JP2002059075A - Retaining method of strength and hardness by preventing incomplete hydration reaction caused by atmospheric temperature and quality of base material with water base paint and covering material containing cement system inorganic sealant as indispensable component - Google Patents

Retaining method of strength and hardness by preventing incomplete hydration reaction caused by atmospheric temperature and quality of base material with water base paint and covering material containing cement system inorganic sealant as indispensable component

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Publication number
JP2002059075A
JP2002059075A JP2000253649A JP2000253649A JP2002059075A JP 2002059075 A JP2002059075 A JP 2002059075A JP 2000253649 A JP2000253649 A JP 2000253649A JP 2000253649 A JP2000253649 A JP 2000253649A JP 2002059075 A JP2002059075 A JP 2002059075A
Authority
JP
Japan
Prior art keywords
water
moisture
cement
hydration reaction
base material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000253649A
Other languages
Japanese (ja)
Inventor
Masaharu Shinoda
正治 篠田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ELEGANT KK
Original Assignee
ELEGANT KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ELEGANT KK filed Critical ELEGANT KK
Priority to JP2000253649A priority Critical patent/JP2002059075A/en
Publication of JP2002059075A publication Critical patent/JP2002059075A/en
Pending legal-status Critical Current

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  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)
  • Paints Or Removers (AREA)

Abstract

PROBLEM TO BE SOLVED: To retain a hardness and a strength of a surface and to prevent a deterioration phenomenon at the time of applying a painting and covering to a base material having a high water-absorbing/hygroscopic ability. SOLUTION: A water base paint and a water base covering material containing a cement system inorganic sealant as an indispensable component and preventing a ductility and a crack of a coating film surface caused by an incomplete hydration reaction generated by a water-absorbing/hygroscopic performance of a base material are coated. Thereafter, the ductility and the crack on the coating film surface are prevented by adjusting a moisture content replenishment onto a surface of the coating film.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【001】[001]

【産業上の利用分野】屋内における内装材等に関して、
シックハウス症候群の多発から無機質剤を主材とした人
にやさしい建材が多く開発されている。その中で不燃性
であり、吸放湿効果の高い湿度調整基材が結露防止効果
も含めて注目されている。本願発明はこれら湿度調整建
材の問題点を解決することによって日本の風土気候に適
した人にやさしい内装材の普及が期待できる他、セメン
ト系無機質接合剤の持つ短所を解決することにより、各
分野での幅広い需要が期待できる。
[Industrial applications] For interior materials etc. indoors,
Since the sick house syndrome occurs frequently, many human-friendly building materials mainly composed of inorganic agents have been developed. Among them, a non-flammable, humidity-adjusting base material having a high moisture absorption / release effect has attracted attention, including an effect of preventing dew condensation. The invention of the present application can be expected to spread the interior materials suitable for the climate of Japan by solving the problems of these humidity-adjusting building materials. A wide range of demand can be expected.

【002】[002]

【従来の技術】セメント系無機質接合剤を成分とした水
性塗料及び水性被覆剤は、気温の高い時期、基材の温度
が高くなる場合、基材に散水して基材の温度を下げ水分
の蒸発を押さえ水和反応の安定をはかってきたが、作業
する面積によっては安定した水和反応は期待できなかっ
た。また、最近では湿度調整内装材の普及により吸水、
吸湿性の高いものが使用されている。このような基材に
表面仕上をする場合は、塗布材の水分が急激に奪われ、
塗布膜表面は脆弱で、粉が噴いた状態になり触れると衣
服を汚す場合も多い。
2. Description of the Related Art A water-based paint and a water-based coating agent containing a cement-based inorganic binder as a component are used to spray water on the base material to lower the temperature of the base material when the temperature of the base material becomes high when the temperature is high. Although the hydration reaction was stabilized by suppressing evaporation, a stable hydration reaction could not be expected depending on the working area. In addition, recently, with the spread of humidity adjustment interior materials, water absorption,
Highly hygroscopic materials are used. When finishing the surface of such a substrate, the moisture of the coating material is rapidly taken away,
The surface of the coating film is fragile, and the powder is in a state of being sprayed and often stains clothes when touched.

【003】[003]

【発明が解決しようとする課題】気温の高い時期又は塗
布しようとする基材の温度が高い場合に発生する不完全
水和反応はセメント系無機質接合剤を必須成分とする水
性塗料及び水性被覆材は強度及び硬度を劣化させる。
The incomplete hydration reaction which occurs when the temperature is high or when the temperature of the substrate to be applied is high is a water-based paint and water-based coating material containing a cement-based inorganic binder as an essential component. Degrades strength and hardness.

【004】また、湿度調整建材の場合、素地で成形される
ことが多く意匠性に問題が残る。着色、柄、模様をつけ
る場合においては、その吸湿、放湿性能を保持する必要
があるため湿度調整建材同等もしくはそれ以上の吸湿、
放湿効果のあるもので着色、柄、模様をつけ意匠性を確
保する必要がある。
In the case of a humidity-adjusting building material, it is often formed from a base material, and there remains a problem in designability. In the case of coloring, patterning, and patterning, it is necessary to maintain the moisture absorption and moisture release performance, so that moisture absorption equal to or more than the humidity adjustment building material,
It is necessary to add coloring, design, and design to the material that has a moisture releasing effect to ensure the design.

【005】透湿性の高い布、紙を貼ることもできるが、貼
ることによってある種の糊付け行為を余儀なくされて建
材そのものの機能を低下させることになるとともに、不
燃性を確保出来にくくなる他、吸水することによって伸
縮するものもある。
[005] A cloth or paper with high moisture permeability can also be applied, but pasting will necessitate a certain type of gluing action, lowering the function of the building material itself, and making it difficult to ensure nonflammability. Some of them expand and contract by absorbing water.

【006】また、従来から吸湿放湿性能を持つ水性無機質
系の塗料及び被覆材は使用されているが、そのほとんど
が表面に粉塵が残り、触ると粉塵が付着し衣服を汚すこ
ともある。粉塵粒度によっては空気中に漂い衛生上にも
好ましくない。また、床に落ち床を汚すことさえある。
In addition, aqueous inorganic paints and coating materials having a moisture absorbing and releasing performance have been used in the past, but most of them have dust left on the surface, and when touched, the dust adheres and may stain clothes. Depending on the particle size of the dust, it floats in the air and is not preferable for sanitation. It can even fall on the floor and soil the floor.

【007】[007]

【課題を解決するための手段】本願の請求項1に記載し
た発明は、気温の高い時期又は塗布する基材の温度が高
い時に発生するセメント系無機質接合剤を必須成分とし
た水性塗料及び水性被覆材の水分の早期蒸発による不完
全水和反応による脆性防止クラック防止を塗布後、塗布
物表面の水分補給の調整により防止することを特徴とす
る。また、本願発明で言う水和反応とは、セメント系無
機質接合剤が水と混合して化合し、水和物を生成して硬
化することを言う。
Means for Solving the Problems The invention described in claim 1 of the present application relates to a water-based paint and a water-based paint containing a cement-based inorganic binder generated as an essential component when the temperature is high or when the temperature of the substrate to be applied is high. It is characterized in that the brittleness is prevented by the incomplete hydration reaction due to the early evaporation of the moisture of the coating material and the crack is prevented by adjusting the water supply on the surface of the coated material after coating. In addition, the hydration reaction referred to in the present invention means that the cement-based inorganic bonding agent is mixed with water to form a hydrate and hardens.

【008】本願の請求項2に記載した発明は、セメント系無
機質接合剤を必須成分とする水性塗料及び水性被覆材
が、基材の持つ吸水、吸湿性能により発生する不完全水
和反応によると塗布膜表面の脆性防止及びクラック防止
を塗布後、塗布物表面の水分補給の調整により防止する
ことを特徴とする。
The invention described in claim 2 of the present application is based on the fact that the water-based paint and the water-based coating material containing the cement-based inorganic bonding agent as an essential component are based on the incomplete hydration reaction generated by the water absorption and moisture absorption properties of the base material. After coating, the prevention of brittleness and cracks on the coating film surface is prevented by adjusting the water supply on the surface of the coating material.

【009】本願の請求項3に記載した発明は、セメント系無
機質接合を必須成分とする水性塗料及び水性被覆材自体
が吸水、吸湿能力、又はその目的を持つもので、同種能
力、目的を持つ基材に塗布した時に発生する不完全水和
反応による塗布膜表面の脆性防止及びクラック防止を塗
布後、塗布物表面の水分補給の調整により防止すること
を特徴とする。
[009] In the invention described in claim 3 of the present application, the water-based paint and the water-based coating material having cement-based inorganic bonding as an essential component have water absorption, moisture absorption ability, or the purpose thereof, and have the same kind of ability and purpose. Prevention of brittleness and cracks on the surface of the coating film due to incomplete hydration reaction that occurs when the composition is applied to a substrate is prevented by adjusting the water supply on the surface of the coating material after coating.

【010】本願の請求項4に記載した発明は、セメント系無
機質接合剤を必須成分とする水性塗料及び被覆材が吸
水、吸湿性能又はその目的を持ったものであり、塗布す
る基材の種別が不特定である場合の、クラック防止及び
塗布表面の脆性劣化を塗布後、塗布物表面の水分補給の
調整により防止することを特徴とする。
[0102] The invention described in claim 4 of the present application is characterized in that the water-based paint and the coating material containing the cement-based inorganic binder as an essential component have water absorption and moisture absorption performance or the purpose thereof, and Is unspecified, cracks are prevented and brittleness deterioration of the coated surface is prevented by adjusting the water supply on the coated surface after coating.

【011】気温の高い時期、基材の温度が高くなる場合が
多いが、このような基材に本願で言う水性塗料及び被覆
材を塗布することにより、水分の蒸発が急激に起こり塗
材の水和反応が不完全な状態になり、脆性な塗膜が形成
される。この場合、水分の蒸発の度合いに応じて表面塗
膜に水分の補給をする。この補給方法は、表面塗膜に圧
力を加えない方法、たとえば噴霧器、スプレ−等で補給
することが好ましい。
[0111] When the temperature is high, the temperature of the base material often rises. By applying the water-based paint and the coating material referred to in the present application to such a base material, evaporation of moisture rapidly occurs, and The hydration reaction is incomplete and a brittle coating is formed. In this case, water is supplied to the surface coating according to the degree of evaporation of the water. This replenishment method is preferably a method in which pressure is not applied to the surface coating film, for example, by using a sprayer, a sprayer or the like.

【012】また、気温に関係なく吸水、吸湿性能の高い基
材の場合も本願請求項で言う塗材が、基材に水分を急激
に吸収されるため不完全な水和反応によりクラックの発
生又は表面に粉状のものが浮いた状態になり、触手する
と粉状の組成物が付着してくる。このような状態を防止
するためには、塗材表面の水分の吸収状態により水分補
給を行うが、基材の水分吸収能力に応じて複数回水分補
給をすることが好ましい。また、いずれの場合も水分補
給は水和反応の終了、すなわち、セメント系無機質接合
剤が水と混合して化合し、水和物を生成して硬化するま
での間の早い時期に水分補給をする必要がある。
Further, even in the case of a substrate having high water absorption and moisture absorption performance irrespective of the temperature, cracks occur due to incomplete hydration reaction because the coating material according to the present invention rapidly absorbs water. Alternatively, a powdery substance floats on the surface, and the powdery composition adheres when touched. In order to prevent such a state, water is replenished according to the state of water absorption on the surface of the coating material. However, it is preferable to replenish water a plurality of times according to the water absorbing ability of the base material. In each case, hydration is completed at the end of the hydration reaction, that is, at an early stage until the cement-based inorganic bonding agent mixes with water to form a hydrate and hardens. There is a need to.

【013】このようになる場合はその吸湿能力と塗膜厚に
もよるが、早いものでは塗布後数分で塗布膜表面の水分
がなくなり、その様子が容易に確認できる。
In such a case, although it depends on the moisture absorption capacity and the thickness of the coating film, if it is earlier, the moisture on the surface of the coating film disappears within a few minutes after application, and the state can be easily confirmed.

【014】この場合、セメント系無機質接合剤に着色した
顔料はセメント系無機質接合剤の早期硬化により水分補
給による影響は受けない。
In this case, the pigment colored in the cement-based inorganic bonding agent is not affected by water replenishment due to the early curing of the cement-based inorganic bonding agent.

【015】また、水分は水蒸気でもよく設備の可能な工場
内等で成形物に塗布及び被覆する場合は、水分補給にも
なり成形物の良好な早期硬化につながり能率も上がる。
この場合、水蒸気の温度が高いほど良好な早期硬化が期
待できる。
[0151] Further, when water is applied to a molded product in a factory or the like where water can be used even when water vapor can be used, it also replenishes moisture and leads to favorable early curing of the molded product, thereby increasing efficiency.
In this case, better early curing can be expected as the temperature of the steam becomes higher.

【016】[016]

【発明実施の形態】以下、本願発明に係る実施の形態を
具体的に説明する。基材には段谷産業株式会社製e.ウォ
−ル吸湿ボ−ドで、その吸湿性能は、25℃×50%RH.4
8h→25℃×90%RH.24h(吸湿)25℃×50%RH.24
h(放湿)g/m2 227の性能を持つ吸湿性能の高い
ものを使用した。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments according to the present invention will be specifically described below. The base material is e.Wall moisture absorption board manufactured by Tanya Sangyo Co., Ltd. The moisture absorption performance is 25 ° C. × 50% RH.4
8h → 25 ℃ × 90% RH.24h (moisture absorption) 25 ℃ × 50% RH.24
A material having a high moisture absorption performance having a performance of h (dehumidification) g / m 2 227 was used.

【017】セメント系無機質接合剤として白色ポルトラン
ドセメント、炭酸カルシウム質粉体、二酸化珪素質粉
体、活性炭、樹脂エマルジョン、顔料を配合して水を加
え攪拌して吸湿性の高い水性塗料にした。
[0173] White Portland cement, calcium carbonate-based powder, silicon dioxide-based powder, activated carbon, resin emulsion, and pigment were blended as a cement-based inorganic bonding agent, and water was added thereto with stirring to obtain an aqueous paint having high hygroscopicity.

【018】室温28℃湿度55%の条件で、上記吸湿ボ−ド三
枚を用意して一枚を水に没水して水分を充分に吸水させ
二枚はそのままの状態で、三枚に上記塗料をスプレ−で
塗膜厚0.5mmに塗布した。
[0182] Under the conditions of room temperature 28 ° C and humidity 55%, prepare the above three moisture absorbing boards, submerge one in water, absorb enough water, and leave the two pieces as they are. The above paint was applied by spraying to a film thickness of 0.5 mm.

【019】スプレ−後表面を観察したところ、没水した一
枚以外は2分間で表面の水分がなくなり表面が乾燥状態
になったが、没水した一枚は表面が乾燥状態になるまで
15分間を要した。
When the surface after spraying was observed, except for one of the submerged ones, the surface water was lost in 2 minutes and the surface became dry, but one of the submerged ones until the surface became dry
It took 15 minutes.

【020】没水した吸湿ボ−ド一枚と、それ以外の一枚を
そのままの状態で放置、乾燥させた。また、残り一枚の
吸湿ボ−ドには塗布30分後、表面に水をスプレ−で噴霧
したが再び表面が乾燥状態になったので、水の噴霧を3
回繰り返した後、放置乾燥した。
One submerged moisture-absorbing board and the other one were left as they were and dried. Also, 30 minutes after application to the remaining one moisture absorbing board, water was sprayed on the surface by spraying. However, since the surface became dry again, spraying of water was performed for 3 minutes.
After repeating this time, it was left to dry.

【021】24時間後、上記三枚の吸湿ボ−ドに塗布した塗
料を比較したところ、没水せず水の噴霧もしなかったボ
−ドは表面に組成物の粉状のものが浮き、手で触ると手
に粉状のものが大量に付着した。また、没水したもの
は、わずかであるが粉状のものが手に付着して表面にわ
ずか粉感触が残った。しかし、表面に水を噴霧したもの
は、手に粉状のものは一切付着せず、その感触もなく、
硬度も高かった。また、顔料を観察したが、顔料が滲む
こともなく、色彩も前二枚に比べて優れていた。
After 24 hours, when the paints applied to the above three moisture absorbing boards were compared, the powder which was not submerged nor sprayed with water had a powdery composition floating on the surface, When touched by hand, a large amount of powdery substances adhered to the hand. The submerged one was slightly powdery but adhered to the hand, leaving a slight powder feel on the surface. However, when spraying water on the surface, powdery substances do not adhere to the hands at all, there is no touch,
Hardness was also high. In addition, the pigment was observed, but the pigment did not bleed and the color was excellent as compared with the previous two sheets.

─────────────────────────────────────────────────────
────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成12年10月18日(2000.10.
18)
[Submission date] October 18, 2000 (2000.10.
18)

【手続補正1】[Procedure amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】特許請求の範囲[Correction target item name] Claims

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【特許請求の範囲】[Claims]

【提出日】平成12年11月6日(2000.11.
6)
[Submission date] November 6, 2000 (200.11.
6)

【手続補正2】[Procedure amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】発明の詳細な説明[Correction target item name] Detailed description of the invention

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【001】[001]

【産業上の利用分野】屋内における内装材等に関して、
シックハウス症候群の多発から無機質剤を主材とした人
にやさしい建材が多く開発されている。その中で不燃性
であり、吸放湿効果の高い湿度調整基材が結露防止効果
も含めて注目されている。本願発明はこれら湿度調整建
材の問題点を解決することによって日本の風土気候に適
した人にやさしい内装材の普及が期待できる他、セメン
ト系無機質接合剤の持つ短所を解決することにより、各
分野での幅広い需要が期待できる。
[Industrial applications] For interior materials etc. indoors,
Since the sick house syndrome occurs frequently, many human-friendly building materials mainly composed of inorganic agents have been developed. Among them, a non-flammable, humidity-adjusting base material having a high moisture absorption / release effect has attracted attention, including an effect of preventing dew condensation. The invention of the present application can be expected to spread human-friendly interior materials suitable for the climate of Japan by solving the problems of the humidity-adjusting building materials, and solve the disadvantages of the cement-based inorganic bonding agent in various fields. A wide range of demand can be expected.

【002】[002]

【従来の技術】セメント系無機質接合剤を成分とした水
性塗料及び水性被覆剤は、気温の高い時期、基材の温度
が高くなる場合、基材に散水して基材の温度を下げ水分
の蒸発を押さえ水和反応の安定をはかってきたが、作業
する面積によっては安定した水和反応は期待できなかっ
た。また、最近では湿度調整内装材の普及により吸水、
吸湿性の高いものが使用されている。このような基材に
表面仕上をする場合は、塗布材の水分が急激に奪われ、
塗布膜表面は脆弱で、粉が噴いた状態になり触れると衣
服を汚す場合も多い。
2. Description of the Related Art A water-based paint and a water-based coating agent containing a cement-based inorganic binder as a component are used to spray water on the base material to lower the temperature of the base material when the temperature of the base material becomes high when the temperature is high. Although the hydration reaction was stabilized by suppressing evaporation, a stable hydration reaction could not be expected depending on the working area. In addition, recently, with the spread of humidity adjustment interior materials, water absorption,
Highly hygroscopic materials are used. When finishing the surface of such a substrate, the moisture of the coating material is rapidly taken away,
The surface of the coating film is fragile, and the powder is in a state of being sprayed and often stains clothes when touched.

【003】[003]

【発明が解決しようとする課題】気温の高い時期又は塗
布しようとする基材の温度が高い場合に発生する不完全
水和反応はセメント系無機質接合剤を必須成分とする水
性塗料及び水性被覆材は強度及び硬度を劣化させる。
The incomplete hydration reaction which occurs when the temperature is high or when the temperature of the substrate to be applied is high is a water-based paint and water-based coating material containing a cement-based inorganic binder as an essential component. Degrades strength and hardness.

【004】また、湿度調整建材の場合、素地で成形される
ことが多く意匠性に問題が残る。着色、柄、模様をつけ
る場合においては、その吸湿、放湿性能を保持する必要
があるため湿度調整建材同等もしくはそれ以上の吸湿、
放湿効果のあるもので着色、柄、模様をつけ意匠性を確
保する必要がある。
In the case of a humidity-adjusting building material, it is often formed from a base material, and there remains a problem in designability. In the case of coloring, patterning, and patterning, it is necessary to maintain the moisture absorption and moisture release performance, so that moisture absorption equal to or more than the humidity adjustment building material,
It is necessary to add coloring, design, and design to the material with moisture release effect to secure the design.

【005】透湿性の高い布、紙を貼ることもできるが、貼
ることによってある種の糊付け行為を余儀なくされて建
材そのものの機能を低下させることになるとともに、不
燃性を確保出来にくくなる他、吸水することによって伸
縮するものもある。
[005] A cloth or paper with high moisture permeability can also be applied, but pasting will necessitate a certain type of gluing action, lowering the function of the building material itself, and making it difficult to ensure nonflammability. Some of them expand and contract by absorbing water.

【006】また、従来から吸湿放湿性能を持つ水性無機質
系の塗料及び被覆材は使用されているが、そのほとんど
が表面に粉塵が残り、触ると粉塵が付着し衣服を汚すこ
ともある。粉塵粒度によっては空気中に漂い衛生上にも
好ましくない。また、床に落ち床を汚すことさえある。
In addition, aqueous inorganic paints and coating materials having a moisture absorbing and releasing performance have been used in the past, but most of them have dust left on the surface, and when touched, the dust adheres and may stain clothes. Depending on the particle size of the dust, it floats in the air and is not preferable for sanitation. It can even fall on the floor and soil the floor.

【007】[007]

【課題を解決するための手段】本願の請求項1に記載し
た発明は、気温の高い時期又は塗布する基材の温度が高
い時に発生するセメント系無機質接合剤を必須成分とし
た水性塗料及び水性被覆材の水分の早期蒸発による不完
全水和反応による脆性防止クラック防止を塗布後、塗布
物表面の水分補給の調整により防止することを特徴とす
る。また、本願発明で言う水和反応とは、セメント系無
機質接合剤が水と混合して化合し、水和物を生成して硬
化することを言う。
Means for Solving the Problems The invention described in claim 1 of the present application relates to a water-based paint and a water-based paint containing a cement-based inorganic binder generated as an essential component when the temperature is high or when the temperature of the substrate to be applied is high. It is characterized in that the brittleness is prevented by the incomplete hydration reaction due to the early evaporation of the moisture of the coating material and the crack is prevented by adjusting the water supply on the surface of the coated material after coating. In addition, the hydration reaction referred to in the present invention means that the cement-based inorganic bonding agent is mixed with water to form a hydrate and hardens.

【008】本願の請求項2に記載した発明は、セメント系無
機質接合剤を必須成分とする水性塗料及び水性被覆材
が、基材の持つ吸水、吸湿性能により発生する不完全水
和反応によると塗布膜表面の脆性防止及びクラック防止
を塗布後、塗布物表面の水分補給の調整により防止する
ことを特徴とする。
The invention described in claim 2 of the present application is based on the fact that the water-based paint and the water-based coating material containing the cement-based inorganic bonding agent as an essential component are based on the incomplete hydration reaction generated by the water absorption and moisture absorption properties of the base material. After coating, the prevention of brittleness and cracks on the coating film surface is prevented by adjusting the water supply on the surface of the coating material.

【009】本願の請求項3に記載した発明は、セメント系無
機質接合を必須成分とする水性塗料及び水性被覆材自体
が吸水、吸湿能力、又はその目的を持つもので、同種能
力、目的を持つ基材に塗布した時に発生する不完全水和
反応による塗布膜表面の脆性防止及びクラック防止を塗
布後、塗布物表面の水分補給の調整により防止すること
を特徴とする。
[009] In the invention described in claim 3 of the present application, the water-based paint and the water-based coating material having cement-based inorganic bonding as an essential component have water absorption, moisture absorption ability, or the purpose thereof, and have the same kind of ability and purpose. Prevention of brittleness and cracks on the surface of the coating film due to incomplete hydration reaction that occurs when the composition is applied to a substrate is prevented by adjusting the water supply on the surface of the coating material after coating.

【010】本願の請求項4に記載した発明は、セメント系無
機質接合剤を必須成分とする水性塗料及び被覆材が吸
水、吸湿性能又はその目的を持ったものであり、塗布す
る基材の種別が不特定である場合の、クラック防止及び
塗布表面の脆性劣化を塗布後、塗布物表面の水分補給の
調整により防止することを特徴とする。
[0102] The invention described in claim 4 of the present application is characterized in that the water-based paint and the coating material containing the cement-based inorganic binder as an essential component have water absorption and moisture absorption performance or the purpose thereof, and Is unspecified, cracks are prevented and brittleness deterioration of the coated surface is prevented by adjusting the water supply on the coated surface after coating.

【011】気温の高い時期、基材の温度が高くなる場合が
多いが、このような基材に本願で言う水性塗料及び被覆
材を塗布することにより、水分の蒸発が急激に起こり塗
材の水和反応が不完全な状態になり、脆性な塗膜が形成
される。この場合、水分の蒸発の度合いに応じて表面塗
膜に水分の補給をする。この補給方法は、表面塗膜に圧
力を加えない方法、たとえば噴霧器、スプレ−等で補給
することが好ましい。
[0111] When the temperature is high, the temperature of the base material often rises. By applying the water-based paint and the coating material referred to in the present application to such a base material, evaporation of moisture rapidly occurs, and The hydration reaction is incomplete and a brittle coating is formed. In this case, water is supplied to the surface coating according to the degree of evaporation of the water. This replenishment method is preferably a method in which pressure is not applied to the surface coating film, for example, by using a sprayer, a sprayer or the like.

【012】また、気温に関係なく吸水、吸湿性能の高い基
材の場合も本願請求項で言う塗材が、基材に水分を急激
に吸収されるため不完全な水和反応によりクラックの発
生又は表面に粉状のものが浮いた状態になり、触手する
と粉状の組成物が付着してくる。このような状態を防止
するためには、塗材表面の水分の吸収状態により水分補
給を行うが、基材の水分吸収能力に応じて複数回水分補
給をすることが好ましい。また、いずれの場合も水分補
給は水和反応の終了、すなわち、セメント系無機質接合
剤が水と混合して化合し、水和物を生成して硬化するま
での間の早い時期に水分補給をする必要がある。
Further, even in the case of a substrate having high water absorption and moisture absorption performance irrespective of the temperature, cracks occur due to incomplete hydration reaction because the coating material according to the present invention rapidly absorbs water. Alternatively, a powdery substance floats on the surface, and the powdery composition adheres when touched. In order to prevent such a state, water is replenished according to the state of water absorption on the surface of the coating material. However, it is preferable to replenish water a plurality of times according to the water absorbing ability of the base material. In each case, hydration is completed at the end of the hydration reaction, that is, at an early stage until the cement-based inorganic bonding agent mixes with water to form a hydrate and hardens. There is a need to.

【013】このようになる場合はその吸湿能力と塗膜厚に
もよるが、早いものでは塗布後数分で塗布膜表面の水分
がなくなり、その様子が容易に確認できる。
In such a case, although it depends on the moisture absorption capacity and the thickness of the coating film, if it is earlier, the moisture on the surface of the coating film disappears within a few minutes after application, and the state can be easily confirmed.

【014】この場合、セメント系無機質接合剤に着色した
顔料はセメント系無機質接合剤の早期硬化により水分補
給による影響は受けない。
In this case, the pigment colored in the cement-based inorganic bonding agent is not affected by water replenishment due to the early curing of the cement-based inorganic bonding agent.

【015】請求項5に記載した発明は、水分で洗い流すこと
を特徴として、多孔質性のような表面の粗い基材に効果
的で、基材そのものが目的機能をもつものであるときに
は、その機能を損なわず着色、柄、模様が表現できる特
徴と、基材の厚みサイズをほとんど変えず意匠性が確保
できる。この場合、使用する水性塗料及び被覆材の粒子
は微粒子が好ましい。また、上記すべての発明による水
分の表示は水蒸気でもよく設備の可能な工場内等で成形
物に塗布及び被覆する場合は、水分補給にもなり成形物
の良好な早期硬化につながり能率も上がる。この場合、
水蒸気の温度が高いほど良好な早期硬化が期待できる。
The invention described in claim 5 is characterized in that it is washed away with water, and is effective for a substrate having a rough surface such as a porous material. Features that can express coloring, patterns, and patterns without impairing the function, and design properties can be secured without substantially changing the thickness of the base material. In this case, the particles of the water-based paint and the coating material used are preferably fine particles. In addition, the indication of moisture according to all of the above-mentioned inventions may be made of water vapor, and when it is applied to and coated on a molded product in a factory or the like where equipment is available, it also provides water replenishment and leads to favorable early curing of the molded product, thereby increasing efficiency. in this case,
The higher the steam temperature, the better the early curing can be expected.

【016】[016]

【発明実施の形態】以下、本願発明に係る実施の形態を
具体的に説明する。基材には段谷産業株式会社製e.ウォ
−ル吸湿ボ−ドで、その吸湿性能は、25℃×50%RH.4
8h→25℃×90%RH.24h(吸湿)25℃×50%RH.24
h(放湿)g/m2 227の性能を持つ吸湿性能の高い
ものを使用した。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments according to the present invention will be specifically described below. The base material is e.Wall moisture absorption board manufactured by Tanya Sangyo Co., Ltd. The moisture absorption performance is 25 ° C. × 50% RH.4
8h → 25 ℃ × 90% RH.24h (moisture absorption) 25 ℃ × 50% RH.24
A material having a high moisture absorption performance having a performance of h (dehumidification) g / m 2 227 was used.

【017】セメント系無機質接合剤として白色ポルトラン
ドセメント、炭酸カルシウム質粉体、二酸化珪素質粉
体、活性炭、樹脂エマルジョン、顔料を配合して水を加
え攪拌して吸湿性の高い水性塗料にした。
[0173] White Portland cement, calcium carbonate-based powder, silicon dioxide-based powder, activated carbon, resin emulsion, and pigment were blended as a cement-based inorganic bonding agent, and water was added thereto with stirring to obtain an aqueous paint having high hygroscopicity.

【018】室温28℃湿度55%の条件で、上記吸湿ボ−ド三
枚を用意して一枚を水に没水して水分を充分に吸水させ
二枚はそのままの状態で、三枚に上記塗料をスプレ−で
塗膜厚0.5mmに塗布した。
[0182] Under the conditions of room temperature 28 ° C and humidity 55%, prepare the above three moisture absorbing boards, submerge one in water, absorb enough water, and leave the two pieces as they are. The above paint was applied by spraying to a film thickness of 0.5 mm.

【019】スプレ−後表面を観察したところ、没水した一
枚以外は2分間で表面の水分がなくなり表面が乾燥状態
になったが、没水した一枚は表面が乾燥状態になるまで
15分間を要した。
When the surface after spraying was observed, except for one of the submerged ones, the surface water was lost in 2 minutes and the surface became dry, but one of the submerged ones until the surface became dry
It took 15 minutes.

【020】没水した吸湿ボ−ド一枚と、それ以外の一枚を
そのままの状態で放置、乾燥させた。また、残り一枚の
吸湿ボ−ドには塗布30分後、表面に水をスプレ−で噴霧
したが再び表面が乾燥状態になったので、水の噴霧を3
回繰り返した後、放置乾燥した。
One submerged moisture-absorbing board and the other one were left as they were and dried. Also, 30 minutes after application to the remaining one moisture absorbing board, water was sprayed on the surface by spraying. However, since the surface became dry again, spraying of water was performed for 3 minutes.
After repeating this time, it was left to dry.

【021】24時間後、上記三枚の吸湿ボ−ドに塗布した塗
料を比較したところ、没水せず水の噴霧もしなかったボ
−ドは表面に組成物の粉状のものが浮き、手で触ると手
に粉状のものが大量に付着した。また、没水したもの
は、わずかであるが粉状のものが手に付着して表面にわ
ずか粉感触が残った。しかし、表面に水を噴霧したもの
は、手に粉状のものは一切付着せず、その感触もなく、
硬度も高かった。また、顔料を観察したが、顔料が滲む
こともなく、色彩も前二枚に比べて優れていた。
After 24 hours, when the paints applied to the above three moisture absorbing boards were compared, the powder which was not submerged nor sprayed with water had a powdery composition floating on the surface, When touched by hand, a large amount of powdery substances adhered to the hand. The submerged one was slightly powdery but adhered to the hand, leaving a slight powder feel on the surface. However, when spraying water on the surface, powdery substances do not adhere to the hands at all, there is no touch,
Hardness was also high. In addition, the pigment was observed, but the pigment did not bleed and the color was excellent as compared with the previous two sheets.

【022】また、請求項5について、上記ボ−ドにスプレ−
した3分後、水で洗い流しボ−ドを観察したところ基材
表面全部に着色しており、乾燥後も変化なく、ウエスに
水をつけて摩擦してもウエスに顔料の付着もなく良好で
あった。 ─────────────────────────────────────────────────────
[0222] In claim 5, a spray is applied to the board.
After 3 minutes, rinsed with water and observed the board.The whole surface of the base material was colored, and there was no change even after drying. there were. ────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成12年11月7日(2000.11.
7)
[Submission date] November 7, 2000 (200.11.
7)

【手続補正1】[Procedure amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】特許請求の範囲[Correction target item name] Claims

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【特許請求の範囲】[Claims]

【手続補正2】[Procedure amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】発明の詳細な説明[Correction target item name] Detailed description of the invention

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【001】[001]

【産業上の利用分野】屋内における内装材等に関して、
シックハウス症候群の多発から無機質剤を主材とした人
にやさしい建材が多く開発されている。その中で不燃性
であり、吸放湿効果の高い湿度調整基材が結露防止効果
も含めて注目されている。本願発明はこれら湿度調整建
材の問題点を解決することによって日本の風土気候に適
した人にやさしい内装材の普及が期待できる他、セメン
ト系無機質接合剤の持つ短所を解決することにより、各
分野での幅広い需要が期待できる。
[Industrial applications] For interior materials etc. indoors,
Since the sick house syndrome occurs frequently, many human-friendly building materials mainly composed of inorganic agents have been developed. Among them, a non-flammable, humidity-adjusting base material having a high moisture absorption / release effect has attracted attention, including an effect of preventing dew condensation. The invention of the present application can be expected to spread human-friendly interior materials suitable for the climate of Japan by solving the problems of the humidity-adjusting building materials, and solve the disadvantages of the cement-based inorganic bonding agent in various fields. A wide range of demand can be expected.

【002】[002]

【従来の技術】セメント系無機質接合剤を成分とした水
性塗料及び水性被覆剤は、気温の高い時期、基材の温度
が高くなる場合、基材に散水して基材の温度を下げ水分
の蒸発を押さえ水和反応の安定をはかってきたが、作業
する面積によっては安定した水和反応は期待できなかっ
た。また、最近では湿度調整内装材の普及により吸水、
吸湿性の高いものが使用されている。このような基材に
表面仕上をする場合は、塗布材の水分が急激に奪われ、
塗布膜表面は脆弱で、粉が噴いた状態になり触れると衣
服を汚す場合も多い。
2. Description of the Related Art A water-based paint and a water-based coating agent containing a cement-based inorganic binder as a component are used to spray water on the base material to lower the temperature of the base material when the temperature of the base material becomes high when the temperature is high. Although the hydration reaction was stabilized by suppressing evaporation, a stable hydration reaction could not be expected depending on the working area. In addition, recently, with the spread of humidity adjustment interior materials, water absorption,
Highly hygroscopic materials are used. When finishing the surface of such a substrate, the moisture of the coating material is rapidly taken away,
The surface of the coating film is fragile, and the powder is in a state of being sprayed and often stains clothes when touched.

【003】[003]

【発明が解決しようとする課題】気温の高い時期又は塗
布しようとする基材の温度が高い場合に発生する不完全
水和反応はセメント系無機質接合剤を必須成分とする水
性塗料及び水性被覆材は強度及び硬度を劣化させる。
The incomplete hydration reaction which occurs when the temperature is high or when the temperature of the substrate to be applied is high is a water-based paint and water-based coating material containing a cement-based inorganic binder as an essential component. Degrades strength and hardness.

【004】また、湿度調整建材の場合、素地で成形される
ことが多く意匠性に問題が残る。着色、柄、模様をつけ
る場合においては、その吸湿、放湿性能を保持する必要
があるため湿度調整建材同等もしくはそれ以上の吸湿、
放湿効果のあるもので着色、柄、模様をつけ意匠性を確
保する必要がある。
In the case of a humidity-adjusting building material, it is often formed from a base material, and there remains a problem in designability. In the case of coloring, patterning, and patterning, it is necessary to maintain the moisture absorption and moisture release performance, so that moisture absorption equal to or more than the humidity adjustment building material,
It is necessary to add coloring, design, and design to the material that has a moisture releasing effect to ensure the design.

【005】透湿性の高い布、紙を貼ることもできるが、貼
ることによってある種の糊付け行為を余儀なくされて建
材そのものの機能を低下させることになるとともに、不
燃性を確保出来にくくなる他、吸水することによって伸
縮するものもある。
[005] A cloth or paper with high moisture permeability can also be applied, but pasting will necessitate a certain type of gluing action, lowering the function of the building material itself, and making it difficult to ensure nonflammability. Some of them expand and contract by absorbing water.

【006】また、従来から吸湿放湿性能を持つ水性無機質
系の塗料及び被覆材は使用されているが、そのほとんど
が表面に粉塵が残り、触ると粉塵が付着し衣服を汚すこ
ともある。粉塵粒度によっては空気中に漂い衛生上にも
好ましくない。また、床に落ち床を汚すことさえある。
In addition, aqueous inorganic paints and coating materials having a moisture absorbing and releasing performance have been used in the past, but most of them have dust left on the surface, and when touched, the dust adheres and may stain clothes. Depending on the particle size of the dust, it floats in the air and is not preferable for sanitation. It can even fall on the floor and soil the floor.

【007】[007]

【課題を解決するための手段】本願の請求項1に記載し
た発明は、気温の高い時期又は塗布する基材の温度が高
い時に発生するセメント系無機質接合剤を必須成分とし
た水性塗料及び水性被覆材の水分の早期蒸発による不完
全水和反応による脆性防止クラック防止を塗布後、塗布
物表面の水分補給の調整により防止することを特徴とす
る。また、本願発明で言う水和反応とは、セメント系無
機質接合剤が水と混合して化合し、水和物を生成して硬
化することを言う。
Means for Solving the Problems The invention described in claim 1 of the present application relates to a water-based paint and a water-based paint containing a cement-based inorganic binder generated as an essential component when the temperature is high or when the temperature of the substrate to be applied is high. It is characterized in that the brittleness is prevented by the incomplete hydration reaction due to the early evaporation of the moisture of the coating material and the crack is prevented by adjusting the water supply on the surface of the coated material after coating. In addition, the hydration reaction referred to in the present invention means that the cement-based inorganic bonding agent is mixed with water to form a hydrate and hardens.

【008】本願の請求項2に記載した発明は、セメント系無
機質接合剤を必須成分とする水性塗料及び水性被覆材
が、基材の持つ吸水、吸湿性能により発生する不完全水
和反応によると塗布膜表面の脆性防止及びクラック防止
を塗布後、塗布物表面の水分補給の調整により防止する
ことを特徴とする。
The invention described in claim 2 of the present application is based on the fact that the water-based paint and the water-based coating material containing the cement-based inorganic bonding agent as an essential component are based on the incomplete hydration reaction generated by the water absorption and moisture absorption properties of the base material. After coating, the prevention of brittleness and cracks on the coating film surface is prevented by adjusting the water supply on the surface of the coating material.

【009】本願の請求項3に記載した発明は、セメント系無
機質接合を必須成分とする水性塗料及び水性被覆材自体
が吸水、吸湿能力、又はその目的を持つもので、同種能
力、目的を持つ基材に塗布した時に発生する不完全水和
反応による塗布膜表面の脆性防止及びクラック防止を塗
布後、塗布物表面の水分補給の調整により防止すること
を特徴とする。
[009] In the invention described in claim 3 of the present application, the water-based paint and the water-based coating material having cement-based inorganic bonding as an essential component have water absorption, moisture absorption ability, or the purpose thereof, and have the same kind of ability and purpose. Prevention of brittleness and cracks on the surface of the coating film due to incomplete hydration reaction that occurs when the composition is applied to a substrate is prevented by adjusting the water supply on the surface of the coating material after coating.

【010】本願の請求項4に記載した発明は、セメント系無
機質接合剤を必須成分とする水性塗料及び被覆材が吸
水、吸湿性能又はその目的を持ったものであり、塗布す
る基材の種別が不特定である場合の、クラック防止及び
塗布表面の脆性劣化を塗布後、塗布物表面の水分補給の
調整により防止することを特徴とする。
[0102] The invention described in claim 4 of the present application is characterized in that the water-based paint and the coating material containing the cement-based inorganic binder as an essential component have water absorption and moisture absorption performance or the purpose thereof, and Is unspecified, cracks are prevented and brittleness deterioration of the coated surface is prevented by adjusting the water supply on the coated surface after coating.

【011】気温の高い時期、基材の温度が高くなる場合が
多いが、このような基材に本願で言う水性塗料及び被覆
材を塗布することにより、水分の蒸発が急激に起こり塗
材の水和反応が不完全な状態になり、脆性な塗膜が形成
される。この場合、水分の蒸発の度合いに応じて表面塗
膜に水分の補給をする。この補給方法は、表面塗膜に圧
力を加えない方法、たとえば噴霧器、スプレ−等で補給
することが好ましい。
[0111] When the temperature is high, the temperature of the base material often rises. However, by applying the water-based paint and the coating material referred to in the present application to such a base material, evaporation of moisture rapidly occurs and the coating material The hydration reaction is incomplete and a brittle coating is formed. In this case, water is supplied to the surface coating according to the degree of evaporation of the water. This replenishment method is preferably a method in which pressure is not applied to the surface coating film, for example, by using a sprayer, a sprayer or the like.

【012】また、気温に関係なく吸水、吸湿性能の高い基
材の場合も本願請求項で言う塗材が、基材に水分を急激
に吸収されるため不完全な水和反応によりクラックの発
生又は表面に粉状のものが浮いた状態になり、触手する
と粉状の組成物が付着してくる。このような状態を防止
するためには、塗材表面の水分の吸収状態により水分補
給を行うが、基材の水分吸収能力に応じて複数回水分補
給をすることが好ましい。また、いずれの場合も水分補
給は水和反応の終了、すなわち、セメント系無機質接合
剤が水と混合して化合し、水和物を生成して硬化するま
での間の早い時期に水分補給をする必要がある。
Further, even in the case of a substrate having high water absorption and moisture absorption performance irrespective of the temperature, cracks occur due to incomplete hydration reaction because the coating material according to the present invention rapidly absorbs water. Alternatively, a powdery substance floats on the surface, and the powdery composition adheres when touched. In order to prevent such a state, water is replenished according to the state of water absorption on the surface of the coating material. However, it is preferable to replenish water a plurality of times according to the water absorbing ability of the base material. In each case, hydration is completed at the end of the hydration reaction, that is, at an early stage until the cement-based inorganic bonding agent mixes with water to form a hydrate and hardens. There is a need to.

【013】このようになる場合はその吸湿能力と塗膜厚に
もよるが、早いものでは塗布後数分で塗布膜表面の水分
がなくなり、その様子が容易に確認できる。
In such a case, although it depends on the moisture absorption capacity and the thickness of the coating film, if it is earlier, the moisture on the surface of the coating film disappears within a few minutes after application, and the state can be easily confirmed.

【014】この場合、セメント系無機質接合剤に着色した
顔料はセメント系無機質接合剤の早期硬化により水分補
給による影響は受けない。
In this case, the pigment colored in the cement-based inorganic bonding agent is not affected by water replenishment due to the early curing of the cement-based inorganic bonding agent.

【015】請求項5に記載した発明は、水分で洗い流すこと
を特徴として、多孔質性のような表面の粗い基材に効果
的で、基材そのものが目的機能をもつものであるときに
は、その機能を損なわず着色、柄、模様が表現できる特
徴と、基材の厚みサイズをほとんど変えず意匠性が確保
できる。この場合、使用する水性塗料及び被覆材の粒子
は微粒子が好ましい。また、上記すべての発明による水
分の表示は水蒸気でもよく設備の可能な工場内等で成形
物に塗布及び被覆する場合は、水分補給にもなり成形物
の良好な早期硬化につながり能率も上がる。この場合、
水蒸気の温度が高いほど良好な早期硬化が期待できる。
請求項6に記載した発明は、基材にあらかじめ吸湿、吸
水させることにより、その保水した水分を塗布物の反対
面すなわち裏側から30℃以上で好ましくは80℃〜150℃
の加熱、温風等の処理をすることにより、基材に保水し
た水分が蒸発および気化により塗布物表面、及び塗布物
全般に、水分不足のため発生する不完全水和反応による
塗布物の劣化、及び脆弱を防止するのに効果的である。
また、請求項7に記載した発明は、上記方法と、塗布物
表面よりの水分補給を併用したもので、不完全水和反応
の防止としてはセメント系無機質接合剤を必須成分とし
た水性塗料及び被覆材にはより効果的である。
The invention described in claim 5 is characterized in that it is washed away with water, and is effective for a substrate having a rough surface such as a porous material. Features that can express coloring, patterns, and patterns without impairing the function, and design properties can be secured without substantially changing the thickness of the base material. In this case, the particles of the water-based paint and the coating material used are preferably fine particles. In addition, the indication of moisture according to all of the above-mentioned inventions may be made of water vapor, and when it is applied to and coated on a molded product in a factory or the like where equipment is available, it also provides water replenishment and leads to favorable early curing of the molded product, thereby increasing efficiency. in this case,
The higher the temperature of the steam, the better early curing can be expected.
The invention described in claim 6 is that the base material absorbs moisture in advance and absorbs water, so that the retained water is 30 ° C. or more, preferably 80 ° C. to 150 ° C., from the opposite surface of the coated material, that is, from the back side.
Deterioration of coated material due to incomplete hydration reaction that occurs due to insufficient water on the surface of coated material and overall coated material due to evaporation and vaporization of water retained in the substrate by heating, warm air, etc. , And vulnerabilities.
Further, the invention according to claim 7 is a method in which the above method and water replenishment from the surface of the applied material are used in combination, and in order to prevent the incomplete hydration reaction, an aqueous paint containing a cement inorganic binder as an essential component and It is more effective for coating materials.

【016】[016]

【発明実施の形態】以下、本願発明に係る実施の形態を
具体的に説明する。基材には段谷産業株式会社製e.ウォ
−ル吸湿ボ−ドで、その吸湿性能は、25℃×50%RH.4
8h→25℃×90%RH.24h(吸湿)25℃×50%RH.24
h(放湿)g/m2 227の性能を持つ吸湿性能の高い
ものを使用した。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments according to the present invention will be specifically described below. The base material is e.Wall moisture absorption board manufactured by Tanya Sangyo Co., Ltd. The moisture absorption performance is 25 ° C. × 50% RH.4
8h → 25 ℃ × 90% RH.24h (moisture absorption) 25 ℃ × 50% RH.24
A material having a high moisture absorption performance having a performance of h (dehumidification) g / m 2 227 was used.

【017】セメント系無機質接合剤として白色ポルトラン
ドセメント、炭酸カルシウム質粉体、二酸化珪素質粉
体、活性炭、樹脂エマルジョン、顔料を配合して水を加
え攪拌して吸湿性の高い水性塗料にした。
[0173] White Portland cement, calcium carbonate-based powder, silicon dioxide-based powder, activated carbon, resin emulsion, and pigment were blended as a cement-based inorganic bonding agent, and water was added thereto with stirring to obtain an aqueous paint having high hygroscopicity.

【018】室温28℃湿度55%の条件で、上記吸湿ボ−ド三
枚を用意して一枚を水に没水して水分を充分に吸水させ
二枚はそのままの状態で、三枚に上記塗料をスプレ−で
塗膜厚0.5mmに塗布した。
[0182] Under the conditions of room temperature 28 ° C and humidity 55%, prepare the above three moisture absorbing boards, submerge one in water, absorb enough water, and leave the two pieces as they are. The above paint was applied by spraying to a film thickness of 0.5 mm.

【019】スプレ−後表面を観察したところ、没水した一
枚以外は2分間で表面の水分がなくなり表面が乾燥状態
になったが、没水した一枚は表面が乾燥状態になるまで
15分間を要した。
When the surface after spraying was observed, except for one of the submerged ones, the surface water was lost in 2 minutes and the surface became dry, but one of the submerged ones until the surface became dry
It took 15 minutes.

【020】没水した吸湿ボ−ド一枚と、それ以外の一枚を
そのままの状態で放置、乾燥させた。また、残り一枚の
吸湿ボ−ドには塗布30分後、表面に水をスプレ−で噴霧
したが再び表面が乾燥状態になったので、水の噴霧を3
回繰り返した後、放置乾燥した。
One submerged moisture-absorbing board and the other one were left as they were and dried. Also, 30 minutes after application to the remaining one moisture absorbing board, water was sprayed on the surface by spraying. However, since the surface became dry again, spraying of water was performed for 3 minutes.
After repeating this time, it was left to dry.

【021】24時間後、上記三枚の吸湿ボ−ドに塗布した塗
料を比較したところ、没水せず水の噴霧もしなかったボ
−ドは表面に組成物の粉状のものが浮き、手で触ると手
に粉状のものが大量に付着した。また、没水したもの
は、わずかであるが粉状のものが手に付着して表面にわ
ずか粉感触が残った。しかし、表面に水を噴霧したもの
は、手に粉状のものは一切付着せず、その感触もなく、
硬度も高かった。また、顔料を観察したが、顔料が滲む
こともなく、色彩も前二枚に比べて優れていた。
After 24 hours, when the paints applied to the above three moisture absorbing boards were compared, the powder which was not submerged nor sprayed with water had a powdery composition floating on the surface, When touched by hand, a large amount of powdery substances adhered to the hand. The submerged one was slightly powdery but adhered to the hand, leaving a slight powder feel on the surface. However, when spraying water on the surface, powdery substances do not adhere to the hands at all, there is no touch,
Hardness was also high. In addition, the pigment was observed, but the pigment did not bleed and the color was excellent as compared with the previous two sheets.

【022】また、請求項5について、上記ボ−ドにスプレ−
した3分後、水で洗い流しボ−ドを観察したところ基材
表面全部に着色しており、乾燥後も変化なく、ウエスに
水をつけて摩擦してもウエスに顔料の付着もなく良好で
あった。
[0222] In claim 5, a spray is applied to the board.
After 3 minutes, rinsed with water and observed the board.The whole surface of the base material was colored, and there was no change even after drying. there were.

【023】請求項6について、上記ボ−ドを1分間水没させ
保水させた後、上記塗布物を同条件で塗布し、ボ−ドの
反対側、すなわち裏面より130℃の温風を当てたところ
水蒸気が立上がり10分後観察したところ、塗布物表面は
良好な水和反応での硬化が観察でき温風を止め、20分間
放置したところ塗布物は良好に乾燥硬化した。また、24
時間後には更に硬度が確認できた。請求項7について、
上記同条件でボ−ドに塗布し、温風過熱しながら塗布物
表面にスプレ−で水分補給を行い上記と同じ10分後観察
したところ、上記と同じく良好な水和反応での硬化がみ
られ、さらに20分間放置したところ、上記乾燥硬化とほ
とんど変化はないように見えたが、24時間後では上記乾
燥硬化したものより塗布物全体の硬度の高いことが確認
できた。
According to claim 6, after the board is submerged for 1 minute to retain water, the coated material is applied under the same conditions, and hot air of 130 ° C. is blown from the opposite side of the board, that is, from the back surface. Observation was made 10 minutes after the rise of water vapor, and the surface of the coated product was found to be hardened by a good hydration reaction. The warm air was stopped, and the coated product was dried and cured well when left standing for 20 minutes. Also, 24
After the time, the hardness was further confirmed. Regarding claim 7,
The coating was applied to the board under the same conditions as described above, and the surface of the coating was hydrated with a spray while heating with hot air. Observation was conducted 10 minutes after the above. After further standing for 20 minutes, it seemed that there was almost no change from the above-mentioned dried and cured, but after 24 hours, it was confirmed that the hardness of the entire coated product was higher than that of the dried and cured one.

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 4D075 BB79Z CA02 CA03 CA37 CA39 CA40 DA06 DA23 DC01 EA06 EB03 4F100 AD11 AE00 AE01A AE09 AP10 AR00B AT00B BA02 CA13 CA23A CC00A EH462 EJ982 GB07 JB05A JC00 JD15B JK01 JK12 4G028 DA01 DB01 DC01 DC07 4J038 AA011 HA496 MA08 NA01 NA06 NA11 PB05 PC06  ──────────────────────────────────────────────────続 き Continuing on the front page F term (reference) 4D075 BB79Z CA02 CA03 CA37 CA39 CA40 DA06 DA23 DC01 EA06 EB03 4F100 AD11 AE00 AE01A AE09 AP10 AR00B AT00B BA02 CA13 CA23A CC00A EH462 EJ982 GB07 JB05A JC01 JD014J01 DC1 AA011 HA496 MA08 NA01 NA06 NA11 PB05 PC06

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】セメント系無機質接合剤を必須成分とする
水性塗料及び水性被覆材を塗布し、塗布後、塗布物表面
の水分補給により塗布物を良好な強度及び硬度にするこ
とを特徴とする。
An aqueous paint and an aqueous coating material containing a cement-based inorganic bonding agent as an essential component are applied, and after application, the applied material has good strength and hardness by rehydrating the surface of the applied material. .
【請求項2】吸水性及び吸湿性が高い、又はそれを目的
とした成形物の表面に、セメント系無機質接合剤を必須
成分とした水性塗料及び水性被覆材を塗布し、塗布後、
塗布物表面の水分補給により塗布物を良好な強度及び硬
度にすることを特徴とする。
2. A water-based paint and a water-based coating material having a cement-based inorganic bonding agent as an essential component are applied to the surface of a molded product having high water absorbency and hygroscopicity or intended for the purpose, and after the application,
It is characterized in that the applied material has good strength and hardness by rehydrating the surface of the applied material.
【請求項3】セメント系無機質接合剤を必須成分とした
水性塗料及び水性被覆材が、吸水及び吸湿目的を持つも
ので、同じ吸水、吸湿目的を持つ基材に塗布し、塗布
後、塗布物表面の水分補給により塗布物を良好な強度及
び硬度にすることを特徴とする。
3. A water-based paint and a water-based coating material having a cement-based inorganic bonding agent as an essential component have a water-absorbing and moisture-absorbing purpose, and are applied to a substrate having the same water-absorbing and moisture-absorbing purpose. It is characterized in that the coated material has good strength and hardness by hydration of the surface.
【請求項4】セメント系無機質接合剤を必須成分とした
水性塗料及び水性被覆材が吸水及び吸湿目的をもつもの
で、各種別の不特定基材を対象に塗布し、塗布後、塗布
物表面の水分補給により塗布物が良好な強度及び硬度に
することを特徴とする。
4. A water-based paint and a water-based coating material having a cement-based inorganic binder as an essential component have a water-absorbing and moisture-absorbing purpose, and are applied to various unspecified base materials. Is characterized in that the applied material has good strength and hardness by hydration.
JP2000253649A 2000-08-24 2000-08-24 Retaining method of strength and hardness by preventing incomplete hydration reaction caused by atmospheric temperature and quality of base material with water base paint and covering material containing cement system inorganic sealant as indispensable component Pending JP2002059075A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000253649A JP2002059075A (en) 2000-08-24 2000-08-24 Retaining method of strength and hardness by preventing incomplete hydration reaction caused by atmospheric temperature and quality of base material with water base paint and covering material containing cement system inorganic sealant as indispensable component

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000253649A JP2002059075A (en) 2000-08-24 2000-08-24 Retaining method of strength and hardness by preventing incomplete hydration reaction caused by atmospheric temperature and quality of base material with water base paint and covering material containing cement system inorganic sealant as indispensable component

Publications (1)

Publication Number Publication Date
JP2002059075A true JP2002059075A (en) 2002-02-26

Family

ID=18742710

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000253649A Pending JP2002059075A (en) 2000-08-24 2000-08-24 Retaining method of strength and hardness by preventing incomplete hydration reaction caused by atmospheric temperature and quality of base material with water base paint and covering material containing cement system inorganic sealant as indispensable component

Country Status (1)

Country Link
JP (1) JP2002059075A (en)

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