JP2001331983A - Molding method and molding device for optical disk - Google Patents

Molding method and molding device for optical disk

Info

Publication number
JP2001331983A
JP2001331983A JP2000151947A JP2000151947A JP2001331983A JP 2001331983 A JP2001331983 A JP 2001331983A JP 2000151947 A JP2000151947 A JP 2000151947A JP 2000151947 A JP2000151947 A JP 2000151947A JP 2001331983 A JP2001331983 A JP 2001331983A
Authority
JP
Japan
Prior art keywords
molding
resin
melting point
mold
stamper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000151947A
Other languages
Japanese (ja)
Inventor
Takaaki Higashida
隆亮 東田
Yoshio Maruyama
義雄 丸山
Shinji Kadoriku
晋二 角陸
Hiroshi Yuya
博 油谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP2000151947A priority Critical patent/JP2001331983A/en
Publication of JP2001331983A publication Critical patent/JP2001331983A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/263Moulds with mould wall parts provided with fine grooves or impressions, e.g. for record discs
    • B29C45/2632Stampers; Mountings thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/263Moulds with mould wall parts provided with fine grooves or impressions, e.g. for record discs
    • B29C45/2632Stampers; Mountings thereof
    • B29C2045/2634Stampers; Mountings thereof mounting layers between stamper and mould or on the rear surface of the stamper

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Manufacturing Optical Record Carriers (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a molding method for optical disks which can improve the quality and productivity of products by preventing the wear which occurs between a metal mold and a stamper during pouring of a resin. SOLUTION: The molding device constituted by interposing a metallic layer 3 consisting of metal having a melting point lower than the melting point of the resin 7 for molding substrates between the opposite surfaces of the metal mold 10 and the stamper 1 arranged in the prescribed position within the metal mold 10 for transferring ruggedness to the optical disk substrate is used in a molding process step for the optical disks.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は光ディスクの成形方
法および成形装置に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an optical disk molding method and apparatus.

【0002】[0002]

【従来の技術】従来の光ディスクの成形においては、図
3に示すように、SUSからなる下金型102に載置、
固定されたNiからなるスタンパ101とSUSからな
る上金型110によって形成される空隙部にスプル10
6より流し込まれた樹脂が充填され、スタンパ101に
刻みつけられた凹凸が樹脂表面に転写される。スタンパ
101に刻みつけられた凹凸が転写された後、樹脂を冷
却する。型開き完了後、エジェクトロッド107により
スプル106と成形体の突き上げを行い、下金型102
から成形体を取出す。エジェクト動作終了後、成形体を
成形機の外部に移送する。なお図3において、108は
ゲートカットパンチ、109はシリンダである。
2. Description of the Related Art In a conventional optical disk molding, as shown in FIG. 3, the optical disk is placed on a lower die 102 made of SUS.
A sprue 10 is formed in a gap formed by a fixed stamper 101 made of Ni and an upper mold 110 made of SUS.
The resin poured from 6 is filled, and the irregularities engraved on the stamper 101 are transferred to the resin surface. After the irregularities engraved on the stamper 101 are transferred, the resin is cooled. After the mold opening is completed, the sprue 106 and the molded body are pushed up by the eject rod 107, and the lower mold 102
Remove the compact from After the end of the eject operation, the molded body is transferred to the outside of the molding machine. In FIG. 3, reference numeral 108 denotes a gate cut punch, and 109 denotes a cylinder.

【0003】[0003]

【発明が解決しようとする課題】上記従来例において
は、樹脂がスプル106より金型102、110内に注
入充填される際に、樹脂の流動圧と熱(NiとSUSと
の間に熱膨張率の差がある。)とにより、スタンパ10
1と下金型102とが圧接状態で相対動して、両者間に
大きな摩擦力が発生する。これにより、スタンパ101
と下金型102との間に、金属成分の移動を伴う凝着磨
耗現象や擦り傷の付くアブレシブ磨耗現象が生じる。前
記凝着磨耗により、主として下金型102には数μmの
高さの凸部ができ、スタンパ101の記録面にこの凸部
が現れ、これが成形体に転写され、不良品となる。また
前記アブレシブ磨耗により、主としてスタンパ101の
形状劣化や金属粉の発生を招く。
In the above conventional example, when the resin is injected and filled into the molds 102 and 110 from the sprue 106, the flow pressure of the resin and the heat (thermal expansion between Ni and SUS) occur. And the stamper 10).
1 and the lower mold 102 move relative to each other in a press-contact state, and a large frictional force is generated between the two. Thereby, the stamper 101
An adhesive wear phenomenon accompanied by movement of a metal component and an abrasive wear phenomenon with abrasion occur between the metal mold and the lower mold 102. Due to the adhesion and abrasion, a convex part having a height of several μm is mainly formed on the lower mold 102, and this convex part appears on the recording surface of the stamper 101, and this convex part is transferred to a molded body, resulting in a defective product. In addition, the abrasive wear mainly causes deterioration of the shape of the stamper 101 and generation of metal powder.

【0004】上記のような理由で、成形体の品質が許容
範囲を越えて劣化した時点でスタンパ101の交換をす
る必要があるが、この交換作業には時間がかかり、しか
も従来例においてはこの交換作業を頻繁に行わなければ
ならないため、生産性の低下を招いている。
[0004] For the above reasons, it is necessary to replace the stamper 101 when the quality of the molded product has deteriorated beyond the allowable range. Since the replacement work must be performed frequently, productivity is reduced.

【0005】本発明は上記問題点に鑑み、樹脂注入時に
金型とスタンパとの間に前記磨耗現象が発生するのを防
ぎ、製品の品質向上および生産性向上を図ることができ
る光ディスクの成形方法及び成形装置を提供することを
目的とする。
SUMMARY OF THE INVENTION In view of the above problems, the present invention prevents an abrasion phenomenon between a mold and a stamper at the time of injecting a resin, and improves the quality and productivity of a product. And a molding apparatus.

【0006】[0006]

【課題を解決するための手段】本発明は上記目的を達成
するため、光ディスクの成形工程において、金型と、光
ディスク基板に凹凸を転写するために金型内の所定位置
に配置されたスタンパとの対向面間に、基板成形用樹脂
の融点より低融点の金属からなる金属層を介在させた成
形装置を用いることを特徴とする。
SUMMARY OF THE INVENTION In order to achieve the above object, the present invention provides a method for forming a mold in an optical disc, comprising: a mold and a stamper disposed at a predetermined position in the mold for transferring irregularities to an optical disc substrate; Characterized in that a molding apparatus having a metal layer made of a metal having a lower melting point than the melting point of the resin for substrate molding is interposed between the opposing surfaces.

【0007】前記低融点の金属は、基板成形用樹脂の金
型内注入時の温度に比較し100℃以下となる融点を有
するものであることが好適であり、またIn、InとB
iの合金、InとBiとSnの合金、PbとSnの合金
のいずれかであることが好適である。
It is preferable that the low melting point metal has a melting point of 100 ° C. or less as compared with the temperature at the time of injection of the resin for molding a substrate into a mold.
It is preferable to use any one of an alloy of i, an alloy of In, Bi, and Sn, and an alloy of Pb and Sn.

【0008】前記金属層の厚みは30〜150μmの範
囲であることが好適である。
The thickness of the metal layer is preferably in the range of 30 to 150 μm.

【0009】前記基板成形用樹脂は、ポリカーボネー
ト、アクリルのいずれかであることが好適である。
It is preferable that the resin for molding a substrate is one of polycarbonate and acrylic.

【0010】本発明によれば、樹脂注入時の樹脂の熱が
スタンパを介して金属層に伝わり、この金属層が固相か
ら固液相、液相に状態変化する。このため、樹脂の流動
圧や熱膨張差によるスタンパと金型との間に生ずる相対
移動が、両者間に介在する固液相、液相の金属層の働き
によって円滑になされ、凝着磨耗現象やアブレシブ磨耗
現象の発生を防ぐことができる。この結果、本発明によ
れば、製品の品質向上および生産性向上を図ることがで
きる光ディスクの成形方法および成形装置を提供するこ
とができる。
According to the present invention, the heat of the resin during resin injection is transmitted to the metal layer via the stamper, and the metal layer changes from a solid phase to a solid-liquid phase and a liquid phase. Therefore, the relative movement between the stamper and the mold due to the flow pressure of the resin and the difference in thermal expansion is made smooth by the action of the solid-liquid phase and the liquid phase metal layer interposed between them, and the adhesion and wear phenomenon occurs. And abrasive wear phenomena can be prevented. As a result, according to the present invention, it is possible to provide an optical disk molding method and an optical disk molding apparatus capable of improving product quality and productivity.

【0011】[0011]

【発明の実施の形態】図1、図2に示す本発明の実施の
形態は、基板成形用樹脂としてポリカーボネートを用
い、射出圧縮成形により光ディスクを成形する方法およ
び装置に係るものである。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The embodiment of the present invention shown in FIGS. 1 and 2 relates to a method and an apparatus for molding an optical disk by injection compression molding using polycarbonate as a resin for molding a substrate.

【0012】光ディスク基板に凹凸を転写するための凹
凸面を有するNi製のスタンパ1は、SUS製の上金型
10の下面にSUS製のスタンパホルダ5を用いて固定
されている。このスタンパ1の上面と上金型10の下面
との間には、図2に示すような中空円板状の金属層3が
介在されている。この金属層3は基板成形用樹脂(ポリ
カーボネート)7の融点より低融点の金属、具体的には
InとBiとの共晶合金からなり、常温時は固体状態で
ある。
A Ni stamper 1 having an irregular surface for transferring irregularities to an optical disk substrate is fixed to the lower surface of an SUS upper mold 10 using a SUS stamper holder 5. A hollow disk-shaped metal layer 3 as shown in FIG. 2 is interposed between the upper surface of the stamper 1 and the lower surface of the upper mold 10. The metal layer 3 is made of a metal having a melting point lower than the melting point of the substrate molding resin (polycarbonate) 7, specifically, a eutectic alloy of In and Bi, and is in a solid state at normal temperature.

【0013】上下動可能に配置されたSUS製の下金型
2と、前記スタンパ1と、上下金型10、2の外周に配
置されたSUS製の外周リング8との内空間に、光ディ
スク成型用のキャビティが形成され、このキャビティに
前記スタンパホルダ5の中心軸を貫通するようにして形
成されたノズル部6より、加熱溶融状態の基板成形用樹
脂7が圧力を加えられて注入充填される。
An optical disk is formed in the inner space of the lower SUS die 2 movably arranged, the stamper 1, and the SUS outer ring 8 arranged on the outer periphery of the upper and lower dies 10, 2. A cavity 7 is formed, and through a nozzle portion 6 formed so as to penetrate the center axis of the stamper holder 5, a resin 7 for molding a substrate in a heated and melted state is injected and filled by applying pressure. .

【0014】上下金型10、2は80〜120℃(1例
として100℃)に、基板成形用樹脂(ポリカーボネー
ト)7の溶融樹脂温度は370℃〜400℃(1例とし
て380℃)に、それぞれ設定されている。スタンパ1
は半径60mm、厚さ0.3mm、その凹凸面の高さは
0.12μm、ピッチは0.3μmである。金属層(I
n、Biの共晶合金)3は半径60mm、厚さ80μ
m、融点約80℃である。
The upper and lower molds 10 and 2 are at 80 to 120 ° C. (for example, 100 ° C.), the molten resin temperature of the substrate molding resin (polycarbonate) 7 is 370 to 400 ° C. (for example, 380 ° C.), Each is set. Stamper 1
Has a radius of 60 mm, a thickness of 0.3 mm, a height of the uneven surface of 0.12 μm, and a pitch of 0.3 μm. Metal layer (I
eutectic alloy of n and Bi) 3 has a radius of 60 mm and a thickness of 80 μm
m, melting point about 80 ° C.

【0015】射出圧縮成形により光ディスクを成形する
に際して、〜に示す工程が順次用いられる。
In molding an optical disk by injection compression molding, the following steps are sequentially used.

【0016】 型締め 射出 圧縮 保圧 冷却 型開き 取出し の工程(射出工程)において、樹脂注入時の樹脂7の
熱がスタンパ1を介して金属層3に伝わり、この金属層
3が固相から固液相(場合によっては液相)に状態変化
する。このため樹脂流動圧や熱膨張差によるスタンパ1
と上金型10との間に生ずる相対移動が、両者間に介在
する固液相の金属層3の働きによって円滑になされ、凝
着磨耗現象やアブレシブ磨耗現象が生ずるのを防ぐこと
ができる。また金属層3のクッション作用により、スタ
ンパ1に対する圧力が均等に分散される。なお、前記金
属層3はその表面に薄い酸化被膜が形成されており、熱
を受けることにより内部が固液相あるいは液相となっ
て、水を充填した風船のような状態となる。
In the process of mold clamping, injection, compression, holding pressure, cooling, mold opening, and removal (injection process), the heat of the resin 7 at the time of resin injection is transmitted to the metal layer 3 via the stamper 1, and the metal layer 3 is solidified from the solid phase. The state changes to a liquid phase (or a liquid phase in some cases). Therefore, the stamper 1 due to the resin flow pressure and the difference in thermal expansion
The relative movement occurring between the upper mold 10 and the upper mold 10 is smoothly performed by the function of the solid-liquid phase metal layer 3 interposed therebetween, thereby preventing the occurrence of adhesion wear phenomenon and abrasive wear phenomenon. The pressure on the stamper 1 is evenly distributed by the cushioning action of the metal layer 3. The metal layer 3 has a thin oxide film formed on its surface, and receives heat so that the inside becomes a solid-liquid phase or a liquid phase, and becomes a state like a balloon filled with water.

【0017】の工程(圧縮工程)では、下金型2が
0.6mm程度上昇してキャビティ内の樹脂7を圧縮す
るのであるが、このときには前記金属層3は概ね液相状
態となっており、スタンパ1に局部的に高圧力が作用す
ることを防止できる。
In the step (compression step), the lower mold 2 rises by about 0.6 mm to compress the resin 7 in the cavity. At this time, the metal layer 3 is in a substantially liquid state. In addition, local high pressure can be prevented from acting on the stamper 1.

【0018】の工程(保圧工程)で、金属層3は液相
から、固液相、固相に状態変化し、の工程(冷却工
程)で金属層3は完全に固相となる。同時に前記樹脂7
が冷却されて、光ディスクの成形が完了する。の工程
(型開き工程)、の工程(取出し工程)は、従来の周
知の方法を用いて行われ、成形品である光ディスクが取
出される。
In the step (pressure holding step), the metal layer 3 changes from a liquid phase to a solid-liquid phase and a solid phase, and in the step (cooling step), the metal layer 3 is completely turned into a solid phase. At the same time, the resin 7
Is cooled to complete the molding of the optical disk. The step (mold opening step) and the step (ejection step) are performed by using a conventionally known method, and an optical disc as a molded product is ejected.

【0019】前記金属層3の厚みは、30〜150μm
の範囲、望ましくは50〜100μmの範囲が好適であ
る。30μm未満であると、金属層3の磨耗現象防止作
用やクッション作用が不十分となる。他方、150μm
を越えると、金属層3の表面に形成される酸化被膜が、
圧力によって被れて不都合となる。
The thickness of the metal layer 3 is 30 to 150 μm.
, Preferably in the range of 50 to 100 μm. If it is less than 30 μm, the effect of preventing the metal layer 3 from being worn and the effect of cushioning become insufficient. On the other hand, 150 μm
Is exceeded, the oxide film formed on the surface of the metal layer 3 becomes
It is inconvenient to suffer from pressure.

【0020】また前記金属層3として、InとBiの合
金の他、InとBiとSnとの合金(共晶合金の場合、
融点89.9℃)、In(融点156.4℃)、Pbと
Snとの合金(共晶合金の場合、融点183℃)等を用
いることができる。この金属層3として、基板成形用樹
脂7の金型内注入時の温度に比較し100℃以下となる
融点を有する金属を用いると、射出工程時に速やかに固
相から固液相、液相に状態変化するので好適である。
The metal layer 3 may be made of an alloy of In, Bi, and Sn (in the case of a eutectic alloy,
Melting point 89.9 ° C.), In (melting point 156.4 ° C.), an alloy of Pb and Sn (melting point 183 ° C. in the case of a eutectic alloy), or the like can be used. When a metal having a melting point of 100 ° C. or less as compared to the temperature at the time of injecting the resin 7 for molding a substrate into the mold is used as the metal layer 3, the solid phase is rapidly changed from a solid phase to a solid-liquid phase and a liquid phase during the injection step. This is preferable because the state changes.

【0021】上記実施の形態においては、上金型10内
の所定位置にスタンパ1を配置しているが、本発明を図
3に示すような下金型内の所定位置にスタンパを配置し
たものに適用することができ、この場合には下金型とス
タンパとの対向面間に、基板成形用樹脂より低融点の金
属からなる金属層を介在させればよい。
In the above embodiment, the stamper 1 is arranged at a predetermined position in the upper mold 10, but the present invention is applied to a case where the stamper is arranged at a predetermined position in the lower mold as shown in FIG. In this case, a metal layer made of a metal having a lower melting point than the resin for substrate molding may be interposed between the opposing surfaces of the lower mold and the stamper.

【0022】[0022]

【発明の効果】本発明によれば、樹脂注入時に金型とス
タンパとの間に発生する磨耗現象を防ぎ、製品の品質向
上および生産性向上を図ることができる光ディスクの成
形方法および成形装置を提供することができる。
According to the present invention, there is provided a method and apparatus for molding an optical disk capable of preventing a wear phenomenon occurring between a mold and a stamper at the time of injecting a resin, thereby improving product quality and productivity. Can be provided.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施の形態を示す断面図。FIG. 1 is a cross-sectional view illustrating an embodiment of the present invention.

【図2】金属層を示す斜視図。FIG. 2 is a perspective view showing a metal layer.

【図3】従来例を示す断面図。FIG. 3 is a sectional view showing a conventional example.

【符号の説明】[Explanation of symbols]

1 スタンパ 2 下金型 3 金属層 7 基板成形用樹脂 10 上金型 Reference Signs List 1 stamper 2 lower mold 3 metal layer 7 resin for substrate molding 10 upper mold

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) B29L 17:00 B29L 17:00 (72)発明者 角陸 晋二 大阪府門真市大字門真1006番地 松下電器 産業株式会社内 (72)発明者 油谷 博 大阪府門真市大字門真1006番地 松下電器 産業株式会社内 Fターム(参考) 4F202 AA21 AA28 AG05 AH79 AJ02 AJ08 AM32 CA11 CB01 CD02 5D121 AA02 DD05 DD17 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) B29L 17:00 B29L 17:00 (72) Inventor Shinji Sakuriku 1006 Kazuma Kazuma, Kadoma City, Osaka Matsushita Electric Industrial Co., Ltd. (72) Inventor Hiroshi Aburaya 1006 Kadoma, Kadoma, Osaka Prefecture Matsushita Electric Industrial Co., Ltd.F-term (reference)

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 光ディスクの成形工程において、金型
と、光ディスク基板に凹凸を転写するために金型内の所
定位置に配置されたスタンパとの対向面間に、基板成形
用樹脂の融点より低融点の金属からなる金属層を介在さ
せた成形装置を用いることを特徴とする光ディスクの成
形方法。
In an optical disc molding process, a temperature lower than a melting point of a resin for molding a substrate is set between opposing surfaces of a mold and a stamper arranged at a predetermined position in the mold to transfer irregularities to an optical disc substrate. A method of molding an optical disk, characterized by using a molding device having a metal layer made of a metal having a melting point interposed.
【請求項2】 低融点の金属は、基板成形用樹脂の金型
内注入時の温度に比較し100℃以下となる融点を有す
るものである請求項1記載の光ディスクの成形方法。
2. The method of molding an optical disk according to claim 1, wherein the metal having a low melting point has a melting point of 100 ° C. or less as compared with a temperature at the time of injecting the resin for molding a substrate into a mold.
【請求項3】 低融点の金属は、下記のいずれかである
請求項1記載の光ディスクの成形方法。 In In,Biの合金 In,Bi,Snの合金 Pb,Snの合金
3. The method according to claim 1, wherein the metal having a low melting point is one of the following. In alloy of In, Bi Alloy of In, Bi, Sn Alloy of Pb, Sn
【請求項4】 金属層の厚みは30〜150μmの範囲
である請求項1〜3のいずれかに記載の光ディスクの成
形方法。
4. The method according to claim 1, wherein the thickness of the metal layer is in the range of 30 to 150 μm.
【請求項5】 基板成形用樹脂は下記のいずれかである
請求項1〜4のいずれかに記載の光ディスクの成形方
法。 ポリカーボネート アクリル
5. The method for molding an optical disk according to claim 1, wherein the resin for molding a substrate is any of the following. Polycarbonate acrylic
【請求項6】 金型と、 光ディスク基板に凹凸を転写するために金型内の所定位
置に配置されたスタンパと、 前記スタンパと金型との間に配設され、基板成形用樹脂
の融点より低融点の金属からなる金属層とを、 備えたことを特徴とする光ディスクの成形装置。
6. A mold, a stamper disposed at a predetermined position in the mold for transferring irregularities to the optical disk substrate, and a melting point of the resin for molding the substrate, which is disposed between the stamper and the mold. An optical disk molding device, comprising: a metal layer made of a metal having a lower melting point.
JP2000151947A 2000-05-23 2000-05-23 Molding method and molding device for optical disk Pending JP2001331983A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019166825A (en) * 2018-03-22 2019-10-03 本田技研工業株式会社 Reusable mold for injection molding and molding method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019166825A (en) * 2018-03-22 2019-10-03 本田技研工業株式会社 Reusable mold for injection molding and molding method
JP7263029B2 (en) 2018-03-22 2023-04-24 本田技研工業株式会社 Reusable mold and molding method for injection molding

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