JP2001252043A - Paprika coloring matter preparation - Google Patents

Paprika coloring matter preparation

Info

Publication number
JP2001252043A
JP2001252043A JP2000065869A JP2000065869A JP2001252043A JP 2001252043 A JP2001252043 A JP 2001252043A JP 2000065869 A JP2000065869 A JP 2000065869A JP 2000065869 A JP2000065869 A JP 2000065869A JP 2001252043 A JP2001252043 A JP 2001252043A
Authority
JP
Japan
Prior art keywords
paprika
pigment preparation
mass
saib
emulsified particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000065869A
Other languages
Japanese (ja)
Other versions
JP3556877B2 (en
Inventor
Tetsuya Nakamura
哲也 中村
Mitsuhide Yokoyama
光英 横山
Hayato Hori
速人 堀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
T Hasegawa Co Ltd
Original Assignee
T Hasegawa Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by T Hasegawa Co Ltd filed Critical T Hasegawa Co Ltd
Priority to JP2000065869A priority Critical patent/JP3556877B2/en
Publication of JP2001252043A publication Critical patent/JP2001252043A/en
Application granted granted Critical
Publication of JP3556877B2 publication Critical patent/JP3556877B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To obtain a paprika coloring matter preparation having no breakage of emulsified particles when added to various kneaded foods, capable of imparting more intense red color to the various kneaded foods, and also having no bad smell. SOLUTION: This paprika coloring matter preparation is obtained by dispersing emulsified particles comprising a paprika oleoresin and a sucrose diacetate hexaisobutyrate (SAIB) in an aqueous system containing an emulsifier.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、食品着色用パプリ
カ色素製剤に関し、更に詳しくは、各種混練食品を赤色
系に着色することができるパプリカ色素製剤に関する。
The present invention relates to a paprika pigment preparation for coloring foods, and more particularly to a paprika pigment preparation capable of coloring various kneaded foods red.

【0002】[0002]

【従来の技術】従来、パプリカ(Capsicum annum L.)
の果実やその乾燥物をアルコール類、ケトン類、ハロゲ
ン化炭化水素類などの溶媒で抽出した抽出物から溶媒を
除去したいわゆるパプリカオレオレジンを、例えば、食
品着色剤として利用することは知られている。また、該
パプリカオレオレジンに含まれるパプリカ特有の香味を
除去するため、例えば、アルコール抽出、水蒸気蒸留、
アルカリ処理、超臨界二酸化炭素抽出などによるパプリ
カ色素の精製が行われている。
2. Description of the Related Art Conventionally, paprika (Capsicum annum L.)
It is known to use so-called paprika oleoresin obtained by removing the solvent from an extract obtained by extracting a fruit or its dried product with a solvent such as alcohols, ketones, and halogenated hydrocarbons, for example, as a food coloring agent. I have. Further, in order to remove the flavor peculiar to paprika contained in the paprika oleoresin, for example, alcohol extraction, steam distillation,
Purification of paprika dyes by alkali treatment, supercritical carbon dioxide extraction, and the like has been performed.

【0003】しかしながら、パプリカ色素を利用して例
えば、各種混練食品を着色する際には、パプリカ色素特
有のオレンジ色の色調が強い影響を与えたり、着色する
食品によっては、その製造工程で色の変化が起きてしま
い必ずしも加工食品で計画している色調に合致しない場
合がある。特に、最近はより赤色味の強い色調が求めら
れ、該色調を長期間に渡って安定に保つことができる改
善されたパプリカ色素製剤の出現が望まれている。この
赤色味の強い色調に着色するためには、例えば、より赤
色味の強いパプリカオレオレジンによって製造されたパ
プリカ色素製剤を使用することが考えられるが、パプリ
カオレオレジンの色調は原料産地や産出年度によって変
動するため、常により赤色味の強い同一色調のパプリカ
オレオレジンを得ることは困難である。
However, when coloring various kneaded foods using paprika pigments, for example, the orange color tone peculiar to the paprika pigments has a strong influence, and depending on the foodstuff to be colored, the color may not be produced during the production process. Changes may occur and may not always match the planned color for processed foods. In particular, a color tone with a stronger red color has recently been required, and the appearance of an improved paprika pigment preparation capable of maintaining the color tone stably for a long period of time has been desired. In order to color this reddish color tone, for example, it is conceivable to use a paprika oleoresin produced by a more reddish paprika oleoresin. Therefore, it is difficult to always obtain paprika oleoresin of the same color with a stronger red color.

【0004】そこで、パプリカオレオレジン自体の色調
に依存されることなく、食品を強い赤色味に着色できる
ような食品着色用パプリカ色素製剤を提供することを目
的として、例えば、植物樹脂とパプリカオレオレジンと
を含有した乳化粒子が、乳化剤を含有する水性系中に分
散した食品着色用パプリカ色素製剤(特開平5−316
995号公報)が提案されている。
Therefore, in order to provide a paprika oleoresin for coloring food, which is capable of coloring a food with a strong red color irrespective of the color tone of paprika oleoresin itself, for example, a plant resin and paprika oleoresin are used. A paprika pigment preparation for coloring foodstuffs, in which emulsified particles containing the same are dispersed in an aqueous system containing an emulsifier (JP-A-5-316)
No. 995).

【0005】[0005]

【発明が解決しようとする課題】しかしながら、上述し
た特開平5−316995号公報で製造されたパプリカ
色素製剤は混練食品に安定かつ良好な赤色系着色を付与
することができるが、使用している植物樹脂由来の樹脂
臭が混練食品に移行するという問題があり、必ずしも満
足できるものではない。従って本発明の目的は、食品を
強い赤色味に着色することができ、かつ異臭のないパプ
リカ色素製剤を提供することである。
However, the paprika pigment preparation produced in the above-mentioned JP-A-5-316995 can impart a stable and good reddish color to kneaded foods, but it is used. There is a problem that the resin odor derived from vegetable resin is transferred to the kneaded food, which is not always satisfactory. Accordingly, an object of the present invention is to provide a paprika pigment preparation which can color foods with a strong red color and has no off-flavor.

【0006】[0006]

【課題を解決するための手段】本発明者等は、上述の課
題を解決するため鋭意研究を行なった結果、乳化液中の
乳化粒子を、パプリカオレオレジンなどのパプリカ色素
成分にシュークロース・ジアセテート・ヘキサイソブチ
レート(以下、SAIBと称する)を加えたものとし、
しかも該乳化粒子の平均サイズを3〜40ミクロンの範
囲とすることにより乳化粒子の強度を高めることがで
き、各種混練食品に添加したときに乳化粒子の破壊がな
く、より強い赤色味を長期間に渡って付与することがで
き、かつ異臭のないパプリカ色素製剤を調製できること
を見出し本発明を完成した。なお、SAIBは一般的に
飲料用乳化製剤の比重調整用に用いられるが、混練食品
の着色用色素製剤の安定化に用いることについてはこれ
まで開示も示唆もされていない。
Means for Solving the Problems The inventors of the present invention have conducted intensive studies to solve the above-mentioned problems, and as a result, the emulsified particles in the emulsified solution have been added to a paprika dye component such as paprika oleoresin. Acetate hexaisobutyrate (hereinafter referred to as SAIB),
Moreover, by setting the average size of the emulsified particles in the range of 3 to 40 microns, the strength of the emulsified particles can be increased, and when added to various kneaded foods, there is no destruction of the emulsified particles, and a stronger red taste can be obtained for a long time The present invention has been found that a paprika pigment preparation having no off-flavor can be prepared, and the present invention has been completed. In addition, SAIB is generally used for adjusting the specific gravity of an emulsified preparation for beverages, but it has not been disclosed or suggested to use it for stabilizing a coloring preparation for coloring kneaded foods.

【0007】即ち、本発明の第1の発明はパプリカ色素
成分とSAIBからなるパプリカ色素製剤である。
That is, the first invention of the present invention is a paprika pigment preparation comprising a paprika pigment component and SAIB.

【0008】第2の発明は、パプリカオレオレジンとS
AIBとを含有した乳化粒子が、乳化剤を含有する水性
系中に分散してなるパプリカ色素製剤である。
[0008] The second invention relates to paprika oleoresin and S
This is a paprika pigment preparation in which emulsified particles containing AIB are dispersed in an aqueous system containing an emulsifier.

【0009】第3の発明は、第2の発明のパプリカ色素
製剤について、乳化粒子の平均粒子サイズを着色の色調
に応じて選択したものである。
According to a third aspect, in the paprika pigment preparation of the second aspect, the average particle size of the emulsified particles is selected according to the color tone.

【0010】第4の発明は、第2または第3の発明のパ
プリカ色素製剤について、乳化粒子の平均粒子サイズが
3〜40ミクロンであるものである。
In a fourth aspect, the paprika pigment preparation of the second or third aspect has an average particle size of emulsified particles of 3 to 40 microns.

【0011】[0011]

【発明の実施の形態】以下に、本発明の具体的態様につ
いて説明する。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, specific embodiments of the present invention will be described.

【0012】本発明で用いるパプリカ色素成分として
は、パプリカオレオレジン及びパプリカオレオレジンか
ら各種の処理によりパプリカ臭を除去したものを使用す
ることができる。即ち例えば、パプリカの果実の乾燥粉
砕物に、アセトン、n−ペンタン、n−ヘキサン、メチ
レンクロライド、エチレンジクロライドなどの如き有機
溶剤を加えて抽出した後、有機溶剤相を分離し、常圧乃
至減圧下で該有機溶剤を留去させるなどの手段で得るこ
とができる。また、該パプリカオレオレジンからパプリ
カ臭を除去する手段としては、例えば、アルコール抽
出、水蒸気蒸留、アルカリ処理、超臨界二酸化炭素抽出
などを例示することができる。
As the paprika oleoresin used in the present invention, paprika oleoresin or a product obtained by removing paprika odor from paprika oleoresin by various treatments can be used. That is, for example, an organic solvent such as acetone, n-pentane, n-hexane, methylene chloride, ethylene dichloride, etc. is added to the dried and ground paprika fruit and extracted, the organic solvent phase is separated, and the pressure is reduced from normal pressure to reduced pressure. The organic solvent can be obtained by distilling off the organic solvent below. Examples of means for removing paprika odor from the paprika oleoresin include alcohol extraction, steam distillation, alkali treatment, and supercritical carbon dioxide extraction.

【0013】本発明では、上記例示のパプリカオレオレ
ジンにSAIBを混合するが、SAIBの使用量は乳化
粒子のサイズに影響を与え、その使用量はパプリカオレ
オレジン1質量部に対して、例えば、0.01〜10質
量部の範囲、好ましくは0.05〜5質量部の範囲内を
例示することができる。SAIBの使用量が0.01質
量部未満では乳化粒子の安定性が悪く、SAIBの使用
量が10質量部を超える量では赤色味を付与することが
困難である。
In the present invention, SAIB is mixed with the above-mentioned paprika oleoresin. The amount of SAIB affects the size of the emulsified particles, and the amount of SAIB is, for example, 1 part by mass of paprika oleoresin. A range of 0.01 to 10 parts by mass, preferably a range of 0.05 to 5 parts by mass can be exemplified. If the amount of SAIB is less than 0.01 part by mass, the stability of the emulsified particles is poor, and if the amount of SAIB exceeds 10 parts by mass, it is difficult to impart a reddish tint.

【0014】本発明のパプリカ色素製剤は乳化粒子の平
均サイズによって、例えば、約1〜3ミクロンのときは
オレンジ色、40ミクロンのときは赤紫色、これらの中
間粒子径ではその中間の色調のものがそれぞれ得られる
ことになるので、目的とする色調に応じて乳化粒子径を
選択し、それに応じた量のSAIBを添加する。
The paprika pigment preparation of the present invention has, depending on the average size of the emulsified particles, for example, an orange color at about 1 to 3 microns, a reddish purple at 40 microns, and an intermediate color at these intermediate particle diameters. Are respectively obtained, so that the emulsified particle size is selected according to the desired color tone, and SAIB is added in an amount corresponding thereto.

【0015】パプリカオレオレジンとSAIBの混合物
の乳化液の形成には、乳化剤及び増粘物質が利用され
る。乳化剤としては、例えば、キラヤ抽出物、酵素処理
レシチン、ショ糖脂肪酸エステル、ポリグリセリン脂肪
酸エステル、グリセリン脂肪酸エステル、アラビアガ
ム、サイクロデキストリンなどを挙げることができる。
これらの乳化剤は単独で、或いは複数種を組み合わせて
使用することができ、乳化剤は通常水溶液の状態で使用
される。乳化剤の使用量は、乳化剤の種類によって適宜
選択できるが、例えば、水溶液が0.1〜50質量%の
濃度範囲を例示することができる。
An emulsifier and a thickener are used to form an emulsion of a mixture of paprika oleoresin and SAIB. Examples of the emulsifier include Kiraya extract, enzyme-treated lecithin, sucrose fatty acid ester, polyglycerin fatty acid ester, glycerin fatty acid ester, gum arabic, cyclodextrin and the like.
These emulsifiers can be used alone or in combination of two or more, and the emulsifier is usually used in the form of an aqueous solution. The use amount of the emulsifier can be appropriately selected depending on the type of the emulsifier, and for example, the concentration range of the aqueous solution can be exemplified as 0.1 to 50% by mass.

【0016】また、増粘物質としては、例えば、アルギ
ン酸ナトリウム、寒天、カラギーナン、ローカストビー
ンガム、グアーガム、キサンタンガム、ペクチン、CM
Cなどのような多糖類を好ましく例示することができ
る。これらの増粘物質は単独でも、或いは複数種を組み
合わせて使用することができる。増粘物質の使用量はそ
の種類や併用する乳化剤の種類、使用量によって適宜選
択できるが、例えば、乳化物質量に対して0.5〜30
質量%、好ましくは0.5〜5質量%程度の範囲を挙げ
ることができる。
Examples of the thickener include sodium alginate, agar, carrageenan, locust bean gum, guar gum, xanthan gum, pectin, CM
Preferred examples include polysaccharides such as C. These thickeners can be used alone or in combination of two or more. The amount of the thickener used can be appropriately selected depending on the type and the type and amount of the emulsifier used in combination.
% By mass, preferably in the range of about 0.5 to 5% by mass.

【0017】更に、パプリカオレオレジンとSAIBと
の混合物の使用量は、乳化剤及び増粘物質を含有する水
性系の質量に対して、例えば、1〜50質量%を例示す
ることができる。
Furthermore, the amount of the mixture of paprika oleoresin and SAIB can be, for example, 1 to 50% by mass based on the mass of the aqueous system containing the emulsifier and the thickener.

【0018】本発明のパプリカ色素製剤の調製方法の好
ましい一実施態様を例示すれば、パプリカオレオレジン
とSAIBとを混合し、混合した系を例えば、70〜8
0℃程度に加温して均一な混合油とする。得られる混合
油1質量部を、例えば、ポリグリセリン脂肪酸エステル
を混合溶解した水溶液約1〜約10質量部(水分含有量
約90〜約95質量%)と混合し、ホモミキサー、コロ
イドミル等を用いて乳化処理することにより、粒子径約
3〜約40ミクロンの極めて安定なパプリカ色素製剤を
得ることができる。
In a preferred embodiment of the method for preparing the paprika pigment preparation of the present invention, paprika oleoresin and SAIB are mixed, and the mixed system is, for example, 70 to 8
The mixture is heated to about 0 ° C. to obtain a uniform mixed oil. One part by mass of the obtained mixed oil is mixed with, for example, about 1 to about 10 parts by weight (water content of about 90 to about 95% by weight) of an aqueous solution in which polyglycerin fatty acid ester is mixed and dissolved, and then a homomixer, a colloid mill, or the like is used. By emulsifying the paprika pigment preparation, an extremely stable paprika pigment preparation having a particle size of about 3 to about 40 microns can be obtained.

【0019】本発明では、乳化操作を容易にするため、
必要に応じて他の添加剤を併用することができる。この
ような添加剤としては、例えば、植物油脂、脂肪酸トリ
グリセライド、ソルビトール、グリセリン、プロピレン
グリコールなどを例示することができる。
In the present invention, in order to facilitate the emulsification operation,
If necessary, other additives can be used in combination. Examples of such additives include vegetable oils and fats, fatty acid triglycerides, sorbitol, glycerin, propylene glycol and the like.

【0020】本発明のパプリカ色素製剤によって、安定
かつ良好な赤色系着色を付与できる混練食品としては広
範囲のものが挙げられるが、例えば、かまぼこ、かにあ
しかまぼこ、はんぺん、ちくわ、ハム、ソーセージなど
を例示することができる。
There are a wide variety of kneaded foods which can impart a stable and good reddish color by the paprika pigment preparation of the present invention. Can be exemplified.

【0021】[0021]

【実施例】次に実施例を挙げて本発明を更に具体的に説
明する。
Next, the present invention will be described more specifically with reference to examples.

【0022】実施例1 パプリカオレオレジン1質量部に対し、SAIB1質量
部を添加混合後、ポリグリセリン脂肪酸エステル1質量
部、グリセリン10質量部の混合液に添加し、平均粒径
が5ミクロンになるまで乳化機で乳化して、本発明の食
品着色用パプリカ色素製剤を得た(本発明品1)。 (タラすり身への着色例)本発明1のパプリカ色素製剤
を食塩3質量%、でんぷん1質量%を含むタラすり身に
1質量%添加し、よく混練したところ、すり身は赤味の
あるオレンジ色を呈し、かにかまぼこの着色に用いられ
ているモナスカス色素を添加したものとほぼ同じ色調の
ものが得られた。このものは1週間程度室温に放置した
ところ、ほとんど退色しなかった。
Example 1 After adding and mixing 1 part by mass of SAIB to 1 part by mass of paprika oleoresin, the mixture was added to a mixture of 1 part by mass of polyglycerin fatty acid ester and 10 parts by mass of glycerin, and the average particle size became 5 μm. The emulsion was emulsified with an emulsifier until a paprika pigment preparation for coloring food of the present invention was obtained (Product 1 of the present invention). (Coloring example of cod surimi) The paprika pigment preparation of the present invention 1 was added to cod surimi containing 3% by mass of salt and 1% by mass of starch at 1% by mass and kneaded well, and the surimi became reddish orange. The color obtained was almost the same as that obtained by adding the Monascus pigment used for coloring kamaboko. When this product was allowed to stand at room temperature for about one week, almost no fading occurred.

【0023】実施例2 パプリカオレオレジン1質量部に対し、SAIB2質量
部を添加混合後、アラビアガム水溶液(アラビアガム濃
度:35質量%)6質量部、ソルビトール1質量部の混
合液に添加し、平均粒径が20ミクロンになるまで乳化
機で乳化して、本発明の食品着色用パプリカ色素製剤を
得た(本発明品2)。 (ポークのすり身への着色例)本発明品2のパプリカ色
素製剤をポークのすり身に1質量%添加し、よく混練し
たところ、サラミソーセージ様の着色が得られた。
Example 2 To 1 part by mass of paprika oleoresin, 2 parts by mass of SAIB was added and mixed. The mixture was added to a mixture of 6 parts by mass of an aqueous solution of gum arabic (gum arabic: 35% by mass) and 1 part by mass of sorbitol. The emulsion was emulsified with an emulsifier until the average particle size became 20 microns to obtain a paprika pigment preparation for food coloring of the present invention (Product 2 of the present invention). (Example of Coloring of Pork Surimi) When the paprika pigment preparation of the product 2 of the present invention was added to the pork surimi at 1% by mass and kneaded well, salami sausage-like coloring was obtained.

【0024】実施例3 SAIBの添加量を変え、パプリカオレオレジンとSA
IBとを含有した乳化粒子の平均粒径が、2ミクロン、
5ミクロン、10ミクロン、30ミクロンとなるように
した以外は実施例1と同様の条件下で、タラすり身の着
色を行った。各粒径のパプリカ色素製剤を使用してタラ
すり身に着色した際の、色調の肉眼観察を表1に示し
た。本発明のパプリカ色素製剤の平均粒径を変えること
により色調を調節できることが確認された。
Example 3 The amount of SAIB was changed and paprika oleoresin and SA were added.
The average particle size of the emulsified particles containing IB is 2 microns,
Cod surimi was colored under the same conditions as in Example 1 except that the thickness was changed to 5, 10 and 30 microns. Table 1 shows the visual observation of the color tone when the cod surimi was colored using the paprika pigment preparation of each particle size. It was confirmed that the color tone can be adjusted by changing the average particle size of the paprika pigment preparation of the present invention.

【0025】[0025]

【表1】表1:平均粒径の差による色調の変化 Table 1: Change in color tone due to difference in average particle size

【0026】[0026]

【発明の効果】本発明のパプリカ色素製剤は、各種混練
食品に添加したときに乳化粒子の破壊がなく、より強い
赤色味を付与することができ、かつ異臭のないパプリカ
色素製剤を提供することができる。
Industrial Applicability The paprika pigment preparation of the present invention provides a paprika pigment preparation which can be added to various kneaded foods, does not destroy emulsified particles, can impart a stronger reddish taste, and has no off-flavor. Can be.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 パプリカ色素成分とシュークロース・ジ
アセテート・ヘキサイソブチレート(SAIB)からな
るパプリカ色素製剤。
1. A paprika pigment preparation comprising a paprika pigment component and sucrose diacetate hexaisobutyrate (SAIB).
【請求項2】 パプリカオレオレジンとシュークロース
・ジアセテート・ヘキサイソブチレート(SAIB)と
を含有した乳化粒子が、乳化剤を含有する水性系中に分
散してなるパプリカ色素製剤。
2. A paprika dye preparation comprising emulsified particles containing paprika oleoresin and sucrose diacetate hexaisobutyrate (SAIB) dispersed in an aqueous system containing an emulsifier.
【請求項3】 乳化粒子の平均粒子サイズを着色の色調
に応じて選択した請求項2記載のパプリカ色素製剤。
3. The paprika pigment preparation according to claim 2, wherein the average particle size of the emulsified particles is selected according to the color tone.
【請求項4】 乳化粒子の平均粒子サイズが3〜40ミ
クロンである請求項2または3記載のパプリカ色素製
剤。
4. The paprika pigment preparation according to claim 2, wherein the average particle size of the emulsified particles is 3 to 40 microns.
JP2000065869A 2000-03-10 2000-03-10 Paprika pigment preparation Expired - Fee Related JP3556877B2 (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7097867B2 (en) 2003-03-24 2006-08-29 Council Of Scientific And Industrial Research Process of extracting chili (capsicum) oleoresin
CN102958372A (en) * 2010-07-09 2013-03-06 长谷川香料株式会社 Emulsifying composition, production method thereof and food and drink products that contain same
WO2021230353A1 (en) * 2020-05-15 2021-11-18 三栄源エフ・エフ・アイ株式会社 Paprika emulsified dye preparation and method for producing same

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7097867B2 (en) 2003-03-24 2006-08-29 Council Of Scientific And Industrial Research Process of extracting chili (capsicum) oleoresin
CN102958372A (en) * 2010-07-09 2013-03-06 长谷川香料株式会社 Emulsifying composition, production method thereof and food and drink products that contain same
CN102958372B (en) * 2010-07-09 2015-02-25 长谷川香料株式会社 Emulsifying composition, production method thereof and food and drink products that contain same
WO2021230353A1 (en) * 2020-05-15 2021-11-18 三栄源エフ・エフ・アイ株式会社 Paprika emulsified dye preparation and method for producing same

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