JP2001263850A - Absorption cooler - Google Patents

Absorption cooler

Info

Publication number
JP2001263850A
JP2001263850A JP2000074021A JP2000074021A JP2001263850A JP 2001263850 A JP2001263850 A JP 2001263850A JP 2000074021 A JP2000074021 A JP 2000074021A JP 2000074021 A JP2000074021 A JP 2000074021A JP 2001263850 A JP2001263850 A JP 2001263850A
Authority
JP
Japan
Prior art keywords
absorption
regenerator
heat exchanger
heat
condenser
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000074021A
Other languages
Japanese (ja)
Inventor
Takashi Sawada
敬 澤田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP2000074021A priority Critical patent/JP2001263850A/en
Publication of JP2001263850A publication Critical patent/JP2001263850A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/27Relating to heating, ventilation or air conditioning [HVAC] technologies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/62Absorption based systems

Landscapes

  • Sorption Type Refrigeration Machines (AREA)

Abstract

PROBLEM TO BE SOLVED: To realize a high performance absorption cooler having a simple structure and exhibiting excellent assembling performance in which a large capacity can be generated instantaneously. SOLUTION: Since an absorption cooler comprising a heating means 1 and an absorption heat exchanger 3 is further provided with an absorption regenerator 24 storing mixture solution of absorption liquid and refrigerant and a condenser 6, a large capacity can be generated through a simple structure by supplying refrigerant generated from the absorption regenerator 24 and stored in the condenser 6 instantaneously. Furthermore, an absorption cooler having reduced number of components and piping joints and exhibiting excellent assembling performance can be realized.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、空調機および冷蔵
庫等に搭載して用いられる吸収式冷却装置に関するもの
である。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an absorption cooling device mounted on an air conditioner, a refrigerator and the like.

【0002】[0002]

【従来の技術】従来この種の吸収式冷却装置は、図8に
示す構成となっている。すなわち、加熱手段1を有する
再生器2と、吸収熱交換器3を有する吸収器4と、凝縮
熱交換器5を有する凝縮器6と、蒸発器7と、再生器2
と凝縮器6とを接続する高温ガス配管8と、凝縮器6と
蒸発器7とを接続する液配管9と、蒸発器7と吸収器4
とを接続する低温ガス配管10と、吸収器4と再生器2
とを接続する再生管11と、再生器2と吸収器4を接続
する溶液管12と、液配管9に設けた第1絞り手段13
と、溶液管12に設けた第2絞り手段14と、再生管1
1に設けた溶液ポンプ15とを備え、吸収熱交換器3に
は放熱器16とファン17と循環ポンプ18よりなる放
熱手段19が接続され、凝縮熱交換器5には放熱器20
とファン21と循環ポンプ22よりなる放熱手段23が
接続された構成となっている。また再生器2の内部に
は、水等の吸収液とアンモニア等の冷媒の混合溶液が充
填されている。
2. Description of the Related Art Conventionally, this type of absorption cooling device has the structure shown in FIG. That is, a regenerator 2 having a heating means 1, an absorber 4 having an absorption heat exchanger 3, a condenser 6 having a condensation heat exchanger 5, an evaporator 7, and a regenerator 2.
High-temperature gas pipe 8 connecting the condenser 6 and the condenser 6, a liquid pipe 9 connecting the condenser 6 and the evaporator 7, the evaporator 7 and the absorber 4
Low-temperature gas pipe 10 for connecting the gas, the absorber 4 and the regenerator 2
, A solution pipe 12 connecting the regenerator 2 and the absorber 4, and a first throttle means 13 provided in the liquid pipe 9.
The second throttle means 14 provided in the solution pipe 12 and the regeneration pipe 1
1, a radiator 16, a fan 17, and a circulating pump 18 are connected to the absorption heat exchanger 3, and a radiator 20 is connected to the condensation heat exchanger 5.
And a heat radiating means 23 comprising a fan 21 and a circulation pump 22 are connected. The inside of the regenerator 2 is filled with a mixed solution of an absorbing liquid such as water and a refrigerant such as ammonia.

【0003】加熱手段1により再生器2を加熱すると、
冷媒が蒸発して凝縮器6に送り出され、凝縮熱交換器5
で放熱手段23を動作させることにより液化し、蒸発器
7で蒸発することにより冷却熱が得られる。加熱手段1
としては、電気ヒータや燃焼器等を用いることが出来
る。また、蒸発器7としては放熱フィンを設けたものや
送風ファンを備えた構成のものが知られている。この
時、再生器2で冷媒の濃度が低くなった混合溶液は溶液
管12から吸収器4に送られ低温ガス配管10から送ら
れる低温ガスを吸収して吸収器4内部に溜まるが、この
溶液は溶液ポンプ15によって再び再生器2へ戻され加
熱されるということにより吸収式のサイクルが成り立っ
ていた。
When the regenerator 2 is heated by the heating means 1,
The refrigerant evaporates and is sent out to the condenser 6, and the condensing heat exchanger 5
The liquid is liquefied by operating the heat radiating means 23, and is evaporated by the evaporator 7 to obtain cooling heat. Heating means 1
For example, an electric heater or a combustor can be used. Further, as the evaporator 7, those having a radiation fin and those having a blower fan are known. At this time, the mixed solution in which the concentration of the refrigerant has become low in the regenerator 2 is sent from the solution pipe 12 to the absorber 4 and absorbs the low-temperature gas sent from the low-temperature gas pipe 10, and accumulates inside the absorber 4. Was returned to the regenerator 2 by the solution pump 15 and heated, whereby an absorption cycle was established.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、従来の
吸収式冷却装置では、冷媒回路部品が多く回路構成が複
雑になり装置が大きくなるとともに配管も煩雑になると
いう課題を有していた。
However, the conventional absorption type cooling apparatus has a problem that the number of refrigerant circuit components is large, the circuit configuration is complicated, the apparatus is large, and the piping is complicated.

【0005】また、凝縮熱と吸収熱のそれぞれを放熱す
るための放熱手段が必要になり構成が複雑で装置も大き
くなるという課題を有していた。
Further, a heat radiating means for radiating each of the heat of condensation and the heat of absorption is required, so that there is a problem that the structure is complicated and the device becomes large.

【0006】さらに、凝縮熱と吸収熱を大量に外気等へ
放熱するためにエネルギーの効率も低く放熱のために冷
却ファンを高速で回転させるため騒音も大きいという課
題を有していた。
Furthermore, there is another problem that the efficiency of energy is low to radiate a large amount of condensation heat and absorption heat to the outside air or the like, and the noise is high because the cooling fan is rotated at high speed for heat radiation.

【0007】さらに、冷却能力を大きくするためには各
熱交換器を大きくする必要があるが特にガスを溶液に吸
収させるための吸収器が大きくなり装置全体も大きくな
ってしまうという課題を有していた。
Further, in order to increase the cooling capacity, it is necessary to increase the size of each heat exchanger. However, in particular, there is a problem that the absorber for absorbing gas into the solution becomes large and the whole apparatus becomes large. I was

【0008】さらに、アンモニアと水を充填して用いる
装置等では高温で溶液を加熱する再生器は高温高アルカ
リの環境となり加熱部の表面に腐食が発生するなどの課
題を有していた。
Further, in an apparatus or the like using ammonia and water filled therein, a regenerator for heating a solution at a high temperature has a high temperature and high alkali environment, and has a problem that corrosion occurs on the surface of a heating section.

【0009】さらに、吸収器および再生器とも接続管が
3本以上必要であるのと同時に再生器には加熱部も必要
であるので組立て構成が複雑になる等の課題を有してい
た。
Furthermore, both the absorber and the regenerator require three or more connection pipes, and at the same time, the regenerator also requires a heating unit, so that there is a problem that the assembling structure is complicated.

【0010】本発明は、上記従来の課題を解決するもの
で、再生器と吸収器とを一体に構成し、冷却装置の回路
構成を簡潔にするとともに装置の小型化および組立ての
容易化を図ることを目的とする。
SUMMARY OF THE INVENTION The present invention solves the above-mentioned conventional problems, in which a regenerator and an absorber are integrally formed, thereby simplifying the circuit configuration of the cooling device, and miniaturizing the device and facilitating assembly. The purpose is to:

【0011】[0011]

【課題を解決するための手段】上記課題を解決するため
に、本発明の吸収式冷却装置は、吸収再生器、凝縮器、
蒸発器のぞれぞれをを繋ぐ導管に流体制御手段を設けて
冷媒の循環を制御すると共に吸収再生器と凝縮器におけ
る放熱を制御することにより、簡単な構成で冷却熱を得
るものである。
In order to solve the above-mentioned problems, an absorption cooling device of the present invention comprises an absorption regenerator, a condenser,
By providing a fluid control means in a conduit connecting each of the evaporators to control the circulation of the refrigerant and to control the heat radiation in the absorption regenerator and the condenser, cooling heat is obtained with a simple configuration. .

【0012】[0012]

【発明の実施の形態】請求項1に記載の発明は、加熱手
段と吸収熱交換器を具備し吸収液と冷媒の混合溶液を貯
留する吸収再生器と、前記吸収熱交換器の吸収熱を放熱
する第1の放熱手段と、凝縮熱交換器を具備し液冷媒を
貯留する凝縮器と、前記凝縮熱交換器の凝縮熱を放熱す
る第2の放熱手段と、蒸発器と、前記吸収再生器と前記
凝縮器とを繋ぐ導管上に設けられた第1の流体制御手段
と、前記凝縮器と前記蒸発器とを繋ぐ導管上に設けられ
た第2の流体制御手段と、前記蒸発器と前記吸収再生器
とを繋ぐ導管上に設けられた第3の流体制御手段を備え
たことにより、冷媒の再生と吸収を行う為の構成部品を
一体化し、構成を簡単にし装置を小型化するものとな
る。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The invention according to claim 1 is an absorption regenerator having a heating means and an absorption heat exchanger for storing a mixed solution of an absorbing liquid and a refrigerant, and an absorption regenerator for the absorption heat exchanger. A first heat radiating means for radiating heat, a condenser having a condensation heat exchanger and storing a liquid refrigerant, a second heat radiating means for radiating heat of condensation of the condensation heat exchanger, an evaporator, and the absorption regeneration A first fluid control means provided on a conduit connecting a condenser and the condenser, a second fluid control means provided on a conduit connecting the condenser and the evaporator, and the evaporator. By providing a third fluid control means provided on a conduit connecting to the absorption regenerator, components for regenerating and absorbing the refrigerant are integrated, thereby simplifying the configuration and miniaturizing the apparatus. Becomes

【0013】請求項2に記載の発明は、加熱手段と吸収
熱交換器を具備し吸収液と冷媒の混合溶液を貯留する吸
収再生器と、凝縮熱交換器を具備し液冷媒を貯留する凝
縮器と、前記吸収熱交換器の吸収熱および前記凝縮熱交
換器の凝縮熱を放熱する第3の放熱手段と、前記吸収熱
交換器と前記凝縮熱交換器の一方を前記第3の放熱手段
に連通させる流路制御手段と、蒸発器と、前記吸収再生
器と前記凝縮器とを繋ぐ導管上に設けられた第1の流体
制御手段と、前記凝縮器と前記蒸発器とを繋ぐ導管上に
設けられた第2の流体制御手段と、前記蒸発器と前記吸
収再生器とを繋ぐ導管上に設けられた第3の流体制御手
段を備えたことにより、吸収熱交換器の放熱と凝集熱交
換器の放熱を一つの放熱手段により行い、放熱手段の数
を減らして構成を簡単にすると共に装置を小型化するも
のとなる。
According to a second aspect of the present invention, there is provided an absorption regenerator having a heating means and an absorption heat exchanger for storing a mixed solution of an absorbing liquid and a refrigerant, and a condensing apparatus having a condensation heat exchanger and storing a liquid refrigerant. A third heat radiating means for radiating the heat of absorption of the absorption heat exchanger and the heat of condensation of the condensation heat exchanger; and a third heat radiating means for disposing one of the absorption heat exchanger and the condensation heat exchanger. A first fluid control means provided on a conduit connecting the absorption regenerator and the condenser; and a conduit connecting the condenser and the evaporator. And a third fluid control means provided on a conduit connecting the evaporator and the absorption regenerator, so that heat release and coagulation heat of the absorption heat exchanger are provided. The heat is radiated from the exchanger by one heat radiating means, and the number of heat radiating means is reduced. It becomes to reduce the size of the device with simply.

【0014】請求項3に記載の発明は、特に、請求項2
に記載の第3の放熱手段を、第3の放熱手段は、貯水槽
と、前記貯水槽の液体を汲み上げる揚水ポンプとから構
成することにより、ファンを回転させることなく放熱を
行い、装置の騒音を逓減するものとなる。
[0014] The invention described in claim 3 is particularly advantageous in claim 2.
The third heat dissipating means described in 1 above, the third heat dissipating means comprises a water storage tank and a water pump for pumping up the liquid in the water storage tank, so that heat is released without rotating the fan, and the noise of the apparatus is reduced. Is gradually reduced.

【0015】請求項4に記載の発明は、特に、第1の流
体制御手段と第3の流体制御手段の少なくとも一方は逆
止弁とすることにより、流体制御手段による制御を簡単
にするものとなる。
The invention described in claim 4 is to simplify the control by the fluid control means by providing at least one of the first fluid control means and the third fluid control means with a check valve. Become.

【0016】請求項5に記載の発明は、特に、蒸発器と
吸収再生器とを繋ぐ導管と前記吸収再生器との接続部に
おいて、前記導管は前記吸収再生器に貯留した混合溶液
と連通する構成とすることにより、蒸発器からの冷媒ガ
スを直接混合溶液に送り込こんで吸収効率を高め、冷却
能力を高める共に吸収再生器を小型化するものとなる。
According to a fifth aspect of the present invention, in particular, at a connection portion between the absorption regenerator and a conduit connecting the evaporator and the absorption regenerator, the conduit communicates with the mixed solution stored in the absorption regenerator. With this configuration, the refrigerant gas from the evaporator is directly fed into the mixed solution to increase the absorption efficiency, increase the cooling capacity, and reduce the size of the absorption regenerator.

【0017】請求項6に記載の発明は、特に、吸収再生
器の内部に吸収促進材を充填した構成とすることによ
り、冷媒ガスの吸収時は吸収液と冷媒ガスとの接触が促
進され吸収性能が向上すると共に、再生時には吸収促進
剤が伝熱フィンの役割を果たし加熱能力が向上すること
となり、同一構成で吸収と再生の性能を同時に向上させ
ることが可能となり、冷却能力を高める共に吸収再生器
を小型化するものとなる。
According to a sixth aspect of the present invention, the absorption regenerator is filled with an absorption-promoting material, so that when the refrigerant gas is absorbed, the contact between the absorbing liquid and the refrigerant gas is promoted and the absorption is promoted. In addition to improved performance, the absorption promoter plays the role of a heat transfer fin during regeneration, increasing the heating capacity, enabling the absorption and regeneration performance to be improved simultaneously with the same configuration, increasing the cooling capacity and absorbing The size of the regenerator is reduced.

【0018】請求項7に記載の発明は、特に、吸収再生
器の内部の少なくとも加熱部表面に耐食性皮膜を形成し
て構成することにより、加熱部の表面に腐食が発生する
ことを防止し、再生時に高温で加熱することが可能とな
り高効率で信頼性を向上させるものとなる。
[0018] The invention according to claim 7 is to prevent corrosion from occurring on the surface of the heating section by forming a corrosion-resistant coating on at least the surface of the heating section inside the absorption regenerator, Heating can be performed at a high temperature at the time of regeneration, and the reliability is improved with high efficiency.

【0019】請求項8に記載の発明は、特に、加熱手段
を吸収再生器の底部に配置するとともに蒸発器と前記吸
収再生器とを繋ぐ導管を前記吸収再生器上部より配管し
底部で開放して構成することにより再生時は底部から加
熱されることにより内部で対流が生じ加熱が促進される
とともに、吸収時は底部の配管端部から冷媒が泡状のガ
スとして出て来るため吸収再生器内部の混合溶液が攪拌
されることにより吸収性能が向上し、吸収性能と再生性
能の両性能を同時に向上させることができるものであ
る。
In the invention according to claim 8, the heating means is arranged at the bottom of the absorption regenerator, and a conduit connecting the evaporator and the absorption regenerator is piped from the top of the absorption regenerator and opened at the bottom. During regeneration, convection is generated inside by heating from the bottom during regeneration, and heating is promoted.At the time of absorption, the refrigerant comes out from the bottom end of the pipe as a foamy gas. By stirring the mixed solution inside, the absorption performance is improved, and both the absorption performance and the regeneration performance can be simultaneously improved.

【0020】[0020]

【実施例】以下、本発明の実施例について、図1〜7を
参照しながら説明する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to FIGS.

【0021】(実施例1)図1は本発明の第1の実施例
における吸収式冷却装置の構成図である。図1におい
て、吸収再生器24は加熱手段1と吸収熱交換器3とを
具備している。加熱手段1は、電気ヒータまたは燃焼器
などにより実現できる。凝縮器6は、凝縮熱交換器5を
具備している。吸収再生器24と凝縮器6とは導管25
で配管接続されている。蒸発器7は凝縮器6と導管26
で接続されるとともに吸収再生器24と導管27で接続
されている。導管25には第1の流体制御手段である開
閉弁28が設けられている。導管26には第2の流体制
御手段である開閉弁29が設けられている。必要に応じ
て、キャピラリーチューブ30を設け絞り機能を付加し
てもよいが、開閉弁29に一体構成としてもよい。勿
論、絞り機能の実現手段はキャピラリーチューブに限定
されるものではない。導管27には第3の流体制御手段
である開閉弁31が設けられている。吸収熱交換器3に
は放熱器16とファン17と循環ポンプ18とからなる
放熱手段19が接続されている。凝縮熱交換器5には放
熱器20とファン21と循環ポンプ22とからなる放熱
手段23が接続されている。吸収再生器24には吸収液
である水と冷媒であるアンモニアの混合溶液が貯留され
ている。放熱手段19と放熱手段23内には水などの液
体を充填されている。
(Embodiment 1) FIG. 1 is a configuration diagram of an absorption cooling apparatus according to a first embodiment of the present invention. In FIG. 1, the absorption regenerator 24 includes a heating means 1 and an absorption heat exchanger 3. The heating means 1 can be realized by an electric heater or a combustor. The condenser 6 includes the condensing heat exchanger 5. The absorption regenerator 24 and the condenser 6 are connected to a conduit 25.
Is connected by piping. The evaporator 7 includes the condenser 6 and the conduit 26
And connected by an absorption regenerator 24 and a conduit 27. The conduit 25 is provided with an on-off valve 28 as first fluid control means. The conduit 26 is provided with an on-off valve 29 as a second fluid control means. If necessary, a capillary tube 30 may be provided to add a throttling function, but may be integrated with the on-off valve 29. Of course, the means for realizing the aperture function is not limited to the capillary tube. The conduit 27 is provided with an on-off valve 31 as third fluid control means. To the absorption heat exchanger 3, a radiator 19 composed of a radiator 16, a fan 17, and a circulation pump 18 is connected. The condenser heat exchanger 5 is connected to a radiator 23 composed of a radiator 20, a fan 21, and a circulation pump 22. The absorption regenerator 24 stores a mixed solution of water as an absorption liquid and ammonia as a refrigerant. The heat radiating means 19 and the heat radiating means 23 are filled with a liquid such as water.

【0022】以下、本実施例の動作について説明する。
始めに開閉弁29と開閉弁31を閉じ、開閉弁28を開
いた状態で加熱手段1により吸収再生器24内の吸収液
と冷媒の混合溶液を加熱すると、冷媒が蒸発して導管2
5を通って凝縮器6に入る。この時、循環ポンプ22を
運転して放熱手段23を動作させることにより、凝縮器
6内の高温の冷媒ガスは凝縮熱交換器5によって冷却さ
れるため、液化し凝縮器6の内部に溜まる。次に加熱手
段1の加熱を停止した状態で循環ポンプ22を停止し、
循環ポンプ18を運転して放熱手段19を動作させる
と、吸収再生器22内の冷媒の濃度が薄まった混合溶液
は温度が低くなりため圧力が低くなる。次に、開閉弁2
8を閉じて開閉弁29と開閉弁31を開放すると、凝縮
器6内の冷媒はキャピラリーチューブ30で減圧されて
蒸発器7に入り蒸発することにより蒸発器7で冷熱を得
ることができる。この冷熱をもちいて冷房、冷蔵および
除湿などの機能を得ることができる。さらに蒸発器7で
蒸発した冷媒のガスは導管27を通って吸収再生器22
に入り吸収液と接触し吸収される。この時発生した吸収
熱は吸収熱交換機3によって吸熱し放熱手段19によっ
て外部に放熱される。必要な冷却が終了するかまたは凝
縮器6内の冷媒が無くなると最初の運転にもどり凝縮器
6に冷媒を溜める運転を行う。
Hereinafter, the operation of this embodiment will be described.
First, when the mixed solution of the absorbing liquid and the refrigerant in the absorption regenerator 24 is heated by the heating means 1 with the on-off valve 29 and the on-off valve 31 closed and the on-off valve 28 opened, the refrigerant evaporates and the conduit 2
5 enters the condenser 6. At this time, by operating the circulating pump 22 to operate the heat radiating means 23, the high-temperature refrigerant gas in the condenser 6 is cooled by the condensation heat exchanger 5, and is liquefied and accumulated inside the condenser 6. Next, the circulation pump 22 is stopped with the heating of the heating means 1 stopped,
When the circulating pump 18 is operated to operate the heat radiating means 19, the pressure of the mixed solution in which the concentration of the refrigerant in the absorption regenerator 22 is reduced becomes low because the temperature becomes low. Next, on-off valve 2
When the valve 8 is closed and the on-off valves 29 and 31 are opened, the refrigerant in the condenser 6 is depressurized by the capillary tube 30 and enters the evaporator 7 to evaporate, whereby cold heat can be obtained in the evaporator 7. Using this cold heat, functions such as cooling, refrigeration, and dehumidification can be obtained. Further, the refrigerant gas evaporated in the evaporator 7 passes through the conduit 27 and passes through the absorption regenerator 22.
Enters and is absorbed by the absorbent. The absorption heat generated at this time is absorbed by the absorption heat exchanger 3 and is radiated to the outside by the radiation means 19. When the necessary cooling is completed or the refrigerant in the condenser 6 runs out, the operation returns to the first operation and the operation for storing the refrigerant in the condenser 6 is performed.

【0023】以上のように、本実施例においては吸収再
生器24は冷媒の吸収と再生を一体で行うことができる
ため全体の構成が簡素化され、装置の小型化に寄与する
ものである。
As described above, in the present embodiment, since the absorption regenerator 24 can integrally absorb and regenerate the refrigerant, the overall configuration is simplified, which contributes to downsizing of the apparatus.

【0024】(実施例2)図2は本発明の第2の実施例
における吸収式冷却装置の構成図である。図2におい
て、吸収熱交換器3と凝縮熱交換器5のそれぞれの一端
は放熱器32とファン33と循環ポンプ34からなる第
3の放熱手段35とを接続する配管の先に吸収熱交換器
3と接続し、他端は流路制御手段である三方弁36を介
して第3の放熱手段35と接続している。再生運転時に
は三方弁36を凝縮熱交換器5と連通するように切りか
えるとともに循環ポンプ34を運転して第3の放熱手段
35を動作させると、第3の放熱手段35内部の水は凝
縮熱交換器5に流れ放熱器32で放熱して再び凝縮熱交
換器5に流れ込む。一方、吸収運転時は三方弁36を吸
収熱交換器3の側に連通させるように切りかえると、内
部の水は吸収熱交換器3に流れ受熱した後放熱器32で
放熱して再び吸収熱交換器3に戻ってくる。三方弁36
を再生運転時と吸収運転時で切りかえることにより、第
3の放熱手段35だけで吸収熱と凝縮熱を放熱すること
ができる。従って、放熱手段の数を減らすことができ、
構成を簡素化し装置の小型化を図ることが出来る。
(Embodiment 2) FIG. 2 is a configuration diagram of an absorption cooling device in a second embodiment of the present invention. In FIG. 2, one end of each of the absorption heat exchanger 3 and the condensation heat exchanger 5 is connected to the end of a pipe connecting the radiator 32, the fan 33, and the third radiating means 35 including the circulating pump 34. 3 and the other end is connected to a third heat radiation means 35 via a three-way valve 36 which is a flow path control means. At the time of the regeneration operation, the three-way valve 36 is switched to communicate with the condensing heat exchanger 5, and the circulating pump 34 is operated to operate the third radiating means 35. The heat flows into the heat exchanger 5 and is radiated by the radiator 32 to flow again into the condensation heat exchanger 5. On the other hand, in the absorption operation, if the three-way valve 36 is switched so as to communicate with the absorption heat exchanger 3 side, the water inside flows into the absorption heat exchanger 3 and receives heat, then radiates heat in the radiator 32 and absorbs heat again. Return to vessel 3. Three-way valve 36
Is switched between the regeneration operation and the absorption operation, so that only the third heat radiating means 35 can radiate the heat of absorption and the heat of condensation. Therefore, the number of heat radiating means can be reduced,
The configuration can be simplified and the size of the device can be reduced.

【0025】なお、必要に応じて逆止弁37と逆止弁3
8を吸収熱交換器3と凝縮熱交換器5のそれぞれが第3
の放熱手段35に接続する導管上に設けてもよい。これ
により、再生運転時には逆止弁37により吸収熱交換器
3に水が流れ込むのが防止され、吸収運転時には逆止弁
38により凝縮熱交換器5に水が流れ込むのが防止され
る。
If necessary, the check valve 37 and the check valve 3
8, the absorption heat exchanger 3 and the condensation heat exchanger 5
May be provided on a conduit connected to the heat radiating means 35. Thus, during the regeneration operation, the check valve 37 prevents water from flowing into the absorption heat exchanger 3, and during the absorption operation, the check valve 38 prevents water from flowing into the condensation heat exchanger 5.

【0026】また、本実施例では流路制御手段として三
方弁36を用いたが、これは本発明を限定するものでな
いことは明らかである。例えば、吸収熱交換器3と凝縮
熱交換器5に通じる導管に開閉弁(図示せず)を設けるこ
とによっても流路の切替は実現できる。
In this embodiment, the three-way valve 36 is used as the flow path control means. However, it is clear that this does not limit the present invention. For example, the flow path can be switched by providing an on-off valve (not shown) in a conduit communicating with the absorption heat exchanger 3 and the condensation heat exchanger 5.

【0027】(実施例3)図3は本発明の第3の実施例
における吸収式冷却装置の構成図である。図3におい
て、第3の放熱手段35は貯水槽39と揚水ポンプ40
より構成されている。そして揚水ポンプ40は貯水槽3
9の水を汲み上げ吸収熱交換器3と凝縮熱交換器5のい
ずれか一方に連通するように構成された三方弁36に接
続されている。吸収熱交換器3と凝縮熱交換器5の三方
弁36に接続していない端部は、貯水槽39の上部で開
放されるように配管接続されている。
(Embodiment 3) FIG. 3 is a block diagram of an absorption type cooling apparatus according to a third embodiment of the present invention. In FIG. 3, the third heat radiating means 35 includes a water tank 39 and a pump 40.
It is composed of And the pump 40 is the water tank 3
9 is connected to a three-way valve 36 configured to pump up water and communicate with one of the absorption heat exchanger 3 and the condensation heat exchanger 5. The ends of the absorption heat exchanger 3 and the condensation heat exchanger 5 that are not connected to the three-way valve 36 are connected by piping so as to be opened at the upper part of the water storage tank 39.

【0028】上記構成において、再生運転時には三方弁
36を凝縮熱交換器5側に切り替えて揚水ポンプ40を
運転すると、貯水槽39内の水は揚水ポンプ40によっ
てくみ上げられ凝縮熱交換器5で凝縮熱を受熱した後、
貯水槽39に流れ込む。一方、吸収運転時は、三方弁3
6を吸収熱交換器3の側に連通させるように切り替える
と、貯水槽39内の水は揚水ポンプ40によってくみ上
げられ吸収熱交換器3で吸収熱を受熱した後、貯水槽3
9に流れ込む。再生運転と吸収運転に応じて三方弁36
を切り替えることにより凝縮熱と吸収熱を貯水槽39内
に回収し貯えることが出来る。
In the above configuration, when the three-way valve 36 is switched to the condensing heat exchanger 5 and the pump 40 is operated during the regeneration operation, the water in the water storage tank 39 is pumped up by the pump 40 and condensed by the condensing heat exchanger 5. After receiving the heat,
It flows into the water storage tank 39. On the other hand, during absorption operation, the three-way valve 3
6 is switched to communicate with the absorption heat exchanger 3, the water in the water storage tank 39 is pumped up by the pump 40 and receives the absorption heat in the absorption heat exchanger 3.
Flow into 9. Three-way valve 36 according to regeneration operation and absorption operation
, The heat of condensation and the heat of absorption can be collected and stored in the water tank 39.

【0029】本実施例によれば、ファンを回転させるこ
となく放熱を行い、装置の騒音を逓減する事が出来る。
さらに、貯水槽39に貯えられた水を給湯に利用しても
よい。
According to this embodiment, heat can be dissipated without rotating the fan, and the noise of the apparatus can be reduced gradually.
Further, the water stored in the water storage tank 39 may be used for hot water supply.

【0030】(実施例4)図4は本発明の第4の実施例
における吸収式冷却装置の構成図である。図4におい
て、導管25上に逆止弁41を設けるとともに、導管2
7上に逆止弁42とを設けたものである。実施例1と
は、開閉弁28が逆止弁41に、また開閉弁29が逆止
弁42に置き換わった点で異なる。
(Embodiment 4) FIG. 4 is a configuration diagram of an absorption cooling device according to a fourth embodiment of the present invention. In FIG. 4, a check valve 41 is provided on a conduit 25 and
7 is provided with a check valve 42. Embodiment 2 is different from Embodiment 1 in that the on-off valve 28 is replaced by a check valve 41 and the on-off valve 29 is replaced by a check valve 42.

【0031】上記構成において、再生時は吸収再生器2
4内の圧力は凝縮器6および蒸発器7内の圧力より高く
なるので、開閉弁29を閉じると冷媒ガスは導管25の
逆止弁41を通って凝縮器6に流れ、一方では導管27
に逆止弁42が設けられているため蒸発器7への流入が
妨げられる。また、吸収時には吸収再生器24内の圧力
が最も低くなるため開閉弁29を開くと凝縮器6内の冷
媒は蒸発器7に入って蒸発したあと吸収再生器24内に
流れ込む、この時、逆止弁41は凝縮器6内の冷媒が導
管25を通過して吸収再生器24内に流れ込むのを防ぐ
役割を果たすこととなる。
In the above configuration, at the time of reproduction, the absorption regenerator 2
Since the pressure in condenser 4 is higher than the pressure in condenser 6 and evaporator 7, when on-off valve 29 is closed, the refrigerant gas flows to condenser 6 through check valve 41 of conduit 25, while conduit 27
Is provided with a check valve 42 so that the flow into the evaporator 7 is prevented. When the on-off valve 29 is opened, the refrigerant in the condenser 6 enters the evaporator 7, evaporates and flows into the absorption regenerator 24 when the on-off valve 29 is opened. The stop valve 41 serves to prevent the refrigerant in the condenser 6 from flowing through the conduit 25 and into the absorption regenerator 24.

【0032】以上のように、本実施例によれば開閉弁を
用いる場合と比較して流体制御を簡単にすることが出来
る。なお、本実施例では二つの逆止弁を用いたがどちら
か一方のみ逆止弁としてもよいことは言うまでもない。
As described above, according to the present embodiment, the fluid control can be simplified as compared with the case where the on-off valve is used. In this embodiment, two check valves are used, but it goes without saying that only one of the check valves may be used.

【0033】(実施例5)図1の導管27と吸収再生器
24との接続部43において、導管27は吸収再生器2
4に貯留した吸収液と連通している。蒸発器7で蒸発し
た冷媒のガスは吸収再生器24内の混合溶液中で泡状に
なり吸収される。
(Embodiment 5) At a connecting portion 43 between the conduit 27 and the absorption regenerator 24 shown in FIG.
It is in communication with the absorbent stored in 4. The refrigerant gas evaporated in the evaporator 7 is foamed and absorbed in the mixed solution in the absorption regenerator 24.

【0034】本実施例では、混合溶液と連通しないで接
続した場合に比べ、直接に混合溶液に触れるので吸収効
率が向上するという効果を有する。尚、接続部43は気
泡の上昇を考慮し、吸収再生器24の底部に設けること
が望ましい。
In this embodiment, as compared with the case where the connection is made without communication with the mixed solution, there is an effect that the absorption efficiency is improved because the mixed solution is directly touched. It is desirable that the connecting portion 43 be provided at the bottom of the absorption regenerator 24 in consideration of rising of air bubbles.

【0035】(実施例6)図5は本発明の第6の実施例
における吸収式冷却装置の構成図である。図5におい
て、吸収再生器24の内部に例えばスプリングの形状を
した吸収促進材44が添加されており、吸収運転時は導
管27から流れ込む泡状の冷媒ガスが吸収促進材44に
衝突することにより微細な気体粒子となり吸収液体との
接触面積が急激に拡大されることにより吸収性能が著し
く向上する。一方再生運転時には吸収促進材44は伝熱
フィンとして作用するため加熱手段1で発生した熱を吸
収液に効率良く伝えることができ冷媒の発生量を拡大さ
せて性能を上げることとなる。吸収促進剤44として
は、例えばステンレス素材のものやフッ素樹脂素材のも
のを利用することが出来る。
(Embodiment 6) FIG. 5 is a configuration diagram of an absorption cooling device in a sixth embodiment of the present invention. In FIG. 5, an absorption promoting material 44 in the form of, for example, a spring is added to the inside of the absorption regenerator 24. During the absorption operation, the foamed refrigerant gas flowing from the conduit 27 collides with the absorption promoting material 44. The absorption performance is remarkably improved due to a sharp increase in the contact area with the absorbing liquid as fine gas particles. On the other hand, at the time of the regeneration operation, the absorption promoting material 44 acts as a heat transfer fin, so that the heat generated by the heating means 1 can be efficiently transmitted to the absorbing liquid, thereby increasing the amount of generated refrigerant and improving the performance. As the absorption promoter 44, for example, a stainless steel material or a fluororesin material can be used.

【0036】(実施例7)図6は本発明の第7の実施例
における吸収式冷却装置の構成図である。図7におい
て、耐食皮膜45は吸収再生器24の加熱手段1に接触
する内表面に蒸着などの方法で形成された例えばクロム
またはチタンの成分を有する皮膜である。再生運転時は
混合溶液の温度を高くすればするほど冷媒の発生量が増
大するが、一方では、アンモニア等を冷媒として用いた
高温高アルカリ性の極めて腐食性の強い環境になるため
腐食の発生する恐れがある。特に高温になる加熱手段1
の近傍に高耐食皮膜45を形成することにより、吸収再
生器24の内面全体に形成するよりも安価に腐食を防止
することができる。
(Embodiment 7) FIG. 6 is a block diagram of an absorption cooling device according to a seventh embodiment of the present invention. In FIG. 7, a corrosion-resistant film 45 is a film having a component of, for example, chromium or titanium formed on the inner surface of the absorption regenerator 24 in contact with the heating means 1 by vapor deposition or the like. During regeneration operation, the higher the temperature of the mixed solution, the higher the amount of refrigerant generated, but on the other hand, the environment becomes extremely corrosive at high temperatures and high alkalinity using ammonia or the like as a refrigerant, and corrosion occurs. There is fear. Heating means 1 that is particularly hot
, The corrosion can be prevented at a lower cost than when it is formed on the entire inner surface of the absorption regenerator 24.

【0037】(実施例8)図7は本発明の第8の実施例
における吸収式冷却装置の構成図である。図7におい
て、加熱手段1は吸収再生器24の底部に設けられてい
る。また、導管27は吸収再生器24の上部に接続挿入
するとともにその端部を吸収再生器24の底部の近傍で
開放する構成としてある。
(Embodiment 8) FIG. 7 is a block diagram of an absorption cooling device in an eighth embodiment of the present invention. In FIG. 7, the heating means 1 is provided at the bottom of the absorption regenerator 24. Further, the conduit 27 is connected to and inserted into the upper part of the absorption regenerator 24, and the end thereof is opened near the bottom of the absorption regenerator 24.

【0038】上記構成において、再生運転時には底部に
設けた加熱手段1で加熱することにより内部の混合溶液
に対流が発生し加熱が促進されるため温度上昇も早く冷
媒の発生が増大して再生性能が上がる。一方、吸収運転
時には導管27の端部は吸収再生器24の底部で開放さ
れているため流入した冷媒は気泡として上昇しながら混
合溶液を勢い良く攪拌して吸収性能を向上させる。また
加熱手段1と導管27の位置が離れているため組立性に
優れた装置が実現できる。
In the above configuration, during the regeneration operation, by heating with the heating means 1 provided at the bottom, convection is generated in the mixed solution inside and the heating is promoted. Goes up. On the other hand, at the time of the absorption operation, the end of the conduit 27 is opened at the bottom of the absorption regenerator 24, so that the inflowing refrigerant rises as bubbles and vigorously agitates the mixed solution to improve the absorption performance. Further, since the position of the heating means 1 and the conduit 27 are far apart, an apparatus excellent in assemblability can be realized.

【0039】[0039]

【発明の効果】以上のように請求項1、2または4に記
載の発明によれば、小型の冷却装置を実現することが出
来る。
As described above, according to the first, second or fourth aspect of the present invention, a compact cooling device can be realized.

【0040】さらに請求項3に記載の発明によれば、装
置の静音化を図ることが出来る。
Further, according to the third aspect of the present invention, it is possible to reduce the noise of the apparatus.

【0041】さらに請求項5、6または8に記載の発明
によれば、冷却効率を向上させることが出来る。
Further, according to the fifth, sixth or eighth aspect, the cooling efficiency can be improved.

【0042】さらに請求項7に記載の発明によれば、吸
収再生器内部の腐食を防止することが出来る。
Further, according to the present invention, corrosion inside the absorption regenerator can be prevented.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施例1および5における吸収式冷却
装置の構成図
FIG. 1 is a configuration diagram of an absorption-type cooling device according to first and fifth embodiments of the present invention.

【図2】本発明の実施例2における吸収式冷却装置の構
成図
FIG. 2 is a configuration diagram of an absorption cooling device according to a second embodiment of the present invention.

【図3】本発明の実施例3における吸収式冷却装置の構
成図
FIG. 3 is a configuration diagram of an absorption cooling device according to a third embodiment of the present invention.

【図4】本発明の実施例4における吸収式冷却装置の構
成図
FIG. 4 is a configuration diagram of an absorption cooling device according to a fourth embodiment of the present invention.

【図5】本発明の実施例6における吸収式冷却装置の構
成図
FIG. 5 is a configuration diagram of an absorption cooling device according to a sixth embodiment of the present invention.

【図6】本発明の実施例7における吸収式冷却装置の構
成図
FIG. 6 is a configuration diagram of an absorption cooling device according to a seventh embodiment of the present invention.

【図7】本発明の実施例8における吸収式冷却装置の構
成図
FIG. 7 is a configuration diagram of an absorption cooling device according to an eighth embodiment of the present invention.

【図8】従来の吸収式冷却装置の構成図FIG. 8 is a configuration diagram of a conventional absorption cooling device.

【符号の説明】[Explanation of symbols]

1 加熱手段 3 吸収熱交換器 5 凝縮熱交換器 6 凝縮器 7 蒸発器 19 第1の放熱手段 23 第2の放熱手段 24 吸収再生器 25、26、27 導管 28 開閉弁(第1の流体制御手段) 29 開閉弁(第2の流体制御手段) 31 開閉弁(第3の流体制御手段) 35 第3の放熱手段 36 三方弁(流路制御手段) 39 貯水槽 40 揚水ポンプ 41、42 逆止弁 43 接続部 44 吸収促進剤 45 耐食皮膜 DESCRIPTION OF SYMBOLS 1 Heating means 3 Absorption heat exchanger 5 Condensing heat exchanger 6 Condenser 7 Evaporator 19 1st heat radiating means 23 2nd heat radiating means 24 Absorption regenerator 25,26,27 Pipe 28 Open / close valve (1st fluid control Means) 29 On-off valve (second fluid control means) 31 On-off valve (third fluid control means) 35 Third radiating means 36 Three-way valve (flow path control means) 39 Water tank 40 Pumping pump 41, 42 Check Valve 43 Connection part 44 Absorption promoter 45 Corrosion resistant coating

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) F25B 37/00 F25B 37/00 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) F25B 37/00 F25B 37/00

Claims (8)

【特許請求の範囲】[Claims] 【請求項1】 加熱手段と吸収熱交換器を具備し吸収液
と冷媒の混合溶液を貯留する吸収再生器と、前記吸収熱
交換器の吸収熱を放熱する第1の放熱手段と、凝縮熱交
換器を具備し液冷媒を貯留する凝縮器と、前記凝縮熱交
換器の凝縮熱を放熱する第2の放熱手段と、蒸発器と、
前記吸収再生器と前記凝縮器とを繋ぐ導管上に設けられ
た第1の流体制御手段と、前記凝縮器と前記蒸発器とを
繋ぐ導管上に設けられた第2の流体制御手段と、前記蒸
発器と前記吸収再生器とを繋ぐ導管上に設けられた第3
の流体制御手段を備えてなる吸収式冷却装置。
1. An absorption regenerator having a heating means and an absorption heat exchanger for storing a mixed solution of an absorption liquid and a refrigerant, a first heat radiation means for radiating heat absorbed by the absorption heat exchanger, and a heat of condensation A condenser having an exchanger for storing the liquid refrigerant, a second radiator for radiating heat of condensation of the condensation heat exchanger, and an evaporator;
A first fluid control means provided on a conduit connecting the absorption regenerator and the condenser, a second fluid control means provided on a conduit connecting the condenser and the evaporator, A third provided on a conduit connecting the evaporator and the absorption regenerator;
Absorption cooling device comprising a fluid control means.
【請求項2】 加熱手段と吸収熱交換器を具備し吸収液
と冷媒の混合溶液を貯留する吸収再生器と、凝縮熱交換
器を具備し液冷媒を貯留する凝縮器と、前記吸収熱交換
器の吸収熱および前記凝縮熱交換器の凝縮熱を放熱する
第3の放熱手段と、前記吸収熱交換器と前記凝縮熱交換
器の一方を前記第3の放熱手段に連通させる流路制御手
段と、蒸発器と、前記吸収再生器と前記凝縮器とを繋ぐ
導管上に設けられた第1の流体制御手段と、前記凝縮器
と前記蒸発器とを繋ぐ導管上に設けられた第2の流体制
御手段と、前記蒸発器と前記吸収再生器とを繋ぐ導管上
に設けられた第3の流体制御手段を備えてなる吸収式冷
却装置。
2. An absorption regenerator having a heating means and an absorption heat exchanger for storing a mixed solution of an absorption liquid and a refrigerant; a condenser having a condensation heat exchanger and storing a liquid refrigerant; Third heat radiation means for radiating heat absorbed by the heat exchanger and condensation heat of the condensation heat exchanger, and flow path control means for communicating one of the absorption heat exchanger and the condensation heat exchanger to the third heat radiation means. An evaporator, first fluid control means provided on a conduit connecting the absorption regenerator and the condenser, and a second fluid control means provided on a conduit connecting the condenser and the evaporator. An absorption cooling device comprising: a fluid control means; and a third fluid control means provided on a conduit connecting the evaporator and the absorption regenerator.
【請求項3】 第3の放熱手段は、貯水槽と、前記貯水
槽の液体を汲み上げる揚水ポンプとからなる請求項2記
載の吸収式冷却装置。
3. The absorption cooling device according to claim 2, wherein the third heat radiating means comprises a water storage tank and a water pump for pumping liquid in the water storage tank.
【請求項4】 第1の流体制御手段と第3の流体制御手
段の少なくとも一方は逆止弁である請求項1〜3のいず
れか1項記載の吸収式冷却装置。
4. The absorption cooling device according to claim 1, wherein at least one of the first fluid control means and the third fluid control means is a check valve.
【請求項5】 蒸発器と吸収再生器とを繋ぐ導管と前記
吸収再生器との接続部において、前記導管は前記吸収再
生器に貯留した混合溶液と連通する構成とする請求項1
〜4のいずれか1項記載の吸収式冷却装置。
5. A connecting part between a conduit connecting an evaporator and an absorption regenerator and the absorption regenerator, wherein the conduit communicates with a mixed solution stored in the absorption regenerator.
5. The absorption cooling device according to any one of claims 1 to 4.
【請求項6】 吸収再生器の内部に吸収促進材を充填し
て構成する請求項1〜5のいずれか1項記載の吸収式冷
却装置。
6. The absorption cooling device according to claim 1, wherein the absorption regenerator is filled with an absorption promoting material.
【請求項7】 吸収再生器の内部の加熱手段取付面に耐
食性皮膜を形成した請求項1〜6のいずれか1項記載の
吸収式冷却装置。
7. The absorption type cooling apparatus according to claim 1, wherein a corrosion resistant film is formed on a heating means mounting surface inside the absorption regenerator.
【請求項8】 加熱手段を吸収再生器の底部に配置する
とともに蒸発器と前記吸収再生器とを繋ぐ導管を前記吸
収再生器上部より配管し底部で開放して構成する請求項
1〜7のいずれか1項記載の吸収式冷却装置。
8. The absorption regenerator according to claim 1, wherein the heating means is arranged at the bottom of the absorption regenerator and a conduit connecting the evaporator and the absorption regenerator is piped from the upper part of the absorption regenerator and opened at the bottom. An absorption cooling device according to any one of the preceding claims.
JP2000074021A 2000-03-16 2000-03-16 Absorption cooler Pending JP2001263850A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000074021A JP2001263850A (en) 2000-03-16 2000-03-16 Absorption cooler

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000074021A JP2001263850A (en) 2000-03-16 2000-03-16 Absorption cooler

Publications (1)

Publication Number Publication Date
JP2001263850A true JP2001263850A (en) 2001-09-26

Family

ID=18592136

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000074021A Pending JP2001263850A (en) 2000-03-16 2000-03-16 Absorption cooler

Country Status (1)

Country Link
JP (1) JP2001263850A (en)

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