JP2002131555A - Light-scattering light guide body and light source device which scatters and guides light - Google Patents

Light-scattering light guide body and light source device which scatters and guides light

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Publication number
JP2002131555A
JP2002131555A JP2001249458A JP2001249458A JP2002131555A JP 2002131555 A JP2002131555 A JP 2002131555A JP 2001249458 A JP2001249458 A JP 2001249458A JP 2001249458 A JP2001249458 A JP 2001249458A JP 2002131555 A JP2002131555 A JP 2002131555A
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JP
Japan
Prior art keywords
light
scattering
scattered
light guide
region
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2001249458A
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Japanese (ja)
Other versions
JP3414727B2 (en
Inventor
Yasuhiro Koike
康博 小池
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Individual
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Individual
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Publication of JP2002131555A publication Critical patent/JP2002131555A/en
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Abstract

PROBLEM TO BE SOLVED: To provide a light-scattering light guide body and a light source device having a simple structure from which bright uniform light can be obtained. SOLUTION: The exiting face of the scattered light of a light-scattering light guide body 1 has a rugged region 2 to control the intensity-angle characteristics of the exiting scattered light, and a rod-like light source element (fluorescent lamp) 5 is disposed in the side of the body. A reflection film 4 made of another material is disposed in the opposite side of the light-scattering light guide body to the exiting face of the scattered light. The light emitting from the rod-like light source 5 and entering the light-scattering light guide body 1 is guided while scattered inside. Most of the light propagating the reflection film 4 side is immediately reflected by the reflection film 4 to return to the light-scattering light guide body 1. The light used as the back light of a liquid crystal display device or the like is the light exiting from the exiting region of the scattered light. The directional characteristics of the intensity of the light are controlled by the rugged region 2. The distance d in the figure represents the pitch of the rugged pattern formed into lines. The light source element may be embedded in the light-scattering light guide body or may be housed in the recessed part.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、光源要素から発せ
られた光を受け入れて導光しながら散乱光を周囲に向け
て出射し得る光散乱導光体並びに光散乱導光体と光源要
素を組み合わせた光散乱導光光源装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a light-scattering light guide capable of emitting scattered light to the surroundings while receiving and guiding light emitted from a light source element, and a light-scattering light guide and a light source element. The present invention relates to a combined light scattering and light guiding light source device.

【0002】更に詳しく言えば、本発明は、液晶表示装
置(LCD)のバックライト光源等に適用して特に有用
な、散乱出射光強度の角度特性が調整された光散乱導光
体並びに光散乱導光体と光源要素の配置関係に工夫を加
えることによって、明るく均一な散乱出射光を取出表面
領域の大小に拘らず容易に得ることの出来る光散乱導光
光源装置に関する。
More specifically, the present invention is particularly useful when applied to a backlight light source of a liquid crystal display device (LCD) and the like, and a light-scattering light guide and a light-scattering light having an adjusted angle characteristic of scattered emission light intensity. The present invention relates to a light-scattering light-guiding light source device capable of easily obtaining bright and uniform scattered emission light irrespective of the size of an extraction surface area by devising the arrangement relationship between a light guide and a light source element.

【0003】[0003]

【従来の技術】従来より、散乱現象を利用して光を所望
の方向に向け出射させる型の光学要素あるいは装置とし
て種々のものが公知となっており、液晶表示装置のバッ
クライト光源等の用途に使われている。
2. Description of the Related Art Hitherto, various types of optical elements or devices for emitting light in a desired direction by utilizing a scattering phenomenon have been known, and are used for backlight sources of liquid crystal display devices. Used in

【0004】これら公知の光学要素あるいは装置の1つ
の類型は、延在した板状の透明材料の側方より光を入射
させ、一方の面側に反射要素を配し、他方の表面付近に
光拡散性を与えて光出射面とする面状光源を構成し、液
晶表示装置のバックライト光源等として使用するもので
ある。
One type of these known optical elements or devices is that light is incident from the side of an extended plate-shaped transparent material, a reflecting element is arranged on one surface side, and light is emitted near the other surface. A planar light source having a light emitting surface with diffusivity is provided, and is used as a backlight light source of a liquid crystal display device.

【0005】例えば、特開昭62―235905号公
報、特開昭63―63083号公報、特開平2―139
25号公報及び特開平2―245787号公報に記載さ
れたものがこれに当る。
For example, Japanese Patent Application Laid-Open Nos. 62-235905, 63-63083, and 2-139
No. 25 and JP-A-2-245787 correspond to this.

【0006】これら光散乱導光装置を用いた面状光源に
おいては、光散乱が透明体の内部で体積的に生起されて
おらず、透明体の表面付近あるいは反射要素における乱
反射や鏡面反射を利用して光出射方向に拡がりを持たせ
ているのみなので、光散乱導光装置から取り出せる散乱
光の割合を十分に上げるには原理的な困難があった。
[0006] In the planar light source using these light-scattering light-guiding devices, light scattering is not generated volumetrically inside the transparent body, and irregular reflection or specular reflection near the surface of the transparent body or at a reflection element is used. However, there is only a spread in the light emitting direction, and there has been a fundamental difficulty in sufficiently increasing the ratio of scattered light that can be extracted from the light scattering light guide device.

【0007】また、側方から光を入射させて均一な照度
を有する面状光源を得ようとした場合、上記各公知文献
に示された例からも容易に理解されるように、反射要素
の反射能等になんらかの勾配を持たせなければならず、
光散乱導光体装置部分の構造が複雑かつ大型のものとな
り、製造コストも高くならざるを得なかった。
Further, when light is incident from the side to obtain a planar light source having a uniform illuminance, as will be easily understood from the examples shown in the above-mentioned known documents, the reflection element It is necessary to have some gradient in the reflectivity etc.
The structure of the light-scattering light guide device part becomes complicated and large, and the manufacturing cost must be high.

【0008】従って、この型の光散乱導光装置を液晶表
示装置のバックライト光源等の用途に用いた場合、明る
さ、面状光源として照度の均一性、薄型構造、経済性等
の要求のうちのいくつかを犠牲にせざるを得なかった。
Therefore, when this type of light-scattering light guide device is used for a backlight light source of a liquid crystal display device or the like, it is required to provide brightness, uniform illuminance as a planar light source, a thin structure, economical efficiency and the like. I had to sacrifice some of them.

【0009】公知の光学要素あるいは装置のもう1つの
類型は、延在した板状の透明材料の内部に該透明材料と
屈折率の異なる粒状物質を分散させて光導光板を構成す
るものである。
Another type of a known optical element or device is one in which a light guide plate is formed by dispersing a particulate material having a different refractive index from that of an extended plate-shaped transparent material.

【0010】例えば、特開平1―172801号公報、
特開平1―236257号公報、特開平1―26990
1号公報、特開平2―221925号公報及び特開平4
―145485号公報に開示されたものがこの類型に属
する。
[0010] For example, JP-A-1-172801,
JP-A-1-236257, JP-A-1-26990
No. 1, JP-A-2-221925 and JP-A-4-221.
The one disclosed in JP-A-145485 belongs to this type.

【0011】特に、上記特開平2―221925号公報
及び特開平4―145485号公報開には、光導光板の
側方より光を入射させ、一方の面側に反射要素を配し他
方の面を光出射面として、液晶表示装置のバックライト
光源等を構成することが開示されている。
[0011] In particular, in the above-mentioned JP-A-2-221925 and JP-A-4-145485, light is incident from the side of the light guide plate, a reflecting element is arranged on one side, and the other side is arranged. It is disclosed that a backlight light source or the like of a liquid crystal display device is configured as a light emitting surface.

【0012】これらの光導光板においては、透明体の内
部に分散混入された粒状物質によって生じる屈折率の不
均一によって光散乱が体積的に生起されている。その意
味において、上記第1の類型のものに比して、光拡散効
率を改善し得るものということは出来るが、この型の光
散乱体を光散乱導光体として組み込んで光散乱導光装置
を構成する場合に、従来、次のような問題が生じてい
た。
In these light guide plates, light scattering occurs volumetrically due to non-uniform refractive index caused by particulate matter dispersed and mixed in the transparent body. In that sense, it can be said that the light diffusion efficiency can be improved as compared with the first type, but this type of light scatterer is incorporated as a light scatterer and light guide device. The following problems have conventionally arisen in the configuration of

【0013】すなわち、上記公知例でも判るように、そ
れ自身が光散乱能を有し、光を散乱させながら導光する
機能を有する素子、即ち、光散乱導光体と、該光散乱導
光体の側方より光を入射させる光源素子とを組み合わせ
て光散乱導光装置とした場合には、出射散乱光強度の均
一化を意図して光散乱導光体内に分散させた粒状物質の
分散濃度に勾配を与えたり、あるいは、光散乱導光体の
裏面側に光拡散性インク等を用いて、網目状、ドット状
などの散乱補強手段を設け、場合によっては、該網目や
ドットの密度に勾配を付け、該散乱補強手段が散乱光取
出面の側から観察した時に透けて見える不都合を回避す
る為に散乱光取出面側に別の光拡散板を設けるというよ
うなことが行われていた。
That is, as can be seen from the above-mentioned known examples, an element having a light scattering ability by itself and having a function of guiding light while scattering light, that is, a light scattering light guide, and the light scattering light guide When a light scattering device is used in combination with a light source element that allows light to enter from the side of the body, the dispersion of the particulate matter dispersed in the light scattering device is intended to make the intensity of the emitted scattered light uniform. By giving a gradient to the concentration, or by using a light-diffusing ink or the like on the back side of the light-scattering light guide, a mesh-like or dot-like scattering reinforcing means is provided, and in some cases, the density of the mesh or the dot is increased. In order to avoid the inconvenience that the scattering reinforcing means can see through when observed from the side of the scattered light extraction surface, another light diffusion plate is provided on the scattered light extraction surface side. Was.

【0014】即ち、従来は、光源に近い部分では散乱能
を意識的に落し、光源から離れた部分では裏面側の網目
状あるいはドット状の補強層を含めて光散乱能を最大限
に高めるという考え方や、裏面領域に網目状あるいはド
ット状の拡散インキ層等の補強手段を付加して光散乱能
を最大限に高めるという考え方が採用されて来た。この
ような状況は、光散乱導光体になんらかの散乱能勾配が
存在しない場合には、光源に近い光散乱導光体縁部付近
のみが明るく見え、中央部では、照度が低下してしまう
傾向が生じ、また、裏面領域の補強手段なくしては明る
さ自体を確保し得ないと信じられていたことによるもの
と思われる。
That is, conventionally, the scattering power is consciously reduced in a portion close to the light source, and the light scattering capability is maximized in a portion away from the light source, including a mesh-like or dot-like reinforcing layer on the back side. The idea and the idea of adding a reinforcing means such as a mesh-like or dot-like diffusion ink layer to the back surface region to maximize the light scattering ability have been adopted. In such a situation, when there is no scattering power gradient in the light scattering light guide, only the light scattering light guide near the light source edge looks bright, and in the center, the illuminance tends to decrease. This is considered to be due to the fact that it was believed that the brightness itself could not be ensured without reinforcing means for the back surface region.

【0015】確かに、光源から出た光の1次散乱のみを
考慮した場合には、裏面に光散乱補強手段を形成し、光
散乱能を与える粒子の分布や裏面の反射散乱補強層に散
乱能勾配を与えなければ、均一な出射光強度が実現され
ないという結論にならざるを得ないから、製造工程上の
不利を承知の上で、上記したような手段が取られていた
のは無理からぬことと言える。
Indeed, when only the primary scattering of light emitted from the light source is taken into consideration, a light scattering reinforcing means is formed on the back surface, and the distribution of particles imparting light scattering ability and the scattering on the reflection scattering reinforcing layer on the back surface are increased. Unless a gradient is given, it must be concluded that a uniform intensity of emitted light cannot be realized.Therefore, it is impossible to take the above-mentioned measures with knowledge of the disadvantages in the manufacturing process. I can say nothing.

【0016】また、従来の公知技術においては、散乱出
射光強度の角度特性を調整する手段が設けられていなか
ったので、異屈折率粒状物質の粒子径やマトリックスと
の屈折率差等によって定まってしまう角度特性をそのま
ま受け入れて使用していた。異屈折率粒状物質の粒子径
や屈折率差等は、光学材料選択上の制約や製造技術上の
制約を受けるから、得られた製品の散乱光強度角度特性
が希望したものと一致しないことも多く、不必要な方向
へ出射した多くの光が無駄になることがしばしば生じて
いた。例えば、比較的大きな粒径を有する異屈折率粒状
物質を内部に分布させた光散乱導光体の側方から光を入
射させて液晶表示装置用のバックライト光源とした場合
には、散乱出射光が前方に偏って散乱する傾向があり、
液晶表示装置の正面方向から観察した場合に、表示面が
明るく見えないという事態が起こっていた。
In the prior art, there is no means for adjusting the angular characteristic of the intensity of the scattered and emitted light, so that it is determined by the particle size of the particulate material having a different refractive index and the difference in the refractive index from the matrix. The angle characteristics that would be lost were used as they were. Since the particle diameter and refractive index difference of the different refractive index particulate material are subject to restrictions on the selection of optical materials and restrictions on manufacturing technology, the scattered light intensity angle characteristics of the obtained product may not match the desired one. Often, a lot of light emitted in unnecessary directions is wasted. For example, when light is incident from the side of a light-scattering light guide in which a hetero-refractive-index particulate material having a relatively large particle size is distributed, a scattered light is generated. The light tends to scatter forward and
When viewed from the front of the liquid crystal display device, a situation has occurred where the display surface does not appear bright.

【0017】光散乱導光体乃至装置において散乱出射光
強度の角度特性を調整する手段を設けるという技術思想
自体は、本発明者が既に提案し、日本国特許庁に出願し
た特許出願(平成4年11月27日出願)の明細書に開
示したところであるが、本発明は該技術思想を更に具体
的に展開した一形態を提供するものである。
The technical idea of providing a means for adjusting the angle characteristic of the scattered light intensity in the light scattering light guide or device itself has already been proposed by the inventor of the present invention and has been filed with the Japan Patent Office (Heisei 4). The present invention provides an embodiment in which the technical idea is developed in a more specific manner.

【0018】[0018]

【発明が解決しようとする課題】本発明は、上記説明し
た従来技術の諸々の問題点、即ち、(a)散乱能の勾配
付与や拡散インキ層等の補強手段付加に伴う製造工程の
複雑化と装置の大型化の問題、(b)散乱出射光強度の
角度特性の問題を解決することを企図したものである。
SUMMARY OF THE INVENTION The present invention has various problems in the prior art described above, that is, (a) the manufacturing process is complicated due to the addition of a gradient of scattering power and the addition of reinforcing means such as a diffusion ink layer. And (b) the problem of the angular characteristic of the intensity of scattered emitted light.

【0019】[0019]

【課題を解決するための手段】本発明は、入射光受入表
面領域と、入射光受入表面領域からの入射光を起源とす
る散乱出射光を取り出す為の散乱出射光取出表面領域
と、光散乱能が実質的に一様に与えられた光散乱体積領
域とを有し、前記散乱出射光取出表面領域あるいは散乱
出射光取出表面領域と相反する側の面(外部の反射要素
に対向)の少なくとも一部に、散乱出射光強度の角度特
性を調整する規則的なプリズム状要素配列からなる凹凸
領域を設けることで上記(a)及び(b)の問題を解決
する基本的構成を提供したものである(請求項1、請求
項2)。
SUMMARY OF THE INVENTION The present invention comprises an incident light receiving surface area, a scattered and emitted light extraction surface area for extracting scattered and emitted light originating from incident light from the incident light receiving surface area, and a light scattering. And a light scattering volume region in which the function is provided substantially uniformly, and at least a scattered emission light extraction surface region or a surface opposite to the scattered emission light extraction surface region (facing an external reflection element). A basic configuration that solves the above problems (a) and (b) by partially providing a concavo-convex area composed of a regular array of prismatic elements for adjusting the angular characteristics of the scattered emission light intensity is provided. (Claims 1 and 2).

【0020】ここで、光散乱体積領域の散乱特性につい
ては、有効散乱照射パラメータEと相関距離aを用い
て、特に実際的な条件を特定したものである。
Here, regarding the scattering characteristics of the light scattering volume region, practical conditions are particularly specified by using the effective scattering irradiation parameter E and the correlation distance a.

【0021】また、光散乱体積領域の形状の主要部(凹
凸領域を除いた部分)を直方体状に特定して、特に通常
形状の液晶表示装置のバックライト光源装置等に本発明
の散乱出射光強度角度特性調整手段付きの光散乱導光体
を組み込んだ場合に、上記問題点(a)及び(b)を解
決する典型的且つ基本的な構成を提供したものである
(請求項3、請求項4)。
The main part of the shape of the light scattering volume region (the portion excluding the uneven region) is specified as a rectangular parallelepiped, and the scattered emission light of the present invention is particularly applied to a backlight light source device of a liquid crystal display device having a normal shape. The present invention provides a typical and basic configuration that solves the above problems (a) and (b) when a light scattering light guide with intensity angle characteristic adjusting means is incorporated. Item 4).

【0022】そして、光散乱体積領域の主要部形状を直
方体状に特定すると共に光源要素の形状を棒状に特定す
れば、特に通常形状の液晶表示装置のバックライト光源
装置等に本発明の光源要素配置を採用する際の、上記問
題点(a)及び(b)を解決する為の典型的な構成が提
供出来る(請求項5)。
If the shape of the main part of the light scattering volume region is specified as a rectangular parallelepiped and the shape of the light source element is specified as a rod shape, the light source element of the present invention can be applied particularly to a backlight light source device of a liquid crystal display device having a normal shape. A typical configuration for solving the above problems (a) and (b) when employing the arrangement can be provided (claim 5).

【0023】なお、光散乱導光装置で用いられる光散乱
体積領域の散乱特性については、請求項1、請求項2と
同じ条件が、有効散乱照射パラメータEと相関距離aを
用いて、規定される。
With respect to the scattering characteristics of the light scattering volume region used in the light scattering light guide device, the same conditions as those in claims 1 and 2 are defined using the effective scattering irradiation parameter E and the correlation distance a. You.

【0024】本発明の光散乱導光体あるいは光散乱導光
光源装置において光散乱体積領域を形成する材料につい
ては、実質的に均一な散乱能を有するものであれば任意
の材料を選択することが出来るが、それら材料の代表的
なものを列挙すれば、次の(1)〜(3)に挙げる型の
ものがある。
As for the material forming the light scattering volume region in the light scattering light guide or light scattering light guide device of the present invention, any material can be selected as long as it has a substantially uniform scattering ability. The following types (1) to (3) are listed as typical examples of those materials.

【0025】(1)光学樹脂マトリックス中に該マトリ
ックスと屈折率の異なる粒状物質(異屈折率粒状物質)
を分散させた材料。 (2)重合過程で生々された屈折率不均一構造によって
散乱能が与えられている樹脂材料。 (3)2種類以上の屈折率の相互に異なるポリマー材料
を混合加熱して、練り合わす混練工程と成形工程(射出
成形工程、押し出し工程等)を組み合わせて製造される
樹脂材料。以下、各型の材料について具体的に説明す
る。
(1) A particulate material having a different refractive index from that of the optical resin matrix (a particulate material having a different refractive index)
Dispersed material. (2) A resin material having a scattering ability provided by a non-uniform refractive index structure produced during the polymerization process. (3) A resin material manufactured by mixing and heating two or more types of polymer materials having different refractive indices and kneading them together with a molding step (injection molding step, extrusion step, etc.). Hereinafter, each type of material will be specifically described.

【0026】(1)の型の材料について;この型の材料
自体は、前述したように、特開平1―172801号公
報、特開平1―236257号公報、特開平1―269
901号公報、特開平2―221925号公報及び特開
平4―145485号公報に開示されている通り公知の
ものである。
As for the material of the mold of (1), as described above, the material of the mold itself is disclosed in JP-A-1-172801, JP-A-1-236257, and JP-A-1-269.
These are known ones as disclosed in JP-A-901-901, JP-A-2-221925 and JP-A-4-145485.

【0027】ポリマーマトリックス材料として代表的な
ものには、後記する表1、表2にも挙げられているPM
MA(ポリメチルメタクリレート)、PSt(ポリスチ
レン)、PC(ポリカーボネート)等がある。
Representative examples of the polymer matrix material include PM, which is also listed in Tables 1 and 2 below.
MA (polymethyl methacrylate), PSt (polystyrene), PC (polycarbonate) and the like.

【0028】又、粒子状物質としては、例えば、シリコ
ン系樹脂、メタクリル樹脂、ポリスチレン樹脂のような
有機材料からなる粒子や酸化チタン、炭酸カルシウム、
シリカ等の無機材料からなる粒子が使用出来る。製造方
法については、上記各公報にも記載されているような各
種の公知の方法を利用すれば良いので、詳しい説明を省
略する。なお、公知でない手法の1つに、本発明者の発
明に係る(3)の型の材料に対する製造方法を適用する
やり方がある。これについては、(3)の型の材料の項
で実例を挙げて説明する。
Examples of the particulate matter include particles made of organic materials such as silicone resin, methacrylic resin and polystyrene resin, titanium oxide, calcium carbonate, and the like.
Particles made of an inorganic material such as silica can be used. Regarding the manufacturing method, various known methods as described in each of the above publications may be used, and a detailed description thereof will be omitted. As one of the unknown techniques, there is a method of applying the manufacturing method for the material of the type (3) according to the present inventor's invention. This will be described by way of an example in the section of the material of the type (3).

【0029】(2)の型の材料について;この型の材料
は、光散乱導光体の素材として、本発明者に係る国際出
願(PCT/JP92/01230号)に開示されてい
る。
Material of type (2): This type of material is disclosed in the international application (PCT / JP92 / 01230) of the present inventor as a material for the light scattering light guide.

【0030】即ち、光散乱導光体に散乱能を与える屈折
率不均一構造が、有機材料の重合過程で生成されている
ものである。有機材料の重合過程によって屈折率不均一
構造を形成させて光散乱導光体を得る原理の概要を簡単
に説明する。
That is, a non-uniform refractive index structure that gives the light-scattering light guide a scattering power is generated during the polymerization process of the organic material. The principle of obtaining a light-scattering light guide by forming a non-uniform refractive index structure by a polymerization process of an organic material will be briefly described.

【0031】一般に、有機材料の重合過程においては、
種々のメカニズムによって不均一構造が生成され、これ
を利用して屈折率不均一構造を有する光散乱導光体を得
ることが出来る。そのメカニズムのいくつかを挙げる
と、次のようになる。
Generally, in the process of polymerizing an organic material,
A non-uniform structure is generated by various mechanisms, and a light-scattering light guide having a non-uniform refractive index structure can be obtained using the non-uniform structure. Some of the mechanisms are as follows.

【0032】(I) 第1材料としてのモノマーに第2材
料としてのポリマー(オリゴマーであっても良い。以
下、特にことわりの無い限り、ポリマーと言えばオリゴ
マーを含むものとする。)を少量溶解させる。この状態
では、ポリマーの個々の分子が完全に溶解している。従
って、均一に混ざり合った透明な混合溶液の形態をとっ
ており、光散乱性は生じていない。この混合溶液に重合
開始剤等を添加して加熱するなどの手段により重合反応
を開始させる。重合反応が進行し、高転化率になってき
た時、それまでに生成されてきた第1材料のポリマーと
第2材料のポリマーとの相溶性が、該第2材料のポリマ
ーと第1材料のモノマーとの相溶性に比べて小さい場合
には、第2材料のポリマーは徐々に凝集構造を形成す
る。第1材料のポリマーと第2材料のポリマーの屈折率
が実質的に相異するように有機材料を組み合わせれば、
屈折率がゆらいだ構造、すなわち屈折率不均一構造が生
成される。
(I) A small amount of a polymer (an oligomer may be used. Hereinafter, unless otherwise specified, the polymer includes an oligomer) is dissolved in a monomer as a first material. In this state, the individual molecules of the polymer are completely dissolved. Therefore, it is in the form of a transparent mixed solution uniformly mixed, and no light scattering property is generated. The polymerization reaction is started by means such as adding a polymerization initiator or the like to the mixed solution and heating. When the polymerization reaction proceeds and a high conversion rate is reached, the compatibility between the polymer of the first material and the polymer of the second material that has been produced up to that point is due to the compatibility between the polymer of the second material and the first material. If the compatibility with the monomer is small, the polymer of the second material gradually forms an aggregated structure. If organic materials are combined so that the refractive indices of the polymer of the first material and the polymer of the second material are substantially different,
A structure in which the refractive index fluctuates, that is, a non-uniform refractive index structure is generated.

【0033】この場合、粒子状の物質をモノマーに混入
分散させて重合を行わせたり、ポリマーに粒子を高温条
件下で練り込ませたりする従来技術とは違って、重合前
にポリマー分子1つ1つのレベルで均一に溶解した状態
が実現しており、その状態からスタートして不均一構造
を徐々に形成しているので、極めて高い均一度で不均一
構造が分布した光散乱導光体を得ることが出来る。
In this case, unlike a conventional technique in which a particulate substance is mixed and dispersed in a monomer to carry out polymerization or a polymer is kneaded with particles under a high temperature condition, one polymer molecule is used before polymerization. A state of uniform melting at one level is realized, and a non-uniform structure is gradually formed starting from that state. Can be obtained.

【0034】(II) 第1材料としてのモノマーに第2材
料としてのモノマーを適量混合して重合反応を起こさせ
る。この時例えば、第1材料のモノマーの反応性比r1
と第2材料のモノマーの反応性比r2 について、r1 >
1且つr2 <1が成立するように材料を選択しておけ
ば、重合反応の過程で第1材料のモノマーは優先的に重
合し、未反応モノマー中の第2材料のモノマーの割合は
次第に増大する。第1材料のモノマーの大半が重合する
と、今度は第2材料のモノマーの重合する割合が増加し
始め、最終段階においては、第2材料のポリマーのみが
生成されることになる。
(II) An appropriate amount of a monomer as a second material is mixed with a monomer as a first material to cause a polymerization reaction. At this time, for example, the reactivity ratio r1 of the monomer of the first material
And the reactivity ratio r2 between the monomer of the second material and r2>
If the materials are selected so that 1 and r2 <1, the monomers of the first material polymerize preferentially during the polymerization reaction, and the proportion of the monomers of the second material in the unreacted monomers gradually increases. I do. As the majority of the monomers of the first material polymerize, the rate of polymerization of the monomers of the second material then begins to increase, and in the final stage, only the polymer of the second material will be produced.

【0035】第1材料のポリマーと第2材料のポリマー
の相溶性が比較的小さければ、組成の似たもの同士、す
なわち、第1材料のポリマーと第2材料のポリマーとが
それぞれ凝集構造を形成することになる。両ポリマーの
屈折率が実質的に異なれば、屈折率がゆらいだ屈折率不
均一構造が生成される。この場合も重合前にモノマー同
士を均一に混ぜることは容易なので、まんべんなく屈折
率不均一構造が形成される。
If the compatibility of the polymer of the first material and the polymer of the second material is relatively small, those having similar compositions, that is, the polymer of the first material and the polymer of the second material each form an aggregated structure. Will do. If the refractive indices of the two polymers are substantially different, a non-uniform refractive index structure having a fluctuating refractive index is generated. Also in this case, it is easy to uniformly mix the monomers before polymerization, so that a non-uniform refractive index structure is evenly formed.

【0036】(III) 単独材料のモノマーのみを重合さ
せても、屈折率不均一構造を形成することが出来る。す
なわち、モノマーとポリマーの比重が十分に異なれば、
重合が進んでポリマーがある程度固くなってくると、残
存モノマーがポリマーになった時の体積収縮部分は、い
わゆるマイクロボイドとなる。このマイクロボイドは極
めて多数形成され、重合反応の結果得られるポリマー内
に3次元的に均一分布した光散乱中心として機能するの
で、従来の物質粒子を分散混入させた光散乱導光体に比
して特性の良い光散乱導光体が得られる。
(III) Even if only a monomer of a single material is polymerized, a non-uniform refractive index structure can be formed. That is, if the specific gravity of the monomer and the polymer are sufficiently different,
When the polymerization proceeds and the polymer becomes hard to some extent, the volume shrinkage portion when the residual monomer becomes a polymer becomes a so-called microvoid. An extremely large number of these microvoids are formed and function as light scattering centers uniformly distributed three-dimensionally in the polymer obtained as a result of the polymerization reaction. Thus, a light-scattering light guide having good characteristics can be obtained.

【0037】(IV) 上記(I) の類型の変形として、上
記第2の材料に低分子量であって、第1材料のモノマー
との相溶性は良好であるが第1材料ポリマーとの相溶性
は劣るものを選択することも可能である。この場合に
も、上記(I) で述べたのと同様のメカニズムによって、
第2材料(低分子量物質)が凝集して不均一構造が生ま
れる。第2材料の屈折率が第1材料ポリマーと実質的に
異なるような組合せを採用すれば光散乱導光体が製造さ
れる。
(IV) As a modification of the type (I), the second material has a low molecular weight and has good compatibility with the monomer of the first material, but has good compatibility with the polymer of the first material. It is also possible to select an inferior one. Also in this case, by the same mechanism as described in (I) above,
The second material (low molecular weight substance) aggregates to form a non-uniform structure. If a combination is used in which the refractive index of the second material is substantially different from that of the first material polymer, a light scattering light guide is manufactured.

【0038】このような低分子材料として用い得る物質
は数多く存在するが、例を挙げれば、フタル酸ジフェニ
ル、ヘキサフロロイソプロピルテレフタレート、ビフェ
ニル、安息香酸フェニル等がある。屈折率不均一構造の
生成メカニズムの細部には多様性があるが、本発明で
は、そのようなメカニズムの差異にかかわりなく、いず
れの材料を使用することも許容するものである。
There are many substances that can be used as such a low molecular weight material. Examples thereof include diphenyl phthalate, hexafluoroisopropyl terephthalate, biphenyl and phenyl benzoate. Although the details of the mechanism of creating a non-uniform refractive index structure vary widely, the present invention allows for the use of any material, regardless of the differences in such mechanisms.

【0039】有機材料の具体的選定、重合条件等に関し
ては、上記明細書に詳しく記述されているので、ここで
は詳細を省略し、いくつかの実例を挙げるにとどめるこ
とにする。
The specific selection of the organic material, the polymerization conditions, and the like are described in detail in the above specification, so that the details are omitted here and only some examples will be given.

【0040】[重合過程を利用して光散乱導光体を得る
方法の実例] [1]MMAにトリフルオロエチルメタクリレート(3
FMA)のポリマーを0.1wt%溶解し、ラジカル重
合開始剤としてt―ブチルパーオキシイソプロピルカー
ボネート0.2wt%、連鎖移動剤として、n―ブチル
メルカプタンを0.2wt%加え、70゜Cで96時間
重合した後、熱処理を行い、棒状、板状等各種形状の光
散乱導光体を得ることが出来る。 [2]MMAとビニルベンゾエート(VB)を4対1の
割合で共重合させる。重合開始剤としてディ・ターシャ
リー・ブチルパーオキサイド(DBPO)を0.2wt
%、連鎖移動剤としてn―ブチルメルカプタンを0.2
wt%用い、130゜Cで96時間重合させる。得られ
た光散乱導光体は、上記[1]で得られるものとほぼ同
様の特性を示す。
[Example of Method for Obtaining Light Scattering Light Guide Using Polymerization Process] [1] Trifluoroethyl methacrylate (3
FMA) was dissolved in 0.1 wt%, 0.2 wt% of t-butyl peroxyisopropyl carbonate was added as a radical polymerization initiator, and 0.2 wt% of n-butyl mercaptan was added as a chain transfer agent. After polymerization for a period of time, heat treatment is performed to obtain light-scattering light guides in various shapes such as a rod shape and a plate shape. [2] MMA and vinyl benzoate (VB) are copolymerized at a ratio of 4: 1. 0.2 wt% of tertiary butyl peroxide (DBPO) as a polymerization initiator
%, 0.2% of n-butyl mercaptan as a chain transfer agent
Polymerization is carried out at 130 ° C for 96 hours using wt%. The obtained light-scattering light guide exhibits substantially the same characteristics as those obtained in the above [1].

【0041】[3]MMAに3FMAのポリマーを0.
15wt%溶解したものと、0.1wt%溶解したもの
を調製し、各々にラジカル重合開始剤としてt―ブチル
パーオキシイソプロピルカーボネート0.2wt%、連
鎖移動剤として、n―ブチルメルカプタンを0.2wt
%加え、70゜Cで72時間重合した後、130゜Cで
24時間熱処理を行い、光散乱導光体を製造することが
出来る。 [4]MMAとビニルベンゾエート(VB)を4対1の
割合で共重合させた。重合開始剤としてディ・ターシャ
リー・ブチルパーオキサイド(DBPO)を0.2wt
%、連鎖移動剤としてn―ブチルメルカプタンを0.2
wt%用い、70゜Cで96時間重合させて、光散乱導
光体を得ることが出来る。Debyeの関係式を使って
相関距離aと誘電率ゆらぎ2乗平均τを計算した結果、
相関距離a=720オングストローム、誘電率ゆらぎ2
乗平均τ=0.00000122という値を得た(aや
τの意味については、作用の説明の欄参照)。
[3] Add 3FMA polymer to MMA.
A solution prepared by dissolving 15 wt% and a solution prepared by dissolving 0.1 wt% were prepared, each containing 0.2 wt% of t-butyl peroxyisopropyl carbonate as a radical polymerization initiator and 0.2 wt% of n-butyl mercaptan as a chain transfer agent.
%, Polymerized at 70 ° C. for 72 hours, and then heat-treated at 130 ° C. for 24 hours to produce a light-scattering light guide. [4] MMA and vinyl benzoate (VB) were copolymerized at a ratio of 4: 1. 0.2 wt% of tertiary butyl peroxide (DBPO) as a polymerization initiator
%, 0.2% of n-butyl mercaptan as a chain transfer agent
The light scattering light guide can be obtained by polymerizing at 70 ° C. for 96 hours using wt%. As a result of calculating the correlation distance a and the dielectric constant fluctuation root mean square τ using the Debye relational expression,
Correlation distance a = 720 angstroms, dielectric constant fluctuation 2
A value of root mean τ = 0.00000122 was obtained (for the meaning of a and τ, see the column of action description).

【0042】[5]分子量47500のポリスチレンポ
リマーをMMAに0.2wt%溶解し、ラジカル重合開
始剤としてt―ブチルパーオキシイソプロピルカーボネ
ート0.2wt%、連鎖移動剤として、n―ブチルメル
カプタンを0.2wt%加え、70゜Cで96時間重合
させて光散乱導光体を製造することが出来る。
[5] A polystyrene polymer having a molecular weight of 47,500 was dissolved in MMA in an amount of 0.2 wt%, 0.2 wt% of t-butyl peroxyisopropyl carbonate was used as a radical polymerization initiator, and 0.1 wt% of n-butyl mercaptan was used as a chain transfer agent. By adding 2 wt% and polymerizing at 70 ° C. for 96 hours, a light-scattering light guide can be manufactured.

【0043】[6]MMAに3FMAのポリマーを0.
1wt%溶解し、ラジカル重合開始剤としてt―ブチル
パーオキシイソプロピルカーボネート0.2wt%、連
鎖移動剤として、n―ブチルメルカプタンを0.2wt
%加え、70゜Cで72時間重合した後、130゜Cで
24時間熱処理を行い、光散乱導光体を製造することが
出来る。
[6] Add 3FMA polymer to MMA.
1 wt% dissolved, 0.2 wt% of t-butyl peroxyisopropyl carbonate as a radical polymerization initiator, 0.2 wt% of n-butyl mercaptan as a chain transfer agent
%, Polymerized at 70 ° C. for 72 hours, and then heat-treated at 130 ° C. for 24 hours to produce a light-scattering light guide.

【0044】[7]MMAに3FMAのポリマーを0.
1wt%溶解し、ラジカル重合開始剤としてt―ブチル
パーオキシイソプロピルカーボネート0.2wt%、連
鎖移動剤として、n―ブチルメルカプタンを0.2wt
%加え、70゜Cで72時間重合した後、130゜Cで
24時間熱処理を行い、光散乱導光体を製造することが
出来る。 [8]MMAに、ラジカル重合開始剤としてt―ブチル
パーオキシイソプロピルカーボネート0.2wt%、連
鎖移動剤として、n―ブチルメルカプタンを0.2wt
%加え、60゜C(ガラス転移温度以下)で240時間
にわたって重合反応を行わせた。残存しているモノマー
は、高転化率が実現した段階で固化したPMMAマトリ
ックス中にトラップされているが、このモノマーは長時
間の加熱により重合する。ここでモノマーからポリマー
へ変化する際に生じる体積変化(収縮)により、無数の
マイクロボイドが生成し、これが光散乱をもたらす屈折
率不均一構造としての機能を果たす。
[7] MMA with 3FMA polymer
1 wt% dissolved, 0.2 wt% of t-butyl peroxyisopropyl carbonate as a radical polymerization initiator, 0.2 wt% of n-butyl mercaptan as a chain transfer agent
%, Polymerized at 70 ° C. for 72 hours, and then heat-treated at 130 ° C. for 24 hours to produce a light-scattering light guide. [8] In MMA, 0.2 wt% of t-butyl peroxyisopropyl carbonate as a radical polymerization initiator and 0.2 wt% of n-butyl mercaptan as a chain transfer agent
%, And the polymerization reaction was carried out at 60 ° C. (below the glass transition temperature) for 240 hours. The remaining monomer is trapped in the solidified PMMA matrix at the stage where the high conversion has been achieved, but this monomer is polymerized by prolonged heating. Here, the volume change (shrinkage) that occurs when changing from a monomer to a polymer generates innumerable microvoids, which function as a non-uniform refractive index structure that causes light scattering.

【0045】このようなプロセスで得られた光散乱導光
体サンプルについて、Vv 散乱強度の角度依存性を測定
し、Debyeの関係式に基づいて相関距離aを計算し
たところ、850オングストロームという値が得られ
た。また、誘電率ゆらぎ2乗平均τの値はτ=0.00
000011、有効散乱照射パラメータEについてはE
=0.17[cm-1]という値であった(有効散乱照射パ
ラメータEの意味については、作用の説明の欄参照)。
For the light-scattering light guide sample obtained by such a process, the angle dependency of the Vv scattering intensity was measured, and the correlation distance a was calculated based on the Debye's relational expression. As a result, a value of 850 Å was obtained. Obtained. The value of the mean square τ of the dielectric constant fluctuation is τ = 0.00
000011, the effective scattering irradiation parameter E is
= 0.17 [cm -1 ] (for the meaning of the effective scattering irradiation parameter E, refer to the column of action description).

【0046】(3)の型の材料について;この型の材料
は、本発明者に係る前述の散乱光出射方向修正手段に関
する提案を含む日本国特許出願(出願日;平成4年11
月27日)の明細書中に、散乱光出射方向修正手段と同
時に開示されているものである。2種類以上のポリマー
材料を混合加熱して、練り合わす混練工程は、ポリマー
ブレンドと言うべき工程であるが、この混練されるポリ
マー材料の組合せに屈折率が実質的に異なる(典型的に
は、屈折率差0.001以上)ものを選択して、射出成
形、押し出し成形等の公知の成形工程を組み合わせれば
均一な散乱能を有する任意形状の光散乱導光体を得るこ
とが出来るという知見に基づいて製造される材料であ
る。
Regarding the material of the type (3), this type of material is disclosed in Japanese Patent Application (Filing date;
27) is disclosed together with the means for correcting the scattered light emission direction. The kneading step of mixing and heating two or more types of polymer materials and kneading them is a process called a polymer blend, and the refractive index differs substantially depending on the combination of the kneaded polymer materials (typically, (A refractive index difference of 0.001 or more) is selected, and a known light-scattering light guide having a uniform scattering ability can be obtained by combining known molding steps such as injection molding and extrusion molding. It is a material manufactured based on.

【0047】即ち、2種類以上の屈折率の相互に異なる
ポリマー材料(任意形状で良い。工業的には、例えばペ
レット状のものが考えられる。)を混合加熱して、練り
合わす(混練工程)。そして、混練された液状材料を射
出成形機の金型内に高圧で射出注入し、冷却固化するこ
とによって成形された光散乱導光体を金型から取り出せ
ば金型形状に対応した形状の光散乱導光体を得ることが
出来る。混練された2種類以上のポリマーは完全には混
ざり合うことなく固化するので、それらの局所的濃度に
不均一(ゆらぎ)が生まれて固定される。従って、混練
されるポリマー同士に実質的な屈折率差があれば、屈折
率不均一構造を有する光散乱導光体が製造されることに
なる。
That is, two or more types of polymer materials having different refractive indices mutually different (arbitrary shape may be used, and industrially, for example, pellets are considered), and heated and kneaded (kneading step). . Then, the kneaded liquid material is injected and injected into the mold of the injection molding machine at a high pressure, and the light-scattering light guide formed by cooling and solidifying is taken out of the mold to obtain a light having a shape corresponding to the shape of the mold. A scattering light guide can be obtained. Since the kneaded two or more kinds of polymers solidify without being completely mixed, unevenness (fluctuation) is generated in their local concentration and fixed. Therefore, if there is a substantial difference in refractive index between the polymers to be kneaded, a light-scattering light guide having a non-uniform refractive index structure is manufactured.

【0048】また、混練された材料を押し出し成形機の
シリンダー内に注入し、通常のやり方で押し出せば目的
とする成形物を得ることが出来る。
The kneaded material is poured into a cylinder of an extruder and extruded in a usual manner to obtain a desired molded product.

【0049】これらポリマーブレンドの組合せや混合割
合、及び成形工程については、非常に幅広い選択が可能
であり、屈折率差、成形プロセスで生成される屈折率不
均一構造の強さや性質(有効散乱照射パラメータE、相
関距離a、誘電率ゆらぎ2乗平均τで記述される。)、
最終製品の形状や大きさ等を考慮して決定すれば良い。
A wide variety of combinations and mixing ratios of these polymer blends and the molding step can be selected, and the refractive index difference, the strength and properties of the non-uniform refractive index structure generated in the molding process (effective scattering irradiation) It is described by a parameter E, a correlation distance a, and a dielectric constant fluctuation root mean square τ).
What is necessary is just to determine in consideration of the shape, size, etc. of a final product.

【0050】使用し得るポリマー材料の代表的なものを
表1及び表2に挙げる。これらの材料は、あくまで例示
であり、本発明における光散乱導光体に使用される材料
を限定する趣旨のものではない。
Representative polymer materials which can be used are listed in Tables 1 and 2. These materials are merely examples, and are not intended to limit the materials used in the light-scattering light guide of the present invention.

【0051】[0051]

【表1】 [Table 1]

【0052】[0052]

【表2】 [Table 2]

【0053】このポリマーブレンドによる方法による材
料製造方法の、より具体的な実例の幾つかを以下に示
す。
Some more specific examples of the method for producing a material by the polymer blend method are shown below.

【0054】<例1>メタクリル樹脂のペレット(旭化
成製、デルベット80N)に粒径0.3μmのシリコン
系樹脂粉体(東芝シリコン製、トスパール103)を
0.25wt%添加し、ミキサーで混合分散させた後、
押し出し機でストランド状に押し出し、ペレタイザーで
ペレット化することにより、シリコン系樹脂粉体が均一
に分散されたペレットを調製した。
Example 1 0.25% by weight of a silicon resin powder (Tospearl 103, manufactured by Toshiba Silicon) having a particle size of 0.3 μm was added to methacrylic resin pellets (Delvet 80N, manufactured by Asahi Kasei Corporation) and mixed and dispersed by a mixer. After letting
Extruders were extruded into strands using an extruder, and pelletized with a pelletizer to prepare pellets in which silicon-based resin powder was uniformly dispersed.

【0055】このペレットを射出成形機を用い、シリン
ダー温度230゜C〜260゜C、型温度50゜Cの条
件で成形して、縦56mm、横75mm、厚さ4.7m
mの板状光散乱導光体を得た。
The pellets are molded using an injection molding machine under the conditions of a cylinder temperature of 230 ° C. to 260 ° C. and a mold temperature of 50 ° C., and are 56 mm long, 75 mm wide and 4.7 m thick.
Thus, a plate-shaped light scattering light guide of m was obtained.

【0056】<例2>メタクリル樹脂のペレット(旭化
成製、デルベット80N)に粒径0.8μmのシリコン
系樹脂粉体(東芝シリコン製、トスパール108)を
0.3wt%添加し、ミキサーで混合分散させた後、押
し出し機でストランド状に押し出し、ペレタイザーでペ
レット化することにより、シリコン系樹脂粉体が均一に
分散されたペレットを調製した。
Example 2 0.3 wt% of a silicon resin powder (Tospearl 108, manufactured by Toshiba Silicon) having a particle size of 0.8 μm was added to methacrylic resin pellets (Delvet 80N, manufactured by Asahi Kasei Corporation) and mixed and dispersed by a mixer. After that, the mixture was extruded into a strand with an extruder, and pelletized with a pelletizer to prepare a pellet in which silicon-based resin powder was uniformly dispersed.

【0057】このペレットを射出成形機を用い、シリン
ダー温度230゜C〜260゜C、型温度50゜Cの条
件で成形して、縦56mm、横75mm、厚さ4.5m
mの板状光散乱導光体を得た。
The pellets were molded using an injection molding machine under the conditions of a cylinder temperature of 230 ° C. to 260 ° C. and a mold temperature of 50 ° C., and were 56 mm long, 75 mm wide and 4.5 m thick.
Thus, a plate-shaped light scattering light guide of m was obtained.

【0058】<例3>メタクリル樹脂のペレット(旭化
成製、デルベット80N)に粒径3μmのシリコン系樹
脂粉体(東芝シリコン製、トスパール130)を0.3
5wt%添加し、ミキサーで混合分散させた後、押し出
し機でストランド状に押し出し、ペレタイザーでペレッ
ト化することにより、シリコン系樹脂粉体が均一に分散
されたペレットを調製した。
<Example 3> A methacrylic resin pellet (Delvet 80N, manufactured by Asahi Kasei Corporation) was mixed with 0.3 μm of silicon resin powder (Tospearl 130, manufactured by Toshiba Silicon) having a particle size of 0.3 μm.
After adding 5 wt% and mixing and dispersing with a mixer, the mixture was extruded into a strand with an extruder, and pelletized with a pelletizer, thereby preparing pellets in which the silicon-based resin powder was uniformly dispersed.

【0059】このペレットを射出成形機を用い、シリン
ダー温度230゜C〜260゜C、型温度50゜Cの条
件で成形して、縦56mm、横75mm、厚さ4.6m
mの板状光散乱導光体を得た。
The pellets are molded using an injection molding machine under the conditions of a cylinder temperature of 230 ° C. to 260 ° C. and a mold temperature of 50 ° C., and are 56 mm long, 75 mm wide and 4.6 m thick.
Thus, a plate-shaped light scattering light guide of m was obtained.

【0060】<例4>80mlの水に、2.2gの過酸
化ベンゾイル、12mlのクロルデカン、10mlのジ
クロルエタン及び0.25gのNa―ラウリルサルフェ
ートをホモゲナイザーを用いて乳化し、直径0.1μm
〜0.2μmのエマルジョンを調製した。このエマルジ
ョンを粒径0.55μm、濃度8.5wt%の単分散ポ
リスチレンのシードラテックス90mlに添加した。更
に、20mlの水、及び15mlのアセトンを35゜C
〜40゜Cで添加し、40゜Cで12時間にわたって撹
はんした後、アセトン及びジクロルエタンを真空蒸留に
より除去した。
Example 4 2.2 g of benzoyl peroxide, 12 ml of chlordecane, 10 ml of dichloroethane and 0.25 g of Na-lauryl sulfate were emulsified in 80 ml of water using a homogenizer, and the diameter was 0.1 μm.
An emulsion of 0.20.2 μm was prepared. This emulsion was added to 90 ml of monodispersed polystyrene seed latex having a particle size of 0.55 μm and a concentration of 8.5 wt%. Further, add 20 ml of water and 15 ml of acetone at 35 ° C.
After addition at ゜ 40 ° C. and stirring at 40 ° C. for 12 hours, acetone and dichloroethane were removed by vacuum distillation.

【0061】次に、1.2gのNa―ラウリルサルフェ
ートを添加した後、水で希釈して全体で1.2リットル
とした。そして、スチレン65g、メタクリル酸メチル
171g、ブチルアクリレート45g、及びトリメチロ
ールプロパントリアクリレート9gを30゜Cで撹はん
しながら添加した後、更に、30゜Cで15時間にわた
って撹はんした。その後、60゜Cに温度を上げて重合
反応を開始させ、25時間反応を持続させ、平均粒径
2.8μm、屈折率1.502の有機架橋粒子材料を得
た。
Next, after adding 1.2 g of Na-lauryl sulfate, the mixture was diluted with water to make a total of 1.2 liters. Then, 65 g of styrene, 171 g of methyl methacrylate, 45 g of butyl acrylate, and 9 g of trimethylolpropane triacrylate were added with stirring at 30 ° C., and the mixture was further stirred at 30 ° C. for 15 hours. Thereafter, the temperature was raised to 60 ° C. to start the polymerization reaction, and the reaction was continued for 25 hours to obtain an organic crosslinked particle material having an average particle size of 2.8 μm and a refractive index of 1.502.

【0062】メチルメタクリレート(MMA)とトリフ
ルオロエチルメタクリレート(3FMA)の組成比1対
1の共重合体1kgに、上記粒子材料を0.5wt%添
加し、ミキサーで十分混練した後、直径20mmのノズ
ルより押し出した。これを長さ50mmとして、両端を
切削研磨して、円筒状の光散乱導光体を得た。
To 1 kg of a copolymer of methyl methacrylate (MMA) and trifluoroethyl methacrylate (3FMA) having a composition ratio of 1 to 1 was added 0.5 wt% of the above-mentioned particle material, and the mixture was sufficiently kneaded with a mixer. Extruded from the nozzle. This was set to a length of 50 mm, and both ends were cut and polished to obtain a cylindrical light-scattering light guide.

【0063】得られた光散乱導光体について、Deby
eの関係式を使って相関距離aと誘電率のゆらぎ2乗平
均τを計算したところ、相関距離a=1.87μm、誘
電率のゆらぎ2乗平均τ=0.0000808という結
果を得た。また、前記式(10)を用いて、有効散乱照
射パラメータEの値を求めた結果は、E=44.03
[cm-1]であった。
With respect to the obtained light scattering light guide, Deby
When the correlation distance a and the mean square τ of the fluctuation of the permittivity were calculated using the relational expression of e, the result was obtained that the correlation distance a = 1.87 μm and the mean square τ of the fluctuation of the permittivity = 0.00000808. Further, the result of obtaining the value of the effective scattering irradiation parameter E using the above equation (10) is E = 44.03.
[Cm -1 ].

【0064】<例5>ラウリル硫酸ナトリウム3gを溶
解させたイオン交換水350gに、スチレン32g及び
メチルメタクルレート108gを分散させた後、これを
撹はんしながら、窒素気流の下で70゜Cに昇温させ、
次いで過硫酸カリウム0.15gを溶解させたイオン交
換水25gを加え、70゜Cに8時間保持して初期シー
ド粒子を得た。このシード粒子の粒径は、0.04μm
であった。
Example 5 After dispersing 32 g of styrene and 108 g of methyl methacrylate in 350 g of ion-exchanged water in which 3 g of sodium lauryl sulfate was dissolved, the mixture was stirred at 70 ° C. under a nitrogen stream. Raise the temperature to C,
Next, 25 g of ion-exchanged water in which 0.15 g of potassium persulfate was dissolved was added, and kept at 70 ° C. for 8 hours to obtain initial seed particles. The particle size of the seed particles is 0.04 μm
Met.

【0065】次に、得られた初期シード粒子の水分散液
50gと、イオン交換水325gを混合して70゜Cに
昇温した後、スチレン33g、メチルメタクリレート8
2g及びブチルアクリレート25gを加えて1時間撹は
んし、次いで過硫酸カリウム0.15gを溶解させたイ
オン交換水25gを加え、8時間経過させて粒径0.1
28μmの2次シード粒子水分散液を得た。
Next, after mixing 50 g of the obtained aqueous dispersion of the initial seed particles and 325 g of ion-exchanged water and raising the temperature to 70 ° C., 33 g of styrene and methyl methacrylate 8 were added.
2 g and 25 g of butyl acrylate were added and stirred for 1 hour. Then, 25 g of ion-exchanged water in which 0.15 g of potassium persulfate was dissolved was added.
An aqueous dispersion of 28 μm secondary seed particles was obtained.

【0066】そして更に、上述の方法にならって、粒径
0.128μmの2次シード粒子から粒径0.312μ
mの3次シード粒子を作り、この粒径0.312μmの
3次シード粒子から粒径0.653μmの4次シード粒
子を作るというプロセスを繰り返した。
Further, according to the above-described method, the secondary seed particles having a particle size of 0.128 μm are converted to a particle size of 0.312 μm.
m, and the process of forming quaternary seed particles having a particle size of 0.653 μm from the tertiary seed particles having a particle size of 0.312 μm was repeated.

【0067】こうして得られた4次シード粒子を含む調
製液100gに、イオン交換水1000gとポリビニル
アルコール(ケン化度88%)の10wt%水溶液10
0gを加えて均一に撹はんした上で、スチレン28g、
メチルメタクリレート70g及びブチルアクリレート2
1g、ジビニルベンゼン0.5g、過酸化ベンゾイル1
g、及びラウリル硫酸ナトリウム0.08gをイオン交
換水1500gに混合して超音波処理によって乳化液と
したものを添加し、撹はんしながら窒素気流の下で9時
間にわたって重合反応を行わせ、低架橋微粒子の水分散
液を得た。この微粒子の粒径は、1.12μmであっ
た。
To 100 g of the prepared solution containing the quaternary seed particles thus obtained, 1000 g of ion-exchanged water and 10 wt% aqueous solution of polyvinyl alcohol (saponification degree 88%) were added.
After adding 0 g and stirring uniformly, styrene 28 g,
70 g of methyl methacrylate and butyl acrylate 2
1 g, divinylbenzene 0.5 g, benzoyl peroxide 1
g, and 0.08 g of sodium lauryl sulfate were mixed with 1500 g of ion-exchanged water to obtain an emulsion by sonication, and the polymerization reaction was carried out for 9 hours under a nitrogen stream while stirring. An aqueous dispersion of low crosslinked fine particles was obtained. The particle size of the fine particles was 1.12 μm.

【0068】次に、この低架橋微粒子を10wt%含む
水分散液300gにイオン交換水1500gと前記と同
じポリビニルアルコール水溶液15gを加えて均一に撹
はんし、トリメチロールプロパントリアクリレート50
gにイオン交換水1200gとラウリル硫酸ナトリウム
0.045gとアセトン300gを混合してこれを超音
波処理により乳化液として加え、室温下で24時間撹は
んし、低架橋微粒子中にトリメチロールプロパントリア
クリレートを完全に吸収させた。
Next, 1500 g of ion-exchanged water and 15 g of the same aqueous polyvinyl alcohol solution as described above were added to 300 g of an aqueous dispersion containing 10% by weight of the low crosslinked fine particles, and the mixture was stirred uniformly, and trimethylolpropane triacrylate 50 g was added.
g, ion-exchanged water (1200 g), sodium lauryl sulfate (0.045 g) and acetone (300 g) were mixed, and the mixture was added as an emulsified solution by ultrasonication. The mixture was stirred at room temperature for 24 hours to give trimethylolpropanetriene in the low-crosslinked fine particles. The acrylate was completely absorbed.

【0069】次に、アセトンをエバポレータを用いて除
去し、得られた膨潤粒子を含む分散液に、スチレン58
g、メチルメタクリレート164g及びブチルアクリレ
ート45g、ジビニルベンゼン25g、過酸化ベンゾイ
ル5gからなる混合物を溶解させ、これにイオン交換水
12gとラウリル硫酸ナトリウム0.2gを混合し超音
波処理で乳化液としたものを加え、撹はんしながら窒素
気流下60゜Cで2時間、続いて80゜Cに昇温して6
時間重合させ、均一な径を有する微粒子材料を得た。こ
の微粒子は、屈折率1.502、平均粒径2.61μ
m、粒径分布の標準偏差は、0.26μmであった。
Next, acetone was removed using an evaporator, and styrene 58 was added to the resulting dispersion containing swollen particles.
g, 164 g of methyl methacrylate, 45 g of butyl acrylate, 25 g of divinylbenzene, and 5 g of benzoyl peroxide were dissolved, and 12 g of ion-exchanged water and 0.2 g of sodium lauryl sulfate were mixed to obtain an emulsion by ultrasonic treatment. While stirring and at a temperature of 60 ° C. for 2 hours under a nitrogen stream, and then raising the temperature to 80 ° C.
Polymerization was performed for a period of time to obtain a fine particle material having a uniform diameter. These fine particles have a refractive index of 1.502 and an average particle size of 2.61 μm.
m, the standard deviation of the particle size distribution was 0.26 μm.

【0070】メチルメタクリレート(MMA)とトリフ
ルオロエチルメタクリレート(3FMA)の組成比1対
1の共重合体1kgに、上記粒子材料を0.5wt%添
加し、ミキサーで十分混練した後、直径20mmのノズ
ルより押し出した。これを長さ50mmとして、両端を
切削研磨して、円筒状の光散乱導光体を得た。
The above-mentioned particle material was added to 1 kg of a copolymer of methyl methacrylate (MMA) and trifluoroethyl methacrylate (3FMA) having a composition ratio of 1: 1 by 0.5 wt%, and the mixture was sufficiently kneaded with a mixer. Extruded from the nozzle. This was set to a length of 50 mm, and both ends were cut and polished to obtain a cylindrical light-scattering light guide.

【0071】獲られた光散乱導光体について、Deby
eの関係式を使って相関距離aと誘電率のゆらぎ2乗平
均τを計算したところ、相関距離a=1.75μm、誘
電率のゆらぎ2乗平均τ=0.0000808という結
果を得た。また、前記式(10)を用いて、有効散乱照
射パラメータEの値を求めた結果は、E=41.16
[cm-1]であった。
For the captured light scattering light guide, Deby
Calculation of the correlation distance a and the fluctuation mean square τ of the dielectric constant using the relational expression of e yielded the result that the correlation distance a = 1.75 μm and the fluctuation mean square τ of the dielectric constant = 0.00000808. Further, the result of obtaining the value of the effective scattering irradiation parameter E using the above equation (10) is E = 41.16.
[Cm -1 ].

【0072】<例6>ポリメチルメタクリレート(PM
MA)にポリスチレン(PSt)を0.5wt%添加
し、V型タンブラーを用いて10分間、次いでヘンシェ
ルミキサーを用いて5分間混合した。これを径30mm
の2軸押し出し機[ナカタニ機械(株)製]を使って、
シリンダー温度220゜C〜250゜C、スクリュー回
転数75rpm、吐出量6kg/hrの条件で融解混合
してペレットを作成した。
Example 6 Polymethyl methacrylate (PM
MA), 0.5 wt% of polystyrene (PSt) was added, and mixed for 10 minutes using a V-type tumbler and then for 5 minutes using a Henschel mixer. This is 30mm in diameter
Using a twin-screw extruder [manufactured by Nakatani Machinery Co., Ltd.]
The pellets were prepared by melting and mixing at a cylinder temperature of 220 ° C. to 250 ° C., a screw rotation speed of 75 rpm, and a discharge rate of 6 kg / hr.

【0073】このペレットを射出成形機を用い、シリン
ダー温度220゜C〜250゜C、型温度65゜C、射
出速度中速、射出圧力ショートショット圧プラス10k
g/cm2 の条件で成形して、縦横35mm、厚さ4.
5mmの板状光散乱導光体を得た。
Using an injection molding machine, the pellets were subjected to a cylinder temperature of 220 ° C. to 250 ° C., a mold temperature of 65 ° C., a medium injection speed, an injection pressure short shot pressure plus 10 k.
g / cm 2 , molded 35 mm in width and 35 mm in thickness.
A 5 mm plate-like light scattering light guide was obtained.

【0074】本発明の光散乱導光体及び光散乱導光光源
装置について、その作用を中心に、更に詳しく説明す
る。先ず、図2〜図5を参照して、各請求項に記載され
た構成の作用を説明する。
The light-scattering light guide and the light-scattering light-guiding light source device of the present invention will be described in more detail, focusing on their functions. First, the operation of the configuration described in each claim will be described with reference to FIGS.

【0075】図2、図3は、各々散乱出射光取出表面領
域側に散乱出射光強度角度特性調整凹凸領域を形成した
場合と、前記散乱出射光取出表面領域と相反する方向
に、外部の反射要素に対向した散乱出射光強度角度特性
調整凹凸領域を形成した場合の典型的な配置を表してい
る。
FIGS. 2 and 3 show the case where the scattered / emitted light intensity / angle characteristic adjusting irregularities are formed on the side of the scattered / emitted light extraction surface and the case where the external reflection is opposite to the scattered / emission light extraction surface. This shows a typical arrangement in the case where a scattered emission light intensity angle characteristic adjustment uneven region facing an element is formed.

【0076】図2の配置においては、光散乱導光体1の
散乱出射光取出表面領域が散乱出射光強度の角度特性を
調整する凹凸領域2を形成しており、側方に棒状光源要
素(例えば、蛍光灯)5が置かれている。光散乱導光体
の散乱光取出面と反対側には、光散乱導光体1とは別の
素材からなる反射フィルム4が配置されている。
In the arrangement shown in FIG. 2, the scattered / emitted light extraction surface area of the light scattering / guiding member 1 forms an uneven area 2 for adjusting the angle characteristic of the scattered / emitted light intensity, and a rod-shaped light source element ( For example, a fluorescent lamp) 5 is placed. A reflection film 4 made of a material different from the light scattering light guide 1 is disposed on the opposite side of the light scattering light guide from the scattered light extraction surface.

【0077】棒状光源5から光散乱導光体1へ入射した
光は、光散乱導光体1内部で散乱しながら導光される。
光散乱導光体1の反射フィルム4側に出た光の多くの部
分は、直ちに反射フィルム4で反射されて光散乱導光体
1に戻る。液晶表示装置のバックライト光等として利用
される光は、散乱出射光取出領域側から出射する光であ
るが、その光強度の方向特性が凹凸領域2によって調整
される。dは、列状に形成された凹凸のピッチを表して
いる。
Light incident on the light scattering guide 1 from the rod-shaped light source 5 is guided while being scattered inside the light scattering guide 1.
Most of the light emitted from the light scattering light guide 1 toward the reflection film 4 is immediately reflected by the reflection film 4 and returns to the light scattering light guide 1. The light used as the backlight light or the like of the liquid crystal display device is light emitted from the scattered emission light extraction region side, and the directional characteristic of the light intensity is adjusted by the uneven region 2. d represents the pitch of the unevenness formed in a row.

【0078】図4は、光散乱導光体1の凹凸領域2から
の出射の前後の光線の何本かを例示的に描いたものであ
る。光散乱導光体1の屈折率をn、外部(通常は空気)
3の屈折率をn0 (ほぼ1に等しい)とすれば、n0 <
nが成立するから、図示したように、出射光は光散乱導
光体に再接近しようとする方向に屈曲する(P1 →Q1
、P2 →Q2 参照)また、場所と角度によっては、光
散乱導光体1の表面に再度入射し、一部は反射し(P3
→Q3 )、一部は光散乱導光体1内部に戻る(P3 →Q
3´)。
FIG. 4 exemplarily shows some light beams before and after emission from the uneven region 2 of the light scattering guide 1. FIG. The refractive index of the light-scattering light guide 1 is n, external (usually air)
Assuming that the refractive index of 3 is n0 (substantially equal to 1), n0 <
Since n holds, as shown in the figure, the emitted light is bent in a direction in which the light tends to approach the light-scattering light guide again (P1 → Q1).
, P2 → Q2) Depending on the location and angle, the light again enters the surface of the light scattering / guiding member 1 and is partially reflected (P3
→ Q3), a part returns to the inside of the light scattering guide 1 (P3 → Q3).
3´).

【0079】更に、凹凸領域2の表面に垂直な方向に出
射した光はそのまま直進することになる(P4 →Q4
)。このように、散乱出射光の方向修正は複雑に種々
の方向に向けて起こり得るが、プリズム状凹凸要素2の
頂角α及び残りの角β及びγを選ぶことで修正方向を制
御することが出来る。即ち、凹凸領域が無いと仮定した
場合の出射光強度の角度特性を考慮して、α、β、γの
値を種々選択することによって、極めて多様な角度特性
を得ることが出来る。1つの傾向として明らかなのは、
相当広範囲の頂角αについて、βとγをほぼ同じ値にし
てみると、図上で左右方向に寝た角度で出射しようとす
る光を上方へ向けて修正する作用が期待出来るというこ
とである。
Further, the light emitted in the direction perpendicular to the surface of the uneven area 2 goes straight as it is (P4 → Q4).
). As described above, the direction correction of the scattered emission light can occur in various directions in a complicated manner, but the correction direction can be controlled by selecting the apex angle α and the remaining angles β and γ of the prismatic uneven element 2. I can do it. That is, extremely various angle characteristics can be obtained by variously selecting the values of α, β, and γ in consideration of the angle characteristics of the emitted light intensity when there is no uneven region. One obvious trend is that
If β and γ are set to almost the same value for a wide range of apex angles α, it is expected that an effect of upwardly correcting light that is going to be emitted at an angle lying left and right in the figure can be expected. .

【0080】例えば、光散乱導光体1内光の進行方向が
等方的である場合に、αを80゜程度にとり、β=γ=
約50゜とすると、図中真上方向から見た明るさを増大
させる作用が期待出来る(後述の実施例参照)。また、
光散乱導光体1内光の進行方向の分布が非等方的である
場合に、その性質とα、β、γ相互間の大小関係、屈折
率nの大きさ等を組み合わせれば、より自由度の大きな
選択が可能である。例えば、正面方向よりもむしろやや
前方方向に偏った散乱光分布などが実現可能である。
For example, when the traveling direction of the light in the light-scattering light guide 1 is isotropic, α is set to about 80 °, and β = γ =
When the angle is set to about 50 °, an effect of increasing the brightness as viewed from directly above in the drawing can be expected (see the embodiment described later). Also,
When the distribution of the light in the light-scattering light guide 1 in the traveling direction is anisotropic, if that property is combined with the magnitude relationship between α, β, and γ, the magnitude of the refractive index n, etc. Selection with a large degree of freedom is possible. For example, a scattered light distribution slightly biased forward rather than frontward can be realized.

【0081】個々のケースについて、α、β、γの具体
的な数値を理論的アプローチのみによって決定すること
は現実的ではなく、例えば、使用する光散乱導光体の散
乱特性を調査した上で、実験的手法を混じえてこれら値
を選択するのが好ましいと考えられる。
For each case, it is not realistic to determine specific numerical values of α, β, and γ only by a theoretical approach. For example, after investigating the scattering characteristics of the light scattering light guide used. It is considered preferable to select these values by mixing experimental methods.

【0082】図3及び図5は、光散乱導光体1の散乱出
射光取出表面領域と相反する方向に散乱出射光強度の角
度特性を調整する凹凸領域2を形成した場合の配置と光
の進行の様子を示したものである。側方に置かれた棒状
光源要素(例えば、蛍光灯)5から光散乱導光体1に入
射した光は、図2、図4の場合と同様に内部で散乱しな
がら導光される。光散乱導光体1の反射フィルム4側に
出射しようとする光は、そこに形成されている凹凸領域
2の作用によって、光散乱導光体1に再接近する方向に
屈曲された後で反射フィルム4により反射される。反射
光の一部が光散乱導光体1表面で再反射され残りが光散
乱導光体1内部に戻される。個々の光線の経路は図4の
場合よりも一層複雑である(P5 →Q5 、P5 →Q5
´、P6 →Q6´、P7 →Q7 参照)。
FIG. 3 and FIG. 5 show the arrangement and the light distribution when the uneven region 2 for adjusting the angle characteristic of the scattered light intensity in the direction opposite to the scattered light extraction surface region of the light scattering light guide 1 is formed. It shows the state of progress. Light incident on the light-scattering light guide 1 from a rod-like light source element (for example, a fluorescent lamp) 5 placed on the side is guided while being scattered inside similarly to the case of FIGS. Light to be emitted to the reflection film 4 side of the light-scattering light guide 1 is reflected after being bent in a direction approaching the light-scattering light guide 1 by the action of the uneven region 2 formed therein. The light is reflected by the film 4. A part of the reflected light is re-reflected on the surface of the light-scattering light guide 1 and the rest is returned to the inside of the light-scattering light guide 1. The paths of the individual rays are more complicated than in FIG. 4 (P5 → Q5, P5 → Q5).
', P6 → Q6', P7 → Q7).

【0083】従って、最終的なα、β、γの値は、図
2、図4の場合と同じく、光散乱導光体1の散乱特性、
屈折率等を考慮し、実験的手法を取り入れた検討をした
上で選択・決定することにより、希望する散乱出射光強
度の角度分布を実現することが好ましい。
Accordingly, the final values of α, β and γ are the same as those in FIGS.
It is preferable to realize the desired angular distribution of the intensity of the scattered emitted light by selecting and determining after examining an experimental method in consideration of the refractive index and the like.

【0084】尚、凹凸のピッチdについては特に制限は
無いが、光の波長のオーダーに接近する程微細な場合に
は、回折に起因した着色現象が起こり、逆に余り大きい
と光散乱導光体全体をコンパクトで整った形に出来ず、
また、方向特性の修正機能にむらが生じるから、実際的
な範囲は数十分の1mm〜数mmの範囲であると考えら
れる。
The pitch d of the unevenness is not particularly limited. However, when the pitch is as small as approaching the order of the wavelength of light, a coloring phenomenon caused by diffraction occurs. The whole body could not be compact and well-formed,
Further, since the function of correcting the directional characteristics becomes uneven, the practical range is considered to be several ten minutes to several mm to several mm.

【0085】また、凹凸の形状について、図2〜図5で
は3角形断面の列状アレイの場合を説明したが、本発明
の技術思想に照らして、散乱出射光の方向を修正する作
用がある他の形状を採用することも全く差し支えない。
例えば、半円筒断面列状アレイ、半球状突起群の面状ア
レイ、3角錐状凹部群の面状アレイ等々、いずれの形状
のものを光散乱導光体表面領域に形成しても本発明の技
術思想に整合した光散乱導光体乃至光散乱導光光源装置
が構成され得ることは言うまでもない。
Further, as to the shape of the unevenness, FIGS. 2 to 5 show the case of a row array having a triangular cross section. However, in view of the technical idea of the present invention, there is an action of correcting the direction of the scattered emitted light. It is perfectly acceptable to adopt other shapes.
For example, any shape such as a semi-cylindrical sectional array, a planar array of hemispherical projections, and a planar array of triangular pyramidal recesses may be formed in the light scattering / guiding member surface area. It goes without saying that a light-scattering light guide or a light-scattering light-guiding light source device that matches the technical idea can be configured.

【0086】更に、光散乱導光体1の全体形状について
も、必ずしも直方体状乃至板状である必要はない。例え
ば、散乱光出射面が内側にゆるやかに湾曲した形状のも
のを組み合わせて全体を大面積の散乱導光光源とするこ
とが出来るし、全体をドーム状にし、後述する光源埋め
込み構造と組み合わせて、所望の方向特性を有する光源
装置を構成すること等が考えられる。また、光散乱導光
体を長尺状のものとして、強い出射方向の偏りを与えれ
ば、特定方向から見た時に明るく見える線状の散乱光光
源を得ることが出来る。これらいずれの形状のものも、
液晶表示装置等のバックライト光源に適用が可能な光散
乱導光体である。
Further, the entire shape of the light scattering / guiding member 1 does not necessarily have to be a rectangular parallelepiped or a plate. For example, the entire scattered light emitting surface can be made into a large-area scattered light guide light source by combining those having a shape that is gently curved inward, or the whole can be made into a dome shape, in combination with a light source embedded structure described later, It is conceivable to configure a light source device having desired directional characteristics. Further, if the light scattering light guide is elongated and a strong light emitting direction is biased, a linear scattered light source that looks bright when viewed from a specific direction can be obtained. Any of these shapes,
It is a light-scattering light guide applicable to a backlight light source such as a liquid crystal display device.

【0087】次に、請求項1〜請求項4において光散乱
導光体の散乱能を数値限定する為に使用されている有効
散乱照射パラメータEと相関距離aについて、Deby
eの理論を引用して説明する。
Next, the effective scattering irradiation parameter E and the correlation distance a used for limiting the scattering power of the light scattering light guide in the claims 1 to 4 will be described by Debye.
This will be described with reference to the theory of e.

【0088】強度I0 の光が媒体中をy(cm)透過し、そ
の間の散乱により強度がIに減衰した場合に、有効有効
散乱照射パラメータEを次式(1)または(2)で定義
する。
When the light of intensity I0 passes through the medium in y (cm) and the intensity is attenuated to I by scattering during the period, the effective effective scattering irradiation parameter E is defined by the following equation (1) or (2). .

【0089】[0089]

【数1】 (Equation 1)

【0090】式(1)、(2)は各々いわゆる積分形及
び微分形の表現であって、物理的な意味は等価である。
なお、このEは濁度と呼ばれることもある。
Equations (1) and (2) are so-called integral and differential expressions, respectively, and their physical meanings are equivalent.
In addition, this E may be called turbidity.

【0091】一方、媒体内に分布した不均一構造によっ
て光散乱が起こる場合の散乱光強度は、縦偏光の入射光
に対して出射光の大半が縦偏光である通常の場合(VV
散乱)には、次式(3)で表される。
On the other hand, the scattered light intensity in the case where light scattering occurs due to the non-uniform structure distributed in the medium is the normal case where most of the outgoing light is vertically polarized light with respect to vertically polarized incident light (VV
(Scattering) is represented by the following equation (3).

【0092】[0092]

【数2】 (Equation 2)

【0093】自然光を入射させた場合には、Hh 散乱を
考慮して、式(3)の右辺に(1+cos θ)を乗じた
次式を考えれば良いことが知られている。
It is known that when natural light is incident, the following equation in which the right side of equation (3) is multiplied by (1 + cos θ 2 ) in consideration of Hh scattering may be considered.

【0094】[0094]

【数3】 (Equation 3)

【0095】ここで、λ0 は入射光の波長、ν=(2π
n)/λ0 、s=2sin (θ/2)、nは媒体の屈折
率、θは散乱角、<η>は媒体中の誘電率ゆらぎ2乗
平均(以下、<η>=τとして、τを適宜使用す
る。)であり、γ(r)は相関関数と呼ばれるものであ
る。
Here, λ 0 is the wavelength of the incident light, and ν = (2π
n) / λ0, s = 2sin (θ / 2), n is the refractive index of the medium, theta is the scattering angle, <eta 2> is the dielectric constant fluctuation squares mean of the medium (hereinafter, the <η 2> = τ , Τ are used as appropriate.), And γ (r) is called a correlation function.

【0096】Debyeによると、媒体の屈折率不均一
構造が界面を持ってA相とB相に分かれて分散している
場合には、誘電率のゆらぎに関して相関関数γ(r)、
相関距離a、誘電率ゆらぎ2乗平均τ等が次のような関
係式で表される。
According to Debye, when the non-uniform refractive index structure of the medium is divided into an A phase and a B phase with an interface and dispersed, the correlation function γ (r),
The correlation distance a, the dielectric constant fluctuation root mean square τ, and the like are represented by the following relational expressions.

【0097】[0097]

【数4】 (Equation 4)

【0098】不均一構造が半径Rの球状界面で構成され
ているとみなせば、相関距離aは次式で表される。
Assuming that the non-uniform structure is constituted by a spherical interface having a radius R, the correlation distance a is expressed by the following equation.

【0099】[0099]

【数5】 (Equation 5)

【0100】相関関数γ(r)についての式(6)を用
い、式(5)に基づいて自然光を媒体に入射させた時の
有効散乱照射パラメータEを計算すると結果は次のよう
になる。
Using the equation (6) for the correlation function γ (r) and calculating the effective scattering irradiation parameter E when natural light is incident on the medium based on the equation (5), the result is as follows.

【0101】[0101]

【数6】 (Equation 6)

【0102】以上述べた関係から、相関距離a及び誘電
率ゆらぎ2乗平均τを変化させることにより、散乱光強
度、散乱光強度の角度依存性及び有効散乱照射パラメー
タEを制御することが可能であることが判る。散乱光強
度の角度依存性は、本発明の光散乱導光体を実際の照明
装置等に適用する場合に考慮され得る事項であることは
言うまでもない。
From the relationship described above, it is possible to control the scattered light intensity, the angle dependence of the scattered light intensity, and the effective scattered irradiation parameter E by changing the correlation distance a and the dielectric constant fluctuation mean square τ. It turns out there is. It goes without saying that the angle dependency of the scattered light intensity is a matter that can be considered when the light scattering guide of the present invention is applied to an actual lighting device or the like.

【0103】図1は、横軸に相関距離a、縦軸に誘電率
ゆらぎ2乗平均τをとって有効散乱照射パラメータEの
曲線をE=50[cm-1]及びE=100[cm-1]の場合
について例示したものである。
FIG. 1 shows the curves of the effective scattering irradiation parameter E with the correlation distance a on the horizontal axis and the root mean square τ of the dielectric constant fluctuation on the vertical axis, where E = 50 [cm −1 ] and E = 100 [cm −]. 1 ].

【0104】一般に、Eが大きければ散乱能が大きく、
Eが小さければ散乱能が小さい、換言すれば透明に近く
なる。E=0は全く散乱の無いことに対応する。
In general, the larger E is, the larger the scattering power is,
If E is small, the scattering power is small, in other words, it is almost transparent. E = 0 corresponds to no scattering at all.

【0105】従って、大面積の面状光源や長尺のファイ
バー状乃至棒状の均一照明光源等に本発明の光散乱導光
体を適用する場合にはEを小さく選べば良い。
Therefore, when applying the light-scattering light guide of the present invention to a large-area surface light source, a long fiber-like or rod-like uniform illumination light source, etc., it is sufficient to select a small value of E.

【0106】一応の目安としては、例えば、E=0.0
01[cm-1]程度とすれば、数十mの寸法のファイバー
状の光散乱導光体を均一に光らせることが出来る。図1
に示したE=100[cm-1]の程度にとれば、数mmの
範囲を集中的且つ均一に照明するのに適している。
As a rough guide, for example, E = 0.0
When it is about 01 [cm -1 ], a fiber-like light-scattering light guide having a size of several tens of meters can be uniformly illuminated. FIG.
Taking the degree of E = 100 [cm -1] shown in, it is suitable for intensive and uniform illumination of the range of a few mm.

【0107】また、図1のE=50[cm-1]のケースで
は、それらの中間的なサイズ(例えば、数cm〜数十c
m)の光散乱導光体を均一に光らせるのに好適なのが一
般的である。
In the case of E = 50 [cm -1 ] in FIG. 1, the intermediate size (for example, several cm to several tens c) is used.
It is generally suitable to make the light-scattering light guide of m) uniform.

【0108】但し、これら有効散乱照射パラメータEの
値はあくまで目安であり、具体的な適用装置の使用条
件、例えば1次光源の強さ、周辺に配置された光学要素
に依存する散乱光補強あるいは減衰ファクター等も考慮
して柔軟に選択されることが好ましく、光散乱の角度特
性が特殊な場合等には、E=1000あるいはそれ以上
の値を選択する場合もあり得る。
However, the values of the effective scattering irradiation parameter E are only for reference, and the scattered light reinforcement or the scattered light depending on the use conditions of the specific application device, for example, the intensity of the primary light source, the optical element arranged in the periphery, etc. It is preferable to flexibly select in consideration of the attenuation factor and the like. When the angular characteristics of light scattering are special, a value of E = 1000 or more may be selected.

【0109】相関距離aについては、一応0.005μ
m〜50μm程度が実際的と考えられるが、個々のケー
スについては、要求される角度特性等を考慮して定めら
れることが好ましい。
For the correlation distance a, once, 0.005 μm
Although it is considered that m to 50 μm is practical, it is preferable that each case is determined in consideration of required angle characteristics and the like.

【0110】散乱現象に対して以上のような取り扱いを
することによって、光散乱導光体に散乱特性を、有効散
乱照射パラメータE及び相関距離aの範囲を特定する形
で定めることが出来る。請求項1〜請求項4に記載した
光散乱特性に関する数値限定は、このような考えに基づ
いて、実際的に有用な可能性が高い範囲を特定したもの
である。
By treating the scattering phenomenon as described above, the scattering characteristics of the light-scattering light guide can be determined by specifying the range of the effective scattering irradiation parameter E and the correlation distance a. The numerical limitations on the light scattering characteristics described in claims 1 to 4 specify a range in which the possibility of practical use is high based on such an idea.

【0111】[0111]

【実施例】以下、本発明の構成を更に具体化した幾つか
の実施例について説明する。 <実施例1>MMA(メチルメタクリレート)にP3F
MA(トリフルオロエチルメタクリレートのポリマー)
を0.3wt%溶解し、ラジカル重合開始剤としてベン
ゾイルパーオキサイド(BPO)0.5wt%を使用
し、70゜Cで20時間注型重合させて縦56mm、横
75mm,厚さ4.8mmの板状(直方体形状)の光散
乱導光体を得た。この光散乱導光体の一方の表面を図
2、図4に示されたようにプリズム状に切削加工した。
プリズム形状の頂角α=80゜、凹凸のピッチd=0.
2mm、深さは0.1mmとした。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Some embodiments of the present invention will be described below. <Example 1> P3F on MMA (methyl methacrylate)
MA (polymer of trifluoroethyl methacrylate)
Was dissolved in 0.3 wt%, and 0.5 wt% of benzoyl peroxide (BPO) was used as a radical polymerization initiator, and the mixture was subjected to casting polymerization at 70 ° C. for 20 hours to obtain a 56 mm long, 75 mm wide and 4.8 mm thick. A plate-shaped (cuboid) light scattering light guide was obtained. One surface of the light scattering light guide was cut into a prism shape as shown in FIGS.
The apex angle α of the prism shape is 80 °, and the pitch d of the unevenness is d = 0.
The thickness was 2 mm and the depth was 0.1 mm.

【0112】プリズム状加工面を上に向けて、図2で示
した配置を構成した。光散乱導光体の背後には、光散乱
導光体とは別体の反射フィルムを置き、通常のバックラ
イト光源で使用されている蛍光灯の光を両側側面から入
射させて出射散乱光強度を測定した。(光散乱導光体下
側の面に、光拡散性インキのドットパターン等の散乱補
強手段を設けることはしない。)また、プリズム加工を
施していない場合には約4000カンデラの明るさであ
ったのに対し、プリズム加工を施した場合には、蛍光灯
に近い部分で、6000カンデラを上回る照度の散乱光
強度を得ることが出来た。
The arrangement shown in FIG. 2 was constructed with the prismatic processing surface facing upward. Behind the light-scattering light guide, a reflective film separate from the light-scattering light guide is placed, and the light of a fluorescent lamp used in a normal backlight light source is made incident on both sides to emit scattered light. Was measured. (A scattering reinforcing means such as a dot pattern of light-diffusing ink is not provided on the lower surface of the light-scattering light guide.) When the prism processing is not performed, the brightness is about 4000 candela. On the other hand, when the prism processing was performed, a scattered light intensity of illuminance exceeding 6000 candela could be obtained in a portion near the fluorescent lamp.

【0113】更に、上記プリズム加工済みの光散乱導光
体の上面に頂角約110゜のプリズムのプリズム状凹凸
面を有する別体のフィルム(以下、単にプリズムフィル
ムと言う。)を載置して、同様の条件で出射散乱光強度
を測定したところ、約5253カンデラという結果が得
られた。最明部に対する最暗部の照度比(以下、単に明
暗比と言う。)は、約0.8であった。
Further, a separate film (hereinafter, simply referred to as a prism film) having a prism-shaped irregular surface of a prism having a vertex angle of about 110 ° is placed on the upper surface of the light-scattering light guide after the prism processing. When the intensity of the emitted scattered light was measured under the same conditions, a result of about 5253 candela was obtained. The illuminance ratio of the darkest part to the brightest part (hereinafter, simply referred to as light-dark ratio) was about 0.8.

【0114】市販されているメタクリル樹脂製の光導光
板の下面に光拡散性の印刷を施し、上面側に光拡散板を
置いた従来の配置をとり、上記角ケースと同条件で出射
光の強度を測定したところ、約4052カンデラという
結果を得た。
Light diffusing printing is applied to the lower surface of a commercially available light guide plate made of methacrylic resin, and the light diffusing plate is placed on the upper surface side in a conventional arrangement. Was measured and a result of about 4052 candela was obtained.

【0115】即ち、上面側にプリズム加工を施した光散
乱導光体によれば、プリズムフィルムを付加使用するだ
けで、従来に比べて約30%の照度向上が達成されるこ
とが確かめられた。
That is, according to the light scattering / guiding member having the prism processing on the upper surface side, it was confirmed that the illuminance improvement of about 30% as compared with the conventional one was achieved only by additionally using the prism film. .

【0116】<実施例2>MMA(メチルメタクリレー
ト)にP3FMA(トリフルオロエチルメタクリレート
のポリマー)を0.3wt%溶解し、ラジカル重合開始
剤としてベンゾイルパーオキサイド(BPO)0.5w
t%を使用し、70゜Cで20時間注型重合させて縦5
6mm、横75mm,厚さ4.8mmの板状(直方体形
状)の光散乱導光体を得た。この光散乱導光体の一方の
表面を図3、図5に示されたようにプリズム状に切削加
工した。プリズム形状の頂角α=80゜、凹凸のピッチ
d=0.2mm、深さは0.1mmとした。
Example 2 0.3 wt% of P3FMA (a polymer of trifluoroethyl methacrylate) was dissolved in MMA (methyl methacrylate), and 0.5 w of benzoyl peroxide (BPO) was used as a radical polymerization initiator.
t%, and polymerized by casting at 70 ° C for 20 hours.
A plate-shaped (cuboid) light-scattering light guide having a size of 6 mm, a width of 75 mm and a thickness of 4.8 mm was obtained. One surface of the light scattering light guide was cut into a prism shape as shown in FIGS. The vertex angle α of the prism shape was 80 °, the pitch d of the unevenness was 0.2 mm, and the depth was 0.1 mm.

【0117】プリズム状加工面を下に向けて、図3で示
した配置を構成した。光散乱導光体の背後には、光散乱
導光体とは別体の反射フィルムを置き、通常のバックラ
イト光源で使用されている蛍光灯の光を両側側面から入
射させて出射散乱光強度を測定した。(光散乱導光体下
側の面に、光拡散性インキのドットパターン等の散乱補
強手段を設けることはしない。) その結果、光散乱導光体の上面全体にわたって約350
4カンデラの明るさを有していることが判った。明暗比
は0.76であった。また、上記プリズム加工面を下に
向けた光散乱導光体の上面に頂角約110゜のプリズム
フィルムを載置して、同様の条件で出射散乱光強度を測
定したところ、約5546カンデラという結果が得られ
た。最明部に対する最暗部の照度比(明暗比)は、約
0.75であった。
The arrangement shown in FIG. 3 was constructed with the prism-shaped processed surface facing downward. Behind the light-scattering light guide, a reflective film separate from the light-scattering light guide is placed, and the light of the fluorescent lamp used in a normal backlight light source is made incident on both sides to emit the scattered light intensity. Was measured. (A scattering reinforcing means such as a dot pattern of light-diffusing ink is not provided on the lower surface of the light-scattering light guide.) As a result, about 350 mm over the entire upper surface of the light-scattering light guide.
It was found that it had a brightness of 4 candela. The light-dark ratio was 0.76. When a prism film having an apex angle of about 110 ° was placed on the upper surface of the light-scattering light guide with the prism processing surface facing downward, and the emitted scattered light intensity was measured under the same conditions, the result was about 5546 candela. The result was obtained. The illuminance ratio (light-dark ratio) of the darkest part to the brightest part was about 0.75.

【0118】市販されているメタクリル樹脂製の光導光
板の下面に光拡散性の印刷を施し、上面側に光拡散板を
置いた従来の配置をとり、上記角ケースと同条件で出射
光の強度を測定したところ、約4052カンデラという
結果を得た。
Light diffusing printing is applied to the lower surface of a commercially available light guide plate made of methacrylic resin, and the light diffusing plate is placed on the upper surface side in a conventional arrangement. Was measured and a result of about 4052 candela was obtained.

【0119】即ち、下面側にプリズム加工を施してた光
散乱導光体によれば、プリズムフィルムを付加使用する
だけで、従来に比べて約37%の照度向上が達成される
ことが確かめられた。
That is, according to the light-scattering light guide having the prism processing on the lower surface side, it can be confirmed that the illuminance improvement of about 37% as compared with the conventional one can be achieved only by additionally using the prism film. Was.

【0120】<実施例3>MMA(メチルメタクリレー
ト)に重量平均分子量Mw=43.9×104 のポリベ
ンジルメタクリレート(PBzMA)を0.2wt%溶
解し、ラジカル重合開始剤としてベンゾイルパーオキサ
イド(BPO)0.5wt%、連鎖移動剤としてn―ブ
チルメルカプタン(n―BM)0.2wt%を使用し、
70゜Cで20時間注型重合させて170mm角、厚さ
10mmの板状(直方体形状)の光散乱導光体を得た。
この光散乱導光体の一側面から円筒状の切削加工を行
い、図6に示したように、円筒状の空所16を形成して
その内部に蛍光灯15を収容した。空所16は計3ヶ所
とし、蛍光灯のサイズは直径4mm,長さ170mmで
あった。各蛍光灯の真上側には図7に示したカバー乃至
シールド21を施した。なお、アルミニウム蒸着膜22
を使用しても良い。
Example 3 0.2 wt% of polybenzyl methacrylate (PBzMA) having a weight average molecular weight Mw = 43.9 × 10 4 was dissolved in MMA (methyl methacrylate), and benzoyl peroxide (BPO) was used as a radical polymerization initiator. 0.5% by weight, 0.2% by weight of n-butyl mercaptan (n-BM) as a chain transfer agent,
Casting polymerization was performed at 70 ° C. for 20 hours to obtain a plate-shaped (rectangular parallelepiped) light-scattering light guide of 170 mm square and 10 mm thickness.
A cylindrical cutting process was performed from one side surface of the light-scattering light guide, and as shown in FIG. 6, a cylindrical cavity 16 was formed, and the fluorescent lamp 15 was accommodated therein. The number of the empty spaces 16 was three, and the size of the fluorescent lamp was 4 mm in diameter and 170 mm in length. The cover or shield 21 shown in FIG. 7 was provided directly above each fluorescent lamp. In addition, the aluminum deposition film 22
May be used.

【0121】図7(a)及び(b)に示したカバーは、
強い直接光が上方に向けて貫通して散乱光取出面が局所
的に強く輝くのを防ぐ為のものであり、場合によって
は、半透明にすることや、全く使用しないことも有り得
るものである。カバー乃至シールド21の内側は反射面
として、少しでも光量を無駄にしないことが好ましいこ
とは、言うまでもない。
The cover shown in FIGS. 7A and 7B
This is to prevent strong direct light from penetrating upward and prevent the scattered light extraction surface from shining strongly locally, and in some cases, it may be translucent or not used at all. . It is needless to say that it is preferable that the inside of the cover or the shield 21 be a reflection surface so as not to waste a little light.

【0122】散乱導光体の背後には、光散乱導光体とは
別体の反射フィルムを置き、光散乱導光体の上面に頂角
約110゜のプリズムフィルムを載置して散乱出射光の
強度を測定した。(光散乱導光体下側の面に、光拡散性
インキのドットパターン等の散乱補強手段を設けること
はしない。)その結果、光散乱導光体の上面全体にわた
って約7500カンデラの明るさを有していることが判
った。
A reflection film separate from the light-scattering light guide is placed behind the light-scattering light guide, and a prism film having an apex angle of about 110 ° is placed on the upper surface of the light-scattering light guide to scatter light. The intensity of the emitted light was measured. (A scattering reinforcing means such as a dot pattern of a light-diffusing ink is not provided on the lower surface of the light-scattering light guide.) As a result, the brightness of about 7500 candela is obtained over the entire upper surface of the light-scattering light guide. It was found to have.

【0123】次に、同じ蛍光灯埋め込み済みの光散乱導
光体の表面に、頂角α=80゜、凹凸のピッチd=0.
2mm、深さは0.1mmのプリズム状加工を施し、こ
のプリズム加工面を上に向けた場合と、下に向けた場合
とについて出射散乱光強度を測定したところ、いずれの
場合にも、光散乱導光体の上面全体にわたって約750
0カンデラを超える均一な明るさが観測された。
Next, the apex angle α = 80 ° and the pitch d of the unevenness d = 0.
The scattered light intensity was measured for a prism processed with a prism processing surface of 2 mm and a depth of 0.1 mm, and the prism processing surface was directed upward and downward. About 750 over the entire top surface of the scattering light guide
Uniform brightness exceeding 0 candela was observed.

【0124】<実施例4>MMA(メチルメタクリレー
ト)に粒径3μmのシリコン系樹脂粉体(東芝シリコン
製;トスパール130)を0.35wt%加えて均一に
分散させた上で、ラジカル重合開始剤としてベンゾイル
パーオキサイド(BPO)0.5wt%、連鎖移動剤と
してn―ブチルメルカプタン(n―BM)0.2wt%
を添加し、70゜Cで20時間注型重合させて170m
m角、厚さ10mmの板状(直方体形状)の光散乱導光
体を得た。この光散乱導光体の一側面から円筒状の切削
加工を行い、図6に示した如く円筒状の空所16内に蛍
光灯15を収容した。空所16は計3ヶ所とし、蛍光灯
15のサイズは直径4mm,長さ170mmであった。
各蛍光灯の真上側には図7に示したカバー21乃至シー
ルド22を施した。
Example 4 0.35 wt% of a silicon-based resin powder having a particle size of 3 μm (manufactured by Toshiba Silicon; Tospearl 130) was added to MMA (methyl methacrylate) and uniformly dispersed, and then a radical polymerization initiator was added. 0.5 wt% of benzoyl peroxide (BPO) and 0.2 wt% of n-butyl mercaptan (n-BM) as a chain transfer agent
Is added and the mixture is cast-polymerized at 70 ° C. for 20 hours.
A plate-shaped (rectangular parallelepiped) light-scattering light guide having an m-square and a thickness of 10 mm was obtained. A cylindrical cutting process was performed from one side of the light scattering light guide, and the fluorescent lamp 15 was accommodated in a cylindrical space 16 as shown in FIG. The number of the empty spaces 16 was three, and the size of the fluorescent lamp 15 was 4 mm in diameter and 170 mm in length.
The cover 21 and the shield 22 shown in FIG. 7 were provided directly above each fluorescent lamp.

【0125】散乱導光体の背後には、光散乱導光体とは
別体の反射フィルムを置き、光散乱導光体の上面に頂角
約110゜のプリズムフィルムを載置し光源装置を構成
した。(光散乱導光体下側の面に、光拡散性インキのド
ットパターン等の散乱補強手段を設けることはしな
い。)目視によって全体の明るさを観察したところ、全
面が明るく見え、特に明暗差の認められなかった。明暗
比の実測値は、約0.86であった。このことから、公
知の散乱粒子分散型の導光体を光拡散層印刷等の散乱補
強手段なしに使用した場合でも、光源要素を内部に埋め
込んだ配置を採用することによって均一で明るい光源装
置が得られることが判った。
A reflection film separate from the light-scattering light guide is placed behind the light-scattering light guide, and a prism film having an apex angle of about 110 ° is placed on the upper surface of the light-scattering light guide, and the light source device is mounted. Configured. (A scattering reinforcing means such as a dot pattern of light-diffusing ink is not provided on the lower surface of the light-scattering light guide.) When the entire brightness is visually observed, the entire surface looks bright, and particularly the difference in brightness and darkness. Was not recognized. The measured value of the light-dark ratio was about 0.86. From this, even when a known scattering particle dispersion type light guide is used without scattering reinforcing means such as light diffusion layer printing, a uniform and bright light source device is obtained by adopting the arrangement in which the light source elements are embedded inside. It turned out to be obtained.

【0126】<実施例5>MMA(メチルメタクリレー
ト)に粒径0.8μmのシリコン系樹脂粉体(東芝シリ
コン製;トスパール108)を0.3wt%加えて均一
に分散させた上で、ラジカル重合開始剤としてベンゾイ
ルパーオキサイド(BPO)0.5wt%、連鎖移動剤
としてn―ブチルメルカプタン(n―BM)0.2wt
%を添加し、70゜Cで20時間注型重合させて170
mm角、厚さ10mmの板状(直方体形状)の光散乱導
光体を得た。この光散乱導光体の一側面から円筒状の切
削加工を行い、図6に示した如く円筒状の空所16内に
蛍光灯15を収容した。空所16は計3ヶ所とし、蛍光
灯15のサイズは直径4mm,長さ170mmであっ
た。各蛍光灯の真上側には図8に示したカバー乃至シー
ルド21を施した。なお、アルミニウム蒸着膜22を使
用しても良い。
<Example 5> 0.3 wt% of a silicon resin powder (manufactured by Toshiba Silicon; Tospearl 108) having a particle size of 0.8 μm was added to MMA (methyl methacrylate), and the mixture was uniformly dispersed, followed by radical polymerization. Benzoyl peroxide (BPO) 0.5 wt% as initiator, n-butyl mercaptan (n-BM) 0.2 wt as chain transfer agent
% At 70 ° C. for 20 hours.
A plate-shaped (rectangular parallelepiped) light-scattering light guide having a square shape and a thickness of 10 mm was obtained. A cylindrical cutting process was performed from one side of the light scattering light guide, and the fluorescent lamp 15 was accommodated in a cylindrical space 16 as shown in FIG. The number of the empty spaces 16 was three, and the size of the fluorescent lamp 15 was 4 mm in diameter and 170 mm in length. The cover or shield 21 shown in FIG. 8 was provided directly above each fluorescent lamp. In addition, you may use the aluminum vapor deposition film 22.

【0127】散乱導光体の背後には、光散乱導光体とは
別体の反射フィルムを置き、光散乱導光体の上面に頂角
約110゜のプリズムフィルムを載置し光源装置を構成
した。(光散乱導光体下側の面に、光拡散性インキのド
ットパターン等の散乱補強手段を設けることはしな
い。) 目視によって全体の明るさを観察したところ、全面が明
るく見え、特に明暗差は認められなかった。
A reflection film separate from the light-scattering light guide is placed behind the light-scattering light guide, and a prism film having an apex angle of about 110 ° is placed on the upper surface of the light-scattering light guide to mount the light source device. Configured. (A scattering reinforcing means such as a dot pattern of light-diffusing ink is not provided on the lower surface of the light-scattering light guide.) When the entire brightness is visually observed, the entire surface looks bright, and particularly the difference in brightness. Was not found.

【0128】次に、同じ蛍光灯埋め込み済みの光散乱導
光体の表面に、頂角α=80゜、凹凸のピッチd=0.
2mm、深さは0.1mmのプリズム状加工を施し、こ
のプリズム加工面を上に向けた場合と、下に向けた場合
とについて出射散乱光強度を測定したところ、いずれの
場合にも、光散乱導光体の上面全体にわたってプリズム
加工を施す前よりも明るい散乱光が観測された。
Next, the apex angle α = 80 ° and the pitch d of the unevenness d = 0.
The scattered light intensity was measured for a prism processed with a prism processing surface of 2 mm and a depth of 0.1 mm, and the prism processing surface was directed upward and downward. Brighter scattered light was observed over the entire upper surface of the scattering light guide than before performing the prism processing.

【0129】[0129]

【発明の効果】本発明によれば、従来技術では避け難か
った装置の複雑化、大型化を回避し、極めて簡単な構成
で均一で明るい光出射面を持つ、製造が簡単な光散乱導
光装置が提供される。即ち、本発明によって、散乱能の
勾配付与や拡散インキ層等の補強手段付加を必要としな
くなるから、製造工程の複雑化と装置の大型化を避ける
ことが可能になり、光散乱導光体表面に凹凸を設けると
いう簡単且つスペースを要しない手段によって、散乱出
射光強度の角度特性を調整出来るから、サイズを変えず
に光散乱導光光源装置の実質的な明るさを改善すること
が出来るようになった。
According to the present invention, a light-scattering light guide which is simple to manufacture and has a uniform and bright light emitting surface with an extremely simple structure, avoiding the complexity and size increase of the device which was inevitable in the prior art. An apparatus is provided. That is, according to the present invention, since it is not necessary to add a gradient means of scattering ability or to add reinforcing means such as a diffusion ink layer, it is possible to avoid a complicated manufacturing process and an increase in the size of the apparatus, and the light scattering guide surface Since the angular characteristics of the scattered light intensity can be adjusted by a simple and space-free means of providing irregularities on the surface, it is possible to improve the substantial brightness of the light-scattering light-guiding light source device without changing the size. Became.

【0130】また、光源要素を光散乱導光体の空所ある
いは凹部に収容する構成を採用することによって、従来
の光源要素の配置上の制約に伴う問題(光量と明るさ均
一度の不足、光源要素配置の為の付加スペースの問題)
を一挙に解決することが出来た。
Further, by adopting a configuration in which the light source element is accommodated in a space or a concave portion of the light-scattering light guide, problems associated with the conventional restrictions on the arrangement of the light source element (lack of light quantity and brightness uniformity, Problem of additional space for light source element arrangement)
Was solved at once.

【0131】更に、本発明は、前述した本発明者に係る
幾つかの提案と組み合わせることによって、著しい相乗
的効果が発揮されることも着目されるべきである。特
に、前述の平成4年11月27日出願の日本国特許出願
の明細書に開示した光出射方向修正素子(例えば、プリ
ズムフィルム)は、本発明のいずれの形態(請求項1〜
請求項5)に従った構成にも組み合わせて用いることが
可能であり、また、その組み合わせによる相乗効果も大
きい(<実施例1>〜<実施例5>におけるプリズムフ
ィルムの使用を参照)。
It should also be noted that the present invention, when combined with some of the proposals according to the inventor described above, exhibits a remarkable synergistic effect. In particular, the light-emitting direction correcting element (for example, a prism film) disclosed in the specification of the Japanese Patent Application filed on November 27, 1992 mentioned above is applicable to any of the embodiments of the present invention (claims 1 to 3).
The combination according to claim 5) can be used in combination, and the combination has a large synergistic effect (see the use of the prism film in <Example 1> to <Example 5>).

【0132】また、本発明者の創出した製造法(重合過
程を利用した方法及びポリマーブレンドによる方法)に
よって製造される各種特性を有する光散乱導光体材料
を、本発明に置ける光散乱導光体の素材に用い、凹凸加
工、光源埋め込み等の手段を施すことによって、材料の
調整を含めた光散乱導光装置全体の製造工程を合理化
し、装置の性能を大幅に改善する効果が得られるもので
ある。
Further, the light-scattering light-guiding material having various properties manufactured by the manufacturing method (method utilizing a polymerization process and method using a polymer blend) created by the present inventors is used as the light-scattering light-guiding material according to the present invention. By using the body material and applying means such as embossing and embedding of a light source, it is possible to streamline the manufacturing process of the entire light scattering and light guiding device, including the adjustment of the material, and to obtain the effect of greatly improving the performance of the device. Things.

【0133】本発明の光散乱導光体あるいは光散乱導光
光源装置は、このような利点を備えているから、液晶表
示装置等各種ディスプレイのバックライト光源装置、自
動車等におけるバックライト光源、1次光源として太陽
光あるいは通常の照明光源を利用した各種の照明システ
ムにおける各種形状と各種寸法の照明光源装置、レーザ
や発光ダイオード等の光源を1次光源に用いた際の光束
拡張装置、光信号伝送システムにおける光分岐装置・混
合、顕微鏡等において狭い範囲を集中的且つ強力に照明
する装置等への適用を通じて、幅広い光学分野でその有
用性を発揮するものである。
The light-scattering light guide or light-scattering light-guiding light source device of the present invention has such advantages. Illumination light source devices of various shapes and dimensions in various illumination systems using sunlight or a normal illumination light source as a secondary light source, a light beam expansion device when a light source such as a laser or a light emitting diode is used as a primary light source, an optical signal The present invention exerts its usefulness in a wide range of optical fields through application to devices that intensively and strongly illuminate a narrow area in an optical branching device, a mixing device, a microscope, and the like in a transmission system.

【図面の簡単な説明】[Brief description of the drawings]

【図1】横軸に相関距離a、縦軸に誘電率ゆらぎ2乗平
均τ=<η>をとって有効散乱照射パラメータEの曲
線をE=50[cm-1]及びE=100[cm-1]の場合に
ついて描いた図である。
FIG. 1 shows a curve of an effective scattering irradiation parameter E with a correlation distance a on the horizontal axis and a root mean square τ = <η 2 > on the vertical axis, where E = 50 [cm −1 ] and E = 100 [ cm -1 ].

【図2】本発明に従って、散乱出射光強度を調整する凹
凸領域を散乱出射光取出面側に形成した光散乱導光体を
用いた光散乱導光光源装置の典型的な配置を示す図であ
る。
FIG. 2 is a diagram showing a typical arrangement of a light-scattering light-guiding light source device using a light-scattering light-guiding body in which an uneven area for adjusting the intensity of scattered light is formed on the side of the scattered light extraction surface according to the present invention. is there.

【図3】本発明に従って、散乱出射光強度を調整する凹
凸領域を散乱出射光取出面と相反する側に形成した光散
乱導光体を用いた光散乱導光光源装置の典型的な配置を
示す図である。
FIG. 3 shows a typical arrangement of a light-scattering light-guiding light source device using a light-scattering light-guiding body in which a concavo-convex region for adjusting the intensity of the scattered light is formed on the side opposite to the surface from which the scattered light is extracted according to the present invention. FIG.

【図4】図2に示された光散乱導光体における光線進路
を例示した図である。
FIG. 4 is a diagram exemplifying a ray trajectory in the light-scattering light guide shown in FIG. 2;

【図5】図3に示された光散乱導光体における光線進路
を例示した図である。
FIG. 5 is a diagram exemplifying a ray trajectory in the light-scattering light guide shown in FIG. 3;

【図6】光源要素を光散乱導光体の空所に配置した光散
乱導光光源装置の配置を例示した図である。
FIG. 6 is a diagram exemplifying an arrangement of a light-scattering light-guiding light source device in which a light source element is arranged in a space of a light-scattering light guide.

【図7】光源要素の周囲の一部を覆うように形成乃至配
置されるカバー乃至シールドのの一つの例(a)及び別
の例(b)を示した図である。
FIG. 7 is a diagram showing one example (a) and another example (b) of a cover or a shield formed or arranged so as to cover a part of the periphery of the light source element.

【符号の説明】[Explanation of symbols]

1、11 光散乱導光体 2 凹凸領域 3 外部(空気) 4、14 反射フィルム 5、15 光源要素(蛍光灯) 16 空所 21、22 カバー乃至シールド DESCRIPTION OF SYMBOLS 1, 11 Light-scattering light guide 2 Uneven area 3 Outside (air) 4, 14 Reflective film 5, 15 Light source element (fluorescent lamp) 16 Void 21, 22 Cover or shield

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) G02B 5/08 G02B 5/08 A // G02F 1/13357 G02F 1/13357 F21Y 101:02 F21Y 101:02 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) G02B 5/08 G02B 5/08 A // G02F 1/13357 G02F 1/13357 F21Y 101: 02 F21Y 101: 02

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 入射光受入表面領域と、前記入射光受入
表面領域からの入射光を起源とする散乱出射光を取り出
す為の散乱出射光取出表面領域と、光散乱能が実質的に
一様に与えられた光散乱体積領域とを有する光散乱導光
体であって;前記散乱出射光取出表面領域の少なくとも
一部には散乱出射光強度の角度特性を調整するプリズム
状凹凸要素配列が規則的に繰り返し形成されており、 前記光散乱体積領域の有効散乱照射パラメータE[c
m-1]の値が、0.001≦E≦1000の範囲にあ
り、 該光散乱体積領域に前記散乱能を生じせしめる屈折率不
均一構造の相関関数γ(r)を近似式γ(r)=exp
[―r/a](但しrは、光散乱導光体内の2点間距離
[μm])で表した時の相関距離aの範囲が、0.00
5μm≦a≦50μmの範囲にある、前記光散乱導光
体。
1. An incident light receiving surface region, a scattered and emitted light extraction surface region for extracting scattered and emitted light originating from incident light from the incident light receiving surface region, and a light scattering capability is substantially uniform. A light-scattering light guide having a light-scattering volume region given to the light-emitting device; The effective scattering irradiation parameter E [c in the light scattering volume region
m -1 ] is in the range of 0.001 ≦ E ≦ 1000, and the correlation function γ (r) of the non-uniform refractive index structure causing the scattering power in the light scattering volume region is approximated by γ (r ) = Exp
The range of the correlation distance a when expressed as [−r / a] (where r is the distance [μm] between two points in the light scattering light guide) is 0.00
The light-scattering light guide according to the present invention, wherein 5 μm ≦ a ≦ 50 μm.
【請求項2】 入射光受入表面領域と、前記入射光受入
表面領域からの入射光を起源とする散乱出射光を取り出
す為の散乱出射光取出表面領域と、光散乱能が実質的に
一様に与えられた光散乱体積領域とを有する光散乱導光
体であって;前記散乱出射光取出表面領域と相反する側
の面の少なくとも一部には、外部の反射要素に対向し、
散乱出射光強度の角度特性を調整するプリズム状凹凸要
素配列が規則的に繰り返し形成されており、 前記光散乱体積領域の有効散乱照射パラメータE[c
m-1]の値が、0.001≦E≦1000の範囲にあ
り、 該光散乱体積領域に前記散乱能を生じせしめる屈折率不
均一構造の相関関数γ(r)を近似式γ(r)=exp
[―r/a](但しrは、光散乱導光体内の2点間距離
[μm])で表した時の相関距離aの範囲が、0.00
5μm≦a≦50μmの範囲にある、前記光散乱導光
体。
2. An incident light receiving surface area, a scattered emission light extraction surface area for extracting scattered emission light originating from incident light from the incident light reception surface area, and a light scattering ability is substantially uniform. A light-scattering light guide having a light-scattering volume region given to at least a part of a surface on a side opposite to the scattered emission light extraction surface region, facing an external reflection element,
An array of prismatic concavo-convex elements for adjusting the angular characteristic of the scattered light intensity is regularly and repeatedly formed, and the effective scattering irradiation parameter E [c of the light scattering volume region is formed.
m -1 ] is in the range of 0.001 ≦ E ≦ 1000, and the correlation function γ (r) of the non-uniform refractive index structure causing the scattering power in the light scattering volume region is approximated by γ (r ) = Exp
The range of the correlation distance a when expressed as [−r / a] (where r is the distance [μm] between two points in the light scattering light guide) is 0.00
The light-scattering light guide according to the present invention, wherein 5 μm ≦ a ≦ 50 μm.
【請求項3】 入射光受入表面領域と、前記入射光受入
表面領域からの入射光を起源とする散乱出射光を取り出
す為の散乱出射光取出表面領域と、光散乱能が実質的に
一様に与えられた光散乱体積領域とを有し、前記散乱出
射光取出表面領域の少なくとも一部には散乱出射光強度
の角度特性を調整するプリズム状凹凸要素配列が規則的
に繰り返し形成されている光散乱導光体と、 前記光散乱導光体に光供給を行なう光源要素とを備えた
光散乱導光装置であって:前記光散乱体積領域は、前記
プリズム状凹凸要素配列部分と直方体形状部分とを含
み、 前記光源要素は、前記直方体形状の側面部分の近傍に配
置されており、 前記光散乱体積領域の有効散乱照射パラメータE[c
m-1]の値が、0.001≦E≦1000の範囲にあ
り、 該光散乱体積領域に前記散乱能を生じせしめる屈折率不
均一構造の相関関数γ(r)を近似式γ(r)=exp
[―r/a](但しrは、光散乱導光体内の2点間距離
[μm])で表した時の相関距離aの範囲が、0.00
5μm≦a≦50μmの範囲にある、前記光散乱導光装
置。
3. An incident light receiving surface area, a scattered and emitted light extraction surface area for extracting scattered and emitted light originating from the incident light from the incident light receiving surface area, and a light scattering ability is substantially uniform. And a light scattering volume region given to the scattered emission light extraction surface region, and at least part of the scattered emission light extraction surface region is regularly and repeatedly formed with prismatic concave and convex element arrays for adjusting the angular characteristics of the scattered emission light intensity. A light-scattering light-guiding device comprising: a light-scattering light guide; and a light source element for supplying light to the light-scattering light guide, wherein the light-scattering volume region has a rectangular parallelepiped shape with the prism-shaped unevenness element array portion. The light source element is disposed near a side surface portion of the rectangular parallelepiped shape, and an effective scattering irradiation parameter E [c of the light scattering volume region is included.
m -1 ] is in the range of 0.001 ≦ E ≦ 1000, and the correlation function γ (r) of the non-uniform refractive index structure causing the scattering power in the light scattering volume region is approximated by γ (r ) = Exp
The range of the correlation distance a when expressed as [−r / a] (where r is the distance [μm] between two points in the light scattering light guide) is 0.00
The light-scattering and light-guiding device according to claim 1, wherein 5 μm ≦ a ≦ 50 μm.
【請求項4】 入射光受入表面領域と、前記入射光受入
表面領域からの入射光を起源とする散乱出射光を取り出
す為の散乱出射光取出表面領域と、光散乱能が実質的に
一様に与えられた直方体形状の光散乱体積領域とを有
し、前記散乱出射光取出表面領域と相反する側の面の少
なくとも一部には、外部の反射要素に対向し、且つ、散
乱出射光強度の角度特性を調整するプリズム状凹凸要素
配列が規則的に繰り返し形成されている光散乱導光体
と、 前記光散乱導光体に光供給を行なう光源要素とを備えた
光散乱導光装置であって:前記光散乱体積領域は、前記
プリズム状凹凸要素配列部分と直方体形状部分とを含
み、 前記光源要素は、前記直方体形状の側面部分の近傍に配
置されており、 前記光散乱体積領域の有効散乱照射パラメータE[c
m-1]の値が、0.001≦E≦1000の範囲にあ
り、 該光散乱体積領域に前記散乱能を生じせしめる屈折率不
均一構造の相関関数γ(r)を近似式γ(r)=exp
[―r/a](但しrは、光散乱導光体内の2点間距離
[μm])で表した時の相関距離aの範囲が、0.00
5μm≦a≦50μmの範囲にある、前記光散乱導光装
置。徴とする光散乱導光光源装置。
4. An incident light receiving surface area, a scattered and emitted light extraction surface area for extracting scattered and emitted light originating from incident light from the incident light receiving surface area, and a light scattering ability is substantially uniform. Having a rectangular parallelepiped light scattering volume region, and at least a part of a surface opposite to the scattered emission light extraction surface region faces an external reflection element, and has a scattered emission light intensity. A light-scattering and light-guiding device comprising: a light-scattering light-guiding body in which a prismatic concave-convex element array for adjusting the angular characteristics of the light-scattering light is regularly and repeatedly formed; and a light source element for supplying light to the light-scattering light-guiding body. At least: the light scattering volume region includes the prismatic concave and convex element array portion and a rectangular parallelepiped portion; the light source element is disposed near a side portion of the rectangular parallelepiped shape; Effective scattering irradiation parameter E [c
m -1 ] is in the range of 0.001 ≦ E ≦ 1000, and the correlation function γ (r) of the non-uniform refractive index structure causing the scattering power in the light scattering volume region is approximated by γ (r ) = Exp
The range of the correlation distance a when expressed as [−r / a] (where r is the distance [μm] between two points in the light scattering light guide) is 0.00
The light-scattering and light-guiding device according to claim 1, wherein 5 μm ≦ a ≦ 50 μm. Light scattering light guide light source device.
【請求項5】 前記光源要素は棒状の形状を有し、前記
直方体形状の側面部分に沿うように配置されていること
を特徴とする、請求項3または請求項4に記載された光
散乱導光光源装置。
5. The light-scattering light guide according to claim 3, wherein the light source element has a rod-like shape and is arranged along a side portion of the rectangular parallelepiped. Light source device.
JP2001249458A 2001-08-20 2001-08-20 Light scattering light guide and light scattering light source device Expired - Lifetime JP3414727B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001249458A JP3414727B2 (en) 2001-08-20 2001-08-20 Light scattering light guide and light scattering light source device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001249458A JP3414727B2 (en) 2001-08-20 2001-08-20 Light scattering light guide and light scattering light source device

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP35507392A Division JP3279690B2 (en) 1992-12-16 1992-12-16 Light scattering light guide and light scattering light source device

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Publication Number Publication Date
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JP3414727B2 JP3414727B2 (en) 2003-06-09

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007100180A1 (en) * 2006-02-28 2007-09-07 Attocon Co., Ltd. Light emitting keypad comprising light guide film and light guide film
JPWO2007097117A1 (en) * 2006-02-20 2009-07-09 シチズン電子株式会社 Side light emitting unit and illumination panel
JP2012243539A (en) * 2011-05-19 2012-12-10 Stanley Electric Co Ltd Light guide lens and vehicular lamp
CN106094073A (en) * 2016-08-19 2016-11-09 上海理湃光晶技术有限公司 A kind of scattering film for AR glasses

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2007097117A1 (en) * 2006-02-20 2009-07-09 シチズン電子株式会社 Side light emitting unit and illumination panel
US7884296B2 (en) 2006-02-20 2011-02-08 Citizen Electronics Co., Ltd. Side-surface light-emitting unit and illuminated panel using the same
WO2007100180A1 (en) * 2006-02-28 2007-09-07 Attocon Co., Ltd. Light emitting keypad comprising light guide film and light guide film
US7683279B2 (en) 2006-02-28 2010-03-23 Hyun Soo Kim Light emitting keypad comprising light guide film and light guide
JP2012243539A (en) * 2011-05-19 2012-12-10 Stanley Electric Co Ltd Light guide lens and vehicular lamp
CN106094073A (en) * 2016-08-19 2016-11-09 上海理湃光晶技术有限公司 A kind of scattering film for AR glasses

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