JP2001130164A - Damping water composition for lithographic printing plate - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a damping water composition for a lithographic printing block used in place of an isopropyl alcohol family, being comfortable in the working environment, provided with low dynamic surface tension, demonstrating stable printability even under the conditions of using a member rotated at a high speed, also demonstrating the good and stabilized printability for various kinds of inks and obtaining a superior printed matter. SOLUTION: A damping water composition for the lithographic printing block contains at least one kind of compound represented by following formula I (wherein, R1 represents a 1-8C alkyl and (m) represents an integer of 1-3). And at least one kind of compound selected from a group formed of compounds represented by formulas II, III and IV. (In the formula II, R2 represents a 1-4C alkyl and (n) represents an integer of 1-4, and in the formula III, R3 represents a 2-4C alkyl, and in the formula IV, R4 represents a hydrogen atom or a methyl).

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention relates to a fountain solution composition for a lithographic printing plate, and more particularly to a fountain solution composition useful for offset printing of a lithographic printing plate.

[0002]

2. Description of the Related Art Lithographic printing is a printing method that skillfully utilizes the property that water and oil are not essentially mixed. The printing plate surface has a region that receives water and repels oil-based ink, and a water-repellent oil-based ink. The former is a non-image area, and the latter is an image area. The dampening solution wets the non-image area to enlarge the surface chemistry difference between the image area and the non-image area, thereby increasing the ink repellency of the non-image area and the ink receptivity of the image area. Done. Examples of the fountain solution generally known in the art include alkali metal salts or ammonium salts of dichromic acid, phosphoric acid or salts thereof, such as ammonium salts, gum arabic, and colloidal substances such as carboxymethylcellulose (CMC). There is an aqueous solution added. However, the fountain solution containing only these compounds has a disadvantage that it is difficult to uniformly wet the non-image area of the plate, so that the printed matter sometimes becomes dirty, and considerable skill is required to adjust the supply amount of the fountain solution. Required.

In order to remedy this drawback, a Dahlgren system using an aqueous solution containing about 20 to 25% of isopropyl alcohol as dampening water has been proposed. According to this method, the wetting of the non-image area is improved, the amount of dampening water is small, the balance between the supply amounts of the printing ink and water is easily adjusted, and the dampening water in the printing ink is easily adjusted. There are many advantages in terms of workability and accuracy of the printed matter obtained, such as a reduction in the amount of emulsification of the ink and an improvement in the transferability of the printing ink to the blanket. However, since isopropyl alcohol is easy to evaporate, a special device for keeping the isopropyl alcohol concentration of the dampening solution constant is required, which is expensive in terms of price. Further, isopropyl alcohol has a peculiar unpleasant odor and also has a problem in toxicity, which is not preferable in a working environment. In addition, even if this dampening solution to which isopropyl alcohol is added is applied to offset printing using a normal water rod, the effect cannot be exerted because isopropyl alcohol evaporates on the roller and the plate surface, so that the effect cannot be exhibited. Had become.

[0004] Further, in recent years, public interest in industrial pollution has become extremely high, the regulation of chromium ion emission in wastewater has become strict, and the use of organic solvents such as isopropyl alcohol tends to be regulated in terms of safety and health. . Therefore, it is safe in terms of environmental hygiene, it can easily adjust the supply amount without requiring professional skills in printing work, and it not only prevents the printing plate from being stained, but also suitable for high-speed printing There is a need for a fountain solution composition for a lithographic printing plate that is capable of obtaining a high quality printed matter having excellent fountain solution properties.

[0005]

SUMMARY OF THE INVENTION It is an object of the present invention to provide a work environment which is comfortable and safe in place of isopropyl alcohol, and has a low dynamic surface tension and is excellent even under conditions of a member rotating at high speed. It is an object of the present invention to provide a fountain solution composition for a lithographic printing plate, which can exhibit stable printability and exhibit stable printability for various inks and can obtain excellent printed matter.

[0006]

Means for Solving the Problems The present inventors have set forth the above object.
On fountain solution composition for lithographic printing plate to achieve the target
As a result, a compound represented by the following general formula (I):
A compound represented by the following general formula (II), (III) or (IV)
And at least one compound selected from the group consisting of
By using them together, they are suitable for printing on various inks.
Has been greatly improved, and it is said that printing is particularly difficult
Inks containing metallic pigments, UV inks, etc.
Excellent fountain solution composition that specifically improves printing stability
Was obtained, and the present invention was completed.
Therefore, the present invention provides at least a compound represented by the following general formula (I).
And one compound represented by the following general formula (II), (III) or (I
V) at least selected from the group consisting of the compounds represented by
Lithographic printing plate characterized in that it also contains one compound
The present invention relates to a fountain solution composition. R¹O-(-CH_TwoCH (CH_Three) -O-)_m—H (I) (in the formula (I), R¹Represents an alkyl group having 1 to 8 carbon atoms.
And m represents an integer of 1 to 3. ) R^TwoO-(-CH_TwoCH_Two-O-)_n-H (II) R^ThreeOH (III) CH_Three-C (R^Four) (OCH_Three) -CH_TwoCH_TwoOH (IV) (in the formula (II), R^TwoRepresents an alkyl group having 1 to 4 carbon atoms
And n represents 1-4, and in formula (III), R^ThreeIs a carbon source
Represents an alkyl group having 2 to 4 children, and in the formula (IV), R ^FourIs water
Represents an elementary atom or a methyl group. )

[0007]

BEST MODE FOR CARRYING OUT THE INVENTION The fountain solution composition for lithographic printing plates of the present invention will be described in detail below. In general, when a fountain solution composition is used on a commercial basis, it is generally concentrated and commercialized. When used, such a concentrated solution is appropriately diluted and used. The contents and addition amounts of the various components mentioned below in this specification are based on the total weight of the fountain solution composition at the time of use, unless otherwise specified.

In the compound of the formula (I) used in the fountain solution composition for a lithographic printing plate of the present invention, R ¹ is a straight-chain or branched chain having 1 to 8 carbon atoms, preferably 3 to 6 carbon atoms. Represents an alkyl group of a chain, and m represents an integer of 1 to 3. These compounds are conventionally known as wettability improvers.
The compound of the general formula (I) is specifically exemplified by propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether, tripropylene glycol monoethyl ether, tetrapropylene glycol monoethyl ether. Propylene glycol monoethyl ether, propylene glycol monopropyl ether, dipropylene glycol monopropyl ether, tripropylene glycol monopropyl ether, propylene glycol monoisopropyl ether, dipropylene glycol monoisopropyl ether, tripropylene glycol monoisopropyl ether, propylene glycol monobutyl ether , Dipropylene glycol Monobutyl ether, tripropylene glycol monobutyl ether, propylene glycol monoisobutyl ether, dipropylene glycol monoisobutyl ether, tripropylene glycol monoisobutyl ether, propylene glycol monotertiary butyl ether, dipropylene glycol monotertiary butyl ether, tripropylene glycol monotertiary Butyl ether, propylene glycol monopentyl ether, dipropylene glycol monopentyl ether, propylene glycol monoisopentyl ether, dipropylene glycol monoisopentyl ether, propylene glycol mono n-hexane ether, dipropylene glycol n-hexane ether, propylene glycol monomethyl pliers Ether, dipropylene glycol monomethyl pentyl ether, propylene glycol mono-2-ethylbutyl ether, propylene glycol n- heptane ether, propylene grayed call n- octane ether, and the like. These compounds can be used alone or in combination of two or more.

[0009] Among them, propylene glycol monoisopropyl ether, dipropylene glycol monoisopropyl ether, propylene glycol mono n-butyl ether, propylene glycol mono t-butyl ether, dipropylene glycol mono n-butyl ether,
Dipropylene glycol mono-t-butyl ether, propylene glycol monoisobutyl ether, dipropylene glycol monoisobutyl ether, propylene glycol monoisopentyl ether, and the like can be preferably used. The content of the compound represented by the general formula (I) in the fountain solution composition is 0.2 based on the total mass of the fountain solution composition.
The amount is suitably from 8 to 8% by mass, more preferably from 0.5 to 5% by mass. When the amount is less than 0.2% by mass, the wettability of the dampening solution to the plate is poor. On the other hand, when the amount exceeds 8% by mass, the roller strip or the printing plate tends to have poor printing durability.

In the general formula (II), R ² represents a straight or branched chain having 1 to 4 carbon atoms, and n represents an integer of 1 to 4. Specific examples of the compound represented by the general formula (II) include ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, tetraethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol monoethyl ether, and triethylene glycol monomethyl ether. Ethyl ether, tetraethylene glycol monoethyl ether, ethylene glycol monopropyl ether, diethylene glycol monopropyl ether, triethylene glycol monopropyl ether, tetraethylene glycol monopropyl ether, ethyne glycol monoisopropyl ether, dietin glycol monoisopropyl ether, triet Tingle coal monoisopropyl A Le, tetra et quenching Le call monoisopropyl ether,

Ethylene glycol monobutyl ether,
Diethylene glycol monobutyl ether, triethylene glycol monobutyl ether, tetraethylene glycol monobutyl ether, ethylene glycol monoisobutyl ether, diethylene glycol monoisobutyl ether, triethylene glycol monoisobutyl ether, tetraethylene glycol monoisobutyl ether, ethylene glycol monotertiary butyl ether, diethylene glycol mono There are tertiary butyl ether, triethylene glycol monotertiary butyl ether, and tetraethylene glycol monotertiary butyl ether. These compounds can be used alone or in combination of two or more. Among them, ethylene glycol mono n-propyl ether, ethylene glycol mono t-butyl ether, ethylene glycol mono n-butyl ether and the like can be preferably used.

The compound represented by the general formula (III) is specifically ethyl alcohol, propyl alcohol, isopropyl alcohol, n-butyl alcohol, isobutyl alcohol, sec-butyl alcohol, tert-butyl alcohol. These compounds can be used alone or in combination of two or more. Among them, ethyl alcohol, n-butyl alcohol and t-butyl alcohol can be preferably used. Further, the compound represented by the general formula (IV) is specifically 3-methyl-3-methoxybutanol and 3-methoxybutanol. In particular, these two compounds can be preferably used because they have a function having excellent solubilizing properties.

The fountain solution composition of the present invention has the above general formula (I)
At least one compound selected from the group consisting of compounds represented by I), (III) and (IV) is contained. The kind and combination of the compound represented by the general formula (II), (III) or (IV) to be used, and the amount of the compound used are represented by the general formula (I)
It is important to appropriately select in consideration of the solubility of the compound represented by, the solubility of the water-soluble polymer compound used in the fountain solution, the cloud point or the dynamic surface tension of the fountain solution during use. is there.
For example, when a compound having a large number of carbon atoms in the alkyl group is used in the compound of the general formula (I), the compound of the general formula (II), (II)
The amount of the compound represented by I) or (IV) is usually relatively large. The compound represented by the general formula (II), (III) or (IV) has a cloud point of 40 ° C. of the fountain solution composition at the time of use.
In order to maintain the above, the dynamic surface tension is 30 to
It is desirable to select the combination and usage amount so as to be around 50 dyn / cm. Further, since the fountain solution composition is usually prepared as a concentrated composition for commercial use, the general formula (II), ( It is preferable to select the type, combination, and amount of the compound represented by (III) or (IV).

Accordingly, the general formula (II) used in the present invention,
At least one selected from the group consisting of the compounds represented by (III) or (IV), the combination and the amount of use are suitably selected in consideration of fountain solution suitability, solubilizing ability, economic cost and the like. Yes, depending on these factors. The amount of at least one selected from the group consisting of the compounds represented by the general formulas (II), (III) and (IV) is generally 0.05 to 5% based on the total weight of the fountain solution composition.
5.0 mass% is suitable, preferably 0.1 to 3.0 mass%.
It is.

The fountain solution composition of the present invention may further include the following. (a) Auxiliary agent for improving wettability (b) Water-soluble polymer compound (c) pH adjuster (d) Odor masking agent (e) Others (preservative, chelating agent, coloring agent,
Rust inhibitor, defoamer, etc.)

(A) As an auxiliary agent for improving the wettability, a surfactant or another solvent can be used. Among surfactants, for example, anionic surfactants include fatty acid salts, abietic salts, hydroxyalkanesulfonates, alkanesulfonates, dialkylsulfosuccinates, linear alkylbenzenesulfonates, branched alkylbenzenesulfonates Acid salts, alkyl naphthalene sulfonates, alkyl phenoxy polyoxyethylene propyl sulfonates, polyoxyethylene alkyl sulfenyl ether salts, N-methyl-N-oleyl taurine sodium salts, N-alkyl sulfosuccinic acid monoamide disodium salts, Petroleum sulfonates, sulfated castor oil, sulfated tallow oil, sulfates of fatty acid alkyl esters, alkyl sulfates, polyoxyethylene alkyl ether sulfates, fatty acids Noglyceride sulfates, polyoxyethylene alkyl phenyl ether sulfates, polyoxyethylene styryl phenyl ether sulfates, alkyl phosphates, polyoxyethylene alkyl ether phosphates, polyoxyethylene alkyl phenyl ether phosphates, styrene -Partially saponified products of maleic anhydride copolymer, partially saponified products of olefin-maleic anhydride copolymer, and naphthalenesulfonic acid formalin condensates. Of these, dialkyl sulfosuccinates, alkyl sulfates and alkyl naphthalene sulfonates are particularly preferably used.

Examples of nonionic surfactants include polyoxyethylene alkyl ethers, polyoxyethylene alkyl phenyl ethers, polyoxyethylene polystyryl phenyl ethers, polyoxyethylene polyoxypropylene alkyl ethers, and glycerin fatty acid partial esters. , Sorbitan fatty acid partial esters, pentaerythritol fatty acid partial esters, propylene glycol monofatty acid esters, sucrose fatty acid partial esters, polyoxyethylene sorbitan fatty acid partial esters, polyoxyethylene sorbitol fatty acid partial esters, polyethylene glycol fatty acid esters Kind,
Polyglycerin fatty acid partial esters, polyoxyethylenated castor oils, polyoxyethylene glycerin fatty acid partial esters, fatty acid diethanolamides, N,
Examples include N-bis-2-hydroxyalkylamines, polyoxyethylene alkylamines, triethanolamine fatty acid esters, and trialkylamine oxides. In addition, a fluorine-based surfactant and a silicon-based surfactant can also be used. Among them, polyoxyethylene alkyl phenyl ethers, polyoxyethylene-polyoxypropylene block polymers and the like are preferably used. Further, a surfactant such as a silicon derivative or a fluorine derivative may also be used. When a surfactant is used, its content is suitably 1.0% by mass or less, preferably 0.001 to 0.5% by mass in view of foaming. Also, two or more kinds can be used in combination.

Other auxiliaries include propylene glycol, dipropylene glycol, tripropylene glycol, tetrapropylene glycol and pentapropylene glycol, ethylene glycol, diethylene glycol, triethylene glycol, butylene glycol, hexylene glycol, glycerin, diglycerin. , Polyglycerin, trimethylolpropane, and the like. These solvents may be used alone,
More than one species may be used in combination. In general, these solvents are suitably used in the range of 0.1 to 3% by mass, preferably 0.3 to 2% by mass, based on the total mass of the fountain solution composition.

The water-soluble polymer compound (b) used in the fountain solution composition of the present invention includes, for example, gum arabic, starch derivatives (eg, dextrin, enzymatically decomposed dextrin,
Natural products such as hydroxypropylated enzyme-decomposed dextrin, carboxymethylated starch, phosphate starch, octenylsuccinated starch), alginate, and fibrin derivatives (eg, carboxymethylcellulose, carboxyethylcellulose, methylcellulose) and modified products thereof, polyethylene glycol and The copolymer, polyvinyl alcohol and its derivatives, polyvinylpyrrolidone, polyacrylamide and its copolymer, polyacrylic acid and its copolymer, vinyl methyl ether / maleic anhydride copolymer, vinyl acetate / maleic anhydride copolymer And a composite of polystyrene sulfonic acid and a copolymer thereof.
The content of the water-soluble polymer compound is based on the fountain solution composition.
0.0001 to 0.1% by mass is suitable, and more preferably 0.0005 to 0.05% by mass.

(C) p used in the fountain solution composition of the present invention
As the H regulator, water-soluble organic and / or inorganic acids or salts thereof can be used.
It is effective for H adjustment, pH buffering, moderate etching of the lithographic printing plate support or anticorrosion. Preferred organic acids include, for example, citric acid, ascorbic acid, malic acid, tartaric acid, lactic acid, acetic acid, gluconic acid, acetic acid, hydroxyacetic acid, oxalic acid, malonic acid, levulinic acid, sulfanilic acid, p
-Toluenesulfonic acid, phytic acid, organic phosphonic acid and the like. Examples of the inorganic acid include phosphoric acid, nitric acid, sulfuric acid, and polyphosphoric acid. Further, these organic acids and / or
Or alkali metal salts of inorganic acids, alkaline earth metal salts or ammonium salts, organic amine salts are also suitably used,
These organic acids, inorganic acids and / or salts thereof may be used alone or as a mixture of two or more. The amount of these pH adjusters added to the fountain solution composition of the present invention is preferably in the range of 0.001 to 0.3% by mass, and the pH value of the fountain solution composition is in the acidic range of 3 to 7. Although it is preferable to use, it can also be used in an alkaline range of pH 7 to 11 containing alkali metal hydroxide, phosphoric acid, alkali metal salt, alkali metal carbonate, silicate and the like.

(D) The odor masking agent includes esters which are conventionally known for use as fragrances. For example, there is one represented by the following general formula (V). R ⁵ —COOR ⁶ (V) In the compound of the general formula (V), R ⁵ is a group having 1 carbon atom.
To 15 alkyl groups, alkenyl groups or aralkyl groups,
Alternatively, it is a phenyl group. In the case of an alkyl group or an alkenyl group, the number of carbon atoms is preferably 4 to 8.
When R ⁵ represents an alkyl group, an alkenyl group or an aralkyl group, they may be linear or branched. As the alkenyl group, one having one double bond is particularly suitable. Examples of the aralkyl group include a benzyl group and a phenylethyl group. In addition, one or more hydrogen atoms of the alkyl group, alkenyl group, or aralkyl group represented by R ⁵ or the phenyl group may be substituted with a hydroxyl group or an acetyl group. R ⁶ is an alkyl group having 3 to 10 carbon atoms, an aralkyl group or a phenyl group, which may be linear or branched. In the case of an alkyl group, it preferably has 3 to 9 carbon atoms. Examples of the aralkyl group include a benzyl group and a phenylethyl group.

Specific examples of (d) odor masking agents that can be used include formic acid, acetic acid, propionic acid, butyric acid, isobutyric acid,
2-ethylbutyric acid, valeric acid, isovaleric acid, 2-methylvaleric acid, hexanoic acid (caproic acid), 4-methylpentanoic acid (isohexanoic acid), 2-hexenoic acid, 4-pentenoic acid, heptanoic acid, 2- Methylheptanoic acid, octanoic acid (caprylic acid), nonanoic acid, decanoic acid (capric acid),
Esters of 2-decenoic acid, lauric acid or myristic acid. In addition, there are acetoacetic esters such as benzyl phenylacetate, ethyl acetoacetate and 2-hexyl acetoacetate. Among them, preferred are n-pentyl acetate, isopentyl acetate, n-butyl butyrate, n-pentyl butyrate and isopentyl butyrate, with n-butyl butyrate, n-pentyl butyrate and isopentyl butyrate being particularly preferred. The content of these odor masking agents (d) in the dampening solution composition is suitably 0.0001 to 10% by mass, more preferably 0.001 to 1% by mass, based on the total mass of the dampening solution composition. %. By using these, the working environment can be further improved. Also. Vanillin, ethyl vanillin and the like may be used in combination.

The preservative (e) used in the fountain solution composition of the present invention includes phenol or a derivative thereof, formalin, an imidazole derivative, sodium dehydroacetate,
-Isothiazolin-3-one derivatives, benztriazole derivatives, amidine or guanidine derivatives, quaternary ammonium salts, pyridine, quinoline or guanidine derivatives, diazine or triazole derivatives, oxazole or oxazine derivatives, bromonitro alcohol-based bromonitro Propanol, 1,1-dibromo-1
-Nitro-2-ethanol, 3-bromo-3-nitropentane, 2,4-diol and the like. The preferred amount of addition is an amount that exerts a stable effect on bacteria, molds, yeasts, etc., and varies depending on the type of bacteria, molds, and yeasts. The range is preferably 0.0% by mass, and it is preferable to use two or more preservatives which are effective against various molds, bacteria and yeasts.

The fountain solution composition of the present invention further comprises (e)
Chelating agents can be added. The fountain solution composition is usually prepared by diluting the concentrated fountain solution composition with tap water, well water and the like at the time of use, and at this time, calcium ions contained in the diluted tap water or well water are used. May adversely affect printing and may cause stains on printed matter. In such a case, the above-mentioned disadvantage can be solved by adding a chelating agent. Preferred chelating agents include, for example, ethylenediaminetetraacetic acid, its potassium salt and its sodium salt; diethylenetriaminepentaacetic acid, its potassium salt and its sodium salt;
Triethylenetetramine hexaacetic acid, its potassium salt,
Its sodium salt, hydroxyethylethylenediaminetriacetic acid, its potassium salt, its sodium salt; nitrilotriacetic acid, its sodium salt; 1-hydroxyethane-1,1-diphosphonic acid, its potassium salt, its sodium salt; aminotri (methylenephosphonic acid) ), Potassium salts and sodium salts thereof, and the like, and organic phosphonic acids or phosphonoalkanetricarboxylic acids. Instead of the sodium or potassium salt of the chelating agent, a salt of an organic amine is also effective. These chelating agents are selected from those which are stably present in the fountain solution composition at the time of use and do not inhibit printability. The content of the chelate compound in the fountain solution composition at the time of use is suitably 0.001 to 0.3% by mass, and preferably 0.01 to 0.3% by mass.
~ 0.1% by mass.

As the (e) colorant used in the fountain solution composition of the present invention, food coloring agents and the like can be preferably used. For example, as a yellow pigment, CI No. 19140, 1598
5, red pigments are CI No. 16185, 4543
0, 16255, 45380, 45100, CI No. 42640 as a purple pigment, and CI No. 42 as a blue pigment.
42090, 73015, CI No. 4 as a green pigment
2095, and the like. As the rust preventive (e) used in the fountain solution composition of the present invention, for example, benzotriazole, 5-methylbenzotriazole, thiosalicylic acid,
Benzimidazole and its derivatives are exemplified. As the (e) antifoaming agent used in the fountain solution composition of the present invention, a silicone antifoaming agent is preferable, and among them, any of an emulsifying dispersion type and a solubilizing type can be used.

The balance of the fountain solution composition of the present invention is water. A fountain solution composition is generally concentrated and commercialized for commercial use. Therefore, a concentrated humidified water composition can be obtained as an aqueous solution in which the above-mentioned various components are dissolved using water, preferably demineralized water, that is, pure water. When such a concentrated solution is used, it is usually diluted about 10 to 200 times with tap water, well water or the like at the time of use to obtain a fountain solution composition at the time of use.

[0027]

The fountain solution composition for a lithographic printing plate of the present invention comprises:
Prevents the accumulation of divalent metal ions adhering to the chromium roller and rubber roller used in the fountain solution supply system of the continuous water supply system, and stably forms a uniform film of the fountain solution on the lithographic printing plate. Can be supplied to Also, in the work environment,
Comfortable and safe. Even under the condition of a member having a low dynamic surface tension and rotating at a high speed, good and stable printability is exhibited, and a printed matter excellent in stability can be obtained. In particular,
It is possible to improve the printability when using a metal pigment ink which has been conventionally difficult to print with dampening water. Because it can be used stably for a long period of time, it leads to an improvement in productivity.

[0028]

Next, the present invention will be described more specifically with reference to examples. Here,% indicates mass% unless otherwise specified.

Examples 1 to 10 Various compositions were prepared according to the compositions shown in Tables 1 and 2. Examples 1 to 5 are fountain solution compositions, and Examples 6 to 10 are additive liquid compositions. The unit is gram,
Water was added to a final volume of 1000 ml. All are concentrated types and are diluted when used.

[0029]

[Table 1]

[0030]

[Table 2]

The compositions of Examples 1 to 5 prepared as described above were diluted 40 times with simulated hard water having a hardness of 400 ppm, and NaOH / pH was adjusted to about 4.8 to 5.3. The composition was adjusted with phosphoric acid (85%) and subjected to a printing test as a fountain solution composition actually used. Further, the compositions of Examples 6 to 10 were diluted 50-fold, and 0.5% of a dampening solution (etch solution) 1F-202 of Fuji Photo Film Co., Ltd. was added, and the dampening solution composition actually used was used. Was subjected to a print test. The following printing test was carried out using a diamond water supply system of Mitsubishi Printing Machine Co., Ltd., using Toyo Ink Co., Ltd. name Hi-Echo cyan ink and VPS manufactured by Fuji Photo Film Co., Ltd. as a plate used under standard conditions. Was carried out. The results are shown in Table 3 below.

(A) Suitability for Continuous Printing and Stability of Water Supply Roller Printing was carried out on 10,000 sheets per day for 7 consecutive days. Suitability for continuous printing: The amount of change based on the scale of the water supply amount of the printing press at the start (scale 1 to 100, which is also a measure of the number of rotations of the water supply roller) was observed. ○ ‥‥ Change within 15 scales △ ‥‥ Change of 15-20 scales × ‥‥ Change of scales of 20 or more Water supply roller stability ‥‥ Day 1 (after printing 10,000 sheets), Day 3 ( After printing 30,000 sheets), the fifth day (after printing 50,000 sheets), and 7 days
On the day (after printing 70,000 sheets), dirt on the water supply roller (whether or not a water film can be uniformly and cleanly formed on the roller) was observed. ○ ‥‥ Almost no dirt △ ‥‥ Some dirt can be seen × ‥‥ Dirt

(B) Bleeding property After printing 5,000 sheets and 10,000 sheets, the operation of the printing press was stopped, and the extent to which the ink in the image area had spread to the non-image area was examined. ○ ‥‥ Almost no bleeding △ ‥‥ Slight bleeding × ‥‥ Many bleeding (c) Metal pigment ink, UV ink printing stability Ink used: Megami Ink Co., Ltd. Gold ink (blue mouth),
Best cure red (UV ink) Toka Dye Co., Ltd. ○ ‥‥ Good for printing 5000 sheets △ ‥‥ Ink stain on blanket (washing the plate once) × ‥‥ Ink stain around 1000 sheets (on the way, plate and blanket) (Wash twice)

(D) Odor Using an ultrasonic nebulizer in a room at 30 ° C./60% RH.
The odor after one minute was judged by a sensory test. ○ ‥‥ Good odor △ ‥‥ Slightly unpleasant odor × ‥‥ Unpleasant odor

(E) Change in composition during printing 20 000 prints were made with a 20 liter dampening solution composition, and the dampening solution at the start and the liquid after printing 20 000 prints were analyzed by gas chromatography. The composition change was examined. ○ ‥‥ Change in the range of 1-3% △ ‥‥ Change in the range of 3-7% × ‥‥ Change of 7% or more

[0036]

[Table 3]

The fountain solution composition according to the present invention was excellent in all test items, a good printed matter was obtained, and the suitability for fountain solution was also excellent.

Claims (1)

[Claims] 1. At least one represented by the following general formula (I)
One kind of compound and the following general formula (II), (III) or (IV)
At least one selected from the group consisting of compounds represented by
For lithographic printing plates, characterized by containing various compounds
Water composition. R¹O-(-CH_TwoCH (CH_Three) -O-)_m—H (I) (in the formula (I), R¹Represents an alkyl group having 1 to 8 carbon atoms.
And m represents an integer of 1 to 3. ) R^TwoO-(-CH_TwoCH_Two-O-)_n-H (II) R^ThreeOH (III) CH_Three-C (R^Four) (OCH_Three) -CH_TwoCH_TwoOH (IV) (in the formula (II), R^TwoRepresents an alkyl group having 1 to 4 carbon atoms
And n represents 1-4, and in formula (III), R^ThreeIs a carbon source
Represents an alkyl group having 2 to 4 children, and in the formula (IV), R ^FourIs water
Represents an elementary atom or a methyl group. )