JP2002093458A - Lead-acid battery - Google Patents

Lead-acid battery

Info

Publication number
JP2002093458A
JP2002093458A JP2000279673A JP2000279673A JP2002093458A JP 2002093458 A JP2002093458 A JP 2002093458A JP 2000279673 A JP2000279673 A JP 2000279673A JP 2000279673 A JP2000279673 A JP 2000279673A JP 2002093458 A JP2002093458 A JP 2002093458A
Authority
JP
Japan
Prior art keywords
lead
electrode plate
battery
acid battery
current collecting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000279673A
Other languages
Japanese (ja)
Other versions
JP4765154B2 (en
Inventor
Yasuyuki Yoshihara
靖之 吉原
Ayako Hirao
亜矢子 平尾
Kazuhiro Sugie
一宏 杉江
宣行 ▲たか▼見
Nobuyuki Takami
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP2000279673A priority Critical patent/JP4765154B2/en
Publication of JP2002093458A publication Critical patent/JP2002093458A/en
Application granted granted Critical
Publication of JP4765154B2 publication Critical patent/JP4765154B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Secondary Cells (AREA)
  • Connection Of Batteries Or Terminals (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

PROBLEM TO BE SOLVED: To improve the output characteristic of a lead-acid battery. SOLUTION: The improvement of the output characteristic being an important target demanded on the lead-acid battery is achieved by such a simple means that the length of a negative plate current collecting lug part 4 is formed shorter than that of a positive plate current collecting lug part 2, in the electrode plates for the lead-acid battery.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、鉛蓄電池に関する
ものであり、特に高出力特性を要求される鉛蓄電池に関
するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a lead storage battery, and more particularly to a lead storage battery required to have high output characteristics.

【0002】[0002]

【従来の技術】近年、使用機器の高性能化にともない電
池へはコンパクト化と負荷の増大に対応できる高出力特
性が要求されており、鉛部品については電流経路の短縮
化による低抵抗化が検討され、極板群については格子体
形状の最適化、極板枚数の増加が提案されてきた。
2. Description of the Related Art In recent years, as the performance of used equipment has increased, batteries have been required to have high output characteristics capable of coping with compactness and an increase in load. For lead components, lower resistance has been required by shortening the current path. Investigations have suggested that for the electrode group, optimization of the lattice shape and increase in the number of electrode plates have been proposed.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、従来の
構成では重量の増加や、品質の低下およびその複雑さゆ
えに生じる生産性の低下などの課題があった。
However, the conventional structure has problems such as an increase in weight, a decrease in quality, and a decrease in productivity caused by its complexity.

【0004】本発明はこのような従来の課題を解決する
ものであり、従来の諸電池の特性や品質、生産性を損な
わず出力特性に優れる鉛蓄電池を提供することを目的と
するものである。
An object of the present invention is to solve such a conventional problem, and an object of the present invention is to provide a lead storage battery having excellent output characteristics without impairing the characteristics, quality, and productivity of conventional batteries. .

【0005】[0005]

【課題を解決するための手段】上記目的を達成するため
に本発明は、鉛蓄電池用極板において、負極板集電耳部
の長さを正極板集電耳部の長さに比べて短い構成とした
ものである。
In order to achieve the above object, the present invention provides a lead-acid battery electrode plate in which the length of the negative electrode plate current collecting ear is shorter than the length of the positive electrode plate current collecting ear. It is configured.

【0006】[0006]

【発明の実施の形態】以下、本発明の実施の形態につい
て、図面を参照しながら説明する。
Embodiments of the present invention will be described below with reference to the drawings.

【0007】極板の製作には鉛合金を圧延した帯状シー
ト材料に切り目を入れ、展開して、升目を形成するエキ
スパンド格子体に連続的にペースト状活物質を塗着する
方法を用いた。エキスパンド方式には金型カッターが上
下して帯状シートに切り目を入れると同時に展開するレ
シプロ方式を用いた。
For the production of the electrode plate, a method is used in which a cut is made in a strip-shaped sheet material obtained by rolling a lead alloy, developed, and a paste-like active material is continuously applied to an expanded lattice body forming a grid. For the expanding method, a reciprocating method was used in which the mold cutter moved up and down to cut the band-shaped sheet and unfolded at the same time.

【0008】ペースト状活物質は鉛酸化物を主成分とす
る粉体に水と硫酸を加え練合して作製しこれを前記格子
体に同質量の活物質を塗着、熟成乾燥して極板を作製し
た。これら極板を正極6枚、負極7枚を用いて群を構成
した後、6セルを直列接続した定格12V30Ahの電
池を作製した。群を構成するに当たり、ストラップの形
成には負極板集電耳部の長さをバーナ溶接法より短くす
ることができる利点を有するキャストオンストラップ工
法を用いた。そして従来例電池の正極1aの正極板集電
耳部2aの長さと負極3aの負極板集電耳部4aの長さ
を共に16mmにし、本発明電池の正極1の正極板集電
耳部2の長さを16mm、負極3の負極板集電耳部4の
長さを8mmとした。尚、5はセパレータを、6はスト
ラップを示す。
The paste-like active material is prepared by adding water and sulfuric acid to a powder containing lead oxide as a main component, kneading the active material, applying the same mass of active material to the lattice, aging and drying. A plate was made. After forming a group by using six positive electrodes and seven negative electrodes of these electrode plates, a battery having a rating of 12 V and 30 Ah in which six cells were connected in series was produced. In forming the group, the strap was formed by a cast-on-strap method which has an advantage that the length of the negative electrode plate current collecting ear can be made shorter than that of the burner welding method. The length of the positive electrode plate current collecting ear 2a of the positive electrode 1a of the conventional battery and the length of the negative electrode plate current collecting ear 4a of the negative electrode 3a were both set to 16 mm. Was 16 mm, and the length of the negative electrode plate current collecting ear portion 4 of the negative electrode 3 was 8 mm. In addition, 5 indicates a separator, and 6 indicates a strap.

【0009】また、本発明電池における負極板集電耳部
の短い群を構成するに当たっては表1に示した各手段を
用いた。まず極板の大きさを変化させない手段としては
負極板を上部に8mmずらした(電池番号No.2)。
また極板の高さを高くする手段としては負極活物質保持
部の高さを8mm拡げる手段(電池番号No.3)と負
極板肩部幅を8mm拡げる手段(電池番号No.4)で
行った。そして従来例電池の群構成図を図2に、本発明
電池の群構成図を図1に示す。
Further, in forming a short group of the current collecting ears of the negative electrode plate in the battery of the present invention, each means shown in Table 1 was used. First, as means for keeping the size of the electrode plate unchanged, the negative electrode plate was shifted upward by 8 mm (battery number No. 2).
Means for increasing the height of the electrode plate include a means for increasing the height of the negative electrode active material holding portion by 8 mm (battery number No. 3) and a means for increasing the width of the shoulder portion of the negative electrode plate by 8 mm (battery number No. 4). Was. FIG. 2 shows a group configuration diagram of the conventional battery, and FIG. 1 shows a group configuration diagram of the battery of the present invention.

【0010】[0010]

【表1】 [Table 1]

【0011】[0011]

【実施例】以上のように構成された本発明の鉛蓄電池
(No.2,No.3,No.4)と従来例の鉛蓄電池
(No.1)について放電電流−電池電圧特性の評価と
45℃環境温度下で3CA放電サイクル寿命試験により
評価を行った。尚、従来例の鉛蓄電池でこの評価を行う
と正極の格子体の腐食によって寿命になることが分かっ
ている。このサイクル寿命試験では3CAの定電流で
8.4Vまで放電した後、2段定電流充電で充電をする
過程を1サイクルとした。ここでいう2段定電流充電は
1段目電流(0.2CA)で14.4Vまで充電し、そ
の後、2段目充電電流(0.05CA)で4時間充電す
る方法である。
The evaluation of the discharge current-battery voltage characteristics of the lead-acid battery (No. 2, No. 3, No. 4) of the present invention and the lead-acid battery (No. 1) of the prior art configured as described above. The evaluation was performed by a 3CA discharge cycle life test under an environment temperature of 45 ° C. In addition, it is known that when this evaluation is performed on a conventional lead-acid battery, the service life is extended due to corrosion of the grid of the positive electrode. In this cycle life test, a process in which the battery was discharged to 8.4 V at a constant current of 3 CA and then charged by two-stage constant current charging was defined as one cycle. The second-stage constant current charging is a method of charging to 14.4 V with the first-stage current (0.2 CA), and then charging for 4 hours with the second-stage charging current (0.05 CA).

【0012】図3に25℃環境下における放電電流−電
池電圧特性の結果を示す。この図から分かるように電池
番号No.2からNo.4の電池は従来例電池No.1
に比べて高い電圧特性を示している。
FIG. 3 shows the results of discharge current-battery voltage characteristics under a 25 ° C. environment. As can be seen from FIG. 2 to No. 2 Battery No. 4 is a conventional battery No. 1
It shows a higher voltage characteristic than that of.

【0013】図4に45℃、3CA放電サイクル寿命特
性と極板種類の関係を示す。
FIG. 4 shows the relationship between the 45 ° C., 3CA discharge cycle life characteristics and the types of electrode plates.

【0014】この図から分かるように電池番号No.2
からNo.4の電池は従来例電池No.1とほぼ同等の
寿命特性を有することが分かった。
As can be seen from FIG. 2
From No. Battery No. 4 is a conventional battery No. It was found to have a life characteristic almost equivalent to that of No. 1.

【0015】尚、本実施例において格子体の単位面積当
たりの質量を変化させる手段として格子骨の太さを変化
させたが、格子体升目面積を変化させることで単位面積
当たりの質量を変化させる手段でも同様の効果が得られ
る。
In this embodiment, the thickness of the lattice bone is changed as a means for changing the mass per unit area of the lattice body. However, the mass per unit area is changed by changing the lattice cell area. The same effect can be obtained by means.

【0016】更に、本実施例においては格子体をレシプ
ロエキスパンド方式によるものとしたが、幾重にも重な
った円板状カッターで形成される型で帯状シートに切り
込みを入れ、別工程で所定の幅寸法まで展開するロータ
リエキスパンド方式を用いた格子体についても同様の効
果を得ることができる。加えて、鋳造格子を用いた場合
も効果は得られ、本発明は格子体製造工法を限定するも
のではない。
Further, in the present embodiment, the lattice body is of the reciprocating expand type, but the band-shaped sheet is cut by a mold formed by a plurality of overlapping disk-shaped cutters, and a predetermined width is formed in another step. The same effect can be obtained for a lattice body using a rotary expanding method that expands to the size. In addition, effects can be obtained even when a casting grid is used, and the present invention does not limit the grid body manufacturing method.

【0017】更に、本発明はベント式鉛蓄電池において
効果的であるが、充電時の酸素吸収サイクルなどの発熱
反応があったり、電解液が少なく小熱容量のために温度
上昇しやすい密閉式鉛蓄電池ではより効果が顕著であ
る。
Furthermore, although the present invention is effective in a vented lead storage battery, a sealed lead storage battery which has an exothermic reaction such as an oxygen absorption cycle at the time of charging or has a small amount of electrolyte and is likely to rise in temperature due to a small heat capacity. The effect is more remarkable.

【0018】[0018]

【発明の効果】以上の説明で明らかなように本発明によ
れば、鉛蓄電池用極板において、負極板集電耳部の長さ
を正極板集電耳部の長さに比べて短くすることにより、
出力特性に優れた鉛蓄電池を実現できるものである。
As is apparent from the above description, according to the present invention, in the lead plate for a lead storage battery, the length of the current collecting ear portion of the negative electrode plate is made shorter than the length of the current collecting ear portion of the positive electrode plate. By doing
A lead storage battery having excellent output characteristics can be realized.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施例に使用した極板群の平面図FIG. 1 is a plan view of an electrode group used in an embodiment of the present invention.

【図2】従来例に使用した極板群の平面図FIG. 2 is a plan view of an electrode group used in a conventional example.

【図3】25℃放電電流−電池電圧特性図FIG. 3 is a discharge current-battery voltage characteristic diagram at 25 ° C.

【図4】45℃、3CAサイクル寿命試験結果を示す図FIG. 4 shows the results of a 45 ° C., 3CA cycle life test.

【符号の説明】[Explanation of symbols]

1,1a 正極 2,2a 正極板集電耳部 3,3a 負極 4,4a 負極板集電耳部 5 セパレータ 6 ストラップ 1,1a Positive electrode 2,2a Positive electrode plate current collecting ear 3,3a Negative electrode 4,4a Negative electrode plate current collecting ear 5 Separator 6 Strap

───────────────────────────────────────────────────── フロントページの続き (72)発明者 杉江 一宏 大阪府門真市大字門真1006番地 松下電器 産業株式会社内 (72)発明者 ▲たか▼見 宣行 大阪府門真市大字門真1006番地 松下電器 産業株式会社内 Fターム(参考) 5H022 AA01 CC15 CC19 CC23 CC24 5H028 AA05 CC05 CC11 HH06 5H050 AA02 BA09 FA02 HA04  ──────────────────────────────────────────────────の Continuing on the front page (72) Inventor Kazuhiro Sugie 1006 Kadoma Kadoma, Osaka Prefecture Inside Matsushita Electric Industrial Co., Ltd. F term in reference (reference) 5H022 AA01 CC15 CC19 CC23 CC24 5H028 AA05 CC05 CC11 HH06 5H050 AA02 BA09 FA02 HA04

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 鉛蓄電池用極板において、負極板集電耳
部の長さを正極板集電耳部の長さに比べて短くしたこと
を特徴とする鉛蓄電池。
1. A lead storage battery according to claim 1, wherein the length of the current collecting ear portion of the negative electrode plate is shorter than the length of the current collecting ear portion of the positive electrode plate.
【請求項2】 鉛蓄電池用極板において、負極板高さを
正極板高さに比べて高くしたことを特徴とする請求項1
に記載の鉛蓄電池。
2. The lead plate for a lead storage battery, wherein the height of the negative electrode plate is higher than the height of the positive electrode plate.
The lead-acid battery according to 1.
【請求項3】 鉛蓄電池用極板において、負極板肩部幅
を正極板肩部幅に比べて広くしたことを特徴とする請求
項1に記載の鉛蓄電池。
3. The lead storage battery according to claim 1, wherein the width of the shoulder of the negative electrode plate is wider than the width of the shoulder of the positive electrode plate.
【請求項4】 ストラップ形成工法としてキャストオン
ストラップ工法を用いたことを特徴とする請求項1に記
載の鉛蓄電池。
4. The lead-acid battery according to claim 1, wherein a cast-on-strap method is used as the strap forming method.
JP2000279673A 2000-09-14 2000-09-14 Lead acid battery Expired - Lifetime JP4765154B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000279673A JP4765154B2 (en) 2000-09-14 2000-09-14 Lead acid battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000279673A JP4765154B2 (en) 2000-09-14 2000-09-14 Lead acid battery

Publications (2)

Publication Number Publication Date
JP2002093458A true JP2002093458A (en) 2002-03-29
JP4765154B2 JP4765154B2 (en) 2011-09-07

Family

ID=18764641

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000279673A Expired - Lifetime JP4765154B2 (en) 2000-09-14 2000-09-14 Lead acid battery

Country Status (1)

Country Link
JP (1) JP4765154B2 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1140187A (en) * 1997-07-16 1999-02-12 Japan Storage Battery Co Ltd Lead-acid battery
JP2002075325A (en) * 2000-08-25 2002-03-15 Shin Kobe Electric Mach Co Ltd Small control valve type lead-acid battery

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1140187A (en) * 1997-07-16 1999-02-12 Japan Storage Battery Co Ltd Lead-acid battery
JP2002075325A (en) * 2000-08-25 2002-03-15 Shin Kobe Electric Mach Co Ltd Small control valve type lead-acid battery

Also Published As

Publication number Publication date
JP4765154B2 (en) 2011-09-07

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