JP5796143B1 - Oil composition for solid roux and solid roux containing the same - Google Patents

Oil composition for solid roux and solid roux containing the same Download PDF

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JP5796143B1
JP5796143B1 JP2015002772A JP2015002772A JP5796143B1 JP 5796143 B1 JP5796143 B1 JP 5796143B1 JP 2015002772 A JP2015002772 A JP 2015002772A JP 2015002772 A JP2015002772 A JP 2015002772A JP 5796143 B1 JP5796143 B1 JP 5796143B1
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謙太郎 村川
謙太郎 村川
千恵 堀越
千恵 堀越
崇史 堤
崇史 堤
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月島食品工業株式会社
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Abstract

【課題】製造時における固化性が良好で、ブルーミングが生じにくく、かつ、ソースとする際のお湯への溶解性が良好な固形ルウ用油脂組成物及びそれを含有する固形ルウを提供する。【解決手段】動物油脂の極度硬化油(A)及び動物油脂を分別処理して得られる動物油脂分別軟質部(B)を含む混合油脂組成物(C)を、エステル交換して得られるエステル交換油(D)と、動物油脂を分別処理して得られる動物油脂分別硬質部(E)とを含む固形ルウ用油脂組成物を得る。この固形ルウ用油脂組成物を用いて固形ルウを作製する。【選択図】なしAn oil and fat composition for solid roux that has good solidification during production, is less likely to cause blooming, and has good solubility in hot water when used as a sauce, and a solid roux containing the same. The transesterification obtained by transesterifying the mixed fat composition (C) containing the animal oil / fat fractionated soft part (B) obtained by fractionating the animal oil / fat extremely hardened oil (A) and the animal fat / oil. An oil / fat composition for solid roux comprising oil (D) and animal oil / fat fractionated hard part (E) obtained by fractionating animal oil / fat is obtained. A solid roux is produced using this fat and oil composition for solid roux. [Selection figure] None

Description

本発明は、例えばカレー、シチュー、ハヤシなどの即席ルウに適した固形ルウ用油脂組成物及びそれを含有する固形ルウに関する。   The present invention relates to an oil composition for solid roux suitable for instant roux such as curry, stew, and palm and a solid roux containing the same.

カレー、シチュー、ハヤシなどの即席ルウに用いられる固形ルウは、家庭だけでなく、レストランや給食などで広く使用されている。固形ルウは、小麦粉若しくは澱粉と、油脂とを、約100〜140℃位に加熱混合後、加熱しながら乳化剤、砂糖、塩、グルタミン酸ソーダなどの調味料、香辛料、その他を添加して攪拌混合した後、容器に充填し、冷却雰囲気下で数十分から数時間かけて冷却固化して製造される。また、冷却用容器から固化したルウを出し、粉砕あるいは裁断などの仕上げを行いフレーク状、顆粒状などにして使用されることもある。   Solid roux used for instant roux such as curry, stew, and hayashi is widely used not only at home but also in restaurants and school lunches. Solid roux is a mixture of wheat flour or starch and fats and oils heated to about 100-140 ° C., then added with seasonings such as emulsifier, sugar, salt, sodium glutamate, spices, etc. while stirring. Thereafter, the container is filled and cooled and solidified in a cooling atmosphere over several tens of minutes to several hours. In some cases, solidified roux is taken out from the cooling container and finished in the form of pulverization or cutting to form flakes or granules.

このような固形ルウとして、下記特許文献1には、動物油脂及び動物油脂の極度硬化油を配合してエステル交換した油脂と、動物油脂とを配合した油脂組成物を含ませた即席調理食品が開示されている。   As such a solid roux, the following Patent Document 1 discloses an instant cooked food containing an oil / fat composition in which animal oil / fat and an extremely fat-cured oil of animal / fat oil are mixed and transesterified, and animal oil / fat is added. It is disclosed.

また、下記特許文献2には、牛脂/豚脂と、牛脂/豚脂の極度硬化油とからなる油脂混合物を、ランダムエステル交換反応して作製したトランス脂肪酸含量が4%以下のルー用油脂組成物が開示されている。   Patent Document 2 below discloses a fat composition for roux having a trans-fatty acid content of 4% or less prepared by random transesterification of an oil / fat mixture comprising beef tallow / tallow and beef tallow / tallow extremely hardened oil. Things are disclosed.

更に、下記特許文献3には、牛脂を分別処理して得られる牛脂分別硬質部の極度硬化油と、牛脂を分別処理して得られる牛脂分別軟質部とを混合してなる油脂混合物(A)を含む油脂組成物を、エステル交換反応させて得られ、トランス脂肪酸含量が2%以下であることを特徴とする即席ルー用油脂組成物が開示されている。   Furthermore, in Patent Document 3 below, an oil and fat mixture (A) obtained by mixing an extremely hardened oil of a beef tallow fraction hard part obtained by separating beef tallow and a beef tallow fraction soft part obtained by fractionating beef tallow An oil composition for instant roux is disclosed, which is obtained by subjecting an oil / fat composition containing a transesterification reaction to a trans fatty acid content of 2% or less.

特開2006−197884号公報JP 2006-197884 A 特開2006−325509号公報JP 2006-325509 A 特開2014−50343号公報JP 2014-50343 A

固形ルウの製造時の冷却処理は、製造工程上の都合から瞬間固化できないため、以下のような問題があった。
(1)冷却処理時間が長く、エネルギーやスペースの多消費型となり、効率が悪い。
(2)冷却過程で油脂結晶粗大化による白色化(ブルーミング)が発生し油脂が表面に浸出する。
(3)固化までの時間が長くなると比重の大きい成分が沈降して上層部分と下層部分とで成分分布が異なり、バラツキがでて不均一になる。
(4)フレークや顆粒状などの形状が不均一になる。
(5)過度の冷却( 過冷却)により表面に結露が発生するので、保存性が悪化する。
(6)表面に結露が発生すると、食塩、砂糖などの水溶性成分が結露水に溶解し、結露水が蒸発すると表面にその結晶が出現し、外観が悪化する。
The cooling process during the production of solid roux has the following problems because it cannot be instantly solidified for convenience of the production process.
(1) The cooling process takes a long time, energy and space are highly consumed, and the efficiency is poor.
(2) Whitening (blooming) occurs due to coarsening of fat and oil crystals during the cooling process, and the fat and oil leaches to the surface.
(3) When the time until solidification becomes longer, the component having a large specific gravity settles, the component distribution is different between the upper layer portion and the lower layer portion, and the variation becomes uneven and non-uniform.
(4) Shapes such as flakes and granules are not uniform.
(5) Condensation occurs on the surface due to excessive cooling (overcooling), so the storage stability is deteriorated.
(6) When dew condensation occurs on the surface, water-soluble components such as salt and sugar dissolve in the dew condensation water, and when the dew condensation water evaporates, the crystals appear on the surface and the appearance deteriorates.

このような固形ルウの課題に対して、前記特許文献1,2に開示された固形ルウにおいては、製造工程における冷却時の固化性が悪いため、沈殿が生じやすく、また、ブルーミング防止効果がやや劣り、ソースとする際のお湯への溶解性が悪いという問題があった。   With respect to such a problem of solid roux, the solid roux disclosed in Patent Documents 1 and 2 is poor in solidification at the time of cooling in the production process, so that precipitation is likely to occur, and the blooming prevention effect is somewhat low. There was a problem that it was inferior and poorly soluble in hot water when used as a sauce.

また、前記特許文献3に開示された固形ルウにおいては、冷えたときに粘度が出過ぎて、口溶けが悪くなる傾向があった。   Moreover, in the solid roux disclosed in the above-mentioned Patent Document 3, there is a tendency that when it is cooled, the viscosity is excessively increased and the melting of the mouth is deteriorated.

したがって、本発明の目的は、製造時における固化性が良好で、ブルーミングが生じにくく、かつ、ソースとする際のお湯への溶解性が良好な固形ルウ用油脂組成物及びそれを含有する固形ルウを提供することにある。   Accordingly, an object of the present invention is to provide an oil and fat composition for solid roux that has good solidification during production, is less likely to cause blooming, and has good solubility in hot water when used as a sauce, and solid roux containing the same Is to provide.

本発明者らは上記課題を解決するために鋭意研究を重ねた結果、動物油脂を分別処理して作製した動物油脂分別軟質部と動物油脂の極度硬化油を一定の割合以上含有する油脂組成物を、エステル交換してエステル交換油脂を作製し、前記エステル交換油脂と、動物油脂を分別処理して作製した動物油脂分別硬質部とを一定の割合以上含有する油脂組成物を用いることにより、ルウ製造工程中のルウの固化性に優れ、油脂と固形分の分離やブルーミングが発生せず、かつソースとする際のお湯への溶解性が良い即席ルーが得られることを見出し、本発明を完成するに至った。   As a result of intensive studies to solve the above problems, the inventors of the present invention have obtained an oil / fat composition containing an animal oil / fat fractionated soft part prepared by fractionating animal oil / fat and an animal oil / fat extremely hardened oil in a certain ratio or more. By transesterifying to produce a transesterified oil and fat, and using the oil and fat composition containing the transesterified oil and fat and the animal oil and fat fractionated hard part produced by fractionating the animal fat and oil at a certain ratio or more, The present invention was completed by finding that it has excellent solidification of roux during the manufacturing process, does not cause separation of oil and fat and solids, blooming, and can obtain instant roux with good solubility in hot water when used as a sauce. It came to do.

すなわち、本発明の固形ルウ用油脂組成物は、動物油脂の極度硬化油(A)及び動物油脂を分別処理して得られる動物油脂分別軟質部(B)を含む混合油脂組成物(C)を、エステル交換して得られるエステル交換油(D)と、動物油脂を分別処理して得られる動物油脂分別硬質部(E)とを含むことを特徴とする。   That is, the fat and oil composition for solid roux of the present invention comprises a mixed fat and oil composition (C) including an animal fat and oil fractionated soft part (B) obtained by fractionating an extremely hardened oil (A) of animal fat and animal fat. The transesterified oil (D) obtained by transesterification and the animal oil / fat fractionated hard part (E) obtained by fractionating the animal oil / fat are included.

本発明の固形ルウ用油脂組成物の好ましい一態様において、前記混合油脂組成物(C)は、前記動物油脂の極度硬化油(A)、前記動物油脂分別軟質部(B)、及び動物油脂(F)を含むものであってもよい。   In a preferred embodiment of the solid lube oil / fat composition of the present invention, the mixed oil / fat composition (C) comprises the animal oil / fat extremely hardened oil (A), the animal oil / fat fractionated soft part (B), and the animal oil / fat ( F) may be included.

また、本発明の固形ルウ用油脂組成物の好ましい一態様において、前記固形ルウは、前記エステル交換油(D)と、前記動物油脂分別硬質部(E)と、動物油脂(F)とを含むものであってもよい。   Moreover, in one preferable aspect of the fat and oil composition for solid roux of the present invention, the solid roux includes the transesterified oil (D), the animal oil and fat fractionation hard part (E), and the animal fat and oil (F). It may be a thing.

また、本発明の固形ルウ用油脂組成物においては、動物油脂由来の全油脂中における前記動物油脂分別硬質部(E)の含量が5〜60質量%であることが好ましい。   Moreover, in the oil composition for solid roux of this invention, it is preferable that the content of the said animal fats and oils classification hard part (E) in the whole fats and oils derived from animal fats is 5-60 mass%.

また、本発明の固形ルウ用油脂組成物においては、動物油脂由来の全油脂中における前記エステル交換油(D)の含量が30〜95質量%であることが好ましい。   Moreover, in the oil composition for solid luu of this invention, it is preferable that the content of the said transesterified oil (D) in all the fats and oils derived from animal fats is 30-95 mass%.

また、本発明の固形ルウ用油脂組成物においては、前記混合油脂組成物(C)中における前記動物油脂分別軟質部(B)の含量が5〜75質量%であることが好ましい。   Moreover, in the oil composition for solid roux of this invention, it is preferable that the content of the said animal fat classification part (B) in the said mixed fat composition (C) is 5-75 mass%.

また、本発明の固形ルウ用油脂組成物においては、前記混合油脂組成物(C)中における前記動物油脂の極度硬化油(A)の含量が25〜70質量%であることが好ましい。   Moreover, in the oil composition for solid roux of the present invention, the content of the extremely hardened oil (A) of the animal fat in the mixed fat composition (C) is preferably 25 to 70% by mass.

また、本発明の固形ルウ用油脂組成物においては、前記動物油脂分別硬質部(E)が、動物油脂の分別処理の際に、硬質部と軟質部との質量比が30:70〜70:30になるように分別処理した硬質部からなることが好ましい。   In the oil composition for solid roux of the present invention, the animal oil / fat fractionated hard part (E) has a mass ratio of the hard part to the soft part of 30:70 to 70: It is preferable that it consists of the hard part which carried out the separation process so that it might be set to 30.

更に、本発明の固形ルウ用油脂組成物においては、前記動物油脂分別軟質部(B)が、動物油脂の分別処理の際に、硬質部と軟質部との質量比が30:70〜70:30になるように分別処理した軟質部からなることが好ましい。   Furthermore, in the oil composition for solid roux of the present invention, the animal oil / fat fractionated soft part (B) has a mass ratio of the hard part to the soft part of 30:70 to 70: Preferably, it is composed of a soft part that has been subjected to a fractionation treatment so as to be 30.

更にまた、本発明の固形ルウ用油脂組成物においては、トランス脂肪酸含量が2%以下であることが好ましい。   Furthermore, in the oil composition for solid roux of the present invention, the trans fatty acid content is preferably 2% or less.

一方、本発明の固形ルウは、前記固形ルウ用油脂組成物を含有することを特徴とする。   On the other hand, the solid roux of the present invention is characterized by containing the oil composition for solid roux.

本発明の固形ルウ用油脂組成物によれば、動物油脂を分別処理して得られる結晶性の良い動物油脂分別硬質部を配合したため、固形ルウの製造工程中のルウの固化性が良好で、固形分の沈殿が発生しづらい。また、動物油脂極度硬化油と動物油脂分別軟質部とを含む混合油をエステル交換したエステル交換油を含むことにより、使用時におけるお湯への溶解性が良好となると共に、製造されたルウの口溶けが良好となる。更に、エステル交換油の原料の1つとして、動物油脂極度硬化油を用いるため、トランス脂肪酸を低減することができる。   According to the oil composition for solid roux of the present invention, since the animal oil / fat fractionated hard part with good crystallinity obtained by fractionating animal oil / fat is blended, the solidification property of the roux during the production process of solid roux is good, Precipitation of solids is difficult to occur. In addition, by including a transesterified oil obtained by transesterification of a mixed oil containing animal oil / fat extremely hardened oil and animal oil / fat fractionated soft part, the solubility in hot water during use is improved and the mouth of the produced roux is melted. Becomes better. Furthermore, since one of the raw materials for the transesterified oil is animal oil / extremely hardened oil, trans fatty acid can be reduced.

本発明のルウ用油脂組成物は、動物油脂の極度硬化油(A)及び動物油脂を分別処理して得られる動物油脂分別軟質部(B)を含む混合油脂組成物(C)を、エステル交換して得られるエステル交換油(D)と、動物油脂を分別処理して得られる動物油脂分別硬質部(E)とを含んでいる。   The oil-and-fat composition for luu of the present invention transesterifies a mixed oil-and-fat composition (C) containing an animal oil-and-fat fractionated soft part (B) obtained by fractionating animal oil-and-fat extremely hardened oil (A) and animal-and-fat. The transesterified oil (D) obtained in this manner and the animal oil / fat fractionated hard part (E) obtained by fractionating the animal oil / fat are included.

本発明で用いる動物油脂としては、特に制限はなく、例えば牛脂、豚脂、魚油、羊油、鶏油、鯨油、乳脂などから選ばれる1種又は2種以上の油脂を混合して使用することができる。この中でも、特に豚脂、牛脂が好ましい。これらの動物油脂としては、一般的に得られる品位のものを使用することができ、抽出方法、精製方法などに制限はない。   There is no restriction | limiting in particular as animal fat used in this invention, For example, 1 type, or 2 or more types of fats and oils chosen from beef tallow, lard, fish oil, sheep oil, chicken oil, whale oil, milk fat, etc. should be mixed and used. Can do. Of these, pork fat and beef tallow are particularly preferable. As these animal fats and oils, those generally obtained can be used, and there are no limitations on the extraction method, purification method, and the like.

本発明において、動物油脂の極度硬化油(A)としては、動物油脂を、常法により圧力容器中でニッケル触媒を用いて、ヨウ素価3以下まで水素添加したものを用いることができる。   In the present invention, as the extremely hardened oil (A) of animal fats and oils, those obtained by hydrogenating animal fats and oils to a iodine value of 3 or less using a nickel catalyst in a pressure vessel by a conventional method can be used.

また、本発明における動物油脂分別軟質部(B)及び動物油脂分別硬質部(E)は、動物油脂を分別処理することにより得られる。ここで、分別処理は、自然分別であるドライ分別法(乾式分別)、あるいは有機溶剤を用いる溶剤分別法、もしくはその他の方法のいずれでも良く、その方法に制限はないが、安全性の問題やコストの観点から溶剤を使用しないドライ分別法が好ましい。分別時の温度条件は、特に限定されないが、晶析温度±3℃程度であれば、軟質部と硬質部とに容易に効率良く分別することができる。分別の際の硬質部と軟質部との比(質量比)は、好ましくは30:70〜70:30、より好ましくは60:40〜40:60である。硬質部と軟質部との比(質量比)が上記範囲内であれば、分別油脂としての特性を良好に得ることができる。   Moreover, the animal oil / fat fractionation soft part (B) and the animal oil / fat fractionation hard part (E) in the present invention can be obtained by subjecting the animal oil / fat to a fractionation treatment. Here, the separation process may be either a natural separation dry separation method (dry separation), a solvent separation method using an organic solvent, or any other method. From the viewpoint of cost, a dry fractionation method using no solvent is preferred. Although the temperature condition at the time of fractionation is not particularly limited, if the crystallization temperature is about ± 3 ° C., the soft part and the hard part can be easily and efficiently separated. The ratio (mass ratio) between the hard part and the soft part in the fractionation is preferably 30:70 to 70:30, more preferably 60:40 to 40:60. If the ratio (mass ratio) between the hard part and the soft part is within the above range, the characteristics as a fractionated oil can be obtained well.

こうして分別処理して得られる動物油脂分別硬質部は、炭素原子数16個以上の飽和脂肪酸残基を35〜55質量%含み、動物油脂分別軟質部は、炭素原子数18個以上の不飽和脂肪酸残基を45〜65質量%含むことが望ましい。これらの分別動物油脂は一度の分別処理で同時に得られた硬質部と軟質部を用いても良く、又はそれぞれ別の分別処理で得られた硬質部と軟質部を用いても差し支えない。   The animal oil / fat fractionated hard part thus obtained by fractionation treatment contains 35 to 55% by mass of saturated fatty acid residues having 16 or more carbon atoms, and the animal / fat fractionation soft part is an unsaturated fatty acid having 18 or more carbon atoms. It is desirable to contain 45-65 mass% of a residue. These fractionated animal fats and oils may use a hard part and a soft part obtained simultaneously by a single fractionation process, or may use a hard part and a soft part obtained by separate fractionation processes.

本発明に使用する混合油脂組成物(C)は、前記動物油脂の極度硬化油(A)及び前記動物油脂分別軟質部(B)を含むものであればよいが、前記動物油脂の極度硬化油(A)及び前記動物油脂分別軟質部(B)の他に、動物油脂(F)を含んでいてもよい。   The mixed oil / fat composition (C) used in the present invention may be one containing the animal oil / fat extremely hardened oil (A) and the animal oil / fat fractionated soft part (B). Animal fats and oils (F) may be included in addition to (A) and the animal fats and oils classification soft part (B).

上記動物油脂(F)としては、前述した動物油脂の中から適宜選択したものを用いることができるが、特に豚脂、牛脂が好ましい。動物油脂(F)は、動物油脂の極度硬化油(A)又は動物油脂分別軟質部(B)の原料と同じ動物油脂であってもよく、異なる動物油脂であってもよい。   As said animal fats and oils (F), what was selected suitably from the animal fats and oils mentioned above can be used, However, Pork fat and beef tallow are especially preferable. The animal oil / fat (F) may be the same animal oil / fat as the raw material of the extremely hardened oil (A) or animal oil / fat fractionated soft part (B) of the animal oil / fat, or may be a different animal oil / fat.

本発明において、混合油脂組成物(C)中における動物油脂分別軟質部(B)の含量は、5〜75質量%であることが好ましく、15〜70質量%であることがより好ましい。混合油脂組成物(C)中における動物油脂分別軟質部(B)の含量が、5質量%未満では、使用時におけるお湯への溶解性が悪くなる傾向があり、75質量%を超えると、ブルーミング防止効果およびスナップ性が低下する傾向がある。   In the present invention, the content of the animal oil / fat fractionated soft part (B) in the mixed oil / fat composition (C) is preferably 5 to 75% by mass, and more preferably 15 to 70% by mass. If the content of the animal oil / fat fractionated soft part (B) in the mixed oil / fat composition (C) is less than 5% by mass, the solubility in hot water during use tends to be poor. There exists a tendency for the prevention effect and snapping property to fall.

本発明において、混合油脂組成物(C)中における動物油脂の極度硬化油(A)の含量は、25〜70質量%であることが好ましく、30〜55質量%であることがより好ましい。混合油脂組成物(C)中における動物油脂の極度硬化油(A)の含量が、25質量%未満では、ブルーミング防止効果の低下およびスナップ性が悪くなる傾向があり、70質量%を超えると、使用時におけるお湯への溶解性が悪くなる傾向がある。本発明では、混合油脂組成物(C)の原料の1つとして動物油脂の極度硬化油(A)を用いることにより、エステル交換油(D)のトランス脂肪酸含量を低くすることができる。   In the present invention, the content of the extremely hardened oil (A) of the animal fat in the mixed fat composition (C) is preferably 25 to 70% by mass, and more preferably 30 to 55% by mass. When the content of the extremely hardened oil (A) of the animal fat in the mixed fat composition (C) is less than 25% by mass, the blooming prevention effect tends to deteriorate and the snapping property tends to deteriorate, and when it exceeds 70% by mass, There is a tendency for solubility in hot water to deteriorate during use. In the present invention, the trans fatty acid content of the transesterified oil (D) can be reduced by using the extremely hardened oil (A) of animal fat as one of the raw materials of the mixed fat composition (C).

本発明において、エステル交換の方法としては、特に制限はなく、例えば、ソジウムメチラート等のアルカリ金属触媒を用いて化学的にエステル交換を行う方法、位置特異性を有しないリパーゼ等の酵素を用いて生化学的にエステル交換を行う方法が挙げられる。   In the present invention, the transesterification method is not particularly limited. For example, a method of chemically transesterifying using an alkali metal catalyst such as sodium methylate, an enzyme such as lipase having no position specificity is used. And a method in which transesterification is performed biochemically.

本発明において、動物油脂由来の全油脂中における前記エステル交換油(D)の含量は、30〜95質量%であることが好ましく、50〜70質量%であることがより好ましい。動物油脂由来の全油脂中におけるエステル交換油(D)の含量が、30量%未満では、ブルーミング防止効果及びスナップ性が低下する傾向があり、95質量%を超えると、製造工程中のルウの固化性が悪くなり、お湯への溶解性が悪くなる傾向がある。   In the present invention, the content of the transesterified oil (D) in the total fat derived from animal fats is preferably 30 to 95% by mass, and more preferably 50 to 70% by mass. If the content of the transesterified oil (D) in the total fat derived from animal fats is less than 30% by weight, the blooming prevention effect and the snapping property tend to decrease, and if it exceeds 95% by weight, There is a tendency for the solidification property to deteriorate and the solubility in hot water to deteriorate.

本発明において、動物油脂由来の全油脂中における前記動物油脂分別硬質部(E)の含量は、5〜60質量%であることが好ましく、10〜40質量%であることがより好ましい。動物油脂由来の全油脂中における動物油脂分別硬質部(E)の含量が、5質量%未満では、製造固定中のルウの固化性が悪くなり、スナップ性が低下する傾向があり、60質量%を超えると、ブルーミング防止効果が悪くなる傾向がある。   In this invention, it is preferable that it is 5-60 mass%, and, as for the content of the said animal fat separation part (E) in all the fats derived from animal fat, it is more preferable that it is 10-40 mass%. If the content of animal oil / fat fractionated hard part (E) in the total fat / oil derived from animal oil / fat is less than 5% by mass, the solidification property of roux during production fixation tends to deteriorate, and the snapping property tends to decrease, and 60% by mass. If it exceeds, the blooming prevention effect tends to deteriorate.

本発明の固形ルウ用組成物は、前記エステル交換油(D)と、前記動物油脂分別硬質部(E)とを含むものであればよいが、更に、動物油脂(F)を含有してもよい。この動物油脂(F)としては、前述したものを用いることができる。   Although the composition for solid roux of this invention should just contain the said transesterified oil (D) and the said animal fats and oils classification hard part (E), it may contain animal fats and oils (F) further. Good. As the animal fat (F), those described above can be used.

本発明の固形ルウ用組成物には、本発明の効果を損なわない範囲で、植物油脂を含有させることができる。植物油脂としては、特に制限はなく、例えばパーム油、パーム核油、ヤシ油、なたね油、大豆油、とうもろこし油、ひまわり油、サフラワー油、ごま油、米油、オリーブ油などから得られる1種または2種以上の油脂を混合して使用することができ、更にはこれらを水素添加、分別処理、エステル交換して得られる油脂も使用することができる。   The composition for solid roux of the present invention can contain vegetable oils and fats as long as the effects of the present invention are not impaired. There is no restriction | limiting in particular as vegetable oil and fat, For example, 1 type or 2 obtained from palm oil, palm kernel oil, coconut oil, rapeseed oil, soybean oil, corn oil, sunflower oil, safflower oil, sesame oil, rice oil, olive oil etc. More than one kind of fats and oils can be mixed and used, and furthermore, fats and oils obtained by hydrogenation, fractionation and transesterification of these can also be used.

本発明の固形ルウ用組成物の原料とする動物油脂及び植物油脂のトランス脂肪酸量は、5%以下であることが好ましく、3%以下であることが更に好ましい。また、本発明の固形ルウ用組成物全体としてのトランス脂肪酸含量(g/100g)は、2%以下とされることが好ましく、1.6%以下とされることが更に好ましい。なお、本発明におけるトランス脂肪酸含量の測定は、(社)日本油化学会基準油脂分析試験法暫17−2007に従って行った。   The amount of trans fatty acids in animal fats and vegetable fats and oils used as the raw material for the composition for solid roux of the present invention is preferably 5% or less, more preferably 3% or less. In addition, the trans fatty acid content (g / 100 g) of the entire solid roux composition of the present invention is preferably 2% or less, and more preferably 1.6% or less. In addition, the measurement of the trans fatty acid content in the present invention was carried out according to Japan Oil Chemists' Society standard oil analysis test method provisional 17-2007.

本発明の即席ルウ用油脂組成物には、必要に応じてその他の成分、例えば各種乳化剤、酸化防止剤、味付け材やフレーバー等を適宜使用することができる。   Other ingredients such as various emulsifiers, antioxidants, seasonings, flavors and the like can be used as appropriate in the instant roux oil composition of the present invention as necessary.

本発明の即席ルウは、上記即席ルウ用油脂組成物を用いて製造されたものである。上記即席ルウ用油脂組成物以外の原料としては、特に限定されないが、例えば、小麦粉、澱粉等の澱粉質原料、カレー粉等の香辛料、牛乳、粉乳、チーズ等の乳製品、砂糖等の糖類、塩、グルタミン酸ナトリウム等の調味料、オニオン、ガーリックなどの野菜類、オレンジ、リンゴ、バナナなどの果実類などが挙げられ、これらの原料を用途に応じて適宜組み合わせて用いることができる。これらの原料を、加熱混合し、例えばトレー等の容器に流し込んで、冷却固化することにより、本発明の即席ルウを得ることができる。   The instant roux of the present invention is produced using the above-mentioned instant fat oil composition. The raw materials other than the instant ruo fat composition are not particularly limited, for example, starchy raw materials such as wheat flour and starch, spices such as curry powder, milk products such as milk, powdered milk and cheese, sugars such as sugar, Examples include salt, seasonings such as sodium glutamate, vegetables such as onion and garlic, fruits such as orange, apple, and banana, and these raw materials can be used in appropriate combination depending on the application. These raw materials are heated and mixed, poured into a container such as a tray, and then cooled and solidified to obtain the instant roux of the present invention.

こうして得られた本発明の即席ルウは、保管中に比較的高温になっても白色化や軟化が発生せず、常法により、カレー、シチュー、ハヤシなどのソースとしたとき、口溶けが良好で、充分なコク味を有している。   The instant roux of the present invention thus obtained does not whiten or soften even when it becomes relatively hot during storage, and when melted into a sauce such as curry, stew, or hay, it has good melting characteristics. , Has a sufficient rich taste.

以下に実施例を挙げて、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」は質量基準である。   EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to these examples. In the examples, “part” is based on mass.

<実施例1>
(1)豚脂分別硬質部及び豚脂分別軟質部の調製
豚脂脱色油(ヨウ素価58.7)を、70℃に加熱して完全に溶解し、30℃で攪拌しながら24時間晶析した。晶析後、3.0MPaでフィルタープレスし、豚脂分別硬質部(E1)及び豚脂分別軟質部(B1)を得た。
<Example 1>
(1) Preparation of pork fat fraction hard part and pork fat fraction soft part Pork fat bleaching oil (iodine value 58.7) is heated to 70 ° C to completely dissolve and crystallize for 24 hours while stirring at 30 ° C. did. After crystallization, filter press was performed at 3.0 MPa to obtain a pork fat fraction hard part (E1) and a pork fat fraction soft part (B1).

(2)ランダムエステル交換油脂の調製
豚脂を常法によりニッケル触媒を用いて硬化し、豚脂極度硬化油(ヨウ素価0.2)(A1)を作製した。
(2) Preparation of random transesterified oils and fats Pork fat was hardened by a conventional method using a nickel catalyst to produce pork fat extremely hardened oil (iodine value 0.2) (A1).

次に、上記豚脂の極度硬化油(A1)45部と、(1)で調製した豚脂分別軟質部(ヨウ素価62.7)(B1)55部とを混合し、得られた油脂混合物(C1)を90℃で30分間、真空下で脱水を行った。次いで、ナトリウムメチラート0.3部を加え、90℃、窒素気流下で30分間ランダムエステル交換反応を行い、水を加えて反応を停止し水洗した。次に、常法により活性白土を用いて脱色し、次いで脱臭を行い、ランダムエステル交換油(D1)を作製した。   Next, 45 parts of the extremely hardened oil (A1) of the above pork fat and 55 parts of the pork fat fractionated soft part (iodine value 62.7) (B1) prepared in (1) were mixed, and the resulting fat mixture (C1) was dehydrated under vacuum at 90 ° C. for 30 minutes. Next, 0.3 part of sodium methylate was added, and a random transesterification reaction was performed at 90 ° C. under a nitrogen stream for 30 minutes. Water was added to stop the reaction and wash with water. Next, decolorization was performed using activated clay according to a conventional method, followed by deodorization to produce a random transesterified oil (D1).

(3)油脂組成物の調製
(1)で調製した豚脂分別硬質部(ヨウ素価52.1)(E1)30部と、(2)で作製したランダムエステル交換油(D1)50部と、豚脂(F1)20部とを混合し、固形ルウ用油脂組成物を作製した。
(3) Preparation of oil and fat composition 30 parts of pork fat fraction hard part (iodine value 52.1) (E1) prepared in (1), 50 parts of random transesterified oil (D1) prepared in (2), 20 parts of pork fat (F1) was mixed to prepare a fat oil composition for solid roux.

<実施例2>
実施例1で作製した豚脂分別硬質部(E1)10部と、ランダムエステル交換油(D1)50部と、豚脂(F1)40部を混合し、固形ルウ用油脂組成物を作製した。
<Example 2>
10 parts of pork fat fraction hard part (E1) produced in Example 1, 50 parts of random transesterified oil (D1), and 40 parts of pork fat (F1) were mixed to prepare an oil composition for solid roux.

<実施例3>
実施例1で作製した豚脂分別軟質部(B1)15部と、豚脂極度硬化油(A1)35部と、豚脂(F1)50部とを混合し、得られた油脂混合物(C2)を用いて実施例1と同様にしてランダムエステル交換反応を行って、ランダムエステル交換油(D2)を作製した。実施例1で作製した豚脂分別硬質部(E1)40部と前記ランダムエステル交換油(D2)60部とを混合し、固形ルウ用油脂組成物を作製した。
<Example 3>
The fat and oil mixture (C2) obtained by mixing 15 parts of pork fat fraction soft part (B1) prepared in Example 1, 35 parts of pork fat hardened oil (A1) and 50 parts of pork fat (F1). A random transesterification reaction was carried out in the same manner as in Example 1 to prepare a random transesterified oil (D2). 40 parts of pork fat fraction hard part (E1) produced in Example 1 and 60 parts of the random transesterified oil (D2) were mixed to produce an oil composition for solid roux.

<実施例4>
実施例1で作製した豚脂分別硬質部(E1)20部と、実施例3で作製したランダムエステル交換油(D2)60部と、豚脂(F1)20とを混合し、固形ルウ用油脂組成物を作製した。
<Example 4>
20 parts of the pork fat fraction hard part (E1) produced in Example 1, 60 parts of the random transesterified oil (D2) produced in Example 3, and pork fat (F1) 20 are mixed, and the fat and oil for solid roux A composition was prepared.

<実施例5>
実施例1で作製した豚脂分別硬質部(E1)5部と、実施例3で作製したランダムエステル交換油(D2)95部とを混合し、固形ルウ用油脂組成物を作製した。
<Example 5>
5 parts of the pork fat fraction hard part (E1) produced in Example 1 and 95 parts of the random transesterified oil (D2) produced in Example 3 were mixed to produce an oil composition for solid roux.

<実施例6>
実施例1で作製した豚脂分別硬質部(E1)60部と、ランダムエステル交換油(D1)30部と、豚脂(F1)10部とを混合し、固形ルウ用油脂組成物を作製した。
<Example 6>
60 parts of pork fat fraction hard part (E1) produced in Example 1, 30 parts of random transesterified oil (D1), and 10 parts of pork fat (F1) were mixed to produce an oil composition for solid roux. .

<実施例7>
(1)牛脂分別硬質部及び牛脂分別軟質部の調製
牛脂脱色油(ヨウ素価49.0)を、70℃に加熱して完全に溶解し、30℃で攪拌しながら24時間晶析した。晶析後、3.0MPaでフィルタープレスし、牛脂分別硬質部(E2)及び豚脂分別軟質部(B2)を得た。
<Example 7>
(1) Preparation of beef tallow fractionated hard part and beef tallow fraction soft part Tallow decolorized oil (iodine value 49.0) was heated to 70 ° C and completely dissolved, and crystallized for 24 hours while stirring at 30 ° C. After crystallization, filter press was performed at 3.0 MPa to obtain a beef tallow fraction hard part (E2) and a pork tart fraction soft part (B2).

(2)ランダムエステル交換油脂の調製
牛脂を常法によりニッケル触媒を用いて硬化し、牛脂極度硬化油(ヨウ素価0.2)(A2)を作製した。
(2) Preparation of Random Transesterified Oils and Fats Tallow was cured by a conventional method using a nickel catalyst to prepare beef tallow extremely hardened oil (iodine value 0.2) (A2).

次に、上記牛脂の極度硬化油(A2)40部と、(1)で調製した牛脂分別軟質部(ヨウ素価53.4)(B2)60部とを混合し、得られた油脂混合物(C3)を用いて実施例1と同様にしてランダムエステル交換反応を行って、ランダムエステル交換油(D3)を作製した。   Next, 40 parts of the beef tallow extremely hardened oil (A2) and 60 parts of the beef tallow fractionated soft part (iodine value 53.4) (B2) prepared in (1) were mixed, and the resulting fat mixture (C3 ) Was used in the same manner as in Example 1 to produce a random transesterification oil (D3).

(3)油脂組成物の調製
(1)で調製した牛脂分別硬質部(ヨウ素価44.1)(E2)10部と、(2)で作製したランダムエステル交換油(D3)60部と、牛脂(F2)30部とを混合し、固形ルウ用油脂組成物を作製した。
(3) Preparation of oil / fat composition 10 parts of beef tallow fraction hard part (iodine value 44.1) (E2) prepared in (1), 60 parts of random transesterified oil (D3) prepared in (2), and beef tallow (F2) 30 parts was mixed to prepare an oil composition for solid roux.

<比較例1>
実施例1で作製した豚脂極度硬化油(A1)45部と、豚脂(F1)55部とを混合し、得られた油脂組成物(C4)を用いて実施例1と同様にしてランダムエステル交換油(D4)を作製した。豚脂(F1)50部と、前記ランダムエステル交換油(D4)50部とを混合し、得固形ルウ用油脂組成物を得た。
<Comparative Example 1>
45 parts of pork fat hardened oil (A1) prepared in Example 1 and 55 parts of pork fat (F1) were mixed and randomly obtained in the same manner as in Example 1 using the resulting oil composition (C4). A transesterified oil (D4) was produced. 50 parts of pork fat (F1) and 50 parts of the random transesterified oil (D4) were mixed to obtain an oil composition for solid roux.

<比較例2>
実施例1で作製した豚脂分別硬質部(E1)20部と、比較例1で作製したランダムエステル交換油(D4)50部と、豚脂(F1)30部とを混合し、固形ルウ用油脂組成物を得た。
<Comparative Example 2>
20 parts of pork fat fraction hard part (E1) produced in Example 1, 50 parts of random transesterified oil (D4) produced in Comparative Example 1, and 30 parts of pork fat (F1) are mixed and used for solid roux An oil and fat composition was obtained.

<比較例3>
実施例3で作製したランダムエステル交換油(D2)95部と、豚脂(F1)5部とを混合し、固形ルウ用油脂組成物を得た。
<Comparative Example 3>
95 parts of random transesterified oil (D2) produced in Example 3 and 5 parts of pork fat (F1) were mixed to obtain an oil composition for solid roux.

<比較例4>
実施例1で作製した豚脂分別硬質部(E1)80部と、ランダムエステル交換油(D1)20部とを混合し、固形ルウ用油脂組成物を作製した。
<Comparative Example 4>
80 parts of pork fat fraction hard part (E1) produced in Example 1 and 20 parts of random transesterified oil (D1) were mixed to produce an oil composition for solid roux.

<比較例5>
実施例1で作製したランダムエステル交換油(D1)100を固形ルウ用油脂組成物とした。
<Comparative Example 5>
Random transesterified oil (D1) 100 produced in Example 1 was used as an oil composition for solid roux.

<比較例6>
実施例1で作製した豚脂分別硬質部(E1)60部と、ランダムエステル交換油(D1)20部と豚脂(F1)20部を混合し、固形ルウ用油脂組成物を作製した。
<Comparative Example 6>
60 parts of pork fat fraction hard part (E1) produced in Example 1, 20 parts of random transesterified oil (D1), and 20 parts of pork fat (F1) were mixed to produce an oil composition for solid roux.

<比較例7>
実施例7で作製したランダムエステル交換油(D4)60部と、牛脂(F2)40部を混合し、固形ルウ用油脂組成物を作製した。
<Comparative Example 7>
60 parts of the random transesterified oil (D4) prepared in Example 7 and 40 parts of beef tallow (F2) were mixed to prepare an oil composition for solid roux.

<比較例8>
(1)ランダムエステル交換油脂の調製
実施例7で作製した牛脂の極度硬化油(A2)40部と、牛脂(F2)60部とを混合し、得られた油脂混合物(C5)を用いて実施例1と同様にしてランダムエステル交換反応を行って、ランダムエステル交換油(D5)を作製した。
<Comparative Example 8>
(1) Preparation of random transesterified fats and oils 40 parts of beef tallow extremely hardened oil (A2) prepared in Example 7 and 60 parts of beef tallow (F2) were mixed, and the resulting fat and oil mixture (C5) was used. A random transesterification reaction was performed in the same manner as in Example 1 to prepare a random transesterified oil (D5).

(2)油脂組成物の調製
実施例7で作製した牛脂分別硬質部(E2)10部と、(1)で作製したランダムエステル交換油(D5)60部と、牛脂(F2)30部とを混合し、固形ルウ用油脂組成物を作製した。
(2) Preparation of oil and fat composition 10 parts of beef tallow fraction hard part (E2) produced in Example 7, 60 parts of random transesterified oil (D5) produced in (1), and 30 parts of beef tallow (F2) It mixed and the fats and oils composition for solid roux was produced.

<比較例9>
比較例8で作製したランダムエステル交換油(D5)60部と、牛脂(F2)40部とを混合し、固形ルウ用油脂組成物を作製した。
<Comparative Example 9>
60 parts of random transesterified oil (D5) prepared in Comparative Example 8 and 40 parts of beef tallow (F2) were mixed to prepare an oil composition for solid roux.

<特性評価>
下記表1に、上記実施例1〜7、比較例1〜9におけるランダムエステル交換油の原料油脂配合と、トランス脂肪酸含量と、SFC(固体脂含量)とを示した。
<Characteristic evaluation>
Table 1 below shows the raw oil and fat composition of the random transesterified oil, the trans fatty acid content, and the SFC (solid fat content) in Examples 1 to 7 and Comparative Examples 1 to 9.

また、下記表2、3に、上記実施例1〜7、比較例1〜9で得られた固形ルウ用油脂組成物の原料油脂配合と、トランス脂肪酸含量と、SFC(固体脂含量)とを示した。   In Tables 2 and 3 below, the raw oil composition of the oil composition for solid roux obtained in Examples 1-7 and Comparative Examples 1-9, trans fatty acid content, and SFC (solid fat content) are shown. Indicated.

なお、表中のSFC(固体脂含量)とは、所定の温度(表中に示された温度)における固体脂含量(質量%)のことである。SFC(固体脂含量)は、IUPAC法2.150a Solid Content determination in Fats by NMRに準じて測定した。   In addition, SFC (solid fat content) in a table | surface is solid fat content (mass%) in predetermined | prescribed temperature (temperature shown in the table | surface). SFC (solid fat content) was measured according to IUPAC method 2.150a Solid Content determination in Fats by NMR.

<試験例>
(1)カレールウの調製
実施例1〜7、比較例1〜9で得られた固形ルウ用油脂組成物300部、小麦粉300部、糖類50部、食塩30部、カレー粉200部、調味ペースト30部を平鍋にとり、120℃で30分間混合した後、品温が60℃になるまで冷却した。次に、ポリプロピレン製のトレーにルウを流し入れ、−10℃、−5℃、0℃、5℃、10℃、15℃の各温度帯で30分間保持し、その後20℃で一晩保持して固化した。
<Test example>
(1) Preparation of curry roux 300 parts solid fat oil composition obtained in Examples 1-7 and Comparative Examples 1-9, 300 parts flour, 50 parts sugar, 30 parts salt, 200 parts curry powder, seasoning paste 30 The portion was placed in a flat pan, mixed at 120 ° C. for 30 minutes, and then cooled until the product temperature reached 60 ° C. Next, pour into a polypropylene tray and hold at −10 ° C., −5 ° C., 0 ° C., 5 ° C., 10 ° C. and 15 ° C. for 30 minutes, and then hold at 20 ° C. overnight. Solidified.

(2)カレールウの固化性試験
上記(1)で調製した各カレールウを切断し、断面を肉眼観察して固形物の沈殿状態を評価した。得られた結果を下記表4,5に示す。なお、固形物の沈殿状態は、下記基準によって評価した。
◎:固形分の沈殿が全くなし
○:固形分の沈殿がわずかにあり
△:固形分の沈殿が少しあり
×:固形分の沈殿が多い
(2) Solidification test of curry roux Each curry roux prepared in the above (1) was cut and the cross section was observed with the naked eye to evaluate the precipitation state of the solid matter. The obtained results are shown in Tables 4 and 5 below. In addition, the precipitation state of the solid substance was evaluated according to the following criteria.
A: There is no solid content precipitation. ○: There is a slight solid content precipitation. Δ: There is a little solid content precipitation.

(3)カレールウのブルーミング、スナップ性、溶解性
上記(1)の5℃30分の冷却条件で調製したカレールウについて、ブルーミング、スナップ性、溶解性を評価した。得られた結果を下記表6,7に示す。
(3) Blooming, snapping property and solubility of Caraleu The blooming, snapping property and solubility were evaluated for the Caraleu prepared under the cooling condition of 5 ° C for 30 minutes as described in (1) above. The obtained results are shown in Tables 6 and 7 below.

なお、それぞれの評価基準は、下記の通りである。
(ブルーミング)
◎:ブルーミングが全くなし
○:ブルーミングがわずかにあり
△:ブルーミングが少しあり
×:ブルーミングが多数あり
(スナップ性)
固形ルウを、20℃に調温した後、手での折りやすさを下記基準で評価した。
◎:とても良い
○:良い
△:やや悪い
×:悪い
(溶解性)
◎:お湯(60℃)への溶解性がとても良い
○:お湯(60℃)への溶解性が良い
△:お湯(60℃)への溶解性がやや悪い
×:お湯(60℃)への溶解性が悪い
Each evaluation standard is as follows.
(Blooming)
◎: No blooming ○: Slight blooming △: Slight blooming ×: Lots of blooming (snap)
After adjusting the solid roux to 20 ° C., the ease of folding by hand was evaluated according to the following criteria.
◎: Very good ○: Good △: Slightly bad ×: Poor (solubility)
◎: Very good solubility in hot water (60 ° C) ○: Good solubility in hot water (60 ° C) △: Slightly poor solubility in hot water (60 ° C) ×: Insoluble in hot water (60 ° C) Poor solubility

表4〜7に示したように、実施例1〜7の油脂組成物を用いて作製したルウは、動物油脂の分別軟質部と動物油脂極度硬化油を一定の割合以上含有する油脂組成物を、ランダムエステル交換してランダムエステル交換油脂(D1,D2,D3)を作製し、前記ランダムエステル交換油脂(D1,D2,D3)と動物油脂を分別処理して作製した動物油脂の分別硬質部(E1,E2)を一定の割合以上含有する油脂組成物からなるため、固化性がとても良く、ブルーミング防止効果やスナップ性に優れるものであり、60℃のお湯への溶解性がとても良いものとなった。   As shown in Tables 4 to 7, the roux produced using the oil and fat compositions of Examples 1 to 7 contains an oil and fat composition containing a certain proportion or more of a fractionated soft part of animal oil and fat and an extremely hardened oil of animal oil and fat. Random transesterification to produce random transesterified fats and oils (D1, D2, D3), and fractionated hard parts of animal fats and oils produced by separating the random transesterified fats and oils (D1, D2, D3) and animal fats ( Since it is composed of an oil and fat composition containing a certain proportion of E1, E2), it has excellent solidification properties, excellent blooming prevention effects and snapping properties, and very good solubility in hot water at 60 ° C. It was.

これに対して、動物油脂の極度硬化油と動物油脂とを混合し、ランダムエステル交換してランダムエステル交換油脂(D4, D5)を作製し、前記ランダムエステル交換油脂(D4, D5)を含む油脂組成物を用いて作製した比較例1、比較例2、比較例8、比較例9のルウは、60℃のお湯への溶解性が悪かった。   On the other hand, extremely hardened oil of animal fats and oils are mixed, and random transesterification is performed to produce random transesterified fats and oils (D4, D5), and the fats and oils containing the random transesterified fats (D4, D5) The rouxes of Comparative Example 1, Comparative Example 2, Comparative Example 8, and Comparative Example 9 produced using the composition had poor solubility in hot water at 60 ° C.

また、動物油脂の分別硬質部を含有しない油脂組成物を用いて作製した比較例1、比較例3、比較例5、比較例7、比較例9のルウは固化性が悪く、スナップ性も劣るものとなった。
動物油脂の分別硬質部を一定の割合以上含む油脂組成物を用いて作製した比較例2、比較例4、比較例6、比較例8のルウは固化性に優れるが、硬質部が60質量%よりも多く含まれる比較例4はブルーミング防止効果が劣るものとなった。
ランダムエステル交換油を一定の割合以上含む油脂組成物を用いて作製した比較例1、比較例2、比較例3、比較例5、比較例8、比較例9はブルーミング防止効果に優れるが、ランダムエステル交換油脂の割合が30質量%よりも低い油脂組成物を用いた比較例4、比較例6のルウはブルーミング防止効果が劣るものとなった。
Moreover, the rouxes of Comparative Example 1, Comparative Example 3, Comparative Example 5, Comparative Example 7, Comparative Example 9 and Comparative Example 9 produced using an oil / fat composition not containing a fractionated hard part of animal oil / fat have poor solidification properties and inferior snapping properties. It became a thing.
The rouxes of Comparative Example 2, Comparative Example 4, Comparative Example 6, and Comparative Example 8 prepared using an oil and fat composition containing a certain proportion or more of the fractionated hard part of animal fats and oils are excellent in solidification properties, but the hard part is 60% by mass. The comparative example 4 contained more than it was inferior in the blooming prevention effect.
Comparative Example 1, Comparative Example 2, Comparative Example 3, Comparative Example 3, Comparative Example 5, Comparative Example 8, and Comparative Example 9 prepared using an oil and fat composition containing a certain proportion or more of a random transesterified oil are excellent in the blooming prevention effect. The roux of the comparative example 4 and the comparative example 6 using the oil-fat composition whose ratio of transesterified oil and fat is lower than 30 mass% became inferior in blooming prevention effect.

Claims (9)

動物油脂の極度硬化油(A)及び動物油脂を分別処理して得られる動物油脂分別軟質部(B)からなる混合油脂組成物(C)を、エステル交換して得られるエステル交換油(D)と、動物油脂を分別処理して得られる動物油脂分別硬質部(E)とを含み、動物油脂由来の全油脂中における、前記エステル交換油(D)の含量が30〜95質量%であり、前記動物油脂分別硬質部(E)の含量が5〜60質量%であることを特徴とする固形ルウ用油脂組成物。 Extremely hydrogenated oil of animal fats (A) and animal fats soft fractionated portion of the animal fat obtained by fractionating (B) mixtures fat composition consisting of (C) a transesterification oil obtained by transesterification (D) When, viewed contains animal fat fractionation hard part obtained by fractionating the animal fats and (E), in all fat in animal-derived fat and oil, the content of the interesterified oil (D) is 30 to 95 wt% The oil / fat composition for solid roux , wherein the content of the animal oil / fat fractionated hard part (E) is 5 to 60% by mass . 動物油脂の極度硬化油(A)、動物油脂を分別処理して得られる動物油脂分別軟質部(B)、及び動物油脂(F)からなる混合油脂組成物(C)を、エステル交換して得られるエステル交換油(D)と、動物油脂を分別処理して得られる動物油脂分別硬質部(E)とを含み、動物油脂由来の全油脂中における、前記エステル交換油(D)の含量が30〜95質量%であり、前記動物油脂分別硬質部(E)の含量が5〜60質量%であることを特徴とする固形ルウ用油脂組成物。 Obtained by transesterification of a mixed oil / fat composition (C) consisting of an extremely hardened oil (A) of animal fats and oils, an animal oil / fat fractionated soft part (B) obtained by fractionating animal fats and oils (F) The transesterified oil (D) and the animal oil / fat fractionated hard part (E) obtained by fractionating the animal oil / fat, the content of the transesterified oil (D) in the total oil / fat derived from the animal oil / fat is 30. It is -95 mass%, The content of the said animal oil-fat classification hard part (E) is 5-60 mass%, The oil-fat composition for solid roux characterized by the above-mentioned . 前記エステル交換油(D)と、前記動物油脂分別硬質部(E)と、動物油脂(F)とを含む、請求項1又は2記載の固形ルウ用油脂組成物。   The oil composition for solid roux according to claim 1 or 2, comprising the transesterified oil (D), the animal oil / fat fractionated hard part (E), and the animal oil / fat (F). 前記混合油脂組成物(C)中における前記動物油脂分別軟質部(B)の含量が5〜75質量%である、請求項1〜のいずれか1つに記載の固形ルウ用油脂組成物。 The fat and oil composition for solid roux according to any one of claims 1 to 3 , wherein the content of the animal fat and oil fractionated soft part (B) in the mixed fat and oil composition (C) is 5 to 75 mass%. 前記混合油脂組成物(C)中における前記動物油脂の極度硬化油(A)の含量が25〜70質量%である、請求項1〜のいずれか1つに記載の固形ルウ用油脂組成物。 The fat and oil composition for solid roux according to any one of claims 1 to 4 , wherein the content of the extremely hardened oil (A) of the animal fat and oil in the mixed fat and oil composition (C) is 25 to 70% by mass. . 前記動物油脂分別硬質部(E)が、動物油脂の分別処理の際に、硬質部と軟質部との質量比が30:70〜70:30になるように分別処理した硬質部からなる、請求項1〜のいずれか1つに記載の固形ルウ用油脂組成物。 The animal oil / fat fractionated hard part (E) comprises a hard part that has been subjected to a fractionation process so that the mass ratio of the hard part to the soft part is 30:70 to 70:30 during the animal oil / fat fractionation process. Item 6. The fat and oil composition for solid roux according to any one of items 1 to 5 . 前記動物油脂分別軟質部(B)が、動物油脂の分別処理の際に、硬質部と軟質部との質量比が30:70〜70:30になるように分別処理した軟質部からなる、請求項1〜のいずれか1つに記載の固形ルウ用油脂組成物。 The animal oil / fat fractionated soft part (B) comprises a soft part that has been fractionated so that the mass ratio of the hard part to the soft part is 30:70 to 70:30 during the animal oil / fat fractionation process. Item 7. The fat and oil composition for solid roux according to any one of items 1 to 6 . トランス脂肪酸含量が2%以下である、請求項1〜のいずれか1つに記載の固形ルウ用油脂組成物。 The fat and oil composition for solid roux according to any one of claims 1 to 7 , wherein the trans fatty acid content is 2% or less. 前記請求項1〜のいずれか1つに示した油脂組成物を含有することを特徴とする固形ルウ。
A solid roux comprising the oil or fat composition according to any one of claims 1 to 8 .
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JP2006160906A (en) * 2004-12-08 2006-06-22 Asahi Denka Kogyo Kk Plastic composition of fat and oil
JP2006197884A (en) * 2005-01-24 2006-08-03 House Foods Corp Instant cooked food
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JP2014050343A (en) * 2012-09-06 2014-03-20 Tsukishima Foods Industry Co Ltd Instant roux fat composition and instant roux using the same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000204389A (en) * 1999-01-14 2000-07-25 Kanegafuchi Chem Ind Co Ltd Fractionation of lard
JP2001238597A (en) * 2000-03-02 2001-09-04 Kanegafuchi Chem Ind Co Ltd Plastic oil and fat
JP2006160906A (en) * 2004-12-08 2006-06-22 Asahi Denka Kogyo Kk Plastic composition of fat and oil
JP2006197884A (en) * 2005-01-24 2006-08-03 House Foods Corp Instant cooked food
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JP2014050343A (en) * 2012-09-06 2014-03-20 Tsukishima Foods Industry Co Ltd Instant roux fat composition and instant roux using the same

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