JP2001238644A - Fish roe food packed in flexible tube - Google Patents

Fish roe food packed in flexible tube

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Publication number
JP2001238644A
JP2001238644A JP2000053076A JP2000053076A JP2001238644A JP 2001238644 A JP2001238644 A JP 2001238644A JP 2000053076 A JP2000053076 A JP 2000053076A JP 2000053076 A JP2000053076 A JP 2000053076A JP 2001238644 A JP2001238644 A JP 2001238644A
Authority
JP
Japan
Prior art keywords
fat
fish
oil
melting point
fish egg
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000053076A
Other languages
Japanese (ja)
Other versions
JP3295407B2 (en
Inventor
Koji Mochizuki
康次 望月
Junsuke Inoue
淳介 井上
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QP Corp
Original Assignee
QP Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QP Corp filed Critical QP Corp
Priority to JP2000053076A priority Critical patent/JP3295407B2/en
Publication of JP2001238644A publication Critical patent/JP2001238644A/en
Application granted granted Critical
Publication of JP3295407B2 publication Critical patent/JP3295407B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To provide a fish roe food packed in a flexible tube, having good flavor of fish roe, preservable for a long period at normal temperatures, and easily usable at any desired time after extruding the food out of the flexible tube. SOLUTION: This fish roe food packed in a flexible tube is such that a fish roe composition comprising fish roe produced through heat denaturation and oils and fats is packed in the flexible tube; wherein the oils and fats comprise low-melting oils add fats and high-melting point oils and fats and account for 5-25 wt.% of the fish roe composition, and the fish roe accounts for 20-60 wt.% of the fish roe composition, and the viscosity of the fish roe composition at 5-35 deg.C is 4,000-1,000,000 mPa/s.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、タラ、マダラ、ス
ケトウダラ、ニシン、飛魚、シシャモ等の腹子である魚
卵をバラしたバラ卵を加熱変性させて、軟質チューブ容
器等の可撓性容器に充填密封した、パスタソース、パン
のフィリング、ピザの具、お握りの具、炒飯の素等とし
て用いることができる食品用の魚卵食品に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a flexible container, such as a flexible tube container, which is obtained by heating and denaturing rose eggs obtained by separating fish eggs which are litters of cod, cod, walleye pollock, herring, flying fish, shishamo, etc. The present invention relates to a fish egg food for food which can be used as a pasta sauce, filling bread, filling pizza, rice balls, fried rice, etc.

【0002】[0002]

【従来の技術】タラコや明太子、シシャモ等の魚卵を長
期間保存可能とするために、従来は、塩蔵することが一
般的に行われている。塩蔵加工したとしても、チルドや
冷凍保管が必要であり、常温保管するには、過飽和にな
るまで、塩濃度を高くしなくてはならず、塩抜きしなく
ては食べられないものである。また、魚卵を、20℃〜
35℃の常温で1ヶ月以上の長期間保存できるパスタソ
ースやフリカケとして用いられているものには、乾燥物
として利用されている。乾燥したものであると、魚卵特
有の風味が乾燥時に飛んでしまい、また水分が少ないこ
とから、舌に感じる美味しさが劣り、そして乾燥するた
めの手間、コストがかかるものとなっている。
2. Description of the Related Art Conventionally, salting is generally performed in order to preserve fish eggs such as cod roe, mentaiko and shishamo for a long period of time. Even if salting is performed, chilled or frozen storage is required. For storage at room temperature, the salt concentration must be increased until supersaturation occurs, and the salt cannot be eaten without salt removal. In addition, fish egg
Pasta sauces that can be stored at room temperature of 35 ° C. for a long period of one month or longer, and those used as flickering are used as dried products. If it is dried, the flavor peculiar to the fish egg will fly when it is dried, and since it has little water, the taste to be felt on the tongue will be inferior, and it will take time and cost to dry.

【0003】[0003]

【発明が解決しようとする課題】そこで、本発明は、魚
卵を、乾燥することなく、常温で長期間保存でき、魚卵
風味の良好な、必要な時に手軽に軟質チューブ容器から
押し出して使用することができる可撓性容器詰魚卵食品
を提供することを目的としてなされた発明である。そし
て、可撓性容器に、ただ加熱変性させバラした魚卵を充
填するだけでは、保存中の分離、反復使用による分離の
抑制、保型性、押出し適性が無いので、これらを解決し
ようとしてなされた発明である。
SUMMARY OF THE INVENTION Accordingly, the present invention provides a method of using a fish egg which can be stored at room temperature for a long period of time without drying, has good fish egg flavor, and is easily pushed out of a flexible tube container when necessary. It is an invention made for the purpose of providing a flexible packaged fish egg food that can be prepared. Then, simply filling a flexible container with heat-denatured and rose fish eggs does not provide separation during storage, suppression of separation due to repeated use, shape retention, and extrusion suitability. Invention.

【0004】[0004]

【課題を解決するための手段】本発明者等は、上記目的
を達成するために種々研究した結果、本発明を完成し
た。すなわち、(1)加熱変性してなる魚卵及び油脂か
らなる魚卵組成物が可撓性容器に充填された魚卵食品で
あって、油脂として低融点油脂と高融点油脂を含有し、
油脂含量が魚卵組成物の5%以上25%以下、魚卵含量
が20%以上60%以下、かつ魚卵組成物の5℃以上3
5℃以下における粘度が4000mPa・s以上100
万mPa・s以下である魚卵食品、(2)低融点油脂の
上昇融点が20℃以下であり、高融点油脂の上昇融点が
40℃以上である(1)記載の魚卵食品、(3)油脂の
低融点油脂含量が65%以上99%以下であり、高融点
油脂含量が1%以上35%以下である(1)又は(2)
記載の魚卵食品である。
Means for Solving the Problems The present inventors have conducted various studies to achieve the above object, and as a result, completed the present invention. That is, (1) a fish egg food in which a fish egg composition comprising a heat-denatured fish egg and a fat and oil is filled in a flexible container, wherein the fat and oil contain a low-melting fat and a high-melting fat,
The oil content is 5% or more and 25% or less of the fish egg composition, the fish egg content is 20% or more and 60% or less, and the fish egg composition is 5 ° C or more and 3% or more.
Viscosity at 5 ° C or less is 4000 mPa · s or more and 100
(2) The fish egg food according to (1), wherein the rising melting point of the low melting point fat is 20 ° C. or less and the rising melting point of the high melting point fat is 40 ° C. or more, (3) (1) The fat or oil content of the fat or oil is 65% or more and 99% or less, and the fat or oil content of the high melting point is 1% or more and 35% or less (1) or (2).
A fish egg food as described.

【0005】[0005]

【発明の実施の形態】以下本発明を詳述する。なお、本
発明において「%」の表示は「質量%」を意味するもの
である。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail. In the present invention, the expression “%” means “% by mass”.

【0006】本発明に用いる魚卵としては、タラ、マダ
ラ、スケトウダラ、ニシン、飛魚、シシャモ等の腹子を
バラしてあるもので、タラコ、明太子、トビッコ、数の
子等として用いられているものである。用いる魚卵とし
ては、生状のものでも乾燥物でも構わないが、風味の面
より生魚卵を用いるのがよい。また、塩蔵や冷凍品も用
いることができる。なお、イクラは粒が大きいために、
本発明のような魚卵組成物として用いるには相応しくな
いものである。
[0006] The fish eggs used in the present invention include cod, madara, walleye pollock, herring, flying fish, shishamo, and the like, and are used as cod roe, mentaiko, tobiko, mazuko, etc. is there. The fish eggs to be used may be raw or dried, but raw fish eggs are preferably used in terms of flavor. Also, salted and frozen products can be used. In addition, because Ikura has a large grain,
It is not suitable for use as a fish egg composition as in the present invention.

【0007】これらの魚卵を加熱変性させるには、85
℃以上の加熱処理を施すとよい。85℃以上の加熱で、
魚卵の蛋白成分が熱変性し、風味の良好な魚卵が得られ
る。加熱するには、魚卵そのままを、あるいは、バラし
た魚卵をオーブン、ロースター等の焼成機で焼成すれば
よく、あらかじめ油脂と混合して加熱するのでも構わな
い。また、必要に応じ、適宜糖アルコール類、澱粉類、
糖類、蛋白質類、塩類、調味料、その他野菜、畜肉、魚
介類等の副原料と、予め混合してから加熱変性させるこ
ともできる。例えば、魚卵と糖アルコールの混合物を、
予め85℃以上の加熱してから用いてもよい。100℃
以上の加熱を施すと魚卵は焼き風味を有するようにな
り、特に風味が良好となり望ましい。
In order to heat denature these fish eggs, 85
It is preferable to perform heat treatment at a temperature of not less than ° C. With heating over 85 ° C,
The protein component of the fish egg is thermally denatured, and a fish egg with good flavor is obtained. To heat, the fish eggs may be baked as they are or rose fish eggs may be baked in a baking machine such as an oven or a roaster. In addition, if necessary, sugar alcohols, starches,
It is also possible to mix with sugars, proteins, salts, seasonings, and other auxiliary materials such as vegetables, livestock meat, fish and shellfish in advance, and then heat-denature them. For example, a mixture of fish egg and sugar alcohol,
It may be used after heating at 85 ° C. or more in advance. 100 ℃
When the above-mentioned heating is performed, the fish eggs have a baked flavor, and the flavor is particularly good, which is desirable.

【0008】また、魚卵は、ほぐして、バラ卵として用
いるとよい。バラ状の魚卵を油脂と混合して、魚卵がほ
ぼ均一に分散している魚卵組成物にすることで、可撓性
容器から、押し出したときに外観が良好となる。また、
パスタソースなどとして用いる場合に、パスタに絡め易
くなる。そして、魚卵特有のツブツブ感を呈するので、
魚卵を擂り潰さない程度にバラして用いればよい。例え
ば、魚卵の種類にもよるが、スケトウダラやシシャモの
腹子の場合、1mm目程度の網で濾してきょう雑物を取り
除いて用いるとよい。生タラコや明太子のようにツブツ
ブ感を呈し、舌触り、食感の良好な魚卵組成物が得られ
るものである。なお、魚卵を擂り潰して、魚卵風味を向
上させ調味のために添加してもよいことは言うまでな
い。
[0008] The fish eggs may be loosened and used as rose eggs. By mixing a rose-shaped fish egg with an oil or fat to form a fish egg composition in which the fish eggs are substantially uniformly dispersed, the appearance becomes good when extruded from a flexible container. Also,
When used as a pasta sauce or the like, it becomes easy to entangle with pasta. And because it shows a peculiar feeling peculiar to fish eggs,
It is sufficient to use the fish eggs so that they are not crushed. For example, although it depends on the type of fish egg, in the case of walleye pollock or shishamo litter, it is preferable to use a net of about 1 mm to remove foreign matter. It is a fish egg composition which has a smooth texture like a raw taraco or a mentaiko and has a good texture and texture. Needless to say, the fish eggs may be ground to improve the fish egg flavor and added for seasoning.

【0009】魚卵を配合する量としては、魚卵組成物全
体に対し、生魚卵で20%以上60%以下にするとお握
り、お寿司の具、パスタソースとして用いるのに、魚卵
の風味が良好で、魚卵のツブツブ感があり、舌触り、食
感が美味しく感じられるので、より望ましい。なお、魚
卵の配合量は、魚卵の種類によっても異なるが固形分換
算で約5%〜20%に相当する。
[0009] The amount of the fish egg to be blended should be 20% or more and 60% or less of the raw fish egg with respect to the whole fish egg composition. It is more desirable because it is good, has a slick feeling of fish eggs, and has a pleasant texture and texture. The amount of fish egg varies depending on the type of fish egg, but is equivalent to about 5% to 20% in terms of solid content.

【0010】魚卵組成物は水分のあるほうが、風味が良
好で美味しく感じられる。乾燥した魚卵を用いて別途水
分を添加するのでも構わないが、この水分は、魚卵由来
の水分の方が風味が良く、よって、生魚卵を用いるのが
よい。魚卵組成物中の水分含量としては、用いる魚卵に
よっても多少異なるが10%以上40%以下程度にする
とよい。水分が多くなり過ぎても、水分離や、保型性、
保存安定性が低下する。
[0010] A fish egg composition having a higher moisture content has a better flavor and feels more delicious. Although it is possible to add water separately using dried fish eggs, this water derived from fish eggs has a better flavor, and therefore it is preferable to use raw fish eggs. The water content in the fish egg composition varies slightly depending on the fish egg used, but is preferably about 10% to 40%. Water separation, shape retention,
Storage stability decreases.

【0011】本発明に用いる低融点油脂としては、例え
ば、菜種油、コーン油、サフラワー油、綿実油、大豆
油、オリーブ油、ピーナッツ油、ヒマワリ油、ゴマ油、
米油、魚油等の天然油脂、これら天然油脂を微水添した
もの、これらの油脂から高融点部分を除いたもの、これ
らの油脂の低融点部分を集めたもの等をあげることがで
き、このような油脂の単独種を使用してもよく、複数種
を併用してもよい。これらの中でも上昇融点20℃以下
の油脂が望ましく、特に、上昇融点0〜15℃の油脂で
あると、より安定性が得られ望ましい。
Examples of the low melting point fat used in the present invention include rapeseed oil, corn oil, safflower oil, cottonseed oil, soybean oil, olive oil, peanut oil, sunflower oil, sesame oil,
Rice oil, natural oils such as fish oils, those obtained by slightly hydrogenating these natural oils and fats, those obtained by removing the high melting point parts from these oils and fats, and those obtained by collecting the low melting point parts of these oils and fats. A single kind of such fats and oils may be used, or a plurality of kinds may be used in combination. Among them, fats and oils having a rising melting point of 20 ° C. or less are desirable. In particular, fats and oils having a rising melting point of 0 to 15 ° C. are preferable because more stability can be obtained.

【0012】次に本発明の高融点油脂としては、動植物
油脂を水添して得られる油脂や、高融点部分を集めた油
脂等がある。これらの中でも、上昇融点が40℃以上の
油脂が望ましく、特に、上昇融点50℃以上の油脂であ
ると、より安定性が得られ望ましい。このような油脂と
して風味や品質安定性の面から、菜種極度硬化油脂、牛
脂極度硬化油脂、極度硬化ヤシ油をあげることができ
る。なお、このような油脂の単独種を使用してもよく、
複数種を併用してもよい。
The high melting point fats and oils of the present invention include fats and oils obtained by hydrogenating animal and vegetable fats and oils, and fats and oils obtained by collecting high melting point portions. Among them, oils and fats having a rising melting point of 40 ° C. or more are desirable. In particular, oils and fats having an increasing melting point of 50 ° C. or more are preferable because more stability can be obtained. Examples of such fats and oils include rapeseed extremely hardened fat, beef tallow extremely hardened fat, and extremely hardened coconut oil in view of flavor and quality stability. Incidentally, a single kind of such fats and oils may be used,
A plurality of types may be used in combination.

【0013】魚卵組成物中の油脂における低融点油脂と
高融点油脂の占める割合としては、低融点油脂含量を油
脂の65〜99%とし、高融点油脂含量を油脂の1〜3
5%とするとよく、低融点油脂含量を油脂の80〜97
%とし、高融点油脂含量を油脂の3〜20%とするとよ
り望ましい。これにより、温度変化による液油の分離を
特に抑制することができ、長期間にわたって安定した品
質で保存することができる。これに対し、高融点油脂の
比率が高すぎると油脂組成物が硬くなり、ボソボソ感を
呈する。反対に低すぎると液油が分離したり、魚卵やそ
の他の具材が凝集したりする。
The proportion of the low-melting-point fat and the high-melting-point fat in the oil-and-fat composition in the fish egg composition is such that the low-melting-point fat and oil content is 65-99% of the fat and oil, and the high-melting-point fat and oil content is 1-3
The content of the low melting point fat is preferably 80 to 97% of the fat and oil.
% And the high melting point fat content is preferably 3 to 20% of the fat or oil. Thereby, the separation of the liquid oil due to the temperature change can be particularly suppressed, and the liquid oil can be stored with stable quality for a long time. On the other hand, if the ratio of the high melting point fat is too high, the fat composition becomes hard and exhibits a rough feeling. Conversely, if it is too low, the liquid oil will separate or fish eggs and other ingredients will agglomerate.

【0014】魚卵組成物中の低融点油脂と高融点油脂の
双方を含む合計の油脂含量は、少なすぎると保型性を保
持しにくくなるので3%以上とするのが望ましく、また
油脂を多く配合し過ぎても油っぽくなるので25%以下
とするのが望ましい。
If the total amount of the fats and oils including both the low-melting fat and the high-melting fat in the fish egg composition is too small, it is difficult to maintain the shape-retaining property. Even if it is mixed too much, it becomes oily, so it is desirable to make it 25% or less.

【0015】魚卵組成物中に油脂として低融点油脂と高
融点油脂を含有させると、魚卵組成物を低融点油脂の融
点より低い温度から昇温した場合に、低融点油脂の融点
以下の温度で液油が分離しないだけでなく、低融点油脂
の融点を超えた温度においても液油非分離状態を維持す
るという特異的な性質を有する。温度や圧力の変化に対
して粘度が安定し、魚卵、その他の具材の凝集や沈殿も
抑制されたものとなる。
When a low melting point fat and a high melting point fat are contained in the fish egg composition as a fat or oil, when the temperature of the fish egg composition is raised from a temperature lower than the melting point of the low melting point fat or oil, it is lower than the melting point of the low melting point fat or oil. Not only does the liquid oil not separate at the temperature, but also has the unique property of maintaining the liquid oil non-separated state even at a temperature exceeding the melting point of the low melting point fat. The viscosity is stable against changes in temperature and pressure, and aggregation and precipitation of fish eggs and other ingredients are suppressed.

【0016】このような性質を有する魚卵組成物は、魚
卵、低融点油脂、高融点油脂を、例えば、85℃で加熱
混和し、室温程度に冷却し、6時間から10日間静置
し、粘度4000mPa・s以上のペースト状ないし可
塑性を有する状態とすることにより得られる。
A fish egg composition having such properties is prepared by mixing a fish egg, a low-melting oil and a high-melting oil with heating at, for example, 85 ° C., cooling to about room temperature, and allowing to stand for 6 hours to 10 days. And a viscosity of 4000 mPa · s or more in a paste state or a state having plasticity.

【0017】こうして得られる油脂組成物は、高融点油
脂の整然とした配列の間隙に低融点油脂が保持されてい
る網目構造を有すると推察される。この網目構造は、低
融点油脂と高融点油脂を加熱混和した後、−10℃以下
の冷媒を用いて急冷する、所謂、急冷捏和処理で得られ
るもの、即ち、低融点油脂中に高融点油脂の微結晶が分
散しているものとは異なる。
It is presumed that the thus obtained oil / fat composition has a network structure in which the low-melting-point oil / fat is retained in the gaps of the high-melting-point oil / fat in a regular arrangement. This network structure is obtained by so-called quenching kneading treatment, in which a low melting point fat and a high melting point fat are heated and mixed, and then quenched using a refrigerant of -10 ° C or less, that is, a high melting point fat in the low melting point fat. It is different from those in which fine crystals of fats and oils are dispersed.

【0018】魚卵組成物の粘度は、可撓性容器から押し
出す時の液だれを防止する点から、5〜35℃において
4000mPa・s〜100万mPa・sとする。これ
により、通常の室内の温度範囲において可撓性容器から
容易に押し出すことができる。より望ましい粘度は、可
撓性容器の口部の開口面積にもよるが、例えば、可撓性
容器の口部が開口面積80mm2以下の場合、可撓性容
器からの絞り出し易さの点から、3万mPa・s〜80
万mPa・sとするとよく、5万mPa・s〜50万m
Pa・sとするとより望ましい。
The viscosity of the fish egg composition is 4,000 mPa · s to 1,000,000 mPa · s at 5 to 35 ° C. in order to prevent dripping during extrusion from the flexible container. Thereby, it can be easily extruded from the flexible container in a normal room temperature range. More desirable viscosity depends on the opening area of the mouth of the flexible container, for example, when the mouth of the flexible container has an opening area of 80 mm 2 or less, from the viewpoint of easy squeezing from the flexible container. 30,000 mPa · s to 80
It is good to be 10,000 mPa · s, and 50,000 mPa · s to 500,000 m
More preferably, it is Pa · s.

【0019】用いる容器としては、食品用に用いられ細
菌等の侵入を防ぎ、密封できるものであれば、特に制限
はなく、例えば、缶詰や、あるいは、ポリエチレン(P
E)、ポリプロピレン(PP)等の単層材料、より好ま
しくは、酸素透過性の低いエチレン−ビニルアルコール
共重合体(EVOH)、塩化ビニリデン(PVDC)、
アルミニウム、その他のガスバリア材料とポリエチレン
(PE)又はポリプロピレン(PP)とからなる多層材
料等をあげることができる。また、容器形状としては、
一端に蓋付きの口部を有するチューブや、小袋等とする
ことができる。口部の形状や大きさについても、魚卵組
成物を、そこに含まれる具材ごと押し出すことができる
限り特に制限はない。丸型、矩形、星型等とすることが
できる。
The container to be used is not particularly limited as long as it is used for food and can prevent the invasion of bacteria and the like and can be sealed. For example, canned or polyethylene (P)
E), a single layer material such as polypropylene (PP), more preferably ethylene-vinyl alcohol copolymer (EVOH) having low oxygen permeability, vinylidene chloride (PVDC),
Examples include a multilayer material made of aluminum or another gas barrier material and polyethylene (PE) or polypropylene (PP). Also, as the container shape,
It can be a tube having a mouth with a lid at one end, a small bag or the like. There is no particular limitation on the shape and size of the mouth as long as the fish egg composition and the ingredients contained therein can be extruded. It can be round, rectangular, star-shaped or the like.

【0020】なお、魚卵組成物には、副原料として必要
に応じガム類、澱粉類等の粘度調整剤や糖類、蛋白質
類、塩類、調味料、その他野菜、畜肉、魚介類等を添加
することができる。
The fish egg composition may be added with a viscosity modifier such as gums and starches, sugars, proteins, salts, seasonings, other vegetables, livestock meat, fish and shellfish as necessary as auxiliary materials. be able to.

【0021】適宜必要に応じて選択すればよいが、例え
ば、糖アルコールを添加する場合は、エリスリトール、
ソルビトール、マンニトール、マルチトール、ラクチト
ール、トレハロース、還元パラチノース、デキストリン
アルコール、還元オリゴ糖、還元水飴等を用いることが
でき、これらの中でも、甘味度50以下の糖アルコール
がよく、風味の面から還元オリゴ糖、還元水飴を用いる
と特によい。糖アルコールを用いる場合は、魚卵組成物
全体に対し20%以上40%以下程度にするとよい。こ
の範囲であると、魚卵組成物が凝固せず、褐変を適度に
調整し、食品の具、あるいは、料理の素として用い易い
粘度を保持するものとなる。また、加熱することで、魚
卵が良好な風味を有するものとなる。
It is possible to appropriately select as needed. For example, when a sugar alcohol is added, erythritol,
Sorbitol, mannitol, maltitol, lactitol, trehalose, reduced palatinose, dextrin alcohol, reduced oligosaccharides, reduced syrup can be used. It is particularly preferable to use sugar and reduced starch syrup. When a sugar alcohol is used, the content is preferably about 20% to 40% based on the whole fish egg composition. Within this range, the fish egg composition does not coagulate, moderately adjusts browning, and retains a viscosity that is easy to use as a food ingredient or cooking ingredient. Further, by heating, the fish egg has a good flavor.

【0022】また、魚卵組成物のボディー感を保持させ
るために、澱粉類、増粘多糖類、食物繊維類等を用いる
とよい。澱粉類の中でも、冷水で膨潤するα化澱粉を用
いるとよく、市販されているものでよい。例えば、α化
タピオカ澱粉、α化馬鈴薯澱粉、α化コーンスターチ、
α化小麦澱粉等が挙げられる。添加率としては、魚卵組
成物全体に対し、固形分換算で1%以上4%以下程度添
加するとよい。この範囲であると、水分離が抑制され、
容器から押し出したときの魚卵組成物のボディー感が良
好となる。また、食品用セルロース等の食物繊維を添加
することで、魚卵のツブツブ感を、より強調することが
でき、食感が良好となる。用いる食物繊維としては、
0.01〜1mm程度のものが良く、1μm程度の微結
晶セルロースは適さない。微結晶セルロースであると、
ツブツブ感が得られず、好ましくない。添加率として
は、魚卵組成物全体に対し、固形分換算で0.1%以上
1%以下であるのが望ましい。添加率が0.1%を下回
ると効果が得られ難く、1%を上回ると食物繊維のボソ
ボソ感が出て逆に食感が劣るものとなる。
Further, in order to maintain the body feeling of the fish egg composition, starches, thickening polysaccharides, dietary fibers and the like are preferably used. Among the starches, pregelatinized starch that swells with cold water may be used, and commercially available starch may be used. For example, pregelatinized tapioca starch, pregelatinized potato starch, pregelatinized corn starch,
Gelatinized wheat starch and the like can be mentioned. The addition ratio is preferably about 1% or more and 4% or less in terms of solid content based on the whole fish egg composition. In this range, water separation is suppressed,
The body feeling of the fish egg composition when extruded from the container is improved. Further, by adding dietary fiber such as cellulose for food, the lumpy feeling of fish eggs can be further emphasized, and the texture is improved. As the dietary fiber used,
Those having a size of about 0.01 to 1 mm are preferable, and microcrystalline cellulose having a size of about 1 μm is not suitable. When it is microcrystalline cellulose,
Unsmooth feeling cannot be obtained, which is not preferable. The addition ratio is preferably 0.1% or more and 1% or less in terms of solid content with respect to the whole fish egg composition. If the addition ratio is less than 0.1%, the effect is hardly obtained, and if it exceeds 1%, the dietary fiber has a loose feeling and conversely the texture is inferior.

【0023】本発明の魚卵組成物は、20℃〜35℃程
度の常温で1ヶ月以上、あるいは、6ヶ月以上保存でき
るように、密封容器詰としてある。常温で保存可能とす
るためには、耐熱性菌を死滅させるのに十分な加熱殺菌
を施してもよいが、加熱・が過酷であるので、食品とし
ての美味しさが損なわれる場合があり、そのような場合
には、死滅させるにいたらない加熱でも水分活性を0.
75以上0.85以下として常温保存可能とすることが
できる。水分活性は塩分、糖類等で適宜調整するとよ
い。
The fish egg composition of the present invention is packed in a sealed container so that it can be stored at room temperature of about 20 ° C. to 35 ° C. for 1 month or more, or 6 months or more. In order to be storable at room temperature, heat sterilization may be applied enough to kill the heat-resistant bacteria, but since the heating is severe, the taste as food may be impaired. In such a case, the water activity can be reduced to 0.
It can be stored at room temperature at 75 to 0.85. The water activity may be appropriately adjusted with salts, sugars and the like.

【0024】次に本発明の魚卵組成物の代表的製造方法
について説明する。タラ、マダラ、スケトウダラ、ニシ
ン、飛魚、シシャモ等の腹子を、必要に応じて腹子を包
んでいる皮等を取り除き、ほぐした魚卵を準備する。用
いる魚卵は、塩蔵品でも凍結品を用いてもよい。例え
ば、攪拌機付き二重釜に、生魚卵、低融点油脂、高融点
油脂、その他必要に応じて澱粉類、増粘多頭類、糖アル
コール、塩類、清水、調味料等の副原料を投入し、攪拌
混合しながら、85℃以上に昇温し、魚卵が加熱変性
し、焼き風味を有する程度に加熱するとよい。続いて、
このまま蓋付チューブ容器や、小袋等の可撓性容器に充
填密封し、6時間から10日間、好ましくは2日間〜5
日間常温で静置する。なお、必要に応じ、容器に充填密
封後、常法に従い100℃以上で加圧加熱殺菌を施して
もよい。あるいは、包装体に充填する前に100℃以上
でアセプティック殺菌した後、これを包装体に無菌的に
充填・密封することもできる。また、保存性を持たせる
ために、菌数を減らす目的に応じて常法に従い加熱温
度、時間を適宜選択し、加熱後は常法に従い、冷却すれ
ばよい。
Next, a typical method for producing the fish egg composition of the present invention will be described. The litters of cod, cod, walleye pollock, herring, flying fish, shishamo, etc. are removed as necessary, and the skin surrounding the litter is removed to prepare unraveled fish eggs. The fish egg used may be a salted product or a frozen product. For example, in a double kettle equipped with a stirrer, raw fish eggs, low melting oils and fats, high melting oils and fats, if necessary, starch, thickening polycephalus, sugar alcohols, salts, fresh water, seasoning, etc. The temperature may be raised to 85 ° C. or higher while stirring and mixing, and the egg may be heated and denatured by heating to such an extent that it has a grilled flavor. continue,
As it is, the container is filled and sealed in a flexible container such as a tube container with a lid or a small bag, and is used for 6 hours to 10 days, preferably 2 days to 5 days.
Leave at room temperature for days. If necessary, after filling and sealing the container, the container may be subjected to pressurized heat sterilization at 100 ° C. or higher according to a conventional method. Alternatively, after aseptic sterilization at 100 ° C. or higher before filling the package, the package can be aseptically filled and sealed. Further, in order to impart preservability, the heating temperature and time may be appropriately selected according to a conventional method according to the purpose of reducing the number of bacteria, and after heating, cooling may be performed according to a conventional method.

【0025】このようにして得られる本発明の魚卵組成
物は、パスタソース、ピザの具、パンのフィリング、炒
飯の素、お茶漬けの素、お握りや寿司の具として用いる
ことができる。
The thus obtained fish egg composition of the present invention can be used as pasta sauce, pizza ingredients, bread filling, fried rice ingredients, ochazuke ingredients, rice balls and sushi ingredients.

【0026】次に本発明の実施例と試験例に基づき、詳
細に説明する。 実施例1 スケトウダラの腹子を、5%の食塩水で洗浄し、目開き
1mmの篩により、きょう雑物を取り除き、得られた3
6kgのバラタラコと還元オリゴ糖35kgを混合後、
レトルトパウチに5kgづつ充填密封し、常法に従って
中心温度121℃、4分間の加圧加熱殺菌後、二重釜に
開封投入し、さらに、上昇融点5℃の菜種微水添油12
kg、上昇融点55℃の菜種極度硬化油1kg、塩8kg、バ
ター4kg、α化澱粉2.5kg、アミノ酸調味料1kg、
食品用セルロース「セキセルDC(旭化成工業株式会社
製)」0.5kgを投入して加熱しながら攪拌し、95℃
に達したところで加熱を止め、そのまま蓋付き軟質チュ
ーブ容器に100gづつ充填密封し、室温に冷却して2
日間保管して本発明の密封容器詰タラコパスタソースと
した。なお、水分活性は0.80であり、1ヶ月以上に
わたり常温保存可能であった。これを炊飯米に混ぜ合わ
せて、お握りにしたところ、焼きタラコ風味の良好なタ
ラコお握りが得られた。
Next, the present invention will be described in detail with reference to examples and test examples. Example 1 The litter of Alaska pollack was washed with 5% saline solution, and foreign matter was removed with a sieve having an opening of 1 mm to obtain 3
After mixing 6 kg of balataco and 35 kg of reduced oligosaccharide,
The retort pouch was filled and sealed in 5 kg increments, sterilized by pressurizing and heating at a center temperature of 121 ° C. for 4 minutes according to a conventional method, and then opened and placed in a double kettle.
kg, extremely hardened rapeseed oil having a rising melting point of 55 ° C. 1 kg, salt 8 kg, butter 4 kg, pregelatinized starch 2.5 kg, amino acid seasoning 1 kg,
0.5 kg of cellulose for food “Sexel DC (manufactured by Asahi Kasei Kogyo Co., Ltd.)” is added, stirred while heating, and heated to 95 ° C.
When the temperature reached, the heating was stopped, and 100 g of a soft tube container with a lid was filled and sealed as it was, and cooled to room temperature.
After storage for a day, the taraco pasta sauce packed in a sealed container of the present invention was obtained. The water activity was 0.80, and it could be stored at room temperature for one month or more. When this was mixed with cooked rice and made into a rice ball, a grilled tarako rice flavor with a good flavor was obtained.

【0027】試験例1 (油脂含量の評価) 生タラコ40kg、塩8kg、油脂、還元オリゴ糖を混
合しながら加熱し、90℃に達したところで加熱を止
め、65℃になったところで、蓋付き軟質チューブ容器
(可撓性容器)に200gづつ充填密封後、10℃の冷
却水で冷却して、室温に保管して簡易の容器詰タラコ食
品を試作した。油脂と還元オリゴ糖の配合量を、下記表
1に示すとおりに変化させて、油脂の配合量の適性値を
評価した。なお、用いた油脂は、上昇融点55℃の菜種
極度硬化油(高融点油脂)と上昇融点5℃の菜種微水添
油(低融点油脂)の配合比率を1:9にした。得られた
容器詰タラコ食品の評価方法としては、容器から絞り出
したタラコ組成物の外観と、茹でたパスタにタラコ食品
を混ぜ合わせた印象、それを食した時の風味を、次の基
準で10名の専門パネラーにより評価し、その10名の
評価値の平均を四捨五入した。この結果を表1に示す。 2:タラコの風味、まろやかさが良好で、テリがある。 1:タラコ風味は良好であるが、若干麺に絡み難く僅か
にテリに欠ける、又は、若干油っぽく感じる。 0:テリが無く、麺に絡み難い、又は油っこい。
Test Example 1 (Evaluation of oil and fat content) Heat while mixing 40 kg of raw tarako, 8 kg of salt, oil and fat, and reduced oligosaccharide, stop heating when the temperature reaches 90 ° C, and attach a lid when the temperature reaches 65 ° C. After filling and sealing 200 g of each in a flexible tube container (flexible container), the container was cooled with cooling water at 10 ° C. and stored at room temperature to produce a simple container-packed tarako food product. The appropriate amounts of the fats and oils were evaluated by changing the amounts of the fats and oils and the reduced oligosaccharides as shown in Table 1 below. In addition, the mixing ratio of the rapeseed extremely hardened oil (high melting point fat) having a rising melting point of 55 ° C and the rapeseed slightly hydrogenated oil (low melting point fat) having a rising melting point of 5 ° C was 1: 9. As an evaluation method of the obtained container-packed taraco food, the appearance of the taraco composition squeezed out of the container, the impression of mixing the taraco food with the boiled pasta, and the flavor when eating it were evaluated according to the following criteria. The evaluation was performed by a panel of experts, and the average of the evaluation values of the 10 persons was rounded off. Table 1 shows the results. 2: Tarako has a good flavor and mellowness, and has a bitter taste. 1: Tarako flavor is good, but it is hardly entangled with the noodles and slightly lacks in crispness or feels slightly oily. 0: No terry, hardly tangled with noodles, or greasy.

【0028】[0028]

【表1】 [Table 1]

【0029】表1から、油脂が5%以上、より望ましく
は10%以上であると、パスタに絡め易く、テリが良
く、タラコ風味、まろやかさの良好なタラコ組成物が得
られ、また、油脂が25%を超えると油っぽく感じら
れ、20%以下にするとより望ましいことが理解でき
る。
From Table 1, it can be seen that when the fat or oil is at least 5%, more desirably at least 10%, a taraco composition which is easy to be entangled with pasta, has a good crispness, and has a good tarako flavor and mellowness is obtained. If it exceeds 25%, it will feel oily, and if it is 20% or less, it will be understood that it is more desirable.

【0030】試験例2 (魚卵含量の評価) 油脂15kg、塩8kg、生タラコ、還元オリゴ糖を混
合しながら加熱して90℃に達したところで加熱を止
め、65℃になったところで、蓋付き軟質チューブ容器
(可撓性容器)に200gづつ充填密封後、10℃の冷
却水で冷却して、室温に保管して簡易の容器詰タラコ食
品を試作した。生タラコと還元オリゴ糖の配合量を、下
記表2に示すとおりに変化させて、魚卵の配合量の適性
値を評価した。なお、用いた油脂は、上昇融点55℃の
菜種極度硬化油(高融点油脂)と上昇融点5℃の菜種微
水添油(低融点油脂)の配合比率を1:9にした。得ら
れた容器詰タラコ食品の評価方法としては、容器から絞
り出したタラコ食品を、茹でたパスタに混ぜ合わせて用
いた時の印象と、それを食した風味を、次の基準で10
名の専門パネラーにより評価し、その10名の評価値の
平均を四捨五入した。この結果を表2に示す。 1:タラコ風味が良好で、タラコの配合量が適度であ
る。 0:タラコ風味が足りず、タラコ配合量が少な過ぎると
感じる、又は混ぜ合わせ難く、タラコ配合量が多過ぎる
と感じる。
Test Example 2 (Evaluation of Fish Egg Content) Heating was performed while mixing 15 kg of oil and fat, 8 kg of salt, raw tarako, and reduced oligosaccharide, and when the temperature reached 90 ° C., the heating was stopped. After filling and sealing 200 g of each in a flexible tube container (flexible container), the container was cooled with cooling water at 10 ° C., stored at room temperature, and a simple packaged taraco food was trial-produced. The suitability of the amount of fish egg was evaluated by changing the blending amounts of the raw cod and the reduced oligosaccharide as shown in Table 2 below. In addition, the mixing ratio of the rapeseed extremely hardened oil (high melting point fat) having a rising melting point of 55 ° C and the rapeseed slightly hydrogenated oil (low melting point fat) having a rising melting point of 5 ° C was 1: 9. As an evaluation method of the obtained packaged taraco food, the impression when the taraco food squeezed out of the container was mixed with the boiled pasta and the flavor of eating the taraco food were evaluated according to the following criteria.
The evaluation was performed by a panel of experts, and the average of the evaluation values of the 10 persons was rounded off. Table 2 shows the results. 1: Tarako flavor is good, and the amount of tarako is appropriate. 0: Tarako flavor is insufficient, and it is felt that the amount of tarako is too small, or it is difficult to mix, and that the amount of tarako is too much.

【0031】[0031]

【表2】 [Table 2]

【0032】表2から、魚卵の配合量が20%以上60
%以下であると、風味が良好で配合量が適度に感じられ
ることが理解できる。
From Table 2, it can be seen that the blended amount of fish eggs is not less than 20% and not more than 60%.
%, It can be understood that the flavor is good and the blending amount is appropriately felt.

【0033】試験例3 (容器口部に対する適性な粘度
の評価) 生タラコ40kg、還元オリゴ糖32kg、塩8kg、
油脂20kgを混合しながら加熱して、90℃に達した
ところで加熱を止め、65℃になったところで、蓋付き
軟質チューブ容器(可撓性容器)に200gづつ充填密
封後、10℃の冷却水で冷却して、室温に保管して簡易
の容器詰タラコ食品を試作し、容器口部に対する適性な
粘度を評価した。なお、粘度の調整は、油脂中の上昇融
点55℃の菜種極度硬化油(高融点油脂)と上昇融点5
℃の菜種微水添油(低融点油脂)の配合比率を変え、ま
た、室温での保管時間と保管温度を変えて行ない、その
粘度をB型粘度計で測定した。この粘度測定では、N
o.2〜No.7のローター(回転棒)を2〜10rp
mで回転させた。また、得られたタラコ食品の可撓性容
器からの絞り出し易さを、次の基準で10名の専門パネ
ラーにより評価し、その10名の評価値の平均を四捨五
入した。この結果を表3に示す。 2:可撓性容器から非常に出し易い。 1:可撓性容器から出し易い。 0:液ダレが起こる、又は可撓性容器から出ないか若し
くは出し難い。
Test Example 3 (Evaluation of suitable viscosity for container mouth) 40 kg of raw tarako, 32 kg of reduced oligosaccharide, 8 kg of salt,
20 kg of fats and oils are mixed and heated. When the temperature reaches 90 ° C., the heating is stopped. When the temperature reaches 65 ° C., 200 g of a soft tube container with a lid (flexible container) is filled and sealed, and then cooled at 10 ° C. , And stored at room temperature to produce a simple packaged taraco food product and evaluate the appropriate viscosity for the mouth of the container. The viscosity was adjusted by adjusting rapeseed extremely hardened oil (high melting point oil and fat) having a rising melting point of 55 ° C. in oil and fat.
The mixing ratio of rapeseed slightly hydrogenated oil (low melting point oil) at ℃ was changed, and the storage time and storage temperature at room temperature were changed, and the viscosity was measured with a B-type viscometer. In this viscosity measurement, N
o. 2-No. 7 rotor (rotating rod) 2-10rpm
m. In addition, the ease of squeezing the obtained taraco food from the flexible container was evaluated by the following standard by ten expert panelists, and the average of the evaluation values of the ten persons was rounded off. Table 3 shows the results. 2: It is very easy to take out from the flexible container. 1: Easy to take out of flexible container. 0: Liquid dripping occurs or does not come out of the flexible container or is difficult to come out.

【0034】[0034]

【表3】 [Table 3]

【0035】表3から、このタラコ食品は、可撓性容器
の開口面積を10mm2とする場合、粘度4000mP
a・s〜50万mPa・sとすることが望ましく、開口
面積を40mm2 程度とする場合には粘度4000mP
a・s〜80万mPa・s、特に、3万mPa・s〜5
0万mPa・sとすることが望ましく、また、開口面積
を80mm2 とする場合には粘度3万〜100万mPa
・s、特に、5万mPa・s〜80万mPa・sとする
ことが望ましいことがわかる。
According to Table 3, this taraco food has a viscosity of 4000 mP when the opening area of the flexible container is 10 mm 2.
a · s to 500,000 mPa · s is desirable, and when the opening area is about 40 mm 2 , the viscosity is 4000 mP · s.
a · s to 800,000 mPa · s, especially 30,000 mPa · s to 5
Desirably, the viscosity is 30,000 to 1,000,000 mPa · s when the opening area is 80 mm 2.
S, in particular, 50,000 mPa · s to 800,000 mPa · s.

【0036】試験例4 (油脂中の高融点油脂、低融点
油脂の配合比率の評価) 生タラコ40kg、還元オリゴ糖32kg、塩8kg、
油脂20kgを混合しながら加熱して90℃に達したと
ころで加熱を止め、65℃になったところで、蓋付き軟
質チューブ容器(可撓性容器)に200gづつ充填密封
後、10℃の冷却水で冷却して、室温に保管して簡易の
容器詰タラコ食品を試作した。油脂中の上昇融点55℃
の菜種極度硬化油(高融点油脂)と上昇融点5℃の菜種
微水添油(低融点油脂)の配合比率を表4に示すとおり
に変化させて、高融点油脂と低融点油脂の配合比率の適
性値を、次の基準で10名の専門パネラーにより評価し
た。なお、10名の評価値の平均を四捨五入し、この結
果を表4に示す。 2:分離が無く、保型性が良好である。 1:保型性はあるが、表面に僅かな分離が認められる。 0:分離し液ダレを起こす、又は容器から出し難い。
Test Example 4 (Evaluation of blending ratio of high melting point fat and low melting point fat in fats and oils) 40 kg of raw tarako, 32 kg of reduced oligosaccharide, 8 kg of salt,
When 20 kg of fats and oils were mixed and heated to 90 ° C., the heating was stopped. When the temperature reached 65 ° C., 200 g of a flexible tube container with a lid (flexible container) was filled and sealed, and then cooled with 10 ° C. cooling water. It was cooled and stored at room temperature to produce a simple packaged taraco food product. 55 ° C rising melting point in fats and oils
The mixing ratio of high-melting oil and low-melting oil was changed as shown in Table 4 by changing the mixing ratio of rapeseed extremely hardened oil (high-melting oil and fat) and rapeseed slightly hydrogenated oil (low-melting oil and fat) having a rising melting point of 5 ° C. Were evaluated by 10 expert panelists according to the following criteria. In addition, the average of the evaluation values of 10 persons was rounded off, and the results are shown in Table 4. 2: No separation and good shape retention. 1: There is shape retention, but slight separation is observed on the surface. 0: Separation causes liquid dripping or is difficult to remove from the container.

【0037】[0037]

【表4】 [Table 4]

【0038】表4から、魚卵組成物中の油脂における低
融点油脂と高融点油脂の占める割合としては、低融点油
脂含量を油脂の65〜99%とし、高融点油脂含量を油
脂の1〜35%とすると保型性のある分離が抑制された
魚卵食品が得られ、低融点油脂含量を油脂の80〜97
%とし、高融点油脂含量を油脂の3〜20%とするとよ
り望ましいことが分かる。
From Table 4, the ratio of the low-melting-point fat and the high-melting-point fat in the oil-and-fat composition in the fish-egg composition is such that the low-melting-point fat and oil content is 65-99% of the fat and oil, and the high-melting-point fat and oil content is 1- When the content is 35%, a fish egg food having a shape retaining property and in which separation is suppressed is obtained, and the low melting point fat content is 80 to 97% of the fat content.
% And the high melting point fat content is preferably 3 to 20% of the fat.

【0039】[0039]

【発明の効果】以上述べたように、本発明の可撓性容器
詰魚卵食品は、必要な時に手軽に軟質チューブ容器から
押し出して使用することができ、魚卵風味が良好で、パ
スタ等に絡め易く、分離が抑制され、容器からの押出し
適性が良好な粘度であり、押し出した後のテリ、保型性
があり、常温で長期間保存できるので、パスタソース、
ピザの具、パンのフィリング、炒飯の素、お茶漬けの
素、お握りや寿司の具として好適である。
As described above, the flexible container-packed fish egg food of the present invention can be easily pushed out of a flexible tube container when needed, and has a good fish egg flavor, pasta and the like. It is easy to entangle, separation is suppressed, extrudability from the container is good viscosity, it has a shape after extruding, it has shape retention, it can be stored at room temperature for a long time, so pasta sauce,
It is suitable as a pizza ingredient, bread filling, fried rice ingredients, ochazuke ingredients, rice balls and sushi ingredients.

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 加熱変性してなる魚卵及び油脂からなる
魚卵組成物が可撓性容器に充填された魚卵食品であっ
て、油脂として低融点油脂と高融点油脂を含有し、油脂
含量が魚卵組成物の5%以上25%以下、魚卵含量が2
0%以上60%以下、かつ魚卵組成物の5℃以上35℃
以下における粘度が4000mPa・s以上100万m
Pa・s以下である魚卵食品。
1. A fish egg food in which a fish egg composition comprising a heat-denatured fish egg and a fat is filled in a flexible container, wherein the fat contains a low-melting fat and a high-melting fat as a fat. The content is 5% or more and 25% or less of the fish egg composition, and the fish egg content is 2
0% to 60%, and 5 ° C to 35 ° C of the fish egg composition
Viscosity at or below 4000 mPa · s to 1,000,000 m
Fish egg food having Pa · s or less.
【請求項2】 低融点油脂の上昇融点が20℃以下であ
り、高融点油脂の上昇融点が40℃以上である請求項1
記載の魚卵食品。
2. The rising melting point of the low melting point fat is 20 ° C. or less, and the rising melting point of the high melting point fat is 40 ° C. or more.
Fish egg food as described.
【請求項3】 油脂の低融点油脂含量が65%以上99
%以下であり、高融点油脂含量が1%以上35%以下で
ある請求項1又は2記載の魚卵食品。
3. The fat or oil having a low melting point fat content of 65% or more and 99% or less.
The fish egg food according to claim 1 or 2, wherein the high melting point oil content is 1% or more and 35% or less.
JP2000053076A 2000-02-29 2000-02-29 Flexible packaged fish egg food Expired - Fee Related JP3295407B2 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011250712A (en) * 2010-05-31 2011-12-15 Nisshin Foods Kk Fish egg containing sauce
JP2014003918A (en) * 2012-06-21 2014-01-16 Q P Corp Gas-containing oil-and-fat food
JP2015156816A (en) * 2014-02-24 2015-09-03 日本水産株式会社 Roes-molded product, and production method thereof
JP2015208315A (en) * 2014-04-30 2015-11-24 旭化成ケミカルズ株式会社 Liquid composition comprising water-insoluble component

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011250712A (en) * 2010-05-31 2011-12-15 Nisshin Foods Kk Fish egg containing sauce
JP2014003918A (en) * 2012-06-21 2014-01-16 Q P Corp Gas-containing oil-and-fat food
JP2015156816A (en) * 2014-02-24 2015-09-03 日本水産株式会社 Roes-molded product, and production method thereof
JP2015208315A (en) * 2014-04-30 2015-11-24 旭化成ケミカルズ株式会社 Liquid composition comprising water-insoluble component

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