JP2001239364A - Hot working method for, austenitic stainless steel containing b - Google Patents

Hot working method for, austenitic stainless steel containing b

Info

Publication number
JP2001239364A
JP2001239364A JP2000378687A JP2000378687A JP2001239364A JP 2001239364 A JP2001239364 A JP 2001239364A JP 2000378687 A JP2000378687 A JP 2000378687A JP 2000378687 A JP2000378687 A JP 2000378687A JP 2001239364 A JP2001239364 A JP 2001239364A
Authority
JP
Japan
Prior art keywords
stainless steel
welding
hot
austenitic stainless
less
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000378687A
Other languages
Japanese (ja)
Other versions
JP3801861B2 (en
Inventor
Nobuhiko Hiraide
信彦 平出
Kazuhiro Ogawa
和博 小川
Shinji Tsuge
信二 柘植
Yoshiaki Noguchi
良明 野口
Satoru Nishimura
悟 西村
Akihiko Shibata
明彦 柴田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumikin Welding Industries Ltd
Nippon Steel Corp
Original Assignee
Sumikin Welding Industries Ltd
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumikin Welding Industries Ltd, Sumitomo Metal Industries Ltd filed Critical Sumikin Welding Industries Ltd
Priority to JP2000378687A priority Critical patent/JP3801861B2/en
Publication of JP2001239364A publication Critical patent/JP2001239364A/en
Application granted granted Critical
Publication of JP3801861B2 publication Critical patent/JP3801861B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00Energy generation of nuclear origin
    • Y02E30/30Nuclear fission reactors

Landscapes

  • Butt Welding And Welding Of Specific Article (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a hot working method for an austenitic stainless steel plate containing B which causes no welding crack when a high efficient overlaying welding is performed and which can be free from edge cracking of rolled materials during hot working. SOLUTION: When an austenitic stainless steel plate containing 0.3 to 2.5, by weight percent of B is hot worked, the invention relates to the hot working method for an austenitic stainless steel containing B which is hot worked by locating an overlaying welding film layer having 3 mm or more wall thickness on the side of the steel plate that consists of stainless steel having Ni: not more than 4% and B: 0.1-0.4% in weight percent.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、核燃料輸送用容
器、使用済み核燃料貯蔵ラック等原子力関連機器の中性
子遮断材として用いられるB含有オーステナイト系ステ
ンレス鋼の熱間加工方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hot working method for B-containing austenitic stainless steel used as a neutron shielding material for nuclear-related equipment such as containers for transporting nuclear fuel, used nuclear fuel storage racks, and the like.

【0002】[0002]

【従来の技術】Bの優れた熱中性子吸収作用を利用し
て、Bを添加したオーステナイト系ステンレス鋼が、熱
中性子の制御材および遮断材として、核燃料輸送容器、
使用済核燃料保管ラック等に用いられている。一般に、
原子力発電所で使用された使用済核燃料は、再処理工場
にて処理されるまで、発電所内のプール内に保管され
る。限られた敷地内でできるだけ多くの使用済核燃料を
保管したいとのニーズから、B含有オーステナイト系ス
テンレス鋼に添加されるB量は増加し、かつ板厚は薄く
なる傾向にある。
2. Description of the Related Art Utilizing the excellent thermal neutron absorption of B, austenitic stainless steel to which B is added is used as a thermal neutron controlling material and a blocking material, as a nuclear fuel transport container,
Used for spent nuclear fuel storage racks. In general,
Spent nuclear fuel used at a nuclear power plant is stored in a pool at the power plant until it is processed at a reprocessing plant. Due to the need to store as much spent nuclear fuel as possible in a limited site, the amount of B added to the B-containing austenitic stainless steel tends to increase and the plate thickness to decrease.

【0003】Bのオーステナイト中への固溶量は非常に
小さく、添加したBのほとんどがFe、Crを含むボライド
として析出する。このボライドの存在により、熱間加工
性、耐食性が劣化するが、B量の増加と共にその傾向は
顕著になる。
[0003] The amount of B dissolved in austenite is very small, and most of the added B precipitates as a boron containing Fe and Cr. Although the hot workability and the corrosion resistance deteriorate due to the presence of the boron, the tendency becomes remarkable as the B content increases.

【0004】一般に、B含有オーステナイト系ステンレ
ス鋼の鍛造、圧延等の熱間加工は、加熱炉によるスラブ
の加熱と、鍛造や圧延等の加工とを繰り返して被加工材
の温度低下を防止することにより熱間加工性を確保しな
がら行われている。B含有量が多いほど熱間加工性に劣
るので、被加工材の温度低下を防止するためには加熱−
加工の繰り返し回数が増加する。したがって、含有B量
の増加や鋼の薄肉加工は製造コスト高を招くことにな
る。
Generally, in hot working such as forging and rolling of a B-containing austenitic stainless steel, the slab is heated by a heating furnace and working such as forging and rolling is repeated to prevent the temperature of the workpiece from lowering. This is performed while ensuring hot workability. Since the hot workability is inferior as the B content is higher, the heating-
The number of processing repetitions increases. Therefore, an increase in the B content and a thinning of the steel result in an increase in manufacturing cost.

【0005】上記問題を解決するために、これまでに種
々検討されてきた。特開昭61−201726号公報に
は、B含有ステンレス鋼塊をそのままか、あるいは長方
形状に整形後、鋼塊の少なくとも4主面を鉄筒にて密着
包囲し、分塊圧延または鍛造により圧着させてから熱間
圧延する方法が開示されている。
In order to solve the above problems, various studies have been made so far. Japanese Patent Application Laid-Open No. 61-201726 discloses that a B-containing stainless steel ingot is directly or after being shaped into a rectangular shape, and at least four main surfaces of the steel ingot are tightly surrounded by an iron tube, and then compacted by slab rolling or forging. A method of hot rolling after the rolling is disclosed.

【0006】特開昭63−220904号公報では、母
材のB含有オーステナイト系ステンレス鋼材を、それよ
りも変形抵抗の小さい鋼材によりパックした後、110
0℃以上1175℃以下で加熱し、T(℃)=53×B
(質量%)+870以上の温度で仕上圧延する方法が開
示されている。
In Japanese Patent Application Laid-Open No. 63-220904, a B-containing austenitic stainless steel as a base material is packed with a steel material having a smaller deformation resistance and then packed in a 110
Heat at 0 ° C or higher and 1175 ° C or lower, T (° C) = 53 × B
A method of finish rolling at a temperature of (mass%) + 870 or more is disclosed.

【0007】これらの方法により耳割れを防止すること
ができるが、必要な板厚精度を確保することが困難にな
ると共に、パック材の包み込み作業および圧延後の解体
作業が必要となり、製造コスト高になる問題がある。
[0007] Although these methods can prevent ear cracks, it is difficult to secure the required thickness accuracy, and also requires the work of wrapping the pack material and the dismantling work after rolling, which increases the manufacturing cost. Problem.

【0008】板厚精度や、パック材の包み込みおよび解
体作業の問題を回避できる方法として、特開平4−25
3506号公報には、母材のB含有オーステナイト系ス
テンレス鋼材の側面を、母材よりも変形抵抗の小さい鋼
材をフレーム材として溶接により被覆して圧延する、耳
割れの発生を防止することのできる熱間圧延方法が開示
されている。この方法では、精度の高い開先形状を有す
るフレーム材を用意し、かつ熱間加工時に剥離しないよ
うに溶接する必要がある。したがって、通常鋳造したイ
ンゴット(鋼塊)や分塊鍛造スラブ等は厚さが80mm
以上もあるので、これらを熱間加工に適用するのは困難
である。
As a method for avoiding problems of plate thickness accuracy, wrapping of a pack material and dismantling work, Japanese Patent Laid-Open No.
Japanese Patent No. 3506 discloses that a side surface of a B-containing austenitic stainless steel material as a base material is rolled by welding and rolling a steel material having a smaller deformation resistance than the base material as a frame material, thereby preventing occurrence of edge cracks. A hot rolling method is disclosed. In this method, it is necessary to prepare a frame material having a high-precision groove shape and weld it so as not to peel off during hot working. Therefore, the thickness of the normally cast ingot (steel ingot) or forged slab is 80 mm.
Because of the above, it is difficult to apply them to hot working.

【0009】そのほか、特開平1−195243号公報
や特開平5−263133号公報には、耳割れ防止を目
的として、1ヒートあたりの圧下率、下限温度等を規制
して、加熱−圧延を繰り返すことにより所定の厚さのB
含有オーステナイト系ステンレス鋼板を得る方法が開示
されている。これらの方法もやはり、ヒート回数の増加
によるコストアップが問題となると共に、機構上再加熱
が不可能な高生産性タンデム圧延機への適用が困難であ
る。
In addition, JP-A-1-195243 and JP-A-5-263133 disclose the purpose of preventing edge cracking by regulating the rolling reduction per heat, the lower limit temperature, and the like, and repeating the heating-rolling. The B of a predetermined thickness
A method for obtaining a steel containing austenitic stainless steel is disclosed. These methods also have a problem of cost increase due to an increase in the number of heats, and are also difficult to apply to a high-productivity tandem rolling mill in which reheating is mechanically impossible.

【0010】また、鋼片の側面に熱間加工性の良好な金
属材料を肉盛り溶接して圧延する方法が知られている。
この方法によれば、圧延後トリマー等により肉盛り溶接
部を比較的容易に除去できる利点がある。しかしなが
ら、この肉盛り溶接方法においては、MAG、SAWと
いった高能率な溶接方法では、溶接金属中の酸素量が高
くなり、溶接割れが発生しやすい。溶接割れが発生する
と、それが起点となって耳割れの発生に繋がる場合があ
り、完全に耳割れを防止することができなかった。
[0010] Further, a method is known in which a metal material having good hot workability is overlay-welded to the side surface of a steel slab and rolled.
According to this method, there is an advantage that the weld overlay can be relatively easily removed by a trimmer or the like after rolling. However, in this overlay welding method, in a highly efficient welding method such as MAG and SAW, the amount of oxygen in the weld metal increases, and welding cracks are likely to occur. When a weld crack occurs, it may be a starting point and lead to the occurrence of an ear crack, and the ear crack cannot be completely prevented.

【0011】特に大面積の被圧延材側面へ肉盛り溶接す
るには、TIG等に比べMAG、SAWといった高能率
な溶接方法を採用しなければ、溶接作業費を抑えること
ができない。
In particular, for overlay welding on the side surface of a material to be rolled having a large area, unless a highly efficient welding method such as MAG or SAW is employed as compared with TIG or the like, the welding operation cost cannot be reduced.

【0012】[0012]

【発明が解決しようとする課題】本発明の課題は、高B
含有オーステナイト系ステンレス鋼を、熱間加工中に再
加熱することなく、所定の板厚まで耳割れを発生させる
ことなく加工できる熱間加工方法を提供することにあ
る。より具体的には、高能率の溶接方法により鋼片の側
面に肉盛り溶接を行っても溶接割れの発生がなく、かつ
熱間加工中の被圧延材の耳割れの発生を防止することの
できる、高B含有オーステナイト系ステンレス鋼片の熱
間加工方法を提供することにある。
The object of the present invention is to provide a high B
It is an object of the present invention to provide a hot working method capable of working a contained austenitic stainless steel without reheating during hot working and without generating edge cracks up to a predetermined plate thickness. More specifically, even if overlay welding is performed on the side surfaces of the billet by a high-efficiency welding method, there is no occurrence of welding cracks, and the occurrence of edge cracks in the material to be rolled during hot working is to be prevented. An object of the present invention is to provide a hot working method for a high-B content austenitic stainless steel slab that can be performed.

【0013】[0013]

【課題を解決するための手段】本発明は、下記(1)〜
(3)のB含有オーステナイト系ステンレス鋼の熱間加
工方法を要旨としている。
Means for Solving the Problems The present invention provides the following (1) to
The gist of the present invention is a hot working method of (3) B-containing austenitic stainless steel.

【0014】(1)Bを0.3〜2.5質量%含有する
オーステナイト系ステンレス鋼片を熱間加工するに際
し、その鋼片の側面に、質量%でNi:4%以下、B:
0.1〜0.4%を含有するステンレス鋼からなる厚さ
3mm以上の肉盛り溶接被覆層を設けて熱間加工するB
含有オーステナイト系ステンレス鋼の熱間加工方法。
(1) When hot working an austenitic stainless steel slab containing 0.3 to 2.5% by mass of B, Ni: 4% or less by mass% on the side surface of the slab, B:
B which is provided with a build-up welding coating layer having a thickness of 3 mm or more made of stainless steel containing 0.1 to 0.4% and hot-worked B
Hot-working method for austenitic stainless steels containing steel.

【0015】(2)Bを0.3〜2.5質量%含有する
オーステナイト系ステンレス鋼片を熱間加工するに際
し、その鋼片の側面に、質量%でNi:4%以下、B:
0.4%以下、Ti:0.01〜2%を含有するステンレ
ス鋼からなる厚さ3mm以上の肉盛り溶接被覆層を設け
て熱間加工するB含有オーステナイト系ステンレス鋼の
熱間加工方法。
(2) When hot working an austenitic stainless steel slab containing 0.3 to 2.5% by mass of B, Ni: 4% or less by mass% on the side surface of the slab, B:
A hot working method for a B-containing austenitic stainless steel, in which a build-up welding coating layer having a thickness of 3 mm or more made of stainless steel containing 0.4% or less and Ti: 0.01 to 2% is provided and hot-worked.

【0016】(3)肉盛り溶接被覆層が、さらに質量%
でAl:0.003〜0.4%を含有するステンレス鋼か
らなる肉盛り溶接被覆層である(2)記載のB含有オー
ステナイト系ステンレス鋼の熱間加工方法。
(3) The overlay welding coating layer further comprises
(2) The hot working method for B-containing austenitic stainless steel according to (2), which is a build-up weld coating layer of stainless steel containing Al: 0.003 to 0.4%.

【0017】ここで、鋼片とは、連続鋳造スラブ、分塊
鋳造スラブ、分塊圧延スラブおよび鋳造したインゴット
(鋼塊)をいう。
Here, the slab refers to a continuously cast slab, a bulk cast slab, a bulk rolled slab, and a cast ingot (steel ingot).

【0018】本発明者らは、スラブをパックする方法に
比べ経済的な、被圧延材の側面に肉盛り溶接被覆層を設
ける方法を採用することとし、肉盛り溶接被覆に好適な
金属材料を開発するため、種々の試験を行い検討した結
果、下記の知見を得た。
The present inventors have adopted a method of providing a build-up weld coating layer on the side surface of a material to be rolled, which is more economical than a method of packing a slab, and using a metal material suitable for build-up weld coating. As a result of conducting various tests for development, the following findings were obtained.

【0019】a)肉盛り溶接被覆層の溶接割れの感受性
および熱間加工性は、肉盛り溶接被覆層のNiおよびBの
含有量が影響しており、 b)肉盛り溶接被覆層にTi、Alを含有させると、溶接割
れ防止効果、耳割れ防止効果が一層顕著になる。
A) The weld cracking susceptibility and hot workability of the overlay welding coating layer are affected by the contents of Ni and B in the overlay welding coating layer. B) Ti, When Al is contained, the effect of preventing welding cracks and the effect of preventing ear cracks become more remarkable.

【0020】以下、上記知見を得るに至った試験につい
て説明する。
Hereinafter, a description will be given of a test which led to the above finding.

【0021】(試験1)溶接割れの発生がなく、耳割れ
防止に有効な溶接被覆材料を選定するにあたり、まず既
存材料を中心に検討した。
(Test 1) In selecting a welding coating material which does not cause welding cracks and is effective in preventing ear cracks, first, the present invention was mainly studied.

【0022】被圧延材として、Bを1質量%含有する幅
140mm、厚さ80mm、長さ200mmのオーステ
ナイト系ステンレス鋼の分塊鋳造スラブを用いた。ま
た、溶接被覆材料として、オーステナイト系ステンレス
鋼のSUS308L、フェライト系ステンレス鋼のSU
S436L、2相(オーステナイト−フェライト)ステ
ンレス鋼のSUS329J4Lおよび高純度Feを用い
て、上記スラブ片側側面全面にTIG2層溶接にて5m
m厚の肉盛溶接被層を設けた。反対側の側端面は無垢と
した。
As the material to be rolled, a lump-cast slab of austenitic stainless steel having a width of 140 mm, a thickness of 80 mm, and a length of 200 mm containing 1% by mass of B was used. As the welding coating material, SUS308L of austenitic stainless steel and SU of ferritic stainless steel were used.
S436L, two-phase (austenite-ferrite) stainless steel SUS329J4L and high-purity Fe, 5 m by TIG two-layer welding on the entire side surface of one side of the slab
An m-thick overlay coating was provided. The opposite side edge was solid.

【0023】溶接条件は、電流:160A、電圧:17
V、溶接速度:10cm/分とした。肉盛り溶接後に、
断面の浸透探傷試験により溶接割れの有無を確認したと
ころ、SUS329J4L、高純度Feには割れが認めら
れたが、SUS308L、SUS436Lには割れは認
められなかった。
The welding conditions were as follows: current: 160 A, voltage: 17
V, welding speed: 10 cm / min. After build-up welding,
When the presence or absence of welding cracks was confirmed by a penetrant inspection test of the cross section, cracks were found in SUS329J4L and high-purity Fe, but no cracks were found in SUS308L and SUS436L.

【0024】このように肉盛り溶接したスラブを、ワー
クロール直径が450mmのリバース式熱間圧延機を用
いて圧延を行った。スラブの加熱温度は溶融脆性を避け
るため1180℃とした。パススケジュールは下記の通
りであった。
The slab welded in the above manner was rolled using a reverse hot rolling mill having a work roll diameter of 450 mm. The heating temperature of the slab was 1180 ° C. to avoid melt embrittlement. The pass schedule was as follows.

【0025】80→60→45→35→28→21→1
6→12→9→7→5→4(mm)目視により耳割れ状
況を確認しながら圧延を実施し、両側面に耳割れが発生
したパスで圧延を中止した。無垢側の側面に関しては、
被圧延材の表面積が増加すると共に温度低下も大きくな
る7パス目で、耳割れ発生が認められた。
80 → 60 → 45 → 35 → 28 → 21 → 1
6 → 12 → 9 → 7 → 5 → 4 (mm) The rolling was carried out while visually checking the state of the ear cracks, and the rolling was stopped at the pass where the ear cracks occurred on both sides. As for the solid side,
Ear cracks were observed at the seventh pass when the surface area of the material to be rolled increased and the temperature decreased greatly.

【0026】肉盛り被覆を施した側面においては、被覆
材料がSUS329J4L、高純度Feの場合には8パス
目で耳割れが発生し、高純度Feでは、5mm程度の耳割
れが認められた。高純度FeのようにB含有オーステナイ
ト系ステンレス鋼に比べ変形抵抗が小さい材料において
も、溶接割れが存在する場合には、耳割れ防止効果が十
分に得られないことが判明した。一方、被覆材料がSU
S308L、SUS436Lの場合には11パス後でも
耳割れが認められず、耳割れ防止に有効な溶接被覆材料
であることが判明した。
On the side of the overlaid coating, when the coating material was SUS329J4L and high-purity Fe, ear cracks were generated at the eighth pass, and with high-purity Fe, ear cracks of about 5 mm were observed. It has been found that even in a material such as high-purity Fe having a smaller deformation resistance than a B-containing austenitic stainless steel, the effect of preventing ear cracks cannot be sufficiently obtained when welding cracks are present. On the other hand, if the coating material is SU
In the case of S308L and SUS436L, no ear cracks were observed even after 11 passes, which proved to be a weld coating material effective for preventing ear cracks.

【0027】(試験2)試験1の結果を踏まえ、溶接被
覆材料として、SUS308L、SUS436Lを中心
としたCr含有ステンレス鋼を中心にさらに詳細に検討し
た。肉盛り被覆層中のNi、B量等は溶接施工時の希釈率
によって変化するため、肉盛り溶接被覆層の化学成分
は、溶接割れ、耳割れ防止には重要と考え、以下の試験
を実施した。
(Test 2) Based on the results of Test 1, a more detailed study was conducted mainly on a Cr-containing stainless steel centering on SUS308L and SUS436L as welding coating materials. Since the amounts of Ni and B in the cladding layer change depending on the dilution ratio during welding, the chemical composition of the cladding layer is considered important for preventing welding cracks and edge cracks. did.

【0028】素材には、B含有量を種々変化させた板厚
150mm、幅150mm、長さ150mmのオーステ
ナイト系ステンレス鋼の分塊鍛造スラブを用いた。組成
の異なる溶接材料にてスラブ側面に肉盛り溶接して、溶
接割れ、熱間加工性を評価した。なお、素材および溶接
材料のCr量は19〜20質量%とした。(以下、化学組
成の%表示は全て質量%とする。) 溶接方法はTIGに比べ高能率なMAG溶接とし、電
流:220A、電圧:25V、溶接速度:15cm/分
の条件にて、スラブ側面に10〜15mm厚の肉盛り溶
接を行った。
As the material, a lump-forged austenitic stainless steel slab having a thickness of 150 mm, a width of 150 mm, and a length of 150 mm with various B contents was used. Overlay welding was performed on the side surfaces of the slab with welding materials having different compositions to evaluate weld cracking and hot workability. In addition, the Cr amount of the raw material and the welding material was set to 19 to 20% by mass. (Hereinafter, all chemical composition percentages are expressed as mass%.) The welding method is MAG welding, which is more efficient than TIG, and the current is 220 A, the voltage is 25 V, and the welding speed is 15 cm / min. Was welded to a thickness of 10 to 15 mm.

【0029】溶接割れは、断面を浸透深傷して評価し
た。熱間加工性の評価には高温引張試験を用いた。肉盛
り溶接金属部から径10mm、長さ130mmの試験片
を切り出し、1150℃に加熱後、100℃/分の速度
で冷却し、900℃にて引張試験を行った。引張試験の
歪速度は1/Sとし、試験後直ちに急冷して試験片の絞
り(断面収縮率、単位%)を求めた。
[0029] Weld cracks were evaluated by penetrating deep flaws in the cross section. A hot tensile test was used for evaluation of hot workability. A test piece having a diameter of 10 mm and a length of 130 mm was cut out from the weld metal portion, heated to 1150 ° C, cooled at a rate of 100 ° C / min, and subjected to a tensile test at 900 ° C. The strain rate in the tensile test was set to 1 / S, and the specimen was rapidly cooled immediately after the test to determine the drawing (cross-sectional shrinkage, unit%) of the test piece.

【0030】図1は、分析により求めた肉盛り溶接金属
のNi、B量と、スラブ拘束溶接割れ性との相関を示す図
である。図1から、溶接割れの発生は、Ni、B量により
依存し、一定の範囲にあるとき、優れた溶接割れ抵抗性
を示すことが分かる。
FIG. 1 is a graph showing the correlation between the amounts of Ni and B in the build-up weld metal obtained by the analysis and the slab restrained weld cracking. From FIG. 1, it can be seen that the occurrence of welding cracks depends on the amounts of Ni and B, and exhibits excellent weld cracking resistance when in a certain range.

【0031】図2は、肉盛り溶接金属のNi量およびB量
と、高温引張試験結果における絞りとの相関を示す。図
2から、Ni:4%以下、B:0.4%以下の範囲にある
肉盛り溶接被覆層は、900℃の絞りが60%以上あ
り、優れた熱間加工性を示すことが分かる。
FIG. 2 shows the correlation between the Ni content and the B content of the overlay weld metal and the reduction in the results of the high temperature tensile test. From FIG. 2, it can be seen that the build-up weld coating layer in the range of Ni: 4% or less and B: 0.4% or less has a drawn at 900 ° C. of 60% or more, and shows excellent hot workability.

【0032】(試験3)試験2の結果を踏まえ、熱延に
よる耳割れ評価試験を実施した。被圧延材として、Bを
1%含有する幅140mm、厚さ80mm、長さ200
mmのオーステナイト系ステンレス鋼の分塊鍛造スラブ
を用いた。溶接材料として、フェライト系ステンレス鋼
であるSUS430鋼、SUS436L鋼を用い、上記
スラブの片側側面全面に希釈率を変化させて肉盛り溶接
を実施した。溶接方法及び条件は試験2と同一とし、肉
盛り溶接被覆層の厚さを3mmとした。その反対側の側
面は無垢とした。
(Test 3) Based on the results of Test 2, an evaluation test for ear cracks caused by hot rolling was performed. As a material to be rolled, a width of 140 mm, a thickness of 80 mm, and a length of 200 containing 1% of B
A forged slab of austenitic stainless steel with a diameter of 0.2 mm was used. SUS430 steel and SUS436L steel, which are ferritic stainless steels, were used as welding materials, and overlay welding was performed on the entire surface on one side of the slab while changing the dilution ratio. The welding method and conditions were the same as in Test 2, and the thickness of the overlay welding coating layer was 3 mm. The opposite side was solid.

【0033】溶接部断面を浸透探傷試験により溶接割れ
を評価したが、いずれも割れは認められなかった。
The weld section was evaluated for weld cracking by a penetrant inspection test, and no crack was observed in any case.

【0034】このように肉盛り溶接したスラブを、試験
1と同一の条件にて熱間圧延を実施した。試験1と同
様、目視により耳割れ状況を確認しながら圧延し、両側
面に耳割れが発生したパスで圧延を中止した。
The slab thus welded was subjected to hot rolling under the same conditions as in Test 1. As in Test 1, rolling was performed while visually confirming the state of ear cracks, and rolling was stopped at a path where ear cracks occurred on both sides.

【0035】無垢側の側面に関しては、試験1と同様、
被圧延材の表面積が増加すると共に温度低下も大きくな
る7パス目で、耳割れ発生が認められた。希釈率の大き
い、すなわち、肉盛り溶接金属中のNi、B量が多いほ
ど、少ないパス回数で耳割れが発生した。無垢材と同じ
7パス目で耳割れ発生したものは、肉盛り溶接金属中の
Ni、B量は4%、0.4%を超えており耳割れ防止効果
が得られなかった。
Regarding the solid side, as in Test 1,
Ear cracks were observed at the seventh pass when the surface area of the material to be rolled increased and the temperature decreased greatly. The larger the dilution ratio, that is, the larger the amount of Ni and B in the build-up weld metal, the smaller the number of passes, the more cracks occurred. Ear cracking occurred in the same 7th pass as solid wood
The amounts of Ni and B exceeded 4% and 0.4%, and the effect of preventing ear cracks was not obtained.

【0036】肉盛り溶接金属がNi:4%以下、B:0.
4%以下の場合、9パス以降で耳割れ発生が認められ、
耳割れ防止効果が得られた。一方、Tiを含有するSUS
436L鋼を溶接材料として用い、肉盛り溶接金属のN
i:4%以下、B:0.4%以下の場合には、11パス
圧延しても耳割れの発生が認められず、優れた耳割れ防
止効果が得られた。
When the build-up weld metal is Ni: 4% or less, B: 0% or less.
If it is less than 4%, ear cracks are observed after 9 passes,
Ear crack preventing effect was obtained. On the other hand, SUS containing Ti
436L steel is used as welding material,
When i: 4% or less and B: 0.4% or less, generation of edge cracks was not observed even after 11-pass rolling, and an excellent edge crack prevention effect was obtained.

【0037】そこで、さらにTi量を広く変化させたフェ
ライト系ステンレス鋼を溶接材料に用い、前記同様、ス
ラブ側面に肉盛り溶接して熱間圧延による耳割れ評価を
実施した。すると、0.01〜2%の範囲でTiを含有す
る場合には良好な耳割れ防止効果、溶接割れ防止効果が
得られた。特にこれらの効果は0.03〜1%の範囲内
にあるとき顕著であった。肉盛り溶接金属層に含まれる
B量が0.1%に満たない場合、溶接割れが発生しやす
い傾向があるが、Tiを含有する場合には、特に溶接割れ
は起こることはなかった。これは、肉盛り溶接部組織が
非常に微細であり、これにより良好な耳割れ防止効果が
得られたと考えられる。さらに詳細に観察したところ、
Ti窒化物、Ti硼化物の生成が認められ、これらが核とな
り微細な凝固組織が形成されたと推定した。
Therefore, a ferritic stainless steel in which the Ti content was further changed widely was used as a welding material, and as in the above-mentioned manner, edge cracks were evaluated by hot-rolling by overlay welding on the slab side surfaces. Then, when Ti was contained in the range of 0.01 to 2%, a good effect of preventing ear cracks and welding cracks was obtained. In particular, these effects were remarkable when they were in the range of 0.03 to 1%. When the amount of B contained in the build-up weld metal layer is less than 0.1%, welding cracks tend to occur easily, but when Ti is contained, welding cracks do not particularly occur. This is considered to be due to the fact that the build-up welded structure was very fine, and thereby a good edge crack preventing effect was obtained. Upon closer observation,
Generation of Ti nitride and Ti boride was observed, and it was presumed that these formed nuclei to form a fine solidified structure.

【0038】[0038]

【発明の実施の形態】B含有オーステナイト系ステンレ
ス鋼片:被熱間加工材のオーステナイト系ステンレス鋼
中のB量は、0.3〜2.5%とする。0.3%未満で
は熱中性子吸収能が十分でない。B添加量の増加と共に
熱中性子吸収能は向上するが、2.5%を超えると、常
温での延性及び靱性の劣化が顕著になる。そのためB含
有量は0.3〜2.5%とした。
BEST MODE FOR CARRYING OUT THE INVENTION B-containing austenitic stainless steel slab: The amount of B in austenitic stainless steel as a material to be hot worked is set to 0.3 to 2.5%. If it is less than 0.3%, the thermal neutron absorption capacity is not sufficient. Although the thermal neutron absorption ability increases with an increase in the amount of B added, if it exceeds 2.5%, the ductility and toughness at room temperature deteriorate significantly. Therefore, the B content is set to 0.3 to 2.5%.

【0039】本発明が、対象とするB含有オーステナイ
ト系ステンレス鋼の、前記B以外の元素は、C:0.0
8%以下、Si:1%以下、Mn:2%以下、P:0.04
%以下、S:0.01%以下、Cr:16〜25%、Ni:
7〜15%とすることが好ましい。また、必要に応じて
Mo:1.5%以下、Cu:0.5%以下、Al:0.3%以
下を単独または組み合わせて含有させることが好まし
い。十分な溶接性を確保する観点から、N:0.05%
以下とすることが好ましい。
The element other than B in the B-containing austenitic stainless steel of the present invention is C: 0.0
8% or less, Si: 1% or less, Mn: 2% or less, P: 0.04
%, S: 0.01% or less, Cr: 16 to 25%, Ni:
It is preferred to be 7 to 15%. Also, if necessary
It is preferable to contain Mo: 1.5% or less, Cu: 0.5% or less, and Al: 0.3% or less singly or in combination. From the viewpoint of ensuring sufficient weldability, N: 0.05%
It is preferable to set the following.

【0040】ステンレス鋼片とは、前述したように連続
鋳造スラブ、分塊鍛造スラブ、分塊圧延スラブおよび鋳
造したインゴット(鋼塊)をいう。これらの鋼片は一般
に直方体であり、その長手方向に延びるように熱間圧延
や鍛造等の熱間加工が施される。鋼片の側面とは、加工
面(圧延の場合、ロールと接触する面)以外の面であ
り、通常は長手方向の2側面の全面に肉盛り溶接被覆層
を設ければよい。なお、鋼片のコーナー部を面取り加工
する場合があるが、この場合にはコーナー部や加工面側
に回り込ませて肉盛り溶接被覆層を設けてもよい。
The stainless steel slab refers to a continuously cast slab, a forged slab, a slab rolled slab, and a cast ingot (steel ingot) as described above. These slabs are generally rectangular parallelepipeds, and are subjected to hot working such as hot rolling or forging so as to extend in the longitudinal direction. The side surface of the steel slab is a surface other than the processing surface (in the case of rolling, the surface that comes into contact with the roll), and usually, a build-up welding coating layer may be provided on the entire two side surfaces in the longitudinal direction. In some cases, the corners of the steel slab are chamfered. In this case, the overlaid weld coating layer may be provided so as to extend around the corners and the machined surface.

【0041】肉盛り溶接被覆:肉盛り溶接被覆層は、N
i:4%以下、B:0.1〜0.4%を含有するステン
レス鋼とした。なお、必要に応じTi:0.01〜2%、
Al:0.003〜0.4%を含有させる場合は、B量を
0.4%以下(0.1%以下も含む)とすることができ
る。
Build-up weld coat: The build-up weld coat layer is N
i: stainless steel containing 4% or less and B: 0.1 to 0.4%. In addition, if necessary, Ti: 0.01 to 2%,
When Al is contained in an amount of 0.003 to 0.4%, the B content can be set to 0.4% or less (including 0.1% or less).

【0042】Ni:4%、B:0.4%を超えると熱間加
工性が十分でない。また、Ni:4%以下、B:0.4%
以下のような範囲でも、Bが0.1%以上ない場合に
は、肉盛り溶接時の凝固割れ感受性が増加し、溶接割れ
が起こりやすくなる。なお、Ti:0.01〜2%を含有
させる、あるいは、Tiに加えさらにAl:0.003〜
0.4%を含有させる場合には、Bが0.1%に満たな
くても、溶接割れが起こることはない。
If the Ni content exceeds 4% and the B content exceeds 0.4%, the hot workability is not sufficient. Ni: 4% or less, B: 0.4%
Even in the following ranges, when B is not 0.1% or more, the susceptibility to solidification cracking during build-up welding increases, and welding cracks are likely to occur. In addition, Ti: 0.01 to 2% is contained, or Al: 0.003 to
In the case where 0.4% is contained, even if B is less than 0.1%, no welding crack occurs.

【0043】肉盛り溶接被覆層中のNiおよびB量を上記
のような範囲とするには、溶接材料および溶接条件を調
整する必要がある。すなわち、溶接材料として、Ni量が
3%以下、B量が0.3%以下のフェライト系ステンレ
ス鋼を用いるのが好ましい。Bを含有することなくNi量
が3%以下のフェライト系ステンレス鋼を用いる場合に
は、例えば、SAW(バンドアーク溶接を含む)では、
Bを添加したフラックスを用いて、肉盛り溶接被覆層中
のNiおよびB量をコントロールすればよい。また、MA
Gの場合は溶接材料中にこれらの合金元素を含んだフラ
ックス入りワイヤを用いることによって、肉盛り溶接被
覆層のNiおよびB量をコントロールすればよい。被覆ア
ーク溶接棒の場合も同様である。
In order to keep the Ni and B contents in the build-up weld coating layer within the above ranges, it is necessary to adjust the welding materials and welding conditions. That is, it is preferable to use a ferritic stainless steel having a Ni content of 3% or less and a B content of 0.3% or less as a welding material. When using a ferritic stainless steel having a Ni content of 3% or less without containing B, for example, in SAW (including band arc welding),
The amounts of Ni and B in the build-up weld coating layer may be controlled using a flux containing B. Also, MA
In the case of G, the amounts of Ni and B in the build-up welding coating layer may be controlled by using a flux-cored wire containing these alloy elements in the welding material. The same applies to the case of a covered arc welding rod.

【0044】また、肉盛り溶接時に熱量を下げることに
より被熱間加工時のB含有ステンレス鋼が肉盛り溶接層
に溶け込むのをできるだけ少なくするのがよい。
It is also preferable to reduce the amount of heat during the overlay welding to minimize the dissolution of the B-containing stainless steel into the overlay welding layer during hot working.

【0045】肉盛り溶接層に良好な溶接割れ抵抗性、熱
間加工性を付与するには、少なくとも0.01%以上の
Tiを含有させるのが好ましい。一方、2%を超えると、
耳割れ防止効果が飽和すると共に、溶接性および靱性に
悪影響を与えるため、含有させる場合は0.01〜2%
とした。また、1%を超えると溶接割れ防止効果も飽和
する。したがって、Ti量は0.01〜1%とすることが
好ましい。顕著な耳割れ防止効果、溶接割れ効果を得る
ためには、Ti量を0.03〜0.5%とすることが好ま
しい。
In order to impart good weld crack resistance and hot workability to the build-up welded layer, at least 0.01% or more is required.
It is preferable to contain Ti. On the other hand, if it exceeds 2%,
In order to saturate the effect of preventing ear cracks and adversely affect the weldability and toughness, if it is contained, 0.01 to 2%
And On the other hand, if it exceeds 1%, the effect of preventing welding cracks is saturated. Therefore, the amount of Ti is preferably set to 0.01 to 1%. In order to obtain a remarkable edge crack prevention effect and a weld cracking effect, the Ti content is preferably set to 0.03 to 0.5%.

【0046】Alは、脱酸元素として、Tiによる凝固組織
の微細化に有効に作用するため、必要に応じて含有させ
る。その効果を得るには、少なくとも、0.003%以
上含有させる必要があり、0.4%を超えて含有させる
と、靱性に悪影響を及ぼすため、Al量は0.003〜
0.4%とすることが好ましい。より好ましくは、0.
01〜0.2%である。
Al is contained as necessary as a deoxidizing element because it effectively acts to refine the solidified structure by Ti. In order to obtain the effect, it is necessary to contain at least 0.003% or more. If the content exceeds 0.4%, the toughness is adversely affected.
Preferably it is 0.4%. More preferably, 0.
01 to 0.2%.

【0047】なお、肉盛り溶接被覆層にTi、Alを含有さ
せる場合は、肉盛り溶接被覆層のBが0.1%未満であ
っても、十分な溶接割れ防止効果が得られる。
When Ti and Al are contained in the build-up weld coating layer, a sufficient weld crack preventing effect can be obtained even if B of the build-up weld coating layer is less than 0.1%.

【0048】肉盛り溶接被覆層をステンレス鋼に限定し
た理由は、溶接金属中のフェライト量を確保すると共
に、素材のB含有オーステナイト系ステンレス鋼と同程
度の耐酸化性、耐食性を付与するためである。このた
め、一般に12%以上のCr量を含有する鋼がステンレス
鋼とよばれるが、肉盛り溶接被覆層のCr量としては、1
6%以上、25%以下であることが好ましく、より好ま
しくは18%以上である。
The reason why the build-up welding coating layer is limited to stainless steel is to secure the amount of ferrite in the weld metal and to provide the same oxidation resistance and corrosion resistance as the B-containing austenitic stainless steel as the material. is there. For this reason, steel containing a Cr content of 12% or more is generally referred to as stainless steel.
It is preferably at least 6% and at most 25%, more preferably at least 18%.

【0049】肉盛り溶接被覆層が上に示した量のNi、
B、そして必要に応じTi、Alを含むステンレス鋼であれ
ば、本発明の目的は達成される。しかし、肉盛り溶接被
覆層に、他の元素が含まれていてもかまわない。以下
に、肉盛り溶接被覆層に含まれていてもよい元素とその
含有量について述べる。
When the build-up weld coating layer has the above amount of Ni,
The object of the present invention is achieved by using stainless steel containing B and, if necessary, Ti and Al. However, other elements may be contained in the build-up weld coating layer. Hereinafter, the elements that may be contained in the build-up weld coating layer and their contents will be described.

【0050】C:耐食性の観点から、0.06%以下で
あることが好ましい。
C: From the viewpoint of corrosion resistance, the content is preferably 0.06% or less.

【0051】N:溶接性の観点から、0.06%以下で
あることが好ましい。
N: From the viewpoint of weldability, the content is preferably 0.06% or less.

【0052】Si、Mn:Si、Mnは脱酸のため添加される。
両元素とも2%以下であることが好ましい。
Si, Mn: Si and Mn are added for deoxidation.
It is preferable that both elements are 2% or less.

【0053】P、S:P、Sは鋼の特性を損なう元素で
ある。それぞれ、0.1%以下、0.03%以下である
ことが好ましい。
P, S: P and S are elements that impair the properties of steel. It is preferably 0.1% or less and 0.03% or less, respectively.

【0054】Mo:耐食性を高めるために必要に応じて添
加することが好ましい。添加量は1.5%以下とするこ
とが好ましい。
Mo: It is preferable to add Mo as needed in order to enhance corrosion resistance. It is preferable that the addition amount be 1.5% or less.

【0055】Nb、V:耐食性を高めるために必要に応じ
て添加することができる。添加量は1%以下とすること
が好ましい。
Nb, V: Can be added as needed to enhance corrosion resistance. It is preferable that the addition amount is 1% or less.

【0056】O:肉盛り溶接被覆層中のOは、溶接金属
材料に比べ不可避的に増加する。Oは靱性を損なう効果
があるため、0.2%以下に制御することが好ましい。
O: O in the build-up weld coating layer inevitably increases as compared to the weld metal material. O has the effect of impairing the toughness, so it is preferable to control it to 0.2% or less.

【0057】また、肉盛り溶接被覆層の金属組織は、フ
ェライト組織、或いは、フェライトとオーステナイトか
らなる組織であることが好ましい。フェライトとオース
テナイトからなる組織の場合、オーステナイト相は50
%以下であることが好ましい。
The metal structure of the overlay welding coating layer is preferably a ferrite structure or a structure composed of ferrite and austenite. In the case of a structure composed of ferrite and austenite, the austenite phase is 50%.
% Is preferable.

【0058】肉盛り溶接被覆層の結晶粒径は、小さい方
がよい。具体的には結晶粒径は0.5mm以下とするこ
とが好ましい。B、Ti、Alを本発明の範囲とすることで
容易に結晶粒径を0.5mm以下にすることができる。
The smaller the crystal grain size of the overlay welding coating layer, the better. Specifically, the crystal grain size is preferably 0.5 mm or less. By setting B, Ti, and Al within the range of the present invention, the crystal grain size can be easily reduced to 0.5 mm or less.

【0059】肉盛り溶接方法としては、TIG、MA
G、SAW(バンドアーク溶接を含む)等が適用され、
必要に応じてこれらを組み合わせて使用できる。MA
G、SAWは溶接効率がよいので、これらの溶接方法が
推奨される。
TIG, MA
G, SAW (including band arc welding) etc. are applied,
These can be used in combination as needed. MA
Since G and SAW have good welding efficiency, these welding methods are recommended.

【0060】被覆層の厚さとしては、耳割れ防止の観点
のみならず、溶接施工性を考慮に入れ、3mm以上とし
た。厚みを増加させると耳割れ防止効果はより確実とな
るため、被覆厚さは5mm以上あることが好ましい。一
方、過度に厚く被覆することは溶接作業コストが増大す
ることから好ましくない。被覆厚さは50mm以下とす
ることが好ましい。被覆厚さは40mm以下とすること
がより好ましく、15mm以下とすることが最も好まし
い。
The thickness of the coating layer is set to 3 mm or more in consideration of not only the prevention of edge cracks but also the welding workability. When the thickness is increased, the effect of preventing ear cracks becomes more certain, so that the coating thickness is preferably 5 mm or more. On the other hand, an excessively thick coating is not preferable because the welding operation cost increases. The coating thickness is preferably set to 50 mm or less. The coating thickness is more preferably 40 mm or less, and most preferably 15 mm or less.

【0061】熱間加工:熱間加工は、分塊鍛造、厚板圧
延および熱延鋼帯圧延等をいう。鋼片の加熱温度は溶融
脆性を生じない範囲での高い温度に設定する。B含有オ
ーステナイト系ステンレス鋼の場合、1100〜120
0℃とするのが好適である。熱間鍛造あるいは熱間圧延
における仕上温度は高い方が耳割れ防止にとって好まし
い。しかし、溶接被覆材の熱間変形能が許す限り、60
0〜900℃の低温仕上げとすることも可能である。
Hot working: Hot working refers to slab forging, thick plate rolling, hot rolling steel strip rolling and the like. The heating temperature of the billet is set to a high temperature within a range that does not cause melt embrittlement. In the case of B-containing austenitic stainless steel, 1100 to 120
The temperature is preferably set to 0 ° C. It is preferable that the finishing temperature in hot forging or hot rolling be high to prevent edge cracks. However, as long as the hot deformability of the welding cladding permits, 60
A low temperature finish of 0 to 900 ° C. is also possible.

【0062】[0062]

【実施例】まず、表1に示す化学組成を有するステンレ
ス鋼を溶製し、鍛造および熱間加工により連続鋳造スラ
ブ、分塊鍛造スラブ、分塊圧延スラブおよび鋼塊(イン
ゴット)の各鋼片とした。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS First, stainless steel having the chemical composition shown in Table 1 is melted, and each steel piece of a continuous cast slab, a slab forged slab, a slab rolled slab, and a steel ingot (ingot) is forged and hot worked. And

【0063】[0063]

【表1】 前記各鋼片の厚さは表2に示すとおりで、長さは全て2
000mmとした。
[Table 1] The thickness of each slab is as shown in Table 2, and the lengths are all 2
000 mm.

【0064】[0064]

【表2】 各鋼片の長手方向側面に表3に示す化学組成を有するフ
ェライト系ステンレス鋼溶接材料を、表4に示す条件で
MAGまたはSAWにより肉盛り溶接した。各肉盛り溶
接層中のNi、B、TiおよびAl含有量を分析により求めた
結果を表2に示す。
[Table 2] A ferritic stainless steel welding material having a chemical composition shown in Table 3 was welded on the side surface in the longitudinal direction of each billet by MAG or SAW under the conditions shown in Table 4. Table 2 shows the results obtained by analyzing the contents of Ni, B, Ti and Al in each overlay welding layer.

【0065】[0065]

【表3】 [Table 3]

【表4】 次に、肉盛り被覆層を設けた鋼片を熱間圧延または熱間
鍛造により再加熱することなく表2に示す仕上げ板厚ま
で加工して鋼板とした。表2に示すように、No.6、
8、9、11〜15および17をSAWで肉盛り溶接
を、それ以外は、肉盛り溶接をしなかった16を除き、
MAGで肉盛り溶接を施した。また、No.4、5、1
0、11、18および19には厚板圧延を、それ以外は
熱延鋼帯圧延を施した。なお、熱間圧延または熱間鍛造
における加熱温度は1150℃とした。
[Table 4] Next, the steel slab provided with the build-up coating layer was processed to a finished plate thickness shown in Table 2 without reheating by hot rolling or hot forging to obtain a steel plate. As shown in Table 2, 6,
8, 9, 11 to 15 and 17 were overlaid with SAW, except for 16 which was not overlaid,
Overlay welding was performed with MAG. In addition, No. 4, 5, 1
Plates 0, 11, 18 and 19 were subjected to thick plate rolling, and the others were subjected to hot rolled steel strip rolling. The heating temperature in hot rolling or hot forging was 1150 ° C.

【0066】SAWによる肉盛り溶接のうち、溶接材料
がaまたはbの場合には、B、Ti、Alを含むフラックス
を使用することにより、肉盛り溶接被覆層のB、Ti、Al
含有量を調整した。具体的には、No.9ではB、Ti、
Al全てを含むフラックス、No.11および12ではB
を含むフラックス、No.15ではTi、Alを含むフラッ
クスを使用した。なお、No.17ではB、Ti、Alを含
まないフラックスを使用している。
When the welding material is a or b in the overlay welding by SAW, the flux containing B, Ti, and Al is used to form B, Ti, and Al of the overlay welding coating layer.
The content was adjusted. Specifically, No. In 9, B, Ti,
Flux containing all of Al. B at 11 and 12
Flux containing No. In No. 15, a flux containing Ti and Al was used. In addition, No. In No. 17, a flux containing no B, Ti, or Al is used.

【0067】溶接割れは、断面を浸透探傷して評価し
た。また、熱間加工後耳割れの有無を目視観察した。
The weld cracks were evaluated by penetrating the cross section for flaw detection. After hot working, the presence or absence of ear cracks was visually observed.

【0068】表2から明らかなように、肉盛り溶接被覆
層のNi、B量がそれぞれ4%以下、0.1〜0.4%の
時、耳割れの発生がなく良好な鋼板が得られた。また、
B量fが0.1%に満たない場合でも、肉盛り溶接被覆
層にTi、あるいはTiに加えAlが含まれている時には、耳
割れの発生がなく良好な鋼板が得られた。
As is clear from Table 2, when the Ni and B contents of the build-up welding coating layer are 4% or less and 0.1 to 0.4%, respectively, a good steel sheet without edge cracks can be obtained. Was. Also,
Even when the B content f was less than 0.1%, when the overlay welding coating layer contained Ti or Al in addition to Ti, a good steel sheet without edge cracks was obtained.

【0069】さらに肉盛り溶接被覆層にTiが含まれてい
るもの(No.1〜4、6〜9、13〜15)とTiが含
まれていないもの(No.5、10〜12)を比較する
と、Tiを0.01〜2%含有する場合には、Tiを含有し
ない場合に比べ、圧下率(加工度)を大きくしても耳割
れ発生が認められなかった。さらに、肉盛り溶接被覆層
にTiが含まれているものの中でも、Alが含まれているも
の(No.8、9、13、15)は、Alが含まれていな
いもの(No.1〜4、6、7、14)に比べ、さらに
圧下率(加工度)を大きくしても耳割れ発生が認められ
なかった。
Further, the overlay welding coating layer containing Ti (Nos. 1-4, 6-9, 13-15) and those not containing Ti (Nos. 5, 10-12) were used. In comparison, when the Ti content was 0.01% to 2%, no ear cracking was observed even when the rolling reduction (working rate) was increased, as compared with the case where Ti was not included. Furthermore, among the cladding weld coating layers containing Ti, those containing Al (Nos. 8, 9, 13, and 15) do not contain Al (Nos. 1 to 4). , 6, 7, 14), the occurrence of ear cracks was not observed even when the rolling reduction (working degree) was further increased.

【0070】一方、溶接被覆しなかったNo.16、肉
盛り溶接被覆層の化学組成が本発明で規定する範囲を外
れているNo.17、18、肉盛り溶接被覆厚さの小さ
いNo.19では、耳割れが発生し、良好な品質の鋼板
が得られなかった。
On the other hand, no. No. 16, the chemical composition of the build-up weld coating layer was out of the range specified in the present invention. Nos. 17, 18 and No. 17 having a small build-up weld coating thickness. In No. 19, ear cracks occurred and a steel sheet of good quality could not be obtained.

【0071】[0071]

【発明の効果】本発明の熱間加工方法によれば、難加工
材の高B含有オーステナイト系ステンレス鋼片を、熱間
加工の途中で再加熱しなくとも耳割れの発生がなく工業
的に安定して歩留まりよく加工することができる。した
がって、近年高まっている核燃料輸送用容器、使用済核
燃料貯蔵ラック等原子力関連機器の中性子遮断材のニー
ズに対し、特性の優れた鋼板を比較的安価に供給でき
る。
According to the hot working method of the present invention, a high B-containing austenitic stainless steel slab, which is a difficult-to-work material, is not cracked even if it is not reheated during hot working and industrially. Processing can be performed stably with good yield. Therefore, it is possible to supply a steel sheet having excellent characteristics relatively inexpensively to the needs of neutron shielding materials for nuclear-related equipment, such as containers for transporting nuclear fuel and spent nuclear fuel storage racks, which have been increasing in recent years.

【図面の簡単な説明】[Brief description of the drawings]

【図1】Ni、B含有量とスラブ拘束溶接割れ性との相関
を示す図である。
FIG. 1 is a diagram showing a correlation between Ni and B contents and slab restrained weld cracking.

【図2】高温引張試験結果における絞りとNi、B含有量
との相関を示す図である。
FIG. 2 is a diagram showing a correlation between drawing and Ni and B contents in a high-temperature tensile test result.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) // C22C 38/00 302 C22C 38/54 38/54 B23K 103:04 B23K 103:04 G21C 19/06 B (72)発明者 小川 和博 大阪府大阪市中央区北浜4丁目5番33号 住友金属工業株式会社内 (72)発明者 柘植 信二 大阪府大阪市中央区北浜4丁目5番33号 住友金属工業株式会社内 (72)発明者 野口 良明 兵庫県尼崎市扶桑町1番17号 住金溶接工 業株式会社内 (72)発明者 西村 悟 兵庫県尼崎市扶桑町1番17号 住金溶接工 業株式会社内 (72)発明者 柴田 明彦 兵庫県尼崎市扶桑町1番17号 住金溶接工 業株式会社内──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) // C22C 38/00 302 C22C 38/54 38/54 B23K 103: 04 B23K 103: 04 G21C 19/06 B (72) Inventor Kazuhiro Ogawa 4-5-33 Kitahama, Chuo-ku, Osaka City, Osaka Prefecture Inside Sumitomo Metal Industries, Ltd. (72) Inventor Shinji Tsuge 4-5-33, Kitahama, Chuo-ku, Osaka City, Osaka Sumitomo Metal Industries In-company (72) Inventor Yoshiaki Noguchi 1-117 Fuso-cho, Amagasaki-shi, Hyogo Sumikin Welding Co., Ltd. (72) Inventor Akihiko Shibata 1-17 Fuso-cho, Amagasaki-shi, Hyogo Sumikin Welding Co., Ltd.

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】Bを0.3〜2.5質量%含有するオース
テナイト系ステンレス鋼片を熱間加工するに際し、その
鋼片の側面に、質量%でNi:4%以下、B:0.1〜
0.4%を含有するステンレス鋼からなる厚さ3mm以
上の肉盛り溶接被覆層を設けて熱間加工することを特徴
とするB含有オーステナイト系ステンレス鋼の熱間加工
方法。
When hot-working an austenitic stainless steel slab containing 0.3 to 2.5% by mass of B, Ni: 4% or less, B: 0. 1 to
A hot working method for a B-containing austenitic stainless steel, comprising providing a build-up weld coating layer having a thickness of 3 mm or more and made of stainless steel containing 0.4%.
【請求項2】Bを0.3〜2.5質量%含有するオース
テナイト系ステンレス鋼片を熱間加工するに際し、その
鋼片の側面に、質量%でNi:4%以下、B:0.4%以
下、Ti:0.01〜2%を含有するステンレス鋼からな
る厚さ3mm以上の肉盛り溶接被覆層を設けて熱間加工
することを特徴とするB含有オーステナイト系ステンレ
ス鋼の熱間加工方法。
2. When hot working an austenitic stainless steel slab containing 0.3 to 2.5% by mass of B, Ni: 4% or less by mass% and B: 0. Hot working of a B-containing austenitic stainless steel characterized in that a build-up welding coating layer of a thickness of 3 mm or more made of stainless steel containing 4% or less and Ti: 0.01 to 2% is provided and hot-worked. Processing method.
【請求項3】肉盛り溶接被覆層が、さらに質量%でAl:
0.003〜0.4%を含有するステンレス鋼からなる
肉盛り溶接被覆層であることを特徴とする請求項2記載
のB含有オーステナイト系ステンレス鋼の熱間加工方
法。
3. The cladding weld coating layer further comprises Al:
The hot-working method for a B-containing austenitic stainless steel according to claim 2, wherein the coating layer is a build-up weld coating layer made of stainless steel containing 0.003 to 0.4%.
JP2000378687A 1999-12-17 2000-12-13 Hot working method for B-containing austenitic stainless steel Expired - Fee Related JP3801861B2 (en)

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JP35997599 1999-12-17
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004024969A1 (en) 2002-09-11 2004-03-25 Sumitomo Metal Industries, Ltd. Stainless steel product containing b and method for production thereof
WO2007032439A1 (en) * 2005-09-15 2007-03-22 Sumitomo Metal Industries, Ltd. Material for trilaminar stainless steel clad steel sheet, process for producing thick sheet or steel sheet for solid polymer type fuel cell separator, and solid polymer type fuel cell separator
JP2008179865A (en) * 2007-01-25 2008-08-07 Daido Castings:Kk Method for manufacturing highly corrosion-resistant boiler padded pipe for waste incinerator and powdery padding material used in the method
JP2008208430A (en) * 2007-02-27 2008-09-11 Nippon Steel & Sumikin Stainless Steel Corp Soft austenitic stainless steel and manufacturing method therefor
CN101947549A (en) * 2010-09-10 2011-01-19 山东泰山钢铁集团有限公司 Production technology for inhibiting nickel-saving austenitic stainless steel hot-rolled plate edge crack

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004024969A1 (en) 2002-09-11 2004-03-25 Sumitomo Metal Industries, Ltd. Stainless steel product containing b and method for production thereof
US7170073B2 (en) 2002-09-11 2007-01-30 Sumitomo Metal Industries, Ltd. Stainless steel product containing B and method for production thereof
WO2007032439A1 (en) * 2005-09-15 2007-03-22 Sumitomo Metal Industries, Ltd. Material for trilaminar stainless steel clad steel sheet, process for producing thick sheet or steel sheet for solid polymer type fuel cell separator, and solid polymer type fuel cell separator
JPWO2007032439A1 (en) * 2005-09-15 2009-03-19 住友金属工業株式会社 Material for three-layer stainless steel clad steel plate, thick plate and method for producing steel plate for polymer electrolyte fuel cell separator, and polymer electrolyte fuel cell separator
KR100987881B1 (en) * 2005-09-15 2010-10-13 수미도모 메탈 인더스트리즈, 리미티드 Material for trilaminar stainless steel clad steel sheet, process for producing thick sheet or steel sheet for solid polymer type fuel cell separator, and solid polymer type fuel cell separator
US8100313B2 (en) 2005-09-15 2012-01-24 Sumitomo Metal Industries, Ltd. Source blank for stainless steel three-ply clad sheet, production methods of clad steel plate and sheet for solid polymer type fuel cell separator, and solid polymer type fuel cell separator
JP4893625B2 (en) * 2005-09-15 2012-03-07 住友金属工業株式会社 Material for three-layer stainless steel clad steel plate, thick plate and method for producing steel plate for polymer electrolyte fuel cell separator, and polymer electrolyte fuel cell separator
JP2008179865A (en) * 2007-01-25 2008-08-07 Daido Castings:Kk Method for manufacturing highly corrosion-resistant boiler padded pipe for waste incinerator and powdery padding material used in the method
JP4633748B2 (en) * 2007-01-25 2011-02-16 株式会社大同キャスティングス Method for producing highly corrosion-resistant boiler cladding for waste incinerator and powder cladding material used therefor
JP2008208430A (en) * 2007-02-27 2008-09-11 Nippon Steel & Sumikin Stainless Steel Corp Soft austenitic stainless steel and manufacturing method therefor
CN101947549A (en) * 2010-09-10 2011-01-19 山东泰山钢铁集团有限公司 Production technology for inhibiting nickel-saving austenitic stainless steel hot-rolled plate edge crack

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