JP2002012513A - Urea-containing whipped cosmetic - Google Patents

Urea-containing whipped cosmetic

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Publication number
JP2002012513A
JP2002012513A JP2001089313A JP2001089313A JP2002012513A JP 2002012513 A JP2002012513 A JP 2002012513A JP 2001089313 A JP2001089313 A JP 2001089313A JP 2001089313 A JP2001089313 A JP 2001089313A JP 2002012513 A JP2002012513 A JP 2002012513A
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Japan
Prior art keywords
urea
cosmetic
containing
present invention
amount
Prior art date
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Pending
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JP2001089313A
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Japanese (ja)
Inventor
Fumiko Sugano
Daisuke Taguchi
Katsuhiko Yoshida
勝彦 吉田
大介 田口
富美子 菅野
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Kanebo Ltd
カネボウ株式会社
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Priority to JP2000-122110 priority Critical
Priority to JP2000122110 priority
Application filed by Kanebo Ltd, カネボウ株式会社 filed Critical Kanebo Ltd
Priority to JP2001089313A priority patent/JP2002012513A/en
Publication of JP2002012513A publication Critical patent/JP2002012513A/en
Application status is Pending legal-status Critical

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Abstract

PROBLEM TO BE SOLVED: To obtain a urea-containing cosmetic excellent in feeling of use and usability. SOLUTION: This urea-containing whipped cosmetic is characterized by filling a cosmetic comprising (A) urea, (B) a urea stabilizer and (C) a surfactant in a non-gas foamer container.

Description

【発明の詳細な説明】 DETAILED DESCRIPTION OF THE INVENTION

【0001】 [0001]

【発明の属する技術分野】本発明は、尿素含有ホイップ状化粧料に関し、詳しくは、特定の容器に充填され、使用感及び使用性に優れた尿素含有ホイップ状化粧料に関する。 The present invention relates to relates to urea-containing whipped-like cosmetic, particularly, is filled to a specific container, to better urea-containing whipped-like cosmetic feel and usability.

【0002】 [0002]

【従来の技術】NMF(天然保湿因子)の1つとして知られている尿素は、角質内水分保持作用、創傷治癒作用、殺菌作用等皮膚に対して優れた作用を有している。 Urea is known as one of the Related Art NMF (natural moisturizing factor), horny the water retention effect, wound healing effect, and has an excellent effect on bactericidal action like skin.
そして尿素を配合した皮膚外用剤が多数開発されている。 The skin external agents have been developed numerous formulated with urea. (特開昭52−105225、特開昭51−484 (JP-A-52-105225, JP-A-51-484
41、特開平3−291221、特開平4−1129、 41, JP-A 3-291221, JP-A-4-1129,
特開平6−24954号公報) JP 6-24954)

【0003】しかしこれらの製剤のほとんどは、クリーム状、軟膏状、乳液状、ローション状、エアゾール状のものである。 However most of these preparations, cream, ointment, milky lotion, lotion, those aerosol form. クリーム状、軟膏状、乳液状の製剤は、塗布時に配合成分である油性成分由来の油膜感、べたつき感等の不快感が生じたり、ローション等の製剤と比べ厚目に塗布されるため、皮膚の上での延展性が十分でない等の問題があった。 For creams, ointments, milky formulation, the oil film feeling from the oil component is a blend component at the time of application, or cause discomfort such as stickiness, is applied to the thick compared to the formulation of lotions, skin spreadability of on there was a problem such as not enough. 一方、ローション状の製剤は、感触は優れるが、誤飲等の安全性の問題があり、また塗布時に液の垂れ落ち等が生じ、目的とする部位に均一に塗布できず、使用性が十分ではなかった。 On the other hand, the lotion-like formulations, but feel superior, has safety problems for ingestion such as erroneous and dripping or the like of the liquid occurs at the time of coating can not be uniformly applied to the site of interest, usability is sufficiently In did not. エアゾール状の製剤についても、感触についてはローション状の製剤と同様、任意に調整ができ好ましいが、フロン、LPGガス等の液化ガスを噴射剤として使用するため、引火等の安全性の問題や、環境問題等から剤型的に好ましくなかった。 For even aerosol form of the formulation, similar to the lotion formulations for feel, but preferably can be arbitrarily adjusted, Freon, for using liquefied gas such as LPG gas as a propellant, problems and safety ignition or the like, environment unfavorable to dosage forms manner from problems like.

【0004】 [0004]

【発明が解決しようとする課題】したがって、使用感及び使用性に優れた尿素を含有する化粧料の開発が望まれていた。 Thus [0007], development of cosmetics containing urea having excellent usability and usability have been desired.

【0005】 [0005]

【課題を解決するための手段】本発明者等は上記事情に鑑み、鋭意研究した結果、特定の容器に充填した尿素含有化粧料が、使用感及び使用性に優れていることを見出し、本発明を完成したものである。 The present inventors have SUMMARY OF THE INVENTION In view of the above circumstances, intensive research and as a result, found that urea-containing cosmetic filled in particular containers, have excellent usability and usability, the invention has been completed the. すなわち、本発明は、(A)尿素、(B)尿素安定剤、及び(C)界面活性剤を含有する化粧料を、ノンガスフォーマー容器に充填したことを特徴とする尿素含有ホイップ状化粧料にある。 That is, the present invention, (A) urea, (B) urea stabilizer, and (C) a cosmetic containing a surfactant, urea-containing whipped-like cosmetic, wherein the filled in non-gas foamer container It is in.

【0006】 [0006]

【発明の実施の形態】 DETAILED DESCRIPTION OF THE INVENTION

【0007】以下、本発明の実施の形態を詳述する。 [0007] Hereinafter, detailed embodiments of the present invention.

【0008】本発明の尿素含有ホイップ状化粧料とは、 [0008] The urea-containing whip-like cosmetic composition of the present invention,
(A)尿素、(B)尿素安定剤、及び(C)界面活性剤を含有する化粧料と空気とが、ノンガスフォーマー容器によって、混合、噴出されることにより、微細な泡沫状となったものである。 (A) urea, (B) urea stabilizer, and (C) is a cosmetic and air containing a surfactant, the non-gas foamer container, mixing by being ejected, was a fine foamy it is intended.

【0009】本発明に用いられる(A)尿素の配合量は、化粧料の総量を基準として0.1〜25質量%(以下、単に%で示す)が好ましく、特に好ましくは1〜2 [0009] The amount of (A) urea used in the present invention, 0.1 to 25 wt% of the total amount of the cosmetic as a reference (hereinafter, simply indicated by%) are preferred, particularly preferably 1 to 2
0%である。 It is 0%. 配合量が0.1%未満では保湿効果が不十分の場合があり、25%を超えて配合しても、それに見合った効果の増大が得られない場合があり、また尿素の安定性を維持することが困難である。 Amount is sometimes insufficient moisturizing effect is less than 0.1%, even though the amount is more than 25%, may increase the effect corresponding thereto is not obtained, also maintain the stability of urea it is difficult to.

【0010】本発明に用いられる(B)尿素安定剤は、 [0010] (B) used in the present invention urea stabilizer,
通常化粧料において尿素の分解を抑制し、安定化を目的として配合されるものであれば特に制限されず、例えば、乳酸及びその塩類、リン酸及びその塩類、クエン酸及びその塩類、エデト酸及びその塩類等が挙げられる。 To suppress the decomposition of urea in normal cosmetics, as long as it can be formulated for the purpose of stabilizing not particularly limited, for example, lactic acid and salts thereof, phosphoric acid and salts thereof, citric acid and its salts, and edetate its salts and the like.
特に、乳酸、乳酸ナトリウムは優れた尿素の安定性を得ることができ好ましい。 In particular, lactic acid, sodium lactate is preferred can be obtained having excellent stability urea.

【0011】本発明に用いられる(B)尿素安定剤は、 [0011] (B) used in the present invention urea stabilizer,
一種単独又は二種以上を組み合わせて用いることができる。 It may be used individually or in combination of two or more. その配合量は、化粧料の総量を基準として0.5〜 The amount thereof, 0.5 to the total amount of the cosmetic as a reference
15%が好ましく、特に好ましくは1〜10%である。 Preferably 15%, particularly preferably 1-10%.
配合量が0.5%未満では尿素の安定性を維持することが困難であり、15%を超えて配合した場合、皮膚に一過性の刺激が生じる場合があり、安全性上好ましくない。 When the amount is less than 0.5%, it is difficult to maintain the stability of the urea, when the amount is more than 15%, there are cases where transient stimulation occurs in the skin, the safety is not preferable.

【0012】本発明に用いられる(C)界面活性剤は、 [0012] (C) surfactant used in the present invention,
通常化粧料に用いられるものであれば特に制限されず、 Is not particularly limited as long as it is used in normal cosmetics,
例えば、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンヒマシ油、硬化ヒマシ油、ポリオキシエチレンアルキルエーテル、ポリオキシエチレン脂肪酸、ポリグリセリン脂肪酸エステル等のノニオン性界面活性剤、アルキルエーテル硫酸エステル塩、ポリオキシエチレンアルキルエーテルリン酸エステル塩、N− For example, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene castor oil, hardened castor oil, polyoxyethylene alkyl ethers, polyoxyethylene fatty acid, nonionic surfactants such as polyglycerol fatty acid esters, alkyl ether sulfate, polyoxy polyoxyethylene alkyl ether phosphate salt, N-
アシルアラニン塩、N−アシルグルタミン酸塩、N−アシルアスパラギン酸塩等のアニオン性界面活性剤、ポリエーテル変性シリコーン等のシリコーン系界面活性剤等が挙げられる。 Acyl alanine salts, N- acyl glutamates, N- acyl aspartate anionic surfactants such as, silicone surfactants such as polyether-modified silicone. 特に好ましくは、POE(20)ヤシ油脂肪酸ソルビタン、POE(20)ラウリン酸ソルビタン、モノオレイン酸POE(20)ソルビタン、POE Particularly preferably, POE (20) coconut oil fatty acid sorbitan, POE (20) sorbitan laurate, mono-oleate POE (20) sorbitan, POE
(80)硬化ヒマシ油、POEセチルエーテル、モノステアリン酸ポリエチレングリコール、モノラウリン酸デカグリセリル、POE(3)アルキルエーテル硫酸トリエタノールアミン液、ジPOE(10)アルキルエーテルリン酸、N−ヤシ油脂肪酸アシル−DL−アラニントリエタノールアミン液(30%)、N−ヤシ油脂肪酸アシル−L−グルタミン酸トリエタノールアミン液(30 (80) hardened castor oil, POE cetyl ether, polyethylene glycol monostearate, decaglyceryl monolaurate, POE (3) alkyl ether sulfate triethanolamine solution, di POE (10) alkyl ether phosphates, N- coconut oil fatty acid acyl -DL- alanine triethanolamine solution (30%), N-cocoyl -L- glutamic acid triethanolamine solution (30
%)、N−アシル−L−アスパラギン酸トリエタノールアミン液(30%)、POEメチルポリシロキサン共重合体等であり、前記以外の界面活性剤の場合、尿素の安定性や、発泡性が十分でない場合がある。 %), N-acyl -L- aspartic acid triethanolamine solution (30%), a POE methylpolysiloxane copolymer, if a surfactant other than the, and stability of urea, foaming is sufficiently it may not.

【0013】本発明に用いられる(C)界面活性剤は、 [0013] (C) surfactant used in the present invention,
一種単独又は二種以上を組み合わせて用いることができる。 It may be used individually or in combination of two or more. その配合量は、化粧料の総量を基準として0.01 The amount thereof, the total amount of the cosmetic relative 0.01
〜4%が好ましく、特に好ましくは0.1〜3%である。 Preferably 4%, particularly preferably 0.1 to 3%. 配合量が0.01%未満では発泡性が不十分な場合があり、4%を超えて配合した場合、適当な泡の消泡性が得られにくい。 If the amount is less than 0.01% may foaming is insufficient, when the amount is more than 4%, defoaming properties suitable foam is difficult to obtain.

【0014】本発明に用いられる(D)多価アルコールとしては、エチレングリコール、ジエチレングリコール、トリエチレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、 [0014] (D) a polyhydric alcohol used in the present invention include ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol,
ポリプロピレングリコール、グリセリン、ジグリセリン、ポリグリセリン、イソプレングリコール、1,3− Polypropylene glycol, glycerol, diglycerol, polyglycerol, isoprene glycol, 1,3
ブチレングリコール、POP(9)ジグリセリン、ヘキシレングリコール、ソルビトール、マンニトール、マルチトール、POE(10)メチルグルコシド、POE Butylene glycol, POP (9) diglycerol, hexylene glycol, sorbitol, mannitol, maltitol, POE (10) methyl glucoside, POE
(20)メチルグルコシド等が挙げられる。 (20) include methyl glucoside and the like.

【0015】本発明に用いられる(D)多価アルコールは、一種単独又は二種以上を組み合わせて用いることができる。 [0015] (D) used in the present invention polyhydric alcohols may be used in combination of at least one kind alone or in combination. これらの(D)多価アルコールを適宜配合することにより、尿素含有ホイップ状化粧料の感触、延展性等を任意に調整することができる。 By blending these (D) a polyhydric alcohol can be appropriately adjusted feel urea-containing whipped-like cosmetic, the ductility and the like arbitrarily. その配合量は、化粧料の総量を基準として0.1〜20%が好ましく、特に好ましくは1〜15%である。 Its amount is from 0.1 to 20% of the total amount of the cosmetic as a reference is preferably, particularly preferably 1 to 15%. 配合量が0.1%未満では肌へのなじみが悪い場合があり、また延展性に欠ける場合がある。 Amount is sometimes affinity for the skin is poor is less than 0.1%, and in some cases lack ductility. 配合量が20%を超える場合、延展性が重く悪く、乾く際にべたつき感が生じる場合がある。 If the amount exceeds 20%, the poor heavy spreadability, stickiness when dry occurs.

【0016】本発明に用いられるノンガスフォーマー容器は、容器内の化粧料を空気と混合し、メッシュや多孔体等の泡生成手段を通過させることにより発泡させ、噴出するものであり、ポンプフォーマー(大和製罐社製) The non-gas foamer container used in the present invention, the cosmetic in the container is mixed with air, foamed by passing the foam generating means such as a mesh or a porous body, which ejected, pump Four Ma (Daiwaseikan Co., Ltd.)
等を例示することができる。 It can be exemplified, and the like. また、特公昭52−165 In addition, JP-B-52-165
67、実公昭60−24426、実開昭62−1034 67, Japanese Utility Model 60-24426, Japanese Utility Model 62-1034
58、実公昭62−42785、実公昭62−4278 58, Japanese Utility Model 62-42785, Japanese Utility Model 62-4278
6、実公昭62−42787、実開昭58−17427 6, Japanese Utility Model 62-42787, Japanese Utility Model 58-17427
2、実開平3−7963、米国特許第4,531,65 2, real-Open 3-7963, U.S. Patent No. 4,531,65
9、米国特許第3,709,437号公報、及び特願2 9, U.S. Patent No. 3,709,437 and JP Application No. 2
000−349047号の願書に最初に添付された明細書又は図面等に開示されている様な容器も用いることができる。 First container such as disclosed in the appended specification or drawings and the like in the application of No. 000-349047 can also be used.

【0017】本発明の尿素含有ホイップ状化粧料には、 [0017] The urea-containing whip-like cosmetic composition of the present invention,
上述の必須成分以外に、通常の化粧料、医薬部外品、医薬品等に用いられる各種任意成分を、本発明の目的を達成する範囲内で適宜配合することができる。 Besides the essential components described above, conventional cosmetics, quasi drugs, various optional components used in pharmaceuticals, etc., it can be appropriately compounded in the range to achieve the object of the present invention. 例えば、一価アルコール、防腐剤、消炎剤、増粘剤、エステル油、 For example, monohydric alcohols, preservatives, anti-inflammatory agents, thickeners, ester oils,
殺菌剤、色素、香料等が挙げられる。 Bactericidal agents, dyes, perfumes and the like.

【0018】具体的には、一価アルコールとしては、エタノール、イソプロパノール、ブタノール、ラウリルアルコール、セタノール、ステアリルアルコール、ベヘニルアルコール等が挙げられ、防腐剤としては、メチルパラベン、エチルパラベン、安息香酸ナトリウム、フェノキシエタノール等が挙げられ、消炎剤としては、β−グリチルレチン酸、グリチルリチン酸ジカリウム、グリチルレチン酸ステアリル、アラントイン等が挙げられ、増粘剤としては、カルボキシビニルポリマー、カルボキシメチルセルロース、ポリビニルアルコール、カラギーナン、ゼラチン等が挙げられ、エステル油としては、高級アルコールと脂肪酸の合成エステル油等が挙げられる。 [0018] Specific examples of the monohydric alcohol, ethanol, isopropanol, butanol, lauryl alcohol, cetanol, stearyl alcohol, behenyl alcohol, and examples of the preservative, methyl paraben, ethyl paraben, sodium benzoate, phenoxyethanol . Examples of the anti-inflammatory agents, beta-glycyrrhetinic acid, dipotassium glycyrrhizinate, glycyrrhetinic acid stearyl, allantoin and the like, as a thickening agent, include carboxyvinyl polymers, carboxymethyl cellulose, polyvinyl alcohol, carrageenan, gelatin etc. It is, as the ester oils, synthetic ester oils such as higher alcohols and fatty acids.

【0019】 [0019]

【実施例】以下、実施例により本発明を詳細に説明する。 EXAMPLES The following examples illustrate the present invention in detail.

【0020】実施例1 表1の組成のローションを常法により調製した後、ポンプフォーマー(大和製罐社製)に充填し、尿素含有ホイップ状化粧料を得た。 [0020] After a routinely prepared lotion composition of Example 1 in Table 1, it was filled in a pump foamer (Daiwaseikan Co.) to obtain a urea-containing whipped-like cosmetic.

【0021】 (表1) [配合成分] [配合量(%)] ・尿素 10.0 ・乳酸 1.5 ・乳酸ナトリウム 3.5 ・エデト酸二ナトリウム 0.5 ・POE(20)モノラウリン酸ソルビタン 1.0 ・ポリエチレングリコール200 10.0 ・エタノール 20.0 ・純水 残量 [0021] (Table 1) [Ingredients] [Amount (%) Urea 10.0 lactate 1.5 - Sodium lactate 3.5 - Disodium edetate 0.5 - POE (20) sorbitan monolaurate 1.0 polyethylene glycol 200 10.0 ethanol 20.0 - pure water Balance

【0022】比較例1 表1の組成のローションを常法により調製した後、ガラス容器に充填し、尿素含有ローション状化粧料を得た。 [0022] After a routinely prepared lotion composition of Comparative Example 1 in Table 1, it was filled in a glass container, to obtain a urea-containing lotions cosmetic.

【0023】<使用性・使用感評価試験>パネラー20 [0023] <usability and use feeling evaluation test> panelists 20
名に実施例1及び比較例1の化粧料を1週間連続使用させた後、使い易さ、延展性、さっぱり感(べたつき感のなさ)の良否を判断してアンケートに答え、その評価を以下のように判定した。 After the name in the cosmetic composition of Example 1 and Comparative Example 1 by one week of continuous use, ease of use, spreadability, answer a questionnaire to determine the quality of the refreshed feeling (lack of sticky feeling), the evaluation below It was determined as.

【0024】 評価基準 評価記号 良いと答えた人が18人以上の場合 ◎ 良いと答えた人が14〜17人の場合 ○ 良いと答えた人が8〜13人の場合 △ 良いと答えた人が7人以下の場合 × In the case if the evaluation criteria evaluation symbol good and people that the answer is 18 or more people ◎ good and people people who answered a good ○ the case of 14 to 17 people that the answer is 8 to 13 people △ good and answered people if × but seven or less

【0025】以下、結果を示す。 [0025] The following shows the results.

【0026】上記より明らかなように、本発明の尿素含有ホイップ状化粧料は、使用部位に塗布し易く、延展性に優れるため、広範囲に均一に塗布することができ、また塗布後にべたつき感がほとんどなく、大変優れた性能を有していた。 [0026] As apparent from the above, the urea-containing whipped form cosmetic of the present invention, easily applied to the use site, is excellent in spreadability, can be widely applied uniformly, also sticky feeling after application little, we had a very good performance. 一方、ホイップ状でない比較例1の化粧料は、液の垂れ落ち等のため、使用性に劣り、均一に塗布することができず、塗布後べたつき感を有していた。 On the other hand, the cosmetic of Comparative Example 1 not whip shape, for dripping or the like of the liquid, poor usability can not be uniformly applied, it had a sticky feeling after application.

【0027】実施例2 次の組成のローションを常法により調製した後、ポンプフォーマー(大和製罐社製)に充填し、尿素含有ホイップ状化粧料を得た。 [0027] After preparing in a conventional manner lotion of Example 2 the following composition was filled in a pump foamer (Daiwaseikan Co.) to obtain a urea-containing whipped-like cosmetic.

【0028】 [配合成分] [配合量(%)] ・尿素 15.0 ・乳酸 5.0 ・乳酸ナトリウム 5.0 ・POE(80)硬化ヒマシ油 0.1 ・グリセリン 1.0 ・エタノール 50.0 ・アロエエキス 残量 [0028] [Ingredients] [Amount (%) Urea 15.0 lactate 5.0 - Sodium lactate 5.0-POE (80) hardened castor oil 0.1 Glycerin 1.0 Ethanol 50. 0 · aloe extract remaining

【0029】実施例3 次の組成のローションを常法により調製した後、ポンプフォーマー(大和製罐社製)に充填し、尿素含有ホイップ状化粧料を得た。 [0029] After preparing in a conventional manner lotion of Example 3 The following composition was filled in a pump foamer (Daiwaseikan Co.) to obtain a urea-containing whipped-like cosmetic.

【0030】 [配合成分] [配合量(%)] ・尿素 5.0 ・乳酸 0.3 ・乳酸ナトリウム 1.2 ・モノラウリン酸デカグリセリル 3.0 ・1,3−ブチレングリコール 15.0 ・エタノール 5.0 ・グリチルリチン酸ジカリウム 0.1 ・メチルパラベン 0.1 ・純水 残量 [0030] [Ingredients] [Amount (%) Urea 5.0 lactate 0.3 - Sodium lactate 1.2-decaglyceryl monolaurate 3.0 1,3-butylene glycol 15.0 Ethanol 5.0-glycyrrhizin dipotassium 0.1 methylparaben 0.1-pure water Balance

【0031】実施例2〜3の尿素含有ホイップ状化粧料はいずれも優れた使用感及び使用性を有していた。 The urea-containing whipped form cosmetic of Example 2-3 had an excellent sense of use and usability either.

【0032】 [0032]

【発明の効果】以上記載のごとく、本発明の尿素含有ホイップ状化粧料は、使用感及び使用性に優れていることは明らかである。 As above described, according to the present invention, urea-containing whipped form cosmetic of the present invention will be apparent that an excellent feeling of use and usability.

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Claims (2)

    【特許請求の範囲】 [The claims]
  1. 【請求項1】 (A)尿素、(B)尿素安定剤、及び(C)界面活性剤を含有する化粧料を、ノンガスフォーマー容器に充填したことを特徴とする尿素含有ホイップ状化粧料。 1. A (A) urea, (B) urea stabilizer, and (C) a cosmetic containing a surfactant, urea-containing whipped-like cosmetic, wherein the filled in non-gas foamer container.
  2. 【請求項2】 更に、(D)多価アルコールを含有することを特徴とする請求項1記載の尿素含有ホイップ状化粧料。 2. A further, (D) a polyhydric urea-containing whipped-like cosmetic according to claim 1, characterized in that it contains an alcohol.
JP2001089313A 2000-04-24 2001-03-27 Urea-containing whipped cosmetic Pending JP2002012513A (en)

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