JP2002176967A - Method and apparatus for observing fermentation state in methane fermentation tank - Google Patents

Method and apparatus for observing fermentation state in methane fermentation tank

Info

Publication number
JP2002176967A
JP2002176967A JP2000381473A JP2000381473A JP2002176967A JP 2002176967 A JP2002176967 A JP 2002176967A JP 2000381473 A JP2000381473 A JP 2000381473A JP 2000381473 A JP2000381473 A JP 2000381473A JP 2002176967 A JP2002176967 A JP 2002176967A
Authority
JP
Japan
Prior art keywords
gas
fermentation tank
gas chamber
fermentation
chamber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000381473A
Other languages
Japanese (ja)
Other versions
JP3430149B2 (en
Inventor
Kozo Nagai
弘三 永易
Hironori Ozaki
弘憲 尾崎
Kazuyoshi Takagaki
一良 高垣
Yasushi Isshiki
泰志 一色
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kawasaki Heavy Industries Ltd
Original Assignee
Kawasaki Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Heavy Industries Ltd filed Critical Kawasaki Heavy Industries Ltd
Priority to JP2000381473A priority Critical patent/JP3430149B2/en
Publication of JP2002176967A publication Critical patent/JP2002176967A/en
Application granted granted Critical
Publication of JP3430149B2 publication Critical patent/JP3430149B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M23/00Constructional details, e.g. recesses, hinges
    • C12M23/36Means for collection or storage of gas; Gas holders
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M41/00Means for regulation, monitoring, measurement or control, e.g. flow regulation
    • C12M41/40Means for regulation, monitoring, measurement or control, e.g. flow regulation of pressure
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

PROBLEM TO BE SOLVED: To instantaneously judge the state of fermentation in a methane fermentation tank and enable to respond in an early stage to the occurrence of an abnormal fermentation. SOLUTION: A generated gas-collecting device 18 for continuously measuring pressures is installed to be located in a liquid in the fermentation tank 10. It has a gas chamber 30 capable of collecting the generated gas and installed with a gas-collecting plate 32 having a shape like a solder's camp hat in the lower part of the gas chamber 30 and a baffle plate 34 is installed under the plate 32. An aerobic siphon pipe 36 is installed in the gas chamber 30, the one end of which is open in the upper part of the gas chamber 30 and the other end of which is communicated with an aerobic pipe 38 on the upper face of the gas chamber 30. A pressure gauge 40 is installed in the gas chamber 30 and the pressure in the gas chamber 30 is continuously measured. The state of fermentation is judged by analyzing a time-dependent change of continuously measured gas pressures.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、メタン発酵におけ
る発生ガス量の刻々の変化を、発生ガスの一部を捕捉
し、ある量になるとガス噴出し、再度発生ガスを捕捉す
るガス室内の圧力を連続測定できるようにした装置を、
1個あるいは必要なら複数個メタン発酵槽内の発酵状況
を診断したい場所へ設置することで、そこでの圧力変化
パターンから知ることができ、さらに、その解析により
発酵状況を診断し連続監視できるメタン発酵槽内の発酵
状況監視方法及び装置に関するものである。
BACKGROUND OF THE INVENTION The present invention relates to a process for measuring the change in the amount of generated gas in methane fermentation every time, by capturing a part of the generated gas, ejecting the gas at a certain amount, and re-pressing the generated gas in the gas chamber. Equipment that enables continuous measurement of
By installing one or more fermentation tanks in the methane fermentation tank where necessary to diagnose the fermentation situation, it is possible to know the pressure change pattern there, and furthermore, by analyzing the fermentation situation, methane fermentation can be diagnosed and continuously monitored The present invention relates to a fermentation status monitoring method and apparatus in a tank.

【0002】[0002]

【従来の技術】メタン発酵を実施している発酵槽の内部
状況を連続的に知るためには、各種の分析用センサーを
用いて連続あるいは半連続でサンプルを抜き出し、サン
プル中の成分の濃度変化を測定して、その結果を総合し
て発酵状況を解析することが通常の手法である。また、
ガス発生量については連続測定して、その発生量の変化
により、全般的な槽内の発酵状況を推定することも普通
に実施されている。
2. Description of the Related Art In order to continuously know the internal state of a fermenter in which methane fermentation is being performed, samples are continuously or semi-continuously extracted using various analytical sensors, and changes in the concentration of components in the sample are performed. It is a common technique to measure the fermentation conditions and analyze the fermentation status based on the results. Also,
It is common practice to continuously measure the amount of gas generated and to estimate the overall fermentation status in the tank based on the change in the amount of gas generated.

【0003】また、メタン発酵のメタン生成活性を直接
測定する方法としては、特開平10−227781号公
報に、メタン生成活性測定用の圧力容器内に分析に供す
るサンプルを投入し、所定の温度管理や攪拌を加えなが
らサンプルのメタン発酵を継続させ、その圧力容器内圧
力を圧力センサーにて連続測定して、その圧力変化量か
らメタン生成活性を測定する方法及び装置が記載されて
いる。
As a method for directly measuring the methane production activity of methane fermentation, Japanese Patent Application Laid-Open No. Hei 10-227781 discloses a method in which a sample to be analyzed is placed in a pressure vessel for measuring the methane production activity and a predetermined temperature control is performed. A method and an apparatus are described in which methane fermentation of a sample is continued while adding water or stirring, the pressure in the pressure vessel is continuously measured by a pressure sensor, and the methane production activity is measured from the pressure change.

【0004】[0004]

【発明が解決しようとする課題】上記の方法は何れもサ
ンプルを取った後の分析評価であり、いくら分析時間が
短縮されたとしても、サンプル採取時と分析結果が出た
時点とには時間差がでて、発酵の異常があった場合等に
は、そのことを知り、対策をとるまでにかなりの時間差
が生じる。また、通常実施されている発生ガスの連続測
定による診断の場合は、測定されるガスが槽全体の発生
ガスの混合であり、槽全体の平均的なメタン生成活性し
か診断することができない。したがって、これらの方法
では槽内の場所の違いによる状況変化や短時間の変化に
ついては、ほとんど計測することができず、状況の変化
に敏感に対応することができず、異常を知っても、その
時点では効果的な対策をとることが不可能なケースが多
かった。
All of the above methods are analysis evaluations after taking a sample. Even if the analysis time is shortened, there is a time lag between the time of sampling and the time when an analysis result is obtained. When there is an abnormality in fermentation, there is a considerable time difference between the fact and the fact that a measure is taken. Further, in the case of the diagnosis by the continuous measurement of the generated gas which is usually performed, the gas to be measured is a mixture of the generated gas in the entire tank, and only the average methane generation activity in the entire tank can be diagnosed. Therefore, with these methods, it is hardly possible to measure a change in the situation or a change in a short time due to a difference in the location in the tank, and it is not possible to respond sensitively to the change in the situation. At that time, it was often impossible to take effective measures.

【0005】本発明は上記の諸点に鑑みなされたもの
で、本発明の目的は、非常に簡単な構造で、かつ自動で
ガス捕集と噴出しの繰返しが可能な発生ガス捕集器を発
酵槽内に1個あるいは複数個必要な場所に設置し、その
ガス捕集器内のガス室内の圧力変化を連続測定すること
により、発酵槽内の必要とする場所の発酵状況を即時に
知ることができ、そのことにより、メタン発酵槽の発酵
状況を総合的に瞬時に診断することが可能となり、異常
発生時にも早期に対応することができるようになるメタ
ン発酵槽内の発酵状況監視方法及び装置を提供すること
にある。
The present invention has been made in view of the above points, and an object of the present invention is to provide a fermented gas collector having a very simple structure and capable of automatically repeating gas collection and ejection. Immediately know the fermentation situation in the required location in the fermentation tank by installing one or more in the required location in the tank and continuously measuring the pressure change in the gas chamber in the gas collector This makes it possible to diagnose the fermentation status of the methane fermentation tank comprehensively and instantaneously, and to be able to respond early even when an abnormality occurs. It is to provide a device.

【0006】[0006]

【課題を解決するための手段】上記の目的を達成するた
めに、本発明のメタン発酵槽内の発酵状況監視方法は、
メタン発酵槽内で発生したガスを該発酵槽内に鉛直方向
又は略鉛直方向に設けられた底部が開口しガス回収用部
材が下部に接続されたガス室に回収し、所定量を充満さ
せた後、ガス室内の発生ガスを上部のガス噴出口から吹
き出させるとともに、ガス室の下側に形成されたガス回
収用部材と邪魔板又は発酵槽底面との隙間、及びガス室
の上側の配管に上端が接続されガス回収用部材の下側に
下端が位置する吸液管の少なくともいずれかから液を吸
い上げる発生ガス捕集器を用いたメタン発酵槽内の発酵
状況監視方法であって、ガス室内のガス圧力を連続測定
し、その経時変化を測定することにより槽内の発酵状況
を診断するように構成されている(図1〜図5、図8、
図9参照)。
In order to achieve the above object, a method for monitoring a fermentation state in a methane fermentation tank according to the present invention comprises:
The gas generated in the methane fermentation tank was collected in a gas chamber connected to the lower part provided with a bottom provided vertically or substantially vertically in the fermentation tank and connected to the lower part, and filled with a predetermined amount. After that, the generated gas in the gas chamber is blown out from the upper gas outlet, and the gap between the gas recovery member formed on the lower side of the gas chamber and the baffle plate or the bottom of the fermentation tank, and the upper pipe of the gas chamber. A method for monitoring a fermentation state in a methane fermentation tank using an evolved gas collector that sucks up liquid from at least one of a liquid suction pipe having an upper end connected and a lower end positioned below a gas recovery member, comprising: It is configured to continuously measure the gas pressure and measure the change with time to diagnose the fermentation situation in the tank (FIGS. 1 to 5, 8,
(See FIG. 9).

【0007】また、本発明の方法は、メタン発酵槽内で
発生したガスを該発酵槽内に鉛直方向又は略鉛直方向に
設けられた底部が開口しガス回収用部材が下部に接続さ
れたガス室に回収し、所定量を充満させた後、ガス室内
の発生ガスを上部のガス噴出口から吹き出させるととも
に、ガス室の下側に形成されたガス回収用部材と邪魔板
又は発酵槽底面との隙間、及びガス室の上側の配管に上
端が接続されガス回収用部材の下側に下端が位置する吸
液管の少なくともいずれかから液を吸い上げる発生ガス
捕集器を用いたメタン発酵槽内の発酵状況監視方法であ
って、発生ガス捕集器を発酵槽内に複数個設置して、そ
れぞれのガス室内のガス圧力を連続測定し、その経時変
化を測定することにより槽内の発酵状況を診断すること
を特徴としている(図8、図9参照)。
Further, according to the method of the present invention, a gas generated in a methane fermentation tank is provided with a gas having a bottom provided vertically or substantially vertically in the fermentation tank and a gas recovery member connected to a lower part. After the gas is collected in the chamber and filled with a predetermined amount, the generated gas in the gas chamber is blown out from the upper gas outlet, and a gas recovery member formed on the lower side of the gas chamber and a baffle plate or a bottom of the fermentation tank. Inside the methane fermentation tank using a generated gas collector that sucks liquid from at least one of the liquid suction pipes whose upper end is connected to the upper pipe of the gas chamber and whose lower end is located below the gas recovery member. The method for monitoring the fermentation state of the above, wherein a plurality of evolved gas collectors are installed in the fermentation tank, the gas pressure in each gas chamber is continuously measured, and the change over time is measured, whereby the fermentation state in the tank is measured. Characterized by diagnosing See FIGS. 8 and 9).

【0008】上記の本発明の方法において、ガス室内に
両端部の位置より下方となる部分を有する管を設け、該
管の一端をガス室内に開口させ、他端をガス室上部のガ
ス噴出口に連通させることが好ましい(図3等参照)。
In the above method of the present invention, a pipe having a portion below the positions of both ends is provided in the gas chamber, one end of the pipe is opened in the gas chamber, and the other end is a gas outlet at the upper part of the gas chamber. (See FIG. 3 etc.).

【0009】また、本発明の方法は、メタン発酵槽内で
発生したガスを該発酵槽内に鉛直方向又は略鉛直方向に
設けられた底部が開口し側面部材を介してガス噴出用通
路が形成されたガス室に回収し、所定量を充満させた
後、ガス室内の発生ガスをガス噴出用通路を経由してガ
ス噴出口から吹き出させるとともに、ガス噴出用通路の
外側に形成された下端が開口し上端がガス噴出口に連通
する配管に接続された吸液通路から液を吸い上げる発生
ガス捕集器を用いたメタン発酵槽内の発酵状況監視方法
であって、ガス室内のガス圧力を連続測定し、その経時
変化を測定することにより槽内の発酵状況を診断するこ
とを特徴としている(図6、図7参照)。
[0009] In the method of the present invention, the gas generated in the methane fermentation tank is opened in the fermentation tank in a vertical or substantially vertical direction, and a gas ejection passage is formed through a side member. After being collected in the gas chamber and filled with a predetermined amount, the generated gas in the gas chamber is blown out from the gas jet through the gas jet passage, and the lower end formed outside the gas jet passage is closed. A fermentation status monitoring method in a methane fermentation tank using an evolved gas collector that sucks up liquid from a liquid suction passage connected to a pipe that is open and has an upper end communicating with a gas outlet. It is characterized in that the fermentation state in the tank is diagnosed by measuring and measuring the change with time (see FIGS. 6 and 7).

【0010】また、本発明の方法は、メタン発酵槽内で
発生したガスを該発酵槽内に鉛直方向又は略鉛直方向に
設けられた底部が開口し側面部材を介してガス噴出用通
路が形成されたガス室に回収し、所定量を充満させた
後、ガス室内の発生ガスをガス噴出用通路を経由してガ
ス噴出口から吹き出させるとともに、ガス噴出用通路の
外側に形成された下端が開口し上端がガス噴出口に連通
する配管に接続された吸液通路から液を吸い上げる発生
ガス捕集器を用いたメタン発酵槽内の発酵状況監視方法
であって、発生ガス捕集器を発酵槽内に複数個設置し
て、それぞれのガス室内のガス圧力を連続測定し、その
経時変化を測定することにより槽内の発酵状況を診断す
ることを特徴としている。
[0010] In the method of the present invention, the gas generated in the methane fermentation tank is opened in the fermentation tank in a vertical or substantially vertical direction, and a gas ejection passage is formed through a side member. After being collected in the gas chamber and filled with a predetermined amount, the generated gas in the gas chamber is blown out from the gas jet through the gas jet passage, and the lower end formed outside the gas jet passage is closed. A fermentation status monitoring method in a methane fermentation tank that uses a generated gas collector that sucks liquid from a liquid suction passage connected to a pipe that opens and has an upper end communicating with a gas outlet. The method is characterized in that a plurality of tanks are installed in the tank, the gas pressure in each gas chamber is continuously measured, and the change over time is measured to diagnose the fermentation state in the tank.

【0011】これらの本発明の方法において、ガス室内
のガス圧力の上昇速度の経時変化と、ガス室のガス噴出
しが発生してから、次のガス噴出しが発生するまでの間
隔時間を計測することにより、発酵槽内の発酵状況の場
所的な相違及び/又は時間的な相違を診断することがで
きる。また、これらの本発明の方法において、ガス室の
ガス噴出口から噴き出すガスの少なくとも一部をサンプ
リングして分析することにより発酵状況を診断すること
も可能である。
In the method of the present invention, the time-dependent change in the rate of rise of the gas pressure in the gas chamber and the interval time from the occurrence of gas ejection in the gas chamber to the occurrence of the next gas ejection are measured. By doing so, it is possible to diagnose a difference in location and / or a difference in time in the state of fermentation in the fermenter. In these methods of the present invention, it is also possible to diagnose the fermentation status by sampling and analyzing at least a part of the gas spouted from the gas spout of the gas chamber.

【0012】本発明のメタン発酵槽内の発酵状況監視装
置は、メタン発酵槽内の液中に位置するように鉛直方向
又は略鉛直方向に設けられた底部が開口したガス室と、
このガス室の下部に接続されたガス回収用の陣笠状部材
と、この陣笠状部材との間に隙間を形成するように陣笠
状部材の下側に略水平に設置された邪魔板と、前記ガス
室の上面部材に設けられたガス噴出口とを包含してなる
発生ガス捕集器を用いたメタン発酵槽内の発酵状況監視
装置であって、ガス室内に圧力計測手段が設けられ、こ
の圧力計測手段に接続されたデータ変換手段及びデータ
解析手段により、連続測定されたガス圧力の経時変化か
ら発酵槽内の発酵状況を診断するようにしたことを特徴
としている(図1〜図4参照)。
The apparatus for monitoring fermentation status in a methane fermentation tank according to the present invention comprises: a gas chamber having a bottom opening and provided in a vertical or substantially vertical direction so as to be located in a liquid in the methane fermentation tank;
A gas-collecting umbrella member connected to the lower part of the gas chamber, and a baffle plate installed substantially horizontally below the umbrella member so as to form a gap between the umbrella member and the umbrella member; A fermentation status monitoring device in a methane fermentation tank using a generated gas collector including a gas ejection port provided in an upper member of a gas chamber, wherein a pressure measuring means is provided in the gas chamber. It is characterized in that the fermentation condition in the fermenter is diagnosed from the time-dependent change of the gas pressure measured continuously by the data conversion means and the data analysis means connected to the pressure measurement means (see FIGS. 1 to 4). ).

【0013】また、本発明の装置は、メタン発酵槽内の
液中に位置するように鉛直方向又は略鉛直方向に設けら
れた底部が開口したガス室と、このガス室の下部に接続
されたガス回収用の陣笠状部材と、この陣笠状部材との
間に隙間を形成するように陣笠状部材の下側に略水平に
設置された邪魔板と、前記ガス室の上面部材に設けられ
たガス噴出口とを包含してなる発生ガス捕集器を用いた
メタン発酵槽内の発酵状況監視装置であって、発生ガス
捕集器が発酵槽内に複数個設置されており、それぞれの
ガス室内に圧力計測手段が設けられ、これらの圧力計測
手段に接続されたデータ変換手段及びデータ解析手段に
より、連続測定されたガス圧力の経時変化から発酵槽内
の発酵状況を診断するようにしたことを特徴としている
(図8、図9参照)。
The apparatus of the present invention is connected to a lower part of the gas chamber, which is provided in the liquid in the methane fermentation tank in a vertical or substantially vertical direction and has an open bottom. A gas-covered umbrella member, a baffle plate installed substantially horizontally below the umbrella member so as to form a gap between the umbrella member, and an upper surface member of the gas chamber. A fermentation status monitoring device in a methane fermentation tank using a generated gas collector including a gas ejection port, wherein a plurality of generated gas collectors are installed in the fermentation tank, and each gas A pressure measuring means is provided in the room, and the data conversion means and the data analyzing means connected to these pressure measuring means diagnose the fermentation state in the fermenter from the time-dependent change of the continuously measured gas pressure. (See FIGS. 8 and 9) .

【0014】上記の本発明の装置において、ガス室内に
両端部の位置より下方となる部分を有する管が設けら
れ、該管の一端がガス室内に開口しており、他端がガス
室上部のガス噴出口に連通している構成とすることが好
ましい(図3等参照)。また、これらの本発明の装置に
おいて、発生ガス捕集器に、ガス室の上側のガス噴出口
と連通する配管に上端が接続されガス回収用の陣笠状部
材を貫通して該部材の下側に下端が位置する1本又は複
数本の吸液管を設ける場合もある(図5参照)。また、
ガス室内に両端部の位置より下方となる部分を有する管
を設ける代わりに、ガス室のガス噴出口と連通する配管
に開閉弁を設けた構成とすることも可能である(図4参
照)。
In the above-described apparatus of the present invention, a pipe having a portion below the positions of both ends is provided in the gas chamber, and one end of the pipe is opened in the gas chamber, and the other end is provided in the upper part of the gas chamber. It is preferable to adopt a configuration communicating with the gas ejection port (see FIG. 3 and the like). Further, in these devices of the present invention, the upper end of the generated gas collector is connected to a pipe communicating with the gas ejection port on the upper side of the gas chamber. In some cases, one or a plurality of liquid suction pipes whose lower ends are located may be provided (see FIG. 5). Also,
Instead of providing a pipe having portions below the positions of both ends in the gas chamber, it is also possible to adopt a configuration in which an on-off valve is provided in a pipe that communicates with a gas ejection port of the gas chamber (see FIG. 4).

【0015】また、本発明の装置は、メタン発酵槽内の
液中に位置するように鉛直方向又は略鉛直方向に設けら
れた底部が開口したガス室と、このガス室に側面部材を
介して設けられた一端がガス室内に開口し他端がガス室
外側にガス噴出口として開口したガス噴出用通路と、こ
のガス噴出用通路の外側に形成された下端が開口し上端
がガス噴出口に連通する配管に接続された吸液通路とを
包含してなる発生ガス捕集器を用いたメタン発酵槽内の
発酵状況監視装置であって、ガス室内に圧力計測手段が
設けられ、この圧力計測手段に接続されたデータ変換手
段及びデータ解析手段により、連続測定されたガス圧力
の経時変化から発酵槽内の発酵状況を診断するようにし
たことを特徴としている(図6、図7参照)。
Further, the apparatus of the present invention comprises a gas chamber provided in a vertical or substantially vertical direction so as to be located in a liquid in a methane fermentation tank and having an open bottom, and a side member connected to the gas chamber via a side member. A gas ejection passage having one end opened into the gas chamber and the other end opened as a gas ejection port outside the gas chamber, and a lower end formed outside the gas ejection passage is open and an upper end is formed in the gas ejection port. A fermentation status monitoring device in a methane fermentation tank using a generated gas collector including a liquid suction passage connected to a communicating pipe, wherein a pressure measuring means is provided in a gas chamber, and the pressure measurement is performed. The method is characterized in that the fermentation condition in the fermenter is diagnosed from the time-dependent change of the gas pressure measured continuously by the data conversion means and the data analysis means connected to the means (see FIGS. 6 and 7).

【0016】また、本発明の装置は、メタン発酵槽内の
液中に位置するように鉛直方向又は略鉛直方向に設けら
れた底部が開口したガス室と、このガス室に側面部材を
介して設けられた一端がガス室内に開口し他端がガス室
外側にガス噴出口として開口したガス噴出用通路と、こ
のガス噴出用通路の外側に形成された下端が開口し上端
がガス噴出口に連通する配管に接続された吸液通路とを
包含してなる発生ガス捕集器を用いたメタン発酵槽内の
発酵状況監視装置であって、発生ガス捕集器が発酵槽内
に複数個設置されており、それぞれのガス室内に圧力計
測手段が設けられ、これらの圧力計測手段に接続された
データ変換手段及びデータ解析手段により、連続測定さ
れたガス圧力の経時変化から発酵槽内の発酵状況を診断
するようにしたことを特徴としている。
Further, the apparatus of the present invention comprises a gas chamber having a bottom opening and provided in a vertical or substantially vertical direction so as to be located in the liquid in the methane fermentation tank. A gas ejection passage having one end opened into the gas chamber and the other end opened as a gas ejection port outside the gas chamber, and a lower end formed outside the gas ejection passage is open and an upper end is formed in the gas ejection port. A fermentation state monitoring device in a methane fermentation tank using a generated gas collector including a liquid suction passage connected to a communicating pipe, wherein a plurality of generated gas collectors are installed in the fermentation tank. The pressure measurement means is provided in each gas chamber, and the data conversion means and the data analysis means connected to these pressure measurement means determine the fermentation condition in the fermenter from the time-dependent change of the gas pressure continuously measured. Diagnostics It is characterized in.

【0017】[0017]

【発明の実施の形態】以下、本発明の実施の形態につい
て説明するが、本発明は下記の実施の形態に何ら限定さ
れるものではなく、適宜変更して実施することが可能な
ものである。図1、図2は、本発明の実施の第1形態に
よるメタン発酵槽内の発酵状況監視方法を実施する装置
の概略構成を示しており、図1は発酵装置の全体構成を
示している。本実施の形態は、圧力連続計測用発生ガス
捕集器を発酵槽内に1個セットしたものである。図1に
示すように、発酵槽10の上部には被処理物投入口12
及び発生ガス出口14が設けられ、上側部には液出口1
6が設けられている。この発酵槽10内の液中に位置す
るように、鉛直方向又は略鉛直方向に圧力連続計測用の
発生ガス捕集器18が設置されている。発生ガス捕集器
18の詳細な構成及びガス圧力の連続測定による発酵状
況の監視・診断の詳細な説明については後述する。20
はデータ変換機、22は計算機、24は記録計である。
発酵槽10では、被処理物投入口12から投入された被
処理物(例えば、家畜ふん尿、食品廃液、汚泥等の湿潤
有機性廃棄物)が嫌気性条件下で消化(発酵)され、発
酵が進むにつれてメタン等のガスが発生する。発生ガス
は発生ガス出口14から取り出されガスタンク26に一
旦貯留された後、種々の用途に有効利用される。発酵処
理後の液は液出口16から抜き出された後、沈殿槽28
で汚泥が沈降分離され、上澄液は処理水として排出され
る。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the present invention will be described below, but the present invention is not limited to the following embodiments and can be implemented with appropriate modifications. . 1 and 2 show a schematic configuration of an apparatus for implementing a method for monitoring a fermentation situation in a methane fermentation tank according to a first embodiment of the present invention, and FIG. 1 shows an entire configuration of the fermentation apparatus. In the present embodiment, one generated gas collector for continuous pressure measurement is set in a fermentation tank. As shown in FIG.
And a generated gas outlet 14, and the liquid outlet 1 is provided on the upper side.
6 are provided. An evolved gas collector 18 for continuous pressure measurement is provided in the liquid in the fermenter 10 in a vertical direction or a substantially vertical direction. The detailed configuration of the generated gas collector 18 and the detailed description of the monitoring and diagnosis of the fermentation status by continuous measurement of the gas pressure will be described later. 20
Is a data converter, 22 is a computer, and 24 is a recorder.
In the fermenter 10, an object to be treated (for example, moist organic waste such as livestock manure, food waste liquid, and sludge) supplied from the object to be treated inlet 12 is digested (fermented) under anaerobic conditions, and fermentation is performed. As it proceeds, gas such as methane is generated. The generated gas is taken out from the generated gas outlet 14 and once stored in the gas tank 26, and then is effectively used for various uses. After the liquid after the fermentation treatment is extracted from the liquid outlet 16, the sedimentation tank 28
Sludge is settled and separated, and the supernatant is discharged as treated water.

【0018】つぎに、図2等に基づいて本実施の形態の
発酵状況監視方法及び装置を詳細に説明する。図2に示
す圧力連続計測用発生ガス捕集器を拡大したものが図3
である。図2、図3に示すように、圧力連続計測用の発
生ガス捕集器18は、発酵槽10内の液中に位置するよ
うに鉛直方向又は略鉛直方向に設置されており、底部が
開口し発生ガスの捕集が可能なガス室30を有してい
る。ガス室30の下部にはガス回収用陣笠状板32がか
さ状に取り付けられており、ガス回収用陣笠状板32の
下側には水平又は略水平に邪魔板34が設置されてい
る。なお、邪魔板34を設けない構成とすることも可能
である。ガス室30内には曝気用サイフォン管36が設
けられており、サイフォン管36の一端はガス室30内
の上部に開口し、他端はガス室30の上面に接続された
曝気用配管38に連通している。曝気用サイフォン管3
6の形状としては、一例として、略U字管形状、略V字
管形状等が用いられるが、これらの形状に限定されるも
のではなく、両端部の位置より下方となる部分を有する
形状の管であれば何ら差し支えない。また、ガス室30
内の圧力が連続測定できるようにガス室上部に圧力計
(圧力センサ)40が設けられている。42は支持部材
である。
Next, the fermentation status monitoring method and apparatus of the present embodiment will be described in detail with reference to FIG. FIG. 3 is an enlarged view of the generated gas collector for continuous pressure measurement shown in FIG.
It is. As shown in FIGS. 2 and 3, the generated gas collector 18 for continuous pressure measurement is installed in a vertical direction or a substantially vertical direction so as to be located in the liquid in the fermenter 10. And a gas chamber 30 capable of collecting generated gas. A gas-collecting umbrella-shaped plate 32 is attached to the lower part of the gas chamber 30 in a bulk shape, and a baffle plate 34 is installed horizontally or substantially horizontally below the gas-collecting umbrella-shaped plate 32. Note that a configuration in which the baffle plate 34 is not provided is also possible. An aeration siphon pipe 36 is provided in the gas chamber 30, and one end of the siphon pipe 36 is opened at an upper part in the gas chamber 30, and the other end is connected to an aeration pipe 38 connected to the upper surface of the gas chamber 30. Communicating. Aeration siphon tube 3
As the shape of 6, for example, a substantially U-shaped tube shape, a substantially V-shaped tube shape, or the like is used, but the shape is not limited to these shapes. If it's a tube, it's fine. The gas chamber 30
A pressure gauge (pressure sensor) 40 is provided above the gas chamber so that the internal pressure can be continuously measured. Reference numeral 42 denotes a support member.

【0019】発酵槽10内に設置された発生ガス捕集器
18は、ガス室30の圧力が測定でき、かつ、自動でガ
ス捕集と噴出しの繰返しが可能(自動修復可能)な構成
である。すなわち、発酵槽内液はガス回収用陣笠状板3
2と邪魔板34の隙間を通ってこれらの間に入り、ここ
で発生したガスはガス回収用陣笠状板32で捕集されガ
ス室30に集まる。ガス室30では、曝気用サイフォン
管36最下部までガスが捕集されると、サイフォン管3
6からガスが噴出し、ガス回収用陣笠状板32と邪魔板
34の間に発酵槽内液が新たに入り、ガス発生と捕集が
再度始まる。その間のガス室30内の圧力は圧力計40
で連続測定される。そして、圧力連続計測用の発生ガス
捕集器18からの圧力信号は、データ変換機20で電気
信号とし、これを計算機22にて解析する。その結果は
記録計24に記録する。
The generated gas collector 18 installed in the fermenter 10 has a configuration in which the pressure of the gas chamber 30 can be measured and the gas collection and ejection can be automatically repeated (automatic restoration is possible). is there. In other words, the liquid in the fermenter is used as a gas recovery hood 3
The gas passes through the gap between the baffle plate 2 and the baffle plate 34, and the gas generated here is collected by the gas collecting hood 32 and collected in the gas chamber 30. In the gas chamber 30, when the gas is collected to the lowermost part of the aeration siphon tube 36, the siphon tube 3
Gas is blown out from 6 and the liquid in the fermentation tank newly enters between the gas collecting hood 32 and the baffle 34, and the gas generation and collection start again. During this time, the pressure in the gas chamber 30 is
Is measured continuously. The pressure signal from the generated gas collector 18 for continuous pressure measurement is converted into an electric signal by the data converter 20, and is analyzed by the computer 22. The result is recorded in recorder 24.

【0020】図2、図3に示す圧力連続計測用発生ガス
捕集器を用いる場合は、ガス捕集と噴出しが自動的に繰
り返され、発酵槽内液の対流も自動的に生じるので、発
酵槽内の攪拌も無動力で行える。ただし、本実施の形態
においては、図3に示す圧力連続計測用発生ガス捕集器
以外にも、例えば、図4に示すような圧力連続計測用発
生ガス捕集器を用いることもできる。すなわち、図4に
示す圧力連続計測用発生ガス捕集器を図2の構成に適用
することが可能である。
When the generated gas collector for continuous pressure measurement shown in FIGS. 2 and 3 is used, gas collection and ejection are automatically repeated, and convection of the liquid in the fermentation tank is automatically generated. Agitation in the fermenter can also be performed without power. However, in the present embodiment, besides the generated gas collector for continuous pressure measurement shown in FIG. 3, for example, a generated gas collector for continuous pressure measurement as shown in FIG. 4 can also be used. That is, the generated gas collector for continuous pressure measurement shown in FIG. 4 can be applied to the configuration of FIG.

【0021】図4に示す発生ガス捕集器18aは、底部
が開口し発生ガスの捕集が可能なガス室30を有し、ガ
ス室30の下部にガス回収用陣笠状板32が取り付けら
れ、ガス回収用陣笠状板32の下側に邪魔板34が設置
されている。なお、邪魔板34を設けない構成とするこ
とも可能である。ガス室30の上面にはガス噴出口44
が設けられ、ガス噴出口44と連通するガス配管46に
は開閉弁48が設けられている。開閉弁48は自動制御
弁でも良いし、単に開閉するだけの簡単な構成でも良
い。また、ガス室30内の圧力が連続測定できるように
ガス室上部に圧力計(圧力センサ)40が設けられてい
る。発生し捕集されたガスはガス室30に集まり、例え
ば、所定量までガスが捕集されたときに開閉弁48を開
いてガスを噴出させる。このとき、ガス回収用陣笠状板
32と邪魔板34の間に発酵槽内液が新たに入り、ガス
発生と捕集が再度始まる。その間のガス室30内の圧力
は圧力計40で連続測定される。
The generated gas collector 18a shown in FIG. 4 has a gas chamber 30 which is open at the bottom and capable of collecting generated gas, and a gas collecting fin plate 32 is attached to the lower part of the gas chamber 30. A baffle plate 34 is provided below the gas-collecting skirt plate 32. Note that a configuration in which the baffle plate 34 is not provided is also possible. A gas outlet 44 is provided on the upper surface of the gas chamber 30.
Is provided, and an on-off valve 48 is provided in a gas pipe 46 communicating with the gas ejection port 44. The opening / closing valve 48 may be an automatic control valve, or may have a simple configuration of simply opening and closing. Further, a pressure gauge (pressure sensor) 40 is provided above the gas chamber 30 so that the pressure in the gas chamber 30 can be continuously measured. The generated and collected gas collects in the gas chamber 30, and for example, when the gas is collected to a predetermined amount, the on-off valve 48 is opened to eject the gas. At this time, the liquid in the fermentation tank newly enters between the gas collecting hood 32 and the baffle plate 34, and gas generation and collection start again. During that time, the pressure in the gas chamber 30 is continuously measured by the pressure gauge 40.

【0022】また、本実施の形態においては、図3に示
す圧力連続計測用発生ガス捕集器以外にも、例えば、図
5に示すような圧力連続計測用発生ガス捕集器を用いる
こともできる。すなわち、図5に示す圧力連続計測用発
生ガス捕集器を図2の構成に適用することが可能であ
る。図5に示す発生ガス捕集器18bは、底部が開口し
発生ガスの捕集が可能なガス室30を有し、ガス室30
の下部にはガス回収用陣笠状板50が取り付けられてい
る。なお、ガス回収用陣笠状板50の下側に邪魔板を設
置することも可能である。ガス室30内には曝気用サイ
フォン管36が設けられており、サイフォン管36の一
端はガス室30内の上部に開口し、他端はガス室30の
上面に接続された曝気用配管38に連通している。この
発生ガス捕集器18bには、曝気用配管38に上端が接
続されガス回収用陣笠状板50を貫通して陣笠状板50
の下側に下端が位置する吸液管52が設けられている。
図5に示す発生ガス捕集器18bでは、曝気用サイフォ
ン管36からガスが噴出するときに、吸液管52で液が
吸い上げられるので、発酵槽内の攪拌効果が大きい。他
の構成及び作用は図3の場合と同様である。
Further, in this embodiment, in addition to the generated gas collector for continuous pressure measurement shown in FIG. 3, for example, a generated gas collector for continuous pressure measurement as shown in FIG. 5 may be used. it can. That is, the generated gas collector for continuous pressure measurement shown in FIG. 5 can be applied to the configuration of FIG. The generated gas collector 18b shown in FIG. 5 has a gas chamber 30 having an open bottom and capable of collecting generated gas.
A gas collecting slab 50 is attached to the lower part of the fin. In addition, it is also possible to install a baffle plate under the gas-collecting cap-shaped plate 50. An aeration siphon pipe 36 is provided in the gas chamber 30, and one end of the siphon pipe 36 is opened at an upper part in the gas chamber 30, and the other end is connected to an aeration pipe 38 connected to the upper surface of the gas chamber 30. Communicating. The generated gas collector 18b has an upper end connected to the aeration pipe 38 and penetrates through the gas recovery hood 50 to form a hood 50.
A liquid suction tube 52 whose lower end is located below the lower side is provided.
In the generated gas collector 18b shown in FIG. 5, when the gas is blown out from the aeration siphon pipe 36, the liquid is sucked up by the liquid suction pipe 52, so that the stirring effect in the fermenter is large. Other configurations and operations are the same as those in FIG.

【0023】また、本実施の形態においては、図3等に
示す圧力連続計測用発生ガス捕集器以外にも、例えば、
図6、図7に示すような圧力連続計測用発生ガス捕集器
を用いることもできる。すなわち、図6、図7に示す圧
力連続計測用発生ガス捕集器を図2の構成に適用するこ
とが可能である。図6、図7に示す発生ガス捕集器18
cは、底部が開口し発生ガスの捕集が可能なガス室58
を有し、ガス室58には側面部材60を介して一端がガ
ス室内に開口し他端がガス室外側にガス噴出口62とし
て開口したガス噴出用通路64が設けられている。ガス
噴出用通路64の外側には下端が開口し上端がガス噴出
口62に連通する配管に接続された吸液通路66が設け
られている。また、ガス室58内の圧力が連続測定でき
るようにガス室上部に圧力計(圧力センサ)40が設け
られている。
Further, in the present embodiment, in addition to the generated gas collector for continuous pressure measurement shown in FIG.
An evolved gas collector for continuous pressure measurement as shown in FIGS. 6 and 7 can also be used. That is, the generated gas collector for continuous pressure measurement shown in FIGS. 6 and 7 can be applied to the configuration of FIG. Generated gas collector 18 shown in FIGS.
c is a gas chamber 58 having an open bottom and capable of collecting generated gas.
The gas chamber 58 is provided with a gas ejection passage 64 having one end opened into the gas chamber and the other end opened as a gas ejection port 62 outside the gas chamber via a side member 60. Outside the gas ejection passage 64, there is provided a liquid suction passage 66 connected to a pipe having a lower end opening and an upper end communicating with the gas ejection port 62. A pressure gauge (pressure sensor) 40 is provided above the gas chamber so that the pressure in the gas chamber 58 can be continuously measured.

【0024】発酵槽内に設置された発生ガス捕集器18
cは、ガス室58の圧力が測定でき、かつ、自動でガス
捕集と噴出しの繰返しが可能(自動修復可能)な構成で
ある。すなわち、ガス室58内で発生ガスが捕集され、
このガスがガス噴出用通路64の最下部まで捕集される
とガス噴出口62からガスが噴出する。ガス室58内に
は新たな液が入ってガス発生と捕集が再度始まる。その
間のガス室58内の圧力が圧力計40で連続測定され
る。図6、図7に示す発生ガス捕集器18cでは、ガス
室58内からガス噴出用通路64を通ってガス噴出口6
2からガスが噴出するときに、吸液通路66にて液が吸
い上げられるので、発酵槽内の攪拌効果が大きい。他の
構成及び作用は図2、図3及び図5の場合と同様であ
る。
The generated gas collector 18 installed in the fermenter
“c” has a configuration in which the pressure of the gas chamber 58 can be measured, and gas collection and ejection can be automatically repeated (automatic restoration is possible). That is, the generated gas is collected in the gas chamber 58,
When this gas is collected to the lowermost part of the gas ejection passage 64, the gas is ejected from the gas ejection port 62. A new liquid enters the gas chamber 58, and gas generation and collection start again. During that time, the pressure in the gas chamber 58 is continuously measured by the pressure gauge 40. In the generated gas collector 18c shown in FIGS. 6 and 7, the gas ejection port 6 passes through the gas ejection passage 64 from inside the gas chamber 58.
When the gas is blown out from 2, the liquid is sucked up in the liquid suction passage 66, so that the stirring effect in the fermenter is large. Other configurations and operations are the same as those in FIGS. 2, 3, and 5.

【0025】また、本実施の形態で説明したメタン発酵
槽内の発酵状況監視方法及び装置においては、ガス室3
0(又はガス室58)から噴き出すガスの少なくとも一
部をサンプリングして成分分析を行うことで、メタンガ
スの生成状況やその他のガス(硫化水素、二酸化炭素
等)の生成状況等を監視することが可能である。これに
より、メタン発酵槽の発酵状況をより総合的に診断する
ことが可能となる。
In the method and apparatus for monitoring the fermentation status in the methane fermentation tank described in this embodiment, the gas chamber 3
By sampling at least a part of the gas ejected from the gas chamber 0 (or the gas chamber 58) and performing component analysis, it is possible to monitor the generation state of methane gas and the generation state of other gases (hydrogen sulfide, carbon dioxide, etc.). It is possible. This makes it possible to more comprehensively diagnose the fermentation status of the methane fermentation tank.

【0026】図8、図9は、本発明の実施の第2形態に
よるメタン発酵槽内の発酵状況監視方法を実施する装置
の概略構成を示している。本実施の形態は、圧力連続計
測用発生ガス捕集器を発酵槽内に複数個セットしたもの
である。図8に示すように、発酵槽10内には圧力連続
計測用の発生ガス捕集器18が異なる場所に、一例とし
て、3個設置されている。この場合は3種の圧力信号を
同じくデータ変換機20を経て計算機22で解析し、場
所ごとの発酵状況を解析し、槽全体の状況を総合的に診
断する。他の構成及び作用は、実施の第1形態の場合と
同様である。
FIGS. 8 and 9 show a schematic configuration of an apparatus for performing a fermentation status monitoring method in a methane fermentation tank according to a second embodiment of the present invention. In the present embodiment, a plurality of generated gas collectors for continuous pressure measurement are set in a fermenter. As shown in FIG. 8, for example, three generated gas collectors 18 for continuous pressure measurement are installed in the fermenter 10 at different locations. In this case, the three types of pressure signals are also analyzed by the computer 22 via the data converter 20 to analyze the fermentation status of each place, and comprehensively diagnose the status of the entire tank. Other configurations and operations are the same as those in the first embodiment.

【0027】また、図9は、圧力連続計測用発生ガス捕
集器を複数個セットした場合の他の例を示しており、横
長形状で押出し流れを形成する発酵槽を用いた場合であ
る。図9に示すように、発酵槽10aは、一端側に被処
理物投入口12、他端側に発生ガス出口14と液出口1
6が設けられており、槽内の液は押出し流れで被処理物
投入口12側から液出口16側に移動している。54は
攪拌手段、56は駆動源(モータ)である。図9では、
発生ガス捕集器18が、一例として、4個設置されてお
り、この場合は4種の圧力信号を同じくデータ変換機2
0を経て計算機22で解析し、場所ごとの経時的な発酵
状況を解析し、槽全体の状況を総合的に診断する。他の
構成及び作用は、実施の第1形態の場合と同様である。
FIG. 9 shows another example in which a plurality of evolved gas collectors for continuous pressure measurement are set, in which a fermenter for forming an extrusion flow in a horizontally long shape is used. As shown in FIG. 9, the fermenter 10 a has a treatment object inlet 12 at one end and a generated gas outlet 14 and a liquid outlet 1 at the other end.
6 is provided, and the liquid in the tank moves from the workpiece inlet 12 side to the liquid outlet 16 side in an extruding flow. 54 is a stirring means, and 56 is a drive source (motor). In FIG.
As an example, four generated gas collectors 18 are provided, and in this case, four types of pressure signals are similarly output from the data converter 2.
After 0, analysis is performed by the computer 22, the fermentation status over time at each location is analyzed, and the status of the entire tank is comprehensively diagnosed. Other configurations and operations are the same as those in the first embodiment.

【0028】[0028]

【実施例】つぎに、本発明の実施例について説明する。 実施例1 発酵槽内に発生ガスの計測機として図3に示すような圧
力連続計測用発生ガス捕集器を投入し、ガス室内の圧力
を連続測定した結果を図10に示した。ガス室内の圧力
の経時変化は、徐々に圧力が増していき、ガス室内のガ
スが噴出した瞬間に急激な圧力の減少が生じた。圧力連
続計測用発生ガス捕集器はガス捕集と噴出しを自動的に
繰り返す特徴があり、その圧力変化のパターンは上記の
経時変化を繰り返すものとなった。この繰り返しパター
ンで重要なのは圧力の上昇速度であり、ガス室の容量は
一定であるため、ガス発生が活発な状況では上昇速度も
速く、次の圧力変化パターンを繰り返すまでの時間は短
くなる。それを常に解析することで刻々のメタン発酵状
況を知ることができた。
Next, an embodiment of the present invention will be described. Example 1 An evolved gas collector for continuous pressure measurement as shown in FIG. 3 was introduced into a fermenter as an evolved gas measuring device, and the result of continuously measuring the pressure in the gas chamber was shown in FIG. The change with time in the pressure in the gas chamber gradually increased, and a sudden decrease in pressure occurred at the moment when the gas in the gas chamber was ejected. The generated gas collector for continuous pressure measurement has a feature that gas collection and ejection are automatically repeated, and the pattern of the pressure change repeats the above temporal change. What is important in this repetition pattern is the rate of pressure rise, and since the capacity of the gas chamber is constant, the rate of rise is fast in a situation where gas generation is active, and the time until the next pressure change pattern is repeated becomes short. By constantly analyzing it, I was able to know the methane fermentation situation every moment.

【0029】実施例2 各種の条件で圧力変化速度を測定し、その時点のガス発
生量の実測値との関係を図11にまとめた。ガス発生状
況は、圧力連続計測用発生ガス捕集器による圧力変化速
度を解析することにより、きわめて精度良く診断できる
ことが判明した。
Example 2 The pressure change rate was measured under various conditions, and the relationship between the pressure change rate and the actually measured gas generation amount at that time was summarized in FIG. It has been found that the gas generation state can be diagnosed with extremely high accuracy by analyzing the pressure change rate by the generated gas collector for continuous pressure measurement.

【0030】[0030]

【発明の効果】本発明は上記のように構成されているの
で、つぎのような効果を奏する。 (1) 圧力連続計測用発生ガス捕集器を発酵槽内の希
望する場所にセットすることにより、信頼性の高い発生
ガスの捕集部の圧力変化データが連続的に得られ、それ
を解析することにより、発酵槽内のメタンガス発生状況
が時間をかけることなく瞬間的に診断できる。これによ
り、異常発生時にも早期に対応することができるように
なる。 (2) 複数個の圧力連続計測用発生ガス捕集器を発酵
槽内各所にセットすることにより、発酵槽内の各部の発
酵状況を同時に知ることができ、これにより、槽内の局
所的な異常診断が可能となり、大型の発酵槽でも総合的
な発酵状況及び異常の診断が可能となる。 (3) 非常に簡単な構造の発生ガス捕集器を利用し
て、発酵槽内の発酵状況を連続監視することができる。
しかも、検出データが圧力変化であるため、検出センサ
ーの信頼度が高い。
As described above, the present invention has the following effects. (1) By setting the generated gas collector for continuous pressure measurement at the desired location in the fermenter, highly reliable pressure change data of the generated gas collection section can be obtained continuously and analyzed. By doing so, the state of methane gas generation in the fermenter can be instantaneously diagnosed without taking much time. As a result, it is possible to respond promptly even when an abnormality occurs. (2) By setting a plurality of generated gas collectors for continuous pressure measurement at various locations in the fermenter, the fermentation status of each part in the fermenter can be known at the same time. Diagnosis of abnormalities becomes possible, and comprehensive fermentation conditions and abnormalities can be diagnosed even in large fermenters. (3) The state of fermentation in the fermenter can be continuously monitored using a generated gas collector having a very simple structure.
Moreover, since the detection data is a pressure change, the reliability of the detection sensor is high.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施の第1形態によるメタン発酵槽内
の発酵状況監視方法を実施する装置を包含する発酵装置
を示す系統的概略構成立断面説明図である。
FIG. 1 is a systematic schematic configuration elevation sectional view showing a fermentation apparatus including an apparatus for implementing a method for monitoring a fermentation situation in a methane fermentation tank according to a first embodiment of the present invention.

【図2】本発明の実施の第1形態によるメタン発酵槽内
の発酵状況監視方法を実施する装置を示す概略構成立断
面説明図である。
FIG. 2 is a schematic sectional elevational view showing an apparatus for implementing a method for monitoring a fermentation status in a methane fermentation tank according to a first embodiment of the present invention.

【図3】本発明の実施の第1形態における圧力連続計測
用発生ガス捕集器の一例を示す拡大立断面説明図であ
る。
FIG. 3 is an enlarged vertical sectional explanatory view showing an example of a generated gas collector for continuous pressure measurement according to the first embodiment of the present invention.

【図4】本発明の実施の第1形態における圧力連続計測
用発生ガス捕集器の他の例を示す拡大立断面説明図であ
る。
FIG. 4 is an enlarged vertical sectional explanatory view showing another example of the generated gas collector for continuous pressure measurement according to the first embodiment of the present invention.

【図5】本発明の実施の第1形態における圧力連続計測
用発生ガス捕集器の他の例を示す拡大立断面説明図であ
る。
FIG. 5 is an enlarged vertical sectional explanatory view showing another example of the generated gas collector for continuous pressure measurement according to the first embodiment of the present invention.

【図6】本発明の実施の第1形態における圧力連続計測
用発生ガス捕集器のさらに他の例を示す拡大立断面説明
図である。
FIG. 6 is an enlarged vertical sectional explanatory view showing still another example of the generated gas collector for continuous pressure measurement according to the first embodiment of the present invention.

【図7】図6に示す発生ガス捕集器の底面図である。FIG. 7 is a bottom view of the generated gas collector shown in FIG.

【図8】本発明の実施の第2形態によるメタン発酵槽内
の発酵状況監視方法を実施する装置の一例を示す概略構
成立断面説明図である。
FIG. 8 is a schematic vertical sectional view showing an example of an apparatus for performing a method for monitoring a fermentation situation in a methane fermentation tank according to a second embodiment of the present invention.

【図9】本発明の実施の第2形態によるメタン発酵槽内
の発酵状況監視方法を実施する装置の他の例を示す概略
構成立断面説明図である。
FIG. 9 is a schematic vertical sectional view showing another example of an apparatus for performing the method for monitoring a fermentation status in a methane fermentation tank according to the second embodiment of the present invention.

【図10】本発明の実施例における圧力変化測定結果を
示すグラフである。
FIG. 10 is a graph showing pressure change measurement results in the example of the present invention.

【図11】本発明の実施例における圧力変化とガス発生
量の実測値との関係を示すグラフである。
FIG. 11 is a graph showing a relationship between a pressure change and an actually measured gas generation amount in the example of the present invention.

【符号の説明】[Explanation of symbols]

10、10a 発酵槽 12 被処理物投入口 14 発生ガス出口 16 液出口 18、18a、18b、18c 発生ガス捕集器 20 データ変換機 22 計算機 24 記録計 26 ガスタンク 28 沈殿槽 30、58 ガス室 32、50 ガス回収用陣笠状板 34 邪魔板 36 曝気用サイフォン管 38 曝気用配管 40 圧力計(圧力センサ) 42 支持部材 44、62 ガス噴出口 46 ガス配管 48 開閉弁 52 吸液管 54 攪拌手段 56 駆動源(モータ) 60 側面部材 64 ガス噴出用通路 66 吸液通路 10, 10a Fermentation tank 12 Processing object input port 14 Generated gas outlet 16 Liquid outlet 18, 18a, 18b, 18c Generated gas collector 20 Data converter 22 Computer 24 Recorder 26 Gas tank 28 Precipitation tank 30, 58 Gas chamber 32 , 50 Gas-collecting cap plate 34 Baffle plate 36 Aeration siphon tube 38 Aeration pipe 40 Pressure gauge (pressure sensor) 42 Support member 44, 62 Gas outlet 46 Gas pipe 48 Open / close valve 52 Suction pipe 54 Stirrer 56 Drive source (motor) 60 Side member 64 Gas ejection passage 66 Liquid absorption passage

───────────────────────────────────────────────────── フロントページの続き (72)発明者 高垣 一良 兵庫県明石市川崎町1番1号 川崎重工業 株式会社明石工場内 (72)発明者 一色 泰志 神戸市中央区東川崎町1丁目1番3号 川 崎重工業株式会社神戸本社内 Fターム(参考) 4D040 AA23 AA61 4D059 AA01 AA03 AA07 BA17 BA48 BE31 BE49 CB19 EA08 EA20 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Kazura Takagaki 1-1, Kawasaki-cho, Akashi-shi, Hyogo Kawasaki Heavy Industries, Ltd. Inside Akashi Plant (72) Inventor Yasushi Isshiki 1-3-1, Higashi-Kawasaki-cho, Chuo-ku, Kobe-shi No. Kawasaki Heavy Industries, Ltd. Kobe Head Office F-term (reference) 4D040 AA23 AA61 4D059 AA01 AA03 AA07 BA17 BA48 BE31 BE49 CB19 EA08 EA20

Claims (14)

【特許請求の範囲】[Claims] 【請求項1】 メタン発酵槽内で発生したガスを該発酵
槽内に鉛直方向又は略鉛直方向に設けられた底部が開口
しガス回収用部材が下部に接続されたガス室に回収し、
所定量を充満させた後、ガス室内の発生ガスを上部のガ
ス噴出口から吹き出させるとともに、ガス室の下側に形
成されたガス回収用部材と邪魔板又は発酵槽底面との隙
間、及びガス室の上側の配管に上端が接続されガス回収
用部材の下側に下端が位置する吸液管の少なくともいず
れかから液を吸い上げる発生ガス捕集器を用いたメタン
発酵槽内の発酵状況監視方法であって、ガス室内のガス
圧力を連続測定し、その経時変化を測定することにより
槽内の発酵状況を診断することを特徴とするメタン発酵
槽内の発酵状況監視方法。
Claims: 1. A gas generated in a methane fermentation tank is collected in a gas chamber having a bottom provided in a vertical direction or a substantially vertical direction in the fermentation tank and a gas collection member connected to a lower part,
After filling a predetermined amount, the generated gas in the gas chamber is blown out from the upper gas outlet, and the gap between the gas recovery member formed on the lower side of the gas chamber and the baffle plate or the bottom of the fermentation tank, and the gas Method for monitoring fermentation status in a methane fermentation tank using an evolved gas collector that sucks a liquid from at least one of a liquid suction pipe whose upper end is connected to a pipe on the upper side of the chamber and whose lower end is located below the gas recovery member A method for monitoring a fermentation state in a methane fermentation tank, wherein the fermentation state in the methane fermentation tank is diagnosed by continuously measuring the gas pressure in the gas chamber and measuring the change over time.
【請求項2】 メタン発酵槽内で発生したガスを該発酵
槽内に鉛直方向又は略鉛直方向に設けられた底部が開口
しガス回収用部材が下部に接続されたガス室に回収し、
所定量を充満させた後、ガス室内の発生ガスを上部のガ
ス噴出口から吹き出させるとともに、ガス室の下側に形
成されたガス回収用部材と邪魔板又は発酵槽底面との隙
間、及びガス室の上側の配管に上端が接続されガス回収
用部材の下側に下端が位置する吸液管の少なくともいず
れかから液を吸い上げる発生ガス捕集器を用いたメタン
発酵槽内の発酵状況監視方法であって、発生ガス捕集器
を発酵槽内に複数個設置して、それぞれのガス室内のガ
ス圧力を連続測定し、その経時変化を測定することによ
り槽内の発酵状況を診断することを特徴とするメタン発
酵槽内の発酵状況監視方法。
2. A gas generated in the methane fermentation tank is collected in a gas chamber in which a bottom provided vertically or substantially vertically in the fermentation tank is open and a gas collection member is connected to a lower part,
After filling a predetermined amount, the generated gas in the gas chamber is blown out from the upper gas outlet, and the gap between the gas recovery member formed on the lower side of the gas chamber and the baffle plate or the bottom of the fermentation tank, and the gas Method for monitoring fermentation status in a methane fermentation tank using an evolved gas collector that sucks a liquid from at least one of a liquid suction pipe whose upper end is connected to a pipe on the upper side of the chamber and whose lower end is located below the gas recovery member Therefore, a plurality of evolved gas collectors are installed in the fermentation tank, and the gas pressure in each gas chamber is continuously measured, and the change over time is measured to diagnose the fermentation state in the tank. Characteristic method of monitoring fermentation status in methane fermentation tank.
【請求項3】 ガス室内に両端部の位置より下方となる
部分を有する管を設け、該管の一端をガス室内に開口さ
せ、他端をガス室上部のガス噴出口に連通させる構造を
保有する請求項1又は2記載のメタン発酵槽内の発酵状
況監視方法。
3. A structure is provided in which a pipe having a portion below the positions of both ends is provided in a gas chamber, one end of the pipe is opened in the gas chamber, and the other end is communicated with a gas outlet above the gas chamber. 3. The method for monitoring fermentation status in a methane fermentation tank according to claim 1 or 2.
【請求項4】 メタン発酵槽内で発生したガスを該発酵
槽内に鉛直方向又は略鉛直方向に設けられた底部が開口
し側面部材を介してガス噴出用通路が形成されたガス室
に回収し、所定量を充満させた後、ガス室内の発生ガス
をガス噴出用通路を経由してガス噴出口から吹き出させ
るとともに、ガス噴出用通路の外側に形成された下端が
開口し上端がガス噴出口に連通する配管に接続された吸
液通路から液を吸い上げる発生ガス捕集器を用いたメタ
ン発酵槽内の発酵状況監視方法であって、ガス室内のガ
ス圧力を連続測定し、その経時変化を測定することによ
り槽内の発酵状況を診断することを特徴とするメタン発
酵槽内の発酵状況監視方法。
4. The gas generated in the methane fermentation tank is recovered in a gas chamber having a vertically or substantially vertically provided bottom opening in the fermentation tank and a gas ejection passage formed through a side member. After the gas is filled with a predetermined amount, the generated gas in the gas chamber is blown out from the gas ejection port via the gas ejection passage, and the lower end formed outside the gas ejection passage is opened and the upper end is opened. This is a method for monitoring the fermentation status in a methane fermentation tank using a generated gas collector that sucks up liquid from a liquid suction passage connected to a pipe connected to an outlet, and continuously measures the gas pressure in a gas chamber and changes over time. A fermentation state monitoring method in a methane fermentation tank, wherein the fermentation state in the methane fermentation tank is diagnosed by measuring the fermentation state in the methane fermentation tank.
【請求項5】 メタン発酵槽内で発生したガスを該発酵
槽内に鉛直方向又は略鉛直方向に設けられた底部が開口
し側面部材を介してガス噴出用通路が形成されたガス室
に回収し、所定量を充満させた後、ガス室内の発生ガス
をガス噴出用通路を経由してガス噴出口から吹き出させ
るとともに、ガス噴出用通路の外側に形成された下端が
開口し上端がガス噴出口に連通する配管に接続された吸
液通路から液を吸い上げる発生ガス捕集器を用いたメタ
ン発酵槽内の発酵状況監視方法であって、発生ガス捕集
器を発酵槽内に複数個設置して、それぞれのガス室内の
ガス圧力を連続測定し、その経時変化を測定することに
より槽内の発酵状況を診断することを特徴とするメタン
発酵槽内の発酵状況監視方法。
5. The gas generated in the methane fermentation tank is recovered in a gas chamber having a bottom provided vertically or substantially vertically in the fermentation tank and having a gas ejection passage formed through a side member. After the gas is filled with a predetermined amount, the generated gas in the gas chamber is blown out from the gas ejection port via the gas ejection passage, and the lower end formed outside the gas ejection passage is opened and the upper end is opened. This is a method for monitoring the fermentation status in a methane fermentation tank using a generated gas collector that sucks up liquid from a liquid suction passage connected to a pipe that communicates with an outlet.A plurality of generated gas collectors are installed in the fermentation tank. A method for monitoring the fermentation status in the methane fermentation tank, wherein the fermentation status in the methane fermentation tank is diagnosed by continuously measuring the gas pressure in each gas chamber and measuring the change over time.
【請求項6】 ガス室内のガス圧力の上昇速度の経時変
化と、ガス室のガス噴出しが発生してから、次のガス噴
出しが発生するまでの間隔時間を計測することにより、
発酵槽内の発酵状況の場所的な相違及び/又は時間的な
相違を診断する請求項1〜5のいずれかに記載のメタン
発酵槽内の発酵状況監視方法。
6. A time-dependent change in a rising speed of a gas pressure in a gas chamber and an interval time from the occurrence of gas ejection in the gas chamber to the occurrence of the next gas ejection are measured.
The method for monitoring fermentation status in a methane fermentation tank according to any one of claims 1 to 5, wherein a difference in location and / or time in the fermentation status in the fermentation tank is diagnosed.
【請求項7】 ガス室のガス噴出口から噴き出すガスの
少なくとも一部をサンプリングして分析することにより
発酵状況を診断する請求項1〜6のいずれかに記載のメ
タン発酵槽内の発酵状況監視方法。
7. The fermentation status monitoring in the methane fermentation tank according to claim 1, wherein the fermentation status is diagnosed by sampling and analyzing at least a part of the gas ejected from the gas outlet of the gas chamber. Method.
【請求項8】 メタン発酵槽内の液中に位置するように
鉛直方向又は略鉛直方向に設けられた底部が開口したガ
ス室と、このガス室の下部に接続されたガス回収用の陣
笠状部材と、この陣笠状部材との間に隙間を形成するよ
うに陣笠状部材の下側に略水平に設置された邪魔板と、
前記ガス室の上面部材に設けられたガス噴出口とを包含
してなる発生ガス捕集器を用いたメタン発酵槽内の発酵
状況監視装置であって、ガス室内に圧力計測手段が設け
られ、この圧力計測手段に接続されたデータ変換手段及
びデータ解析手段により、連続測定されたガス圧力の経
時変化から発酵槽内の発酵状況を診断するようにしたこ
とを特徴とするメタン発酵槽内の発酵状況監視装置。
8. A gas chamber which is provided in a vertical or substantially vertical direction so as to be located in a liquid in a methane fermentation tank, and has a bottom opening, and a gas recovery hood connected to a lower portion of the gas chamber. A member and a baffle plate installed substantially horizontally below the chin-shape member so as to form a gap between the chin-shape member,
A fermentation status monitoring device in a methane fermentation tank using a generated gas collector including a gas ejection port provided on an upper surface member of the gas chamber, wherein a pressure measuring unit is provided in the gas chamber, The fermentation condition in the methane fermentation tank is characterized by diagnosing the fermentation state in the fermentation tank from the time-dependent change in the gas pressure measured continuously by the data conversion means and the data analysis means connected to the pressure measurement means. Condition monitoring device.
【請求項9】 メタン発酵槽内の液中に位置するように
鉛直方向又は略鉛直方向に設けられた底部が開口したガ
ス室と、このガス室の下部に接続されたガス回収用の陣
笠状部材と、この陣笠状部材との間に隙間を形成するよ
うに陣笠状部材の下側に略水平に設置された邪魔板と、
前記ガス室の上面部材に設けられたガス噴出口とを包含
してなる発生ガス捕集器を用いたメタン発酵槽内の発酵
状況監視装置であって、発生ガス捕集器が発酵槽内に複
数個設置されており、それぞれのガス室内に圧力計測手
段が設けられ、これらの圧力計測手段に接続されたデー
タ変換手段及びデータ解析手段により、連続測定された
ガス圧力の経時変化から発酵槽内の発酵状況を診断する
ようにしたことを特徴とするメタン発酵槽内の発酵状況
監視装置。
9. A gas chamber provided in a vertical or substantially vertical direction so as to be located in a liquid in a methane fermentation tank and having an open bottom, and a gas recovery fin-shape connected to a lower portion of the gas chamber. A member and a baffle plate installed substantially horizontally below the chin-shape member so as to form a gap between the chin-shape member,
A fermentation status monitoring device in a methane fermentation tank using a generated gas collector including a gas outlet provided in an upper member of the gas chamber, wherein the generated gas collector is provided in the fermentation tank. A plurality of pressure sensors are provided, and pressure measuring means are provided in each gas chamber.The data converting means and the data analyzing means connected to these pressure measuring means detect the time-dependent change in the gas pressure continuously measured in the fermenter. A fermentation status monitoring device in a methane fermentation tank characterized in that the fermentation status of the methane fermentation tank is diagnosed.
【請求項10】 ガス室内に両端部の位置より下方とな
る部分を有する管が設けられ、該管の一端がガス室内に
開口しており、他端がガス室上部のガス噴出口に連通し
ている請求項8又は9記載のメタン発酵槽内の発酵状況
監視装置。
10. A gas chamber having a tube having a portion below the position of both ends is provided in the gas chamber, one end of the tube is opened in the gas chamber, and the other end communicates with a gas outlet above the gas chamber. The fermentation status monitoring device in the methane fermentation tank according to claim 8 or 9, wherein
【請求項11】 発生ガス捕集器に、ガス室の上側のガ
ス噴出口と連通する配管に上端が接続されガス回収用の
陣笠状部材を貫通して該部材の下側に下端が位置する少
なくとも1本の吸液管を設けた請求項8、9又は10記
載のメタン発酵槽内の発酵状況監視装置。
11. The generated gas collector has an upper end connected to a pipe communicating with a gas jet port above the gas chamber, and penetrates a gas-collecting member, and has a lower end positioned below the member. The fermentation status monitoring device in a methane fermentation tank according to claim 8, 9 or 10, wherein at least one liquid suction pipe is provided.
【請求項12】 ガス室内に両端部の位置より下方とな
る部分を有する管を設ける代わりに、ガス室のガス噴出
口と連通する配管に開閉弁を設けた請求項10記載のメ
タン発酵槽内の発酵状況監視装置。
12. The inside of the methane fermentation tank according to claim 10, wherein an on-off valve is provided in a pipe communicating with a gas ejection port of the gas chamber, instead of providing a pipe having a portion below both ends in the gas chamber. Fermentation status monitoring device.
【請求項13】 メタン発酵槽内の液中に位置するよう
に鉛直方向又は略鉛直方向に設けられた底部が開口した
ガス室と、このガス室に側面部材を介して設けられた一
端がガス室内に開口し他端がガス室外側にガス噴出口と
して開口したガス噴出用通路と、このガス噴出用通路の
外側に形成された下端が開口し上端がガス噴出口に連通
する配管に接続された吸液通路とを包含してなる発生ガ
ス捕集器を用いたメタン発酵槽内の発酵状況監視装置で
あって、ガス室内に圧力計測手段が設けられ、この圧力
計測手段に接続されたデータ変換手段及びデータ解析手
段により、連続測定されたガス圧力の経時変化から発酵
槽内の発酵状況を診断するようにしたことを特徴とする
メタン発酵槽内の発酵状況監視装置。
13. A gas chamber which is provided in a vertical or substantially vertical direction so as to be located in a liquid in a methane fermentation tank and has an open bottom, and one end provided in the gas chamber via a side member is provided with a gas. A gas ejection passage that opens into the chamber and has the other end opened as a gas ejection port outside the gas chamber, and a lower end formed outside the gas ejection passage is connected to a pipe that opens at the lower end and communicates with the gas ejection port at the upper end. A fermentation status monitoring device in a methane fermentation tank using a generated gas collector including a liquid absorption passage, wherein pressure measurement means is provided in the gas chamber, and data connected to the pressure measurement means. A fermentation state monitoring device in a methane fermentation tank characterized in that the conversion means and the data analysis means diagnose the fermentation state in the fermentation tank based on the time-dependent change in the continuously measured gas pressure.
【請求項14】 メタン発酵槽内の液中に位置するよう
に鉛直方向又は略鉛直方向に設けられた底部が開口した
ガス室と、このガス室に側面部材を介して設けられた一
端がガス室内に開口し他端がガス室外側にガス噴出口と
して開口したガス噴出用通路と、このガス噴出用通路の
外側に形成された下端が開口し上端がガス噴出口に連通
する配管に接続された吸液通路とを包含してなる発生ガ
ス捕集器を用いたメタン発酵槽内の発酵状況監視装置で
あって、発生ガス捕集器が発酵槽内に複数個設置されて
おり、それぞれのガス室内に圧力計測手段が設けられ、
これらの圧力計測手段に接続されたデータ変換手段及び
データ解析手段により、連続測定されたガス圧力の経時
変化から発酵槽内の発酵状況を診断するようにしたこと
を特徴とするメタン発酵槽内の発酵状況監視装置。
14. A gas chamber having a bottom opening and provided in a vertical or substantially vertical direction so as to be located in a liquid in a methane fermentation tank, and one end provided through a side member in the gas chamber. A gas ejection passage that opens into the chamber and has the other end opened as a gas ejection port outside the gas chamber, and a lower end formed outside the gas ejection passage is connected to a pipe that opens at the lower end and communicates with the gas ejection port at the upper end. A fermentation status monitoring device in a methane fermentation tank using a generated gas collector comprising a liquid absorbing passage, wherein a plurality of generated gas collectors are installed in the fermentation tank, Pressure measuring means is provided in the gas chamber,
By the data conversion means and the data analysis means connected to these pressure measurement means, in the methane fermentation tank characterized in that the fermentation state in the fermentation tank was diagnosed from the temporal change of the continuously measured gas pressure. Fermentation status monitoring device.
JP2000381473A 2000-12-15 2000-12-15 Method and apparatus for monitoring fermentation status in methane fermentation tank Expired - Lifetime JP3430149B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000381473A JP3430149B2 (en) 2000-12-15 2000-12-15 Method and apparatus for monitoring fermentation status in methane fermentation tank

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000381473A JP3430149B2 (en) 2000-12-15 2000-12-15 Method and apparatus for monitoring fermentation status in methane fermentation tank

Publications (2)

Publication Number Publication Date
JP2002176967A true JP2002176967A (en) 2002-06-25
JP3430149B2 JP3430149B2 (en) 2003-07-28

Family

ID=18849460

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000381473A Expired - Lifetime JP3430149B2 (en) 2000-12-15 2000-12-15 Method and apparatus for monitoring fermentation status in methane fermentation tank

Country Status (1)

Country Link
JP (1) JP3430149B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107076714A (en) * 2014-10-22 2017-08-18 朗泽科技新西兰有限公司 Gas test unit and method
KR101850881B1 (en) 2016-11-02 2018-04-27 주식회사 다운 Feed mixing equipment

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107076714A (en) * 2014-10-22 2017-08-18 朗泽科技新西兰有限公司 Gas test unit and method
CN107076714B (en) * 2014-10-22 2019-12-10 朗泽科技新西兰有限公司 Gas testing unit and method
US11814666B2 (en) 2014-10-22 2023-11-14 Lanzatech Nz, Inc. Gas testing unit and method
KR101850881B1 (en) 2016-11-02 2018-04-27 주식회사 다운 Feed mixing equipment

Also Published As

Publication number Publication date
JP3430149B2 (en) 2003-07-28

Similar Documents

Publication Publication Date Title
CN108414387A (en) A kind of biochemical methane potentiality self-operated measuring unit and method
CN202402268U (en) Device for diagnosing cavitation faults of water pump based on acoustic emission detection
CN208155639U (en) To can polluted-water be used for quickly detecting and sampling tool
CN114361534B (en) Method and apparatus for monitoring internal state of electrochemical device with externally supplied reactant
KR101920922B1 (en) Apparatus for diagnosing pneumatic control valve and method thereof
JP2002176967A (en) Method and apparatus for observing fermentation state in methane fermentation tank
CN218766964U (en) Multi-point-position multi-element full-automatic sampling, sample feeding, sampling and detecting system
CN101236255B (en) Underground fluid composite monitoring method
CN115541528A (en) Infrared spectrum-based online monitoring device and method for dissolved gas in transformer oil
US20240069499A1 (en) Device assembly and method for controlling an integrated continuous pharmaceutical or biopharmaceutical manufacturing process
CN103424557A (en) Biochemical analyzer
CN208421568U (en) A kind of automatic Regulating System of biomass carbonated purification system
CN203670182U (en) Device for detecting unsteady flow of small-flow working condition of centrifugal pump based on acoustic emission technology
CN208224003U (en) A kind of biochemical methane potentiality self-operated measuring unit
CN216513815U (en) Anaerobic fermentation device with early warning system
CN112816271A (en) Device and method for collecting combustible gas in steam
KR970011862B1 (en) Insulating oil checking apparatus
CN115148222B (en) Industrial fluid detection method and system
CN216955338U (en) Gas dehydration sampling mechanism and dynamic detection system thereof
CN114509395B (en) Online monitoring device and method for gas in transformer oil
JP2575663B2 (en) Online moisture analyzer
CN213209619U (en) Surface water sampling device
CN219625128U (en) Sampling device for liquid on upper layer of liquid-solid phase reaction kettle
CN216309962U (en) COD on-line automatic detector for production waste discharge monitoring
CN204330551U (en) Metal erosion speed detector

Legal Events

Date Code Title Description
TRDD Decision of grant or rejection written
R150 Certificate of patent or registration of utility model

Ref document number: 3430149

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080516

Year of fee payment: 5

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313111

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080516

Year of fee payment: 5

R360 Written notification for declining of transfer of rights

Free format text: JAPANESE INTERMEDIATE CODE: R360

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080516

Year of fee payment: 5

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090516

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090516

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100516

Year of fee payment: 7

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110516

Year of fee payment: 8

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313111

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110516

Year of fee payment: 8

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110516

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120516

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120516

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130516

Year of fee payment: 10

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130516

Year of fee payment: 10

EXPY Cancellation because of completion of term