JP2002169256A - Silver halide color photographic sensitive material - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a silver halide color photographic sensitive material excellent in color reproducibility, in particular a color reversal film. SOLUTION: In the silver halide color photographic sensitive material having at least one blue-sensitive emulsion layer, at least one green-sensitive emulsion layer and at least one red-sensitive emulsion layer on the transparent base, at least one of the emulsion layers contains a magenta coupler having a specified structure and at least one layer containing a UV absorbing compound having λmax in the range of 360-400 nm is situated at the side nearer a support than the emulsion layers.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention relates to a silver halide color photographic light-sensitive material, and more particularly to a silver halide color photographic light-sensitive material having excellent image storability.

[0002]

2. Description of the Related Art In the field of silver halide color photographic light-sensitive materials utilizing a coupling reaction between an aromatic primary amine color developing agent and a coupler, as a magenta coupler which provides a preferable magenta dye with little unnecessary side absorption, Zorotriazole couplers are conventionally known.

[0003] Recently, pyrazolotriazole couplers have been widely used in silver halide color papers, and have contributed to improving the performance thereof. On the other hand, in the field of silver halide color reversal films, which similarly form positive images and are provided for direct appreciation, color reversal films using pyrazolotriazole couplers have been commercialized, although their practical use has been considered for a long time. Not realized.

One problem with using pyrazolotriazole couplers in color reversal films is that the relationship between granularity and sensitivity is worsened. The application of pyrazolotriazole magenta couplers to color papers has been mainly studied since the early days, and therefore, 2-equivalent couplers having a leaving group which is eliminated as an anion in a coupling reaction have been mainly studied. Two-equivalent coupler is silver 1
Although the amount of dye formed per mole (or image density) is large, there is an advantage that silver can be reduced. However, in a color reversal film, the sensitivity is lowered. The relationship between graininess and sensitivity is one of the most important qualities in a color reversal film in which the obtained image is a print document or a print document.
The use of equivalent pyrazolotriazole couplers has been difficult in this regard.

On the other hand, when the coupling position is hydrogen
When using an equivalent pyrazolotriazole, since the coupler is chemically reactive and unstable, it is a serious problem that an undesired yellow colored substance is generated over time or light irradiation after the treatment. . As a result of the study by the present inventors, it has been found that yellowing is deteriorated when a treatment is carried out, and then the mixture is stored in a dark place under a high humidity condition and then irradiated with light.

The inventors of the present invention have been diligently studying the solution of this problem for a long time, but the technique for solving the problem particularly in the case of irradiating light with high illuminance has not been sufficient.

[0007]

SUMMARY OF THE INVENTION An object of the present invention is to provide a technique for reducing the yellow color after treatment, which is a problem of a 4-equivalent pyrazolotriazole magenta coupler. Another object of the present invention is to provide a silver halide color photographic light-sensitive material excellent in color reproducibility, especially a color reversal film by introducing the technique.

[0008]

The object of the present invention has been attained by the present invention having the following constitution. (1) In a silver halide color photographic material having at least one blue-sensitive emulsion layer, at least one green-sensitive emulsion layer, and at least one red-sensitive emulsion layer on a transparent support, at least one photosensitive emulsion layer has the following general formula: (MC-I), at least one of the magenta couplers represented by (MC-I), and having a λmax of 360 nm or more on the side closer to the support than the photosensitive emulsion layer.
A silver halide color photographic light-sensitive material comprising at least one layer containing an ultraviolet absorbing compound having a thickness of not more than 00 nm.

[0009]

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[0010] In the formula, _{R 1} represents a hydrogen atom or a _substituent, G 1, _{G 2} represents either a carbon atom, the other is a nitrogen atom, _{R 2} represents a _{substituent, G} 1, G Substitute for the one that is carbon atom of ₂ . R ₁ or _{R 2} may further have a substituent, and may form a multimer of formula via _R 1, _{R 2} (MC-I), _{R 1}
Or it may be bonded to the polymer chain via R _2.

(2) At least one each on a transparent support
In a silver halide color photographic light-sensitive material having a blue-sensitive emulsion layer, a green-sensitive emulsion layer and a red-sensitive emulsion layer, at least one of the light-sensitive emulsion layers is a magenta coupler represented by the following general formula (MC-I). And at least λm on the surface of the support opposite to the photosensitive emulsion layer.
A silver halide color photographic light-sensitive material comprising at least one layer containing an ultraviolet absorbing compound having ax of 360 nm or more and 400 nm or less.

[0012]

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In the formula, R ₁ represents a hydrogen atom or a substituent, _one of G ₁ and G ₂ represents a carbon atom and the other represents a nitrogen atom, R ₂ represents a substituent, G ₁ , G Substitute for the one that is carbon atom of ₂ . R ₁ or _{R 2} may further have a substituent, and may form a multimer of formula via _R 1, _{R 2} (MC-I), _{R 1}
Or it may be bonded to the polymer chain via R _2.

[0014]

DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail.

First, a 4-equivalent magenta coupler represented by the general formula (MC-I) (hereinafter, also referred to as “coupler of the present invention”) will be described.

[0016]

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In the formula, R ₁ represents a hydrogen atom or a substituent, _one of G ₁ and G ₂ represents a carbon atom and the other represents a nitrogen atom, R ₂ represents a substituent, G ₁ , G 2 Substitute for the one that is carbon atom of ₂ . R ₁ or _{R 2} may further have a substituent, and may form a multimer of formula via _R 1, _{R 2} (MC-I), _{R 1}
Or it may be bonded to the polymer chain via R _2.

Next, the general formula (MC-I) will be described in detail. In the formula, R ₁ represents a hydrogen atom or a substituent, and examples of the substituent include an alkyl group (including a cycloalkyl group and a bicycloalkyl group), an alkenyl group (including a cycloalkenyl group and a bicycloalkenyl group), an alkynyl group,
Aryl group, heterocyclic group, cyano group, hydroxyl group,
Nitro group, carboxyl group, alkoxy group, aryloxy group, silyloxy group, heterocyclic oxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group, aryloxycarbonyloxy group, amino group (including anilino group), acylamino group , Aminocarbonylamino group, alkoxycarbonylamino group, aryloxycarbonylamino group, sulfamoylamino group, alkyl and arylsulfonylamino group, mercapto group, alkylthio group, arylthio group, heterocyclic thio group, sulfamoyl group, sulfo group, Alkyl and aryl sulfinyl groups, alkyl and aryl sulfonyl groups, acyl groups, aryloxycarbonyl groups, alkoxycarbonyl groups, carbamoyl groups, aryl and heterocyclic azo groups, imides , A phosphino group, a phosphinyl group,
Examples include a phosphinyloxy group, a phosphinylamino group, and a silyl group.

More specifically, an alkyl group [linear, branched,
Represents a cyclic substituted or unsubstituted alkyl group. An alkyl group (preferably an alkyl group having 1 to 30 carbon atoms such as methyl, ethyl, n-propyl, isopropyl, t-
Butyl, n-octyl, eicosyl, 2-chloroethyl, 2-cyanoethyl, 2-ethylhexyl), cycloalkyl group (preferably a substituted or unsubstituted cycloalkyl group having 3 to 30 carbon atoms, for example, cyclohexyl, cyclopentyl, -N-dodecylcyclohexyl), a bicycloalkyl group (preferably a substituted or unsubstituted bicycloalkyl group having 5 to 30 carbon atoms, that is, a monovalent group obtained by removing one hydrogen atom from a bicycloalkane having 5 to 30 carbon atoms) For example, bicyclo [1,2,2] heptan-2-yl, bicyclo [2,
2,2] octan-3-yl)], an alkenyl group [which represents a linear, branched, or cyclic substituted or unsubstituted alkenyl group. An alkenyl group (preferably a substituted or unsubstituted alkenyl group having 2 to 30 carbon atoms, for example, vinyl, allyl, prenyl, geranyl, oleyl), a cycloalkenyl group (preferably a substituted or unsubstituted 3 to 30 carbon atoms); Cycloalkenyl group, that is, 3 to 30 carbon atoms
Is a monovalent group obtained by removing one hydrogen atom from cycloalkene. For example, 2-cyclopenten-1-yl, 2-
Cyclohexen-1-yl), bicycloalkenyl group (substituted or unsubstituted bicycloalkenyl group, preferably substituted or unsubstituted bicycloalkenyl group having 5 to 30 carbon atoms, that is, hydrogen atom of bicycloalkene having one double bond Is a monovalent group from which one is removed, for example, bicyclo [2,2,1] hept-2-ene-1-
Yl, bicyclo [2,2,2] oct-2-en-4-
Yl)], an alkynyl group (preferably having 2 to 3 carbon atoms)
0 substituted or unsubstituted alkynyl group such as ethynyl, propargyl, trimethylsilylethynyl), aryl group (preferably substituted or unsubstituted aryl group having 6 to 30 carbon atoms such as phenyl, p-tolyl, naphthyl, m- Chlorophenyl, o-hexadecanoylaminophenyl), a heterocyclic group (preferably a monovalent group obtained by removing one hydrogen atom from a 5- or 6-membered substituted or unsubstituted aromatic or non-aromatic heterocyclic compound) And more preferably a 5- or 6-membered aromatic heterocyclic group having 3 to 30 carbon atoms, for example, 2-furyl,
2-thienyl, 2-pyrimidinyl, 2-benzothiazolyl), cyano group, hydroxyl group, nitro group, carboxyl group, alkoxy group (preferably having 1 to 30 carbon atoms)
A substituted or unsubstituted alkoxy group such as methoxy, ethoxy, isopropoxy, t-butoxy, n-octyloxy, 2-methoxyethoxy) and an aryloxy group (preferably substituted or unsubstituted having 6 to 30 carbon atoms) Aryloxy group such as phenoxy, 2-methylphenoxy, 4-t-butylphenoxy, 3-nitrophenoxy, 2-tetradecanoylaminophenoxy), silyloxy group (preferably having 3 to 20 carbon atoms)
Silyloxy group, for example, trimethylsilyloxy,
t-butyldimethylsilyloxy), a heterocyclic oxy group (preferably a substituted or unsubstituted heterocyclic oxy group having 2 to 30 carbon atoms, for example, 1-phenyltetrazol-5-oxy, 2-tetrahydropyranyloxy), An acyloxy group (preferably a formyloxy group, having 2 carbon atoms)
To 30 substituted or unsubstituted alkylcarbonyloxy groups, substituted or unsubstituted arylcarbonyloxy groups having 6 to 30 carbon atoms, for example, formyloxy, acetyloxy, pivaloyloxy, stearoyloxy, benzoyloxy, p-methoxyphenylcarbonyl Oxy), a carbamoyloxy group (preferably a substituted or unsubstituted carbamoyloxy group having 1 to 30 carbon atoms, for example, N, N-dimethylcarbamoyloxy,
N, N-diethylcarbamoyloxy, morpholinocarbonyloxy, N, N-di-n-octylaminocarbonyloxy, Nn-octylcarbamoyloxy),
An alkoxycarbonyloxy group (preferably having 2 carbon atoms)
To 30 substituted or unsubstituted alkoxycarbonyloxy groups such as methoxycarbonyloxy, ethoxycarbonyloxy, t-butoxycarbonyloxy, n-
Octylcarbonyloxy), an aryloxycarbonyloxy group (preferably a substituted or unsubstituted aryloxycarbonyloxy group having 7 to 30 carbon atoms, for example, phenoxycarbonyloxy, p-methoxyphenoxycarbonyloxy, pn-hexadecyl Oxyphenoxycarbonyloxy), amino group (including anilino group) (preferably, amino group, substituted or unsubstituted alkylamino group having 1 to 30 carbon atoms, 6 to 3 carbon atoms)
0 substituted or unsubstituted anilino group, for example, amino, methylamino, dimethylamino, anilino, N-methyl-anilino, diphenylamino), acylamino group (preferably formylamino group, substituted or unsubstituted 1 to 30 carbon atoms) An unsubstituted alkylcarbonylamino group, a substituted or unsubstituted arylcarbonylamino group having 6 to 30 carbon atoms, such as formylamino, acetylamino, pivaloylamino, lauroylamino, benzoylamino, 3,4,5-tri-n- Octyloxyphenylcarbonylamino), aminocarbonylamino group (preferably substituted or unsubstituted aminocarbonylamino group having 1 to 30 carbon atoms, for example, carbamoylamino, N, N-dimethylaminocarbonylamino, N, N
-Diethylaminocarbonylamino, morpholinocarbonylamino), an alkoxycarbonylamino group (preferably a substituted or unsubstituted alkoxycarbonylamino group having 2 to 30 carbon atoms, for example, methoxycarbonylamino, ethoxycarbonylamino, t-butoxycarbonylamino, n- Octadecyloxycarbonylamino,
N-methyl-methoxycarbonylamino), an aryloxycarbonylamino group (preferably having 7 to 3 carbon atoms)
0 substituted or unsubstituted aryloxycarbonylamino group, for example, phenoxycarbonylamino, p-chlorophenoxycarbonylamino, mn-octyloxyphenoxycarbonylamino), sulfamoylamino group (preferably having 0 to 30 substituted or unsubstituted sulfamoylamino groups, for example, sulfamoylamino, N, N-dimethylaminosulfonylamino,
Nn-octylaminosulfonylamino), alkyl and arylsulfonylamino groups (preferably having 1 carbon atom)
To 30 substituted or unsubstituted alkylsulfonylamino groups, substituted or unsubstituted arylsulfonylamino groups having 6 to 30 carbon atoms, for example, methylsulfonylamino, butylsulfonylamino, phenylsulfonylamino, 2,3,5-tri Chlorophenylsulfonylamino, p-methylphenylsulfonylamino), mercapto group, alkylthio group (preferably having 1 to 30 carbon atoms)
A substituted or unsubstituted alkylthio group, for example, methylthio, ethylthio, n-hexadecylthio), an arylthio group (preferably a substituted or unsubstituted arylthio group having 6 to 30 carbon atoms, for example, phenylthio, p-chlorophenylthio, m-methoxy) Phenylthio), a heterocyclic thio group (preferably a substituted or unsubstituted heterocyclic thio group having 3 to 30 carbon atoms, for example, 2-benzothiazolylthio, 1-phenyl-tetrazol-5-ylthio), a sulfamoyl group ( Preferably 0 to 30 carbon atoms
A substituted or unsubstituted sulfamoyl group such as N
-Ethylsulfamoyl, N- (3-dodecyloxypropyl) sulfamoyl, N, N-dimethylsulfamoyl, N-acetylsulfamoyl, N-benzoylsulfamoyl, N- (N'-phenylcarbamoyl) sulfamoyl ), A sulfo group, an alkyl and arylsulfinyl group (preferably a substituted or unsubstituted alkylsulfinyl group having 1 to 30 carbon atoms, a substituted or unsubstituted arylsulfinyl group having 6 to 30 carbon atoms, for example, methylsulfinyl, ethylsulfinyl, Phenylsulfinyl, p-methylphenylsulfinyl), alkyl and arylsulfonyl groups (preferably substituted or unsubstituted alkylsulfonyl groups having 1 to 30 carbon atoms, substituted or unsubstituted arylsulfonyl groups having 6 to 30 carbon atoms, for example, methylsulfonyl group) Nyl, ethylsulfonyl, phenylsulfonyl, p-methylphenylsulfonyl), acyl group (preferably formyl group, substituted or unsubstituted alkylcarbonyl group having 2 to 30 carbon atoms, 7 to 3 carbon atoms)
0 substituted or unsubstituted arylcarbonyl group, for example, acetyl, pivaloyl, 2-chloroacetyl, stearoyl, benzoyl, pn-octyloxyphenylcarbonyl), aryloxycarbonyl group (preferably having 7 to 30 carbon atoms) A substituted or unsubstituted aryloxycarbonyl group, for example, phenoxycarbonyl, o-chlorophenoxycarbonyl, m-nitrophenoxycarbonyl, pt-butylphenoxycarbonyl), an alkoxycarbonyl group (preferably having 2 carbon atoms)
To 30 substituted or unsubstituted alkoxycarbonyl groups, for example, methoxycarbonyl, ethoxycarbonyl, t-butoxycarbonyl, n-octadecyloxycarbonyl), carbamoyl group (preferably having 1 carbon atom)
To 30 substituted or unsubstituted carbamoyl groups, for example, carbamoyl, N-methylcarbamoyl, N, N-
Dimethylcarbamoyl, N, N-di-n-octylcarbamoyl, N- (methylsulfonyl) carbamoyl),
Aryl and heterocyclic azo groups (preferably substituted or unsubstituted arylazo groups having 6 to 30 carbon atoms,
To 30 substituted or unsubstituted heterocyclic azo groups such as phenylazo, p-chlorophenylazo, 5-ethylthio-1,3,4-thiadiazol-2-ylazo), an imide group (preferably N-succinimide, N
-Phthalimide), a phosphino group (preferably a substituted or unsubstituted phosphino group having 2 to 30 carbon atoms, for example, dimethylphosphino, diphenylphosphino, methylphenoxyphosphino), a phosphinyl group (preferably having 2 to 30 carbon atoms) 30 substituted or unsubstituted phosphinyl groups such as phosphinyl, dioctyloxyphosphinyl, diethoxyphosphinyl) and phosphinyloxy groups (preferably substituted or unsubstituted phosphinyl having 2 to 30 carbon atoms) An oxy group such as diphenoxyphosphinyloxy, dioctyloxyphosphinyloxy), a phosphinylamino group (preferably having 2 carbon atoms);
To 30 substituted or unsubstituted phosphinylamino groups such as dimethoxyphosphinylamino, dimethylaminophosphinylamino), silyl group (preferably
A substituted or unsubstituted silyl group having 3 to 30 carbon atoms, for example, trimethylsilyl, t-butyldimethylsilyl,
Phenyldimethylsilyl).

Among the above substituents, those having a hydrogen atom may be removed and further substituted with the above group. Examples of such a substituent include an alkylcarbonylaminosulfonyl group, an arylcarbonylaminosulfonyl group, an alkylsulfonylaminocarbonyl group, and an arylsulfonylaminocarbonyl group. Examples include methylsulfonylaminocarbonyl, p-methylphenylsulfonylaminocarbonyl, acetylaminosulfonyl, and benzoylaminosulfonyl groups.

R ₁ is an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, an acylamino group, an arylthio group, an alkylthio group, an aminocarbonylamino group, an alkoxycarbonylamino group, a carbamoyloxy group, a heterocyclic group. Thio groups are preferred, and these may have a substituent.

R ₁ is more preferably an alkyl group, an aryl group, an alkoxy group, an aryloxy group, or an amino group (including an anilino group), and still more preferably a secondary or tertiary group having 3 to 15 carbon atoms. It is an alkyl group, and a tertiary alkyl group having 4 to 10 carbon atoms is most preferable. G ₁ ,
One of G ₂ is a nitrogen atom, and the other is a carbon atom, and the carbon atom is substituted by R ₂ represented by the general formula (MC-I). The substituent represented by R ₂ is
Those described in sections R ₁ can be given as specific examples.

[0023] Preferably the R _2, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an aminocarbonylamino group, an alkoxycarbonylamino group include acylamino group, further R ₂ having a carbon number of 6 It is a group having a total carbon number of 6 or more and 70 or less containing an alkyl group or an aryl group of 30 or less as a partial structure, and preferably imparts immobility to the coupler of the general formula (MC-I). Or R ₂ is bonded to the polymer chain via an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an aminocarbonylamino group, an alkoxycarbonylamino group, an acylamino group, or a combination thereof. It is also preferable that the group of formula (MC-I) is a group and imparts immobility to the coupler of the general formula (MC-I).

Preferred among the couplers represented by the general formula (MC-I) are those in which R ₁ is a secondary or tertiary alkyl group or aryl group, and R ₂ is a substituted alkyl group or a substituted alkyl group. An aryl group, wherein R ₂ is substituted with an alkoxy group, an aryloxy group, an acylamino group, an aminocarbonylamino group, an alkylthio group, an arylthio group, an alkoxycarbonylamino group, an aryloxycarbonylamino group, an alkyl group and an arylsulfonylamino group; Those having a group selected from a group, a carbamoyl group, a sulfamoyl group, a sulfonyl group, an alkoxycarbonyl group, an acyloxy group, a carbamoyloxy group, a sulfinyl group, a phosphonyl group, an acyl group, and a halogen atom are preferred. More preferable examples of the general formula (MC-I) include compounds in which R ₂ is a substituent represented by the following general formulas (BL-1) to (BL-2).

[0025]

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[0026]

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In the general formula (BL-1), R ₃ , R ₄ , R
₅ , R ₆ and R ₇ each represent a hydrogen atom or a substituent, and at least one of them represents a substituent having a substituted or unsubstituted alkyl group having a total carbon number of 4 to 70 and having a partial structure, A substituent containing a substituted or unsubstituted aryl group having a partial structure of 6 or more and 70 or less.

Hereinafter, the group represented by formula (BL-1) will be described in detail. R ₃ , R ₄ , R ₅ , R ₆ , and R ₇ each independently represent a hydrogen atom or a substituent, and when it is a substituent, examples of the substituent include those described in the section of R ₂ . At least one of R ₃ , R ₄ , R ₅ , R ₆ , and R ₇ has a total number of carbon atoms of 4 to 70, a substituent containing a substituted or unsubstituted alkyl group as a partial structure, or a total number of carbon atoms of 6 or more. It is a substituent containing a substituted or unsubstituted aryl group as a partial structure of 70 or less, preferably a substituted or unsubstituted alkyl group having a total carbon number of 4 or more (6 or more in the case of including an aryl group) or 70 or less. An alkoxy group containing an aryl group as a partial structure, an aryloxy group,
Acylamino group, aminocarbonylamino group, carbamoyl group, alkoxycarbonylamino group, sulfonyl group, alkyl and arylsulfonylamino group, sulfamoyl group, sulfamoylamino group, alkoxycarbonyl group and alkyl group, and aryl group. Among them, the total carbon number is 4 or more (6 or more in case of including an aryl group)
The following alkoxy groups, acylamino groups, alkyl and arylsulfonylamino groups containing a substituted or unsubstituted alkyl or aryl group as a partial structure are preferred.

In particular, when R ₃ or two of R ₄ and R ₆ have the above total number of carbon atoms of 4 or more (6 or more when containing an aryl group)
It is preferably a substituent containing a substituted or unsubstituted alkyl or aryl group of 0 or less as a partial structure. It is wherein G ₃ in the general formula (BL-2) represents a substituted or unsubstituted methylene group, a represents an integer from 1 3, G ₄
Is _{-O -, - SO 2 -,} - NR 8 CO -, - NR 8 SO
₂ - represents, R ₈ is a hydrogen atom or an alkyl group, an aryl group, R ₉ includes at least one phenyl group, the number of 6 or more 70 or less total carbon, a substituted or unsubstituted alkyl group or an aryl group Represents a substituent contained as a partial structure. When R ₉ has a substituent, the substituent may be R ₉
Those mentioned in the section ₂ can be mentioned. a plurality of G ₃ are may all be different even for the same when a is 2 or more.

G₃A substituted or unsubstituted methylene represented by
Is a simple methylene or one or more and no more than 20 carbon atoms
An alkyl group or a substituted or unsubstituted phenyl group
It is preferably a substituted methylene group. is a 1
Represents a natural number of 1 to 3, preferably 1 or 2. Better
Preferably (G₃The group represented by a) is -CH₂-, -C
(CH₃) H-, -C (CH₃)₂-, -C₂H₄−,
-C (CH₃) H-CH₂-, -C (CH ₃)₂-CH
₂-, -C (CH₃)₂-C (CH₃) H-, -C (C
H₃) H-C (CH₃) H-, -C (CH₃)₂-C
(CH₃)₂-, -C (i-C₃H₇) H-, -C (i
-C₃H₇) H-CH₂-.

G ₄ is preferably -NR ₈ CO-,
—NR ₈ SO ₂ —, and R ₈ is preferably a hydrogen atom. R ₉ is preferably a substituted or unsubstituted alkyl or aryl group containing at least one phenyl group and having 10 to 70 carbon atoms in total.

Magenta represented by the general formula (MC-I)
Of the pullers, G₁Is a nitrogen atom and G ₂Is a carbon atom
In that case, R₁Is a tertiary alkyl group, and R₂Is the general formula
A group represented by (BL-1),₄, R₆Is total carbon
Substituted by a substituted or unsubstituted alkyl group of 4 or more
Substituted or unsubstituted ants having 6 or more carbon atoms
Acylamino group substituted by a thiol group, sulfonamido
Group, ureido group, alkoxycarbonylamino group,
Ruphonyl group, carbamoyl group, sulfamoyl group, sulf
Selected from famoylamino group and alkoxycarbonyl group
Preferably, the group is

When G ₁ is a carbon atom and G ₂ is a nitrogen atom among the compounds represented by the general formula (MC-I), R ₁
Is preferably a tertiary alkyl group, and R ₂ is preferably a group represented by the general formula (BL-1) or (BL-2), and particularly preferably, R ₂ is a group represented by the general formula (BL-2) Or a group represented by the general formula (BL-1), wherein R ₃ and R ₇ are an alkyl group having 1 to 6 carbon atoms,
Preferably, at least one of R ₄ , R ₅ , and R ₆ is a group containing a substituted or unsubstituted alkyl group or aryl group having a total carbon number of 6 or more and 70 or less as a partial structure.

In the present invention, G₁Is a carbon atom and G₂Is nitrogen
Atom, R₁Is a tertiary alkyl group, and R₂Is the general formula (BL
-2), and in the general formula (BL-2), R
₉Has a partial structure of an alkyl group having 6 to 50 carbon atoms.
Having at least one substituent as a substituent
The group in which a is 1 or 2 is preferred.
To R₉Is -OH, -SO₂NH₂, -SO₂NH
R₁₀, -NHSO₂R₁₀, -SO₂NHCO
R₁₀, -CONHSO₂R₁₀, -COOH, -CO
NH ₂Is a group having as a partial structure a group selected from
Are particularly preferred.

R ₁₀ is a substituted or unsubstituted alkyl group,
Represents an aryl group, and when R ₁₀ is an aryl group,
It is preferably a phenyl group, and the phenyl group is preferably substituted with at least one electron-withdrawing group.
Preferred electron withdrawing groups include a halogen atom, a cyano group, an alkyl group substituted with at least one halogen atom, an aryl group, an acyl group, a carbamoyl group, an alkyl or aryloxycarbonyl group substituted with at least one halogen atom. , A sulfonyl group, an alkyl or arylaminosulfonyl group. Also R
_{When 10} is an alkyl group, it is preferably a substituted or unsubstituted linear or branched alkyl group having 1 to 50 carbon atoms (more preferably 1 to 30 carbon atoms).
Hereinafter, specific examples of the compound of the general formula (MC-I) are shown, but the present invention is not limited to these specific examples.

[0036]

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[0037]

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[0038]

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[0039]

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[0040]

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[0041]

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[0042]

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[0043]

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[0044]

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The coupler of the general formula (MC-I) of the present invention can be synthesized by a known method. For example, U.S. Pat. Nos. 4,540,654, 4,705,863, 5,451,501, JP-A-61-65245, JP-A-62-209457, JP-A-62-249155, and 6
3-41851, Tokuhei 7-122744, 5-
No. 105682, No. 7-13309, No. 7-8225
No. 2 or U.S. Pat. Nos. 3,725,067 and 4,7
77, 121, JP-A-2-201442, 2-1.
No. 01077, No. 3-125143, No. 4-2422
No. 49.

The coupler of the present invention can be introduced into a light-sensitive material by various known dispersion methods, dissolved in a high-boiling organic solvent (optionally using a low-boiling solvent in combination), and emulsified and dispersed in an aqueous gelatin solution to form a silver halide. An oil-in-water dispersion method to be added to the emulsion is preferred. Examples of the high boiling point solvent used in the oil-in-water dispersion method are described in U.S. Pat. No. 2,322,027.

Examples of high-boiling solvents that can be used in the above-described oil-in-water dispersion method include phthalic acid esters (for example, dibutyl phthalate, dioctyl phthalate, dicyclohexyl phthalate, bis (2-ethylhexyl)).
Phthalate, decyl phthalate, bis (2,4-di-te
rt-amylphenyl) isophthalate, bis (1,1-
Diethyl propyl) phthalate), esters of phosphoric or phosphonic acids (eg, diphenyl phosphate,
Triphenyl phosphate, tricresyl phosphate, 2-ethylhexyl diphenyl phosphate, dioctyl butyl phosphate, tricyclohexyl phosphate, tri-2-ethylhexyl phosphate, tridodecyl phosphate, bis (2-ethylhexyl) phenyl phosphate), benzoic acid esters (for example, ,
2-ethylhexyl benzoate, 2,4-dichlorobenzoate, dodecyl benzoate, 2-ethylhexyl-p-hydroxybenzoate, amides (for example, N, N-diethyldodecaneamide, N, N-diethyllauramide, N, N, N, N-tetrakis (2-
Ethylhexyl) isophthalamide, alcohols or phenols (eg, isostearyl alcohol, 2,4-di-tert-amylphenol), aliphatic esters (eg, dibutoxyethyl succinate, bis (2-succinate) Ethylhexyl), tetradecanoic acid 2
-Hexyldecyl, tributyl citrate, diethyl azelate, isostearyl lactate, trioctyl tosylate), aniline derivatives (for example, N, N-dibutyl-2-butoxy-5-tert-octyl aniline), chlorinated paraffins ( Paraffins having a chlorine content of 10% to 80%), trimesic esters (eg, tributyl trimesate), dodecylbenzene, diisopropylnaphthalene, phenols (eg, 2,4-di-tert-)
Amylphenol, 4-dodecyloxyphenol, 4
-Dodecyloxycarbonylphenol, 4- (4-dodecyloxyphenylsulfonyl) phenol), carboxylic acids (eg, 2- (2,4-di-tert-amylphenoxybutyric acid, 2-ethoxyoctanedecanoic acid), alkyl phosphoric acids (For example, bis (2-ethylhexyl) phosphoric acid, diphenylphosphoric acid, etc.) In addition to the above high boiling point solvents, it is also preferable to use, for example, compounds described in JP-A-6-258803 as high boiling point solvents. .

Of these, phosphoric esters, amides, and aliphatic esters, or a combination of these with an aniline derivative is preferred. The ratio of the amount of the high-boiling organic solvent used in combination with the coupler of the present invention is from 0 to 1.
0 is preferred, more preferably 0 to 0.5,
Particularly, 0 to 0.2 is preferable. As the auxiliary solvent, an organic solvent having a boiling point of 30 ° C. or more and about 160 ° C. or less (eg, ethyl acetate, butyl acetate, ethyl propionate, methyl ethyl ketone, cyclohexanone, 2-ethoxyethyl acetate, dimethylformamide) may be used in combination.
It is also preferable that the coupler of the present invention coexist with an organic solvent-soluble polymer. Such dispersion is described in PCT International Publication No. WO88 / 00723, or JP-A-63-44658 and JP-A-63-250648.
Nos. 64-537, JP-A-1-179944, 2-230240, and 7-104449.

The light-sensitive material of the present invention contains at least one coupler represented by formula (MC-I) in at least one light-sensitive emulsion layer. The content of the coupler of the present invention in the light-sensitive material is preferably 0.01 to 0.01 / m ^2.
g to 10 g, more preferably 0.1 g to ² g per m ² .
The amount is suitably 1 × 10 ⁻³ mol to 1 mol, preferably 2 × 10 ⁻³ mol to 3 × 10 ⁻¹ mol, per mol of silver halide in the same photosensitive emulsion layer. When the photosensitive layer has a unit constitution composed of two or more photosensitive emulsion layers having different sensitivities, the content of the coupler of the present invention per 1 mol of silver halide is 2 × 10 ⁻³ mol or less for the low-sensitivity layer.
2 × 10 ⁻¹ mol is preferred, and 3 × 1 except for the low-sensitivity layer.
It is preferably from 0 to ² mol to 3 × 10 ^-1 mol.

The present invention contains a coupler represented by formula (MC-I), but other couplers may be used in combination.
However, the higher the contribution of the coloring dye of the coupler of the present invention to the total concentration of the coloring matter which forms substantially the same color, the more preferable results are obtained. Specifically, it is preferable to use an amount that occupies preferably 30% or more, more preferably 50% or more, and still more preferably 70% or more, of the color density. Next, the ultraviolet absorbing compound used in the present invention will be described.

The light-sensitive material of the present invention has a λmax of 360 n.
m to 400 nm or less ultraviolet absorbing compound (hereinafter, referred to as
At least one UV-absorbing compound of the present invention). The ultraviolet absorbing compound of the present invention has a λmax
May be any one as long as it is 360 nm or more and 400 nm or less, but is preferably the following general formula (UV-
This is represented by I).

[0052]

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In the formula, R _A and R _B each independently represent a substituted or unsubstituted alkyl group or aryl group, and R _C , R _D ,
R _E each independently represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group or an aryl group, R _F represents a substituted or unsubstituted alkyl group, an aryl group or an electron-withdrawing group, and EWG represents an electron-withdrawing group. Represents a functional group. R _A and R _B ,
R _B and R _C , R _C and R _D , R _D and R _E , R _E and R _F are
It may combine with each other to form a saturated or unsaturated ring.

Hereinafter, general formula (UV-I) will be described in detail. First, EWG will be described. In the present specification, the electron-withdrawing group represented by EWG is an electron-withdrawing group having a Hammett's substituent constant σp value (hereinafter simply referred to as σp value) of 0.20 or more and 1.0 or less. Preferably, σp
An electron-withdrawing group having a value of from 0.30 to 0.8. Hammett's rule was introduced in 1935 by LP H in order to discuss quantitatively the effect of substituents on the reaction or equilibrium of benzene derivatives.
A rule of thumb proposed by ammett, which is widely accepted today. The substituent constants determined by Hammett's rule include σp values and σm values, and these values are described in many general books.
ean, "Lange's Handbook of Chemistry", 12th edition,
1979 (Mc Graw-Hill) and "Chemical Area Special Edition", 1
22, No. 96-103, 1979 (Nankodo), Chem
ical Reviews, 91, 165-195, 1991
Familiar with the year. The present invention does not mean that the literature-known values described in these publications are limited to only certain substituents, and that the values are not included in the range when measured based on the Hammett rule even if the literature is unknown. It is of course included as far as possible.

Specific examples of the electron-withdrawing group having a σp value of 0.20 or more and 1.0 or less include an acyl group, an acyloxy group, a carbamoyl group, an alkyloxycarbonyl group, an aryloxycarbonyl group, a cyano group, and a nitro group. A, dialkylphosphono group, diarylphosphono group, diarylphosphinyl group, alkylsulfinyl group, arylsulfinyl group, alkylsulfonyl group, arylsulfonyl group, sulfonyloxy group, acylthio group, sulfamoyl group, thiocyanate group, thiocarbonyl group, Alkyl group substituted with at least two or more halogen atoms, alkoxy group substituted with at least two or more halogen atoms, aryloxy group substituted with at least two or more halogen atoms, at least two or more halogen atoms Replaced by Alkylamino group, at least two an alkylthio group substituted with a halogen atom, .sigma.p
Examples include an aryl group, a heterocyclic group, a chlorine atom, a bromine atom, an azo group, or a selenocyanate group substituted with another electron-withdrawing group of 0.20 or more. Among these substituents, the group capable of further having a substituent may further have the substituent described above.

Of these, an acyl group, a carbamoyl group, an alkyloxycarbonyl group, an aryloxycarbonyl group, a cyano group, a nitro group, an alkylsulfonyl group, an arylsulfonyl group, a sulfonyloxy group, and a sulfamoyl group are preferred. Preferred are a carbamoyl group, an alkyloxycarbonyl group, an aryloxycarbonyl group, a cyano group, an alkylsulfonyl group, an arylsulfonyl group, a sulfonyloxy group, and a sulfamoyl group.

Next, R_A, R_BWill be described.
R_A, R_BIs each independently a substituted or unsubstituted alkyl
A group or an aryl group;_AAnd R_BAre connected to each other
It may form a saturated or unsaturated ring. R_A, R
_BIs an example of the above-mentioned R of the general formula (MC-I)₁In the example
Examples of the alkyl group and the aryl group include those mentioned above.
But preferably alkyl having 1 to 20 carbon atoms
Or a substituted or unsubstituted phenyl group. Also
R_AAnd R _BIs bonded to form a nitrogen atom represented by N in the formula
Including, for example, piperidine ring, pyrrolidine ring, morpholine
It is also preferred to form a ring such as a ring.

Next, R _C , R _D , and _RE will be described.
_{R C,} R D, R _E are each independently a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, an aryl group, also _{R B} and _R C, _{R C} and _R D, _{R D} and _R E, _RE and _RF may combine with each other to form a saturated or unsaturated ring. Examples of the alkyl group and the aryl group include:
Examples of the alkyl group and the aryl group in the examples of R ₁ in the general formula (MC-I) include the alkyl groups having 1 to 20 carbon atoms, or a substituted or unsubstituted phenyl group. Group or a hydrogen atom. Especially R
_{C, R} D, is preferably a hydrogen atom _{R E.}

[0059] Next, the _{R F} is described. R _F is a substituted or unsubstituted alkyl group, an aryl group or an electron withdrawing group, examples respectively, those mentioned R _A to R _E, examples of EWG earlier when an electron withdrawing group What was mentioned as is mentioned. Of these, electron-withdrawing groups are preferable, and acyl groups, carbamoyl groups, alkyloxycarbonyl groups, aryloxycarbonyl groups, cyano groups, alkylsulfonyl groups, arylsulfonyl groups, sulfonyloxy groups, and sulfamoyl groups are particularly preferable. Hereinafter, specific examples of the ultraviolet absorbing compound represented by the general formula (UV-I) are shown, but the ultraviolet absorbing agent of the present invention is not limited to these specific examples.

[0060]

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[0061]

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[0062]

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When the ultraviolet absorbing compound of the present invention is added to a light-sensitive material, it can be introduced into the light-sensitive material by various known dispersion methods. In particular, an oil-in-water dispersion method of dissolving in a high-boiling organic solvent (and optionally using a low-boiling solvent in combination), emulsifying and dispersing the mixture in an aqueous gelatin solution, and adding it is preferable. The amount of the high boiling organic solvent used in combination with the ultraviolet absorbing compound of the present invention is 0% by mass.
Is preferably from 10 to 10, and more preferably from 0 to 5. Further, as the kind of the high boiling point organic solvent, phosphate esters and aliphatic esters are preferable.

The present invention relates to a photosensitive emulsion layer containing the 4-equivalent magenta coupler of the present invention (hereinafter, also referred to as "the photosensitive emulsion layer of the present invention") and a support, that is, the photosensitive emulsion of the present invention. The layer of the present invention absorbs ultraviolet light on a layer located closer to the support than the layer, or a layer coated on the side opposite to the photosensitive emulsion layer of the present invention (hereinafter also referred to as "back surface") with the support interposed therebetween. Although it is constituted by adding a compound, a preferable added layer is a layer not containing an image forming coupler. More preferably, a non-photosensitive layer located closer to the support than all the photosensitive emulsion layers, or a photosensitive emulsion layer of the present invention,
A non-light-sensitive layer between the silver halide emulsion layer having a different color sensitivity which is located closer to the support and a layer opposite to the light-sensitive emulsion layer of the present invention across the support. Added. In particular, it is preferably added to a non-light-sensitive layer between the light-sensitive emulsion layer of the present invention and the other color-sensitive silver halide emulsion layer located closer to the support than the light-sensitive emulsion layer.

The amount of the ultraviolet absorbing compound of the present invention added on the side closer to the support than the light-sensitive emulsion layer of the present invention containing a 4-equivalent magenta coupler is preferably 5.0 mg per 1 m ² of the light-sensitive material. Not less than 5.0 g,
More preferably 50 mg or more and 1.0 g or less,
The most preferred range is 0 mg to 500 mg. When the ultraviolet absorbing compound of the present invention is added to the back surface side, the amount is preferably 50 mg or more and 5.0 g or less per m ² of the photosensitive material,
100 mg or more and 3.0 g or less are more preferable.

The ultraviolet absorbing compound of the present invention is preferably used in combination with another ultraviolet absorbing compound. Examples of the ultraviolet absorbing compound that can be preferably used in combination include U-1 to U-4 and U-6 described in Example 1 in the present specification. Of course, it may be used in combination with an ultraviolet absorbing compound other than those listed here.

In the present invention, a hydroquinone compound substituted with at least one alkyl group is preferably used in the same layer as the magenta coupler of the present invention, and particularly excellent in combination with the ultraviolet absorbing compound of the present invention. Express the effect. The hydroquinone compound is substituted by at least one alkyl group, and may further have a substituent such as a halogen atom. Particularly preferred is hydroquinone having one alkyl group as a substituent or substituted with two alkyl groups. Preferred hydroquinone compounds to be used in combination include the following.

[0068]

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When the hydroquinone compound is added, the preferable addition amount is 0.0 to 1 mol of the coupler of the present invention.
It is preferably from 01 mol to 0.5 mol, more preferably from 0.005 mol to 0.1 mol. In the present invention, in addition to these hydroquinones, additives such as an anti-fading agent may be contained. These additives are described in, for example, JP-A-61-50136, JP-A-62-250448, and JP-A-63-250448.
163852, 63-163851, JP-A-4
163453, 4-330440, 4-27
No. 3242, No. 4-346345, No. 5-27617
No. 6-75349, No. 6-130602, No. 6
No. 138614, No. 2-208865, No. 2-21
No. 7845, No. 3-25438, No. 4-42153
Nos. 6-43612, 5-241295 and 6
-175316, 6-208211, 7-13
No. 311, No. 7-126264, No. 6-130601
No. etc.

In the present invention, bisphenols cross-linked by a substituted or unsubstituted methylene group at the ortho position of each hydroxyl group, a derivative in which at least one of the hydroxyl groups is an ester or ether group, a dialkoxybenzene derivative, an aniline It is preferable to use a derivative and a hydroxylamine derivative in combination. Examples of preferred additives that can be used in the present invention include the following compounds. Of course, additives other than those mentioned here may be used in combination.

[0072]

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[0073]

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[0074]

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The light-sensitive material of the present invention may have at least one blue-sensitive silver halide emulsion layer, one green-sensitive silver halide emulsion layer, and one red-sensitive silver halide emulsion layer on a support. It is preferable to coat the support in this order from the far side, but the order may be different from this. In the present invention, it is preferable to coat a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, and a blue-sensitive silver halide emulsion layer in this order from the side close to the support,
Each color-sensitive layer preferably has a unit structure including two or more photosensitive emulsion layers having different sensitivities. In particular, each of the color-sensitive layers includes a low-sensitivity layer, a medium-sensitivity layer, and a high-sensitivity layer from the side close to the support. It is preferable to have a three-layer unit structure composed of one photosensitive emulsion layer. These are described in JP-B-49-15495, JP-A-59-202264, and the like.

One of the preferred embodiments of the present invention is as follows. An undercoat layer / antihalation layer / first intermediate layer / red-sensitive emulsion layer unit (low-sensitive red-sensitive layer / Medium red sensitive layer / high sensitive red sensitive layer 3
Layer) / second intermediate layer / green-sensitive emulsion layer unit (consisting of three layers of low-sensitive green-sensitive layer / intermediate green-sensitive layer / high-sensitive green-sensitive layer from the side close to the support) / third intermediate layer / Yellow filter layer / blue-sensitive emulsion layer unit (consisting of 3 layers of low-sensitive blue-sensitive layer / intermediate blue-sensitive layer / high-sensitive blue-sensitive layer from the side close to the support) / first protective layer / second protective layer The photosensitive elements to which the respective layers are applied in this order can be mentioned.

Each of the first, second, and third intermediate layers may be a single layer, or may have a configuration of two or more layers. The first intermediate layer is further divided into two or more layers, and the layer directly adjacent to the red-sensitive layer preferably contains yellow colloidal silver. Similarly,
The second intermediate layer also has two or more layers, and the layer directly adjacent to the green-sensitive layer preferably contains yellow colloidal silver.
It is also preferable to further include a fourth intermediate layer between the yellow filter layer and the blue-sensitive emulsion layer unit. The intermediate layer is described in JP-A-61-43748 and JP-A-59-1134.
No. 38, No. 59-113440, No. 61-20037
And DIR compounds as described in JP-A-62-10038 and JP-A-61-20038, and may contain a color mixing inhibitor as usually used.

Further, the protective layer is composed of three of the first to third protective layers.
It is also preferable to adopt a layer structure. Two or three protective layers
In the case of a layer, the second protective layer has a sphere equivalent average particle size of 0.10.
It preferably contains fine grain silver halide having a particle size of not more than μm. The silver halide is preferably silver bromide or silver iodobromide. Since the object of the present invention is to solve the problem when viewing with transmitted light, as an embodiment of the present invention, it is important that the lowest density portion be a white background. The effect appears. As for the density of the white background portion, the density of all of yellow, magenta and cyan is preferably 0.3 or less, more preferably 0.2 or less.

The most typical embodiment of the present invention is a color reversal film photographic material having a white background density of 0.2 or less. The silver halide color photographic light-sensitive material of the present invention may have a light-sensitive emulsion layer other than those listed here. In particular, it is preferable from the viewpoint of color reproducibility to provide a photosensitive emulsion layer spectrally sensitized in the cyan light region and to provide a red-sensitive emulsion layer with an overlay effect. The layer imparting such a multilayer effect may be blue-sensitive, green-sensitive or red-sensitive. U.S. Pat. Nos. 4,663,271 and 4,705,744
No. 4,707,436, JP-A-62-1604.
No. 48, 63-89850, B
A donor layer having a multilayer effect having a spectral sensitivity distribution different from that of the main photosensitive layer such as L, GL, RL or the like can be arranged adjacent to or close to the main photosensitive layer.

In the present invention, the image forming coupler is preferably used by adding it to a photosensitive emulsion layer which senses light having a complementary color to the color hue of the coupler. That is, the yellow coupler is added to the blue-sensitive emulsion layer, the magenta coupler is added to the green-sensitive emulsion layer, and the cyan coupler is added to the red-sensitive emulsion layer. Further, for the purpose of improving shadow depiction, such a coupler having no complementary color may be mixed and used (for example, a cyan coupler is used in combination with a green sensitive emulsion layer).

Preferred examples of the image forming coupler which can be used in combination with the coupler of the present invention in the light-sensitive material of the present invention include the following.

Yellow coupler; EP502, 424A
EP513, a coupler represented by the formula (I) or (II):
No. 496A, couplers represented by formulas (1) and (2) (for example, Y-28 (page 18)); couplers represented by formula (I) of claim 1 of EP568,037A;
No. 6,576, column 1, lines 45 to 55, general formula (I)
A coupler represented by the general formula (I) in paragraph 0008 of JP-A-4-274425;
8,381 A1 on page 40 of claim 1 (e.g. D-35); EP447,969 A1 on page 4 coupler of formula (Y) (e.g. Y-1, Y-5)
4); US Pat. No. 4,476,219, column 7 36-5.
Couplers represented by formulas (II) to (IV) on line 8;

Magenta coupler; JP-A-3-39737
(For example, L-57, L-68, L-7)
7); couplers described in EP 456, 257A (for example, A
EP-63, A-4-73, A-4-75); EP48
6,965A (for example, M-4, M-6,
M-7) Coupler described in EP 571,959A (for example, M-45) Coupler described in JP-A-5-204106 (for example, M-1); Coupler described in JP-A-4-362263 (for example, M-22) cyan coupler; Couplers described in JP-A-4-208443 (for example, CX-1,3,4,5,11,12,1)
4, 15); couplers described in JP-A-4-43345 (for example, C-7, 10, 34, 35 and (I-1);
(I-17)): a coupler represented by formula (Ia) or (Ib) of claim 1 of JP-A-6-67385; a coupler represented by formula (PC-1) of JP-A-11-119393. Couplers (for example, CB-1, CB-4, CB-
5, CB-9, CB-34, CB-44, CB-49,
CB-51); a coupler represented by formula (NC-1) described in JP-A-11-119393 (for example, CC-1,
CC-17).

These couplers can be introduced into a light-sensitive material by various known dispersion methods similar to the couplers of the present invention described above. In the light-sensitive material of the present invention, a competing compound (a compound which reacts with an oxidized color developing agent in competition with an image forming coupler and does not form a dye image) may be used in combination. Examples of the competitor compound include reducing compounds such as hydroquinones, catechols, hydrazines, and sulfonamidophenols, or compounds that couple to an oxidized color developing agent but do not substantially form a color image (eg, German Patent 1). 155,675, British Patent 861,138.
Nos. 3,876,428 and 3,912,5
A colorless coupler as disclosed in No. 13 or a coupler as disclosed in JP-A-6-83002 in which a formed dye flows out during the processing step.

In the light-sensitive material of the present invention, a non-color-forming intermediate layer may be provided in a photosensitive unit having the same color sensitivity, and the intermediate layer contains a compound which can be selected as the above-mentioned competitor compound. Preferably. The photosensitive material of the present invention can be fixed by reacting with a formaldehyde gas described in U.S. Pat. Nos. 4,411,987 and 4,435,503 to prevent deterioration of photographic performance due to formaldehyde gas. It is preferable that the compound is contained in the light-sensitive material. In the method for producing a photographic light-sensitive material of the present invention, a photographic useful substance is usually added to a photographic coating solution, that is, a hydrophilic colloid solution. The various techniques and inorganic and organic materials which can be used for the silver halide photographic emulsion of the present invention and the silver halide photographic light-sensitive material using the same are generally described in Research Disclosure No. 308119 (1989) and the same. 37
038 (1995) and 40145 (1997) can be used. In addition to this, more specifically, for example, for the techniques and inorganic / organic materials that can be used for color photographic light-sensitive materials to which the silver halide photographic emulsion of the present invention can be applied, see EP 436,9A.
38A2 at the following location and in the patents cited below.

Item The relevant point 1) Layer structure Page 146, line 34 to page 147, line 2) Can be used in combination Page 147, line 26 to page 148, line 12 Silver halide emulsion 3) Page 137, line 35 to page 146, line 33; 14th yellow coupler, page 9, lines 21 to 23 4) Page 149, line 24 to line 28, which can be used in combination; European Patent No. 42 Magenta coupler 1,453A1, page 3, line 5 to page 25, line 55 5) Can be used together, page 149, lines 29 to 33; EP 432 Cyan coupler, page 3 of 804A2 Line 28 to page 40, line 2 6) Polymer coupler, page 149, lines 34 to 38; EP 113,334A2, page 113, line 39 to page 123, line 7 7) Colored coupler Page 53, line 42 to 13 Page 34, line 149, page 39 to line 45 8) Can be used together Page 7, line 1 to page 53, line 41, page 149, 46 Functional coupler line to page 150, line 3 EP 435,334A 2, page 3 line 1 to page 29 line 50 9) Preservatives and fungicides page 150 line 25 to line 28 10) Formalin page 149 line 15 to Line 17 Scavenger 11) P. 153, Lines 38 to 47 which can be used in combination; EP 421, Other Additives, page 75, Line 21 to Page 84, Line 56 of 453A1, page 27, 40 Lines to page 37, line 40 12) Dispersion method Page 150, lines 4 to 24 13) Support: page 150, lines 32 to 34 14) Film thickness and film properties Page 150, line 35 To 49th line 15) Color development step, page 150, line 50 to page 151, line 47 16) Desilvering step, 15th Page 48 line to page 152 line 53 17) Automatic developing machine Page 152 line 54 to page 153 line 2 18) Washing and stabilizing step Page 153 line 3 to line 37 Photographic photosensitive of the present invention After the imagewise exposure, the material is usually processed with an alkali developing solution containing a developing agent, and after this color development, the color photographic light-sensitive material is processed with a processing solution containing a bleaching agent and having a bleaching ability. A forming method is applied.

[0087]

EXAMPLES Hereinafter, the present invention will be described specifically with reference to Examples, but the present invention is not limited thereto.

Example 1 Preparation of Sample 101 (i) Preparation of Triacetyl Cellulose Film Triacetyl cellulose was added to dichloromethane / methanol = 92/8 (mass ratio) by ordinary solution casting method. Dissolution (13% by mass), prepared by adding the plasticizer triphenyl phosphate and biphenyl diphenyl phosphate at a mass ratio of 2: 1, and adding 14% to triacetyl cellulose by the band method. did. The thickness of the support after drying was 97 μm.

(Ii) Contents of Undercoat Layer The following undercoat was applied to both surfaces of the triacetyl cellulose film. The number represents the mass contained per 1.0 liter of the undercoating liquid (hereinafter referred to as “L”. Further, “milliliter” is referred to as “mL”).

Before applying the undercoat, both surfaces were subjected to corona discharge treatment.

Gelatin 10.0 g Salicylic acid 0.5 g Glycerin 4.0 g Acetone 700 mL Methanol 200 mL Dichloromethane 80 mL Formaldehyde 0.1 mg Add water 1.0 L (iii) Coating back layer One side of the undercoated support is as follows. The indicated back layer was applied.

First layer Binder: Acid-treated gelatin (isoelectric point 9.0) 1.00 g Polymer latex P-2 (average particle size 0.1 μm) 0.13 g Polymer latex: P-3 (average particle size 0.2 μm) 0.23 g High boiling organic solvent Oil-2 0.030 g Surfactant W-3 0.010 g Surfactant W-6 3.0 mg.

Second layer Binder: acid-treated gelatin (isoelectric point: 9.0) 3.10 g Polymer latex: P-3 (average particle size: 0.2 μm) 0.11 g High boiling organic solvent Oil-2 0.030 g Surfactant W- 3 0.010 g Surfactant W-6 3.0 mg Dye D-2 0.10 g Dye D-10 0.12 g Potassium sulfate 0.25 g Calcium chloride 0.5 mg Sodium hydroxide 0.03 g.

Third layer Binder: acid-treated gelatin (isoelectric point 9.0) 3.30 g Surfactant W-3 0.020 g potassium sulfate 0.30 g sodium hydroxide 0.03 g Fourth layer binder: lime-treated gelatin (isoelectric point 5.4) 1.15 g 1: 9 copolymer of methacrylic acid and methyl methacrylate (average particle size 2.0 μm) 0.040 g 6: 4 copolymer of methacrylic acid and methyl methacrylate (average particle size 2.0 μm) 0.030 g Surfactant W-3 0.060 g Surfactant W-2 7.0 mg Curing agent H-1 0.23 g.

(Iv) Coating of photosensitive emulsion layer On the side opposite to the side where the back layer was coated, the following photosensitive emulsion layer was coated to obtain Sample 101. Numbers represent the amount per m ^2. The effect of the added compound is not limited to the use described. First layer: Antihalation layer Black colloidal silver 0.25 g Gelatin 2.40 g Dye D-4 1.0 mg Dye D-8 2.5 mg Microcrystalline solid dispersion of Dye E-1 0.05 g.

Second layer: Intermediate layer Gelatin 0.50 g Compound Cpd-A 0.2 mg Compound Cpd-K 3.0 mg Compound Cpd-M 0.030 g High boiling organic solvent Oil-3 0.010 g High boiling organic solvent Oil-4 0.010 g High boiling point Organic solvent Oil-7 2.0 mg Dye D-7 4.0 mg.

Third layer: Intermediate layer Yellow colloidal silver 0.020 g Silver iodobromide emulsion whose surface and inside are covered in advance (cube, average silver iodide content 1%, average sphere equivalent particle size 0.06 μm) Silver Amount 0.010 g Gelatin 0.60 g Compound Cpd-D 0.020 g High boiling organic solvent Oil-3 0.010 g High boiling organic solvent Oil-8 0.010 g.

Fourth layer: low-sensitivity red-sensitive emulsion layer Emulsion A silver content 0.15 g Emulsion B silver content 0.20 g Emulsion C silver content 0.20 g gelatin 0.80 g Coupler C-1 0.10 g Coupler C-2 0.050 g Coupler C-3 0.020 g Coupler C-10 3.0 mg Coupler C-11 2.0 mg Compound Cpd-I 0.020 g Compound Cpd-D 3.0 mg Compound Cpd-J 2.0 mg High boiling organic solvent Oil-2 0.070 g Additive P-1 5.0 mg.

Fifth layer: Medium-speed red-sensitive emulsion layer Emulsion C silver amount 0.25 g Emulsion D silver amount 0.25 g gelatin 0.80 g coupler C-1 0.15 g coupler C-2 0.080 g coupler C-3 0.020 g coupler C-10 3.0 mg Compound Cpd-D 3.0 mg High boiling organic solvent Oil-2 0.10 g Additive P-1 7.0 mg.

Sixth layer: High-sensitivity red-sensitive emulsion layer Emulsion E silver amount 0.25 g Emulsion F silver amount 0.30 g gelatin 1.70 g Coupler C-1 0.10 g Coupler C-2 0.10 g Coupler C-3 0.60 g Coupler C-10 5.0 mg High boiling organic solvent Oil-2 0.050 g Compound Cpd-K 1.0 mg Compound Cpd-F 0.030 g Compound Cpd-L 1.0 mg Additive P-1 0.010 g Additive P-4 0.030 g.

Seventh layer: Intermediate layer Gelatin 0.70 g P-2 added 0.10 g Dye D-5 0.020 g Dye D-9 6.0 mg Compound Cpd-I 0.010 g Compound Cpd-M 0.040 g Compound Cpd-O 3.0 mg Compound Cpd -P 5.0mg High boiling organic solvent Oil-6 0.050g.

Eighth layer: Intermediate layer Yellow colloidal silver Silver amount 0.020 g Gelatin 1.00 g Additive P-2 0.05 g Compound Cpd-A 0.050 g Compound Cpd-D 0.030 g Compound Cpd-M 0.050 g High boiling organic solvent Oil- 3 0.010 g High boiling organic solvent Oil-6 0.050 g.

Ninth layer: low-sensitivity green-sensitive emulsion layer Emulsion G silver amount 0.30 g Emulsion H silver amount 0.35 g Emulsion I silver amount 0.30 g gelatin 1.70 g Coupler C-4 0.20 g Coupler C-5 0.050 g Coupler C-6 0.020 g Coupler C-7 0.010 g Compound Cpd-A 5.0 mg Compound Cpd-B 0.030 g Compound Cpd-D 5.0 mg Compound Cpd-G 2.5 mg Compound Cpd-F 0.010 g Compound Cpd-K 2.0 mg Ultraviolet absorber U-6 5.0 mg High boiling organic solvent Oil-2 0.15 g Additive P-1 5.0 mg.

Tenth Layer: Medium-Sensitive Green-Sensitive Emulsion Layer Emulsion I Silver content 0.30 g Emulsion J Silver content 0.30 g Silver bromide emulsion (cubic, sphere-equivalent mean particle size 0.11 μm) Silver content 3.0 mg Gelatin 0.70 g Coupler C-4 0.050 g Coupler C-5 0.050 g Coupler C-6 0.20 g Coupler C-7 0.010 g Compound Cpd-A 5.0 mg Compound Cpd-B 0.030 g Compound Cpd-F 0.010 g Compound Cpd-G 2.0 mg High boiling organic solvent Oil-2 0.030 g.

Eleventh layer: High-sensitivity green-sensitive emulsion layer Emulsion K Silver amount 0.60 g Gelatin 0.80 g Coupler C-6 0.40 g Coupler C-7 5.0 mg Compound Cpd-A 5.0 mg Compound Cpd-B 0.030 g Compound Cpd-F 0.010 g High boiling organic solvent Oil-2 0.030 g.

Twelfth layer: Yellow filter layer Yellow colloidal silver Silver amount 0.010 g Gelatin 1.0 g Compound Cpd-C 0.010 g Compound Cpd-M 0.10 g High boiling organic solvent Oil-1 0.020 g High boiling organic solvent Oil-6 0.10 g Microcrystalline solid dispersion of Dye E-2 0.20 g 13th layer: Intermediate layer Gelatin 0.40 g Compound Cpd-Q 0.20 g Dye D-6 3.0 mg High boiling organic solvent Oil-5 0.020 g 14th layer: Low sensitivity blue sensitivity Emulsion layer Emulsion L Silver content 0.15 g Emulsion M Silver content 0.20 g Emulsion N Silver content 0.10 g Gelatin 0.80 g Coupler C-8 0.020 g Coupler C-9 0.30 g Coupler C-10 5.0 mg Compound Cpd-B 0.10 g Compound Cpd- I 8.0 mg Compound Cpd-K 1.0 mg Compound Cpd-M 0.010 g Ultraviolet absorber U-6 0.010 g High boiling organic solvent Oil-2 0.010 g.

Fifteenth layer: Medium-sensitivity blue-sensitive emulsion layer Emulsion N Silver amount 0.20 g Emulsion O Silver amount 0.20 g Silver bromide emulsion (cubic, sphere-equivalent average particle size 0.11 μm) silver covered 3.0 silver mg Gelatin 0.80 g Coupler C-8 0.020 g Coupler C-9 0.25 g Coupler C-10 0.010 g Compound Cpd-B 0.10 g Compound Cpd-N 2.0 mg High boiling organic solvent Oil-2 0.010 g.

Sixteenth layer: high-sensitivity blue-sensitive emulsion layer Emulsion P silver amount 0.20 g Emulsion Q silver amount 0.25 g gelatin 2.00 g Coupler C-3 5.0 mg Coupler C-8 0.10 g Coupler C-9 1.00 g Coupler C-10 0.020 g High boiling organic solvent Oil-2 0.10 g High boiling organic solvent Oil-3 0.020 g Ultraviolet absorber U-6 0.10 g Compound Cpd-B 0.20 g Compound Cpd-E 0.10 g Compound Cpd-N 5.0 mg.

17th layer: 1st protective layer Gelatin 1.00 g UV absorber U-1 0.15 g UV absorber U-2 0.050 g UV absorber U-3 0.050 g UV absorber U-5 0.20 g Compound Cpd- O 5.0 mg Compound Cpd-A 0.030 g Compound Cpd-H 0.20 g Dye D-1 8.0 mg Dye D-2 0.010 g Dye D-3 0.010 g High boiling organic solvent Oil-3 0.10 g.

Eighteenth Layer: Second Protective Layer Colloidal Silver Amount 2.5 mg Fine grain silver iodobromide emulsion (average particle size 0.06 μm, AgI content 1 mol%) Silver amount 0.10 g Gelatin 0.80 g Ultraviolet absorber U-1 0.030 g UV absorber U-4 0.020 g UV absorber U-6 0.030 g High boiling organic solvent Oil-3 0.010 g.

19th layer: 3rd protective layer Gelatin 1.00 g Polymethyl methacrylate (average particle size 1.5 μm) 0.10 g Copolymer of methyl methacrylate and methacrylic acid 6: 4 (average particle size 1.5 μm) 0.15 g Silicone oil SO-1 0.20 g Surfactant W-1 3.0 mg Surfactant W-2 8.0 mg Surfactant W-3 0.040 g Surfactant W-7 0.015 g.

Further, additives F-1 to F-9 were added to all the emulsion layers in addition to the above composition. Further, in addition to the above composition, gelatin hardener H-1 and surfactants W-3, W-4, W-5 and W-6 for coating and emulsification were added to each layer. Further, phenol, 1,2-benzisothiazolin-3-one, 2-phenoxyethanol, phenethyl alcohol, and butyl p-benzoate were added as preservatives and fungicides.

The photosensitive emulsion used for Sample 101 is shown in Tables 1 to 5.

[Table 1]

[0114]

[Table 2]

[0115]

[Table 3]

[0116]

[Table 4]

[0117]

[Table 5]

The compounds used for forming each layer of Sample 101 are shown below.

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[0119]

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[0120]

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[0121]

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[0122]

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[0123]

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[0124]

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[0125]

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[0126]

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[0127]

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[0128]

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[0129]

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[0130]

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[0131]

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[0132]

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[0133]

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[0134]

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[0135]

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Preparation of Dispersion of Organic Solid Disperse Dye (Preparation of Dispersion of Dye E-1) A wet cake of dye E-1 (270 g as a net amount of E-1) was added to BASF Pl.
uronic F88 (ethylene oxide-propylene oxide
(Block copolymer) 100 g and water were added and stirred.
000 g. Next, 1700 mL of zirconia beads having an average particle size of 0.5 mm was charged into Ultra Viscomil (UVM-2) manufactured by Imex Co., Ltd., and the slurry was passed through the slurry at a peripheral speed of about 10 m / sec and a discharge rate of 0.51 / min for 2 hours. Crushed. The beads are removed by filtration, water is added, and the dye concentration is 3%.
And then heated at 90 ° C. for 10 hours for stabilization. The average particle size of the obtained fine dye particles was 0.30 μm, and the width of the particle size distribution (standard deviation of particle size × 100 / average particle size) was 20%.

(Preparation of Solid Dispersion of Dye E-2)
270 g of water and W-4 were added to 1400 g of a wet cake of E-2 containing 0% by mass and stirred to obtain a slurry having an E-2 concentration of 40% by mass. Next, a crusher, IMEX Co., Ltd.
Ultra Viscomil (UVM-2) with an average particle size of 0.5
mm of zirconia beads, the peripheral speed is about 10 m / sec through the slurry, and the discharge rate is 0.5 L / mi.
n for 8 hours to obtain a solid fine particle dispersion of E-2.
This was diluted to 20% by mass with ion-exchanged water to obtain a solid fine particle dispersion. The average particle size was 0.15 μm. Preparation of Samples 101 to 123 Next, coupler C- of the ninth, tenth, and eleventh layers of sample 101
4, 5, 6, and 7 were replaced as shown in Table 6, and an ultraviolet absorbing compound was added as shown in Table 6 to obtain Sample 10
2-123 were created.

In replacing the coupler, the coupler of the present invention has a molar ratio of 65 to C-4,5,7.
% And C-6, the molar ratio was changed to 70%, and the amounts of other additives other than those shown in Table 6 were adjusted according to the molar ratio of the coupler. The high boiling point organic solvent was added such that Oil-2 was 0.3 times in mass ratio to the total mass of the coupler in the layer. When an ultraviolet absorber is added, the ultraviolet absorber is added in a mass ratio of 0.1.
A 5-fold higher boiling organic solvent, 0 il-3, was also added. In samples 121 to 123, an ultraviolet absorbing compound was added to the back surface as shown in Table 6.

[0139]

[Table 6]

In this embodiment, the following developing process (developing process A) was performed. At the time of processing, the sample 101
The unexposed sample and the completely exposed sample were subjected to a running process at a ratio of 1: 1 until the replenishment amount became four times the tank capacity, and then a process for evaluation was performed. Processing time Time Temperature Tank capacity Replenishment amount First development 6 minutes 38 ° C 37L 2200mL / m ² First water washing 2 minutes 38 ° C 16L 4000mL / m ² Reversal 2 minutes 38 ° C 17L 1100mL / m ² Color development 6 minutes 38 ° C 30L 2200 mL / ^{m 2} before bleaching 2 min 38 ℃ 19L 1100mL / ^{m 2} bleaching 6 min 38 ℃ 30L 220mL / ^{m 2} Fixing 4 min 38 ℃ 29L 1100mL / ^{m 2} second water washing 4 minutes 38 ℃ 35L 4000mL / ^{m 2} final Rinse 1 minute 25 ° C. 19 L 1100 mL / m ² The composition of each treatment liquid was as follows.

[First developer] [Tank solution] [Replenisher] Nitrilo-N, N, N-trimethylenephosphonic acid · pentasodium salt 1.5 g 1.5 g Diethylenetriaminepentaacetic acid · pentasodium salt 2.0 g 2.0 g Sodium sulfite 30 g 30 g potassium hydroquinone monosulfonate 20 g 20 g potassium carbonate 15 g 20 g potassium bicarbonate 12 g 15 g 1-phenyl-4-methyl-4-hydroxymethyl-3-pyrazolidone 2.5 g 3.0 g potassium bromide 2.5 g 1.4 g Potassium thiocyanate 1.2 g 1.2 g Potassium iodide 2.0 mg-Diethylene glycol 13 g 15 g Water was added to 1000 mL 1000 mL pH 9.60 9.60 The pH was adjusted with sulfuric acid or potassium hydroxide.

[Inversion liquid] [Tank liquid] [Replenishment liquid] Nitrilo-N, N, N-trimethylenephosphonic acid tank liquid ・ Same as 3.0 g of pentasodium salt 1.0 g of stannous chloride / dihydrate p-amino Phenol 0.1 g Sodium hydroxide 8 g Glacial acetic acid 15 mL Water was added to 1000 mL pH 6.00 The pH was adjusted with acetic acid or sodium hydroxide.

[Color developing solution] [Tank solution] [Replenisher] Nitrilo-N, N, N-trimethylenephosphonic acid · pentasodium salt 2.0 g 2.0 g Sodium sulfite 7.0 g 7.0 g Trisodium phosphate / 12 dehydrate 36 g 36 g Potassium bromide 1.0 g-Potassium iodide 90 mg-Sodium hydroxide 12.0 g 12.0 g Citrazinic acid 0.5 g 0.5 g N-ethyl-N- (β-methanesulfonamidoethyl) -3-methyl-4- Aminoaniline-3 / 2 sulfuric acid monohydrate 10 g 10 g 3,6-dithiaoctane-1,8-diol 1.0 g 1.0 g Water was added to the mixture, and the pH was adjusted with sulfuric acid or potassium hydroxide.

[Pre-bleaching] [Tank solution] [Replenisher] Ethylenediaminetetraacetic acid disodium salt dihydrate 8.0 g 8.0 g Sodium sulfite 6.0 g 8.0 g 1-thioglycerol 0.4 g 0.4 g Sodium formaldehyde sodium bisulfite adduct 30 g 35 g Water was added and 1000 mL 1000 mL pH 6.30 6.10 pH was adjusted with acetic acid or sodium hydroxide.

[Bleaching solution] [Tank solution] [Replenisher] Ethylenediaminetetraacetic acid disodium salt dihydrate 2.0 g 4.0 g Ethylenediaminetetraacetic acid Fe (III) ammonium ammonium dihydrate 120 g 240 g Bromide Potassium 100 g 200 g Ammonium nitrate 10 g 20 g Water was added to 1000 mL 1000 mL pH 5.70 5.50 The pH was adjusted with nitric acid or sodium hydroxide.

[Fixing solution] [Tank solution] [Replenisher] Ammonium thiosulfate 80 g Same sodium sulfite 5.0 g に Sodium bisulfite 5.0 g タ ン ク Add water to 1000 mL ｐＨ pH 6.60 Adjust pH with acetic acid or aqueous ammonia did.

[Stabilizing solution] [Tank solution] [Replenishing solution] 1,2-benzoisothiazolin-3-one 0.02 g 0.03 g Polyoxyethylene-p-monononylphenyl ether (average degree of polymerization: 10) 0.3 g 0.3 g Polymalein Acid (weight-average molecular weight: 2,000) 0.1 g 0.15 g Water was added to make 1000 mL 1000 mL pH 7.0 7.0.

In the above developing process, each bath was continuously circulated and stirred with a liquid. Further, on the lower surface of each tank, a foaming tube having small holes of 0.3 mm in diameter at intervals of 1 cm was arranged. Nitrogen gas was continuously bubbled and stirred.

(Evaluation of Sample) (Evaluation of Yellow Coloring on White Background) After cutting the samples 101 to 123 into strips, the samples 101 to 123 were exposed to white light having a color temperature of 4800 ° C. through a wedge having a continuously changed density. Development A) was performed and the density was measured. Thereafter, the sample was heated to 40 ° C.
Store for 1 month under the condition of humidity 70%, then illuminance 10
Light was irradiated from the back surface side for 10 days using a xenon lamp fading tester of 000 lux, and the change in yellow density on a white background during the light irradiation period was observed. Table 7 shows the increase in the yellow density (status A) due to light irradiation as characteristic values.

(Evaluation of Discoloration) At the same time, the robustness of the magenta image before and after light irradiation was also evaluated. Table 7 shows the density after light irradiation at the point where a magenta density of 1.0 was given before light irradiation. It is preferable that the concentration is closer to 1.0 because the discoloration is less.

[0151]

[Table 7]

As is clear from Table 7, 4
It can be seen that the long-wavelength ultraviolet absorbing compound of the present invention has a large effect on the yellow coloring of the equivalent magenta coupler. Also, for example, as can be seen from a comparison of Samples 106 and 107, the ultraviolet absorbing compound of the present invention was used for the green-sensitive emulsion layer of the present invention and the other color-sensitive emulsion layer located closer to the support than the emulsion layer. The effect is enhanced by arranging in the non-photosensitive layer between them. Further, when the hydroquinone compound was used without the ultraviolet absorbing compound of the present invention (Sample 117), not only did the yellow coloring of the white background not improve, but also the robustness of the magenta image was impaired. By disposing the ultraviolet absorbing compound of the present invention here, both were improved.

Example 2 Fourth Samples 101 to 123
Samples 201 to 223 were prepared in the same manner except that the layer, the fifth layer, and the sixth layer were changed to the configurations described below.

Fourth layer: low-sensitivity red-sensitive emulsion layer Emulsion A silver amount 0.10 g Emulsion B silver amount 0.15 g Emulsion C silver amount 0.15 g gelatin 0.80 g Coupler CC-1 0.15 g Coupler CC-2 7.0 mg Coupler C-10 3.0 mg Coupler C-11 2.0 mg UV absorber U-3 0.010 g Compound Cpd-I 0.020 g Compound Cpd-D 3.0 mg Compound Cpd-J 2.0 mg High boiling organic solvent Oil-10 0.030 g Additive P-1 5.0 mg .

Fifth layer: Medium-sensitivity red-sensitive emulsion layer Emulsion C silver content 0.15 g Emulsion D silver content 0.15 g gelatin 0.70 g coupler CC-1 0.15 g coupler CC-2 7.0 mg coupler C-10 3.0 mg compound Cpd-D 3.0mg
UV absorber U-3 0.010 g High boiling organic solvent Oil-10 0.030 g Additive P-1 7.0 mg.

Sixth layer: high-sensitivity red-sensitive emulsion layer Emulsion E silver amount 0.15 g Emulsion F silver amount 0.20 g gelatin 1.50 g Coupler CC-1 0.60 g Coupler CC-2 0.015 g Coupler C-3 0.030 g Coupler C-10 5.0 mg UV absorber U-1 0.010 g UV absorber U-2 0.010 g High boiling organic solvent Oil-6 0.030 g High boiling organic solvent Oil-9 0.020 g High boiling organic solvent Oil-10 0.050 g Compound Cpd-D 5.0 mg Compound Cpd-K 1.0 mg Compound Cpd-F 0.030 g Compound Cpd-L 1.0 mg Additive P-1 0.010 g Additive P-4 0.030 g.

[0157]

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When the samples 201 to 221 were evaluated in the same manner as in Example 1, the same results as in Example 1 were obtained.

Claims (2)

[Claims] 1. A silver halide color photographic material having at least one blue-sensitive emulsion layer, at least one green-sensitive emulsion layer and at least one red-sensitive emulsion layer on a transparent support, wherein at least one photosensitive emulsion layer comprises: It contains at least one magenta coupler represented by the general formula (MC-I) and has a λmax of 360 nm closer to the support than the photosensitive emulsion layer.
A silver halide color photographic light-sensitive material comprising at least one layer containing an ultraviolet absorbing compound having a wavelength of not less than 400 nm and not more than 400 nm. Embedded image In the formula, R ₁ represents a hydrogen atom or a substituent, and G ₁ , G ₂
Represents one of a carbon atom and the other represents a nitrogen atom, and R ₂ represents a substituent, which is substituted on _one of G ₁ and G ₂ which is a carbon atom. R ₁ or _{R 2} may further have a substituent, also via the _R 1, _{R 2} Formula (MC-
It may form a multimer of I) and may be bonded to the polymer chain via R ₁ or R ₂ . 2. A silver halide color photographic material having at least one blue-sensitive emulsion layer, one green-sensitive emulsion layer and one red-sensitive emulsion layer on a transparent support, wherein at least one photosensitive emulsion layer has It contains at least one magenta coupler represented by the general formula (MC-I), and contains, on the surface of the support opposite to the photosensitive emulsion layer, an ultraviolet absorbing compound having λmax of 360 nm or more and 400 nm or less. A silver halide color photographic light-sensitive material comprising at least one layer to be formed. Embedded image In the formula, R ₁ represents a hydrogen atom or a substituent, and G ₁ , G ₂
Represents one of a carbon atom and the other represents a nitrogen atom, R ₂ represents a substituent, and is substituted on _one of G ₁ and G ₂ which is a carbon atom. R ₁ or _{R 2} may further have a substituent, also via the _R 1, _{R 2} Formula (MC-
It may form a multimer of I) and may be bonded to the polymer chain via R ₁ or R ₂ .