JP2002121114A - Cosmetic - Google Patents
CosmeticInfo
- Publication number
- JP2002121114A JP2002121114A JP2000314597A JP2000314597A JP2002121114A JP 2002121114 A JP2002121114 A JP 2002121114A JP 2000314597 A JP2000314597 A JP 2000314597A JP 2000314597 A JP2000314597 A JP 2000314597A JP 2002121114 A JP2002121114 A JP 2002121114A
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- Prior art keywords
- water
- oil
- cosmetic
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- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、入浴剤、化粧水、
各種ローション等の化粧料に関し、水又は湯に投入する
ことにより、保湿作用及び各種化粧料の作用効果等を奏
する水中油型乳化物層と、水溶性保湿成分の揮発を防
ぎ、効率的に皮膚にしっとり感を与え、保持する油層と
が形成される化粧料に関する。TECHNICAL FIELD The present invention relates to a bath preparation, a lotion,
With regard to cosmetics such as lotions, by putting them into water or hot water, an oil-in-water emulsion layer that has a moisturizing action and the effect of various cosmetics, etc. The present invention relates to a cosmetic that gives a moist feeling and forms an oil layer to be retained.
【0002】[0002]
【従来の技術】化粧料、特に、入浴剤、化粧水、各種ロ
ーション等においては、洗浄作用、保湿作用等を得るた
めに、油剤や各種界面活性剤等が配合されることが多
い。しかし、これら従来の化粧料は、水又は湯に投入す
る場合、油剤成分の一部が水面又は湯面に浮くような製
品は外観的に好ましくないため、油剤を水又は湯に乳化
して均一に溶解させるように設計されている。それで
も、油剤の一部が水面又は湯面に浮くような好ましくな
い製品も見うけられるが、通常の使用法により、水面又
は湯面に油層が均一に形成されるような場合はない。こ
のような油剤や界面活性剤を配合した従来の化粧料にお
いて、充分な保湿作用等を得るためには、水又は湯に多
くの油剤を乳化させる必要がある。この場合、油剤を乳
化させた水又は湯に肌が接触している際には保湿効果を
実感できるが、使用後、短時間の経過で、水性成分の揮
発に伴ないその保湿効果が低減する傾向にある。2. Description of the Related Art In cosmetics, especially bath agents, lotions, various lotions, etc., oil agents and various surfactants are often blended in order to obtain a washing action, a moisturizing action and the like. However, when these conventional cosmetics are poured into water or hot water, a product in which a part of the oil agent component floats on the water or hot water surface is not preferable in appearance. It is designed to be dissolved in Nevertheless, there are undesired products in which a part of the oil agent floats on the surface of the water or the surface of the molten metal. In conventional cosmetics containing such oils and surfactants, it is necessary to emulsify many oils in water or hot water in order to obtain a sufficient moisturizing action and the like. In this case, when the skin is in contact with water or hot water in which the oil agent is emulsified, the moisturizing effect can be realized, but after use, in a short time, the moisturizing effect accompanying the volatilization of the aqueous component is reduced. There is a tendency.
【0003】[0003]
【発明が解決しようとする課題】従って、本発明の目的
は、保湿作用及び各種化粧料の作用効果等が得られると
共に、使用後、水溶性保湿剤の揮発を抑制し、効率的に
皮膚にしっとり感を与え、保持しうる、特に、入浴剤、
化粧水、各種ローション等に有効な化粧料を提供するこ
とにある。SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide a moisturizing effect and the effect of various cosmetics, as well as to suppress volatilization of a water-soluble humectant after use and to efficiently apply to the skin. Gives moist feeling and can be kept, especially bath salts,
An object of the present invention is to provide an effective cosmetic for lotion, various lotions, and the like.
【0004】[0004]
【課題を解決するための手段】本発明者らは、上記課題
を解決するため鋭意検討を重ねた結果、2種以上の特定
のHLBを有する非イオン性界面活性剤の混合物を、油
剤と水とを含む化粧料に配合し、且つ水又は湯に投入す
ることにより油層及び水中油型乳化物層の少なくとも2
層が形成されるものとすることによって、油剤の使用量
が、従来の均一乳化物とする化粧料と同程度であって
も、水溶性保湿成分の揮発を抑制し、優れた保湿効果等
が得られ、しかも保存安定性にも優れることを見出し本
発明を完成した。すなわち、本発明によれば、2種類以
上の非イオン性界面活性剤と、油剤と、水とを含み、含
有される非イオン性界面活性剤の混合物のHLBが6.
5〜10.5であり、水又は湯に投入することにより、
油層及び水中油型乳化物層の少なくとも2層が形成され
ることを特徴とする化粧料が提供される。Means for Solving the Problems The present inventors have made intensive studies to solve the above-mentioned problems, and as a result, obtained a mixture of two or more nonionic surfactants having a specific HLB with an oil agent and water. And at least two of an oily layer and an oil-in-water emulsion layer by being added to water or hot water.
By forming a layer, even if the amount of the oil agent used is almost the same as that of a conventional uniform emulsion, the water-soluble moisturizing component is suppressed from being volatilized, and an excellent moisturizing effect is obtained. The present invention was found to be excellent in storage stability and completed the present invention. That is, according to the present invention, the HLB of a mixture of nonionic surfactants containing two or more kinds of nonionic surfactants, an oil agent, and water and containing the same is 6.
5 to 10.5, and by pouring into water or hot water,
A cosmetic is provided, wherein at least two layers, an oil layer and an oil-in-water emulsion layer, are formed.
【0005】[0005]
【発明の実施の形態】以下本発明を更に詳細に説明す
る。本発明の化粧料は、特に、入浴剤、化粧水、各種ロ
ーション等に有用であり、水又は湯に投入することによ
り、油層及び水中油型乳化物層の少なくとも2層が形成
される。ここで、通常、油層は水面又は湯面に形成され
るが、この油層は、水面又は湯面に浮遊するものではな
く、層として、好ましくは均一層として形成されるもの
を意味する。本発明においては、この油層が、水中油型
乳化物層中の水性保湿成分等の皮膚からの揮発を抑制
し、且つ皮膚刺激性を緩和して効率的に所望の作用効果
を発揮させるものと考えられる。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in more detail. The cosmetic of the present invention is particularly useful for bath salts, lotion, various lotions, and the like, and at least two layers of an oil layer and an oil-in-water emulsion layer are formed by being poured into water or hot water. Here, the oil layer is usually formed on the surface of the water or the surface of the molten metal, but this oil layer does not float on the surface of the water or the surface of the molten metal, but means a layer formed as a layer, preferably a uniform layer. In the present invention, the oil layer suppresses volatilization of the aqueous moisturizing component and the like in the oil-in-water emulsion layer from the skin, and alleviates skin irritation, thereby efficiently exhibiting a desired effect. Conceivable.
【0006】本発明に用いる非イオン性界面活性剤は、
2種以上の混合物で配合する。該混合物のHLBは、
6.5〜10.5、好ましくは7.5〜9.5となるよ
うに配合する。非イオン性界面活性剤の種類が1種類の
場合には、製品全体の安定生が悪くなる。また、該混合
物のHLBが6.5未満では、水面又は湯面に浮遊する
油剤が増加して使用感が低下し、10.5を超える場合
には、水面又は湯面に浮遊する油剤が減少し、所望の油
層が形成されない。非イオン性界面活性剤の混合物のH
LBは、以下の数式に従って計算することができる。[0006] The nonionic surfactant used in the present invention comprises:
It is blended in a mixture of two or more. The HLB of the mixture is
It mix | blends so that it may become 6.5-10.5, Preferably it becomes 7.5-9.5. When one kind of nonionic surfactant is used, the stability of the whole product is deteriorated. When the HLB of the mixture is less than 6.5, the amount of oil floating on the surface of the water or the molten metal increases, and the feeling of use decreases. When the HLB of the mixture exceeds 10.5, the amount of oil floating on the surface of the water or the liquid decreases. However, a desired oil layer is not formed. H of the mixture of nonionic surfactants
LB can be calculated according to the following equation.
【数1】 (Equation 1)
【0007】本発明に用いる非イオン性界面活性剤とし
ては、例えば、モノオレイン酸ポリエチレングリコール
等のポリエチレングリコール脂肪酸エステル;モノオレ
イン酸プロピレングリコール等のプロピレングリコール
脂肪酸エステル;グリセリン脂肪酸エステル;ポリオキ
シエチレングリセリン脂肪酸エステル、モノオレイン酸
ヘキサグリセリン、ペンタオレイン酸デカグリセリン等
のポリグリセリン脂肪酸エステル;ソルビタン脂肪酸エ
ステル;ポリオキシエチレンソルビタン脂肪酸エステ
ル;ポリオキシエチレンソルビット脂肪酸エステル;ポ
リオキシエチレン硬化ヒマシ油;ポリオキシエチレンア
ルキルエーテル;ポリオキシエチレンポリオキシプロピ
レンアルキルエーテル;ポリオキシエチレンアルキルフ
ェニルエーテル等が挙げられ、使用に際しては、上記特
定のHLBの範囲となるように2種以上を組合せて使用
する。The nonionic surfactants used in the present invention include, for example, polyethylene glycol fatty acid esters such as polyethylene glycol monooleate; propylene glycol fatty acid esters such as propylene glycol monooleate; glycerin fatty acid esters; polyoxyethylene glycerin Polyglycerol fatty acid esters such as fatty acid esters, hexaglycerin monooleate, decaglycerin pentaoleate; sorbitan fatty acid esters; polyoxyethylene sorbitan fatty acid esters; polyoxyethylene sorbite fatty acid esters; polyoxyethylene hydrogenated castor oil; polyoxyethylene alkyl Ether; polyoxyethylene polyoxypropylene alkyl ether; polyoxyethylene alkyl phenyl ether, etc. Gerare, In use, used as a combination of two or more in the range of the specific HLB.
【0008】本発明に用いる油剤は、通常、保湿作用、
潤滑柔軟作用等を有する化粧料に配合し得るものである
ことが好ましく、例えば、アボガド油、アルモンド油、
オリーブ油、ヤシ油、ヒマシ油、パーム油、牛脂、ミン
ク油等の油脂類;流動パラフィン、スクワラン等の炭化
水素油;ミリスチン酸イソプロピル、パルミチン酸イソ
プロピル、ステアリン酸ステアリル、パルミチン酸セチ
ル、パルミチン酸オクチル、ステアリン酸−2−エチル
ヘキシル、2−エチルヘキサン酸ステアリル、トリ2−
エチルヘキサン酸グリセリル、トリ(カプリル・カプリ
ン酸)グリセリン等のエステル油又はこれらの混合物等
が挙げられる。The oil agent used in the present invention usually has a moisturizing action,
It is preferably one that can be blended into a cosmetic having a lubricating softening action and the like, for example, avocado oil, almond oil,
Oils such as olive oil, coconut oil, castor oil, palm oil, tallow, mink oil; hydrocarbon oils such as liquid paraffin, squalane; isopropyl myristate, isopropyl palmitate, stearyl stearate, cetyl palmitate, octyl palmitate; 2-ethylhexyl stearate, stearyl 2-ethylhexanoate, tri-2-
Examples include ester oils such as glyceryl ethylhexanoate and glycerin tri (caprylic / capric acid), and mixtures thereof.
【0009】本発明の化粧料において、前記非イオン性
界面活性剤の混合物の配合割合は、上記HLBとなるよ
うに配合すれば良いが、油剤、水及び非イオン性界面活
性剤の混合物の合計量に対して、通常、3〜15質量
%、好ましくは4〜10質量%である。3質量%未満で
は、製品の安定生が悪くなり、15質量%を超える場合
には油剤を可溶化し過ぎてしまい使用時のエモリエント
効果が減少するので好ましくない。前記油剤の配合割合
は、化粧料全量に対して、通常、50〜97質量%、好
ましくは70〜97質量%である。50質量%未満で
は、エモリエント効果が減少し、97質量%を超える場
合にはべとつき感が酷くなり好ましくない。前記水の配
合割合は、化粧料全量に対して、通常、0.01〜10
質量%、好ましくは0.01〜5質量%である。0.0
1質量%未満では、製品が透明にならず、10質量%を
超える場合には製品が白濁してしまい安定生が悪くなる
ので好ましくない。In the cosmetic of the present invention, the mixture ratio of the nonionic surfactant may be such that the above HLB is obtained, but the total of the mixture of the oil agent, water and the nonionic surfactant is sufficient. It is usually 3 to 15% by mass, preferably 4 to 10% by mass, based on the amount. If the amount is less than 3% by mass, the stability of the product will be poor, and if it exceeds 15% by mass, the oil agent will be excessively solubilized and the emollient effect at the time of use will be undesirably reduced. The mixing ratio of the oil agent is usually 50 to 97% by mass, and preferably 70 to 97% by mass, based on the total amount of the cosmetic. When the amount is less than 50% by mass, the emollient effect decreases, and when the amount exceeds 97% by mass, the sticky feeling becomes severe, which is not preferable. The mixing ratio of the water is usually 0.01 to 10 with respect to the total amount of the cosmetic.
% By mass, preferably 0.01 to 5% by mass. 0.0
If it is less than 1% by mass, the product will not be transparent, and if it exceeds 10% by mass, the product will be cloudy and the stability will be poor.
【0010】本発明の化粧料には、前記非イオン性界面
活性剤、油剤、水の他に、本発明の所望の効果を損なわ
ない範囲で、通常使用しうる安全な各種成分をその化粧
料の種類に応じて適宜組み合わせて配合することができ
る。例えば、入浴剤、化粧水、ローション等に配合する
成分等が挙げられる。具体的には、多価アルコール、抗
炎症剤、動物・植物抽出液、殺菌剤、防腐剤、カチオン
界面活性剤、アニオン界面活性剤、香料等が挙げられる
が、これらに限定されるものではない。The cosmetic of the present invention contains, in addition to the above-mentioned nonionic surfactant, oil and water, various safe ingredients which can be usually used within a range not to impair the desired effects of the present invention. Can be combined in an appropriate combination according to the type of For example, components to be added to bath salts, lotions, lotions and the like can be mentioned. Specific examples include, but are not limited to, polyhydric alcohols, anti-inflammatory agents, animal / plant extracts, bactericides, preservatives, cationic surfactants, anionic surfactants, fragrances, and the like. .
【0011】本発明の化粧料を調製するには、上記必須
成分を含有するように混合することにより得ることがで
きる。本発明の化粧料の使用は、例えば、水又は湯に本
発明の化粧料を投入、混合し、油層及び水中油型乳化物
層の少なくとも2層を形成させた後、通常の方法と同様
に用いることにより使用することができる。この際、化
粧料の希釈率は、化粧料の種類、並びに化粧料の配合組
成等に応じて適宜決定することができる。例えば、入浴
剤に使用する場合には、10000倍程度に希釈し得る
ように設計することが使用上好ましい。The cosmetic of the present invention can be prepared by mixing the above-mentioned essential components so as to contain them. The use of the cosmetic of the present invention can be performed, for example, by charging and mixing the cosmetic of the present invention in water or hot water, forming at least two layers of an oil layer and an oil-in-water emulsion layer, in the same manner as in a usual method. It can be used by using. At this time, the dilution ratio of the cosmetic can be appropriately determined according to the type of the cosmetic, the composition of the cosmetic, and the like. For example, in the case of using as a bath agent, it is preferable in use to design so as to be able to be diluted about 10,000 times.
【0012】[0012]
【発明の効果】本発明の化粧料は、2種以上の特定のH
LBを有する非イオン性界面活性剤の混合物を、油剤と
水とを含む化粧料に配合し、且つ水又は湯に投入するこ
とにより、油層及び水中油型乳化物層の少なくとも2層
が形成されるので、油剤の使用量が、従来の均一乳化物
とする化粧料と同程度であっても、水溶性保湿成分の揮
発を抑制し、優れた保湿効果等が得られ、保持させるこ
とができる。従って、入浴剤、化粧水及び各種ローショ
ンに極めて有用である。The cosmetic of the present invention comprises two or more specific H
By mixing a mixture of non-ionic surfactants having LB into a cosmetic containing an oil and water and adding the mixture to water or hot water, at least two layers, an oil layer and an oil-in-water emulsion layer, are formed. Therefore, even if the amount of the oil agent used is about the same as that of a conventional cosmetic that is a uniform emulsion, it suppresses the volatilization of the water-soluble moisturizing component, provides an excellent moisturizing effect and the like, and can be retained. . Therefore, it is extremely useful for bath salts, lotions and various lotions.
【0013】[0013]
【実施例】以下実施例及び比較例により、本発明を更に
詳細に説明するが、本発明はこれらに限定されるもので
はない。実施例1、2及び比較例1、2 表1に示す各成分を混合調製し、入浴剤を製造した。得
られた入浴剤を40℃200リットルの湯に20ml投
入、混合し、以下に示す各種評価を10人のパネルによ
り行なった。結果を表1に示す。The present invention will be described in more detail with reference to the following Examples and Comparative Examples, but the present invention is not limited thereto. Examples 1 and 2 and Comparative Examples 1 and 2 Each component shown in Table 1 was mixed and prepared to produce a bath agent. 20 ml of the obtained bath agent was put into 200 liters of hot water at 40 ° C. and mixed, and various evaluations shown below were performed by a panel of 10 persons. Table 1 shows the results.
【0014】<油層の形成評価>得られた入浴剤を湯に
投入、混合後、湯面に均一の油層が形成されるか、否か
を目視で観察した。均一の油層が形成されたものを◎、
形成されなかったものを×とする。なお、油層が形成さ
れたものの下層には、水中油型乳化物層が形成されてい
た。 <保湿効果の評価>油層が形成された浴湯に5分間入浴
した後、タオルで湯を拭き取り30分間後の肌の保湿感
を評価した。評価は、保湿感に非常に優れるものを5点
とし、1〜5点の5段階で評価してもらい、10人のパ
ネルの平均点によって以下の評価基準に従って評価し
た。平均点4.0〜5.0点を◎、平均点3.0〜3.
9点を、平均点2.0〜2.9点を△、平均点1.0〜
1.9点を×とした。 <使用感の評価>油層が形成された浴湯に5分間入浴し
た後、タオルで湯を拭き取り30分間後の肌のべとつき
感を評価し、使用感の評価を行なった。評価は、べとつ
き感がなく使用感に非常に優れるものを5点とし、1〜
5点の5段階で評価してもらい、10人のパネルの平均
点によって保湿効果の評価と同様な評価基準に従って評
価した。<Evaluation of formation of oil layer> The obtained bath agent was poured into hot water, mixed and then visually observed whether or not a uniform oil layer was formed on the surface of the hot water. ◎, with a uniform oil layer formed
Those that were not formed are marked with x. Note that an oil-in-water emulsion layer was formed below the layer where the oil layer was formed. <Evaluation of Moisturizing Effect> After bathing in bath water having an oil layer formed thereon for 5 minutes, the hot water was wiped off with a towel and the moisturizing feeling of the skin after 30 minutes was evaluated. The evaluation was performed on a scale of 1 to 5 having a very excellent moisturizing feeling, and the evaluation was made on a scale of 1 to 5, and the evaluation was made according to the following evaluation criteria by the average score of 10 panels. The average score of 4.0 to 5.0 is represented by ◎, and the average score of 3.0 to 3.0.
9 points, average point 2.0 to 2.9 points Δ, average point 1.0 to
1.9 points were evaluated as x. <Evaluation of feeling of use> After bathing in a bath with an oil layer formed thereon for 5 minutes, the hot water was wiped off with a towel, and the feeling of stickiness of the skin after 30 minutes was evaluated to evaluate the feeling of use. The evaluation was evaluated as 5 points, with no stickiness and very excellent usability.
The evaluation was made on a scale of 5 points, and the evaluation was made according to the same evaluation criteria as the evaluation of the moisturizing effect by the average score of 10 panels.
【0015】[0015]
【表1】 [Table 1]
───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 4C083 AB051 AC022 AC352 AC402 AC422 BB04 BB13 CC01 CC04 CC25 DD05 DD23 DD30 DD31 EE05 EE12 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4C083 AB051 AC022 AC352 AC402 AC422 BB04 BB13 CC01 CC04 CC25 DD05 DD23 DD30 DD31 EE05 EE12
Claims (3)
油剤と、水とを含み、含有される非イオン性界面活性剤
の混合物のHLBが6.5〜10.5であり、水又は湯
に投入することにより、油層及び水中油型乳化物層の少
なくとも2層が形成されることを特徴とする化粧料。1. A composition comprising two or more nonionic surfactants,
An HLB of a mixture of a nonionic surfactant containing an oil agent and water is 6.5 to 10.5, and the mixture is poured into water or hot water to form an oil layer and an oil-in-water emulsion layer. A cosmetic comprising at least two layers.
り、水の含有割合が0.01〜10質量%であることを
特徴とする請求項1に記載の化粧料。2. The cosmetic according to claim 1, wherein the content of the oil agent is 50 to 97% by mass and the content of water is 0.01 to 10% by mass.
ンであり、入浴剤成分、化粧水成分又はローション成分
を含むことを特徴とする請求項1又は2に記載の化粧
料。3. The cosmetic according to claim 1, wherein the cosmetic is a bath salt, a lotion or a lotion, and contains a bath agent component, a lotion component or a lotion component.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000314597A JP2002121114A (en) | 2000-10-16 | 2000-10-16 | Cosmetic |
Applications Claiming Priority (1)
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JP2007001917A (en) * | 2005-06-23 | 2007-01-11 | Pola Chem Ind Inc | Rinsing cosmetic |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2007001917A (en) * | 2005-06-23 | 2007-01-11 | Pola Chem Ind Inc | Rinsing cosmetic |
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