JP2001316987A - Highly weather-resistant tent cloth and method for producing the same - Google Patents
Highly weather-resistant tent cloth and method for producing the sameInfo
- Publication number
- JP2001316987A JP2001316987A JP2000135275A JP2000135275A JP2001316987A JP 2001316987 A JP2001316987 A JP 2001316987A JP 2000135275 A JP2000135275 A JP 2000135275A JP 2000135275 A JP2000135275 A JP 2000135275A JP 2001316987 A JP2001316987 A JP 2001316987A
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- JP
- Japan
- Prior art keywords
- weight
- tent
- film
- agent
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
Landscapes
- Tents Or Canopies (AREA)
- Coloring (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、高耐候で耐光性があ
り、防汚性、撥水性、防炎性、遮光性及び柔軟性に優れ
たテント地に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a tent which has high weather resistance and light resistance, and is excellent in antifouling properties, water repellency, flame resistance, light shielding properties and flexibility.
【０００２】[0002]
【従来の技術】テント地の主たる第一の目的が、日除
け、雨よけであり、第二に屋外で使用するということ
で、存在感主張と宣伝もかねて目立つことが必要で、そ
の為には、そのテントがより鮮明色で濃度感がありそれ
が持続されることが必要になってくる。2. Description of the Related Art The main purpose of a tent site is to protect the sun and the rain, and secondly, it is used outdoors. It is necessary that the tent be more vivid and dense, and that the tent be maintained.
【０００３】また、用途としては、建築材（軒先テン
ト）や、レジャー用テント、運送車輌の幌材、屋外カバ
ー等であるため、要求性能として耐候性、耐光性、防汚
性、撥水性、防炎性、遮光性及び柔軟性等が求められて
おり、特に耐候性については、各用途を通じた必須条件
である。[0003] In addition, since it is used as a building material (eave tent), a leisure tent, a hood material for a transport vehicle, an outdoor cover, and the like, the required performance is weather resistance, light resistance, stain resistance, water repellency, and the like. Flameproofness, light-shielding properties, flexibility and the like are required, and in particular, weather resistance is an essential condition for each application.
【０００４】耐候性の要素の一つである耐光性について
見ると、染料による着色法では、サンシャイン法すなわ
ち耐候性を考慮した試験法であるＪＩＳＬ０８４２での
耐光は、２００時間が限界であり、実使用では６カ月で
褪色してしまい問題があった。その為、顔料とウレタン
樹脂やアクリル樹脂等に代表されるバインダーとを組み
合わせて着色することが試みられてきたが、テント地の
繊維素材によっては縫製時の接着性が悪かったり、テン
トとしての耐久性や柔軟性に問題があったため、使用用
途にも限界があり、一般的に普及はしなかった。Regarding the light resistance, which is one of the elements of the weather resistance, in the coloring method using a dye, the sunshine method, that is, JISL0842 which is a test method considering the weather resistance, has a limit of 200 hours. When used, there was a problem that the color faded in six months. For this reason, attempts have been made to combine pigments with binders typified by urethane resins and acrylic resins to color them.However, depending on the fiber material of the tent fabric, the adhesiveness during sewing is poor, or the durability of the tent is poor. Due to problems in its properties and flexibility, its use was limited, and it was not widely used.
【０００５】前述の顔料とバインダーとの組み合わせに
よる着色の問題点に対し、塩化ビニールやアクリルへの
顔料練り込みによる繊維基材が作られるようになった。
その結果、６００時間の耐光も満足する商品が出回るよ
うになった。[0005] In order to solve the problem of coloring by the combination of the pigment and the binder described above, a fiber base material has been produced by kneading the pigment into vinyl chloride or acrylic.
As a result, a product that also satisfies the light resistance for 600 hours has come to market.
【０００６】[0006]
【発明が解決しようとする課題】しかしながら、塩化ビ
ニールやアクリルへの顔料練り込みは、基材製造の面か
らフィルム様の冷たい表面感となり汎用性が狭かった。
更に、塩素化合物を含有する塩化ビニール素材は、焼却
の際に、有毒ガスの発生を伴うため環境的に問題があ
る。また、アクリル素材においては、防炎性が不十分で
あるという欠点がある。更にテントの目的が存在感と宣
伝もかねて目立つことが必要であるにも拘わらず、顔料
の特徴である鮮明さが時間の経過と共に失われていくと
いった欠点もあった。However, the incorporation of a pigment into vinyl chloride or acrylic has a film-like cold surface feeling from the viewpoint of the production of a base material, and has a narrow versatility.
Furthermore, a vinyl chloride material containing a chlorine compound is harmful to the environment due to the generation of toxic gas when incinerated. Further, the acrylic material has a disadvantage that the flame resistance is insufficient. Further, despite the fact that the purpose of the tent needs to be noticeable in the presence and promotion, there is also a disadvantage that the sharpness which is a characteristic of the pigment is lost over time.
【０００７】本発明は、かかる従来技術に鑑み、テント
地として必要な防水性や難燃性更に耐光を含めた耐候性
を維持しながら、地球に優しい素材を用いて、従来のテ
ント地に見られない柔軟性があり、かつ鮮明で表面の濃
度感があるテント地を提供しようとするものである。SUMMARY OF THE INVENTION In view of the above prior art, the present invention provides a conventional tent using a material which is friendly to the earth while maintaining the waterproofness, flame retardancy and weather resistance including light resistance required for the tent. It is an object of the present invention to provide a tent that is inflexible and has a sharp and dense surface.
【０００８】[0008]
【課題を解決するための手段】本発明は上記の課題を解
決すべく鋭意検討した結果、本発明に到達したものであ
りその構成は次の通りである。Means for Solving the Problems The present invention has been made as a result of intensive studies to solve the above-mentioned problems, and has reached the present invention. The structure thereof is as follows.
【０００９】即ち、本発明は、（１）ポリウレタン樹脂
１０〜５０重量％、難燃剤２〜２５重量％、架橋剤１〜
５重量％、更に表面濃度向上促進剤としての高分子系水
溶性樹脂１〜５重量％からなる皮膜形成剤及び顔料をパ
ッディング法により繊維基材に付与することを特徴とす
る高耐候テント地の製造方法に存する。That is, the present invention relates to (1) 10 to 50% by weight of a polyurethane resin, 2 to 25% by weight of a flame retardant,
5% by weight, and a film-forming agent and a pigment comprising 1 to 5% by weight of a high molecular weight water-soluble resin as a surface concentration improving accelerator are applied to a fiber base material by a padding method. In the manufacturing method.
【００１０】そしてまた、（２）皮膜形成剤が紫外線吸
収剤、柔軟剤、撥水剤、抗菌剤、防黴剤から選ばれる少
なくとも一種以上を含有してなる上記（１）記載の高耐
候テント地の製造方法に存する。Further, (2) the high weather resistant tent according to the above (1), wherein the film-forming agent contains at least one selected from an ultraviolet absorber, a softener, a water repellent, an antibacterial agent, and a fungicide. It depends on the method of manufacturing the land.
【００１１】そしてまた、（３）皮膜形成剤の処理温度
が１００〜２００℃で、処理時間が１０秒〜２０分であ
る上記（１）記載の高耐候テント地の製造方法に存す
る。Further, (3) the method for producing a highly weather-resistant tent according to the above (1), wherein the treatment temperature of the film-forming agent is 100 to 200 ° C. and the treatment time is 10 seconds to 20 minutes.
【００１２】そしてまた、（４）上記（１）から（３）
の方法によって製造された高耐候テント地に存する。(4) The above (1) to (3)
In a highly weathered tent site manufactured by the method of
【００１３】[0013]
【実施の形態】先ず本発明の目的であるが、テントとし
て要求される耐光性、防汚性、撥水性、防炎性、遮光性
等の機能を維持し、且つ、従来にない鮮明で濃度感があ
り、又従来にない柔軟性に富み、環境にも優しい高耐候
性テント地及びその製造方法を提供することにある。DESCRIPTION OF THE PREFERRED EMBODIMENTS First, the object of the present invention is to maintain functions such as light resistance, stain resistance, water repellency, flame resistance and light shielding required for a tent, and to achieve a clear and unprecedented density. An object of the present invention is to provide a highly weather-resistant tent that has a feeling and has unprecedented flexibility and is environmentally friendly, and a method of manufacturing the tent.
【００１４】次に高耐候テント地の主要構成と製造方法
について説明する。本発明に用いられる繊維性基材は木
綿、麻等の天然繊維、ガラス繊維等の無機繊維、ビスコ
ースレーヨン等の再生繊維、アセテート繊維等の半合成
繊維及びポリエステルやナイロン等の合成繊維から選ば
れた一種ないし二種類以上の組み合わせで出来た織編物
を適宜、用いることが出来る。Next, a description will be given of a main structure and a manufacturing method of the high weather tent ground. The fibrous base material used in the present invention is selected from natural fibers such as cotton and hemp, inorganic fibers such as glass fibers, regenerated fibers such as viscose rayon, semi-synthetic fibers such as acetate fibers, and synthetic fibers such as polyester and nylon. A woven or knitted fabric made of one or a combination of two or more kinds can be appropriately used.
【００１５】顔料については、市販の汎用カラーから蛍
光カラーの任意なものを使用することができる。As the pigment, any of commercially available general-purpose colors to fluorescent colors can be used.
【００１６】バインダーとして一般には、メラミン系樹
脂、エポキシ系樹脂、酢酸ビニル系樹脂、アクリル酸系
樹脂、ウレタン系樹脂等の単独ないしそれらの共重合物
が適宜用いられてきたが、本発明においては、ウレタン
系樹脂をベースにしたものが最も柔軟性に富む高耐候性
テント地が得られることを見いだした。また、柔軟性や
耐候性を損なわないウレタン系樹脂に対する架橋剤とし
てエポキシ系が好ましい。In general, a melamine resin, an epoxy resin, a vinyl acetate resin, an acrylic acid resin, a urethane resin or the like alone or a copolymer thereof has been appropriately used as a binder. It has been found that those based on urethane resins can provide the most flexible and highly weather-resistant tents. Further, an epoxy-based resin is preferable as a crosslinking agent for a urethane-based resin that does not impair flexibility and weather resistance.
【００１７】織編物の染料による染色品の表面濃度向上
に深色化剤として、非イオン活性剤やアニオン活性剤が
しばしば使用される。しかし、それらをそのまま顔料に
よる着色品に使用しても深色化の効果は得られない。本
発明において、高分子系水溶性樹脂の中から、顔料着色
物に深色効果のあるアクリル系水溶性樹脂を見いだし
た。深色化の仕組みとしては、バインダーや難燃剤が共
存する中で、凝集しやすい顔料を均一分散させ、その状
態で繊維性基材に固着されているためと考えられる。Nonionic and anionic activators are often used as a deepening agent to improve the surface concentration of dyed articles with dyes of woven or knitted fabric. However, even if they are used as they are for pigmented products, the effect of deep coloration cannot be obtained. In the present invention, an acrylic water-soluble resin having a deep color effect on a pigment coloring matter has been found from among the polymer-based water-soluble resins. It is considered that the mechanism of the deep coloration is that the pigment which easily aggregates is uniformly dispersed in the presence of the binder and the flame retardant, and is fixed to the fibrous base material in that state.
【００１８】難燃剤としては、酸化アンチモンに代表さ
れる金属酸化物や有機燐系化合物、有機硫黄系化合物、
有機窒素グアニジン系などがあり、これらの中から一種
ないしは二種以上の組み合わせで使用することが出来
る。尚、環境性を考慮してハロゲン系の難燃剤は使用し
ない方が好ましい。Examples of the flame retardant include metal oxides represented by antimony oxide, organic phosphorus compounds, organic sulfur compounds,
Organic nitrogen guanidines and the like can be used, and one or a combination of two or more of these can be used. Note that it is preferable not to use a halogen-based flame retardant in consideration of environmental properties.
【００１９】次に、本発明に於ける高耐候性テント地の
製造法について述べる。公知の方法で精練ないし精練漂
白された任意の繊維性基材に、顔料０．５〜２０重量
％、皮膜形成剤の組成としてポリウレタン１０〜５０重
量％、好ましくは１５〜３０重量％、難燃剤２〜２５重
量％、好ましくは１０〜２０重量％、架橋剤１〜５重量
％、更に表面濃度向上促進剤としての高分子系水溶性樹
脂１〜５重量％及び残りの部数が水もしくは水を含む溶
媒からなる着色剤含有皮膜形成剤を、パッディング法で
付与する。Next, a method of manufacturing a tent with high weather resistance according to the present invention will be described. 0.5 to 20% by weight of a pigment, 10 to 50% by weight, preferably 15 to 30% by weight of a polyurethane as a composition of a film forming agent, and a flame retardant in an arbitrary fibrous base material scoured or scoured and bleached by a known method. 2 to 25% by weight, preferably 10 to 20% by weight, 1 to 5% by weight of a crosslinking agent, 1 to 5% by weight of a high molecular water-soluble resin as a surface concentration improving accelerator, and water or water A colorant-containing film-forming agent comprising a solvent is applied by a padding method.
【００２０】付与法としては、パッディング法の他に、
グラビアロール法やコーティング法があるが、前者では
耐候性を得るための付与薬剤量としては不十分であり、
後者で耐候性を得るための付与薬剤量が得られたとして
も、繊維基材の片面での皮膜形成のため、柔軟性に乏し
いテント地しか得られない。これに対し、本発明のパッ
ディング法では、５００〜２，０００ｃｐｓの高粘度の
皮膜形成剤液を用いるにも拘わらず、繊維基材の両面よ
り、繊維基材の内部まで塗布出来、斑のない均一で柔軟
性に富むテント地を得ることができた。As the applying method, besides the padding method,
There are gravure roll method and coating method, but the former is not sufficient as the amount of applied agent to obtain weather resistance,
Even if the amount of the applied agent for obtaining the weather resistance is obtained by the latter, only a tent with poor flexibility can be obtained due to the formation of a film on one side of the fiber base material. On the other hand, in the padding method of the present invention, despite using a high-viscosity film-forming agent liquid of 500 to 2,000 cps, it is possible to apply from both sides of the fiber base material to the inside of the fiber base material, A uniform and flexible tent was obtained.
【００２１】パッディング後、１００〜１２０℃で乾燥
し、１２０〜２００℃で１０秒〜２０分間の乾熱ないし
湿熱処理により皮膜形成を完了させる。After the padding, the film is dried at 100 to 120 ° C., and the film formation is completed by dry heat or wet heat treatment at 120 to 200 ° C. for 10 seconds to 20 minutes.
【００２２】[0022]
【実施例】次に本発明を実施例、比較例により更に詳細
に説明するが、本発明は必ずしも以下の実施例に限定さ
れるものではない。表１に、本発明の１〜４の実施例及
び１〜５の比較例に於けるテント地の構成を示した。Next, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not necessarily limited to the following Examples. Table 1 shows the configuration of the tent ground in Examples 1 to 4 of the present invention and Comparative Examples 1 to 5.
【００２３】本発明に記載した諸特性の測定方法は次の
通りである。The method for measuring various characteristics described in the present invention is as follows.
【００２４】［耐候性］総合的な耐候性を見るために、
次の四つの方法を用いた。 ＪＩＳ Ｌ０８４１ （日光暴露法） ＪＩＳ Ｌ０８４２ （カーボンアーク灯光） ＪＩＳ Ｌ０８４２で耐候性を考慮した試験法（カー
ボンアーク灯光＋断続的水噴射） ＪＩＳ Ｌ０８４３ （キセノンアーク法） そして、その評価の結果を、次のように表した。 ２年間の暴露後の変色を変退色グレースケールで評価
し、３級以上を○、３級以下を×とした。 ブルースケール８級以上を○、７〜８級を△、７級以
下を×とした。 ６００時間照射後の変色を変退色グレースケールで評
価し、３級以上を○、３級以下を×とした。 ２５０Ｋｊ照射後の変色を変退色グレースケールで評
価し、３級以上を○、３級以下を×とした。[Weather Resistance] To see the overall weather resistance,
The following four methods were used. JIS L0841 (sunlight exposure method) JIS L0842 (carbon arc lamp light) Test method in consideration of weather resistance in JIS L0842 (carbon arc lamp light + intermittent water injection) JIS L0843 (xenon arc method) It was expressed as follows. Discoloration after exposure for two years was evaluated by a discoloration and fading gray scale. A blue scale of 8th grade or higher was rated as 〜, 7 to 8th grade was rated as Δ, and 7th grade or lower was rated as x. The discoloration after irradiation for 600 hours was evaluated by a discoloration and fading gray scale. The discoloration after irradiation at 250 Kj was evaluated by a discoloration and discoloration gray scale.
【００２５】［表面濃度］Ｇｒｅｔａｇ Ｍａｃｂｅｔ
ｈ社製の分光光度計ＣＥ−３１００で測色し、表面濃度
をＣＩＥ １９７６Ｌａｂの式、Ｅ＝（Ｌ２＋ａ２＋ｂ
２）１／２ で表し、その濃度Ｅが、比較例２を１００
とした場合、１５０以上を○、１５０〜１２０を△、１
２０以下を×とした。[Surface concentration] Gretag Macbet
Color is measured with a spectrophotometer CE-3100 manufactured by Company h, and the surface density is calculated by the equation of CIE 1976 Lab, E = (L 2 + a 2 + b).
2 ) expressed by 1/2 , and its concentration E was 100% in Comparative Example 2.
１５０, 150 or more, ○, 150 to 120,
20 or less was evaluated as x.
【００２６】［皮膜強度］学振型摩擦試験機を用い摩耗
部の顔料脱落度合いを変退色グレースケールで判定し乾
湿の両方において、４級以上を○、３級を△、２級以下
を×とした。[Film Strength] The degree of pigment detachment of the abraded part was determined by a gray scale using a Gakushin type friction tester. And
【００２７】［柔軟度］ＪＩＳ Ｌ−１０９６ Ａ法に
て柔軟性を比較した。評価法は、５０ｍｍ以下を○、５
０〜７５ｍｍを△、７５ｍｍ以上を×とした。[Flexibility] The flexibility was compared by JIS L-1096 A method. The evaluation method is as follows.
0 to 75 mm was rated as Δ, and 75 mm or more was rated as x.
【００２８】［難燃性］難燃性は次の二つの方法を用い
た。 ＪＩＳ Ｌ１０９１ Ａ−１法（ミクロバーナー法） Ｄ法（接炎試験） そして、その評価の結果は、次のように表した。 残炎時間、残塵時間、炭化面積を測定し基準に従って
合否を判定した。 接炎回数を測定し基準に従って合否を判定した。[Flame retardancy] Flame retardancy was measured by the following two methods. JIS L1091 A-1 method (micro burner method) D method (flame contact test) And the result of the evaluation was expressed as follows. The residual flame time, residual dust time, and carbonized area were measured, and pass / fail was determined according to the standard. The number of times of flame contact was measured and pass / fail was determined according to the standard.
【００２９】[0029]
【実施例１】ポリエステル２０番手の平織り物（タテ糸
密度５５本／ｉｎｃｈＸヨコ糸密度４９本／ｉｎｃｈ）
をアルカリと精練剤を含む液にて精練した後、１８０℃
にてプレセットを行いテント用布帛を得た。この基布
に、次の組成からなる皮膜形成成分をパッディング法に
て付与した。 Ｎｅｗ Ｌａｑｔｕｔｉｍｉｎｅ Ｎ．Ｂｌｕｅ ＦＬ２Ｒ ８重量％ Ｎｅｗ Ｌａｑｔｕｔｉｍｉｎｅ Ｂｌｕｅ ＦＬＧＢ １０重量％ Ｎｅｗ Ｌａｑｔｕｔｉｍｉｎｅ Ｒｅｄ Ｆ２Ｂ ２重量％ （以上、顔料 大日精化） Ｒｙｕｄｙｅ−Ｗ ＦｉｘｅｒＵ−２９ Ｃｏｎｃ ２５重量％ （ウレタンバインダー 大日本インキ） Ｐ２０１ １０重量％ （難燃剤 日華化学） オキザール ＮＦ１１Ｌ １重量％ （架橋剤 林化学） Ｒｙｕｄｙｅ−Ｗ Ａｓｓｉｓｔｅｒ ＨＰ ２重量％ （濃度向上促進剤 大日本インキ） Ｒｙｕｄｙｅ−Ｗ Ａｓｓｉｓｔｅｒ ＲＭ １重量％ （マイグレーション防止剤 大日本インキ） Ｃｉｂａｔｅｘ ＬＦＮ ２重量％ （耐光向上剤 チバガイギー） 水 ３９重量％ この時の付与量は、パッディング前の生地重量に対し５
５％であった。更に、予備乾燥後１５０℃で１分の熱処
理を行いテント地を得た。その評価結果を表２に示し
た。Example 1 Plain woven fabric of polyester 20th count (vertical yarn density 55 yarns / inch X weft yarn density 49 yarns / inch)
After scouring with a liquid containing an alkali and a scouring agent,
And a tent fabric was obtained. A film forming component having the following composition was applied to this base fabric by a padding method. New Laqtutmine N. 8% by weight of Blue FL2R, 10% by weight of New Laqutimine Blue FLGB, 2% by weight of New Laqtutimine Red F2B, and 2% by weight of pigment (Daiichi Seimitsu Pigment). Combustion agent Nikka Chemical) Oxal NF11L 1% by weight (Cross-linking agent Hayashi Chemical) Ryudie-W Assister HP 2% by weight (concentration improving accelerator Dai Nippon Ink) Ryudaye-W Assistant RM 1% by weight (Migration inhibitor Dai Nippon Ink) Cibatex LFN 2% by weight (lightfastening agent Ciba-Geigy) Water 39% by weight The amount applied at this time is 5% based on the weight of the cloth before padding.
5%. Further, after preliminary drying, heat treatment was performed at 150 ° C. for 1 minute to obtain a tent. Table 2 shows the evaluation results.
【００３０】[0030]
【実施例２】実施例１と同じポリエステルスパン糸の平
織り物をアルカリと精練剤を含む液にて精練した後、１
８０℃にてプレセットを行いテント用布帛を得た。この
基布に実施例１と同じ皮膜形成成分をパッド法にて付与
し（この時の付与量は、パッディング前の生地重量に対
し５５％であった。）、予備乾燥後１７５℃で１０分の
過熱蒸気によるスチーミング処理を行いテント地を得
た。その評価結果を表２に示した。Example 2 The same plain spun yarn of polyester spun yarn as in Example 1 was scoured with a liquid containing an alkali and a scouring agent.
Presetting was performed at 80 ° C. to obtain a tent fabric. The same film-forming component as in Example 1 was applied to this base fabric by the pad method (the applied amount at this time was 55% based on the weight of the fabric before padding). Steaming treatment with superheated steam for 10 minutes to obtain a tent. Table 2 shows the evaluation results.
【００３１】[0031]
【実施例３】実施例１，２と異なり、高密度織物である
１５０ｄのナイロンフィラメント糸の平織り物（タテ糸
密度１５６本／ｉｎｃｈＸヨコ糸密度８８本／ｉｎｃ
ｈ）をアルカリと精練剤を含む液にて精練した後、１８
０℃にてプレセットを行いテント用布帛を得た。この基
布に次の組成からなる皮膜形成成分をパッド法にて付与
し（この時の付与量は、パッディング前の生地重量に対
し６５％であった。）、予備乾燥後１５０℃にて熱処理
を行いテント地を得た。 Ｎｅｗ Ｌａｑｔｕｔｉｍｉｎｅ Ｎ．Ｂｌｕｅ ＦＬ２Ｒ ８重量％ Ｎｅｗ Ｌａｑｔｕｔｉｍｉｎｅ Ｂｌｕｅ ＦＬＧＢ １０重量％ Ｎｅｗ Ｌａｑｔｕｔｉｍｉｎｅ Ｒｅｄ Ｆ２Ｂ ２重量％ （以上、顔料 大日精化） Ｒｙｕｄｙｅ−Ｗ ＦｉｘｅｒＵ−２９ Ｃｏｎｃ １０重量％ （ウレタンバインダー 大日本インキ） Ｐ２０１ １０重量％ （難燃剤 日華化学） オキザール ＮＦ１１Ｌ ２重量％ （架橋剤 林化学） Ｒｙｕｄｙｅ−Ｗ Ａｓｓｉｓｔｅｒ ＨＰ １重量％ （濃度向上促進剤 大日本インキ） Ｒｙｕｄｙｅ−Ｗ Ａｓｓｉｓｔｅｒ ＲＭ １重量％ （マイグレーション防止剤 大日本インキ） Ｃｉｂａｔｅｘ ＬＦＮ ２重量％ （耐光向上剤 チバガイギー） 水 ５４重量％ その評価結果を表２に示した。Example 3 Unlike Examples 1 and 2, a plain weave of a 150d nylon filament yarn which is a high-density woven fabric (vertical yarn density 156 yarns / inch X weft yarn density 88 yarns / inc
h) is scoured with a liquid containing an alkali and a scouring agent,
Presetting was performed at 0 ° C. to obtain a tent fabric. A film-forming component having the following composition was applied to this base fabric by a pad method (the applied amount at this time was 65% based on the weight of the fabric before padding). Heat treatment was performed to obtain a tent. New Laqtutmine N. 8% by weight of Blue FL2R, 10% by weight of New Laqutimine Blue FLGB, 2% by weight of New Laqtutimine Red F2B, and 2% by weight of pigment (Daisei Fine Chemicals Co., Ltd.) Ryduee-W Fixer U-29, 10% by weight of Utantan Co., Ltd. Combustion agent Nikka Chemical) Oxal NF11L 2% by weight (Cross-linking agent Hayashi Chemical) Ryudie-W Assister HP 1% by weight (concentration improvement accelerator Dai Nippon Ink) Ryudaye-W Assistant RM 1% by weight (migration inhibitor Dai Nippon Ink) Cibatex LFN 2% by weight (Lightfastener Ciba-Geigy) Water 54% by weight The evaluation results are shown in Table 2.
【００３２】[0032]
【実施例４】ポリエステル１５０ｄ／綿２０番手の混紡
平織り物（綿混率１０％、タテ糸密度１４８本／ｉｎｃ
ｈＸヨコ糸密度８４本／ｉｎｃｈ）をアルカリと精練剤
を含む液にて精練した後、漂白を行い次いで１８０℃に
てプレセットを行いテント用布帛を得た。この基布に実
施例３と同じ皮膜形成成分をパッド法にて付与し（この
時の付与量は、パッディング前の生地重量に対し７０％
であった。）、予備乾燥後１５０℃にて熱処理を行いテ
ント地を得た。その評価結果を表２に示した。Example 4 Blended plain woven fabric of polyester 150d / cotton 20 (cotton blend ratio 10%, warp yarn density 148 / inc)
(hX weft yarn density: 84 yarns / inch) was scoured with a liquid containing an alkali and a scouring agent, then bleached, and then preset at 180 ° C. to obtain a tent fabric. The same film forming components as in Example 3 were applied to this base fabric by the pad method (the applied amount at this time was 70% of the weight of the cloth before padding).
Met. ), Heat treatment was performed at 150 ° C after preliminary drying to obtain a tent material. Table 2 shows the evaluation results.
【００３３】[0033]
【比較例１】実施例１と同じポリエステルスパン糸の平
織り物をアルカリと精練剤を含む液にて精練した後、１
８０℃にてプレセットを行いテント用布帛を得た。この
基布に次の組成から成る粘度２００００cpsの皮膜形成
成分をコーティング法にて付与した。この時の付与量
は、６０ｇ／m２であった。 Ｎｅｗ Ｌａｑｔｕｔｉｍｉｎｅ Ｎ．Ｂｌｕｅ ＦＬ２Ｒ ８重量％ Ｂｌｕｅ ＦＬＧＢ １０重量％ Ｒｅｄ Ｆ２Ｂ ２重量％ Ｒｙｕｄｙｅ−Ｗ ＦｉｘｅｒＵ−２９ Ｃｏｎｃ ２５重量％ Ｐ２０１ １０重量％ オキザール ＮＦ１１Ｌ １重量％ Ｒｙｕｄｙｅ−Ｗ Ａｓｓｉｓｔｅｒ ＨＰ １重量％ Ｒｙｕｄｙｅ−Ｗ Ａｓｓｉｓｔｅｒ ＲＭ １重量％ Ｃｉｂａｔｅｘ ＬＦＮ ２重量％ Ｒｙｕｄｙｅ−Ｗ Ａｓｓｉｓｔｅｒ Ｔ ３重量％ （増粘剤 大日本インキ） 水 ４７重量％ 予備乾燥後、１５０℃で１分の熱処理を行いテント地を
得た。その評価結果を表２に示した。Comparative Example 1 A plain woven material of the same polyester spun yarn as in Example 1 was scoured with a liquid containing an alkali and a scouring agent.
Presetting was performed at 80 ° C. to obtain a tent fabric. A film forming component having the following composition and a viscosity of 20,000 cps was applied to the base fabric by a coating method. The amount applied at this time was 60 g / m 2 . New Laqtutmine N. Blue FL2R 8% by weight Blue FLGB 10% by weight Red F2B 2% by weight Rydaye-W Fixer U-29 Conc 25% by weight P201 10% by weight Oxal NF11L 1% by weight Ryday-W Assistant R1% by weight Cibatex LFN 2% by weight Rydaye-W Assistant T 3% by weight (Thickener Dainippon Ink) Water 47% by weight After preliminary drying, heat treatment was performed at 150 ° C. for 1 minute to obtain a tent. Table 2 shows the evaluation results.
【００３４】[0034]
【比較例２】実施例１と同じポリエステルスパン糸の平
織り物をアルカリと精練剤を含む液にて精練した後、１
８０℃にてプレセットを行いテント用布帛を得た。この
基布に濃度向上促進剤が含まれていない他は、実施例１
と同じ皮膜形成剤をパッディング法にて付与し（この時
の付与量は、パッディング前の生地重量に対し６０％で
あった。）、予備乾燥後１５０℃で１分の熱処理を行い
テント地を得た。その評価結果を表２に示した。Comparative Example 2 A plain woven material of the same polyester spun yarn as in Example 1 was scoured with a liquid containing an alkali and a scouring agent.
Presetting was performed at 80 ° C. to obtain a tent fabric. Example 1 except that this base cloth did not contain a concentration improving accelerator.
The same film-forming agent as that described above was applied by a padding method (the applied amount at this time was 60% based on the weight of the cloth before padding). I got the land. Table 2 shows the evaluation results.
【００３５】[0035]
【比較例３】実施例１と同じポリエステルスパン糸の平
織り物をアルカリと精練剤を含む液にて精練した後、１
８０℃にてプレセットを行いテント用布帛を得た。この
基布に、次の組成からなる皮膜形成成分をトリオールに
て粘度を２００００ｃｐｓに調整し、コーティング法に
て付与した。 パラクランＡＭ２００ ４０重量％ （アクリルバインダー 根上工業 ） Ｄｉｃｔｏｎ Ｙｅｌｌｏｗ ３重量％ Ｒｅｄ ３重量％ Ｂｌｕｅ ５重量％ （以上、顔料 大日本インキ） 三酸化アンチモン ８重量％ （難燃剤 大和化学） チアヌビー３２６ １重量％ （耐光向上剤 チバガイギー） トリオール溶媒 ４０重量％ この時の付与量は、８０ｇ／m２であった。予備乾燥
後、１５０℃で１分の熱処理を行いテント地を得た。そ
の評価結果を表２に示した。Comparative Example 3 A plain woven material of the same polyester spun yarn as in Example 1 was scoured with a liquid containing an alkali and a scouring agent.
Presetting was performed at 80 ° C. to obtain a tent fabric. A film-forming component having the following composition was adjusted to a viscosity of 20,000 cps with triol and applied to the base fabric by a coating method. Paraclan AM200 40% by weight (acrylic binder Negami Kogyo) Dicton Yellow 3% by weight Red 3% by weight Blue 5% by weight (above, pigment Dainippon Ink) Antimony trioxide 8% by weight (flame retardant Daiwa Chemical Co., Ltd.) Chianubi 326 1% by weight ( Light fastness improver Ciba-Geigy) Triol solvent 40% by weight The amount applied at this time was 80 g / m 2 . After the preliminary drying, a heat treatment was performed at 150 ° C. for 1 minute to obtain a tent. Table 2 shows the evaluation results.
【００３６】[0036]
【比較例４】実施例１と同じポリエステルスパン糸の平
織り物をアルカリと精練剤を含む液にて精練した後、１
８０℃にてプレセットを行いテント用布帛を得た。この
基布に次の組成からなる皮膜形成成分をトリオールにて
粘度を２００００ｃｐｓに調整し、コーティング法にて
付与した。 ペーストレジン ４４重量％ （塩化ビニール樹脂 日本ゼオス） Ｄｉｃｔｏｎ Ｙｅｌｌｏｗ ２重量％ Ｒｅｄ ２重量％ Ｂｌｕｅ ３重量％ （以上、顔料 大日本インキ） 三酸化アンチモン ８重量％ （難燃剤 大和化学） チヌビー３２６ １重量％ （耐光向上剤 チバガイギー） トリオール溶媒 ４０重量％ この時の付与量は、８０ｇ／m２であった。予備乾燥
後、１５０℃で１分の熱処理を行いテント地を得た。そ
の評価結果を表２に示した。Comparative Example 4 A plain woven material of the same polyester spun yarn as in Example 1 was scoured with a liquid containing an alkali and a scouring agent.
Presetting was performed at 80 ° C. to obtain a tent fabric. A film-forming component having the following composition was adjusted to a viscosity of 20,000 cps with triol and applied to the base fabric by a coating method. Paste resin 44% by weight (vinyl chloride resin, Nippon Zeos) Diton Yellow 2% by weight Red 2% by weight Blue 3% by weight (above, pigment Dainippon Ink) Antimony trioxide 8% by weight (flame retardant Daiwa Chemical) Tinubi 326 1% by weight (Light fastness enhancer Ciba-Geigy) Triol solvent 40% by weight The amount applied at this time was 80 g / m 2 . After the preliminary drying, a heat treatment was performed at 150 ° C. for 1 minute to obtain a tent. Table 2 shows the evaluation results.
【００３７】[0037]
【比較例５】実施例と同じ、ポリエステルスパン糸の平
織り物をアルカリと精練剤を含む液にて精練した後、１
８０℃にてプレセットを行いテント用布帛を得た。この
基布をつぎに示す高耐光用染料と紫外線吸収剤を含む染
色浴にて浸染法にて着色した。 Ｄｉａｎｉｘ Ｙｅｌｌｏｗ ＫＭ １％ｏｗｆ Ｒｅｄ ＫＭ １％ｏｗｆ Ｂｌｕｅ ＫＭ １％ｏｗｆ （以上、染料 ＤｙＳｔａｒ） Ｃｉｂａｔｅｘ ＬＦＮ ２％ｏｗｆ （紫外線吸収剤 チバガイギー） 浴比： １：２０ 温度×時間： １３０℃×３０分 この後、脱水し、８０℃で３分間乾燥し、更に１５０℃
にて１分のセットを行いテント地を得た。その評価結果
を表２に示した。Comparative Example 5 The same plain woven polyester spun yarn as in the example was scoured with a liquid containing an alkali and a scouring agent.
Presetting was performed at 80 ° C. to obtain a tent fabric. This base fabric was colored by a dyeing method in a dyeing bath containing a dye for high light resistance and an ultraviolet absorber described below. Dianix Yellow KM 1% owf Red KM 1% owf Blue KM 1% owf (above, dye DyStar) Cibatex LFN 2% owf (ultraviolet absorber Ciba-Geigy) Bath ratio: 1:20 Temperature × time: 130 ° C. × 30 min. , Dehydrated, dried at 80 ° C for 3 minutes and then at 150 ° C
And set for 1 minute to obtain a tent ground. Table 2 shows the evaluation results.
【００３８】[0038]
【表１】 [Table 1]
【００３９】[0039]
【表２】 [Table 2]
【００４０】[0040]
【発明の効果】本発明による、種々のテント用素材は、
素材自身の意匠性や表面感、風合いを損なうことなく、
広い色相範囲をカバー出来、しかも従来にない柔軟性が
あり鮮明で濃度感があり、又、環境にも優しい高耐候性
を兼ね備えることが出来た。According to the present invention, various tent materials are
Without spoiling the design, surface feel and texture of the material itself,
It could cover a wide hue range, and had unprecedented flexibility, sharpness and density, and also had environmentally friendly high weather resistance.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｄ０６Ｍ 15/564 Ｄ０６Ｍ 15/564 Ｄ０６Ｐ 5/00 Ｄ０６Ｐ 5/00 Ａ Ｅ０４Ｈ 15/54 Ｅ０４Ｈ 15/54 // Ｄ０６Ｍ 11/47 Ｄ０６Ｍ 13/432 13/432 11/12 Ｆターム(参考） 2E141 AA00 AA08 AA09 EE03 EE04 4H057 AA01 AA02 BA15 CA21 CA26 CA27 CA31 CA36 CB09 CC02 DA01 DA34 FA16 FA17 GA07 HA01 HA02 HA13 JA10 JA11 JA14 JB02 JB03 4J002 CD002 CK021 DE126 ER026 FD136 FD142 GJ02 4L031 BA09 DA00 DA05 DA16 DA17 DA18 DA19 4L033 AC02 AC04 AC05 AC15 CA50 CA70 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) D06M 15/564 D06M 15/564 D06P 5/00 D06P 5/00 A E04H 15/54 E04H 15/54 // D06M 11/47 D06M 13/432 13/432 11/12 F term (reference) 2E141 AA00 AA08 AA09 EE03 EE04 4H057 AA01 AA02 BA15 CA21 CA26 CA27 CA31 CA36 CB09 CC02 DA01 DA34 FA16 FA17 GA07 HA01 HA02 HA13 JA10 J11 JA04 J002 CD002 CK021 DE126 ER026 FD136 FD142 GJ02 4L031 BA09 DA00 DA05 DA16 DA17 DA18 DA19 4L033 AC02 AC04 AC05 AC15 CA50 CA70
Claims (4)
燃剤２〜２５重量％、架橋剤１〜５重量％、更に表面濃
度向上促進剤としての高分子系水溶性樹脂１〜５重量％
からなる皮膜形成剤及び顔料をパッディング法により繊
維基材に付与することを特徴とする高耐候テント地の製
造方法。1. 10 to 50% by weight of a polyurethane resin, 2 to 25% by weight of a flame retardant, 1 to 5% by weight of a crosslinking agent, and 1 to 5% by weight of a high molecular weight water-soluble resin as a surface concentration improving accelerator.
A method for producing a highly weather-resistant tent, comprising applying a film forming agent and a pigment comprising a padding method to a fiber base material.
水剤から選ばれる少なくとも一種以上を含有してなる請
求項１に記載の高耐候テント地の製造方法。2. The method according to claim 1, wherein the film-forming agent contains at least one selected from an ultraviolet absorber, a softener, and a water repellent.
℃で、処理時間が１０秒〜２０分である請求項１に記載
の高耐候テント地の製造方法。3. The treatment temperature of the film forming agent is 100 to 200.
The method according to claim 1, wherein the treatment time is 10 seconds to 20 minutes at ℃.
造された高耐候テント地。4. A highly weatherable tent produced by the method of claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000135275A JP2001316987A (en) | 2000-05-09 | 2000-05-09 | Highly weather-resistant tent cloth and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000135275A JP2001316987A (en) | 2000-05-09 | 2000-05-09 | Highly weather-resistant tent cloth and method for producing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2001316987A true JP2001316987A (en) | 2001-11-16 |
Family
ID=18643383
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|---|---|---|---|
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013117687A (en) * | 2011-12-05 | 2013-06-13 | Seiren Co Ltd | Advertising medium and manufacturing method thereof |
| JP2017036611A (en) * | 2015-08-11 | 2017-02-16 | 鹿田久美子 | Lodge-type tent |
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|---|---|---|---|---|
| JPH0913276A (en) * | 1995-04-26 | 1997-01-14 | Teijin Ltd | Colored flame-retardant nonwoven fabric of polyester fiber |
| JPH111871A (en) * | 1997-06-06 | 1999-01-06 | Saputeii Kk | Production of banner, curtain, flag or the like having excellent flameproofing performance |
-
2000
- 2000-05-09 JP JP2000135275A patent/JP2001316987A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0913276A (en) * | 1995-04-26 | 1997-01-14 | Teijin Ltd | Colored flame-retardant nonwoven fabric of polyester fiber |
| JPH111871A (en) * | 1997-06-06 | 1999-01-06 | Saputeii Kk | Production of banner, curtain, flag or the like having excellent flameproofing performance |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013117687A (en) * | 2011-12-05 | 2013-06-13 | Seiren Co Ltd | Advertising medium and manufacturing method thereof |
| JP2017036611A (en) * | 2015-08-11 | 2017-02-16 | 鹿田久美子 | Lodge-type tent |
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