JP2001170736A - Method for manufacturing magnesium alloy thin formed body and thin formed body - Google Patents

Method for manufacturing magnesium alloy thin formed body and thin formed body

Info

Publication number
JP2001170736A
JP2001170736A JP37323599A JP37323599A JP2001170736A JP 2001170736 A JP2001170736 A JP 2001170736A JP 37323599 A JP37323599 A JP 37323599A JP 37323599 A JP37323599 A JP 37323599A JP 2001170736 A JP2001170736 A JP 2001170736A
Authority
JP
Japan
Prior art keywords
forging
rough
magnesium alloy
thin
peripheral wall
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP37323599A
Other languages
Japanese (ja)
Inventor
Shinji Seki
新治 関
Shigehiro Taniike
茂弘 谷池
Hiroshi Watanabe
洋 渡辺
Yasuo Hama
葆夫 濱
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TOKYO SEITANKOSHO KK
Proterial Ltd
Original Assignee
TOKYO SEITANKOSHO KK
Hitachi Metals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TOKYO SEITANKOSHO KK, Hitachi Metals Ltd filed Critical TOKYO SEITANKOSHO KK
Priority to JP37323599A priority Critical patent/JP2001170736A/en
Publication of JP2001170736A publication Critical patent/JP2001170736A/en
Pending legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To provide a magnesium alloy thin casing having a light weight, high quality, a sufficiently filled boss part and a recessed part at a bottom part. SOLUTION: The method of manufacturing a magnesium alloy forging thin formed body consists of a rough forging process, in which by forging a thin stock at a forging temperature of 200-540 deg.C and at a forging speed of 10-500 mm/sec, the thin stock is forged at a draft of <=75% to be formed to a bottomed rough forged body having a peripheral wall part, and a finish forging process, in which a rough forging formed body obtained in the rough forging process is forged at a forging temperature of 200-540 deg.C and at a draft of <=30% while loading a forming load of 1-20 ton/cm2. In the rough forging process and/or the finish forging process, a projecting part at a center part of a punch and/or a die is arranged so that a thickness near a center of the bottom part of the formed body is thinner than a thickness near a peripheral part, thereby the neighborhood of the bottom center part of the formed body is forged so as to be thinner than a bottom part thickness of the neighborhood of the peripheral part.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本願発明はマグネシウム合金
製薄肉素材を鍛造加工により成形する製造方法に関する
ものであり、特に小形軽量機器の筐体等の用途に適した
マグネシウム合金製薄肉成形体の製造方法に関するもの
である。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of manufacturing a thin magnesium alloy material by forging, and more particularly to a method of manufacturing a thin magnesium alloy product suitable for use in housings of small and lightweight equipment. It is about.

【0002】[0002]

【従来の技術】マグネシウムは、現在実用化されている
金属材料の中で最も比重が小さい材料である。すなわ
ち、マグネシウムの比重は1.8であり、現在、軽量化
材料として各種用途に広く使用されているアルミニウム
の比重2.7と比較しても、非常に小さい。このため、
マグネシウム合金はアルミニウム合金に代わる軽量化材
料として最近注目されており、幅広い分野において使用
されつつある。
2. Description of the Related Art Magnesium is the material having the lowest specific gravity among the metal materials currently put into practical use. That is, the specific gravity of magnesium is 1.8, which is much smaller than the specific gravity of aluminum, which is currently widely used in various applications as a lightweight material, of 2.7. For this reason,
Magnesium alloys have recently received attention as a lightweight material to replace aluminum alloys, and are being used in a wide range of fields.

【0003】しかしながら、アルミニウム合金に比べ、
マグネシウム合金は塑性加工性において問題がある。こ
のため、マグネシウム合金の殆どは鋳造材として使用さ
れているのが現状である。一般的に鋳造材として使用さ
れるマグネシウム合金は、主成分元素であるマグネシウ
ムに、基本的な添加元素としてアルミニウムおよび亜鉛
を含有させて強度の向上を図るとともに鋳造性を得てい
る。また、強度と靭性を付与するためにジルコニウムを
添加したり、結晶粒の微細化を図るためにマンガンを添
加したり、耐熱性を付与するために希土類元素や銀を添
加したりすることもある。しかし、マグネシウム合金溶
湯を鋳造して得られる成形体は、その製法上の制約か
ら、比較的厚肉のものに限定される。また、その製造過
程中において、鋳造欠陥や酸化物を内部および表面に介
在させてしまう恐れが大きい。もしも、これら欠陥等が
介在していると、機械的強度の点で問題があり、また耐
食性等についても問題が発生する。
However, compared to aluminum alloys,
Magnesium alloys have a problem in plastic workability. For this reason, at present, most magnesium alloys are used as cast materials. In general, a magnesium alloy used as a casting material achieves castability while improving strength by adding aluminum and zinc as basic additive elements to magnesium as a main component element. Also, zirconium may be added to impart strength and toughness, manganese may be added to reduce the size of crystal grains, or rare earth elements or silver may be added to impart heat resistance. . However, compacts obtained by casting a magnesium alloy melt are limited to relatively thick ones due to restrictions on the manufacturing method. Further, during the manufacturing process, there is a great possibility that casting defects and oxides are interposed inside and on the surface. If these defects are present, there is a problem in mechanical strength, and a problem also occurs in corrosion resistance and the like.

【0004】マグネシウム合金からなる薄肉成形体を得
る他の方法として、マグネシウム合金薄板素材からの絞
り加工が考えられる。マグネシウム合金薄板の絞り加工
について開示されている文献としては、例えば、特開平
6−55230号公報,特開平6−328155号公報
などがある。しかし、これらの公報には、「ポンチ、フ
ランジ部共に表面温度が175℃以上、500℃以下の
温度範囲に加熱された金型を用いて成形すると、マグネ
シウム薄板の深絞り成形が可能となる」ことが開示さ
れ、深絞りの温間加工に適した金型温度についての示唆
がされているものの、隅部や周壁部のボスの成形につい
ての開示や示唆は無い。
As another method for obtaining a thin molded body made of a magnesium alloy, drawing from a magnesium alloy sheet material can be considered. Documents which disclose the drawing of magnesium alloy sheets include, for example, JP-A-6-55230 and JP-A-6-328155. However, these publications state that "when a punch and a flange are formed using a mold heated to a temperature range of 175 ° C. or more and 500 ° C. or less, deep drawing of a magnesium thin plate becomes possible”. Although there is a suggestion about a mold temperature suitable for deep drawing warm working, there is no disclosure or suggestion about forming a boss at a corner or a peripheral wall.

【0005】[0005]

【発明が解決しようとする課題】近年、電子回路部品・
素子の高集積化・高密度化等を背景にして、携帯電話機
等の小形通信機器,ノート型あるいはモバイル型パソコ
ン等の小形事務機器,その他多くの用途において、小型
化・軽量化が盛んに試みられており、それら機器の筐体
などにも小型化・軽量化が求められている。かかる要求
に応えるものの一つとして、アルミニウム合金からなる
薄肉成形体が広く使われているが、同等以上の機械的強
度を有しつつ更なる軽量化を図るために、マグネシウム
合金製の薄肉成形体の出現が望まれている。しかしなが
ら、マグネシウムの結晶構造が稠密六方晶であるため、
鍛造時のマグネシウム合金の鍛造時の金属流れ(以下
「メタルフロー」という)の制御が極めて難しいため、
理想的な塑性加は極めて難しい。
In recent years, electronic circuit components and
With high integration and high density of devices, miniaturization and weight reduction of small communication equipment such as mobile phones, small office equipment such as notebook and mobile personal computers, and many other applications are actively pursued. Therefore, miniaturization and weight reduction of housings of these devices are also required. To meet such demands, thin-walled compacts made of aluminum alloys are widely used, but in order to further reduce the weight while maintaining the same or higher mechanical strength, thin-walled compacts made of magnesium alloy The emergence of is desired. However, since the crystal structure of magnesium is dense hexagonal,
Because it is extremely difficult to control the metal flow during forging of the magnesium alloy during forging (hereinafter referred to as “metal flow”),
Ideal plasticity is extremely difficult.

【0006】前述したマグネシウム合金薄板素材からの
絞り加工においては、しわの発生防止が不可欠であり、
しわ押さえ部分を必要とするために材料歩留まりの点で
問題がある。このことは、特に小物の成形体を作製する
場合に大きな問題となる。また、隅部や周壁部に厚肉の
ボスがある場合に、このボス部にメタルフローを集めな
ければならない。本願発明は、かかる従来技術における
問題点等を解消するためになされたものであり、アルミ
ニウム合金よりも軽いマグネシウム合金からなる主要部
分の肉厚が1.5mm以下で、底部中央部近辺に薄肉部
を有する薄肉成形体を提供することを目的とするもので
ある。ここでいう主要部分とは、底部や周壁部など大部
分が均一の肉厚を持つ部分を指し、突起部やボスなどの
高さなどは含まないものとする。
In the above-described drawing from a magnesium alloy sheet material, it is essential to prevent the occurrence of wrinkles.
There is a problem in terms of material yield due to the necessity of a wrinkle holding portion. This is a serious problem particularly when a small molded product is manufactured. Also, when there is a thick boss at the corner or the peripheral wall, the metal flow must be collected at this boss. The present invention has been made in order to solve the problems and the like in the prior art, the thickness of the main portion made of a magnesium alloy lighter than the aluminum alloy is 1.5 mm or less, a thin portion near the bottom center portion It is an object of the present invention to provide a thin-walled molded product having the following. Here, the main portion refers to a portion having a substantially uniform thickness, such as a bottom portion and a peripheral wall portion, and does not include the height of a projection or a boss.

【0007】[0007]

【課題を解決するための手段】本願発明者らは、上記目
的を達成するために、種々の加工方法について検討を行
った結果、マグネシウム合金薄板素材を鍛造加工するこ
とにより、目的とする薄肉のマグネシウム合金からなる
成形体を作製できることを知見し、本願発明を完成した
ものである。すなわち、マグネシウム合金薄板素材およ
び型の温度コントロールをした鍛造加工により展伸せし
めて成形体を得るという、絞り加工とは異なる新規な手
段により上記目的を達成出来たものである。更には、底
部中央部近傍に薄肉部を設け、このメタルを隅部や周壁
部のボスへ押し出す技術を完成させたものである。
Means for Solving the Problems The inventors of the present application have studied various processing methods to achieve the above object, and as a result, forged magnesium alloy sheet material to obtain a desired thin wall. The inventors have found that a molded body made of a magnesium alloy can be produced, and have completed the present invention. That is, the above object can be achieved by a novel means different from drawing, in which a magnesium alloy thin sheet material and a mold are stretched by forging with temperature control to obtain a formed body. Further, a technique is provided in which a thin portion is provided near the center of the bottom portion and the metal is extruded to a boss at a corner or a peripheral wall.

【0008】本願発明は、マグネシウム合金からなる薄
板素材を200〜540℃の鍛造温度で、10〜500
mm/秒の鍛造速度で鍛造加工することにより75%以
下の圧下率で薄肉素材を展伸させて周壁部を有する有底
形状荒鍛造成形体に成形する荒鍛造工程と、荒鍛造工程
で得られた荒鍛造成形体を200〜540℃の鍛造温度
で、1〜20ton/cm2 の成形荷重を負荷しながら
圧下率50%以下の鍛造加工をする仕上鍛造工程と、荒
鍛造工程または/および仕上鍛造工程において、成形体
の底部の中央近辺の肉厚が、周壁近傍の肉厚より薄くな
るように、ポンチまたは/およびダイの中央部分に凸部
を設け、成形体の底部中央部近辺が、周壁部近辺の底部
肉厚より肉薄になるように鍛造することを特徴とするマ
グネシウム合金製薄肉成形体の製造方法である。本願発
明において、上記合金薄板は、目的とする薄肉成形体の
底部面積とほぼ同じ若しくはやや大きい程度の形状に作
製したマグネシウム合金薄板を使用することが好まし
い。薄板素材が大きすぎる場合には、成形体隅部にしわ
等の欠陥が発生しやすく、また材料歩留まりも悪くな
る。一方、小さすぎる場合には、隅部や周壁部のボスに
おいて良好なメタルフローが得られず、充填不足や欠け
などが発生して良好な性状のボス部が形成できなくなる
ことがある。
According to the present invention, a thin sheet material made of a magnesium alloy is formed at a forging temperature of 200 to 540 ° C. at a forging temperature of 10 to 500.
By forging at a forging speed of mm / sec, a thin forging material is stretched at a draft of 75% or less to form a rough forged product with a peripheral wall and a bottomed shape. A finishing forging step of performing a forging process at a rolling reduction of 50% or less while applying a forming load of 1 to 20 ton / cm 2 at a forging temperature of 200 to 540 ° C. and a rough forging step or / and In the finish forging step, a convex portion is provided at the center of the punch or / and the die so that the thickness near the center of the bottom of the molded body is smaller than the thickness near the peripheral wall. And a method for manufacturing a thin formed body made of a magnesium alloy, wherein the forging is performed so as to be thinner than a bottom wall thickness near a peripheral wall portion. In the invention of the present application, it is preferable to use a magnesium alloy thin plate manufactured to have a shape approximately the same as or slightly larger than the bottom area of the target thin-walled molded product. If the thin sheet material is too large, defects such as wrinkles are likely to occur at the corners of the formed body, and the material yield is also reduced. On the other hand, if it is too small, a good metal flow cannot be obtained at the bosses at the corners and the peripheral wall portion, and insufficient filling or chipping may occur, making it impossible to form a boss having good properties.

【0009】本願発明において、好ましくは板厚3mm
以下のマグネシウム合金からなる薄板素材を200〜5
40℃の温度で、100〜540℃に加熱保持された荒
鍛造加工用金型内に載置して、3〜30ton/cm2
の成形荷重を負荷しながら10〜500mm/秒の鍛造
速度で鍛造加工することにより75%以下の圧下率で薄
肉素材を展伸させて周壁部を有する有底形状の荒鍛造成
形体に成形する荒鍛造工程と、荒鍛造工程で得られた荒
鍛造成形体を200〜540℃の温度で、100〜54
0℃に加熱保持した仕上鍛造加工用金型内に載置して、
1〜20ton/cm2 の成形荷重を負荷しながら1〜
200mm/秒の鍛造速度で鍛造加工することにより5
0%以下の圧下率で仕上成形する仕上鍛造工程と、荒鍛
造工程または/および仕上鍛造工程において、成形体の
底部の中央近辺の肉厚が、周壁近傍の肉厚より薄くなる
ように、ポンチまたは/およびダイの中央部分に凸部を
設け、成形体の底部中央部近辺が、周壁部近辺の底部肉
厚より肉薄になるように鍛造することを特徴とするマグ
ネシウム合金製薄肉成形体の製造方法である。本願発明
において、3mmを越える板厚のマグネシウム合金薄板
素材を用いた場合には、目的とする1.5mm以下の薄
肉成形体とするためには、鍛造加工における圧下率を大
きくしなければならず、鍛造時のマグネシウム合金のメ
タルフローが著しくなり、再結晶した微細粒子がメタル
フローに沿って出現したり、偏析して存在したりする恐
れがある。このため、本願発明において、薄板素材の板
厚は3mm以下とするのが好ましい。薄板素材は、組織
の均一性、欠陥などを考慮して、圧延材を用いると好ま
しい。
In the present invention, the thickness is preferably 3 mm.
The following sheet materials made of magnesium alloy were prepared for 200-5
At a temperature of 40 ° C., it is placed in a rough forging die heated and maintained at 100 to 540 ° C., and 3 to 30 ton / cm 2.
By forging at a forging speed of 10 to 500 mm / sec while applying a forming load of, a thin material is stretched at a rolling reduction of 75% or less to form a rough forged body having a bottomed shape having a peripheral wall portion. The rough forging step and the rough forging obtained in the rough forging step are performed at a temperature of 200 to 540 ° C. for 100 to 54 ° C.
Placed in a finish forging die heated and held at 0 ° C,
While applying a molding load of 1 to 20 ton / cm 2 ,
5 by forging at a forging speed of 200 mm / sec.
In the finish forging step of finish forming at a rolling reduction of 0% or less, and the rough forging step and / or the finish forging step, the punch is formed so that the thickness near the center of the bottom of the formed body is smaller than the thickness near the peripheral wall. And / or providing a convex portion at the center of the die, and forging such that the vicinity of the center of the bottom of the formed body is thinner than the thickness of the bottom near the peripheral wall. Is the way. In the present invention, when a magnesium alloy sheet material having a thickness of more than 3 mm is used, in order to obtain a target thin-walled molded article having a thickness of 1.5 mm or less, the rolling reduction in forging must be increased. In addition, the metal flow of the magnesium alloy during forging becomes remarkable, and recrystallized fine particles may appear along the metal flow or may be segregated. Therefore, in the present invention, the thickness of the thin plate material is preferably set to 3 mm or less. As the thin sheet material, it is preferable to use a rolled material in consideration of the uniformity of the structure, defects, and the like.

【0010】本願発明において、マグネシウム合金薄板
素材または荒鍛造成形体は、加熱して鍛造用金型内に載
置する。マグネシウム合金薄板素材は、鍛造温度に適し
た温度の200〜540℃(炉内雰囲気温度)に均一加
熱する。200℃未満の温度では鍛造時のメタルフロー
が円滑に得られず、ポンチとダイから構成される空間部
にマグネシウム合金が充満して展伸しないので、薄肉化
が困難であると共に隅部や周壁部のボスを良好に形成す
ることが出来ないことが多い。一方、540℃を超える
と結晶粒の粗大化を招き、また、加工率によっては発火
し燃焼する恐れもあるので、540℃を上限温度とす
る。好ましくは、450℃以下がよい。なお、本願発明
においては薄板素材の加熱が必須条件であるが、前述し
た公知文献記載の深絞り加工法においては、製法上の差
異もあり、マグネシウム合金薄板素材自体を加熱する必
然性については全く示唆されていない。上記本願発明に
おいて、マグネシウム合金薄板素材または荒鍛造成形体
の加熱は、大気中で行うと表面が酸化して、鍛造性,耐
食性,外観等に悪影響を及ぼす恐れがある。このため、
アルゴンガス等の不活性ガス雰囲気で行うことが望まし
い。また、予備加熱には、通常、雰囲気の制御がし易い
電気式加熱炉を用いると良い。
[0010] In the present invention, the magnesium alloy sheet material or the rough forged compact is heated and placed in a forging die. The magnesium alloy sheet material is uniformly heated to 200 to 540 ° C. (furnace atmosphere temperature), which is a temperature suitable for the forging temperature. If the temperature is less than 200 ° C., the metal flow during forging cannot be obtained smoothly, and the space formed by the punch and the die is filled with the magnesium alloy and does not expand. In many cases, it is not possible to form a good boss in the portion. On the other hand, if it exceeds 540 ° C., the crystal grains become coarse, and depending on the processing rate, there is a risk of ignition and burning. Preferably, the temperature is 450 ° C. or lower. In the present invention, heating of the sheet material is an indispensable condition. However, in the deep drawing method described in the above-mentioned known literature, there is a difference in the manufacturing method, and there is no suggestion about the necessity of heating the magnesium alloy sheet material itself. It has not been. In the above invention of the present application, when the magnesium alloy sheet material or the rough forged molded body is heated in the air, the surface is oxidized, which may adversely affect forgeability, corrosion resistance, appearance, and the like. For this reason,
It is desirable to carry out in an inert gas atmosphere such as argon gas. In addition, an electric heating furnace whose atmosphere can be easily controlled is usually preferably used for preheating.

【0011】本願発明において、鍛造加工は、成形荷重
1〜30ton/cm2 、鍛造速度1〜500mm/秒
の条件で鍛造加工することが望ましい。すなわち、鍛造
速度が500mm/秒を越えるような速い速度の場合に
は、メタルフローが鍛造速度に円滑に追随できなくな
り、メタルフローに乱れを生じて所望の形状が得られな
くなるので、鍛造速度の上限は500mm/秒とする。
一方、1mm/秒未満の鍛造速度では、薄板素材の温度
が低下して良好な鍛造精度のものが得にくく、また生産
性の低下も招くので、鍛造速度の下限を1mm/秒とす
る。本願発明において、生産性を重視する荒鍛造加工は
10〜500mm/秒の鍛造速度で行い、成形性を重視
する仕上鍛造加工は1〜200mm/秒の鍛造速度で行
うことが好ましい。
In the present invention, forging is desirably performed under the conditions of a forming load of 1 to 30 ton / cm 2 and a forging speed of 1 to 500 mm / sec. That is, if the forging speed is as fast as over 500 mm / sec, the metal flow cannot smoothly follow the forging speed, and the metal flow is disturbed and a desired shape cannot be obtained. The upper limit is 500 mm / sec.
On the other hand, if the forging speed is less than 1 mm / sec, the temperature of the thin sheet material is lowered, so that it is difficult to obtain a material having good forging accuracy, and the productivity is lowered. Therefore, the lower limit of the forging speed is set to 1 mm / sec. In the present invention, it is preferable that the rough forging with emphasis on productivity is performed at a forging speed of 10 to 500 mm / sec, and the finish forging with emphasis on formability is performed with a forging speed of 1 to 200 mm / sec.

【0012】本願発明において、30ton/cm2
超える成形荷重を負荷した場合には、製品および金型へ
の負荷が過大となるため、成形荷重の上限を30ton
/cm2 とする。一方、1ton/cm2 未満の成形荷
重では成形しにくくなるため、成形荷重の下限を1to
n/cm2 とする。また、本願発明において、特に成形
荷重が必要となる荒鍛造では3〜30ton/cm2
形荷重が小さくても十分である仕上鍛造では1〜20t
on/cm 2 とすることが望ましい。本願発明におい
て、荒鍛造加工時の圧下率を75%以下としたのは、7
5%を越える圧下率で鍛造した場合は、加工による発熱
が付加されて、発火・燃焼する恐れがあるためである。
安全性を考慮すれば、荒鍛造時の圧下率は、50%以下
とするのが好ましい。一方、仕上鍛造加工においては、
荒鍛造加工時の比較的大きな立ち上がり角部の半径を、
目標とする極めて小さな半径に成形するなど、加工量よ
りも成形性が重要なため、圧下率は50%以下,好まし
くは30%以下とするのがよい。このようにすることに
より、成形体の加工硬化を最小限に押さえることがで居
る。
In the present invention, 30 ton / cmTwo To
If a higher molding load is applied to the product and the mold
The upper limit of the molding load is 30 ton
/ CmTwo And On the other hand, 1 ton / cmTwo Less than molded load
Heavy weight makes molding difficult, so the lower limit of the molding load is 1 to
n / cmTwo And In the present invention, in particular,
For rough forging that requires a load, 3 to 30 ton / cmTwo Success
1 to 20 tons for finish forging, which is sufficient even with a small form load
on / cm Two It is desirable that In the present invention
Therefore, the reduction rate during rough forging was set to 75% or less because
When forging is performed with a draft of more than 5%, heat generated by processing
Is added, and there is a risk of ignition and burning.
Taking safety into account, the rolling reduction during rough forging is 50% or less.
It is preferred that On the other hand, in finish forging,
The radius of the relatively large rising corner during rough forging is
Processing amount, such as forming to the target extremely small radius
Since the moldability is important, the rolling reduction is preferably 50% or less.
Or less than 30%. To do this
Work hardening of the compact can be minimized.
You.

【0013】本願発明において、隅部や周壁部のボス部
へメタルフローを十分に流すためには中央部の肉をボス
部へ流すようにしてやればよく、金型の中央部付近を凸
部に形成し、強制的に中央部付近のメタルフローをボス
部へ向けるようにしてやるとよい。結果的にはマグネシ
ウム薄肉筐体の底部中央近辺が周壁部近辺より薄肉とな
る。この底部の薄肉部の形状はボスの位置により変化さ
せてよく、底部の外観から見た形状が、四角などの多角
形、星型または円形など形状は問わないし、断面で見た
時に、必ずしも底が直線でなくとも、円弧状、球形状な
どでもよい。また、薄肉部は筐体の外表面側に設けても
よいし、内表面側に設けてもよいし、また、両側に設け
てもよい。この薄肉部には、ラベルや注意事項などを貼
れるし、また、美観を増す図等を貼る事も出来るなど有
効に活用できる。
In the present invention, in order to sufficiently flow the metal flow to the bosses at the corners and the peripheral wall, the meat at the center may be caused to flow to the bosses. It is good to form and forcibly direct the metal flow near the center to the boss. As a result, the vicinity of the bottom center of the magnesium thin casing becomes thinner than the vicinity of the peripheral wall. The shape of the thin portion at the bottom may be changed depending on the position of the boss, and the shape of the bottom viewed from the external appearance may be any polygon such as a square, a star or a circle, and may not necessarily be the bottom when viewed in cross section. Is not a straight line, but may be an arc, a sphere, or the like. In addition, the thin portion may be provided on the outer surface side of the housing, may be provided on the inner surface side, or may be provided on both sides. Labels and precautions can be affixed to this thin portion, and a drawing that enhances the aesthetic appearance can be affixed.

【0014】本願発明による薄肉成形体は、所望のトリ
ミング、打ち抜き加工及び機械加工を施した後、仮防
食、塗装や陽極酸化皮膜処理を行うことが望ましい。マ
グネシウム合金の鍛造品は、表面性状が良く金属光沢に
優れるが、鍛造後に酸化して表面が金属光沢を失う恐れ
があるためである。特に本願発明による薄肉成形体は、
その外表面の粗度に優れており、底部および/または側
壁部の外側表面に陽極酸化皮膜処理を施すことにより金
属素地自体の光沢を活かした成形体を実現できる。
The thin molded article according to the present invention is desirably subjected to temporary corrosion protection, painting and anodic oxide film treatment after performing desired trimming, punching and machining. This is because a magnesium alloy forged product has good surface properties and excellent metallic luster, but may be oxidized after forging and lose its metallic luster. In particular, the thin molded body according to the present invention is
Its outer surface is excellent in roughness, and by applying an anodic oxide film treatment to the outer surface of the bottom and / or the side wall, it is possible to realize a molded product utilizing the luster of the metal substrate itself.

【0015】マグネシウム合金薄板素材を鍛造して、薄
肉成形体を製造するに際しては、鍛造性に優れたマグネ
シウム合金であることが望ましい。このため、本願発明
においては、重量比率で、Al:1〜6%,Mn:0.
5%以下、微量元素0.2%以下、残部Mg及び不可避
的不純物よりなるマグネシウム合金素材、または前記組
成において更にZn:2%以下を含有するマグネシウム
合金素材を選定することが好ましい。アルミニウムが低
いと鍛造性は良いが、剛性が悪くなるので、少なくとも
アルミニウムは1%以上とするのが良い。一方、アルミ
ニウム含有量が高くなると鍛造性,耐食性が低下するの
で、アルミニウム含有量は6%以下とするのが良い。亜
鉛も同様な影響があり、鍛造性とメタルフローの兼ね合
いから2%以下のものが良い。このような合金として
は、例えば、ASTM規格のAZ31合金、AM20合
金などがある。なお、本願発明に適用できるマグネシウ
ム合金は、上記組成に限定されるものではなく、微量元
素として、希土類元素,リチウム,ジルコニウム等を添
加含有したマグネシウム合金なども本願発明に適用可能
である。
When forging a magnesium alloy sheet material to produce a thin-walled compact, it is desirable that the magnesium alloy be excellent in forgeability. Therefore, in the present invention, Al: 1 to 6%, Mn: 0.
It is preferable to select a magnesium alloy material containing 5% or less, a trace element 0.2% or less, the balance being Mg and unavoidable impurities, or a magnesium alloy material further containing Zn: 2% or less in the above composition. If aluminum is low, forgeability is good, but rigidity deteriorates. Therefore, it is preferable that aluminum is at least 1% or more. On the other hand, if the aluminum content increases, the forgeability and corrosion resistance decrease, so the aluminum content is preferably 6% or less. Zinc has a similar effect, and is preferably 2% or less in view of the balance between forgeability and metal flow. Such alloys include, for example, ASTM standard AZ31 alloy, AM20 alloy and the like. The magnesium alloy applicable to the present invention is not limited to the above composition, and a magnesium alloy containing a rare earth element, lithium, zirconium, or the like as a trace element can also be applied to the present invention.

【0016】[0016]

【発明の実施の形態】以下本願発明の実施の形態につい
て説明する。 (実施の形態)図2は、本願発明により作製しようとす
るマグネシウム合金製薄肉成形体の一例を説明するため
の概略構成斜視図である。図2において、1は隅部およ
び周壁部にボスを持つマグネシウム合金製薄肉成形体で
あり、基本的な形状として、底部2と周壁部3を有する
断面が、図3に示すA−A断面のように、ほぼ凹状の成
形体である。また、底部2および周壁部3の肉厚tが
1.5mm以下と極めて薄肉である。更に、図3に示す
ように周壁部近傍の底部の肉厚w1と底部中央近辺の肉
厚w2をw1>w2とすることにより図3に示す薄肉部
6のメタルフローがボス部へ押し出され良好なボス4、
4’を得ることができる。
Embodiments of the present invention will be described below. (Embodiment) FIG. 2 is a schematic structural perspective view for explaining an example of a thin formed body made of a magnesium alloy to be produced according to the present invention. In FIG. 2, reference numeral 1 denotes a magnesium alloy thin molded body having bosses at corners and peripheral walls, and a cross section having a bottom 2 and a peripheral wall 3 as a basic shape is a cross section taken along the line AA shown in FIG. 3. Thus, it is a substantially concave shaped body. Also, the thickness t of the bottom 2 and the peripheral wall 3 is extremely thin, 1.5 mm or less. Further, as shown in FIG. 3, by setting the thickness w1 at the bottom near the peripheral wall and the thickness w2 near the center of the bottom to be w1> w2, the metal flow of the thin portion 6 shown in FIG. Boss 4,
4 'can be obtained.

【0017】図1は、本願発明の製造方法を実施するた
めの荒鍛造用金型の一例を示す概略構成説明図である。
図1において、11はマグネシウム合金からなる薄板素
材であり、下金型12に設けられた凹部(以下、「ダイ
部」とも称す)13上に載置される。ダイ13の中央凸
部14が形成されている。上金型15にはポンチ17と
呼ばれる凸部が有り、このポンチ17には、隅部や周壁
部にあるボスに相当する位置に窪み18、18’が設け
られている。図1では、底面部寸法よりも少し大きな形
状の薄板素材11を使用して凹部底面との間に若干隙間
があるように設置されているが、本願発明は、このよう
な戴置方法に限定されるものではない。戴置位置は使用
する薄板素材の形状寸法に応じて定められ、凹部底面に
接するように載置したり、凹部を覆うようにして凹部上
端部に戴置しても良い。使用する薄板素材の大きさは、
目標とする成形体の肉厚、周壁部の高さ,金型温度およ
び圧下率などの鍛造条件などから、適正な厚さと大きさ
のものを選択する。通常、得ようとする成形体の底部形
状よりも少し大きめの薄板素材を使用することが好まし
い。
FIG. 1 is a schematic structural explanatory view showing an example of a rough forging die for carrying out the manufacturing method of the present invention.
In FIG. 1, reference numeral 11 denotes a thin plate material made of a magnesium alloy, which is placed on a concave portion (hereinafter, also referred to as a “die portion”) 13 provided in a lower mold 12. A central projection 14 of the die 13 is formed. The upper mold 15 has a convex portion called a punch 17, and the punch 17 is provided with depressions 18 and 18 'at positions corresponding to bosses at corners and peripheral walls. In FIG. 1, the thin plate material 11 having a shape slightly larger than the bottom portion size is used and is installed so as to have a slight gap between the bottom surface of the concave portion. However, the present invention is limited to such a mounting method. It is not something to be done. The placement position is determined according to the shape and size of the thin plate material to be used, and may be placed so as to be in contact with the bottom surface of the concave portion, or may be placed at the upper end portion of the concave portion so as to cover the concave portion. The size of the thin plate material used is
An appropriate thickness and size are selected from the target forging conditions such as the thickness of the compact, the height of the peripheral wall, the mold temperature, and the draft. Usually, it is preferable to use a thin plate material slightly larger than the bottom shape of the molded product to be obtained.

【0018】仕上鍛造工程の金型(図示せず)も荒鍛造
工程の金型とほぼ同じ構成である。仕上鍛造工程金型
は、最終製品となる寸法に仕上がるよう、仕上しろ、削
りしろなどを付加した寸法となっている。本実施例で
は、荒鍛造工程から薄肉部6に相当するダイの凸部を有
している例を示したが、荒鍛造には無く、仕上鍛造工程
のみに、底部の薄肉部6に相当するダイの凸部を設けて
もよい。
The die (not shown) in the finish forging process has substantially the same configuration as the die in the rough forging process. The finish forging process die has dimensions to which a finishing margin, a shaving margin, and the like are added so as to finish to a size that will be a final product. In the present embodiment, an example is shown in which the die has a convex portion corresponding to the thin portion 6 from the rough forging process. However, it is not provided in the rough forging but corresponds to the thin portion 6 at the bottom only in the finish forging process. A projection of the die may be provided.

【0019】なお、上記鍛造加工により得られたマグネ
シウム合金製薄肉成形体には、通常周壁上端部等に鍛造
バリが発生しているので、パンチ等により鍛造バリを除
去するトリミングを行うことが必要である。また、必要
に応じて、所望の箇所に適宜機械加工を施す。マグネシ
ウム合金は鍛造後においても酸化して金属光沢を失うお
それがある。このため、仮防食、塗装等の表面処理を行
うが、特に、陽極酸化皮膜処理により酸化皮膜を形成す
ることで、通常行われている塗装では得られない優れた
防食性および合金素地を生かした金属光沢を有するマグ
ネシウム合金製薄肉成形体とするのが好ましい。
Since the thin formed body made of the magnesium alloy obtained by the above-mentioned forging usually has forged burrs at the upper end portion of the peripheral wall or the like, it is necessary to perform trimming for removing the forged burrs by a punch or the like. It is. Also, if necessary, a desired portion is appropriately machined. Magnesium alloys may be oxidized even after forging and lose their metallic luster. For this reason, surface treatments such as temporary corrosion protection and painting are performed, especially by forming an oxide film by anodic oxidation film treatment to take advantage of the excellent corrosion protection and alloy base material that cannot be obtained by ordinary painting. It is preferable to use a magnesium alloy thin molded body having a metallic luster.

【0020】(実施例1)まず、下金型の凹部(ダイ
部)13の中央部分に凸部14持つ下金型12と、周壁
部ボス4、4’、隅部ボス5に対応する部分の窪み1
8、18’を持つ上金型の凸部(ポンチ部)17を有す
る荒鍛造用金型、および図示しないが下金型の凹部(ダ
イ部)に荒鍛造金型と同じ位置に薄肉部6に相当する凸
部を持つ下金型と、荒鍛造金型と同じ位置に設けた夫々
の隅部ボス、または周壁部ボスに対応する窪みを有する
上金型の凸部(ポンチ部)を持つ仕上鍛造用金型(図示
せず)とを準備した。
(Embodiment 1) First, a lower die 12 having a convex portion 14 in the center of a concave portion (die portion) 13 of the lower die, portions corresponding to the peripheral wall bosses 4 and 4 ', and the corner boss 5. Depression 1
A rough forging die having a convex portion (punch portion) 17 of an upper die having 8, 8 'and a thin portion 6 (not shown) at the same position as the rough forging die in a concave portion (die portion) of a lower die. And a convex portion (punch portion) of an upper die having a depression corresponding to each corner boss or peripheral wall boss provided at the same position as the rough forging die. A finish forging die (not shown) was prepared.

【0021】次に、板厚1.2mm、75×100mm
の平板状AZ31Bマグネシウム合金薄板素材をアルゴ
ンガスで充満した電気式加熱炉内に装入し、450℃に
均一加熱した。次いで、素材を電気式加熱炉内から取り
出し、下金型のダイ部に載置し、金型温度400℃,鍛
造速度200mm/秒,成型荷重10ton/cm2
鍛造条件で荒鍛造を行った結果、底部の概略面積が60
×90mm、周壁部の有効高さが8mm、肉厚0.7m
m、底部薄肉部が0.6mmで、隅部ボスおよび周壁部
ボスを持つ外観上欠陥のない荒鍛造成形体が得られた。
Next, a plate thickness of 1.2 mm, 75 × 100 mm
Was placed in an electric heating furnace filled with argon gas and uniformly heated to 450 ° C. Next, the material was taken out of the electric heating furnace, placed on the die of the lower mold, and subjected to rough forging at a mold temperature of 400 ° C., a forging speed of 200 mm / sec, and a molding load of 10 ton / cm 2 . As a result, the approximate area of the bottom is 60
× 90mm, effective height of peripheral wall 8mm, wall thickness 0.7m
m, the bottom thin portion was 0.6 mm, and a rough forged product having no corner defects and peripheral wall bosses and having no defects in appearance was obtained.

【0022】次に、得られた荒鍛造成形体を電気式加熱
炉に装入して400℃に加熱し、金型温度350℃、鍛
造速度50mm/秒、成形荷重10ton/cm2 の鍛
造条件で仕上鍛造を行った結果、底部の面積が60×9
0mm、周壁部の有効高さが8mm、肉厚が0.6m
m、底部薄肉部0.45mmで、隅部ボスおよび周壁部
ボスを有する外観上欠陥のないマグネシウム合金からな
る薄肉成形体を得ることができた。
Next, the obtained rough forged compact was charged into an electric heating furnace and heated to 400 ° C., and the forging conditions were a mold temperature of 350 ° C., a forging speed of 50 mm / sec, and a forming load of 10 ton / cm 2 . As a result of finish forging, the area of the bottom was 60 × 9
0mm, effective height of peripheral wall is 8mm, wall thickness is 0.6m
m, a thin-walled molded body made of a magnesium alloy having a corner boss and a peripheral wall boss and having no defect in appearance, having a bottom thin portion of 0.45 mm.

【0023】上記実施例1乃至2に記載した実施例にお
いては、下型に凹部(ダイ部)を形成し、上型に凸部
(ポンチ部)を形成したが、本願発明は、その逆の構成
の金型を使っても良い。すなわち下型に形成したポンチ
部(凸部)上にマグネシウム合金薄板素材または荒鍛造
成形体を載置して成形しても良い。また、ダイ部に薄肉
部を作る凸部があることを示したが、ポンチ部に凸部を
設けてもよい。
In the embodiments described in the first and second embodiments, the concave portion (die portion) is formed in the lower die, and the convex portion (punch portion) is formed in the upper die. A mold having a configuration may be used. That is, a magnesium alloy thin plate material or a rough forged product may be placed on a punch portion (convex portion) formed in the lower die and molded. In addition, although it has been described that the die portion has a convex portion that forms a thin portion, the punch portion may have a convex portion.

【0024】[0024]

【発明の効果】本願発明によるマグネシウム合金製薄肉
成形体は、アルミニウム合金製の成形体よりもさらに軽
量で、剛性もあり、底部に薄肉部を設けたことにより、
隅部、周壁部のボスにメタルフローが流れ良好なボス形
状が得られる。この、薄肉部にはラベルや、注意事項等
を貼り付けることが可能である、また、適正な被覆処理
を施すことによりマグネシウム合金素地を生かした金属
光沢を有する製品を得ることも可能であり、各種機器の
軽量化を目的とする小型の薄肉筐体としての用途に適し
たものとして、広くその適用が期待できる。
The magnesium alloy thin molded article according to the present invention is lighter and more rigid than the aluminum alloy molded article, and has a thin section at the bottom.
The metal flow flows through the bosses at the corners and the peripheral wall, and a good boss shape is obtained. It is possible to attach a label, precautions, etc. to this thin part, and it is also possible to obtain a product with metallic luster utilizing the magnesium alloy base by applying an appropriate coating process, It is widely expected to be suitable for use as a small and thin housing for the purpose of reducing the weight of various devices.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本願発明の製造方法に係る荒鍛造用金型の要部
概略構成説明図である。
FIG. 1 is a schematic diagram illustrating a main part of a rough forging die according to a manufacturing method of the present invention.

【図2】本願発明に係るマグネシウム合金製薄肉成形体
の一例を示す概略構成斜視図である。
FIG. 2 is a schematic structural perspective view showing an example of a thin formed body made of a magnesium alloy according to the present invention.

【図3】図2のA−A断面を示す模式図である。FIG. 3 is a schematic view showing an AA cross section of FIG. 2;

【符号の説明】[Explanation of symbols]

1 マグネシウム合金製薄肉成形体 2 底部 3 周壁部 4、4’ボス(周壁部) 5 ボス(隅部) 6 薄肉部 11 マグネシウム合金薄板素材 12 下金型 13 下金型の凹部(ダイ) 14 ダイ部の凸部 15 上金型 17 上金型の凸部(ポンチ) 18、18’ ボス部に対応するポンチの窪み t 成形体肉厚 w1 底部の周壁近傍の肉厚 w2 底部の中央部近傍の肉厚 DESCRIPTION OF SYMBOLS 1 Thin molded body made of magnesium alloy 2 Bottom part 3 Peripheral wall part 4, 4 'boss (peripheral wall part) 5 Boss (corner part) 6 Thin part 11 Magnesium alloy thin plate material 12 Lower mold 13 Lower part of concave part (die) 14 Die Convex part 15 Upper die 17 Convex part (punch) of upper die 18, 18 'Depression of punch corresponding to boss part t Mold thickness w1 Thickness near peripheral wall at bottom w2 Thickness near center of bottom Thickness

───────────────────────────────────────────────────── フロントページの続き (72)発明者 渡辺 洋 東京都港区芝浦一丁目2番1号 日立金属 株式会社内 (72)発明者 濱 葆夫 栃木県真岡市鬼怒ヶ丘11番地 日立金属株 式会社素材研究所内 Fターム(参考) 4E087 BA03 BA19 CA11 CB02 CB04 CB11 CB12 DA04 EC11 HA91 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Hiroshi Watanabe 1-2-1 Shibaura, Minato-ku, Tokyo Within Hitachi Metals Co., Ltd. (72) Inventor Babao Hama 11 Kinuigaoka, Moka City, Tochigi Prefecture Hitachi Metals, Ltd. F-term in Shikisha Materials Research Laboratories (reference) 4E087 BA03 BA19 CA11 CB02 CB04 CB11 CB12 DA04 EC11 HA91

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 マグネシウム合金からなる薄板素材を2
00〜540℃の鍛造温度で、10〜500mm/秒の
鍛造速度で鍛造加工することにより75%以下の圧下率
で薄肉素材を展伸させて周壁部を有する有底形状荒鍛造
成形体に成形する荒鍛造工程と、荒鍛造工程で得られた
荒鍛造成形体を200〜540℃の鍛造温度で、1〜2
0ton/cm2 の成形荷重を負荷しながら圧下率50
%以下の鍛造加工をする仕上鍛造工程と、荒鍛造工程ま
たは/および仕上鍛造工程において、成形体の底部の中
央近辺の肉厚が、周壁近傍の肉厚より薄くなるように、
ポンチまたは/およびダイの中央部分に凸部を設け、成
形体の底部中央部近辺が、周壁部近辺の底部肉厚より肉
薄になるように鍛造することを特徴とするマグネシウム
合金製薄肉成形体の製造方法。
1. A thin sheet material made of a magnesium alloy
By forging at a forging temperature of 00 to 540 ° C. and a forging speed of 10 to 500 mm / sec, the thin material is stretched at a rolling reduction of 75% or less to form a forged bottomed rough molded body having a peripheral wall portion. The rough forging step to be performed and the rough forged body obtained in the rough forging step are forged at a forging temperature of 200 to 540 ° C. for 1 to 2 times.
50% reduction while applying a molding load of 0 ton / cm 2
% In the finish forging process and the rough forging process and / or the finish forging process in which the forging process is performed so that the thickness near the center of the bottom of the molded body is smaller than the thickness near the peripheral wall.
A convex portion is provided at a central portion of a punch or / and a die, and a forging is performed such that a portion near a bottom center portion of the formed body is thinner than a bottom portion thickness near a peripheral wall portion. Production method.
【請求項2】 板厚3mm以下のマグネシウム合金から
なる薄板素材を200〜540℃の温度で、100〜5
40℃に加熱保持された荒鍛造加工用金型に載置して、
3〜30ton/cm2 の成形荷重を負荷しながら10
〜500mm/秒の鍛造速度で鍛造加工することにより
75%以下の圧下率で薄肉素材を展伸させて周壁部を有
する有底形状荒鍛造成形体に成形する荒鍛造工程と、荒
鍛造工程で得られた荒鍛造成形体を200〜540℃の
温度で、100〜540℃に加熱保持した仕上鍛造加工
用金型に載置して、1〜20ton/cm2 の成形荷重
を負荷しながら1〜200mm/秒の鍛造速度で圧下率
50%以下の鍛造加工をする仕上鍛造工程と、荒鍛造工
程または/および仕上鍛造工程において、成形体の底部
の中央近辺の肉厚が、周壁近傍の肉厚より薄くなるよう
に、ポンチまたは/およびダイの中央部分に凸部を設
け、成形体の底部中央部近辺が、周壁部近辺の底部肉厚
より肉薄になるように鍛造することを特徴とするマグネ
シウム合金製薄肉成形体の製造方法。
2. A sheet material made of a magnesium alloy having a sheet thickness of 3 mm or less is treated at a temperature of 200 to 540 ° C. for 100 to 5 minutes.
Placed on a rough forging die held at 40 ° C,
While applying a molding load of 3 to 30 ton / cm 2 , 10
A rough forging process of expanding a thin material at a reduction rate of 75% or less by forging at a forging speed of up to 500 mm / sec and forming it into a bottomed rough forged product having a peripheral wall portion, and a rough forging process. The obtained rough forged compact was placed at a temperature of 200 to 540 ° C. on a finish forging die heated and maintained at 100 to 540 ° C., and a load of 1 to 20 ton / cm 2 was applied thereto while applying a forming load of 1 to 20 ton / cm 2. In the forging process of performing a forging process at a forging speed of up to 200 mm / sec and a reduction rate of 50% or less, and in the rough forging process and / or the forging process, the thickness near the center of the bottom of the molded body is reduced in the vicinity of the peripheral wall. A protrusion is provided at the center of the punch or / and the die so as to be thinner than the thickness, and forging is performed such that the vicinity of the bottom center of the molded body is thinner than the bottom thickness near the peripheral wall. Magnesium alloy thin-walled Method of manufacturing the body.
【請求項3】 マグネシウム合金薄板素材を、鍛造によ
り成形された成形体であって、その主要部分の肉厚が
1.5mm以下で、成形体の底部の中央部付近の肉厚
が、周壁部近傍の底部の肉厚より薄いことを特徴とする
マグネシウム合金製薄肉成形体。
3. A compact formed by forging a magnesium alloy sheet material, wherein the thickness of the main part is 1.5 mm or less, and the thickness near the center of the bottom of the compact is peripheral wall. A thin-walled product made of a magnesium alloy, which is thinner than a thickness of a bottom portion in the vicinity.
JP37323599A 1999-10-08 1999-12-28 Method for manufacturing magnesium alloy thin formed body and thin formed body Pending JP2001170736A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP37323599A JP2001170736A (en) 1999-10-08 1999-12-28 Method for manufacturing magnesium alloy thin formed body and thin formed body

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP28871799 1999-10-08
JP11-288717 1999-10-08
JP37323599A JP2001170736A (en) 1999-10-08 1999-12-28 Method for manufacturing magnesium alloy thin formed body and thin formed body

Publications (1)

Publication Number Publication Date
JP2001170736A true JP2001170736A (en) 2001-06-26

Family

ID=26557293

Family Applications (1)

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JP37323599A Pending JP2001170736A (en) 1999-10-08 1999-12-28 Method for manufacturing magnesium alloy thin formed body and thin formed body

Country Status (1)

Country Link
JP (1) JP2001170736A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003039592A (en) * 2001-07-30 2003-02-13 Hitachi Metals Ltd Thin-wall molded body and manufacturing method thereof
JP2010077465A (en) * 2008-09-24 2010-04-08 Sumitomo Electric Ind Ltd Molded body of magnesium alloy
US8329094B2 (en) 2008-04-01 2012-12-11 Kobe Steel, Ltd. Magnesium alloy and process for producing the same
CN103506808A (en) * 2012-06-27 2014-01-15 廖述源 Manufacturing method and product of slim shell

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003039592A (en) * 2001-07-30 2003-02-13 Hitachi Metals Ltd Thin-wall molded body and manufacturing method thereof
US8329094B2 (en) 2008-04-01 2012-12-11 Kobe Steel, Ltd. Magnesium alloy and process for producing the same
JP2010077465A (en) * 2008-09-24 2010-04-08 Sumitomo Electric Ind Ltd Molded body of magnesium alloy
CN103506808A (en) * 2012-06-27 2014-01-15 廖述源 Manufacturing method and product of slim shell

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