JP2001220595A - Oil and fat composition - Google Patents
Oil and fat compositionInfo
- Publication number
- JP2001220595A JP2001220595A JP2000030310A JP2000030310A JP2001220595A JP 2001220595 A JP2001220595 A JP 2001220595A JP 2000030310 A JP2000030310 A JP 2000030310A JP 2000030310 A JP2000030310 A JP 2000030310A JP 2001220595 A JP2001220595 A JP 2001220595A
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- JP
- Japan
- Prior art keywords
- weight
- oil
- polyglycerin
- fatty acid
- acid ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、高濃度の植物ステ
ロールを含有し、その使用中又は保存中に結晶化を起こ
さない液状油脂組成物、及び植物ステロールの溶解性に
優れ、かつその結晶化を長期間抑制し得る植物ステロー
ル溶解剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a liquid oil / fat composition containing a high concentration of plant sterol and not causing crystallization during use or storage, and excellent solubility of plant sterol and its crystallization. The present invention relates to a plant sterol dissolving agent capable of suppressing the long term.
【０００２】[0002]
【従来の技術】植物ステロールは、遊離状態、脂肪酸エ
ステル、配糖体、フェルラ酸エステル等の形態で広く植
物に存在するステロイドアルコールである。かかる植物
ステロールは、優れた血中コレステロール低下作用を有
するため、これを料理油、サラダ油等の食用油脂に配合
することが行われている。2. Description of the Related Art Plant sterols are steroid alcohols widely present in plants in the free state, in the form of fatty acid esters, glycosides, ferulic acid esters and the like. Since such plant sterols have an excellent blood cholesterol lowering effect, they are blended with edible oils and fats such as cooking oil and salad oil.
【０００３】しかし、植物ステロールは天然物からの抽
出、濃縮及び精製の段階で加水分解され、ほとんどが遊
離の状態となるが、この遊離状態の植物ステロールは食
用油脂に対して極めてわずかしか溶解しないという問題
がある。[0003] However, plant sterols are hydrolyzed at the stage of extraction, concentration and purification from natural products, and are mostly in a free state, but the plant sterol in the free state is very slightly soluble in edible oils and fats. There is a problem.
【０００４】そこで、植物ステロールを食用油脂に対し
て大量に配合すべく、種々の技術開発がなされている。
例えば、溶解剤（乳化剤）を用いて植物ステロールを食
用油脂に配合する技術として、炭素数６〜18の脂肪酸若
しくはその多価アルコールモノエステル又は炭素数６〜
18のアルカノールを用いる方法（特開昭50-40605号公
報）、多価アルコール脂肪酸エステル等の一般的な食品
用乳化剤を用いる方法（特開昭62-148424号公報）、エ
ステル化度２以上の多価アルコール脂肪酸エステルを用
いる方法（WO99/59423）等が知られている。[0004] Therefore, various techniques have been developed in order to mix plant sterols with edible fats and oils in large amounts.
For example, as a technique for blending vegetable sterols into edible oils and fats using a dissolving agent (emulsifier), a fatty acid having 6 to 18 carbon atoms or a polyhydric alcohol monoester or a carbon ester having 6 to 18 carbon atoms can be used.
A method using 18 alkanols (JP-A-50-40605), a method using a general food emulsifier such as a polyhydric alcohol fatty acid ester (JP-A-62-148424), A method using a polyhydric alcohol fatty acid ester (WO99 / 59423) is known.
【０００５】しかし、これらの技術による植物ステロー
ルの溶解効果は不十分であり、調製された植物ステロー
ルを配合した食用油脂組成物は、調整時には清澄な外観
を保っているものの、その使用中又は保存中に空気中の
水分を吸収し、植物ステロールの結晶を生じてしまい、
著しく商品価値を損なうという問題があった。[0005] However, the dissolving effect of plant sterols by these techniques is insufficient, and the edible oil / fat composition containing the prepared plant sterols has a clear appearance at the time of preparation, but during use or storage. Absorbs moisture in the air inside, and produces crystals of plant sterols,
There is a problem that the commercial value is significantly impaired.
【０００６】[0006]
【発明が解決しようとする課題】そこで本発明は、高濃
度の植物ステロールを含有し、その使用中又は保存中に
植物ステロールの結晶化を起こさず、一般の食用油脂と
同様に問題なく使用できる液状油脂組成物、及び植物ス
テロールの溶解性に優れ、かつその結晶化を長期間抑制
し得る植物ステロール溶解剤を提供することを目的とす
る。Therefore, the present invention contains a high concentration of plant sterol, does not cause crystallization of the plant sterol during use or storage, and can be used without any problem similarly to general edible oils and fats. It is an object of the present invention to provide a liquid oleaginous composition and a plant sterol dissolving agent which is excellent in solubility of plant sterol and can suppress crystallization thereof for a long time.
【０００７】[0007]
【課題を解決するための手段】本発明者らは、エステル
化度の低いポリグリセリン脂肪酸エステルが植物ステロ
ールの溶解性に優れていること、並びに、その一方で、
このポリグリセリン脂肪酸エステル中に含まれる遊離の
グリセリン及びポリグリセリンが植物ステロールの結晶
化を促進してしまうことを見出した。The present inventors have found that polyglycerol fatty acid esters having a low degree of esterification have excellent solubility of plant sterols, and, on the other hand,
It has been found that free glycerin and polyglycerin contained in the polyglycerin fatty acid ester promote crystallization of plant sterols.
【０００８】本発明は、(1)遊離のグリセリン及びポリ
グリセリンの合計含量が１重量％未満であり平均エステ
ル化度が0.99を超え２未満であるポリグリセリン不飽和
脂肪酸エステル、及び(2)植物ステロールを溶解状態で
含有する液状油脂組成物を提供するものである。The present invention relates to (1) a polyglycerin unsaturated fatty acid ester having a total content of free glycerin and polyglycerin of less than 1% by weight and an average degree of esterification of more than 0.99 and less than 2, and (2) a plant; It is intended to provide a liquid oil / fat composition containing sterol in a dissolved state.
【０００９】また本発明は、遊離のグリセリン及びポリ
グリセリンの合計含量が１重量％未満であり平均エステ
ル化度が0.99を超え２未満であるポリグリセリン不飽和
脂肪酸エステルからなる植物ステロール溶解剤を提供す
るものである。The present invention also provides a plant sterol dissolving agent comprising a polyglycerin unsaturated fatty acid ester having a total content of free glycerin and polyglycerin of less than 1% by weight and an average degree of esterification of more than 0.99 and less than 2. Is what you do.
【００１０】[0010]
【発明の実施の形態】本発明において植物ステロール溶
解剤として使用される成分(1)のポリグリセリン不飽和
脂肪酸エステルは、植物ステロールの溶解性の点から、
平均エステル化度が0.99を超え２未満であることが必要
であり、更に１〜1.5、特に１〜1.2の範囲が好ましい。BEST MODE FOR CARRYING OUT THE INVENTION The polyglycerin unsaturated fatty acid ester of the component (1) used as a plant sterol-dissolving agent in the present invention has a high solubility in plant sterols.
It is necessary that the average degree of esterification is more than 0.99 and less than 2, more preferably 1 to 1.5, particularly preferably 1 to 1.2.
【００１１】また、上記ポリグリセリン不飽和脂肪酸エ
ステルのポリグリセリン部分の平均重合度は、植物ステ
ロールの溶解性の観点から、1.5〜３、特に1.8〜2.2が
好ましい。またポリグリセリン不飽和脂肪酸エステルの
不飽和脂肪酸としては、炭素数14〜24のもの、例えばミ
リストレイン酸、パルミトレイン酸、オレイン酸、リノ
ール酸、リノレン酸、イコセン酸、ドコセン酸、テトラ
コセン酸等が挙げられ、なかでもオレイン酸が好まし
い。The average degree of polymerization of the polyglycerol moiety of the polyglycerol unsaturated fatty acid ester is preferably from 1.5 to 3, particularly preferably from 1.8 to 2.2, from the viewpoint of the solubility of plant sterols. Examples of the unsaturated fatty acid of the polyglycerin unsaturated fatty acid ester include those having 14 to 24 carbon atoms, such as myristoleic acid, palmitoleic acid, oleic acid, linoleic acid, linolenic acid, icosenoic acid, docosenoic acid, and tetracosenoic acid. Oleic acid is particularly preferred.
【００１２】成分(1)中に含まれる遊離のグリセリン及
びポリグリセリンの量は、空気中の水分の吸収による植
物ステロールの結晶化を抑制する観点から、合計で１重
量％未満であることが必要であり、0.5重量％以下であ
ることが好ましい。ポリグリセリン不飽和脂肪酸エステ
ル中の遊離のグリセリン及びポリグリセリンの含量を減
少させる方法としては、カラムクロマトグラフィーによ
り分画する方法、また工業的には、油脂にポリグリセリ
ン不飽和脂肪酸エステルを高濃度溶解しスチーミングに
付す方法、分子蒸留による方法等が挙げられる。The amount of free glycerin and polyglycerin contained in the component (1) needs to be less than 1% by weight in total from the viewpoint of suppressing crystallization of plant sterols due to absorption of moisture in the air. And preferably 0.5% by weight or less. As a method for reducing the content of free glycerin and polyglycerin in the polyglycerin unsaturated fatty acid ester, a method of fractionating by column chromatography, or industrially, dissolving polyglycerin unsaturated fatty acid ester in fats and oils at a high concentration Steaming, molecular distillation and the like.
【００１３】上記ポリグリセリン不飽和脂肪酸エステル
は、１種以上を適宜選択して使用でき、本発明の液状油
脂組成物中の含有量は、植物ステロールの溶解効果の点
から0.5重量％以上、また調理油としての風味、調理性
能等の点から５重量％以下が好ましい。以上を勘案すれ
ば、本発明の液状油脂組成物中の成分(1)の含有量は、
0.5〜５重量％、更に２〜５重量％が好ましい。One or more of the above-mentioned polyglycerin unsaturated fatty acid esters can be appropriately selected and used. The content in the liquid oil / fat composition of the present invention is 0.5% by weight or more in view of the effect of dissolving plant sterols. The content is preferably 5% by weight or less from the viewpoint of the flavor as a cooking oil and the cooking performance. In view of the above, the content of the component (1) in the liquid oil and fat composition of the present invention,
0.5-5% by weight, more preferably 2-5% by weight.
【００１４】本発明に用いる成分(2)の植物ステロール
としては特に限定されないが、α-シトステロール、β-
シトステロール、スチグマステロール、カンペステロー
ル、α-シトスタノール、β-シトスタノール、スチグマ
スタノール、カンペスタノール、シクロアルテノール
等、及びこれらの脂肪酸エステル、フェルラ酸エステ
ル、桂皮酸エステル、配糖体などが挙げられる。The plant sterol of the component (2) used in the present invention is not particularly restricted but includes α-sitosterol and β-sitosterol.
Sitosterol, stigmasterol, campesterol, α-sitostanol, β-sitostanol, stigmastanol, campestanol, cycloartenol, etc., and their fatty acid esters, ferulic acid esters, cinnamic acid esters, glycosides, etc. No.
【００１５】上記植物ステロールは、１種以上を適宜選
択して使用できる。また植物ステロールは、本発明の液
状油脂組成物中に溶解していれば足り、その溶解量は特
に限定されないが、一般の食用油脂より血中コレステロ
ール値の低減効果を高めるという観点からは1.2重量％
以上、常温で透明な溶解性、及び経時的な溶解安定性の
点からは10重量％以下が好ましい。以上を勘案すれば、
本発明の液状油脂組成物中の成分(2)の含有量は、1.2〜
10重量％、更に1.2〜５重量％、特に２〜５重量％が好
ましい。なお、ここでの植物ステロールの含有量は、も
ともと油脂中に含まれていた量と新たに添加した量の合
計量である。One or more of the above-mentioned plant sterols can be appropriately selected and used. Further, the plant sterol is sufficient if it is dissolved in the liquid oil composition of the present invention, the amount of the dissolution is not particularly limited, but from the viewpoint of enhancing the effect of lowering the blood cholesterol level than general edible oil and fat 1.2 weight. %
As described above, the content is preferably 10% by weight or less from the viewpoint of transparent solubility at room temperature and stability over time. With the above in mind,
The content of the component (2) in the liquid fat composition of the present invention is 1.2 to
10% by weight, preferably 1.2 to 5% by weight, particularly preferably 2 to 5% by weight. Here, the content of plant sterol is the total amount of the amount originally contained in the fat and oil and the newly added amount.
【００１６】本発明に使用される油脂としては、一般的
な食用油脂であれば特に限定されず、天然の動植物油脂
のほか、それらにエステル交換、水素添加、分別等を施
した加工油脂が挙げられ、好ましいものとして、大豆
油、ナタネ油、米糠油、コーン油等の植物油及びそれら
の加工油脂が挙げられる。また、これら一般的な食用油
脂に代え、又はこれらに加え、ジアシルグリセロールを
使用することもできる。ジアシルグリセロールは一般的
な食用油脂に比べ、より多量の植物ステロールを溶解す
ることが可能であり、また植物ステロールとの併用によ
る脂質代謝改善効果を得ることができる。ジアシルグリ
セロールの構成脂肪酸は、炭素数が８〜24、特に12〜22
であるものが好ましく、また不飽和脂肪酸が全構成脂肪
酸の55重量％以上、特に70重量％以上であるのが好まし
い。ジアシルグリセロールは、植物ステロールの溶解性
や脂質代謝改善効果の向上のためには、本発明の液状油
脂組成物中に15重量％以上、更に30重量％以上、特に55
重量％以上配合するのが好ましい。The fats and oils used in the present invention are not particularly limited as long as they are general edible fats and oils. In addition to natural animal and vegetable fats and oils, processed fats and oils obtained by subjecting them to transesterification, hydrogenation, fractionation and the like can be mentioned. Preferred are vegetable oils such as soybean oil, rapeseed oil, rice bran oil, corn oil, and processed oils and fats thereof. In addition, diacylglycerol can be used instead of or in addition to these general edible fats and oils. Diacylglycerol can dissolve a larger amount of plant sterols than general edible oils and fats, and can achieve an effect of improving lipid metabolism when used in combination with plant sterols. Diacylglycerol constituent fatty acids have 8 to 24 carbon atoms, especially 12 to 22 carbon atoms.
The unsaturated fatty acid is preferably 55% by weight or more, more preferably 70% by weight or more of the total constituent fatty acids. In order to improve the solubility of plant sterols and the effect of improving lipid metabolism, diacylglycerol is contained in the liquid fat composition of the present invention in an amount of 15% by weight or more, more preferably 30% by weight or more, particularly 55% by weight or more.
It is preferable to mix it by weight% or more.
【００１７】本発明の液状油脂組成物には、更に一般の
食用油と同様に、保存性及び風味安定性の向上を目的と
して、抗酸化剤を添加することができる。抗酸化剤とし
ては、天然抗酸化剤、トコフェロール、アスコルビルパ
ルミテート、アスコルビルステアレート、BHT、BHA、リ
ン脂質等が挙げられる。これらは１種以上を適宜選択し
て使用することができ、添加量は50〜2000ppmが好まし
い。An antioxidant can be added to the liquid oil / fat composition of the present invention for the purpose of improving storage stability and flavor stability, as in the case of general edible oils. Examples of the antioxidant include natural antioxidants, tocopherol, ascorbyl palmitate, ascorbyl stearate, BHT, BHA, phospholipid and the like. One or more of these can be appropriately selected and used, and the addition amount is preferably 50 to 2000 ppm.
【００１８】本発明の液状油脂組成物は、一般の食用油
とまったく同様に使用でき、油脂を用いた各種飲食物に
広範に適用することができる。例えば、ドリンク、デザ
ート、アイスクリーム、ドレッツシング、トッピング、
マヨネーズ、焼き肉のたれ等の水中油型乳化油脂加工食
品；マーガリン、スプレッド等の油中水型乳化油脂加工
食品；ピーナッツバター、フライングショートニング、
ベーキングショートニング等の加工油脂食品；ポテトチ
ップ、スナック菓子、ケーキ、クッキー、パイ、パン、
チョコレート等の加工食品、更にベーカリーミックス、
加工肉製品、冷凍アントレ、冷凍食品等に使用できる。The liquid fat composition of the present invention can be used in exactly the same manner as general edible oils, and can be widely applied to various foods and drinks using fats and oils. For example, drinks, desserts, ice cream, dressings, toppings,
Oil-in-water emulsified oil / fat processed food such as mayonnaise and grilled meat sauce; Water-in-oil emulsified oil / fat processed food such as margarine and spread; Peanut butter, flying shortening,
Processed oil and fat foods such as baking shortening; potato chips, snacks, cakes, cookies, pies, breads,
Processed foods such as chocolate, bakery mix,
It can be used for processed meat products, frozen entrées, frozen foods, etc.
【００１９】[0019]
【実施例】実施例１ 表１に示す各種乳化剤を用い、表２に示す組成の油脂組
成物を調製し、その保存安定性を評価した結果を表２に
併せて示す。EXAMPLES Example 1 An oil / fat composition having the composition shown in Table 2 was prepared using various emulsifiers shown in Table 1, and the storage stability was evaluated. The results are also shown in Table 2.
【００２０】〔使用成分〕 乳化剤Ａ：サンソフトQ-17B（ジグリセリンモノ・ジオ
レイン酸エステル；太陽化学社製） 乳化剤Ｂ，Ｃ：サンソフトQ-17B（太陽化学社製）をカ
ラムクロマトグラフィーにより分画して得られるもの。 乳化剤Ｄ：サンソフトQ-17B（太陽化学社製）30ｇをジ
アシルグリセロール（ アシル基：ナタネ油脂肪酸由来、全脂肪酸に対する不飽
和脂肪酸量92重量％、トリグリセリド16重量％，ジグリ
セリド83重量％，モノグリセリド１重量％）70ｇに溶解
し、180℃、53.3Paの条件で３時間スチーミングして得
られるもの。 乳化剤Ｅ：ポエムDO-100（理研ビタミン社製；ジグリセ
リンモノオレイン酸エステル） 乳化剤Ｆ：固定化1,3位選択的リパーゼである市販のリ
パーゼ製剤（Lipozyme3A，ノボ・インダストリー社製）
20ｇ、オレイン酸（東京化成社製；パルミチン酸1.5重
量％，ステアリン酸2.6重量％，オレイン酸89.4重量
％，リノール酸4.5重量％）100g及びジグリセリン（K-C
OL-II，鹿島ケミカル社製）27ｇを混合し、45℃で系内
を667Paに減圧しながら６時間反応を行う。反応終了物
からリパーゼ製剤を濾別し、未反応物質を分子蒸留によ
り分離して得られるもの。 植物ステロール：タマ生化学社製、純度95重量％、β-
シトステロール52重量％、スチグマステロール25重量
％、カンペステロール20重量％、ブラシカステロール３
重量％ 油脂ａ：精製ナタネ油 油脂ｂ：ジアシルグリセロール（アシル基：大豆油脂肪
酸由来、全脂肪酸に対する不飽和脂肪酸量95重量％、ト
リグリセリド11重量％，ジグリセリド88重量％，モノグ
リセリド１重量％）[Ingredients] Emulsifier A: Sunsoft Q-17B (diglycerin mono-dioleate; manufactured by Taiyo Kagaku) Emulsifiers B and C: Sunsoft Q-17B (manufactured by Taiyo Chemical) by column chromatography. What is obtained by fractionation. Emulsifier D: 30 g of Sunsoft Q-17B (manufactured by Taiyo Chemical Co., Ltd.) in diacylglycerol (acyl group: derived from rapeseed oil fatty acid, 92% by weight of unsaturated fatty acid relative to total fatty acids, 16% by weight of triglyceride, 83% by weight of diglyceride, monoglyceride 1 (Wt.%) Dissolved in 70 g and steamed at 180 ° C. and 53.3 Pa for 3 hours. Emulsifier E: Poem DO-100 (manufactured by Riken Vitamin Co .; diglycerin monooleate) Emulsifier F: Commercially available lipase preparation (Lipozyme3A, manufactured by Novo Industries) which is an immobilized 1,3-position selective lipase
20 g, 100 g of oleic acid (manufactured by Tokyo Chemical Industry; palmitic acid 1.5% by weight, stearic acid 2.6% by weight, oleic acid 89.4% by weight, linoleic acid 4.5% by weight) and diglycerin (KC
OL-II, manufactured by Kashima Chemical Co., Ltd.), and reacted at 45 ° C. for 6 hours while reducing the pressure of the system to 667 Pa. A product obtained by filtering off a lipase preparation from the reaction product and separating unreacted substances by molecular distillation. Plant sterol: Tama Seikagaku, purity 95% by weight, β-
Sitosterol 52% by weight, Stigmasterol 25% by weight, Campesterol 20% by weight, Brassicasterol 3
% By weight Fat / oil a: Purified rapeseed oil Fat / oil b: Diacylglycerol (acyl group: derived from soybean oil fatty acid, 95% by weight of unsaturated fatty acid with respect to total fatty acids, 11% by weight of triglyceride, 88% by weight of diglyceride, 1% by weight of monoglyceride)
【００２１】[0021]
【表１】 [Table 1]
【００２２】〔評価方法・基準〕各油脂組成物20ｇをそ
れぞれ内径60mmのステンレス製シャーレに入れ、20℃、
80％RH条件下に１週間保存し、植物ステロールの結晶化
状態を観察し、下記基準に従って評価する。なお、各油
脂組成物は調製時にはすべて清澄な液体であり、異味や
異臭は認められない。 ○：結晶化は認められない。 △：油表面にわずかに結晶が認められる。 ×：油表面全体に結晶が認められる。[Evaluation Method / Criteria] 20 g of each fat and oil composition was placed in a stainless steel petri dish having an inner diameter of 60 mm.
After storing for 1 week under the condition of 80% RH, the crystallization state of the plant sterol is observed and evaluated according to the following criteria. In addition, each oil and fat composition is a clear liquid at the time of preparation, and no off-flavor or off-flavor is observed. ：: No crystallization was observed. Δ: Slight crystals are observed on the oil surface. ×: Crystals are observed on the entire oil surface.
【００２３】[0023]
【表２】 [Table 2]
【００２４】[0024]
【発明の効果】本発明によれば、油脂に高濃度の植物ス
テロールを溶解でき、かつその使用中又は保存中におけ
る結晶化を長期間抑制できる。According to the present invention, a high concentration of plant sterol can be dissolved in fats and oils, and crystallization during use or storage can be suppressed for a long period of time.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 中島 義信 東京都墨田区文花２−１−３ 花王株式会 社研究所内 Ｆターム(参考） 4B018 MD14 MD48 ME14 4B026 DC05 DK01 DL05 DX01 4H059 BA34 BB02 BB03 BB04 BB05 BB06 BB57 BC03 BC13 CA51 DA22 DA30 EA01 EA13 ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Yoshinobu Nakajima 2-1-3 Bunka, Sumida-ku, Tokyo F-term in Kao Corporation Research Laboratory F-term (reference) 4B018 MD14 MD48 ME14 4B026 DC05 DK01 DL05 DX01 4H059 BA34 BB02 BB03 BB04 BB05 BB06 BB57 BC03 BC13 CA51 DA22 DA30 EA01 EA13
Claims (5)
ンの合計含量が１重量％未満であり平均エステル化度が
0.99を超え２未満であるポリグリセリン不飽和脂肪酸エ
ステル、及び(2)植物ステロールを溶解状態で含有する
液状油脂組成物。(1) The total content of free glycerin and polyglycerin is less than 1% by weight, and the average degree of esterification is
A liquid oil or fat composition containing a polyglycerin unsaturated fatty acid ester having a content of more than 0.99 and less than 2, and (2) a plant sterol in a dissolved state.
ポリグリセリン平均重合度が1.5〜３である請求項１記
載の液状油脂組成物。2. The liquid fat or oil composition according to claim 1, wherein the polyglycerol unsaturated fatty acid ester has an average degree of polymerization of polyglycerin of 1.5 to 3.
テルを0.5〜５重量％、及び(2)の植物ステロールを1.2
〜10重量％含有するものである請求項１又は２記載の液
状油脂組成物。3. The polyglycerol unsaturated fatty acid ester of (1) is 0.5 to 5% by weight, and the plant sterol of (2) is 1.2% by weight.
The liquid oil / fat composition according to claim 1, wherein the composition comprises from 10 to 10% by weight.
含有する請求項１〜３のいずれかに記載の液状油脂組成
物。4. The liquid oil or fat composition according to claim 1, which contains 15% by weight or more of diacyl diglycerol.
合計含量が１重量％未満であり平均エステル化度が0.99
を超え２未満であるポリグリセリン不飽和脂肪酸エステ
ルからなる植物ステロール溶解剤。5. The total content of free glycerin and polyglycerin is less than 1% by weight and the average degree of esterification is 0.99.
A phytosterol dissolving agent comprising a polyglycerin unsaturated fatty acid ester having a content of more than 2 and less than 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000030310A JP4049503B2 (en) | 2000-02-08 | 2000-02-08 | Oil composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000030310A JP4049503B2 (en) | 2000-02-08 | 2000-02-08 | Oil composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2001220595A true JP2001220595A (en) | 2001-08-14 |
| JP4049503B2 JP4049503B2 (en) | 2008-02-20 |
Family
ID=18555341
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000030310A Expired - Fee Related JP4049503B2 (en) | 2000-02-08 | 2000-02-08 | Oil composition |
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| Country | Link |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001299240A (en) * | 2000-04-21 | 2001-10-30 | Showa Sangyo Co Ltd | Emulsifier composition and oil or fat composition containing the same |
| WO2002060270A1 (en) * | 2001-01-19 | 2002-08-08 | The Nisshin Oillio, Ltd. | Phytosterol-containing edible fat composition with excellent storage stability and process for producing the same |
| JP2003221332A (en) * | 2002-01-25 | 2003-08-05 | Kao Corp | Oil-in-water type emulsion composition |
| EP1483973A1 (en) * | 2003-06-04 | 2004-12-08 | Kao Corporation | Fat or oil composition |
| JP2006333828A (en) * | 2005-06-03 | 2006-12-14 | Sanei Gen Ffi Inc | Vegetable sterol-containing milk beverage and emulsifier for the same |
| JP2011200246A (en) * | 2006-09-26 | 2011-10-13 | Riken Vitamin Co Ltd | Soft candy |
| JP2017112890A (en) * | 2015-12-24 | 2017-06-29 | 昭和産業株式会社 | Separated liquid type dressing oil/fat composition and separated liquid type dressing |
| JP2020043792A (en) * | 2018-09-18 | 2020-03-26 | 理研ビタミン株式会社 | Oil and fat composition for frying |
-
2000
- 2000-02-08 JP JP2000030310A patent/JP4049503B2/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001299240A (en) * | 2000-04-21 | 2001-10-30 | Showa Sangyo Co Ltd | Emulsifier composition and oil or fat composition containing the same |
| WO2002060270A1 (en) * | 2001-01-19 | 2002-08-08 | The Nisshin Oillio, Ltd. | Phytosterol-containing edible fat composition with excellent storage stability and process for producing the same |
| JP2003221332A (en) * | 2002-01-25 | 2003-08-05 | Kao Corp | Oil-in-water type emulsion composition |
| US7494680B2 (en) | 2003-06-04 | 2009-02-24 | Kao Corporation | Fat or oil composition |
| JP2004359784A (en) * | 2003-06-04 | 2004-12-24 | Kao Corp | Oil-and-fat composition |
| EP1483973A1 (en) * | 2003-06-04 | 2004-12-08 | Kao Corporation | Fat or oil composition |
| AU2004202474B2 (en) * | 2003-06-04 | 2010-02-04 | Kao Corporation | Fat or oil composition |
| KR101108796B1 (en) * | 2003-06-04 | 2012-01-31 | 가오 가부시키가이샤 | Fat or oil composition |
| JP2006333828A (en) * | 2005-06-03 | 2006-12-14 | Sanei Gen Ffi Inc | Vegetable sterol-containing milk beverage and emulsifier for the same |
| JP2011200246A (en) * | 2006-09-26 | 2011-10-13 | Riken Vitamin Co Ltd | Soft candy |
| JP2017112890A (en) * | 2015-12-24 | 2017-06-29 | 昭和産業株式会社 | Separated liquid type dressing oil/fat composition and separated liquid type dressing |
| JP2020043792A (en) * | 2018-09-18 | 2020-03-26 | 理研ビタミン株式会社 | Oil and fat composition for frying |
| JP7144254B2 (en) | 2018-09-18 | 2022-09-29 | 理研ビタミン株式会社 | Fat and oil composition for frying |
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