vapor pressure suppressing component alone.
It can also be grasped as a deodorant for hair cosmetics.

Here, (1) the chemical deodorant component is used to deodorize by reacting with the odor component and chemically changing the odor component. The odor component differs depending on the odor component, for example, aldehydes, formate esters and tiglic acid derivatives. One or two or more selected from

Among the odor components, the chemical deodorant components for ammonia or trimethylamine include, for example,
Aliphatic aldehydes having 6 to 12 carbon atoms, trimethylundecanal, 2,6-dimethyl-5-heptene-1-al, 10-undecene-1-al, isohexenylcyclohexenecarboxaldehyde, 2-methyl-4
-(2,2,6-trimethyl-1-cyclohexenyl)
-2-butenal, phenylacetaldehyde, 2-methyl-3- (p-isopropylphenyl) -propionaldehyde, 2-phenylpropanal, 3-phenylpropanal, 3- (4-t-butylphenyl) -propanal, 2-methyl-3- (p-methoxyphenyl)
-Propanal, 4,7-methanoindane-1-carboxaldehyde, p-isopropylphenylacetaldehyde, 2,6,10-trimethyl-5,9-undecadienal, benzaldehyde, dimethyltetrahydrobenzaldehyde, citral, citronellal, hydroxycitro Neral, methoxycitronellal, cinnamaldehyde, methylcinnamaldehyde,
Examples include pt-butyl-α-methylhydrocinnamic aldehyde, cumin aldehyde, anisaldehyde, benzyl formate, citronellyl formate, geranyl formate, phenylethyl formate, anisyl formate, and linalyl formate. Among them, particularly preferred are 2-methyl-3- (p-isopropylphenyl) -propionaldehyde, hydroxycitronellal, pt-butyl-α-methylhydrocinnamic aldehyde, and citronellyl formate.

Examples of the chemical deodorant component against hydrogen sulfide include undecanal, 2-methylundecanal, t-2-hexenal, 3,5,5-trimethylhexenal, 2-phenylpropanal, citronellal and methoxycitro. Neral, methylcinnamic aldehyde, cumin aldehyde, hexyl tiglate and geranyl tiglate are mentioned. Among them, particularly preferred are hexyl tiglate and geranyl tiglate.

(1) The compounding amount of the chemical deodorant component is at least 0.5% by mass, more preferably at least 2.0% by mass, based on the total amount of the deodorant and fragrance composition for hair cosmetics.

The vapor pressure suppressing component (2) used in the present invention reduces the odor by suppressing the evaporation of the odor component, and is almost the same as the flavor retention agent.
For example, esterified polymer of dipropylene glycol, propylene glycol, diethyl phthalate, benzyl benzoate, isopropyl myristate, diisobutyl adipate, tetrahydromethyl aviate, dihydromethyl aviate, methyl abietic acid, adipic acid and oxybis (dipropylene glycol) Is mentioned. Among them, particularly preferred are tetrahydromethyl aviate, dihydromethyl aviate, methyl abietate, and an esterified polymer of adipic acid and oxybis (dipropylene glycol).

(2) The amount of the vapor pressure suppressing component is 2.0% by mass or more, more preferably 10% by mass or more, based on the total amount of the deodorant fragrance composition for hair cosmetics.

In the present invention, the total amount of (1) the chemical deodorant component and / or (2) the vapor pressure suppressing component is at least 5.0% by mass based on the total amount of the deodorant flavor composition for hair cosmetics. , More preferably 15.0% by mass or more. 5.0
If it is less than mass%, the deodorizing effect is insufficient. The deodorant fragrance composition for hair cosmetics of the present invention may comprise only (1) a chemical deodorant component and / or (2) a vapor pressure suppressing component.

In the present invention, it is preferable to use a combination of (1) a chemical deodorant component and (2) a vapor pressure suppressing component from the viewpoint of the deodorant effect.

The deodorant fragrance composition for hair cosmetics of the present invention may further contain a fragrance component other than the above. Examples of such flavor components include menthol, isomenthol, menthol, menthol derivatives, lemon oil, orange oil, lime oil, bergamot oil, lavandin oil, lavender oil, geranium oil, spearmint oil,
Natural essential oils such as peppermint oil, eucalyptus oil, rose oil, sandalwood oil, α-pinene, β-pinene,
Hydrocarbons such as limonene and p-cymene; aliphatic alcohols such as octanol, cis-3-hexenol and p-tert-butylcyclohexanol; terpene alcohols such as citronellol, geraniol and terpineol; benzyl alcohol; phenylethyl alcohol; Aromatic alcohols such as natural alcohols, aliphatic aldehydes, terpene aldehydes, aromatic aldehydes, acetals, chain ketones, cis-jasmon, damascon, yonon, methylyonone and other cyclic ketones, carbene, mentone, camphor and other terpenes Aromatic ketones such as ketones, acetophenone and raspberry ketone, ethers such as dibenzyl ether, oxides such as linalool oxide and rose oxide, and cyclopentade Synthetic musk, such as Norido, γ- nonalactone, lactones, such as γ- undecalactone,
Examples thereof include aliphatic esters such as acetate, propionate and butyrate, and aromatic esters such as benzoate, phenylacetate and salicylate. Among these fragrance components, mint natural essential oil or essential oil components such as peppermint oil, spearmint oil, menthol, isomenthone, menthol, and menthol derivatives are preferred in view of the numbing effect.

When blending these known fragrances with the deodorant fragrance composition for hair cosmetics of the present invention, the components specifically selected and the amounts of the respective components are appropriately selected according to the purpose. And should not be particularly limited.

The hair cosmetics containing the deodorant fragrance composition of the present invention include hair containing or generating odor components such as a perm, a hair straightener, a bleaching agent, a hair dye, a hair bleach, and a hair remover. Cosmetics are mentioned, and among them, a perm, a hair straightener and a hair remover are particularly preferable. The compounding amount of the deodorant fragrance composition in the hair cosmetic of the present invention is usually 0.01 to 2.0% by mass.

The hair cosmetic composition of the present invention may further comprise, in addition to the above-mentioned components, a reducing agent for use as a permanent agent, a hair straightener, a bleaching agent, or an oxidation dye for use as a hair dye, as a main agent for cosmetics. Dyes such as direct dyes, acid dyes, oil-soluble dyes and basic dyes are included.

When used as a permanent agent, a hair straightener or a depigmenting agent, examples of the reducing agent include thioglycolic acid,
Thioglycolate, cysteine, glyceryl thioglycolate, thioglycerin, cysteamine thiosulfate, sodium pyrosulfite and the like.

In the present invention, in addition to the above components,
Other components used in ordinary cosmetics, for example, alcohols such as aromatic alcohols and polyhydric alcohols, cationic surfactants, anionic surfactants, nonionic surfactants, amphoteric surfactants, preservatives, and UV protection Agents, sequestering agents, and the like can be appropriately compounded within a range that does not impair the effects of the present invention.

[0024]

Next, the present invention will be described in more detail with reference to Examples and Comparative Examples. In addition, the compounding amount shown below is represented by mass% unless otherwise specified.

Test Example 1 (First agent of thioglycolic acid-based permanent wave agent) Ammonium thioglycolate (50%) 14.0% by mass Diammonium dithioglycolate (40%) 2.5 Monoethanolamine 0 Aqueous ammonia (28%) 0.5 Ammonium hydrogen carbonate 1.5 EDTA-3Na 0.1 Amino-modified silicone emulsion 4.0 (Toray Silicone SM8702C, manufactured by Dow Corning Toray Co., Ltd.) Marcoat 100 0.5 (Cation manufactured by Calgon, Inc.) Polymer) glycerin 2.0 polyoxyethylene (15E.O.) oleyl ether 0.5 purified water residue

Test Example 2 (First agent of thioglycolic acid-based permanent wave agent) Ammonium thioglycolate (50%) 14.0% by mass Diammonium dithioglycolate (40%) 2.5 Monoethanolamine 0 Aqueous ammonia (28%) 0.5 Ammonium hydrogen carbonate 1.5 EDTA-3Na 0.1 Amino-modified silicone emulsion 4.0 (Toray Silicone SM8702C, manufactured by Dow Corning Toray Co., Ltd.) Marcoat 100 0.5 (Cation manufactured by Calgon, Inc.) Polymer) glycerin 2.0 polyoxyethylene (15E.O.) oleyl ether 0.5 geranyl tiglate 5.0 purified water residue

Test Example 3 (First agent of thioglycolic acid-based permanent wave agent) Ammonium thioglycolate (50%) 14.0% by mass Diammonium dithioglycolate (40%) 2.5 Monoethanolamine 0 Aqueous ammonia (28%) 0.5 Ammonium hydrogen carbonate 1.5 EDTA-3Na 0.1 Amino-modified silicone emulsion 4.0 (Toray Silicone SM8702C, manufactured by Dow Corning Toray Co., Ltd.) Marcoat 100 0.5 (Cation manufactured by Calgon, Inc.) Polymer) glycerin 2.0 polyoxyethylene (15E.O.) oleyl ether 0.5 esterified polymer of adipic acid and oxybis (dipropylene glycol) 5.0 purified water residue

Test Example 4 (First Hair Corrective Agent) Monoethanolamine thioglycolate (50%) 14.0% by mass Diammonium dithioglycolate (40%) 2.5 Monoethanolamine 3.0 EDTA- 3Na 0.1 Cetanol 6.0 Stearyltrimethylammonium chloride (80%) 0.5 Polyoxyethylene (4E.O.) Stearyl ether 3.0 Polyoxyethylene (50E.O.) Oleyl ether 0.3 Purified water Residue

Test Example 5 (Hair Corrector First Agent) Monoethanolamine thioglycolate (50%) 14.0% by mass Diammonium dithioglycolate (40%) 2.5 Monoethanolamine 3.0 EDTA- 3Na 0.1 Cetanol 6.0 Stearyltrimethylammonium chloride (80%) 0.5 Polyoxyethylene (4E.O.) Stearyl ether 3.0 Polyoxyethylene (50E.O.) Oleyl ether 0.3 Fragrance composition 0.07 (geranyl tiglate: esterified polymer of adipic acid and oxybis (dipropylene glycol): menthol = 2: 7: 1) Compounding flavor appropriate amount Purified water residue

Test Example 6 (First Hair Corrective Agent) Monoethanolamine thioglycolate (50%) 14.0% by mass Diammonium dithioglycolate (40%) 2.5 Monoethanolamine 3.0 EDTA- 3Na 0.1 Cetanol 6.0 Stearyltrimethylammonium chloride (80%) 0.5 Polyoxyethylene (4E.O.) Stearyl ether 3.0 Polyoxyethylene (50E.O.) Oleyl ether 0.3 Fragrance composition 0.07 (geranyl tiglate: esterified polymer of adipic acid and oxybis (dipropylene glycol): menthol = 2: 7: 1) purified water residue

The samples obtained in Test Examples 1 to 5 were analyzed by GC-FP
D. The test method and analysis conditions are as follows.

1. Test Method (1) To a bundle of 1 g of hair, add 1 g of the above-mentioned perm agent or hair straightener, rub well, and after a predetermined time (15 min) has elapsed, put the bundle into a 100 ml headspace vial. (2) A filter paper of 1 cm × 1 cm is put in the vial, and 5 μL of an internal standard substance solution (23 ppm in DPG) is dropped to use as a standard substance in the head space. (3) Immediately plug the vial into a vial, then use SPME (Solid
Phase Micro Extract) Insert the fiber and sample the headspace for 5 minutes. Then, GC /
Perform FPD and record the area of each sulfur compound peak.

2. Analytical conditions (1) Gas chromatography Equipment name: 6890 series of Agilent Technologies Column: J & W DB-1 Oven temperature: 35 ° C (retained for 5 minutes) -200 ° C, 8 ° C
/ Min Heating Inlet: 290 ° C Detector: FPD (220 ° C) Carrier gas: Helium (2) SPME Fiber: Carboxen-PDMS

The results are shown in FIGS. Figure 1
5 show the results using the samples of Test Examples 1 to 5, respectively. As can be seen from FIGS. 1 and 2, by adding 5% by mass of geranyl tiglate which is a chemical deodorant, methyl mercaptan (MM), dimethyl disulfide (DMDS), dimethyl trisulfide (DMTS)
Has decreased significantly. Also, as can be seen from FIGS.
By adding 5% by mass of an esterified polymer of adipic acid and oxybis (dipropylene glycol), which are vapor pressure inhibitors, methyl mercaptan (MM), dimethyl disulfide (DMDS) and dimethyl trisulfide (DMTS) can be significantly reduced. Diminished. As can be seen from FIGS. 4 and 5, the same results as described above were obtained with the hair quality correctors of Test Examples 4 and 5. Table 1 shows the peak area of each sample. (Unit: relative ratio)

[0035]

[Table 1] {Test Example 1 2 3 4 5}水 素 Hydrogen sulfide 8616 11247 10692 − − Methyl mercaptan 85548 49525 45772 101028 40537 Dimethyl disulfide 11990 6736 6867 369 134 Dimethyl trisulfide 15977 7270 7516 917 220 ───────────────────────────────────

When the samples of Test Examples 4 to 6 were used, (1) the intensity of the scent and (2) the intensity of the perceived odor were evaluated.
As for the evaluation method, five specialized panels gave their own evaluation points according to the following criteria, and the average points were taken. 0 point: No scent (odor). 1 point: Smell (odor) is weak. 2 points: Smell (odor) is slightly weak. 3 points: Smell (odor) is normal. 4 points: Strong odor (odor). 5 points: Very strong odor (odor).

As a result, the intensity of the scent was 0 point in Test Example 4,
Test Example 5 had 3 points, Test Example 6 had 0 points, and the malodor intensity was 3 points in Test Example 4, and 2 points in both Test Examples 5 and 6.

Example 1 (First agent for thiolactic acid permanent wave agent) Ammonium thiolactate (60%) 8.0% by mass Monoethanolamine thiolactate (40%) 8.0 Monoethanolamine 1.0 Ammonia Water (28%) 0.5 Ammonium hydrogen carbonate 1.5 EDTA-3Na 0.1 Amino-modified silicone emulsion 2.0 (Toray Silicone SM8702C, manufactured by Dow Corning Toray) Marcoat 280 1.0 (Cationic polymer, manufactured by Calgon) Dipropylene glycol 2.0 Polyoxyethylene (20E.O.) Oleyl ether 0.5 Perfume composition 0.15 (geranyl tiglate: hexyl tiglate: propylene glycol = 5: 1: 29) Purified water residue

Example 2 (Sulfite hair setting material) Sodium pyrosulfite 3.0% by mass Urea 10.0 Ethyl alcohol 5.0 Isopropyl alcohol 5.0 Cetylstearyl alcohol 5.0 Cetyltrimethylammonium chloride 1.0 Poly Oxyethylene (30E.O.) Oleyl alcohol 0.5 Perfume composition 1.0 (esterified polymer of adipic acid and oxybis (dipropylene glycol): propylene glycol = 25:10) Purified water residue

Example 3 (First agent for cysteine-based permanent wave) DL-cysteine hydrochloride 4.0% by mass N-acetylcysteine 1.0 L-cysteine 0.5 monoethanolamine 3.0 Ammonia water (28%) 0.5 EDTA-3Na 0.1 cetostearyl alcohol 0.5 cetyltrimethylammonium chloride 0.15 polyoxyethylene (15E.O.) cetyl ether 0.1 fragrance composition 0.1 (menthol: menthol: menthyl acetate) : Propylene glycol = 5: 10: 25: 310) Purified water residue

Example 4 (Hair remover) Calcium thioglycolate 7.0% by mass Sodium pyrosulfite 4.0 Calcium hydroxide 0.5 Sodium hydroxide 0.1 Seto stearyl alcohol 10.0 Liquid paraffin 5.0 Oleic acid monoglyceride 1.0 Polyoxyethylene (40E.O.) Oleyl ether 0.5 Perfume composition 0.1 (geranyl tiglate: hexyl tiglate: esterified product of adipic acid and oxybis (dipropylene glycol) polymer: propylene Glycol = 5: 1: 25: 4) Purified water residue

Example 5 (First Hair Correction Agent) Ammonium Thioglycolate (50%) 14.0% by Mass Diammonium Dithioglycolate (40%) 2.5 Monoethanolamine 1.0 Ammonia Water (28 %) 0.5 Ammonium hydrogen carbonate 1.0 EDTA-3Na 0.1 Ceto stearyl alcohol 8.0 Cetyltrimethylammonium chloride 1.0 Stearyltrimethylammonium chloride 1.0 Dimethylpolysiloxane 3.0 Liquid paraffin 0.5 Poly Oxyethylene (40E.O.) Oleyl ether 1.0 Fragrance composition 0.07 (geranyl tiglate: esterified product of adipic acid and oxybis (dipropylene glycol): menthol = 2: 7: 1) Water residue

[0043]

As described above, according to the present invention, a deodorant fragrance for hair cosmetics which can effectively reduce the odor of hair cosmetics such as perm agents, hair straighteners, hair dyes, hair removers and the like. A composition can be provided.

[Brief description of the drawings]

FIG. 1 is a diagram showing a GC-FPD of Test Example 1.

FIG. 2 is a view showing a GC-FPD of Test Example 2.

FIG. 3 is a view showing a GC-FPD of Test Example 3;

FIG. 4 is a view showing a GC-FPD of Test Example 4;

FIG. 5 is a view showing a GC-FPD of Test Example 5;

 ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Yuji Terashima 2-2-1 Hayabuchi, Tsuzuki-ku, Yokohama, Kanagawa Prefecture Inside Shiseido Research Center (Shin-Yokohama) (72) Inventor Sanae Kubo Hayabuchi, Tsuzuki-ku, Yokohama, Kanagawa 2-2-1 Shiseido Research Center (Shin-Yokohama) F term (reference) 4C083 AB032 AB082 AB352 AC022 AC072 AC102 AC182 AC422 AC532 AC542 AC582 AC662 AC682 AC692 AC772 AD112 AD132 AD152 AD162 BB41 CC31 CC32 CC34 DD06 DD23 EE06 EE07 EE25 FF01

Claims (8)

[Claims] 1. A deodorant fragrance composition for hair cosmetics comprising one or more selected from the group consisting of the following (1) and (2) as an active ingredient. (1) Chemical deodorant component (2) Vapor pressure suppressing component 2. The deodorant fragrance composition for hair cosmetics according to claim 1, wherein (1) a chemical deodorant component and (2) a vapor pressure suppressing component are used in combination. 3. The deodorant fragrance composition for hair cosmetics according to claim 1, further comprising a fragrance component. 4. The deodorant fragrance composition for hair cosmetics according to claim 1, wherein the chemical deodorant component is one or more selected from aldehydes, formate esters and tiglic acid derivatives. 5. The vapor pressure suppressing component is one or more selected from tetrahydromethyl aviate, dihydromethyl aviate, methyl abietic acid, and an esterified polymer of adipic acid and oxybis (dipropylene glycol). Item 2. A deodorant fragrance composition for hair cosmetics according to Item 1. 6. A hair cosmetic comprising the deodorant fragrance composition according to claim 1. 7. The hair cosmetic according to claim 6, which is a perm, a hair straightener or a hair remover. 8. An odor component in the hair cosmetic and / or a part of an odor component generated during use of the hair cosmetic is chemically changed by a chemical deodorant component to deodorize the cosmetic, and
A method for deodorizing hair cosmetics, wherein odors during use of hair cosmetics are reduced by suppressing transpiration of the odor components by a vapor pressure suppressing component.