JP2001254094A - High oil concentration particulate composition and its manufacturing method - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a high oil concentration particulate composition which can be utilized in foods, pharmaceuticals and cosmetics, excels in blocking resistance, can be clearly dissolved in hot water, and is slow in crystallizing of fats and oils after dissolution, and a method of manufacturing the same. SOLUTION: The high oil concentration particulate composition comprises fats and oils having a melting point of 40-55 deg.C whose major component of an 18C fatty acid having one double bond is of the trans type, and a method of manufacturing the high oil concentration particulate composition comprises using and pulverizing fats and oils having a melting point of 40-55 deg.C whose major component of an 18C fatty acid having one double bond is of the trans form type, and then stirring and granulating the resulting powder in the atmosphere of a temperature lower than the melting point of the fats and oils.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to a highly oily granular composition which can be used in foods, pharmaceuticals and cosmetics, has excellent blocking resistance, dissolves in clear when dissolved in hot water, and The present invention relates to a high oil content granular composition having a slow crystallization and a method for producing the same.

[0002]

2. Description of the Related Art Conventional granular compositions containing fats and oils are:
The mainstream was granulated powdered fats and oils obtained by spray-drying an emulsion composed of water, fats and oils, an emulsifier, starch and the like under a high temperature atmosphere. In the granulation method, a method of granulating and drying under a high temperature atmosphere using an aqueous solution of a polysaccharide as a binder has been the mainstream. However, in these methods for producing and granulating powdery fats and oils, a drying step at a high temperature is indispensable. Therefore, not only is the fats and oils severely degraded, but also when flavored fats and oils are used. Had a problem that not only the deterioration of the flavor but also the flavor components volatilized and the flavor was weakened. Also, when encapsulating heat-sensitive active ingredients,
There has been a problem that the required active ingredient is decomposed or the properties of the active ingredient are reduced. Furthermore, since it is a powdery fat or oil obtained by spray-drying an emulsion, it becomes cloudy when dissolved in hot water, and its use in powdery or granular instant soup requiring clarity has been limited.

In order to solve the above problem, Japanese Patent Laid-Open No.
No. 27430 proposes a method for producing a granular oil and fat by mixing and stirring an oil and fat, a base material for containing oil and fat, and a polyol at or above the melting point of the oil and fat. JP-A-10-095
No. 992 proposes a method of producing a powdered fat by granulating a starch hydrolyzate and then absorbing the oil in a temperature range not lower than the melting point of the fat. In Japanese Patent Application Laid-Open No. 7-284380, as a method for producing a granular oil-containing food, a solid fat and a food material other than fats and oils and a starch decomposition product are heated and mixed in a temperature range not lower than the melting point of the solid fat. A method for producing a granular oil-containing food by cooling to a temperature below the melting point has been proposed. However, in these methods, the oil-absorbing performance of the material for inclusion of fats and oils, the starch hydrolyzate, and the food material was limited, and the fats and oils could not be sufficiently increased. Therefore, it is necessary to add a large amount of the above-mentioned granular fats and oils in order to impart richness and flavor of the fats and oils to the granular / powder instant soup and the like, leading to an increase in cost and a problem in versatility.

[0004]

DISCLOSURE OF THE INVENTION The present invention is a granular composition having a high oil content which can be used for foods, pharmaceuticals and cosmetics, has excellent blocking resistance, and dissolves in a clear form when dissolved in hot water.
It is an object of the present invention to provide a high oil content granular composition in which crystallization of fats and oils after dissolution is slow and a method for producing the same.

[0005]

Means for Solving the Problems The inventors of the present invention have conducted intensive studies in order to solve the above problems, and as a result, have found that the melting point is 40 to 55.
° C, and a high oil content granular composition containing fats and oils in which the main component of the C18-1 constituent fatty acid is a trans type, and a melting point of 40.
A method for producing a granular composition having a high oil content, which comprises using an oil or fat whose main component of the C18-1 fatty acid is a trans type at −55 ° C. and making it into a powder state, followed by stirring and granulating under an atmosphere lower than the melting point of the oil and fat. Was found to be available.

[0006]

DETAILED DESCRIPTION OF THE INVENTION The total oil content of the high oil content granular composition of the present invention can be easily increased to 40% by weight or more. When the amount is less than 40% by weight, the composition becomes a granular composition having less flavor and richness of oil and fat.

[0007] The fats and oils used in the present invention include foods, pharmaceuticals,
There are no restrictions on animal and vegetable oils and fats that can be used in cosmetics, for example, palm oil, palm kernel oil, coconut oil, sunflower oil, soybean oil, rapeseed oil, corn oil, sesame oil, peanut oil, cocoa butter, monkey fat, Fats and oils using one or more of shea butter, lard, beef tallow, fish oil and the like, processed fats and oils obtained by subjecting them to separation, hardening, transesterification, and the like, and fats and oils obtained by combining these substances can be given. . Particularly preferred examples of fats and oils include palm olein and palm middle melting point. In addition, fats and oils, food,
It may contain an oil-soluble component that can be used for pharmaceuticals and cosmetics. Examples of oil-soluble components include, in the case of foods, oil-soluble flavors, emulsifiers and the like, and mixtures of these with oils and fats. In the present invention, the fat and oil represents the total weight% of the fat and oil and the oil-soluble component.

In the present invention, the above fats and oils have a melting point of 40
It is preferable to contain fats and oils at -55 ° C and the main component of the C18-1 constituent fatty acid is trans type. The 18-1 constituent fatty acid means a fatty acid having 18 carbon atoms and having one double bond. If the melting point of the fat or oil is less than 40 ° C., sufficient heat resistance cannot be obtained. If the melting point of the fat or oil exceeds 55 ° C., after dissolving in hot water, crystallization on the hot water surface is accelerated and discomfort is felt in the mouth. Feel commercial value decreases.

The fat or oil used in the present invention has a melting point of 40 to 55.
In one preferred embodiment, the C18-1 fatty acid at C is trans / cis ≧ 3 or more. When the melting point of the fat or oil is less than 40 ° C. or the trans / cis type of the C18-1 constituent fatty acid is less than 3, sufficient heat resistance cannot be obtained. As an example of the production method, a method of isomerizing and curing the above oil and fat raw material using a metal catalyst such as nickel or a metal catalyst poisoned with methionine or hydrogen sulfide or the like can be mentioned. It is possible to increase the trans / cis ratio of the C18-1 constituent fatty acid by further separating the cured hardened oil or fat with an organic solvent such as hexane, acetone or ethanol, or by performing dry separation without using a solvent.

Another preferred embodiment of the fat or oil is a fat or oil obtained by hardening a fat or oil containing at least 40% by weight of S2U triglyceride, wherein the trans-form of the C18-1 constituent fatty acid is trans-form / cis-form ≧ 1. There may be. S2U
The type triglyceride means (S is a C12-24 saturated fatty acid; U is a C12-C24 unsaturated fatty acid). Fats and oils obtained by curing fats and oils containing S2U triglyceride in an amount of 40% by weight or more have a melting point of 40 to 55 ° C., and one or more trans / cis-type C18-1 constituent fatty acids,
Preferably, it is an oil or fat hardened to have two or more. In the case where the S2U-type triglyceride is less than 40% by weight of a hardened raw material, the melting point is less than 40 ° C, or the trans- / cis-type fatty acid of the C18-1 constituent fatty acid is less than 1,
Sufficient heat resistance cannot be obtained. When an S2U type fat or oil having a saturated fatty acid lower than C12 or an unsaturated fatty acid lower than C12 is used as a raw material, short-chain fatty acids are easily decomposed into free fatty acids and storage stability is lowered. In addition, a cured product using a S2U type fat or oil having a saturated fatty acid exceeding C24 or an unsaturated fatty acid exceeding C24 as a raw material quickly solidifies, and even if it is melted on the surface of hot water, crystallization occurs immediately in the mouth and a waxy food is obtained. This gives a sense of incongruity and lowers product value. As an example of production, S2U type fats and oils are processed into 40
Weight% or more, and C18-
In order to increase the trans / cis type of the 1-constituent fatty acid, a method of isomerizing and curing using a metal catalyst such as nickel or a metal catalyst poisoned with methionine or hydrogen sulfide or the like can be used. It is possible to increase the trans / cis ratio of C18-1 constituent fatty acids by further separating the obtained isomerized hardened fat with an organic solvent such as hexane, acetone, ethanol or the like, or by performing dry separation without using a solvent. It is.

The above fats and oils are preferably used in the form of powder.
As a method of pulverizing fats and oils, a freeze-pulverization method of solidifying and pulverizing molten fats and oils in a low-temperature atmosphere with liquid nitrogen or the like, a spray of cooling and pulverizing by spraying molten fats and oils in a low-temperature atmosphere. Cooling method, cooling on two or more rolls cooled molten or solid fat,
A roll press method of compressing and solidifying, scraping with a blade having a sharp blade, and then pulverizing the powder is used. If necessary, powdered fats and oils finely divided by a pulverizer or powdered fats and oils classified by a sieve may be used.

The particle size and shape of the powdered fats and oils are not limited, but those subjected to the granulation step are preferably fine particles having an average particle size of 0.5 mm or less, or scaly powder having an average particle size of 3 mm or less.

In the present invention, the above-mentioned powdered fats and oils and another fat and oil can be used together in a state in which the starch hydrolyzate is impregnated with oil. The starch hydrolyzate is not particularly limited as long as it can be used for foods, pharmaceuticals, and cosmetics. For example, starches of potato, tapioca, corn, wheat, rice, etc., or modified starches such as pregelatinized starches thereof, and starch degradation products of modified starches such as octenyl succinic oxidation and phosphorylation are included. Further, the starch hydrolyzate used is preferably water-soluble, and if it is insoluble in water, the hot oil becomes turbid when the produced high oil content granular composition is dissolved in hot water, and the product value is reduced. Further, it is preferable that the starch hydrolyzate has a property of absorbing oil in a dry state. 50% by weight or more, preferably 80% by weight or more, more preferably 100% by weight with respect to its own weight
It is preferable that the product is a starch hydrolyzate having the above oil absorption performance. When the oil absorption performance is less than 50% by weight based on its own weight,
Fats and oils easily seep out and hinder the function of the specific fats and oils used in the form of powder, thereby reducing the heat resistance of the high oil content granular composition and causing blocking to occur easily. Commercially available starch degradation products include “Oil Q No. 50” and “Oil Q-
S "(manufactured by Nisse Chemical Co., Ltd.) and" Pine Flow "(manufactured by Matsutani Chemical Industry Co., Ltd.).

As a method for impregnating the degraded starch with oil and fat, the degraded fat and oil-containing starch is obtained by impregnating the melted fat and oil with stirring in a stirrer.

It is preferable that the ratio of the powdered oil or fat and the decomposed product of the oil or fat-containing starch to starch is such that the ratio of the decomposed product of the oil or fat-containing starch / powdered oil or fat ≦ 9. When the ratio of the oil-and-oil-containing starch-decomposed product / powder oil / fat exceeds 9, the oil / fat content of the granular composition is not sufficiently increased, and the high oil content granular composition is not obtained.

The fat- and oil-containing starch-decomposed product is obtained by adding 20 to 70
It is preferred that it contains weight%. If less than 20% by weight,
The oil and fat content of the granular composition decreases, and the product value decreases.
If it exceeds 70% by weight, it becomes difficult to form a powder or granules in a pace.

The high oil content granular composition of the present invention can be obtained by stirring and granulating. As a stirring granulator, a planetary type such as a universal mixing stirrer may be used, but a high-speed stirring type is effective. As a high-speed stirring type, commercially available "heavy duty-type granulators" and "Pharma type granulators" (Nara Machinery Co., Ltd.),
"Vertical Granulator" (manufactured by Powrex Co., Ltd.), "New Gram Machine" (manufactured by Seishin Enterprise Co., Ltd.), "High Speed Mixer" (manufactured by Fukae Kogyo Co., Ltd.) and the like.

In the granulation method, a powdery fat or oil or a mixture thereof with a fat and oil-containing starch decomposition product is subjected to stirring granulation in an atmosphere lower than the melting point of the fat or oil. When heated above the melting point,
The mixture cannot be granulated because it becomes a liquid, a paste, or a coarse mass by stirring.

For the purpose of further improving the heat resistance of the high oil content granular composition, a starch hydrolyzate containing no fat or oil is added after granulation in an amount of 0.5 part by weight or less based on 1 part by weight of the granular composition. Alternatively, the stirring granulation can be performed in an atmosphere lower than the melting point of the fat or oil of the granular composition. However, when the amount is more than 0.5 part by weight, not only the fat and oil content of the granular composition decreases, but also the time required for granulation becomes longer and the productivity decreases.

The stirring speed at the time of stirring and granulating the high oil content granular composition of the present invention varies depending on the model and scale, and
It can be set experimentally to obtain the desired particle size.

The fats and oils used in the fat and oil-containing starch hydrolyzate of the present invention can be flavored, and the flavoring method may be milk fat, lard, beef tallow, fish oil, sesame oil, sesame oil, peanut oil, coconut oil and the like. Oils and fats having a specific flavor, or oil-soluble flavors may be flavored by appropriately blending them, and oils and fats used in the present invention to further enhance the flavor and solid flavor substances such as rice bran, powdered milk, green onion, sesame and the like. After heating and mixing, oils and fats from which insolubles have been removed may be used.

Further, a seasoning which is edible and contains a powdered or granular animal or plant extract, a flavor, an amino acid, a nucleic acid, inosinic acid, an organic acid or the like which is not easily clouded when dissolved in hot water is granulated. You may mix before or after.

The particle size of the high oil content granular composition is not particularly limited and is adjusted according to the purpose of use. For example, when used for a granular instant soup, the average particle size is preferably 0.1 to 3 mm.

[0024]

The present invention will be described in more detail with reference to examples of the present invention, but the spirit of the present invention is not limited to the following examples. In addition,% and a part mean a weight basis in an example. In the following, trans-type and cis-type analysis methods, dissolution tests, crystallization tests, and blocking tests of C18-1 constituent fatty acids were performed as follows. (Analysis of trans- and cis-forms of C18-1 constituent fatty acids) This analysis is based on THE AMERICAN OIL CHEMISTS 'SOCIETY
Ce 1 of "OFFICIAL METHODS AND RECOMMEND PRACTICES"
The composition of the constituent fatty acids in the fats and oils was measured by the capillary gas chromatography method according to the section c-89, and the ratio between the trans-form and the cis-form of the C18-1 constituent fatty acid was determined. (Dissolution test) In the dissolution test, 4 g of each high oil content granular composition was added to 400 ml of hot water at 95 ° C., and the mixture was stirred. +: Turbidity is observed. -: No turbidity. (Crystallization test) The crystallization test was performed at 400 ° C.
4 g of each high oil content granular composition was dissolved in 1 and cooled at room temperature. After 30 minutes, the presence or absence of crystallization of fats and oils on the surface of hot water was visually confirmed. ：: No crystal precipitation was observed on the hot water surface. ×: Fat crystals precipitated on the surface of hot water, and white solid fat was floating. (Blocking test) 20 g of each high oil content granular composition was placed in a 100 ml glass beaker, allowed to stand at 40 ° C for 48 hours, and then cooled at 20 ° C for 4 hours, and then visually checked for blocking state and fluidity. did. ：: Good flowability without blocking. ：: Slight blocking was observed to the extent that there was no problem on the product, but the blocking was broken by gentle shaking, and the fluidity was restored. ×: Blocking occurred as much as a problem occurred on the product,
Even if shaken vigorously, it is in a blocking state and the fluidity does not recover.

Preparation of fats and oils 1 Isomerization hardening using a nickel catalyst in which palm olein (S2U content: 19.2%) was poisoned with methionine, followed by fractionation with hexane, followed by recovery of a high melting point portion and fractionation by isomerization curing A palm high melting point fat (melting point: 46.1 ° C, trans / cis type of C18-1 = 6.2) was obtained.

Preparation of fats and oils 2 The medium melting point of palm (S2U content 67.5%) is isomerized and cured using a nickel catalyst poisoned with methionine, and isomerized and cured palm medium melting point fat (melting point 53.6 ° C., C18 -1
Trans / cis type = 2.9) was obtained.

Preparation of fat 3 The medium melting point of palm (S2U content 67.5%) is usually hardened, and the hardened palm medium melting point oil (melting point 45.6 ° C, C18-
1 trans type / cis type = 0.5).

Preparation of fats and oils 4 Palm oil (S2U content: 44.2%) is usually hardened and extremely hardened palm oil (melting point: 58.5 ° C., iodine value: 0.7)
I got

Table 1 summarizes the analysis values of fats and oils in Preparations 1 to 4 of fats and oils.

[Table 1]

Example 1 The isomerized and hardened fractionated palm high melting point oil (melting point: 46.1 ° C., trans / cis type = C18-1 = 6.2) obtained in Preparation 1 of oil and fat was melted and roll-pressed ( BUHLER, 3-stage roll, cooling temperature 15 ° C)
Classification was further performed using a 10-mesh sieve to obtain a powdery fat and oil 1 having passed through the sieve. Using a high-speed stirring-type mixing granulator “Heavy Duty Type NMG-10L” (manufactured by Nara Machinery Co., Ltd.), the jacket oil cooling water temperature 3
The mixture was stirred and granulated at 2.0 ° C. to obtain a high oil content granular composition (oil / fat melting point: 46.1 ° C., C18-1 trans / cis type = 6.2, fat / oil content: 100%). The dissolution test evaluation of this high oil content granular composition was-, the crystallization test evaluation was ○, and the blocking test evaluation was ◎.

Example 2 Isomerized and cured palm medium melting point fat obtained in Preparation 2 of fat and oil (melting point 53.6 ° C., trans / cis type of C18-1 =
2.9) was melted, and a roll press machine (manufactured by BUHLER)
The mixture was supplied to a three-stage roll at a cooling temperature of 15 ° C.). After pulverization, the powder was classified with a 10-mesh sieve to obtain a powdery fat 2 having passed through the sieve. Using a high-speed stirring type mixing granulator “Heavy Duty Type NMG-10L” (manufactured by Nara Machinery Co., Ltd.), the cooling water temperature of the powdery fat 2 was 35.
Stir granulation was performed at 0 ° C. to obtain a high oil content granular composition (oil / fat melting point: 53.6 ° C., C18-1 trans / cis type =
2.9, oil and fat content 100%). The dissolution test evaluation of this high oil content granular composition was-, the crystallization test evaluation was ○, and the blocking test evaluation was ◎.

Example 3 The isomerized and hardened fractionated palm high melting point oil (melting point 46.1 ° C., trans / cis type of C18-1 = 6.2) obtained in Preparation 1 of oil and fat was rolled in the same manner as in Example 1. After powdering with a press machine,
Classification was performed to obtain a powdery fat and oil 1. In addition, isomerization-hardened fractionated palm high melting point oil / fat 39.8 in Preparation 1 of oil / fat melted in 50 parts of starch decomposed product “Oil QS” manufactured by Nisseki Chemical Co., Ltd.
, 10 parts of lard, and 0.2 parts of "charshoe flavor" manufactured by Nagaoka Perfume Co., Ltd., and mixed in a universal mixing stirrer to obtain a fat- and oil-containing starch-decomposed product. A mixture of 40 parts of the above-mentioned powdery fat 1 and 60 parts of a fat and oil-containing starch hydrolyzate was mixed with the same granulating machine as in Production Example 1 using a jacket cooling water temperature of 3 parts.
The mixture was stirred and granulated at 2.0 ° C to obtain a high oil content granular composition (oil / fat melting point: 45.0 ° C, C18-1 trans / cis type = 3.5, fat / oil content: 70%). Dissolution test evaluation of this high oil content granular composition is-, crystallization test evaluation is ○,
Blocking test evaluation was ◎ and the result was good.

Example 4 "Melano STS" (melting point: 35.9 ° C) manufactured by Fuji Oil Co., Ltd. dissolved in 50 parts of starch hydrolyzate “Oil QS” 39.
8 parts, lard 10 parts, “charshoo flavor” 0.
Two parts were added and mixed in a universal mixing stirrer to obtain a fat- and oil-containing starch-decomposed product. A mixed powder of 40 parts of the powdery oil or fat 1 obtained in Example 1 and 60 parts of an oil or fat-containing starch-decomposed product was subjected to jacket cooling water temperature of 20.
Stir granulation is performed at 0 ° C. to obtain a high oil content granular composition (oil and fat melting point: 42.9 ° C., C18-1 trans / cis type =
2.4, oil content 70%). The dissolution test evaluation of this high oil content granular composition was-, the crystallization test evaluation was ○, and the blocking test evaluation was ○.

Example 5 85 parts of the high oil content granular composition obtained in Example 4 and 15 parts of the starch hydrolyzate "Oil QS" were again used in the same granulator as in Example 1 and the jacket cooling water temperature was changed. The mixture was stirred and granulated at 20.0 ° C to give a high oil content granular composition (oil and fat melting point of 42.9).
C, trans / cis type of C18-1 = 2.4, oil / fat content 59.5%). The dissolution test evaluation of this high oil content granular composition was-, the crystallization test evaluation was ○, and the blocking test evaluation was ◎.

COMPARATIVE EXAMPLE 1 The cured palm medium melting point fat (oil melting point 4) obtained in Preparation 3 of fats and oils
5.6 ° C., trans / cis type of C18-1 = 0.5)
Was pulverized by the same roll press as in Example 1 and then classified to obtain comparative powdery fat 1. In addition, starch degradation product “Oil Q
-S "50 parts of melted oil and fat, 39.8 parts of cured palm medium-melting oil of Preparation 3, 10 parts of lard, and 0.2 part of" Churshu Flavor "manufactured by Nagaoka Perfume Co., Ltd. are mixed in a universal mixing stirrer. Thus, an oil- and fat-containing starch-decomposed product was obtained. 40 parts of comparative powdery fat 1 and fat / oil-containing starch-decomposed product 6
0 parts of the mixed powder was subjected to stirring granulation at a jacket cooling water temperature of 30.0 ° C using the same granulator as in Production Example 1 to give a high oil content granular composition (oil and fat melting point: 45.1 ° C, C18-1). Trans / cis type = 0.5, oil / fat content 70%). The dissolution test evaluation of this high oil content granular composition was-, the crystallization test evaluation was ○, the blocking test evaluation was ×, and blocking occurred.

Comparative Example 2 Extremely hardened palm oil obtained in Preparation 4 of oil and fat (melting point 5
8.5 ° C. and an iodine value of 0.7) were pulverized with the same roll press as in Example 1 and then classified to obtain comparative powdery fat 2.
The comparative powdery oil and fat 2 was stirred and granulated at 45.0 ° C. in the jacket cooling water temperature using the same granulator as in Example 1 to obtain a high oil content granular composition (oil and fat melting point 58.5 ° C., oil content 100%). )
I got Dissolution test evaluation of this high oil content granular composition
-, Crystallization test evaluation is ×, blocking test evaluation ◎
And the crystallization after dissolution was rapid.

As is evident from the above test results, even when processed oils and fats derived from the same raw material are used, only the high oil content granular composition using oils and fats processed to have a specific oil and fat composition has blocking resistance. It is clear that when dissolved in hot water, it dissolves finely, and crystallization after dissolution is slow.

[0038]

Industrial Applicability The present invention is a granular composition having a high oil content by using a specific fat or oil, a water-soluble starch hydrolyzate, and stirring and granulating at a temperature lower than the melting point of the fat or oil to dissolve in hot water. The present invention provides a granular composition having a high oil content, which dissolves in a clear form upon dissolution, has a slow crystallization after dissolution, and can be used for pharmaceuticals and cosmetics, and a method for producing the same.

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁷ Identification symbol FI Theme coat ゛ (Reference) // A61K 7/00 A61K 47/44 47/44 A23D 9/00 518 F-term (Reference) 4B026 DC06 DH03 DH10 DL03 DP01 DX08 4C076 EE51 4C083 AC241 AC421 AD241 BB12 DD16 FF01 4H059 BA33 BB02 BB03 BB06 BB07 BC03 BC13 BC45 CA34 CA46 DA02 DA16 EA40

Claims (11)

[Claims] 1. A high oil content granular composition comprising a fat having a melting point of 40 to 55 ° C. and a trans-type fatty acid as a main component of C18-1 constituent fatty acid. 2. The high oil content granular composition according to claim 1, wherein the trans-form of the C18-1 constituent fatty acid contains an oil or fat whose trans-form / cis-form is ≧ 3. 3. The method according to claim 2, wherein the fat or oil comprises 40 g of S2U triglyceride.
Fats and oils obtained by curing fats and oils containing at least
2. The high oil content granular composition according to claim 1, wherein the trans-form of the C18-1 constituent fatty acid contains fats and oils satisfying trans-form / cis-form ≧ 1. 3. 4. The raw material state of fats and oils is powdery.
A high oil content granular composition according to any one of claims 3 to 3. 5. A high oil content granular composition using a different oil or fat as a raw material of the oil or fat according to any one of claims 1 to 3, wherein the oil or fat is impregnated in a starch decomposition product. 6. The high-oil granular composition according to claim 5, wherein the fat-and-oil-containing starch-decomposed product, which is a fat and oil impregnated in the powdery fat-and-oil-and-starch-decomposed product, satisfies the formula: object. 7. The oil-and-oil-containing starch-decomposed product is obtained by converting an oil or fat to 20-70.
The high-oil content granular composition according to claim 5 or 6, which contains 0.1% by weight. 8. The high oil granular composition according to claim 5, wherein the starch hydrolyzate is water-soluble. 9. A high oil content granular composition, which is obtained by stirring and granulating powdery fats and oils having a melting point of 40 to 55 ° C. and the main component of a C18-1 constituent fatty acid in a trans form under an atmosphere lower than the melting point of the fats and oils. Manufacturing method. 10. The high oil content granule composition according to claim 9, wherein a mixture of the powdery fat and oil and the fat and oil-containing starch hydrolyzate impregnated in the starch hydrolyzate is stirred and granulated in an atmosphere lower than the melting point of the fat and oil. Manufacturing method. 11. Granulation of a powdery fat or oil or a mixture with an oil-and-oil-containing starch-decomposed product is used, and then the starch-decomposed product is used in an amount of 0.5 part by weight or less per 1 part by weight of the granular composition. The method for producing a granular composition having a high oil content according to claim 9 or 10, wherein the granulation is carried out by stirring under an atmosphere having a temperature lower than the melting point of the fat or oil of the composition.