JP2001204386A - Green tea drink and method for producing the same - Google Patents

Green tea drink and method for producing the same

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Publication number
JP2001204386A
JP2001204386A JP2000013742A JP2000013742A JP2001204386A JP 2001204386 A JP2001204386 A JP 2001204386A JP 2000013742 A JP2000013742 A JP 2000013742A JP 2000013742 A JP2000013742 A JP 2000013742A JP 2001204386 A JP2001204386 A JP 2001204386A
Authority
JP
Japan
Prior art keywords
green tea
enzyme
treated lecithin
lecithin
turbidity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000013742A
Other languages
Japanese (ja)
Inventor
Koichiro Yamauchi
浩一郎 山内
Hiroyuki Yokoyama
寛行 横山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kirin Beverage Corp
Kirin Brewery Co Ltd
Original Assignee
Kirin Beverage Corp
Kirin Brewery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kirin Beverage Corp, Kirin Brewery Co Ltd filed Critical Kirin Beverage Corp
Priority to JP2000013742A priority Critical patent/JP2001204386A/en
Publication of JP2001204386A publication Critical patent/JP2001204386A/en
Pending legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To prepare a green tea drink, especially the green tea drink packed in a transparent sealed container, hardly causing turbidity and precipitation over a long period without reducing the flavor and taste originally possessed by the extract of the green tea, without requiring a complex process. SOLUTION: This green tea drink in which the formation of the turbidity and the precipitation is suppressed, is produced by adding and formulating an enzyme-treated lecithin such as lysolecithin or a preparation containing the enzyme-treated lecithin, preferably in an amount of >=30 ppm expressed in terms of the enzyme-treated lecithin, as an essential active ingredient to and with the extract of the green tea obtained by extracting the leaves of the green tea with hot water, preferably with hot water containing 0.1-3 wt.% L-ascorbic acid based on the amount of the leaves of the green tea.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、混濁あるいは沈殿
の生成が抑制された緑茶飲料、詳しくは酵素処理レシチ
ン又は酵素処理レシチンを必須有効成分として含有する
製剤が配合されている混濁あるいは沈殿の生成が抑制さ
れた緑茶飲料に関する。
The present invention relates to a green tea beverage in which turbidity or sediment formation is suppressed, and more particularly, to the production of turbidity or sediment containing an enzyme-treated lecithin or a preparation containing an enzyme-treated lecithin as an essential active ingredient. The present invention relates to a green tea beverage in which is suppressed.

【0002】[0002]

【従来の技術】近年、缶やプラスチックボトル等の密封
容器に充填して長期間流通・販売される密封容器入り緑
茶飲料の市場は拡大する傾向にある。しかし、茶飲料特
に緑茶飲料は製造後の長期保存において混濁や沈殿を生
じることがあり、このことは特に透明容器詰め飲料とす
る場合に問題であった。緑茶抽出液の混濁や沈殿は、カ
テキン類(例えばカテキンガレート)とカフェインとの
コンプレックスに多糖類が重合して混濁粒子となるとの
報告もあるが、茶葉に含まれるポリフェノール、カフェ
イン、蛋白質、ペクチン、多糖類、カルシウムイオン等
の成分が複雑に関与するともいわれている。従来、この
緑茶飲料の混濁又は沈殿防止に関する技術として、例え
ば以下のものが知られている。
2. Description of the Related Art In recent years, the market for green tea beverages in sealed containers, which are filled in sealed containers such as cans and plastic bottles and distributed and sold for a long period of time, has been expanding. However, tea beverages, particularly green tea beverages, may become turbid or precipitate during long-term storage after production, which has been a problem, particularly in the case of beverages packed in transparent containers. It has been reported that the turbidity and precipitation of the green tea extract are caused by the polymerization of polysaccharides into complexes of catechins (for example, catechin gallate) and caffeine to form turbid particles. However, polyphenols, caffeine, proteins, It is also said that components such as pectin, polysaccharides and calcium ions are involved in a complicated manner. Conventionally, for example, the following techniques are known as techniques for preventing turbidity or sedimentation of this green tea beverage.

【0003】特開平4−45744号公報には、緑茶又
は生鮮乃至乾燥茶葉を抽出して得た水溶性緑茶成分を、
有機素材、無機素材を母体とした限界濾過膜による限界
濾過により分画し、分子量約1万以上の高分子成分をほ
ぼ除去することにより、緑茶飲料中に溶解する高分子化
合物を除いて、緑茶飲料中の白色糸状、綿状固形物の晶
出を防止し、かつ緑茶の滋味成分の濃度を変えずに、こ
く味のある良好な風味を持った緑茶飲料を製造する方法
が記載されている。
[0003] JP-A-4-45744 discloses a water-soluble green tea component obtained by extracting green tea or fresh or dried tea leaves.
Organic materials and inorganic materials are separated by ultrafiltration using ultrafiltration membranes, and high-molecular components having a molecular weight of about 10,000 or more are removed to remove high-molecular compounds soluble in green tea beverages. A method for producing a green tea beverage having a kokumi and a good flavor while preventing crystallization of white thread-like and flocculent solids in the beverage and changing the concentration of the nourishing component of the green tea is described. .

【0004】特開平4−311348号公報には、緑茶
を温水抽出好ましくは約40〜100℃の温水中で約1
〜10分間抽出した後、金属網、布等により茶殻を除去
し、L−アスコルビン酸を用いて、その抽出液のpHを
約4.0〜5.0の酸性域に調整し、次いでこれを室温
以下好ましくは20℃以下に急冷することによって、濁
りやオリの形成を促進させ、濁りやオリ中に各種の高分
子化合物を取り込んで粒子を形成させた後、遠心分離そ
の他の任意手段によって該粒子を含む濁りやオリの成分
を除去し、その後、上澄液に濾過助剤を添加して濾滓濾
過して残余する高分子化合物を除去し、その後抽出液の
pHを約5.5〜7.0の中性域に調整してから瓶、プ
ラスチック容器等、好ましくは透明容器に詰め、常法に
よって殺菌処理を行い、経時的に濁りやオリの発生の生
じない緑茶飲料とする製造方法が記載されている。
Japanese Patent Application Laid-Open No. 4-31348 discloses that green tea is extracted with warm water, preferably in warm water of about 40 to 100 ° C. for about 1 hour.
After extraction for 10 to 10 minutes, the tea husk is removed with a metal net, cloth, or the like, and the pH of the extract is adjusted to about 4.0 to 5.0 in an acidic range using L-ascorbic acid. By rapidly cooling to room temperature or less, preferably 20 ° C. or less, the formation of turbidity or slime is promoted, and various polymer compounds are incorporated into the turbidity or slime to form particles, and then the particles are centrifuged or any other means. After removing turbidity and dust components including particles, a filter aid is added to the supernatant, and the remaining polymer is removed by filtration with a filter cake. Thereafter, the pH of the extract is adjusted to about 5.5 to 5.5. After adjusting to a neutral range of 7.0, filling in a bottle, a plastic container, or the like, preferably a transparent container, sterilizing by a conventional method, and producing a green tea beverage which does not produce turbidity or dust over time. Is described.

【0005】特開平6−269246号公報には、茶を
温水抽出し、得られた抽出液を冷却した後、タンニン酸
を添加して静置し、次いで遠心分離等によって微細な茶
粒子等の混濁物を除去し、更にこの抽出液をケイソウ土
濾過によって清澄化させることを特徴とする長期保存性
を有する茶飲料の製造方法が記載されている。
[0005] JP-A-6-269246 discloses that tea is extracted with warm water, the resulting extract is cooled, tannic acid is added and the mixture is allowed to stand, and then fine tea particles and the like are centrifuged. There is described a method for producing a tea beverage having a long-term storage property, which comprises removing a turbid substance and clarifying the extract by diatomaceous earth filtration.

【0006】特開平7−170912号公報には、茶原
料から茶抽出液を製造するのに際し、茶原料からの有効
成分の抽出及びクエン酸、リンゴ酸、酢酸、アスコルビ
ン酸等の酸成分の添加により、酸性茶抽出液を得る工程
と、上記酸性茶抽出液を高圧均質化する工程を順次備え
てなることを特徴とする茶抽出液の製法、詳しくは、茶
抽出液を一旦酸性域に調整することにより茶抽出液中の
高分子成分の立体構造を変化させ、その後に高圧均質化
することにより高分子成分を微細化し、また、2次凝集
を防止し、長期保存中の濁り、沈殿を防止すると共に、
茶抽出液の風味が損なわれない茶抽出液の製法が記載さ
れている。
[0006] Japanese Patent Application Laid-Open No. 7-170912 discloses that in producing a tea extract from a tea raw material, extraction of an active ingredient from the tea raw material and addition of an acid component such as citric acid, malic acid, acetic acid, and ascorbic acid. A method for producing a tea extract characterized by sequentially comprising a step of obtaining an acidic tea extract and a step of homogenizing the acidic tea extract under high pressure, specifically, once adjusting the tea extract to an acidic region. Changes the tertiary structure of the polymer component in the tea extract, and then homogenizes the polymer component under high pressure to reduce the size of the polymer component, prevent secondary aggregation, and prevent turbidity and sedimentation during long-term storage. To prevent
A method for producing a tea extract that does not impair the flavor of the tea extract is described.

【0007】特開平10−165096号公報には、茶
葉の温水又は熱水抽出液を、予めカリウムイオンを結合
させたスルホン酸基を有する陽イオン交換樹脂により陽
イオン交換処理する工程を含む茶の製造方法、詳しく
は、用いるイオン交換樹脂に対して一定の前処理(予め
カリウムイオンを結合)をしておくことにより、茶本来
の香味を維持できること、陽イオン交換処理の温度条件
を一定範囲(5〜45℃)に制御すれば茶飲料の味を一
層好適に維持することができること、陽イオン交換処理
前に茶抽出液のpHを一定範囲(pH5〜6.5)に調
整すれば長期保存しても全く混濁や沈殿を生じない茶を
製造できること、更に陽イオン交換処理した茶抽出液の
導電率を一定範囲(0.6〜0.8mS/cm)に調整
すれば茶本来の香味を一層確実に維持できることがそれ
ぞれ記載されている。
[0007] Japanese Patent Application Laid-Open No. H10-165096 discloses a method for producing tea comprising a step of subjecting a hot or hot water extract of tea leaves to a cation exchange treatment with a cation exchange resin having a sulfonic acid group to which potassium ions are previously bound. The production method, in particular, that a certain pre-treatment (preliminary binding of potassium ions) to the ion exchange resin to be used can maintain the original flavor of tea, and the temperature conditions of the cation exchange treatment are within a certain range ( (5 to 45 ° C.) to maintain the taste of the tea beverage more favorably. If the pH of the tea extract is adjusted to a certain range (pH 5 to 6.5) before the cation exchange treatment, long-term storage is possible. Even if it is possible to produce tea that does not cause turbidity or sedimentation at all, and if the conductivity of the cation-exchanged tea extract is adjusted to a certain range (0.6 to 0.8 mS / cm), the original flavor of tea Has been described, each can be maintained more reliably.

【0008】他方、酵素処理レシチンの飲料への適用に
関する技術としては、例えば以下のものが知られてい
る。特開昭64−85043号公報には、コーヒー水性
抽出液、乳成分、甘味料からなる飲料にリゾレシチンを
配合してなる耐熱性細菌胞子の発芽・増殖抑制作用及び
乳化安定性を有する乳成分入りコーヒー飲料が記載さ
れ、特開平7−123956号公報には、コーヒー水性
抽出液、乳成分、甘味料等からなる飲料にリゾレシチン
と有機酸モノグリセライドを配合してなる耐熱性細菌胞
子の発芽・増殖抑制作用を有する乳成分入りコーヒー飲
料が記載され、特開平8−182485号公報には、H
LB15〜16のショ糖脂肪酸エステルと酵素処理レシ
チンとを含有する乳化安定性に優れた乳飲料を得るため
の乳化剤製剤が記載されている。
[0008] On the other hand, as a technique relating to the application of enzyme-treated lecithin to beverages, for example, the following are known. JP-A-64-85043 discloses a milk component having a germination / proliferation inhibitory effect and emulsion stability of a heat-resistant bacterial spore prepared by blending lysolecithin in a beverage comprising an aqueous coffee extract, a milk component and a sweetener. A coffee beverage is described, and JP-A-7-123956 discloses the suppression of germination and growth of heat-resistant bacterial spores obtained by blending lysolecithin and an organic acid monoglyceride in a beverage comprising an aqueous coffee extract, a milk component, a sweetener, and the like. JP-A-8-182485 discloses a coffee beverage containing a milk component having an action.
An emulsifier formulation for obtaining a milk beverage having excellent emulsification stability, containing a sucrose fatty acid ester having an LB of 15 to 16 and an enzyme-treated lecithin is described.

【0009】また、特開平9−173028号公報に
は、カルシウム強化飲料に配合される、カルシウムを容
易に分散させることができ、かつその分散状態を長期間
持続させることができる、HLB11以上のショ糖脂肪
酸エステルとリゾレシチンとの重量混合比5:1〜1:
1からなるカルシウム強化飲料用分散剤が記載され、特
開平11−92488号公報には、炭素数12〜22の
飽和及び/又は不飽和脂肪酸を構成脂肪酸とする、モノ
エステル含量が90重量%以上のショ糖脂肪酸エステル
95〜99重量%、並びに脂肪酸乳酸エステル塩、ヒド
ロキシカルボン酸モノグリセリド及びレシチン系化合物
から選ばれるイオン性界面活性剤1〜5重量%を含有す
るショ糖脂肪酸エステル組成物を50ppm〜2重量%
含有する透明飲料水が記載されている。
[0009] Japanese Patent Application Laid-Open No. 9-173028 discloses a composition of HLB11 or higher, which can be easily dispersed in calcium-enriched beverage and can maintain the dispersed state for a long time. Weight mixing ratio of sugar fatty acid ester to lysolecithin 5: 1 to 1:
And JP-A-11-92488 discloses a dispersant for a calcium-enriched beverage comprising a saturated and / or unsaturated fatty acid having 12 to 22 carbon atoms as a constituent fatty acid and having a monoester content of 90% by weight or more. A sucrose fatty acid ester composition containing 95 to 99% by weight of a sucrose fatty acid ester, and 1 to 5% by weight of an ionic surfactant selected from a fatty acid lactate ester salt, a hydroxycarboxylic acid monoglyceride and a lecithin-based compound is 50 ppm to 50 ppm 2% by weight
Contains clear drinking water.

【0010】さらに、酵素処理レシチンの製法に関して
は、例えば以下の技術が知られている。特開昭63−2
79753号公報には、天然由来のレシチン(1,2−
ジアシルグリセロリン脂質)をホスフォリパーゼA2
より部分加水分解してリゾレシチン(1−モノアシルグ
リセロリン脂質)へと改質し、反応中に生成する遊離脂
肪酸及び原料由来の他の脂溶成分を有機溶剤により分離
除去して精製したリゾレシチン成分を総リン脂質中に
6.0重量%以上含む酵素改質レシチンの製造法が記載
され、特開平2−49593号公報には、粗原油にホス
フォリパーゼA活性を有する酵素を作用させ粗原油中の
リン脂質を酵素処理するリゾレシチンの製造方法が記載
され、特開平3−206855号公報には、リン脂質混
合物をフォスフォリパーゼDとフォスフォリパーゼAと
で処理して得られたパン用の食品乳化剤が記載されてい
る。
Further, with respect to a method for producing enzyme-treated lecithin, for example, the following techniques are known. JP-A-63-2
No. 79753 discloses a naturally occurring lecithin (1,2-
Diacyl glycero phospholipids) is partially hydrolyzed with phospholipase A 2 lysolecithin (1-monoacyl glycero phospholipids) to the reforming, free fatty acids and other lipid soluble components an organic solvent derived from the raw material produced during the reaction A method for producing an enzyme-modified lecithin containing 6.0% by weight or more of a lysolecithin component separated and removed by purification in total phospholipids is described. JP-A-2-49593 discloses that phospholipase A is added to crude crude oil. A method for producing lysolecithin by enzymatically treating phospholipids in crude crude oil by the action of an enzyme having an activity is described. JP-A-3-206855 discloses that a phospholipid mixture can be prepared by using phospholipase D and phospholipase A together. A food emulsifier for bread obtained by processing is described.

【0011】[0011]

【発明が解決しようとする課題】緑茶飲料の混濁あるい
は沈殿の生成抑制に関する前記従来技術は、物理的濾過
による混濁あるいは沈殿除去操作により、茶抽出液中の
風味・呈味成分もある程度除かれるという問題があった
り、酸性化工程、高圧ホモゲナイズ処理工程、アルカリ
添加工程を必要とするなど処理工程が増加するという問
題があったり、温度、pH調整、陽イオン交換樹脂の調
製、電気伝導度での処理中の監視など複雑な工程が追加
されるという問題があったりして、満足のいくものでは
なかった。本発明の課題は、複雑な工程を必要とせず、
かつ緑茶抽出液本来の風味・呈味を失うことなく、長期
間にわたり、濁りあるいは沈殿のない緑茶飲料、特に透
明密閉容器入り緑茶飲料を提供することにある。
According to the above-mentioned prior art relating to suppression of turbidity or sedimentation of green tea beverages, the operation of removing turbidity or sediment by physical filtration also removes some of the flavor and taste components in the tea extract. There are problems, such as the need for acidification step, high pressure homogenization treatment step, the need for alkali addition step, increase in the number of treatment steps, temperature, pH adjustment, preparation of cation exchange resin, electric conductivity It was not satisfactory due to the problem of adding complicated steps such as monitoring during processing. The object of the present invention is to eliminate the need for complicated steps,
Another object of the present invention is to provide a green tea beverage which is free from turbidity or sediment for a long period of time without losing the original flavor and taste of the green tea extract, particularly a green tea beverage in a transparent closed container.

【0012】[0012]

【課題を解決するための手段】本発明者らは、上記課題
を解決するため鋭意研究し、食品用乳化剤として知られ
ている酵素処理レシチン又は酵素処理レシチンを必須有
効成分として含有する製剤が、紅茶飲料やウーロン茶飲
料には混濁あるいは沈殿の生成抑制作用を殆ど示さず、
緑茶飲料に混濁あるいは沈殿の生成抑制作用を特異的に
示し、長期間にわたり、緑茶抽出液や緑茶飲料の混濁あ
るいは沈殿の生成を抑制することができることを見い出
した。また、茶葉に対して0.1〜3重量%のL−アス
コルビン酸が配合された湯水を用いて茶葉を抽出した緑
茶抽出液を用いると、酵素処理レシチンと相乗的に作用
して、緑茶抽出液の混濁あるいは沈殿の生成がより一層
抑制された緑茶飲料が得られることを見い出した。本発
明はこれら知見に基づいて完成するに至ったものであ
る。
Means for Solving the Problems The present inventors have conducted intensive studies to solve the above-mentioned problems, and have found that an enzyme-treated lecithin known as a food emulsifier or a preparation containing an enzyme-treated lecithin as an essential active ingredient, Tea beverages and oolong tea beverages have almost no turbidity or sedimentation inhibiting effect,
The present inventors have specifically found that green tea beverages have an inhibitory effect on the formation of turbidity or sediment, and can suppress the formation of turbidity or sedimentation of green tea extract or green tea beverage for a long period of time. In addition, when a green tea extract obtained by extracting tea leaves using hot water containing 0.1 to 3% by weight of L-ascorbic acid with respect to the tea leaves is used, the green tea extract acts synergistically with the enzyme-treated lecithin. It has been found that a green tea beverage in which the turbidity of the liquid or the formation of a precipitate is further suppressed can be obtained. The present invention has been completed based on these findings.

【0013】すなわち本発明は、酵素処理レシチン又は
酵素処理レシチンを必須有効成分として含有する製剤が
配合されていることを特徴とする混濁あるいは沈殿の生
成が抑制された緑茶飲料(請求項1)や、酵素処理レシ
チン又は酵素処理レシチンを必須有効成分として含有す
る製剤、及びL−アスコルビン酸が配合されていること
を特徴とする混濁あるいは沈殿の生成が抑制された緑茶
飲料(請求項2)や、酵素処理レシチンが、リゾレシチ
ンを含む酵素分解レシチン又はリゾレシチンであること
を特徴とする請求項1又は2記載の混濁あるいは沈殿の
生成が抑制された緑茶飲料(請求項3)や、酵素処理が
フォスフォリパーゼA2を用いる酵素処理であることを
特徴とする請求項1〜3のいずれか記載の混濁あるいは
沈殿の生成が抑制された緑茶飲料(請求項4)や、酵素
処理レシチン又は酵素処理レシチンを必須有効成分とし
て含有する製剤が、酵素処理レシチンとして30ppm
以上配合されていることを特徴とする請求項1〜4のい
ずれか記載の混濁あるいは沈殿の生成が抑制された緑茶
飲料(請求項5)や、L−アスコルビン酸が、緑茶抽出
用水性媒体に、茶葉に対して0.1〜3重量%配合され
ていることを特徴とする請求項1〜5のいずれか記載の
混濁あるいは沈殿の生成が抑制された緑茶飲料(請求項
6)や、緑茶飲料が密封容器入り緑茶飲料であることを
特徴とする請求項1〜6のいずれか記載の混濁あるいは
沈殿の生成が抑制された緑茶飲料(請求項7)に関す
る。
That is, the present invention provides a green tea beverage in which turbidity or precipitation is suppressed, wherein an enzyme-treated lecithin or a preparation containing enzyme-treated lecithin as an essential active ingredient is blended (claim 1). An enzyme-treated lecithin or a preparation containing an enzyme-treated lecithin as an essential active ingredient, and a green tea beverage in which turbidity or precipitation is suppressed, wherein L-ascorbic acid is compounded; 3. The green tea beverage (Claim 3) wherein turbidity or precipitation is suppressed, according to claim 1 or 2, wherein the enzyme-treated lecithin is an enzyme-decomposed lecithin containing lysolecithin or lysolecithin. generation suppression of turbidity or precipitation according to any one of claims 1 to 3, characterized in that an enzyme treatment using lipase a 2 Green tea beverage (claim 4) or formulations containing as the essential active ingredient enzymatic treatment lecithin or enzyme treatment lecithin, 30 ppm as enzyme treatment lecithin
The green tea beverage (Claim 5) in which the formation of turbidity or precipitation is suppressed according to any one of claims 1 to 4, and L-ascorbic acid is used as an aqueous medium for extracting green tea, wherein the aqueous medium is extracted. 6. A green tea beverage (Claim 6) in which turbidity or sedimentation is suppressed according to any one of claims 1 to 5, wherein the green tea beverage is blended in an amount of 0.1 to 3% by weight with respect to the tea leaves. The beverage is a green tea beverage contained in a sealed container, and relates to a green tea beverage (claim 7) according to any one of claims 1 to 6, wherein turbidity or precipitation is suppressed.

【0014】また本発明は、緑茶葉を緑茶抽出用水性媒
体で抽出した緑茶抽出液を水性媒体で希釈する緑茶飲料
の製造方法であって、酵素処理レシチン又は酵素処理レ
シチンを必須有効成分として含有する製剤を酵素処理レ
シチンとして30ppm以上前記緑茶抽出液に添加配合
することを特徴とする混濁あるいは沈殿の生成が抑制さ
れた緑茶飲料の製造方法(請求項8)や、緑茶抽出用水
性媒体が、L−アスコルビン酸が茶葉に対して0.1〜
3重量%配合されている水性媒体であることを特徴とす
る請求項8記載の混濁あるいは沈殿の生成が抑制された
緑茶飲料の製造方法(請求項9)に関する。
The present invention also relates to a method for producing a green tea beverage in which a green tea extract obtained by extracting green tea leaves with an aqueous medium for extracting green tea is diluted with an aqueous medium, comprising an enzyme-treated lecithin or an enzyme-treated lecithin as an essential active ingredient. A method for producing a green tea beverage in which turbidity or precipitation is suppressed, characterized in that the preparation to be prepared is added to the green tea extract at least 30 ppm as an enzyme-treated lecithin, and an aqueous medium for extracting green tea, L-ascorbic acid is 0.1 to the tea leaves
The present invention relates to a method for producing a green tea beverage in which turbidity or precipitation is suppressed (claim 9), wherein the aqueous medium is 3% by weight.

【0015】[0015]

【発明の実施の形態】本発明において緑茶とは、原料の
茶葉又は茶芽の製造の最初の工程で、茶葉又は茶芽を蒸
気で蒸すか、釜で煎ることにより、茶葉又は茶芽中の酵
素活性を停止させて、発酵させずに作った不発酵茶をい
い、発酵茶である紅茶や半発酵茶であるウーロン茶は含
まれない。また、本発明における緑茶としては、煎茶、
玉露、抹茶、番茶、ほうじ茶、蒸製玉緑茶、釜煎製玉緑
茶等を具体的に例示することができる。なお、本発明に
おいて緑茶のことを緑茶葉ということもある。
BEST MODE FOR CARRYING OUT THE INVENTION In the present invention, green tea is the first step in the production of tea leaves or tea buds as a raw material, and the enzyme activity in the tea leaves or tea buds is reduced by steaming the tea leaves or tea buds or roasting them in a kettle. It refers to unfermented tea made without fermentation after being stopped, and does not include black tea, which is fermented tea, and oolong tea, which is semi-fermented tea. In addition, as green tea in the present invention, sencha,
Gyokuro, matcha, bancha, roasted green tea, steamed green tea, kamasen green tea and the like can be specifically exemplified. In the present invention, green tea is sometimes referred to as green tea leaf.

【0016】本発明において酵素処理レシチンとは、フ
ォスフォリパーゼで処理したレシチンをいい、またここ
でレシチンとは、フォスファチジルコリン、又はフォス
ファチジルコリン、フォスファチジルエタノールアミン
等種々のリン脂質を含むリン脂質混合物をいう。かかる
リン脂質混合物としては、市販の大豆レシチンや卵黄レ
シチンを挙げることができる(月刊フードケミカル、2
月号、1999、94〜99頁参照)。また、上記酵素
処理レシチンとしては、公知の酵素処理レシチンであれ
ばどのようなものでも使用することができるが、フォス
フォリパーゼとしてフォスフォリパーゼA1、フォスフ
ォリパーゼA2、フォスフォリパーゼB、フォスフォリ
パーゼD等を用い、レシチンから脂肪酸基1個を除いた
1−アシルリゾレシチン、2−アシルリゾレシチン等の
リゾレシチンが好ましく、その中でもフォスフォリパー
ゼA2でレシチンを処理したリゾフォスファチジルコリ
ン等の1−アシルリゾレシチンが好ましく、かかる好ま
しいリゾレシチンとして、上記大豆レシチンをフォスフ
ォリパーゼA2で部分加水分解し、反応中に生成する遊
離脂肪酸及び原料由来の他の脂溶成分を有機溶剤等によ
り分離除去して精製することによって得られるリゾレシ
チンを具体的に例示することができる。
In the present invention, the enzyme-treated lecithin refers to lecithin treated with phospholipase, wherein lecithin is phosphatidylcholine or various phospholipids such as phosphatidylcholine and phosphatidylethanolamine. Refers to a phospholipid mixture containing Examples of such a phospholipid mixture include commercially available soybean lecithin and egg yolk lecithin (Monthly Food Chemical,
Mon., 1999, pp. 94-99). Further, as the enzyme-treated lecithin, any known enzyme-treated lecithin can be used. However, phospholipase A 1 , phospholipase A 2 , phospholipase B, phospholipase with lipase D, etc., 1-acyl lysolecithin by removing one fatty acid group from lecithin, 2-acyl lysolecithin preferably such lysolecithin, lysophosphatidyl choline treated lecithin with phospholipase a 2 among them preferably of 1-acyl lysolecithin, such as preferred lysolecithin, the soybean lecithin partially hydrolyzed with phospholipase a 2, separating the other fat soluble content of free fatty acids and derived from the starting materials produced during the reaction with an organic solvent such as Lysolecithin obtained by removal and purification Can be specifically exemplified.

【0017】本発明において酵素処理レシチンを必須有
効成分として含有する製剤とは、酵素処理レシチンを混
濁あるいは沈殿の生成抑制の必須有効成分として含有す
る製剤をいい、例えば酵素処理レシチンが任意成分とし
て微量に含まれるものは除かれる。かかる本発明におけ
る酵素処理レシチンを必須有効成分として含有する製剤
としては、必須有効成分としての上記酵素処理レシチン
に、緑茶飲料に用いた場合に好ましくない風味・呈味や
濁り等の性質を付与しない賦形剤を適宜割合で配合した
ものを挙げることができ、かかる賦形剤としてはデキス
トリン、乳糖、カゼインナトリウム等を例示することが
できるが、緑茶抽出液に粉末形態の製剤として均一に溶
解分散させることができることから作業性に優れ、かつ
緑茶飲料の風味等に影響を与えることがないデキストリ
ンが好ましい。また、酵素処理レシチンと賦形剤との配
合割合は特に制限されるものではないが、1〜5:5〜
1の範囲で配合することが好ましい。
In the present invention, the preparation containing the enzyme-treated lecithin as an essential active ingredient refers to a preparation containing the enzyme-treated lecithin as an essential active ingredient for suppressing turbidity or the formation of precipitates. Are excluded. As the preparation containing the enzyme-treated lecithin in the present invention as an essential active ingredient, the enzyme-treated lecithin as an essential active ingredient does not impart properties such as unfavorable flavor, taste, and turbidity when used in a green tea beverage. Excipients may be added in appropriate proportions. Examples of such excipients include dextrin, lactose, sodium caseinate, and the like. Dextrin, which is excellent in workability and does not affect the flavor and the like of the green tea beverage because it can be made to work, is preferred. The mixing ratio of the enzyme-treated lecithin and the excipient is not particularly limited, but is 1-5: 5-
It is preferable to mix in the range of 1.

【0018】また、酵素処理レシチン又は酵素処理レシ
チンを必須有効成分として含有する製剤の緑茶飲料にお
ける配合割合は、緑茶の種類、抽出条件等により変わり
うることから一概にはいえないが、通常緑茶飲料中に酵
素処理レシチンとして10ppm以上、好ましくは30
ppm以上配合させることが望ましく、他方配合量の上
限は緑茶飲料の風味に与える影響やコスト面からして5
00ppm以下、好ましくは250ppm以下が望まし
い。
The mixing ratio of the enzyme-treated lecithin or the preparation containing the enzyme-treated lecithin as an essential active ingredient in a green tea beverage cannot be determined unconditionally because it can vary depending on the type of green tea, extraction conditions and the like. 10 ppm or more, preferably 30 ppm or more as enzyme-treated lecithin
ppm or more, and the upper limit of the amount is 5% in view of the effect on the flavor of the green tea beverage and cost.
00 ppm or less, preferably 250 ppm or less is desirable.

【0019】一般に、緑茶飲料の製造は、緑茶を湯水等
の水性媒体と接触せしめ、茶葉に抽出処理を施した後固
形分や不溶成分を除去した緑茶抽出液をそのまま緑茶飲
料とする方法や、濃縮状態で得られた緑茶抽出液をイオ
ン交換水等の調合水で希釈して緑茶飲料とする方法が知
られているが、工業的生産においては抽出効率や成分・
品質調整の簡便さ等の点から、緑茶抽出液を希釈して緑
茶飲料とする方法が採用されている。本発明の混濁ある
いは沈殿の生成が抑制された緑茶飲料は、酵素処理レシ
チン又は酵素処理レシチンを必須有効成分として含有す
る製剤が配合されていることを特徴とするが、緑茶飲料
の製造工程における酵素処理レシチン又は酵素処理レシ
チンを必須有効成分として含有する製剤の配合は、緑茶
抽出液用水性媒体への添加配合でもよいが、緑茶抽出液
に添加配合する方が好ましく、かかる緑茶抽出液への添
加配合の場合、酵素処理レシチン又は酵素処理レシチン
を必須有効成分として含有する製剤を、緑茶抽出液へ直
接添加溶解させることにより、あるいは前記調合水に添
加溶解させたものを緑茶抽出液に添加してもよい。
In general, green tea beverages are produced by bringing green tea into contact with an aqueous medium such as hot water or the like, subjecting the tea leaves to an extraction treatment and then removing the green tea extract from which solids and insoluble components have been removed to produce a green tea beverage as it is. A method is known in which a green tea extract obtained in a concentrated state is diluted with a preparation water such as ion-exchanged water to obtain a green tea beverage.
A method of diluting a green tea extract into a green tea beverage has been adopted from the viewpoint of easy quality control and the like. The green tea beverage of the present invention in which the formation of turbidity or precipitation is suppressed, characterized in that an enzyme-treated lecithin or a preparation containing an enzyme-treated lecithin as an essential active ingredient is blended. Formulation of a preparation containing treated lecithin or enzyme-treated lecithin as an essential active ingredient may be added to the aqueous medium for green tea extract, but is preferably added to the green tea extract and added. In the case of blending, by directly adding and dissolving the enzyme-treated lecithin or the preparation containing the enzyme-treated lecithin as an essential active ingredient to the green tea extract, or by adding and dissolving it to the prepared water to the green tea extract. Is also good.

【0020】濃縮状態の緑茶抽出液の抽出処理条件とし
ては、茶葉に対して20〜50倍、好ましくは30〜4
0倍の重量の水性媒体、特に60〜70℃の水性媒体を
用い、3〜10分程度、好ましくは1回〜数回の攪拌を
伴う抽出処理を挙げることがでる。水性媒体としては、
単なる湯水でもよいが、L−アスコルビン酸が茶葉に対
して0.1〜3重量%、好ましくは0.5〜2重量%、
特に0.8〜1.2重量%配合されているpH5前後の
湯水を用いると、酵素処理レシチンと相乗的に作用し
て、混濁あるいは沈殿の生成がより一層抑制された緑茶
飲料が得られることから好ましい。また、抽出処理後の
固形分や不溶成分の除去方法としては、上記抽出処理終
了後、網濾過して茶葉を濾し取り、その後10℃付近に
冷却して、例えば3000rpm、10分程度の遠心分
離により不溶性成分を除去する方法を例示することがで
きる。
The conditions for the extraction of the concentrated green tea extract are 20 to 50 times, preferably 30 to 4 times, those of the tea leaves.
An aqueous medium having a weight of 0 times, particularly an aqueous medium at 60 to 70 ° C., may be used for extraction for about 3 to 10 minutes, preferably once to several times with stirring. As an aqueous medium,
Although simple hot water may be used, L-ascorbic acid is used in an amount of 0.1 to 3% by weight, preferably 0.5 to 2% by weight based on tea leaves.
In particular, when hot water having a pH of about 5 and containing 0.8 to 1.2% by weight is used, it acts synergistically with the enzyme-treated lecithin to obtain a green tea beverage in which turbidity or precipitation is further suppressed. Is preferred. In addition, as a method for removing solids and insoluble components after the extraction treatment, after completion of the extraction treatment, the tea leaves are collected by filtration through a net, then cooled to about 10 ° C., and centrifuged at, for example, 3000 rpm for about 10 minutes. The method for removing insoluble components can be exemplified.

【0021】本発明の緑茶飲料は、濃縮状態の緑茶抽出
液を、酵素処理レシチンが溶解分散されたイオン交換水
等の調合水で希釈し、重曹(炭酸水素ナトリウム)等に
よりpH調節がなされ、次いで容器に充填後、通常殺菌
処理が施されて製品となるが、緑茶の抽出時や緑茶抽出
液の希釈時等に酵素処理レシチン又は酵素処理レシチン
を必須有効成分として含有する製剤の他に、L−アスコ
ルビン酸等の緑茶飲料の風味等に悪影響を与えることが
ない他の成分を配合することもできる。このようにして
製造された本発明の緑茶飲料は、混濁あるいは沈殿の生
成が抑制されているので、密封容器入り緑茶飲料、特に
ペットボトル等の透明密封容器入り緑茶飲料とすること
が有利である。
The green tea beverage of the present invention is prepared by diluting a concentrated green tea extract with a preparation water such as ion-exchanged water in which enzyme-treated lecithin is dissolved and dispersed, and pH-adjusted with sodium bicarbonate (sodium bicarbonate) or the like. Next, after filling the container, the product is usually subjected to sterilization treatment, but in addition to the preparation containing enzyme-treated lecithin or enzyme-treated lecithin as an essential active ingredient at the time of extracting green tea or diluting the green tea extract, Other components, such as L-ascorbic acid, which do not adversely affect the flavor and the like of the green tea beverage can also be added. Since the green tea beverage of the present invention produced in this way has suppressed cloudiness or generation of sediment, it is advantageous to produce a green tea beverage in a sealed container, particularly a green tea beverage in a transparent sealed container such as a PET bottle. .

【0022】[0022]

【実施例】以下、本発明を実施例により詳細に説明する
が、本発明の技術的範囲は以下の実施例によって限定さ
れるものではない。なお、実施例における「%」は、特
に断りがない場合「重量%」を意味する。
EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples, but the technical scope of the present invention is not limited to the following examples. In the examples, "%" means "% by weight" unless otherwise specified.

【0023】実施例1 緑茶葉(一番茶)を、抽出倍率35倍、抽出温度65
℃、抽出時間5分(直後、2.5分後にそれぞれ10秒
間攪拌)との抽出条件で湯水により抽出し、網濾過後冷
却して、小型冷却遠心機(日立工機社製「OSPR−2
2」)を用い遠心分離(8℃、3000rpm、10
分)により不溶性成分を除去して、緑茶抽出液を得た。
得られた緑茶抽出液を用いて、表1の処方によりサンプ
ル1〜5の5種類の緑茶飲料を調製し、各緑茶飲料は、
195gレトルト壜にホットパック充填し(約90
℃)、小型レトルト殺菌機(日坂製作所製「RCS−4
0RTGN」)を用いて121℃、10分間の殺菌処理
を施した。上記緑茶飲料の調製は、酵素処理レシチン製
剤及び酸化防止剤としてのL−アスコルビン酸をそれぞ
れ添加溶解させた調合水(イオン交換水)を加えて、調
合水で全体が100%となるように緑茶抽出液を希釈す
ることにより行った。したがって、表1における「緑茶
0.6%」は、緑茶飲料1kgを調製するのに6gの茶
葉が使用されたことを意味する。なお、pH調整は重曹
にて行った。また、表1中の酵素処理レシチン製剤とし
ては、太陽化学社製「サンレシチンVA−1(酵素処理
レシチン含量33%,デキストリン67%)」を使用
し、同じくシュガーエステル製剤としては、小川香料社
製「ショ糖脂肪酸エステル(モノエステル含量99%)
10%含有製剤」を使用した。
Example 1 Green tea leaves (first tea) were extracted at a magnification of 35 times and at an extraction temperature of 65.
Extraction with hot and cold water under the extraction conditions of 5 ° C., and an extraction time of 5 minutes (immediately, and 2.5 minutes after stirring for 10 seconds each), followed by net filtration and cooling, followed by cooling with a small cooling centrifuge (“OSPR-2 manufactured by Hitachi Koki Co., Ltd.”
2 ”) and centrifugation (8 ° C., 3000 rpm, 10 rpm)
Min) to remove insoluble components to obtain a green tea extract.
Using the obtained green tea extract, five types of green tea beverages of Samples 1 to 5 are prepared according to the formulation of Table 1, and each green tea beverage is
Fill a 195 g retort bottle with hot pack (about 90
° C), small retort sterilizer (“RCS-4” manufactured by Hisaka Seisakusho)
0RTGN ") at 121 ° C. for 10 minutes. The green tea beverage is prepared by adding an enzyme-treated lecithin preparation and a preparation water (ion-exchanged water) in which L-ascorbic acid as an antioxidant is added and dissolved, and adding 100% of the total green tea with the preparation water. This was done by diluting the extract. Therefore, "0.6% green tea" in Table 1 means that 6 g of tea leaves were used to prepare 1 kg of green tea beverage. The pH was adjusted with sodium bicarbonate. As the enzyme-treated lecithin preparation in Table 1, "Sanlecithin VA-1 (enzyme-treated lecithin content 33%, dextrin 67%)" manufactured by Taiyo Kagaku Co., Ltd. was used. "Sucrose fatty acid ester (Monoester content 99%)
10% containing formulation "was used.

【0024】[0024]

【表1】 [Table 1]

【0025】各サンプルを静置して、室温(約25℃)
で1ヶ月及び40℃で20日間保存し、保存の後フロッ
クの生成状況を目視により観察した。室温保存、40℃
保存とも、対照区(サンプル3)と比較区(サンプル
4,5)では底部に弱いフロックが認められたが、本発
明の酵素処理レシチン製剤配合区(サンプル1,2)で
のフロックの生成は認められなかった。また、緑茶飲料
の官能検査を行ったところ、対照区と本発明の酵素処理
レシチン製剤配合区は呈味・風味において差異が認めら
れなかった。
Each sample is allowed to stand at room temperature (about 25 ° C.)
For 1 month and at 40 ° C. for 20 days, and after storage, the state of floc formation was visually observed. Store at room temperature, 40 ℃
In storage, weak floc was observed at the bottom in the control group (sample 3) and the comparative group (samples 4 and 5), but floc formation in the enzyme-treated lecithin preparation-combined group (samples 1 and 2) of the present invention was not observed. I was not able to admit. When a sensory test was performed on the green tea beverage, no difference was found in the taste and flavor between the control group and the group treated with the enzyme-treated lecithin preparation of the present invention.

【0026】実施例2 実施例1と同様に作製した緑茶抽出液を用いて、表2の
処方によりサンプル6〜19の14種類の緑茶飲料を実
施例1同様に調製し、各緑茶飲料も実施例1同様に殺菌
処理を施した。表2中の酵素処理レシチン製剤として
は、前記太陽化学社製「サンレシチンVA−1(酵素処
理レシチン含量33%,デキストリン67%)」を使用
し、酵素処理レシチンとしては、太陽化学社製「サンレ
シチンA(酵素処理レシチン含量100%)」を使用し
た。
Example 2 Using the green tea extract prepared in the same manner as in Example 1, 14 kinds of green tea beverages of Samples 6 to 19 were prepared in the same manner as in Example 1 according to the formulation in Table 2, and each green tea beverage was also prepared. A sterilization treatment was performed in the same manner as in Example 1. As the enzyme-treated lecithin preparation, "San lecithin VA-1 (enzyme-treated lecithin content 33%, dextrin 67%)" manufactured by Taiyo Kagaku Co., Ltd. was used. San lecithin A (enzyme-treated lecithin content 100%) "was used.

【0027】[0027]

【表2】 [Table 2]

【0028】各サンプルを静置し、室温1ヶ月及び40
℃20日間保存し、室温保存については10日後及び1
ヶ月後に、40℃保存については5日後及び20日後
に、それぞれフロックの生成状況を目視により観察し
た。結果を表3に示す。なお、表3中「−」はフロック
生成が認められない、「±」は僅かにフロック生成が認
められる、「+」はフロック生成が幾分認められる、
「++」フロック生成が認められる、「+++」はフロック
生成が明瞭に認められる、を意味する。この表3の結果
から、本発明の酵素処理レシチン配合区(サンプル7〜
9、14〜16)や酵素処理レシチン製剤配合区(サン
プル10〜12,17〜19)は対照区(サンプル6,
13)に比べてフロックの生成が抑制されていることが
わかった。また、酵素処理レシチンの添加量は、茶葉
0.6%抽出液(サンプル9,12)及び0.9%抽出
液(サンプル16,19)ともに、酵素処理レシチン製
剤として100ppm、酵素処理レシチンとして33p
pm(茶葉当たり0.55重量%)が望ましいことがわ
かった。さらにデキストリンのような安定化剤を含む酵
素処理レシチン製剤は、製剤化により溶解性も向上して
おり操作上も有利であることがわかった。また、緑茶飲
料の官能検査を行ったところ、本発明の酵素処理レシチ
ン配合区と酵素処理レシチン製剤配合区は呈味・風味に
おいて対照区と差異が認められなかった。
Each sample was allowed to stand at room temperature for 1 month and at room temperature.
At room temperature for 20 days.
Months, 5 days and 20 days after storage at 40 ° C., the state of floc formation was visually observed. Table 3 shows the results. In Table 3, "-" indicates no floc formation, "±" indicates slight floc formation, and "+" indicates some floc formation.
"++" means that floc generation is observed, "+++" means that floc generation is clearly observed. From the results shown in Table 3, the enzyme-treated lecithin-containing group of the present invention (samples 7 to
9, 14 to 16) and the group treated with the enzyme-treated lecithin preparation (samples 10 to 12, 17 to 19) were the control group (sample 6,
It was found that the formation of flocs was suppressed as compared with 13). The amount of the enzyme-treated lecithin added was 100 ppm for the enzyme-treated lecithin preparation and 33 ppm for the enzyme-treated lecithin in both the 0.6% extract of tea leaves (samples 9 and 12) and the 0.9% extract (samples 16 and 19).
pm (0.55% by weight per tea leaf) was found to be desirable. Furthermore, it has been found that the enzymatically treated lecithin preparation containing a stabilizer such as dextrin has improved solubility by formulation and is advantageous in operation. In addition, when a sensory test was performed on the green tea beverage, no difference was found in the taste and flavor between the control group and the enzyme-treated lecithin combination group of the present invention.

【0029】[0029]

【表3】 [Table 3]

【0030】実施例3 煎茶葉(一番茶)を、抽出倍率35倍、抽出温度65
℃、抽出時間5分(直後、2.5分後にそれぞれ10秒
間攪拌)との抽出条件で、L−アスコルビン酸を茶葉量
に対してそれぞれ0%、1%、3%となるように含有さ
せた湯水により抽出し、網濾過後冷却して、小型冷却遠
心機(日立工機社製「OSPR−22」)を用い遠心分
離(8℃、3000rpm、10分)により不溶性成分
を除去して、緑茶抽出液を得た。得られた緑茶抽出液を
用いて、表4の処方によりサンプル20〜31の12種
類の緑茶飲料を実施例1同様に調製し、各緑茶飲料も実
施例1同様に殺菌処理を施した。なお、表4の抽出時L
−アスコルビン酸濃度は、最終調合液に換算して表示し
た。また、緑茶飲料の調製に際し、L−アスコルビン酸
を、抽出時に使用した分を差し引いて最終濃度が0.0
4%になるように添加した。そしてまた、表4中の酵素
処理レシチンとしては、前記太陽化学社製「サンレシチ
ンA(酵素処理レシチン含量100%)」を使用した。
Example 3 Sencha leaves (first tea) were extracted at an extraction magnification of 35 times and at an extraction temperature of 65.
L-ascorbic acid was contained at 0%, 1%, and 3% with respect to the amount of tea leaves, respectively, under the extraction conditions of 5 ° C. and an extraction time of 5 minutes (immediately and 2.5 minutes after stirring for 10 seconds each). The mixture was extracted with hot and cold water, cooled after filtration through a net, and insoluble components were removed by centrifugation (8 ° C., 3000 rpm, 10 minutes) using a small cooling centrifuge (“OSPR-22” manufactured by Hitachi Koki Co., Ltd.). A green tea extract was obtained. Using the obtained green tea extract, 12 types of green tea beverages of Samples 20 to 31 were prepared in the same manner as in Example 1 according to the formulation in Table 4, and each green tea beverage was also sterilized as in Example 1. In addition, L at the time of extraction of Table 4
-Ascorbic acid concentration was expressed in terms of the final preparation. In addition, when preparing a green tea beverage, L-ascorbic acid was subtracted from the amount used at the time of extraction to a final concentration of 0.0
It was added to 4%. As the enzyme-treated lecithin in Table 4, "San lecithin A (enzyme-treated lecithin content: 100%)" manufactured by Taiyo Kagaku was used.

【0031】[0031]

【表4】 [Table 4]

【0032】各サンプルを室温(約25℃)で1ヶ月及
び45℃で20日間静置保存し、保存後のフロックの生
成状況を目視検査にて評価した。結果を表5に示す。な
お、表5中のフロック生成量は、「−」〜「+++++」
(下付の「+」は0.5)の10段階評価で示されてい
る。表5における本発明の酵素処理レシチン配合区(サ
ンプル21〜23、25〜27及び29〜31)と、こ
れらそれぞれに対応する対照区(サンプル20)、比較
区(サンプル24,28)との比較からして、酵素処理
レシチンを添加したいずれのサンプルにおいてもフロッ
ク生成抑制効果が認められ、またその効果は添加率に依
存的であることがわかった。また、抽出前の湯水へL−
アスコルビン酸を添加すると、酵素処理レシチン添加と
相俟って一層優れたフロック抑制効果が認められた。特
に、茶葉含量に対してL−アスコルビン酸を1%添加し
たサンプル25〜27においてより一層優れたフロック
生成抑制効果が認められ、中でも酵素処理レシチン10
0ppm以上添加したサンプル26,27においてはフ
ロックの生成が認められなかった。なお、酵素処理レシ
チン無添加の比較区(サンプル24,28)は、表5に
示されるように、抽出時にL−アスコルビン酸無添加の
対照区(サンプル20)と比較して、若干フロック生成
量が少ないものの、保存当初ほどの差は生じていなかっ
た。また、緑茶飲料の官能検査を行ったところ、対照区
と本発明の酵素処理レシチン配合区は呈味・風味におい
て差異が認められなかった。
Each sample was stored at room temperature (about 25 ° C.) for one month and at 45 ° C. for 20 days, and the state of floc formation after storage was evaluated by visual inspection. Table 5 shows the results. Note that the floc generation amount in Table 5 ranges from “−” to “+++++”.
(Subscript “ + ” is 0.5). Comparison of the enzyme-treated lecithin-combined sections of the present invention (samples 21 to 23, 25 to 27 and 29 to 31) in Table 5 with the corresponding control sections (sample 20) and comparative sections (samples 24 and 28). Thus, the effect of inhibiting floc formation was observed in any of the samples to which the enzyme-treated lecithin was added, and it was found that the effect was dependent on the addition ratio. Also, add L-
When ascorbic acid was added, a more excellent floc inhibitory effect was observed in combination with the addition of the enzyme-treated lecithin. Particularly, Samples 25 to 27 to which 1% of L-ascorbic acid was added to the tea leaf content exhibited a more excellent floc formation inhibitory effect.
No floc formation was observed in Samples 26 and 27 to which 0 ppm or more was added. As shown in Table 5, the control group without addition of enzyme-treated lecithin (samples 24 and 28) had a slightly higher floc formation amount than the control group without addition of L-ascorbic acid at the time of extraction (sample 20). However, the difference was not as large as at the time of preservation. When a sensory test was performed on the green tea beverage, no difference was found in the taste and flavor between the control group and the enzyme-treated lecithin combination group of the present invention.

【0033】[0033]

【表5】 [Table 5]

【0034】[0034]

【発明の効果】本発明によると、複雑な工程を必要とせ
ず、酵素処理レシチンを緑茶抽出液に配合することによ
り、長期間にわたり、濁りあるいは沈殿がなく、かつ緑
茶本来の風味・呈味を有する緑茶飲料、特に透明密閉容
器入り緑茶飲料を提供することができる。
According to the present invention, a complex process is not required, and by adding an enzyme-treated lecithin to a green tea extract, there is no turbidity or sedimentation over a long period of time, and the original flavor and taste of green tea are obtained. The present invention can provide a green tea beverage having the same, particularly a green tea beverage in a transparent closed container.

Claims (9)

【特許請求の範囲】[Claims] 【請求項1】 酵素処理レシチン又は酵素処理レシチン
を必須有効成分として含有する製剤が配合されているこ
とを特徴とする混濁あるいは沈殿の生成が抑制された緑
茶飲料。
1. A green tea beverage in which turbidity or precipitation is suppressed, wherein an enzyme-treated lecithin or a preparation containing enzyme-treated lecithin as an essential active ingredient is blended.
【請求項2】 酵素処理レシチン又は酵素処理レシチン
を必須有効成分として含有する製剤、及びL−アスコル
ビン酸が配合されていることを特徴とする混濁あるいは
沈殿の生成が抑制された緑茶飲料。
2. An enzyme-treated lecithin or a preparation containing an enzyme-treated lecithin as an essential active ingredient, and a green tea beverage in which turbidity or precipitation is suppressed, which is characterized by containing L-ascorbic acid.
【請求項3】 酵素処理レシチンが、リゾレシチンを含
む酵素分解レシチン又はリゾレシチンであることを特徴
とする請求項1又は2記載の混濁あるいは沈殿の生成が
抑制された緑茶飲料。
3. The green tea beverage according to claim 1, wherein the enzyme-treated lecithin is an enzyme-decomposed lecithin containing lysolecithin or lysolecithin.
【請求項4】 酵素処理がフォスフォリパーゼA2を用
いる酵素処理であることを特徴とする請求項1〜3のい
ずれか記載の混濁あるいは沈殿の生成が抑制された緑茶
飲料。
Wherein the enzymatic treatment is phospholipase turbidity or precipitate green tea beverage produced is suppressed in any one of claims 1 to 3, characterized in that an enzyme treatment using A 2.
【請求項5】 酵素処理レシチン又は酵素処理レシチン
を必須有効成分として含有する製剤が、酵素処理レシチ
ンとして30ppm以上配合されていることを特徴とす
る請求項1〜4のいずれか記載の混濁あるいは沈殿の生
成が抑制された緑茶飲料。
5. The turbidity or sediment according to claim 1, wherein the enzyme-treated lecithin or the preparation containing the enzyme-treated lecithin as an essential active ingredient is incorporated in an amount of 30 ppm or more as the enzyme-treated lecithin. Green tea beverages with reduced production of water.
【請求項6】 L−アスコルビン酸が、緑茶抽出用水性
媒体に、茶葉に対して0.1〜3重量%配合されている
ことを特徴とする請求項1〜5のいずれか記載の混濁あ
るいは沈殿の生成が抑制された緑茶飲料。
6. The turbidity or opacity according to claim 1, wherein L-ascorbic acid is incorporated in the aqueous medium for extracting green tea in an amount of 0.1 to 3% by weight with respect to the tea leaves. A green tea beverage with reduced formation of precipitates.
【請求項7】 緑茶飲料が密封容器入り緑茶飲料である
ことを特徴とする請求項1〜6のいずれか記載の混濁あ
るいは沈殿の生成が抑制された緑茶飲料。
7. The green tea beverage according to any one of claims 1 to 6, wherein the green tea beverage is a green tea beverage in a sealed container.
【請求項8】 緑茶葉を緑茶抽出用水性媒体で抽出した
緑茶抽出液を水性媒体で希釈する緑茶飲料の製造方法で
あって、酵素処理レシチン又は酵素処理レシチンを必須
有効成分として含有する製剤を酵素処理レシチンとして
30ppm以上前記緑茶抽出液に添加配合することを特
徴とする混濁あるいは沈殿の生成が抑制された緑茶飲料
の製造方法。
8. A method for producing a green tea beverage, comprising diluting a green tea extract obtained by extracting green tea leaves with an aqueous medium for extracting green tea with an aqueous medium, comprising an enzyme-treated lecithin or a preparation containing enzyme-treated lecithin as an essential active ingredient. A method for producing a green tea beverage in which turbidity or precipitation is suppressed, wherein at least 30 ppm of enzyme-treated lecithin is added to the green tea extract.
【請求項9】 緑茶抽出用水性媒体が、L−アスコルビ
ン酸が茶葉に対して0.1〜3重量%配合されている水
性媒体であることを特徴とする請求項8記載の混濁ある
いは沈殿の生成が抑制された緑茶飲料の製造方法。
9. The method of claim 8, wherein the aqueous medium for extracting green tea is an aqueous medium containing 0.1 to 3% by weight of L-ascorbic acid relative to tea leaves. A method for producing a green tea beverage with suppressed production.
JP2000013742A 2000-01-24 2000-01-24 Green tea drink and method for producing the same Pending JP2001204386A (en)

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Country Link
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006308529A (en) * 2005-05-02 2006-11-09 Toyo Seikan Kaisha Ltd Inspection method for sealing performance of retort-sterilized plastic vessel
US7544378B2 (en) * 2003-09-12 2009-06-09 Kao Corporation Preparation process of tea extract
US7682643B2 (en) 2004-02-19 2010-03-23 Ito En, Ltd. Method for manufacturing containered green tea beverage

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7544378B2 (en) * 2003-09-12 2009-06-09 Kao Corporation Preparation process of tea extract
US7682643B2 (en) 2004-02-19 2010-03-23 Ito En, Ltd. Method for manufacturing containered green tea beverage
JP2006308529A (en) * 2005-05-02 2006-11-09 Toyo Seikan Kaisha Ltd Inspection method for sealing performance of retort-sterilized plastic vessel
JP4711052B2 (en) * 2005-05-02 2011-06-29 東洋製罐株式会社 Sealing inspection method for retort sterilized plastic containers

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