JP2001179481A - Flux cored wire for arc welding and method of manufacturing the same - Google Patents

Flux cored wire for arc welding and method of manufacturing the same

Info

Publication number
JP2001179481A
JP2001179481A JP35924099A JP35924099A JP2001179481A JP 2001179481 A JP2001179481 A JP 2001179481A JP 35924099 A JP35924099 A JP 35924099A JP 35924099 A JP35924099 A JP 35924099A JP 2001179481 A JP2001179481 A JP 2001179481A
Authority
JP
Japan
Prior art keywords
wire
lubricant
flux
welding
wet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP35924099A
Other languages
Japanese (ja)
Inventor
Mikio Makita
三宜男 槇田
Setsuo Takahashi
説郎 高橋
Masaki Abe
昌樹 阿部
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Welding and Engineering Co Ltd
Original Assignee
Nippon Steel Welding and Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Welding and Engineering Co Ltd filed Critical Nippon Steel Welding and Engineering Co Ltd
Priority to JP35924099A priority Critical patent/JP2001179481A/en
Publication of JP2001179481A publication Critical patent/JP2001179481A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide a flux cored wire for arc welding which shows a stable color of the wire surface, has an excellent feedability, realizes a stable arc discharge, and generates small amount of fume and sputter, even under a severe welding condition. SOLUTION: The flux cored wire for arc welding whose brightness L* of the wire surface color defined by the L*C*h color space is controlled to be 40 to 60, which has a stable feedability, and which realizes a stable arc discharge is provided by a method in which a flux cored wire having a lapping margin of 15 to 30% of the wire diameter is drawn by wet type drawing after drawn by dry type drawing with a roll or a pore die for drawing to reduce the diameter by as much as 80% or greater in a total sectional reduction rate, the invasion of hydrogen source into the wire is prevented by making use of a mixed lubricant whose dry to wet type ratio is specified as an initial lubricant in a wet type drawing, and adjusting the depositing quantity of the lubricant on the wire surface.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、アーク溶接用フラック
ス入りワイヤおよびフラックス入りワイヤの製造方法に
係り、さらに詳しくはワイヤ表面の色調が良好で、溶接
時の送給性が優れ、良好な作業を維持できる合せ目のあ
るアーク溶接用フラックス入りワイヤおよびフラックス
入りワイヤの製造方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a flux-cored wire for arc welding and a method for producing the flux-cored wire, and more particularly, to a wire having a good color tone, excellent feedability during welding, and good workability. The present invention relates to a flux-cored wire for arc welding and a method for producing a flux-cored wire having a seam capable of maintaining the above conditions.

【0002】[0002]

【従来の技術】アーク溶接用ワイヤはソリッドワイヤと
フラックス入りワイヤがあり、フラックス入りワイヤに
は図1(a)、(b)に例示した様な外皮表面に合せ目
があるワイヤと、同図(c)に示す様な合せ目を溶接し
たシームレスワイヤがある。
2. Description of the Related Art An arc welding wire includes a solid wire and a flux-cored wire. The flux-cored wire includes a wire having a seam on the outer surface as illustrated in FIGS. 1 (a) and 1 (b). There is a seamless wire in which joints are welded as shown in FIG.

【0003】シームレスワイヤはフラックス充填直後に
合せ目を接合しているため、製造工程でソリッドワイヤ
と同様に焼鈍、酸洗、めっきができる。従って拡散性水
素量が低く、耐錆、吸湿性およびターゲット性の点で優
れているが製造の工程数が多くなる。
[0003] Since the seamless wire is joined immediately after filling with the flux, it can be annealed, pickled, and plated in the same manufacturing process as the solid wire. Therefore, the amount of diffusible hydrogen is low, and it is excellent in rust resistance, hygroscopicity and targetability, but the number of manufacturing steps increases.

【0004】アーク溶接用フラックス入りワイヤは造
船、鉄骨橋梁等の溶接において、安定した品質の製品を
より安く提供することが求められており、品質の向上及
び安定化と共により低いコストで製造することが強く求
められている。
[0004] Flux-cored wires for arc welding are required to provide products of stable quality at lower cost in welding of shipbuilding, steel bridges, etc., and to manufacture them at lower cost together with improvement and stabilization of quality. Is strongly required.

【0005】合せ目のあるアーク溶接用フラックス入り
ワイヤ(以下、合せ目フラックス入りワイヤという)を
製造する一般的な方法はフラックス充填後の素線をロー
ルおよび孔ダイスで製品径まで伸線縮径する。孔ダイス
による場合は何らかの伸線潤滑剤を必要とする。
[0005] A general method of manufacturing a flux-cored wire for arc welding with a seam (hereinafter referred to as a seam flux-cored wire) is to reduce the wire after flux filling to a product diameter using a roll and a hole die. I do. In the case of using a hole die, some wire drawing lubricant is required.

【0006】伸線潤滑剤としては乾式と湿式がある。乾
式潤滑剤は金属石鹸類と無機物質を主体とし、これに各
種潤滑性向上剤が添加されている。
The wire drawing lubricant includes a dry type and a wet type. Dry lubricants are mainly composed of metal soaps and inorganic substances, to which various lubricity improvers are added.

【0007】湿式潤滑剤は動・植物油、鉱物油、合成油
および油性向上剤が主体の油性潤滑剤と、水に潤滑成分
を分散、乳化、可溶化させたエマルジョンタイプがあ
り、実際にはこれらを選択使用している。
[0007] Wet lubricants include oily lubricants mainly composed of animal and vegetable oils, mineral oils, synthetic oils and oiliness improvers, and emulsion types in which lubricating components are dispersed, emulsified and solubilized in water. Select and use.

【0008】伸線用潤滑剤の影響について、合せ目フラ
ックス入りワイヤは湿式潤滑剤中を通すと合せ目から潤
滑剤が侵入する場合があるため通常は乾式潤滑剤を使用
する。特にフラックス入りワイヤ製造に使用する帯鋼は
加工性の点から低炭素の冷間圧延帯鋼が殆どであるが、
伸線性の面では表面が非常に滑らかで伸線潤滑剤の乗り
が悪く、潤滑剤の供給が安定せず途切れるため表面荒れ
となり、断線し易く生産性が悪い。乾式ダイス伸線で能
率良く、安定した伸線性を得るにはダイスとワイヤの間
に潤滑層の形成が必要であるが乾式の場合、湿式に比べ
伸線材表面への潤滑剤の安定供給が難しく、潤滑層が粗
く途切れやすいため潤滑層を厚くする傾向がある。従っ
てワイヤ表面に潤滑剤が厚く多量に付着する。しかも、
厚く付着した潤滑剤は伸線中フレーク状に剥離し易くな
るため付着量が安定しない。ワイヤ表面に潤滑剤が多い
と溶接時チップでの通電が安定せずアークが不安定とな
る。また、付着物がコンジットチューブ内で徐々に堆積
し、送給抵抗が増加し送給性が低下するため長期間の使
用に耐えない。
[0008] Regarding the effect of the wire drawing lubricant, a dry lubricating wire is usually used because the flux-cored wire may enter the seam through the wet lubricating agent when it passes through a wet lubricant. In particular, most of the steel strip used for flux cored wire production is a low-carbon cold-rolled steel strip from the viewpoint of workability.
In terms of wire drawing, the surface is very smooth and the wire drawing lubricant is poorly applied, and the supply of the lubricant is not stable and is interrupted, resulting in a rough surface, which is liable to be disconnected and poor in productivity. In order to obtain efficient and stable drawability with dry die wire drawing, it is necessary to form a lubricating layer between the die and wire, but in the case of dry type, it is more difficult to supply lubricant stably to the surface of the drawn material than in the case of wet type In addition, since the lubricating layer is rough and easily broken, the lubricating layer tends to be thick. Therefore, a large amount of a thick lubricant adheres to the wire surface. Moreover,
The thickly adhered lubricant tends to peel off in the form of flakes during wire drawing, so that the amount of adhesion is not stable. If the wire surface contains a large amount of lubricant, the electric current at the tip during welding is not stable and the arc becomes unstable. Further, the deposits gradually accumulate in the conduit tube, and the feeding resistance increases and the feeding property decreases, so that it cannot be used for a long time.

【0009】次に、伸線潤滑剤の構成と効果について、
通常、乾式潤滑剤は金属石鹸あるいは金属石鹸にグラフ
ァイト、MoS2等の潤滑補助剤を添加したものが主体
のため溶接中スパッタ、ヒュームおよび拡散性水素量が
増加傾向を示す。上記の対策の一つとして製品径で焼成
し水素源を除去する方法が公知であるが表面に炭化物が
残るため溶接時にスパッタ、ヒュームが多く、表面の潤
滑成分の変質により送給性が低下する。
Next, regarding the composition and effect of the wire drawing lubricant,
Normally, dry lubricants are mainly metallic soaps or lubricants such as graphite and MoS 2 added to metallic soaps, so that the amount of spatter, fume and diffusible hydrogen during welding tends to increase. As one of the above countermeasures, a method of baking at the product diameter and removing the hydrogen source is known, but since the carbide remains on the surface, there are many spatters and fumes at the time of welding, and the feedability decreases due to deterioration of the lubricating component on the surface. .

【0010】一方、溶接の自動化、高能率化にともな
い、アーク溶接フラックス入りワイヤは益々多用される
傾向にあるが、能率の点から自動、半自動溶接を問わ
ず、高電流の溶接条件が採用される傾向にある。その結
果、必然的にワイヤ送給速度、送給量が大となる。又、
造船等建造能率面から建造ブロックが大型化する。逆に
タンカー座礁のオイル漏れ等の事故による海洋汚染防止
のため船体の二重構造化移行により構造が複雑となりよ
り狭隘部で使用される機会も多くなっている。それら狭
隘な箇所での使い易さの点から、溶接機のワイヤ送給装
置から溶接トーチまでのコンジットケーブルは柔らか
く、かつ長くなる傾向にある。
[0010] On the other hand, with the automation and higher efficiency of welding, arc welding flux cored wires tend to be used more and more. However, from the point of efficiency, high current welding conditions are adopted regardless of automatic or semi-automatic welding. Tend to be. As a result, the wire feeding speed and the feeding amount are inevitably increased. or,
Building blocks will be large in terms of shipbuilding and other building efficiency. Conversely, to prevent marine pollution due to accidents such as oil leaks from tanker groundings, the structure of the hull has become complicated due to the shift to a double hull structure, and the opportunity for use in narrower areas has increased. From the viewpoint of ease of use in these narrow places, the conduit cable from the wire feeder of the welding machine to the welding torch tends to be soft and long.

【0011】しかし、このように溶接ワイヤの供給速度
が大となると共に、長くて曲げ易いコンジットケーブル
が使用されると、ワイヤ送給時そのコンジットチューブ
内をワイヤが通る時の摩擦抵抗が大きくなり、加えてワ
イヤ表面付着物のコンジットチューブ内への堆積も多く
なりワイヤ送給に支障をきたし、アークが不安定となっ
て溶接ができなくなる。
However, when the supply speed of the welding wire is increased as described above and a long and bendable conduit cable is used, the frictional resistance when the wire passes through the conduit tube when the wire is fed increases. In addition, the amount of deposits on the wire surface is increased in the conduit tube, which hinders the wire feeding and makes the arc unstable, making welding impossible.

【0012】このため、これまでにアーク溶接用ワイヤ
の送給性改善のために、種々の対策が提案されているが
年々使用条件が厳しくなるため未だ十分なものはなく、
溶接作業者はより過酷な条件下でしばしば溶接の中断を
余儀なくされ、堆積した付着物の洗浄、摩耗したコンジ
ットチューブの交換など、その対応に苦慮している。
For this reason, various measures have been proposed so far for improving the feedability of the wire for arc welding, but the use conditions are becoming stricter year by year, and there is no sufficient measure.
Welders are often forced to interrupt welding under harsher conditions and struggle with cleaning up accumulated deposits and replacing worn conduit tubes.

【0013】これら溶接用ワイヤの送給性および作業性
の問題に対しては、従来、例えば特開昭55−4006
8号公報に高位脂肪酸と高級1価アルコールからなるエ
ステルおよび前記エステルとMoS2、グラファイト等
を混合被覆したアーク溶接用ワイヤ、あるいは特開昭5
8−184095号公報に記載されているグラファイ
ト、二硫化モリブデン、ガラス粉末などの固形潤滑剤を
混合したものを表面に塗布したアーク溶接用ワイヤなど
が提案されている。
To solve the problems of feedability and workability of these welding wires, for example, Japanese Patent Application Laid-Open No.
No. 8 discloses an arc welding wire coated with an ester comprising a higher fatty acid and a higher monohydric alcohol and a mixture of the ester and MoS 2 , graphite or the like;
Japanese Patent Application Laid-Open No. 8-184,095 proposes an arc welding wire having a surface coated with a mixture of a solid lubricant such as graphite, molybdenum disulfide, and glass powder.

【0014】しかしながら、これらのアーク溶接用ワイ
ヤにおいても前述した軟質で長尺のコンジットケーブル
を使用し、かつ高電流条件で溶接されるような過酷な条
件下では、送給ロール部でワイヤがスリップしたりコン
ジットチューブ内での摩擦抵抗が大きく、またコンジッ
トチューブ内が摩擦熱及びコンジットライナーを包む溶
接用ケーブルの発熱で高温となりワイヤ表面の潤滑剤が
部分的に融け、凝集してワイヤ表面に均一に被覆されな
くなるなどで、その送給性は満足できなくなる。また、
一部融けた潤滑剤は長時間溶接を行っている間にコンジ
ットチューブおよびチップ内に堆積し、ワイヤ通路を狭
めて送給抵抗、チップの通電抵抗を増大させ、アークの
安定持続を妨げるという問題がある。
However, even in these arc welding wires, the above-mentioned soft and long conduit cable is used, and under severe conditions such as welding under high current conditions, the wire slips at the feed roll. The friction resistance inside the conduit tube is large, and the inside of the conduit tube becomes hot due to frictional heat and the heat of the welding cable wrapping the conduit liner, causing the lubricant on the wire surface to partially melt, agglomerate and uniform on the wire surface Because of no longer being coated, the feedability becomes unsatisfactory. Also,
Lubricant that has partially melted accumulates in the conduit tube and tip during prolonged welding, narrowing the wire path, increasing the feed resistance and the tip current-carrying resistance, and hindering stable arcing. There is.

【0015】また、U溝成形部にフラックスを充填しワ
イヤ状にした両端部の合せ目を接合してない合せ目フラ
ックス入りワイヤは成形、充填から伸線工程を経て製品
になる工程でその構造上合せ目から水素源となる油、潤
滑剤が浸入するため通常湿式潤滑剤を避けて乾式伸線潤
滑剤を使用する。
Also, the seam flux-cored wire in which the U-groove forming part is filled with flux and the wire-shaped seam at both ends is not joined is formed by a process of forming, filling, drawing, and drawing into a product to form a product. Since the oil and lubricant serving as a hydrogen source enter from the upper joint, a dry wire drawing lubricant is generally used instead of a wet lubricant.

【0016】しかしながら、乾式および湿式伸線を組み
合わせて伸線し、合せ目フラックス入り溶接ワイヤを製
造する技術は特開平6−15485号公報に減面率70
%以上の大径域で乾式伸線し、10%を越えて70%未
満の領域で湿式、乾式潤滑剤を任意に選択使用して伸線
する巻締型フラックス入りワイヤの製造方法が開示され
ているが、種々検討した結果、前述した課題の解決に達
しなかった。
However, a technique for producing a welding wire with a joint flux by drawing by combining dry and wet drawing is disclosed in Japanese Patent Laid-Open No. 6-15485.
%, And a method for producing a flux-cored wire in which a wire is drawn by arbitrarily using a wet or dry lubricant in a region of more than 10% and less than 70%. However, as a result of various studies, the above-mentioned problem was not solved.

【0017】[0017]

【発明が解決しようとする課題】合せ目を接合してない
合せ目有りのフラックス入りワイヤの湿式伸線を可能に
すること、軟質で長尺のコンジットケーブルを使用し、
かつ高電流条件で溶接する様な過酷な条件でも、コンジ
ットケーブル内の詰まりおよび送給ロールへの潤滑剤成
分の堆積が少なく、送給性が良好で、安定した溶接がで
きるアーク溶接ワイヤおよびその効率的な製造方法にあ
る。
SUMMARY OF THE INVENTION To enable a wet drawing of a flux-cored wire having a seam where the seam is not joined, using a soft and long conduit cable,
Even under severe conditions such as welding under high current conditions, there is little clogging in the conduit cable and accumulation of lubricant components on the feed roll, good feedability, and an arc welding wire capable of stable welding and its welding. There is an efficient manufacturing method.

【0018】[0018]

【課題を解決するための手段】本発明はワイヤ外皮の合
せ目ラップ長さがワイヤ径の15〜30%でありワイヤ
表面の明度L*が40〜60、さらにワイヤ表面に固形
潤滑剤を有し、その上に油性潤滑剤を塗布した事を特徴
とするアーク溶接フラックス入りワイヤにある。
According to the present invention, the seam wrap length of the wire sheath is 15 to 30% of the wire diameter, the lightness L * of the wire surface is 40 to 60, and the wire surface has a solid lubricant. An arc welding flux-cored wire characterized in that an oil-based lubricant is applied thereon.

【0019】フラックスを充填した合せ目ラップ代長さ
がワイヤ径の15〜30%であるフラックス入りワイヤ
を素線とし、該素線を乾式潤滑剤を用いて総減面率で8
0%以上伸線し、次いで孔ダイスを用いて湿式伸線する
ことを特徴とする前記アーク溶接フラックス入りワイヤ
の製造方法にある。
A flux-cored wire having a seam wrap length of 15 to 30% of the wire diameter filled with flux is used as a wire, and the wire is dried with a dry lubricant at a total area reduction of 8%.
The method for producing an arc welding flux-cored wire according to claim 1, wherein the wire is drawn by 0% or more, and then wet drawn using a hole die.

【0020】乾式潤滑剤は重量比で高融点ワックスを2
〜20%含み、湿式潤滑剤は油性潤滑剤に洗浄剤を重量
比で5〜80%含むことを特徴とする前記アーク溶接フ
ラックス入りワイヤの製造方法にある。
The dry lubricant contains 2 parts by weight of high melting point wax.
20 to 20%, and the wet lubricant contains an oil-based lubricant and a detergent in a weight ratio of 5 to 80%.

【0021】湿式伸線の第1ダイス潤滑剤は湿式潤滑剤
に乾式潤滑剤を重量比で40〜60%添加したことを特
徴とする前記アーク溶接フラックス入りワイヤの製造方
法にある。
[0021] The method for producing an arc welding flux cored wire according to the present invention is characterized in that the first die lubricant for wet drawing is obtained by adding 40 to 60% by weight of a dry lubricant to a wet lubricant.

【0022】[0022]

【発明の実施の形態】次に本発明の基本概念および作用
を図1に基づき説明する。本発明者らは合せ目フラック
ス入りワイヤを過酷な条件下でも溶接を安定持続させる
目的で、先ず溶接中のワイヤ送給及びアークの現象を高
速ビデオ、波形解析等の各種装置を用いて観察した結果
と、ワイヤ表面の分析結果からワイヤ表面の構造はワイ
ヤ表面に固体または半固体の潤滑剤を強固に付着させ、
その上層に液体潤滑剤層を設けたことにより、前記した
過酷な条件下でも長時間安定した溶接を持続できること
を見い出した。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, the basic concept and operation of the present invention will be described with reference to FIG. The present inventors first observed the wire feeding and arc phenomena during welding using various devices such as high-speed video and waveform analysis in order to stably maintain welding of the jointed flux-cored wire even under severe conditions. From the results and the analysis results of the wire surface, the structure of the wire surface firmly attaches a solid or semi-solid lubricant to the wire surface,
It has been found that by providing a liquid lubricant layer thereover, stable welding can be maintained for a long time even under the above-mentioned severe conditions.

【0023】先ず,前述した2層構造の潤滑剤は高融点
のワックス等を含む乾式潤滑剤を使用して伸線すること
によりワイヤ表面に潤滑剤を強固に付着させて下層と
し、更に半湿式または湿式伸線により乾式伸線で余分に
付着した潤滑剤量を調整する事により、過酷なコンジッ
トケーブルの使用や高電流条件下においても、コンジッ
トケーブル内の詰りおよび送給ロールへの付着、堆積が
少なく、しかも厳しい屈曲状態でも送給ロールでのスリ
ップが少なく、かつコンジットケーブル内の摩擦抵抗が
小さく出来るので、ワイヤ送給性が向上し、長時間でも
アークの安定した溶接が出来る。乾式潤滑剤は Mo
2、WS2、ポリテトラフルオロエチレン(以下、PT
FEという)、グラファイト、ふっ化黒鉛、金属石鹸の
1種または2種以上から成り、これに高融点のワックス
を重量比で2〜20%添加することにより乾式潤滑剤を
安定して持ち込ませ、付着潤滑剤が伸線中に剥離するを
防止し、ワイヤ表面に溶接時の送給性に有効な潤滑剤を
保持させる。高融点ワックスとしては融点50℃以上の
天然または合成品を使用する。
First, the above-mentioned two-layered lubricant is drawn using a dry lubricant containing a high melting point wax or the like, whereby the lubricant is firmly adhered to the surface of the wire to form a lower layer. Or, by adjusting the amount of extra lubricant attached in dry drawing by wet drawing, clogging in the conduit cable and adhesion and deposition on the feed roll even under severe conduit cable use and high current conditions In addition, even in a severe bending state, the slip on the feed roll is small, and the frictional resistance in the conduit cable can be reduced, so that the wire feedability is improved and stable welding of the arc can be performed even for a long time. Dry lubricant is Mo
S 2 , WS 2 , polytetrafluoroethylene (hereinafter, PT
FE), graphite, graphite fluoride, and one or more metal soaps, and a high-melting-point wax is added in an amount of 2 to 20% by weight to allow a dry lubricant to be stably brought in. Prevents the attached lubricant from peeling off during wire drawing, and keeps the wire surface with a lubricant effective for feedability during welding. As the high melting point wax, a natural or synthetic product having a melting point of 50 ° C. or more is used.

【0024】前述したように、乾式伸線で強固に付着し
た必要以上の潤滑剤除去は湿式伸線による洗浄が効率的
であるが、合せ目フラックス入りワイヤは合せ目の開口
があるため湿式伸線すると合せ目から潤滑剤が侵入し、
溶接したとき溶接金属の拡散性水素量が増大し、溶接部
表面にあばた、溝状の欠陥が発生し、著しい場合は溶接
部に気孔、ブローホールなどの欠陥を生じるため通常適
用できない。そこで、湿式伸線によっても水素源の侵入
が無く、且つ適正な潤滑剤付着量が得られる方法を種々
検討した。
As described above, wet removal by wire drawing is effective for removing excess lubricant that has adhered firmly by dry drawing, but the flux cored wire has a seam opening due to the wet drawing. When lined, lubricant enters from the joint,
When welding, the amount of diffusible hydrogen in the weld metal increases and flaps and groove-like defects are generated on the surface of the welded portion. Therefore, various methods for preventing the intrusion of a hydrogen source even by wet drawing and obtaining an appropriate amount of lubricant attached were examined.

【0025】その結果、図1(b)に示すようにフラッ
クス入りワイヤの合せ目をラップ方式にしてそのラップ
代Lをワイヤ径Dの15〜30%に調整すると合せ目の
接触は殆ど密接状態となることから湿式潤滑剤の侵入が
極めて少なくなることが分かった。更に、湿式伸線を開
始するワイヤ径を細径側にすることで実用上問題のない
レベルまで合せ目からの水素源侵入を防止出来ることを
見いだした。即ち、ワックスを2〜20%添加した乾式
潤滑剤で総減面率80%以上まで縮径伸線後、湿式伸線
することおよび湿式伸線の初頭を湿式潤滑剤に乾式潤滑
剤を重量比で40〜60%添加した混合潤滑剤を使用す
ることによって合せ目からの潤滑剤侵入を防止できた。
この技術により仕上げ工程の湿式洗浄伸線による潤滑剤
除去、即ち潤滑剤付着量の微妙な調整が可能となり、そ
の結果ワイヤ表面の色調を色彩色差計により数値測定
し、明度を特定範囲規定してワイヤ表面の状況を総合的
に管理することにより送給性など溶接作業性を向上し、
安定化させることが出来た。
As a result, as shown in FIG. 1 (b), when the joint of the flux-cored wire is wrapped and the lap margin L is adjusted to 15 to 30% of the wire diameter D, the contact of the joint is almost in a close contact state. Therefore, it was found that the penetration of the wet lubricant was extremely reduced. Furthermore, it has been found that the intrusion of the hydrogen source from the joint can be prevented to a level at which there is no practical problem by setting the wire diameter at the start of wet drawing to a small diameter side. That is, wet-drawing is performed after reducing the diameter to a total area reduction of 80% or more using a dry-type lubricant containing 2 to 20% of wax, and the dry-type lubricant is added to the wet-type lubricant at the beginning of wet-drawing. By using the mixed lubricant added at 40 to 60%, the penetration of the lubricant from the seam could be prevented.
This technology makes it possible to remove lubricant by wet cleaning wire drawing in the finishing process, that is, fine adjustment of the amount of lubricant adhesion, as a result, the color tone of the wire surface is numerically measured by a colorimeter and the brightness is specified in a specific range. Improving welding workability such as feedability by comprehensively managing the condition of the wire surface,
It could be stabilized.

【0026】これらの効果は、各組成物それぞれの共存
効果および配列、順序の組合せによりなし得たものであ
るが、各々の限定理由について以下に述べる。
These effects can be achieved by the coexistence effect of each composition and the combination of the arrangement and the order. The reasons for the limitations are described below.

【0027】表1比較例No.10に示したように、図
1(a)に示すラップなしの合せ目フラックス入りワイ
ヤでは合せ目の開口幅が広く乾式潤滑剤除去の目的で湿
式伸線すると、この開口部から潤滑剤がワイヤ内部に侵
入する。そこで、本発明者らは最も工程を少なくできる
乾式伸線のみでアーク安定性を劣化させず目標の送給性
の得られる潤滑剤構成および方法を種々探索、検討した
が前述したように伸線性を確保すると潤滑剤付着量が過
多となる。逆に、付着量を減少させると潤滑被膜が安定
して形成されず潤滑切れにより伸線性が劣化し、線荒
れ、断線が頻発するため安定した生産ができず生産性と
ワイヤ外観、性能を両立させることは非常に困難なこと
が分かった。また、乾式伸線ワイヤ表面の余分な潤滑剤
をブラシ、バフ等での乾式除去を検討したが、除去むら
等により付着量および色調が安定せず送給性も変動し、
安定した性能が得られなかった。
Table 1 Comparative Example No. As shown in FIG. 10, in the case of the flux-cored wire without wrap shown in FIG. 1A, the opening width of the seam is wide, and when wet drawing is performed for the purpose of removing dry lubricant, the lubricant is discharged from the opening through the wire. Get inside. Therefore, the present inventors have searched and studied various lubricant compositions and methods that can achieve the target feedability without deteriorating the arc stability only by dry drawing that can minimize the number of steps. Is ensured, the amount of lubricant attached becomes excessive. Conversely, if the amount of adhesion is reduced, the lubricating film will not be formed stably, and the wire drawing will deteriorate due to lack of lubrication, and wire roughening and disconnection will occur frequently. It turned out to be very difficult. In addition, we examined the dry removal of excess lubricant on the surface of the dry drawn wire with a brush, buff, etc., but the amount and color tone were not stable due to unevenness of removal, and the feedability fluctuated.
Stable performance could not be obtained.

【0028】[0028]

【表1】 [Table 1]

【0029】先ず、フラックス入りワイヤの合せ目を図
1(b)に示すラップ状とし、ラップ代LRを成形時の
ロール締め付け調整により変えたワイヤを製造し湿式伸
線を始めるワイヤ径、即ち総減面率を変えて伸線してワ
イヤのトータル水素を測定した。なお、ワイヤのトータ
ル水素量は黒鉛坩堝中の試料をHeガス中で高周波溶解
して出る水素ガスを水性ガス融解−熱伝導度法によりJ
IS Z 2614に準拠して測定した。その結果を図2
に示す。この結果から総減面率を80%以上にした場
合、表1比較例No.10,11に示したようにラップ
代15%未満ではでトータル水素量が高く安定化しない
ことが分かった。また、ラップ代LRを30%以上にす
ると表1比較例No.12のようにフラックスの充填率
が小となり必要なフラックス量が不足し、安定したスラ
グ被包およびアークを得ることが困難となる。また、ア
ークの偏りが認められ、ワイヤの直進性も損なわれる。
従ってラップ代は15〜30%に限定した。
First, the joint of the flux-cored wire is illustrated.
A wire is manufactured by changing the wrap margin shown in FIG. 1 (b) and changing the wrap margin LR by adjusting the roll tightening at the time of forming, and changing the wire diameter at which wet drawing is started, that is, changing the total area reduction ratio and drawing the total wire. Hydrogen was measured. The total amount of hydrogen in the wire was determined by subjecting a sample in a graphite crucible to high-frequency melting in He gas and discharging hydrogen gas by water gas fusion-thermal conductivity method.
It was measured according to IS Z 2614. Figure 2 shows the result.
Shown in From this result, when the total area reduction rate was 80% or more, Table 1 Comparative Example No. As shown in FIGS. 10 and 11, it was found that the total hydrogen amount was high and the stabilization was not achieved when the lapping amount was less than 15%. When the lap allowance LR is set to 30% or more, Table 1 Comparative Example No. As shown in 12, the filling rate of the flux becomes small, the required amount of the flux becomes insufficient, and it becomes difficult to obtain a stable slag encapsulation and an arc. In addition, the bias of the arc is recognized, and the straightness of the wire is impaired.
Therefore, the lap cost was limited to 15 to 30%.

【0030】また、ラップ率15%以上で総減面率は8
0%以上であればトータル水素量の増加は少なくなるの
で本発明では下限のみを限定した。しかし、総減面率の
上限は製品径となるが、軟化処理を行わない場合、加工
限界に達し断線率が増加するため97%以下に抑える事
が生産性の点で望ましい。従って、ラップ代が15〜3
0%のフラックス入りワイヤ素線であればワックスを2
〜20%添加した乾式潤滑剤を使用して総減面率80%
以上まで伸線すれば、湿式伸線しても合せ目からの湿式
潤滑剤侵入による水素量増加を防止できることが分かっ
た。
Further, when the lap rate is 15% or more, the total area reduction rate is 8
If it is 0% or more, the increase in the total hydrogen amount is small, and therefore, only the lower limit is limited in the present invention. However, although the upper limit of the total area reduction rate is the product diameter, when the softening treatment is not performed, the processing limit is reached and the disconnection rate increases, so that it is desirable to suppress the reduction to 97% or less from the viewpoint of productivity. Therefore, the lap fee is 15-3
For 0% flux cored wire, use 2 wax.
80% gross surface reduction using dry lubricant added to 20%
It was found that if the wire was drawn up to the above, it was possible to prevent an increase in the amount of hydrogen due to the penetration of the wet lubricant from the joint even by the wet wire drawing.

【0031】次にラップ代をワイヤ径の25%、湿式伸
線までの総減面率90%一定として乾式伸線後、湿式伸
線の混合潤滑剤構成、濃度を変えて伸線し最適洗浄条件
を検討した。洗浄は洗浄油を通すのみでは必要以上に付
着した潤滑剤を十分除去できない。そこで孔ダイス通過
時伸線と同時に余分の潤滑剤を除去するのが効率的であ
るが、洗浄剤のみでは伸線潤滑性が乏しく線荒れ断線を
起こす。又表1比較例No.17のように油性潤滑剤の
みでは洗浄効果が少なく、付着潤滑剤量の減少が少な
い。そこで湿式潤滑剤に洗浄剤を添加して最適の比率を
見いだすため確認試験を実施したが再現性が低いので更
に検討を行った結果、油性潤滑剤に有る範囲で乾式潤滑
剤を添加したほうが洗浄性が向上し、少ないダイス数で
色調が安定し、所期の潤滑剤付着量に出来ることを見出
した。
Next, the wire wrap is fixed at 25% of the wire diameter and the total area reduction rate until the wet drawing is constant at 90%. After the dry drawing, the composition and the concentration of the mixed lubricant of the wet drawing are changed and the drawing is carried out for optimal cleaning. The conditions were examined. In cleaning, it is not possible to sufficiently remove the lubricant adhering more than necessary only by passing the cleaning oil. Therefore, it is efficient to remove excess lubricant at the same time as wire drawing when passing through the hole die. However, with a cleaning agent alone, wire drawing lubricity is poor and wire roughening and wire breakage occur. Table 1 Comparative Example No. As shown in FIG. 17, the cleaning effect is small with only the oil-based lubricant, and the amount of the attached lubricant is small. Therefore, a confirmation test was conducted to find the optimum ratio by adding a cleaning agent to the wet lubricant, but the reproducibility was low.As a result of further investigation, it was found that adding a dry lubricant within the range of oil-based lubricant It has been found that the properties are improved, the color tone is stabilized with a small number of dies, and the desired amount of lubricant attached can be achieved.

【0032】即ち、乾式伸線後の洗浄ダイス伸線潤滑剤
として湿式潤滑剤に乾式潤滑剤を添加した場合、乾式潤
滑剤が重量比で40%未満では表1比較例No.18の
ように付着潤滑剤レベルが低下し、一定となるのに時間
がかかり、付着量、色調も安定しない。逆に、乾式潤滑
剤比率が60%を越えると表1比較例No.19のよう
に湿式潤滑剤の流動性が低下してワイヤ表面へ潤滑剤が
安定して届かず付着量が不安定となり、最終的には潤滑
が途切れて線荒れ断線を起こす。従って混合潤滑剤は乾
式潤滑剤が重量比で40%以上で上限は流動性の点から
60%迄に限定した。
That is, when a dry lubricant is added to a wet lubricant as a cleaning die drawing lubricant after dry drawing, if the dry lubricant is less than 40% by weight, Comparative Example No. 1 in Table 1 is used. As shown in FIG. 18, it takes time for the attached lubricant level to decrease and become constant, and the attached amount and color tone are not stable. On the other hand, when the dry lubricant ratio exceeds 60%, Table 1 Comparative Example No. As shown in FIG. 19, the fluidity of the wet lubricant is reduced, the lubricant does not reach the wire surface stably, and the amount of adhesion becomes unstable, and finally the lubrication is interrupted, resulting in rough and broken wires. Accordingly, the weight of the mixed lubricant is limited to 40% or more by weight of the dry lubricant, and the upper limit is limited to 60% from the viewpoint of fluidity.

【0033】本発明に用いる乾式潤滑剤は高融点ワック
ス、金属石鹸、MoS2、WS2、PTFE、グラファイ
トの1種または2種以上をいう。乾式潤滑剤に混合する
ワックスは乾式潤滑剤を安定して孔ダイスへ持ち込ま
せ、伸線中の剥離脱落を防止し、安定した潤滑剤付着を
確保すると共に合せ目をシールすることにより湿式潤滑
剤の侵入を防止し、洗浄後の製品径での安定した適正付
着量、色調を確保するため添加する。また、ワイヤ表面
に付着した潤滑剤に撥水性を保持させ保管中の吸湿およ
び発錆防止に効果がある。しかし、添加量が2%未満で
は表1比較例No.15のように効果が認められず、2
0%を越えて添加すると表1比較例No.16のように
潤滑剤持ち込み量が過多となり、かえって伸線中に剥離
が発生し、最終径での付着量が変動し、色調、送給性が
安定しないワイヤとなる。従って本発明では乾式潤滑剤
中のワックス添加量は重量比で2〜20%に限定する。
尚、乾式潤滑剤の付着をより安定化させるため圧着ロー
ル、回転ダイスおよびダイス、ロールの水冷等をを併せ
て実施することが望ましい。
The dry lubricant used in the present invention refers to one or more of high melting point wax, metal soap, MoS 2 , WS 2 , PTFE, and graphite. The wax mixed with the dry lubricant allows the dry lubricant to be stably brought into the hole die, prevents peeling and falling off during wire drawing, secures stable lubricant adhesion, and seals the joint to wet lubricant. Is added to prevent intrusion of the ink and to secure a stable and appropriate amount and color tone of the product after cleaning. In addition, the lubricant attached to the wire surface is kept water repellent, which is effective in preventing moisture absorption and rusting during storage. However, if the addition amount is less than 2%, the results are shown in Table 1. No effect was observed as in 15 and 2
When more than 0% is added, Table 1 Comparative Example No. As shown in Fig. 16, the amount of the lubricant brought in becomes excessive, the peeling occurs during the drawing, and the amount of adhesion at the final diameter fluctuates, and the wire becomes unstable in color tone and feedability. Therefore, in the present invention, the amount of wax added to the dry lubricant is limited to 2 to 20% by weight.
In order to further stabilize the adhesion of the dry lubricant, it is preferable to carry out a combination of a pressure roll, a rotary die, and water cooling of the die and the roll.

【0034】また、本発明に使用する湿式潤滑剤は油性
潤滑剤に洗浄剤を重量比で5〜80%添加するが、5%
未満では表1比較例No.20、22に示すように洗浄
が不足し潤滑剤付着量が多くなるため明度が低く、スパ
ッタが多く、アークが安定しない。逆に洗浄剤を80%
以上添加すると表1比較例No.21、23に示すよう
に洗浄過多となり必要な潤滑剤付着量が得られず送給性
が低下し、安定した溶接ができない。
The wet lubricant used in the present invention is obtained by adding a detergent to an oil-based lubricant in a weight ratio of 5 to 80%.
If it is less than Table 1, Comparative Example No. As shown in FIGS. 20 and 22, cleaning is insufficient and the amount of lubricant adhering increases, resulting in low brightness, large spatter, and unstable arc. Conversely, 80% of detergent
When the above additions were made, Table 1 Comparative Example No. As shown in FIGS. 21 and 23, excessive washing resulted in a lack of a necessary amount of lubricant attached, resulting in a decrease in feedability and a failure in stable welding.

【0035】油性潤滑剤は常温で液状であり伸線時の発
熱により変質、固化せずに潤滑性能が損なわれない動植
物油、鉱物油または合成油を基油として使用できる。例
えば植物油としてはパーム油、菜種油、椰子油、オリー
ブ油、ひまし油等、動物油としてはラード、羊油、肝油
等、鉱物油としてはマシン油、タービン油、スピンドル
油等、合成油としてはオレフィン重合油、ジエステル
油、ポリアルキレングリコール油、ハロゲン化炭化水素
油、シリコーン油等がある。
The oil-based lubricant is a liquid at room temperature and can be used as a base oil such as animal or vegetable oils, mineral oils or synthetic oils which are not deteriorated or solidified by the heat generated during drawing and do not impair the lubricating performance. For example, vegetable oils such as palm oil, rapeseed oil, coconut oil, olive oil, castor oil, etc .; animal oils such as lard, sheep oil, liver oil, etc .; mineral oils such as machine oil, turbine oil, spindle oil etc .; There are diester oil, polyalkylene glycol oil, halogenated hydrocarbon oil, silicone oil and the like.

【0036】洗浄剤は沸点が160〜260℃程度のガ
ス油、軽油、灯油、クレオソート油または炭化水素系油
等を使用できるが沸点は低めで範囲の小さいものを選択
した方が分離、再生に有利となる。
As the cleaning agent, gas oil, light oil, kerosene, creosote oil or hydrocarbon oil having a boiling point of about 160 to 260 ° C. can be used. This is advantageous.

【0037】本発明の方法により製造した合せ目フラッ
クス入りワイヤの表面の色調は銀白色の金属色を呈する
が、伸線時の条件、即ち、潤滑剤の種類、組成、温度、
粘度および引抜ダイス材質等の条件により変動する。そ
こで、ワイヤの表面状況を色彩計で計測し、その値とワ
イヤ品質、特に送給性との関係を検討した。
The color tone of the surface of the seam flux-cored wire produced by the method of the present invention has a silver-white metallic color, but the conditions at the time of wire drawing, that is, the kind, composition, temperature,
It varies depending on conditions such as viscosity and drawing die material. Therefore, the surface condition of the wire was measured with a colorimeter, and the relationship between the value and the wire quality, especially the feedability was examined.

【0038】ワイヤ表面の色調は目視感覚条件に近いJ
IS Z 8722定義のD−0法に準拠したパルスキセ
ノンランプ拡散光の垂直反射光を一定条件で計測し、J
ISZ 8729のL***表色系に準拠したL**
表色系で表し、数値記録した。各種条件の本発明例ワイ
ヤおよび比較ワイヤをスプールに整列巻きした後の色調
は表1の試験No.1〜9に示すようになりワイヤ表面
の潤滑剤付着量および送給性と相関のあることが分かっ
た。
The color tone of the wire surface is similar to the visual sense condition.
The vertical reflected light of the pulsed xenon lamp diffused light is measured under certain conditions in accordance with the D-0 method defined in ISZ 8722, and J
L * C * h conforming to L * a * b * color system of ISZ 8729
Expressed in color system and recorded numerically. The color tone of the wire of the present invention under various conditions and the comparative wire after being aligned and wound on a spool are shown in Test No. 1 in Table 1. As shown in FIGS. 1 to 9, it was found that there was a correlation between the amount of lubricant attached to the wire surface and the feedability.

【0039】しかし、ワイヤ表面の色調は金属光沢の銀
白色で色相および彩度の変動は少なく明度L*が最もワ
イヤの色調の変動と良く対応するので、これらの結果か
ら製品ワイヤの明度L*の範囲を40〜60に特定し、
この数値範囲内となるように伸線条件を調整にする事に
より安定した色調と送給性を得ることが出来た。
However, since the color tone of the wire surface is silver-white of metallic luster and the variation in hue and saturation is small and the lightness L * corresponds best with the variation in the color tone of the wire, the lightness L * of the product wire is obtained from these results . Is specified as 40-60,
By adjusting the drawing conditions so as to fall within this numerical range, a stable color tone and feedability could be obtained.

【0040】明度L*が40未満ではワイヤ表面の潤滑
剤の付着量が多く溶接時にワイヤ送給ロールのスリップ
率が高く安定した溶接作業性が得られない。逆に明度L
*が60を越えるとワイヤ表面の潤滑剤付着量が不足
し、送給抵抗が高く、送給が不安定となり、甚だしい場
合はワイヤが挫屈して溶接ができなくなる。
When the lightness L * is less than 40, the amount of lubricant attached to the wire surface is large, and the slip ratio of the wire feed roll during welding is high, and stable welding workability cannot be obtained. Conversely, lightness L
If * exceeds 60, the amount of lubricant attached to the wire surface will be insufficient, the feed resistance will be high, and the feed will be unstable. In extreme cases, the wire will buckle and welding will not be possible.

【0041】さらに、使用条件に応じてはワイヤ製造の
最終工程、例えば伸線の最終ダイスまたはスプール巻き
取り等で潤滑油の微量塗布によりワックス等および個体
潤滑剤のみの場合より送給抵抗が低下し、過酷な条件下
での送給性がより安定化する。例えば、冬季等の低温環
境で溶接を開始したとき一般に送給抵抗は高く、コンジ
ットケーブルの屈曲状態が大きく、送給抵抗が大きい場
合送給が不安定となる場合があるが、この様な場合でも
油を塗布すると送給抵抗がより低く、ア−クが安定する
までの時間がみじかくなる効果がある。塗布油としては
常温で液体である油性潤滑油を使用する。
Further, depending on the use conditions, a small amount of lubricating oil is applied in the final step of wire production, for example, in the final die for wire drawing or spool winding, so that the feeding resistance is lower than in the case of using only wax or the like and solid lubricant. However, the feedability under severe conditions is further stabilized. For example, when welding is started in a low temperature environment such as winter, the feed resistance is generally high, the bent state of the conduit cable is large, and the feed may be unstable if the feed resistance is large. However, applying oil has the effect of lowering the feed resistance and shortening the time until the arc is stabilized. An oily lubricating oil that is liquid at normal temperature is used as the application oil.

【0042】[0042]

【実施例】以下、実施例により本発明の効果を具体的に
説明する。図3に示す工程に従ってラップ幅、総減面率
を変化させて湿式伸線し、ワックス添加量を調整したワ
イヤ径 1.2、1.6mmのJISZ 3313に規定さ
れるYFW−C50DRのフラックス入りワイヤ(充填
率15%)を試作した。供試ワイヤは充填フラックスを
所定の充填率に充填し湿式伸線前の各減面率まで乾式伸
線後、製品径まで湿式伸線した。更に整列巻き工程でス
プールに巻き取り試験に供した。
EXAMPLES The effects of the present invention will be specifically described below with reference to examples. Wet drawing was performed by changing the wrap width and the total area reduction rate according to the process shown in FIG. 3, and the amount of wax added was adjusted. Wire diameter 1.2, 1.6 mm, YFW-C50DR flux contained in JISZ 3313. A wire (filling rate: 15%) was prototyped. The test wire was filled with the filling flux at a predetermined filling rate, dry-drawn to each reduction area before wet-drawing, and then wet-drawn to the product diameter. Further, a winding test was performed on a spool in the alignment winding process.

【0043】色調はJIS Z 8722 D−0法に準
拠して設計された色彩色差計(MINOLTA CR−
300)を巻き取りワイヤ面と垂直となるように設置し
てスプールに整列巻きしたワイヤ表面を図4に示す要領
で5mmずつワイヤ長手方向と直角方向にずらして測定、
これを90゜ずつ回転し4箇所測定した平均値で評価し
た。
The color tone is determined by a colorimeter (MINOLTA CR-) designed in accordance with JIS Z 8722 D-0 method.
300) was placed perpendicular to the winding wire surface, and the wire surface aligned and wound on a spool was measured by shifting the wire surface by 5 mm in the direction shown in FIG.
This was rotated at 90 ° and evaluated at an average value measured at four points.

【0044】溶接作業性および送給性は図5に示す装置
で6m 長さのコンジットケーブル6を使用し、ループ径
D150mmで2ターンさせ7、表2に示す溶接条件で各
20kgずつターンテーブル10の鋼鈑9上で下向き溶接
した。
The welding workability and the feedability were as follows: using a conduit cable 6 having a length of 6 m with the apparatus shown in FIG. Was welded downward on the steel plate 9.

【0045】[0045]

【表2】 [Table 2]

【0046】ワイヤの送給性は上記の条件で溶接中送給
ロールの押し出し力とコンジットケーブルの反力を送給
抵抗R、送給ロールの周速度 VRとワイヤのの送給速度
Wから下式によりスリップ率SLを算出して評価し
た。実際の測定は図5に示す様にワイヤ送給ロール4の
反力によってワイヤ2が後退する方向に負荷がかかるが
このときに生じた力をロードセル5によって送給抵抗R
として測定した。また、ワイヤ送給ロール部でのスリッ
プ率SLは送給ロール4の周速度(VR)と送給ロール入
り口手前に設置したメジャリングロール3によりワイヤ
の送給速度(VW)を測定し次式によって求めた。 スリップ率SL(%)=(VR―VW)・100/VR
The wire feed of the sheet resistance feeding resistors R a reaction force of the pushing force and the conduit cable feed roll during welding in the above condition, the peripheral velocity V R and the wire of the feed speed V W of the feed roll The slip ratio SL was calculated from the following equation and evaluated. In the actual measurement, as shown in FIG. 5, a load is applied in a direction in which the wire 2 retreats due to the reaction force of the wire feed roll 4, but the force generated at this time is supplied by the load cell 5 to the feed resistance R.
Was measured. The slip ratio SL at the wire feeding roll portion is obtained by measuring the peripheral speed (V R ) of the feeding roll 4 and the wire feeding speed (V W ) by the measuring roll 3 installed just before the entrance of the feeding roll. It was determined by the following equation. Slip ratio SL (%) = (V R -V W) · 100 / V R

【0047】送給性の評価は送給抵抗Rが60N以下、
スリップ率SLが10%以下の場合良好と判定した。溶
接は3分/回で溶接トーチ、鋼鈑を冷却して行い、送給
抵抗Rとスリップ率SLを測定し平均値を求めた。アー
クの安定性およびスパッタは感応試験で市販の同種ワイ
ヤと比較して同等以上を○、やや劣るものを△、かなり
劣るものを×とした。それらの結果を表1にまとめて示
す。表1において、試験No.1〜9が本発明の実施
例、試験No.10〜23が比較例である。
The evaluation of the feeding performance was such that the feeding resistance R was 60 N or less,
It was determined to be good when the slip ratio SL was 10% or less. The welding was performed by cooling the welding torch and the steel plate at 3 minutes / time, and the feed resistance R and the slip ratio SL were measured to obtain an average value. Regarding the stability of the arc and the spatter, in the sensitivity test, ○ was evaluated as being equal to or higher than that of a commercially available wire of the same type, Δ was evaluated as being slightly inferior, and × was evaluated as being considerably inferior. The results are summarized in Table 1. In Table 1, Test No. 1 to 9 are Examples of the present invention, Test Nos. 10 to 23 are comparative examples.

【0048】試験のNo.1〜9はワイヤ表面の明度が
安定し、溶接時のスリップ率及び送給抵抗が低く、アー
クも安定しており極めて満足な結果であった。また、い
ずれも拡散性水素量は8mL/100g溶着金属以下であっ
た。
Test No. The samples Nos. 1 to 9 had very satisfactory results in that the brightness of the wire surface was stable, the slip ratio and the feeding resistance during welding were low, and the arc was stable. In each case, the amount of diffusible hydrogen was 8 mL / 100 g or less of the deposited metal.

【0049】No.10、11はラップ率が本発明の範
囲より小さい場合で拡散性水素量が非常に高く、No.
10はピットが多発し、No.11は溶接ビード表面に
溝状の欠陥とピットが発生した。 No.12はラップ
率が本発明の範囲を越えた場合でアークが粗く、スラグ
の被包が安定せずビード外観が劣る。No.13,14
は総減面率が下限より少ない場合でいずれも拡散性水素
量が高く溝状の溶接欠陥が認められた。No.15,1
6は乾式潤滑剤中のワックス添加量が本発明範囲外でN
o.15は潤滑剤の持ち込みが安定せず潤滑剤被膜が途
切れ伸線中断線し易く、ワイヤ表面の送給潤滑剤付着量
が不足のため明度が本発明の範囲を越え、No.16は
逆に付着量が多く、明度が本発明の範囲より低くワイヤ
の送給が不安定で安定した溶接が出来なかった。 N
o.17,18、19は湿式初頭潤滑剤中の乾式潤滑剤
添加量が本発明の範囲外の場合でNo.17,18は洗
浄が不足で安定せず、明度が低くワイヤの送給が不安定
であった。No.19は初頭湿式潤滑剤の流動性が低下
し安定した洗浄が出来ず、溶接アーク、送給性が不安定
であった。 No.20,22は湿式潤滑剤中の洗浄剤
添加量が本発明の範囲より少ない場合でいずれも洗浄不
足で潤滑剤付着量が多く明度が本発明範囲を下回り、ア
ーク、送給性が不安定であった。No.21,23は湿
式潤滑剤中の洗浄剤添加量が本発明の範囲を越え潤滑油
添加量が少ない場合でいずれも洗浄過多で潤滑剤付着量
が少なく明度が本発明範囲を越え、アーク、送給性が不
安定であった。
No. Nos. 10 and 11 have a very high diffusible hydrogen content when the lap ratio is smaller than the range of the present invention.
No. 10 had many pits. No. 11 had groove-like defects and pits on the surface of the weld bead. No. In No. 12, when the lap ratio exceeds the range of the present invention, the arc is coarse, the slag encapsulation is not stable, and the bead appearance is inferior. No. 13,14
In each of the cases where the total area reduction rate was less than the lower limit, the diffusible hydrogen content was high and groove-like welding defects were observed in all cases. No. 15,1
No. 6 indicates that the amount of wax added in the dry lubricant is out of the range of the present invention and N
o. In No. 15, the lubricating agent was not stable, the lubricant film was interrupted, and the drawing was liable to be interrupted, and the amount of the lubricant supplied on the wire surface was insufficient, so that the brightness exceeded the range of the present invention. Conversely, No. 16 had a large amount of adhesion, the lightness was lower than the range of the present invention, and the feeding of the wire was unstable, and stable welding could not be performed. N
o. Nos. 17, 18, and 19 are cases where the amount of dry lubricant added to the wet early lubricant is out of the range of the present invention. Nos. 17 and 18 were not stable due to insufficient cleaning, and had low brightness and unstable wire feeding. No. In No. 19, the fluidity of the initial wet-type lubricant was lowered, stable cleaning could not be performed, and welding arc and feedability were unstable. No. Nos. 20 and 22 are cases where the amount of the detergent added in the wet lubricant is less than the range of the present invention. In all cases, the cleaning is insufficient, the amount of the lubricant attached is large, the brightness falls below the range of the present invention, and the arc and the feeding property are unstable. there were. No. Reference numerals 21 and 23 indicate that when the amount of the detergent added in the wet lubricant exceeds the range of the present invention and the amount of the lubricating oil added is small, the amount of the lubricant exceeds the range of the present invention due to excessive cleaning, the amount of the adhered lubricant is small, and Feeding was unstable.

【0050】本実施例ではJIS Z 3313の軟鋼、
490N/mm2抗張力鋼用YFW−C50RDについて
例示したが他鋼種およびシールドガスス、また、JIS
Z3318、Mo、Cr−Mo鋼、JIS Z 3319
エレクトロガスアーク溶接用、JIS Z 3320耐候
性鋼用、JIS Z 3323ステンレス鋼、JISZ 3
326硬化肉盛用等他鋼種の合せ目のある溶接用フラッ
クス入りワイヤにも適用が可能である。
In the present embodiment, JIS Z 3313 mild steel,
490 N / mm 2 YFW-C50RD for tensile strength steel is illustrated, but other steel types and shielding gas, and JIS
Z3318, Mo, Cr-Mo steel, JIS Z3319
For electrogas arc welding, JIS Z 3320 for weathering steel, JIS Z 3323 stainless steel, JISZ 3
It is also applicable to flux cored wires for welding with seams of other steel types such as 326 hardfacing.

【0051】[0051]

【発明の効果】以上詳述したように、本発明による製造
方法で合せ目のあるフラックス入りワイヤの湿式伸線に
よる、送給潤滑剤付着量調整を可能し、ワイヤ表面の色
調を管理する事により、軟質で長尺のコンジットケーブ
ルを使用した厳しい屈曲条件、かつ高電流条件で溶接さ
れる場合においても、長時間安定したアークの溶接が可
能と成る優れた効果を奏するアーク溶接用フラックス入
りワイヤを提供できる。
As described above in detail, it is possible to control the amount of lubricant supplied and to control the color tone of the wire surface by the wet drawing of the flux-cored wire with seams in the manufacturing method according to the present invention. Flux-cored wire for arc welding that has an excellent effect that enables stable arc welding for a long time even when welding is performed under severe bending conditions and high current conditions using a soft and long conduit cable Can be provided.

【図面の簡単な説明】[Brief description of the drawings]

【図1】フラックス入りワイヤのワイヤ断面を示す図で
ある。
FIG. 1 is a diagram showing a cross section of a flux-cored wire.

【図2】ラップ率および総減面率とトータル水素量の関係を
示す図である
FIG. 2 is a diagram showing a relationship between a lap ratio, a total area reduction ratio, and a total hydrogen amount.

【図3】フラックス入りワイヤの製造工程を示す図であ
る。
FIG. 3 is a view showing a manufacturing process of a flux-cored wire.

【図4】ワイヤ表面の色調測定要領を示す図である。FIG. 4 is a diagram showing a procedure for measuring the color tone of the wire surface.

【図5】本発明の実施例に使用した溶接装置を示す図で
ある。
FIG. 5 is a view showing a welding apparatus used in the embodiment of the present invention.

【符号の説明】[Explanation of symbols]

1 ワイヤスプールコンジットケーブル 2 溶接ワイヤ 3 メジャリングロール 4 送給ロール 5 ロードセル 6 6mコンジットケーブル 7 コンジットケーブル屈曲部 8 溶接トーチ 9 溶接用鋼鈑 10 ターンテーブル DESCRIPTION OF SYMBOLS 1 Wire spool conduit cable 2 Welding wire 3 Measuring roll 4 Feeding roll 5 Load cell 6 6m conduit cable 7 Conduit cable bending part 8 Welding torch 9 Welding steel plate 10 Turntable

───────────────────────────────────────────────────── フロントページの続き (72)発明者 阿部 昌樹 東京都中央区築地三丁目5番4号 日鐵溶 接工業株式会社内 Fターム(参考) 4E084 AA44 CA38 DA09 HA12 4E096 EA02 EA12 EA16 EA24 GA03 HA01 HA02 JA12 JA13 KA01 ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Masaki Abe 3-5-4 Tsukiji, Chuo-ku, Tokyo Nippon Steel Welding Industry Co., Ltd. F-term (reference) 4E084 AA44 CA38 DA09 HA12 4E096 EA02 EA12 EA16 EA24 GA03 HA01 HA02 JA12 JA13 KA01

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 合せ目を有するフラックス入りワイヤに
おいて、ワイヤ外皮の合せ目ラップ代長さがワイヤ径の
15〜30%であり、ワイヤ表面の明度L*が40〜6
0、更にワイヤ表面に固形潤滑剤を有することを特徴と
するアーク溶接用フラックス入りワイヤ。
In a flux-cored wire having a seam, the seam wrap margin length of the wire sheath is 15 to 30% of the wire diameter, and the lightness L * of the wire surface is 40 to 6
0. A flux cored wire for arc welding, further comprising a solid lubricant on the surface of the wire.
【請求項2】 ワイヤ表面の固形潤滑剤の上に油性潤滑
剤を塗布したことを特徴とする請求項1記載のアーク溶
接用フラックス入りワイヤ。
2. The flux cored wire for arc welding according to claim 1, wherein an oily lubricant is applied on the solid lubricant on the surface of the wire.
【請求項3】 合せ目を有するフラックス入りワイヤの
製造方法において、フラックスを充填した合せ目ラップ
代長さがワイヤ径の15〜30%であるフラックス入り
ワイヤを素線とし、該素線を乾式潤滑剤を用いて総減面
率で80%以上伸線し、次いで孔ダイスを用いて湿式伸
線する事を特徴とするアーク溶接用フラックス入りワイ
ヤの製造方法。
3. A method of manufacturing a flux-cored wire having a seam, wherein a flux-cored wire having a length of 15-30% of a wire diameter filled with the flux is used as a wire, and the wire is dry-processed. A method for producing a flux-cored wire for arc welding, comprising drawing a wire in a total area reduction of 80% or more using a lubricant, and then drawing it wet using a hole die.
【請求項4】 乾式潤滑剤は重量比で高融点ワックスを
2〜20%含み、湿式潤滑剤は油性潤滑剤に洗浄剤を重
量比で5〜80%含むことを特徴とする請求項3記載の
アーク溶接用フラックス入りワイヤの製造方法。
4. The dry lubricant contains 2 to 20% by weight of a high melting point wax by weight, and the wet lubricant contains 5 to 80% by weight of a detergent to an oily lubricant. Of manufacturing flux-cored wire for arc welding.
【請求項5】 湿式伸線の第1ダイス潤滑剤は湿式潤滑
剤に乾式潤滑剤を重量比で40〜60%含むことを特徴
とする請求項4記載のアーク溶接用フラックス入りワイ
ヤの製造方法。
5. The method for producing a flux-cored wire for arc welding according to claim 4, wherein the first die lubricant for wet drawing includes a wet lubricant containing 40 to 60% by weight of a dry lubricant. .
JP35924099A 1999-12-17 1999-12-17 Flux cored wire for arc welding and method of manufacturing the same Pending JP2001179481A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP35924099A JP2001179481A (en) 1999-12-17 1999-12-17 Flux cored wire for arc welding and method of manufacturing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP35924099A JP2001179481A (en) 1999-12-17 1999-12-17 Flux cored wire for arc welding and method of manufacturing the same

Publications (1)

Publication Number Publication Date
JP2001179481A true JP2001179481A (en) 2001-07-03

Family

ID=18463484

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP2001179481A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2859122A1 (en) * 2003-08-28 2005-03-04 Kobe Steel Ltd METHOD FOR MANUFACTURING WELDED SOLDER WELDING WIRE
JP2006281315A (en) * 2005-03-10 2006-10-19 Kobe Steel Ltd Welding wire and its manufacturing method
JP2008239221A (en) * 2007-03-28 2008-10-09 Kobe Steel Ltd Method and package for packaging semifinished wire product for welding with seam containing flux
US8901455B2 (en) 2008-06-18 2014-12-02 Lincoln Global, Inc. Welding wire for submerged arc welding
US8952295B2 (en) 2008-06-18 2015-02-10 Lincoln Global, Inc. Welding wire with perovskite coating
CN109475985A (en) * 2016-08-30 2019-03-15 株式会社神户制钢所 Seamless flux-cored wire is used in welding

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2859122A1 (en) * 2003-08-28 2005-03-04 Kobe Steel Ltd METHOD FOR MANUFACTURING WELDED SOLDER WELDING WIRE
US7626139B2 (en) 2003-08-28 2009-12-01 Kabushiki Kaisha Kobe Seiko Sho Method for manufacturing seamed flux-cored welding wire
JP2006281315A (en) * 2005-03-10 2006-10-19 Kobe Steel Ltd Welding wire and its manufacturing method
JP2008239221A (en) * 2007-03-28 2008-10-09 Kobe Steel Ltd Method and package for packaging semifinished wire product for welding with seam containing flux
US8901455B2 (en) 2008-06-18 2014-12-02 Lincoln Global, Inc. Welding wire for submerged arc welding
US8952295B2 (en) 2008-06-18 2015-02-10 Lincoln Global, Inc. Welding wire with perovskite coating
CN109475985A (en) * 2016-08-30 2019-03-15 株式会社神户制钢所 Seamless flux-cored wire is used in welding

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