JP2001521674A - 電気化学的発電装置のチタンオキシスルフィドをベースとする陽極用材料およびその製造方法 - Google Patents
電気化学的発電装置のチタンオキシスルフィドをベースとする陽極用材料およびその製造方法Info
- Publication number
- JP2001521674A JP2001521674A JP54516698A JP54516698A JP2001521674A JP 2001521674 A JP2001521674 A JP 2001521674A JP 54516698 A JP54516698 A JP 54516698A JP 54516698 A JP54516698 A JP 54516698A JP 2001521674 A JP2001521674 A JP 2001521674A
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- tio
- power generator
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
- H01M4/382—Lithium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/581—Chalcogenides or intercalation compounds thereof
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Physical Vapour Deposition (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Conductive Materials (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. 以下の式: TiOaS3+b [式中、aとbは、 0<a≦0.5 0<b≦0.7 である]の無定形化合物の薄層からなる、電気化学的発電装置の陽極の材料。 2. 無定形化合物が、式:TiO0.2S3.3に相当する、請求項1記載の材料。 3. TiS3ターゲットから高周波陰極スパッタリングによって、以下の式: TiOaS3+b [式中、aとbは、 0<a≦0.5 0<b≦0.7 である]の無定形化合物の薄層を基板上に堆積させることからなる、電気化学的 発電装置の陽極の製造方法。 4. 基板が、電気的伝導性材料の層によって被覆された絶縁性基板である、請 求項3記載の方法。 5. 電気的伝導性材料がクロムであり、クロムが陰極スパッタリングによって 絶縁性基板に堆積される、請求項4記載の方法。 6. 陽極が、式:TiOaS3+b [式中、aとbは、 0<a≦0.5 0<b≦0.7 である]の無定形化合物の薄層からなり、当該層が基板上に配置されることを特 徴とする、陽極と、プロトンまたはアルカリ金属イオンを遊離させることができ る陰極と、これら二つの電極間に配置されたイオン伝導性電解質とを含む電気化 学的発電装置。 7. 無定形化合物が、式:TiO0.2S3.3に相当する、請求項6記載の発電装 置。 8. 基板が絶縁性基板であり、電気的伝導性材料の層によって被覆され、さら にその上に化合物TiOaS3+bの薄層が配置された、請求項6または7に記載の 発電装置。 9. 電気的伝導性材料がクロムである、請求項8記載の発電装置。 10. 陰極がリチウムからなる、請求項6ないし9のいずれか一項に記載の発 電装置。 11. 電解質がリチウムイオンを伝導するガラスである、請求項6ないし10 のいずれか一項に記載の発電装置。 12. ガラス伝導体が、1B2O3−O、8Li2O−O、8Li2SO4の組成 を有するリチウム−ホウ素化合物をベースとするガラスである、請求項11記載 の発電装置。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR97/04960 | 1997-04-22 | ||
FR9704960A FR2762448B1 (fr) | 1997-04-22 | 1997-04-22 | Materiau d'electrode positive a base d'oxysulfure de titane pour generateur electrochimique et son procede de preparation |
PCT/FR1998/000799 WO1998048467A1 (fr) | 1997-04-22 | 1998-04-21 | Materiau d'electrode positive a base d'oxysulfure de titane pour generateur electrochimique et son procede de preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2001521674A true JP2001521674A (ja) | 2001-11-06 |
JP4191260B2 JP4191260B2 (ja) | 2008-12-03 |
Family
ID=9506178
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP54516698A Expired - Fee Related JP4191260B2 (ja) | 1997-04-22 | 1998-04-21 | 電気化学的発電装置のチタンオキシスルフィドをベースとする陽極用材料およびその製造方法 |
Country Status (10)
Country | Link |
---|---|
US (1) | US6355376B1 (ja) |
EP (1) | EP0978150B1 (ja) |
JP (1) | JP4191260B2 (ja) |
KR (1) | KR100491961B1 (ja) |
AT (1) | ATE205335T1 (ja) |
CA (1) | CA2288937A1 (ja) |
DE (1) | DE69801573T2 (ja) |
FR (1) | FR2762448B1 (ja) |
TW (1) | TW410487B (ja) |
WO (1) | WO1998048467A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015176854A (ja) * | 2014-03-18 | 2015-10-05 | 公立大学法人大阪府立大学 | 酸化物系固体電解質及びその用途 |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6332900B1 (en) * | 1999-02-08 | 2001-12-25 | Wilson Greatbatch Ltd. | Physical vapor deposited electrode component and method of manufacture |
FR2831318B1 (fr) * | 2001-10-22 | 2006-06-09 | Commissariat Energie Atomique | Dispositif de stockage d'energie a recharge rapide, sous forme de films minces |
US7208195B2 (en) * | 2002-03-27 | 2007-04-24 | Ener1Group, Inc. | Methods and apparatus for deposition of thin films |
FR2862432B1 (fr) | 2003-11-14 | 2006-02-10 | Stephanois Rech Mec | Electrolyte solide, notamment pour cellule electrochimique en couches minces, et un procede de fabrication |
FR2905028B1 (fr) | 2006-08-21 | 2008-12-19 | Commissariat Energie Atomique | Dispositif de memoire electrochimique |
FR2928768B1 (fr) * | 2008-03-13 | 2010-04-09 | Commissariat Energie Atomique | Dispositif de memoire electrochimique non-volatile |
CN102054980B (zh) * | 2009-10-27 | 2014-10-08 | 法拉赛斯能源公司 | 用于锂离子电池正极的复合材料及其制备方法和电池 |
FR2952477B1 (fr) * | 2009-11-06 | 2011-12-09 | St Microelectronics Tours Sas | Procede de formation d'une batterie de type lithium-ion en couches minces |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4066824A (en) * | 1977-01-04 | 1978-01-03 | Exxon Research & Engineering Co. | Cell containing chalcogenide cathode, alkali metal anode and solid halo-aluminum alkali metal compound electrolyte |
US4243624A (en) * | 1979-05-21 | 1981-01-06 | Exxon Research & Engineering Co. | Method of making cathodes derived from ammonium-metal-chalcogen compounds |
US4508608A (en) | 1983-04-21 | 1985-04-02 | Combustion Engineering, Inc. | Method for making chalcogenide cathodes |
JPS59217964A (ja) * | 1983-05-26 | 1984-12-08 | Hitachi Ltd | 薄膜電池の正極構造 |
FR2638764B1 (fr) * | 1988-11-04 | 1993-05-07 | Centre Nat Rech Scient | Element composite comportant une couche en chalcogenure ou oxychalcogenure de titane, utilisable en particulier comme electrode positive dans une cellule electrochimique en couches minces |
US4934922A (en) * | 1989-01-09 | 1990-06-19 | Eic Laboratories, Inc. | Cathode-active materials for secondary batteries |
US5147739A (en) * | 1990-08-01 | 1992-09-15 | Honeywell Inc. | High energy electrochemical cell having composite solid-state anode |
-
1997
- 1997-04-22 FR FR9704960A patent/FR2762448B1/fr not_active Expired - Fee Related
-
1998
- 1998-04-20 TW TW087106017A patent/TW410487B/zh not_active IP Right Cessation
- 1998-04-21 DE DE69801573T patent/DE69801573T2/de not_active Expired - Lifetime
- 1998-04-21 WO PCT/FR1998/000799 patent/WO1998048467A1/fr active IP Right Grant
- 1998-04-21 AT AT98921576T patent/ATE205335T1/de active
- 1998-04-21 EP EP98921576A patent/EP0978150B1/fr not_active Expired - Lifetime
- 1998-04-21 KR KR10-1999-7008851A patent/KR100491961B1/ko not_active IP Right Cessation
- 1998-04-21 JP JP54516698A patent/JP4191260B2/ja not_active Expired - Fee Related
- 1998-04-21 CA CA002288937A patent/CA2288937A1/fr not_active Abandoned
-
1999
- 1999-10-22 US US09/403,035 patent/US6355376B1/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015176854A (ja) * | 2014-03-18 | 2015-10-05 | 公立大学法人大阪府立大学 | 酸化物系固体電解質及びその用途 |
Also Published As
Publication number | Publication date |
---|---|
DE69801573T2 (de) | 2002-07-11 |
FR2762448B1 (fr) | 1999-07-09 |
JP4191260B2 (ja) | 2008-12-03 |
FR2762448A1 (fr) | 1998-10-23 |
US6355376B1 (en) | 2002-03-12 |
CA2288937A1 (fr) | 1998-10-29 |
TW410487B (en) | 2000-11-01 |
KR100491961B1 (ko) | 2005-05-27 |
EP0978150A1 (fr) | 2000-02-09 |
WO1998048467A1 (fr) | 1998-10-29 |
ATE205335T1 (de) | 2001-09-15 |
EP0978150B1 (fr) | 2001-09-05 |
DE69801573D1 (de) | 2001-10-11 |
KR20010005779A (ko) | 2001-01-15 |
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