JP2002105862A - Method for producing fabric product - Google Patents

Method for producing fabric product

Info

Publication number
JP2002105862A
JP2002105862A JP2000287689A JP2000287689A JP2002105862A JP 2002105862 A JP2002105862 A JP 2002105862A JP 2000287689 A JP2000287689 A JP 2000287689A JP 2000287689 A JP2000287689 A JP 2000287689A JP 2002105862 A JP2002105862 A JP 2002105862A
Authority
JP
Japan
Prior art keywords
fiber fabric
dyeing
resin film
fabric
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000287689A
Other languages
Japanese (ja)
Other versions
JP3756050B2 (en
Inventor
Taiji Takagi
泰治 高木
Mutsuko Miyamoto
むつ子 宮元
Kenji Nitta
健二 新田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Komatsu Seiren Co Ltd
Original Assignee
Komatsu Seiren Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Komatsu Seiren Co Ltd filed Critical Komatsu Seiren Co Ltd
Priority to JP2000287689A priority Critical patent/JP3756050B2/en
Publication of JP2002105862A publication Critical patent/JP2002105862A/en
Application granted granted Critical
Publication of JP3756050B2 publication Critical patent/JP3756050B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide a method for producing a fabric product delivered in a short time to timely supply the commodity desired by a consumer to a market, in which a fabric is used on the surface, capable of importing to the surface or a resin film surface, natural wrinkles and crepes as a design and also imparting integrated touch and a dry touch due to the crepes. SOLUTION: This method for producing the fiber fabric product whose fiber fabric substrate is used as the surface in at least one part, including a process for integrating the fiber fabric substrate with the resin film containing a synthetic resin as a main component to form the fiber fabric and then subjecting the fiber fabric to a dyeing treatment.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、繊維布帛製品の製
造方法に関する。本発明は、特に、繊維布帛基材と樹脂
膜とが複合されており、少なくともその一部において繊
維布帛基材側が表面として使用される布帛製品を製造す
るための方法に関する。
[0001] The present invention relates to a method for producing a fiber fabric product. In particular, the present invention relates to a method for producing a fabric product in which a fiber fabric substrate and a resin film are composited, and at least a part of which is used on the fiber fabric substrate side as a surface.

【0002】[0002]

【従来の技術】従来、樹脂膜を有する繊維布帛製品の製
造は、織物、編物、不織布などを染色した後、樹脂膜を
付与し、その後縫製することにより帽子、手袋、衣服、
スキーウエアー、カバン、テント等として製品化するこ
とによっていた。このような工程を経て繊維布帛製品を
製造する方法は、品質の安定した製品を大量に製造する
ことができる点で優れている。しかしながら、現在のよ
うに消費者の嗜好が急速に変化する時代においては、製
品の短納期化が最も重要であり、製造者側が消費者の嗜
好をつかんでから、糸の製造、織物の製造、染色加工、
膜加工および縫製を行うという従来の製造方法によって
製造していたのでは時間がかかりすぎてしまい、消費者
の望んでいる商品をタイムリーに市場に提供することは
不可能である。特に、スキーウエアーをはじめとする防
寒具では、納品までに時間がかかってしまえば確実にビ
ジネスチャンスを逃してしまうことになる。
2. Description of the Related Art Conventionally, a fiber fabric product having a resin film has been produced by dyeing a woven fabric, a knitted fabric, a nonwoven fabric, etc., applying a resin film, and then sewing the hat, gloves, clothes,
It was based on commercialization as ski wear, bags and tents. The method of producing a fiber fabric product through such a process is excellent in that a product of stable quality can be produced in large quantities. However, in today's era where consumer preferences change rapidly, shortening the delivery time of products is the most important. After the manufacturer grasps the consumer's preferences, production of yarn, production of textiles, Dyeing,
Manufacturing by the conventional manufacturing method of performing film processing and sewing takes too much time, and it is impossible to provide a product desired by consumers to the market in a timely manner. In particular, in winter clothing such as ski wear, if it takes time to deliver, business opportunities will surely be missed.

【0003】また、従来の方法で得られた樹脂膜を有す
る繊維布帛に対してシボ加工やシワ加工を行って得られ
る製品においては、繊維布帛基材にシボ加工やシワ加工
を行なった後に膜を付与しているため、シボやシワが弱
かったり、自然なシボ感やシワ感が消滅してしまってい
るといった問題点があった。さらに、従来、防水性を必
要とされる、繊維布帛基材に樹脂膜を付与した繊維布帛
では、洗濯処理により耐水圧が低下することが知られて
いた。従って、温度や処理液の組成(酸、アルカリ、還
元剤等が添加されている)からみて、洗濯処理よりもは
るかに厳しい条件下に行われる染色処理を、樹脂膜を付
与した後に行うことは不可能であると考えられていた。
Further, in a product obtained by subjecting a fiber cloth having a resin film obtained by a conventional method to graining or wrinkling, a film obtained after graining or wrinkling a fiber fabric base material. Therefore, there is a problem that the texture and wrinkles are weak, and the natural texture and wrinkles disappear. Further, conventionally, it has been known that the water pressure of a fiber fabric, which is required to have a waterproof property and is provided with a resin film on a fiber fabric substrate, is reduced by the washing treatment. Therefore, in view of the temperature and the composition of the treatment liquid (acid, alkali, reducing agent, etc. are added), it is difficult to perform the dyeing treatment that is performed under much more severe conditions than the washing treatment after applying the resin film. It was considered impossible.

【0004】[0004]

【発明が解決しようとする課題】本発明は、上記問題点
を解決し、消費者が望んでいる商品をタイムリーに市場
に供給できるように製品の短納期化が可能となり、また
意匠面においても自然なシワやシボを繊維布帛基材面や
樹脂膜面に付与することができ、さらに一体感のある風
合やシボによるドライ感のあるタッチを付与することの
できる、繊維布帛基材側が表面として使用される布帛製
品の製造方法を提供しようとするものである。
DISCLOSURE OF THE INVENTION The present invention solves the above-mentioned problems and shortens the delivery time of products so that the products desired by consumers can be supplied to the market in a timely manner. Also, natural wrinkles and crimps can be imparted to the surface of the fiber fabric substrate or the resin film surface, and furthermore, the fiber fabric substrate side, which can impart a feeling of unity and a dry touch by the crimps, It is an object of the present invention to provide a method for producing a fabric product used as a surface.

【0005】[0005]

【課題を解決するための手段】本発明は、上記課題を解
決するため、繊維布帛基材と合成樹脂を主成分とする樹
脂膜とを一体化して繊維布帛を形成した後、これを染色
処理に付すことを含む、少なくともその一部において繊
維布帛基材側が表面として使用される繊維布帛製品の製
造方法を提供する。
In order to solve the above-mentioned problems, the present invention integrates a fiber fabric base and a resin film containing a synthetic resin as a main component to form a fiber fabric, which is then subjected to a dyeing treatment. The present invention provides a method for producing a fiber fabric product in which the fiber fabric substrate side is used as a surface in at least a part thereof.

【0006】[0006]

【発明の実施の形態】本発明に有用な繊維布帛基材は、
ポリエステル、ナイロン等の合成繊維、ジアセテート、
トリアセテート等の半合成繊維、レーヨン等の再生繊
維、綿、絹、羊毛等の天然繊維、またはそれらの2種以
上の混繊もしくは交織繊維からなる繊維布帛であってよ
く、それらは織物、編物、不織布等のいかなる形態にあ
ってもよい。
BEST MODE FOR CARRYING OUT THE INVENTION A fiber fabric substrate useful in the present invention is:
Synthetic fibers such as polyester and nylon, diacetate,
Semi-synthetic fibers such as triacetate, regenerated fibers such as rayon, cotton, silk, natural fibers such as wool, or fiber fabrics composed of a blended or interwoven fiber of two or more thereof may be woven, knitted, It may be in any form such as a nonwoven fabric.

【0007】また、合成樹脂としては、ウレタン樹脂、
アクリル樹脂、塩化ビニル樹脂、シリコン樹脂、ポリテ
トラフルオロエチレン樹脂を含むフッ素樹脂、ポリエス
テル樹脂等が挙げられる。本発明の繊維布帛における樹
脂膜は、これらの樹脂を主成分とするものであるが、膜
の形態としては無孔質であっても、多孔質であってもよ
く、またこれらを組合せたものであってもよい。膜の厚
さは約0.5μm〜5mm程度であるのが好ましい。
As the synthetic resin, urethane resin,
An acrylic resin, a vinyl chloride resin, a silicone resin, a fluororesin including a polytetrafluoroethylene resin, a polyester resin, and the like can be given. The resin film in the fiber cloth of the present invention contains these resins as main components. The form of the film may be nonporous or porous, or a combination thereof. It may be. The thickness of the film is preferably about 0.5 μm to 5 mm.

【0008】本発明において、繊維布帛基材と一体化さ
れる樹脂膜は、上記の合成樹脂の他に、所望により、顔
料、架橋剤、酸化防止剤、可塑剤や、炭酸カルシウム、
シリカ等の無機微粒子、プロテインパウダー等の有機微
粒子等の添加剤を含んでいてもよい。繊維布帛基材への
合成樹脂を主成分とする樹脂膜の付与方法としては、所
望により上記添加剤を含む合成樹脂またはその溶液をナ
イフコーターやグラビアコーター、ダイコーターなどを
用い、繊維布帛またはこれに多孔質膜や無孔質膜などが
付与された繊維布帛からなる繊維布帛基材に直接コート
するダイレクトコーティングや、同様にして離型紙の上
に樹脂膜を形成し、その上に接着剤を点状もしくは線状
にまたは全面に付与した後、上記の如き繊維布帛基材と
貼り合わせるラミネート法を用いることもできる。ここ
で、樹脂膜の形成は、公知の乾式法または湿式法のいず
れによってもよい。
In the present invention, in addition to the above synthetic resin, the resin film integrated with the fiber fabric base material may optionally include a pigment, a crosslinking agent, an antioxidant, a plasticizer, calcium carbonate,
An additive such as inorganic fine particles such as silica and organic fine particles such as protein powder may be contained. As a method for applying a resin film containing a synthetic resin as a main component to a fiber cloth base material, if necessary, a synthetic resin containing the above-mentioned additive or a solution thereof is coated using a knife coater, a gravure coater, a die coater, or the like. Direct coating on a fiber fabric substrate consisting of a fiber fabric provided with a porous film or a non-porous film, or a resin film is formed on release paper in the same manner, and an adhesive is applied thereon. A laminating method in which the material is applied in a dot or line shape or on the entire surface and then bonded to the fiber fabric substrate as described above can also be used. Here, the formation of the resin film may be performed by any of a known dry method or wet method.

【0009】ラミネート法に用いられる接着剤として
は、染色後の繊維布帛に所望される規格物性を保持でき
るものであれば何を用いてもよいが、基本的には樹脂膜
を構成する樹脂と同系の樹脂からなる接着剤が好まし
い。また、本発明においては、上記のようにして繊維布
帛基材の一面に樹脂膜を付与することにより樹脂膜を含
む繊維布帛としてもよく、またこの樹脂膜上にこの膜を
挟んでさらに繊維布帛基材を付与し、一体化したもので
あってもよい。
As the adhesive used in the laminating method, any adhesive can be used as long as it can maintain the desired physical properties of the fiber fabric after dyeing. Adhesives composed of similar resins are preferred. Further, in the present invention, a fiber cloth containing a resin film may be obtained by applying a resin film to one surface of the fiber cloth base material as described above, or the fiber cloth may be further sandwiched between the resin film and the fiber cloth. A substrate may be provided and integrated.

【0010】本発明の方法によれば、予め樹脂膜を含む
後染め用繊維布帛を形成しておき、流行色や流行のデザ
インをつかんでから染色し、縫製のみを行なえばよいの
で、製品を市場に短納期で供給することができ、ビジネ
スチャンスを逃す危険性が効果的に回避される。さら
に、この後染め用繊維布帛が縫製までされていれば、市
場の流行をつかんで染色のみを行なえばよいことにな
り、市場の要求にマッチする製品をさらに短納期で、タ
イミングよく市場に出すことができる。
[0010] According to the method of the present invention, a fiber fabric for post-dyeing including a resin film is formed in advance, and a fashionable color or a fashionable design is grasped and then dyed, and only sewing is performed. The market can be supplied in a short delivery time, and the risk of missing business opportunities is effectively avoided. Furthermore, if the post-dyeing fiber fabric has been sewn, only the dyeing has to be performed to catch the trend of the market, and a product that meets the demands of the market is put on the market in a shorter delivery time and in a timely manner. be able to.

【0011】なお、染色処理に際しては、繊維布帛基材
および樹脂膜の構成に応じて、それらに適した任意の条
件下に処理を行なえばよく、特に限定されるものではな
い。染料としては、分散染料、酸性染料、直接染料、反
応染料、媒染染料、塩基性染料、建染染料、硫化染料、
アゾイック染料等の任意のものを用いることができ、ま
た染色方法についても、浸染、サーモゾール染色、コー
ルドバッチ染色などの任意の方法を用いることができる
が、大きなシボ、シワ等を表現したい場合(意匠性の観
点)や縫製後に染色を行なう場合(作業性の観点)に
は、浸染法、特に常圧ワッシャー、高圧ワッシャーなど
のような繊維製品に張力のかかり難い浸染用の装置を用
いる方法が好ましい。
In the dyeing treatment, the treatment may be carried out under any conditions suitable for the fiber fabric base material and the resin film, and is not particularly limited. As the dye, disperse dye, acid dye, direct dye, reactive dye, mordant dye, basic dye, vat dye, sulfur dye,
Any dye such as azoic dye can be used, and any dyeing method such as dip dyeing, thermosol dyeing and cold batch dyeing can be used. In the case of performing dyeing after sewing (perspective of workability) or sewing (perspective of workability), it is preferable to use a dyeing method, particularly a method using a dyeing dyeing apparatus such as a normal pressure washer, a high pressure washer, etc., which hardly applies tension to textiles. .

【0012】染色後の堅牢度の観点からは、染料によっ
て汚染されにくい合成樹脂を主成分とする樹脂膜を有す
る繊維布帛であるのが好ましい。また、染色後やその後
のフィックス処理後に公知の界面活性剤を用いて洗浄処
理を行ってもよい。また、上記のようにして、樹脂膜を
有する繊維布帛を染色することにより、繊維布帛基材と
付与された樹脂膜との間の収縮差等により、繊維布帛基
材面および樹脂膜面に自然なシワやシボがあらわれ、ま
た繊維布帛基材と樹脂膜との一体感が得られる。さら
に、樹脂膜面のシワやシボにより肌に膜が触れた場合に
おいても貼りつくような感じがなく、ドライな感じが得
られる。従って、これにより、外観、風合、タッチ等の
意匠性に優れている上に、ドライ感があり、透湿性が多
少低くても、着用者が快適に感じることができる繊維布
帛製品を与えることができる。
From the viewpoint of the fastness after dyeing, it is preferable to use a fiber cloth having a resin film containing a synthetic resin as a main component which is not easily contaminated by the dye. Further, after the dyeing or after the fixing treatment, the washing treatment may be performed using a known surfactant. In addition, by dyeing the fiber cloth having the resin film as described above, a difference in shrinkage between the fiber cloth base material and the applied resin film or the like causes a natural change in the fiber cloth base material surface and the resin film surface. Wrinkles and creasing appear, and a sense of unity between the fiber fabric substrate and the resin film can be obtained. Furthermore, even when the film comes into contact with the skin due to wrinkles or wrinkles on the resin film surface, there is no sticking feeling and a dry feeling can be obtained. Therefore, thereby, it is possible to provide a fiber fabric product which is excellent in design such as appearance, feeling, touch, etc., has a dry feeling, and can be comfortably felt by a wearer even if the moisture permeability is somewhat low. Can be.

【0013】本発明の方法により得られる繊維布帛製品
においては、後染めされた後の繊維布帛の耐水圧が25
0mmH2 O(JIS L1092 低水圧法または高
水圧法)以上であるのが好ましく、透湿度が1000g
/cm2 ・24hrs以上(JIS L1099 塩化
カルシウム法)であり、かつ、耐水圧が1000mmH
2 O以上(JIS L1092 低水圧法または高水圧
法)であるのがさらに好ましい。
[0013] In the fiber fabric product obtained by the method of the present invention, the water-resistant pressure of the post-dyed fiber fabric is 25.
0 mmH 2 O (JIS L1092 low water pressure method or high water pressure method) or more, and a water vapor transmission rate of 1000 g
/ Cm 2 · 24 hrs or more (JIS L1099 calcium chloride method) and a water pressure resistance of 1000 mmH
More preferably, it is 2 O or more (JIS L1092 low water pressure method or high water pressure method).

【0014】また、透湿度が5000g/cm2 ・24
hrs以上(JIS L1099酢酸カリウム法)であ
り、かつ、耐水圧が10000mmH2 O以上(JIS
L1092 高水圧法)であるのが好ましく、透湿度が
10000g/cm2 ・24hrs以上(JIS L1
099 酢酸カリウム法)であり、かつ、耐水圧が10
000mmH2 O以上(JIS L1092 高水圧
法)あるのがさらに好ましい。
The moisture permeability is 5000 g / cm 2 · 24.
a hrs or more (JIS L1099 potassium acetate method), and water pressure resistance 10000mmH 2 O or more (JIS
L1092 high water pressure method), and has a moisture permeability of 10,000 g / cm 2 · 24 hrs or more (JIS L1
099 potassium acetate method) and a water pressure resistance of 10
More preferably, it is 000 mmH 2 O or more (JIS L1092 high water pressure method).

【0015】繊維布帛製品の樹脂膜は、染色および洗濯
による耐水圧の低下を防ぐ観点からは、ポリテトラフル
オロエチレン樹脂を用いた多孔質膜や他の合成樹脂を用
いた無孔質膜であるのが特に好ましいが、耐水圧が低下
する多孔質膜であってもその膜の上にコーティングやラ
ミネートにより無孔質膜を付与することにより耐水圧の
低下を防ぐこともできる。
The resin film of the fiber fabric product is a porous film using a polytetrafluoroethylene resin or a non-porous film using another synthetic resin from the viewpoint of preventing a decrease in water pressure due to dyeing and washing. Although it is particularly preferred, even for a porous membrane having a reduced water pressure, a decrease in the water pressure can be prevented by providing a nonporous film by coating or laminating on the film.

【0016】後染めされた後の繊維布帛は、洗濯耐久性
のある耐水圧を示すのがよく、JIS L0217 1
03法による洗濯を10回行った後の耐水圧保持率が8
0%以上あるのが好ましい。さらに、必要に応じ、染色
前または染色と同時または染色後に、撥水、制電、制
菌、消臭、防汚、防炎、紫外線遮蔽、吸水、防縮加工を
行ない、得られる布帛にこれらの性能を付与してもよ
い。
The post-dyed fiber cloth preferably has a water pressure resistant to washing durability, and is preferably JIS L0217 1
The water pressure retention rate after 8 washes by the 03 method was 8
It is preferably at least 0%. Further, if necessary, before or at the same time as or after dyeing, water repellency, antistatic, antibacterial, deodorant, antifouling, flameproof, ultraviolet shielding, water absorption, shrinkage-proofing, and the resulting cloth Performance may be provided.

【0017】[0017]

【実施例】以下、実施例および比較例により本発明をさ
らに説明する。なお、得られた後染め用繊維布帛の染色
後の性能は、以下の方法により測定したものである。 耐水性 JIS L1092 低水圧法または高水圧法により測
定。水圧をかけることにより試験片が伸びる場合には、
試験片の上にナイロンタフタ(たて密度(2.54cm
当り)とよこ密度(2.54cm当り)の和が210程
度のもの)などを重ねて試験機に取り付け、測定を行っ
た。ただし、高水圧法で測定したものの単位は、低水圧
法の測定値と比較しやすくするため、9.8kPa=水
柱1000mmとして換算した。
The present invention will be further described below with reference to examples and comparative examples. In addition, the performance after dyeing of the obtained fiber fabric for post-dyeing was measured by the following method. Water resistance Measured by JIS L1092 low water pressure method or high water pressure method. If the test piece is stretched by applying water pressure,
Nylon taffeta (vertical density (2.54 cm
Per unit) and the lateral density (per unit of 2.54 cm) of about 210) were mounted on a tester and measured. However, the unit of the value measured by the high water pressure method was converted as 9.8 kPa = 1000 mm of water column to facilitate comparison with the measured value of the low water pressure method.

【0018】透湿性 JIS L1099 塩化カルシウム法または酢酸カリ
ウム法により測定。ただし、単位を24時間に換算し
た。 洗濯耐久性 JIS L0217 103法により洗濯を行い、洗濯
耐久性をみた。
Moisture permeability Measured by the JIS L1099 calcium chloride method or potassium acetate method. However, the unit was converted to 24 hours. Washing durability Washing was performed according to JIS L0217 103 method, and the washing durability was examined.

【0019】膜面摩擦堅牢度 JIS L0849により評価 染色収縮率 染色前に対する染色後の収縮率を求めた。縮みを正の数
で示し、伸びを負の数で示す。
Membrane surface friction fastness Evaluated according to JIS L0849. Dye shrinkage The shrinkage after dyeing before dyeing was determined. Shrinkage is indicated by a positive number and elongation is indicated by a negative number.

【0020】剥離強力 JIS L1089により測定。ただし、単位を1cm
当りに換算した。 実施例1 ナイロン製綾織物(タテ糸70デニール/17フィラメ
ント、ヨコ糸70デニール/68フィラメント)に対
し、常法により精練およびセットを行った。
Peel strength Measured according to JIS L1089. However, the unit is 1cm
It was converted to per hit. Example 1 A nylon twill fabric (vertical yarn 70 denier / 17 filaments, weft yarn 70 denier / 68 filaments) was scoured and set by a conventional method.

【0021】次に、下記樹脂処方の混合樹脂溶液をフル
ダル離型紙(リンテック(株)製、TPD)に付与し、
乾燥し、厚さ10μmのポリウレタン樹脂を主成分とす
る無孔質膜を得た。 混合樹脂溶液 難黄変型エステルエーテル系ポリウレタン樹脂 100重量部 (固形分30%) メチルエチルケトン 40重量部 ジメチルホルムアミド 10重量部 白色顔料 6重量部 次に、上記膜面に下記処方の接着剤溶液を付与し、乾燥
し、厚さ20μmの接着層を作成した後、上記のナイロ
ン織物に貼り合せ、60℃で2日間エージングを行っ
た。
Next, a mixed resin solution having the following resin formulation was applied to Fuldal release paper (TPD, manufactured by Lintec Corporation).
After drying, a non-porous membrane having a thickness of 10 μm and containing a polyurethane resin as a main component was obtained. Mixed resin solution Non-yellowing type ester ether-based polyurethane resin 100 parts by weight (solid content 30%) Methyl ethyl ketone 40 parts by weight Dimethylformamide 10 parts by weight White pigment 6 parts by weight Next, an adhesive solution having the following formulation was applied to the film surface. After drying and forming an adhesive layer having a thickness of 20 μm, the adhesive layer was bonded to the nylon fabric and aged at 60 ° C. for 2 days.

【0022】 接着剤溶液 エステルエーテル系ポリウレタン樹脂 100重量部 (固形分60%、水膨潤率5%) トルエン 60重量部 メチルエチルケトン 10重量部 コロネートHL(架橋剤、日本ポリウレタン工業(株)製) 10重量部 HI215(触媒、大日精化工業(株)製) 1重量部 エージングを行なった後、離型紙を剥がし、樹脂膜を有
する布帛を得た。次いで、この布帛を、そのナイロン織
物側を表面側としてヤッケに縫製し、樹脂膜を含む後染
め用繊維布帛からなる縫製品を得た。
Adhesive solution Ester ether type polyurethane resin 100 parts by weight (solid content 60%, water swelling ratio 5%) Toluene 60 parts by weight Methyl ethyl ketone 10 parts by weight Coronate HL (crosslinking agent, manufactured by Nippon Polyurethane Industry Co., Ltd.) 10 parts by weight Part HI215 (catalyst, manufactured by Dainichi Seika Kogyo Co., Ltd.) 1 part by weight After aging, the release paper was peeled off to obtain a cloth having a resin film. Next, this fabric was sewn on a jacket with the nylon fabric side as the surface side to obtain a sewn product comprising a post-dyeing fiber fabric including a resin film.

【0023】次に、この縫製品を、染料役者((株)オ
ノモリ製のワッシャータイプ高圧型染色機)により、M
itsui Nylon Black GLe/c(三
井BASF染料(株)製)3%owfを用いて100℃
で30分間染色し、洗浄(70℃×10分)を行い、デ
ィマフィックスESK(明成化学工業(株)製)1%o
wfを用いて60℃で20分間フィックス処理を行っ
た。
Next, the sewn product is subjected to a dye actor (Washer type high-pressure dyeing machine manufactured by Onomori Co., Ltd.)
100 ° C. using 3% owf of itsui Nylon Black GLe / c (manufactured by Mitsui BASF Dyestuffs Co., Ltd.)
For 30 minutes, washing (70 ° C. × 10 minutes), 1% o of Dimafix ESK (manufactured by Meisei Chemical Industry Co., Ltd.)
Fix processing was performed at 60 ° C. for 20 minutes using wf.

【0024】さらに、その後、スプレー(旭硝子(株)
製アサヒガード)にて撥水処理を行い、黒色に染色され
たヤッケを得た。得られたヤッケはナチュラルなシワと
シボを有し、樹脂膜面の肌触りもドライ感のあるもので
あった。また、これらの染色および撥水処理に必要な日
数は1日であった。
Further, after that, spray (Asahi Glass Co., Ltd.)
(Asahi Guard Co., Ltd.) to obtain a black dyed Yakke. The obtained Yakke had natural wrinkles and wrinkles, and the feel of the resin film surface was dry. The number of days required for these dyeing and water-repellent treatments was one day.

【0025】染色前と染色後の透湿度、耐水圧、膜面摩
擦堅牢度、収縮率および剥離強力を求め、表1に記し
た。
Before and after dyeing, the moisture permeability, water pressure resistance, film surface friction fastness, shrinkage and peel strength were determined and are shown in Table 1.

【0026】[0026]

【表1】 [Table 1]

【0027】比較例1 精練、セット、染色(液流染色機を用いた)されたもの
を繊維布帛基材として用い、後染め加工を行わなかった
以外は実施例1と全く同様にして、繊維製品を得た。得
られた繊維製品のは、糸の準備からではなく、生機から
の加工によるものであったが、流行色をつかみ、生機か
ら加工して市場に出すまでに約2ヶ月間かかった。
COMPARATIVE EXAMPLE 1 Fibers which had been scoured, set and dyed (using a liquid jet dyeing machine) were used as a fiber fabric base material, and the fiber was prepared in exactly the same manner as in Example 1 except that post dyeing was not performed. Got the product. The obtained textile product was not processed from yarn preparation but processed from a greige machine, but it took about two months to catch the trendy color, process from the greige machine and put it on the market.

【0028】また、この製品の樹脂膜面は平滑で、シボ
やシワがなく、手でさわると貼りつく感じがした。 実施例2 ナイロン製綾織物(タテ糸70デニール/17フィラメ
ント、ヨコ糸70デニール/68フィラメント)に対
し、常法により精練およびセットを行った。
The surface of the resin film of this product was smooth, free of wrinkles and wrinkles, and felt sticky when touched by hand. Example 2 A nylon twill fabric (vertical yarn 70 denier / 17 filaments, weft yarn 70 denier / 68 filaments) was scoured and set by a conventional method.

【0029】この織物の上に下記処方の混合樹脂溶液を
スリット0.13mmで塗布し、次いで水中で凝固し、
脱溶媒し、洗浄し、乾燥して、多孔質膜を有する繊維布
帛を得た。 混合樹脂溶液 エステル系ウレタン樹脂(固形分30%) 100重量部 ジメチルホルムアミド 40重量部 次に、この布帛を実施例1と同様にしてヤッケに縫製
し、樹脂膜を含む後染め用繊維布帛からなる縫製品を得
た。
On the woven fabric, a mixed resin solution having the following formulation was applied with a slit of 0.13 mm, and then coagulated in water.
The solvent was removed, washed, and dried to obtain a fiber fabric having a porous membrane. Mixed resin solution Ester urethane resin (solid content: 30%) 100 parts by weight Dimethylformamide 40 parts by weight Next, this fabric is sewn on a jacket in the same manner as in Example 1, and is made of a post-dyeing fiber fabric including a resin film. A sewn product was obtained.

【0030】次に、この縫製品を、染料役者((株)オ
ノモリ製のワッシャータイプ高圧型染色機)により、M
itsui Nylon Black GLe/c(三
井BASF染料(株)製)3%owfを用いて100℃
で30分間染色し、洗浄(70℃10分)を行い、ディ
マフィックスESK(明成化学工業製)1%owfを用
い、60℃で20分間フィックス処理を行った。
Next, the sewn product was treated with a dye actor (washer-type high-pressure dyeing machine manufactured by Onomori Co., Ltd.)
100 ° C. using 3% owf of itsui Nylon Black GLe / c (manufactured by Mitsui BASF Dyestuffs Co., Ltd.)
For 30 minutes, washing (70 ° C. for 10 minutes), and fix treatment at 60 ° C. for 20 minutes using 1% owf of Dimafix ESK (manufactured by Meisei Chemical Industry Co., Ltd.).

【0031】さらに、その後、スプレー(旭硝子(株)
製アサヒガード)にて撥水処理を行い、黒色に染色され
たヤッケを得た。得られたヤッケはナチュラルなシワと
シボを有し、樹脂膜面の肌触りもドライ感のあるもので
あった。また、これらの染色および撥水処理に必要な日
数は1日であった。
Further, after that, spray (Asahi Glass Co., Ltd.)
(Asahi Guard Co., Ltd.) to obtain a black dyed Yakke. The obtained Yakke had natural wrinkles and wrinkles, and the feel of the resin film surface was dry. The number of days required for these dyeing and water-repellent treatments was one day.

【0032】染色前と染色後の透湿度、耐水圧、膜面摩
擦堅牢度、収縮率および剥離強力を求め、表2に記し
た。
Before and after dyeing, the moisture permeability, water pressure resistance, film surface friction fastness, shrinkage, and peel strength were determined and are shown in Table 2.

【0033】[0033]

【表2】 [Table 2]

【0034】実施例3 ナイロン製綾織物(タテ糸70デニール/17フィラメ
ント、ヨコ糸70デニール/68フィラメント)に対
し、常法により精練およびセットを行った。この織物の
上に下記処方の混合樹脂溶液をスリット0.13mmで
塗布し、次いで水中で凝固し、脱溶媒し、洗浄し、乾燥
して、多孔質膜を有する繊維布帛を得た。
Example 3 Nylon twill fabric (vertical yarn 70 denier / 17 filament, weft yarn 70 denier / 68 filament) was scoured and set by a conventional method. A mixed resin solution having the following formulation was applied on the woven fabric with a slit of 0.13 mm, then solidified in water, desolvated, washed, and dried to obtain a fiber fabric having a porous membrane.

【0035】 混合樹脂溶液 エステル系ウレタン樹脂(固形分30%) 100重量部 ジメチルホルムアミド 40重量部 次に、得られた多孔質膜の上に、下記処方の配合樹脂溶
液を30g/m2 の量で付与し、乾燥し、前記多孔質膜
上に無孔質膜を持つ繊維布帛を得た。
Mixed resin solution Ester urethane resin (solid content: 30%) 100 parts by weight Dimethylformamide 40 parts by weight Next, on the obtained porous membrane, a mixed resin solution having the following formulation was added in an amount of 30 g / m 2 . And dried to obtain a fiber cloth having a nonporous membrane on the porous membrane.

【0036】 配合樹脂溶液 無黄変型エーテルエステル系ポリウレタン樹脂 100重量部 (固形分27%) マット剤含有無黄変型ポリウレタン樹脂(固形分15%) 10重量部 コロネートHL(架橋剤、日本ポリウレタン工業(株)製) 4重量部 次いで、得られた布帛を用い、そのナイロン織物側を表
面側にしてウインドブレーカーを縫製し、樹脂膜を有す
る繊維布帛からなる縫製品を得た。
100% by weight (solid content: 27%) Non-yellowing type polyurethane resin containing a matting agent (solid content: 15%) 10 parts by weight Coronate HL (crosslinking agent, Nippon Polyurethane Industry Co., Ltd.) Then, using the obtained fabric, a windbreaker was sewn with the nylon fabric side facing the surface side to obtain a sewn product made of a fiber fabric having a resin film.

【0037】次に、この縫製品を、染料役者((株)オ
モノリ製のワッシャータイプ高圧型染色機)により、M
itsui Nylon Black GLe/c(三
井BASF染料(株)製)3%owfを用いて100℃
で30分間染色し、洗浄(70℃10分)を行い、ディ
マフィックスESK(明成化学工業製)1%owfを用
い、60℃で20分間フィックス処理を行った。
Next, the sewn product was treated with a dye actor (washer type high-pressure dyeing machine manufactured by Omonori Co., Ltd.)
100 ° C. using 3% owf of itsui Nylon Black GLe / c (manufactured by Mitsui BASF Dyestuffs Co., Ltd.)
For 30 minutes, washing (70 ° C. for 10 minutes), and fix treatment at 60 ° C. for 20 minutes using 1% owf of Dimafix ESK (manufactured by Meisei Chemical Industry Co., Ltd.).

【0038】さらに、その後、スプレー(旭硝子(株)
製アサヒガード)にて撥水処理を行い、黒色に染色され
たウインドブレーカーを得た。得られたウインドブレー
カーはナチュラルなシワとシボを有し、樹脂膜面の肌触
りもドライ感のあるものであった。また、これらの染色
および撥水処理に必要な日数は1日であった。
After that, spraying (Asahi Glass Co., Ltd.)
(Asahi Guard Co., Ltd.) to obtain a windbreaker dyed black. The obtained windbreaker had natural wrinkles and wrinkles, and the feel of the resin film surface was dry. The number of days required for these dyeing and water-repellent treatments was one day.

【0039】染色前と染色後の透湿度、耐水圧、膜面摩
擦堅牢度、収縮率および剥離強力を求め、表3に記し
た。
Before and after dyeing, the moisture permeability, water pressure resistance, film surface friction fastness, shrinkage and peel strength were determined and are shown in Table 3.

【0040】[0040]

【表3】 [Table 3]

【0041】実施例4 ナイロン製綾織物(タテ糸70デニール/17フィラメ
ント、ヨコ糸70デニール/68フィラメント)に対
し、常法により精練およびセットを行った。ポリテトラ
フオロエチレン膜(JIS L1099 B−2法で使
用されるものであって、多孔質膜)上に、接着剤として
湿気硬化ポリウレタン樹脂を用いて130℃のホットメ
ルトグラビアコーテイング(塗布量20g/m2 、38
メッシュ)を行い、次いで上記ナイロン織物と熱ロール
圧着(130℃、エアー圧4kg、5m/分)させた
後、室温で2日間エージングを行った。
Example 4 Nylon twill fabric (vertical yarn 70 denier / 17 filament, weft yarn 70 denier / 68 filament) was scoured and set by a conventional method. On a polytetrafluoroethylene film (used in the JIS L1099 B-2 method, a porous film), a 130 ° C. hot melt gravure coating (a coating amount of 20 g / m 2 , 38
(Mesh), followed by hot roll compression bonding (130 ° C., air pressure 4 kg, 5 m / min) with the above-mentioned nylon fabric, followed by aging at room temperature for 2 days.

【0042】エージングを行なった後、この繊維布帛を
実施例1と同様にして袋に縫製し、樹脂膜を含む後染め
用繊維布帛からなる縫製品を得た。次に、この縫製品
を、染料役者((株)オノモリ製のワッシャータイプ高
圧型染色機)により、Mitsui Nylon Bl
ack GLe/c(三井BASF染料(株)製)3%
owfを用いて100℃で30分間染色し、洗浄(70
℃10分)を行い、ディマフィックスESK(明成化学
工業製)1%owfを用い、60℃で20分間フィック
ス処理を行った。
After aging, this fiber cloth was sewn into a bag in the same manner as in Example 1 to obtain a sewn product comprising a post-dyeing fiber cloth including a resin film. Next, this sewn product was subjected to Mitsui Nylon Bl by a dye actor (a washer-type high-pressure dyeing machine manufactured by Onomori Co., Ltd.).
ack GLe / c (Mitsui BASF Dyeing Co., Ltd.) 3%
owf for 30 minutes at 100 ° C., washing (70
(10 ° C. for 10 minutes), and fixation was performed at 60 ° C. for 20 minutes using 1% owf of Dimafix ESK (manufactured by Meisei Chemical Industry Co., Ltd.).

【0043】さらに、その後、スプレー(旭硝子(株)
製アサヒガード)にて撥水処理を行い、黒色に染色され
た袋を得た。得られた袋はナチュラルなシワとシボを有
し、樹脂膜面の肌触りもドライ感のあるものであった。
また、これらの染色および撥水処理に必要な日数は1日
であった。
Further, after that, spray (Asahi Glass Co., Ltd.)
(Asahi Guard Co., Ltd.) to obtain a bag dyed black. The obtained bag had natural wrinkles and wrinkles, and the resin film surface had a dry touch.
The number of days required for these dyeing and water-repellent treatments was one day.

【0044】染色前と染色後の透湿度、耐水圧、膜面摩
擦堅牢度、収縮率および剥離強力を求め、表4に記し
た。
Before and after dyeing, the moisture permeability, water pressure resistance, film fastness to rubbing, shrinkage and peel strength were determined and are shown in Table 4.

【0045】[0045]

【表4】 [Table 4]

【0046】[0046]

【発明の効果】本発明の方法によれば、流行をつかんで
から短納期で繊維製品を市場に出すことができ、また染
色処理前に縫製までしておくことによりさらに短納期で
市場に出すことができるので、消費者が望む商品をいち
早く供給でき、ビジネスチャンスも逃さなくすることが
できる。
According to the method of the present invention, a textile product can be put on the market in a short delivery time after catching an epidemic, and can be put on the market in a shorter delivery time by sewing before dyeing. As a result, consumers can quickly supply the products they want and avoid missing business opportunities.

【0047】さらに、染色処理により、自然なシワやシ
ボを有し、樹脂膜と基材生地との一体感のある繊維製品
を得ることができるので、樹脂膜独特のタッチを抑え、
ドライ感があり、意匠性にも優れた繊維製品を供給する
ことができる。
Further, by dyeing, it is possible to obtain a fiber product having natural wrinkles and textures and a sense of unity between the resin film and the base material.
It is possible to supply a fiber product having a dry feeling and excellent design properties.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 新田 健二 石川県能美郡根上町浜町ヌ167番地 小松 精練株式会社内 Fターム(参考) 4F100 AK01B AK48 AK51 AK51H BA02 CB00 DG11A DG12 GB72 JL01 4H057 AA02 CA21 CA25 CB08 CC01 CC03 DA01 DA32 GA07 4L033 AA08 AB05 AC03 CA50  ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Kenji Nitta 167 Namahama-cho, Negami-cho, Nomi-gun, Ishikawa Prefecture F-term (reference) 4F100 AK01B AK48 AK51 AK51H BA02 CB00 DG11A DG12 GB72 JL01 4H057 AA02 CA21 CA25 CB08 CC01 CC03 DA01 DA32 GA07 4L033 AA08 AB05 AC03 CA50

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 繊維布帛基材と合成樹脂を主成分とする
樹脂膜とを一体化して繊維布帛を形成した後、これを染
色処理に付すことを含む、少なくともその一部において
繊維布帛基材側が表面として使用される繊維布帛製品の
製造方法。
Claims: 1. A fiber fabric base material is formed by integrating a fiber fabric base material with a resin film containing a synthetic resin as a main component, and then subjecting the fiber fabric to a dyeing treatment. A method for producing a fiber fabric product, the side of which is used as the surface.
【請求項2】 染色処理に付す前に、繊維布帛の縫製を
行う、請求項1に記載の方法。
2. The method according to claim 1, wherein the textile fabric is sewn before being subjected to the dyeing treatment.
【請求項3】 樹脂膜が無孔質膜である、請求項1また
は2に記載の方法。
3. The method according to claim 1, wherein the resin membrane is a non-porous membrane.
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Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008075196A (en) * 2006-09-20 2008-04-03 Komatsu Seiren Co Ltd Method for producing water-repellent textile product

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008075196A (en) * 2006-09-20 2008-04-03 Komatsu Seiren Co Ltd Method for producing water-repellent textile product

Also Published As

Publication number Publication date
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