JP2001112421A - Water-soluble coating composition for food - Google Patents
Water-soluble coating composition for foodInfo
- Publication number
- JP2001112421A JP2001112421A JP29618399A JP29618399A JP2001112421A JP 2001112421 A JP2001112421 A JP 2001112421A JP 29618399 A JP29618399 A JP 29618399A JP 29618399 A JP29618399 A JP 29618399A JP 2001112421 A JP2001112421 A JP 2001112421A
- Authority
- JP
- Japan
- Prior art keywords
- coating
- water
- fatty acid
- parts
- sucrose fatty
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Grain Derivatives (AREA)
- General Preparation And Processing Of Foods (AREA)
- Jellies, Jams, And Syrups (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、錠剤、 顆粒剤、カ
プセル剤、種子等の食品を被覆する際に良好な成膜性を
持ち、かつ作業性の良好な食品用水溶性コーティング組
成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water-soluble coating composition for foods having good film-forming properties and good workability when coating foods such as tablets, granules, capsules and seeds.
【０００２】[0002]
【従来の技術】いわゆる健康食品、機能性食品等と称さ
れる食品は、通常の食品とは異なり、摂取量の管理、 流
通、保管の便宜のため錠剤、顆粒、カプセル等の形状に
成形することが多い。そして、これら食品は該有用成分
の安定状態下での保存、異味、異臭の隠蔽、摂取時の取
り扱いの容易化等の目的で被覆を施すことが多い。2. Description of the Related Art Foods called so-called health foods and functional foods are different from ordinary foods, and are formed into tablets, granules, capsules, etc. for convenience of intake control, distribution and storage. Often. These foods are often coated for the purpose of preserving the useful components in a stable state, hiding off-flavors and off-flavors, facilitating handling at the time of ingestion, and the like.
【０００３】食品に対して被覆を施そうとする場合に、
天然ガムやカンテン、多糖類等の水溶性高分子物質やシ
ェラック、ゼイン等の非水溶性高分子物質を用いること
は公知であるが、この場合コーティング層のひび割れ、
脆化を防ぐ為、可塑剤の添加は不可欠であり、グリセリ
ン、ひまし油等が適当な可塑剤として従来より用いられ
てきた。[0003] When trying to coat food,
It is known to use water-soluble polymer substances such as natural gums and agar, polysaccharides and water-insoluble polymer substances such as shellac and zein, but in this case, cracks in the coating layer,
In order to prevent embrittlement, the addition of a plasticizer is indispensable, and glycerin, castor oil and the like have been conventionally used as a suitable plasticizer.
【０００４】非水溶性高分子、例えばシェラック、ゼイ
ン等を用いて被覆を施す際には、多量の有機溶媒を必要
とし、作業者の安全性面、環境衛生面を考慮すると好ま
しくないものであり、また水溶性高分子物質、例えば天
然ガム類やカンテン、プルラン、ゼラチン等によるコー
ティングに於いても粘着性の高さからスプレー速度を低
く設定せざるを得ずコーティング作業性の低いこと、可
塑剤添加の影響による透湿度の増加、更には基剤の着
色、保存安定性の低下等、好ましくない問題がある。When coating with a water-insoluble polymer, for example, shellac, zein or the like, a large amount of organic solvent is required, which is not preferable in consideration of the safety of workers and environmental health. Also, in the case of coating with a water-soluble polymer substance such as natural gums, agar, pullulan, gelatin, etc., the spray speed must be set low due to the high adhesiveness, and the coating workability is low, and the plasticizer is used. There are undesired problems such as an increase in moisture permeability due to the effect of the addition, a coloring of the base, and a decrease in storage stability.
【０００５】大豆由来のヘミセルロースを用いたコーテ
ィング剤は、特開平９- ７０２８５号公報等で提案され
ているが、そこに例示されているグリセリンを可塑剤と
して用いる場合には、コーティング操作中の皮膜のベタ
つきの発生とそれに由来するコーティング物同士の付
着、皮膜の剥離、又はコーティング物の吸湿性の増大、
更にはコーティング物の変色、被コーティング物の品質
の低下等が危惧されるものである。[0005] A coating agent using soybean-derived hemicellulose has been proposed in Japanese Patent Application Laid-Open No. 9-70285 and the like. In the case where glycerin exemplified therein is used as a plasticizer, a coating agent during coating operation is required. The occurrence of stickiness and the adhesion between coatings resulting therefrom, peeling of the film, or increasing the hygroscopicity of the coating,
Further, discoloration of the coated object, deterioration of the quality of the coated object, and the like are feared.
【０００６】[0006]
【発明が解決しようとする課題】本発明は、前記問題点
を改善する為に、良好な成膜性を持ちかつ作業性の良好
な食品用のコーティング組成物と、これを用いたコーテ
ィング物を提供することをその課題とする。SUMMARY OF THE INVENTION In order to solve the above problems, the present invention relates to a food coating composition having good film-forming properties and good workability, and a coating composition using the same. The task is to provide.
【０００７】[0007]
【課題を解決するための手段】本発明者らは前記課題を
解決する為に鋭意検討を重ねた結果、ショ糖脂肪酸エス
テル単独、又はショ糖脂肪酸エステルとソルビトール及
びマルト・デキストリンのうちの少なくとも１種との混
合物を用いることにより、従来使用されていたグリセリ
ン等の可塑剤を使用した場合の問題点を改善できること
を見出し、本発明に到達した。Means for Solving the Problems As a result of intensive studies to solve the above problems, the present inventors have found that sucrose fatty acid ester alone or sucrose fatty acid ester and at least one of sorbitol and maltodextrin. The present inventors have found that by using a mixture with a seed, it is possible to improve the problems in the case of using a plasticizer such as glycerin which has been conventionally used, and arrived at the present invention.
【０００８】本発明は、以下の各発明を包含する。 (1) 大豆由来のヘミセルロースに、ショ糖脂肪酸エステ
ル単独、又はショ糖脂肪酸エステルとソルビトール及び
マルト・デキストリンより選ばれる少なくとも１種との
混合物を添加してなる食品用水溶性コーティング用組成
物。 (2) ショ糖脂肪酸エステルは、そのＨＬＢ値（Hydrophi
lic-Lypophilic Balance）が７以上である(1) 記載の食
品用水溶性コーティング用組成物。The present invention includes the following inventions. (1) A water-soluble coating composition for food, which is obtained by adding sucrose fatty acid ester alone or a mixture of sucrose fatty acid ester and at least one selected from sorbitol and maltodextrin to soybean-derived hemicellulose. (2) The sucrose fatty acid ester has an HLB value (Hydrophi
(1) The water-soluble coating composition for food according to (1), wherein the composition has a lic-Lypophilic Balance of 7 or more.
【０００９】[0009]
【発明の実施の形態】本発明に用いられるコーティング
剤は、大豆中にセルロース等と結合して存在する多糖類
からなる水不溶性の植物繊維を弱酸性下に加水分解し、
水溶性となった生成物を分離して得られる水溶性ヘミセ
ルロースにショ糖脂肪酸エステル加えたものを使用する
ことを特徴とするものである。BEST MODE FOR CARRYING OUT THE INVENTION The coating agent used in the present invention hydrolyzes water-insoluble plant fibers composed of polysaccharides present in soybean in combination with cellulose and the like under weak acidity,
It is characterized by using a product obtained by adding a sucrose fatty acid ester to water-soluble hemicellulose obtained by separating a water-soluble product.
【００１０】本発明のコーティング用組成物において
は、ショ糖脂肪酸エステルの添加は必須である。また、
本発明のコーティング用組成物の機能をより向上させる
目的で、さらにソルビトール又はマルトデキストリンを
添加する。ショ糖脂肪酸エステルを添加することは、皮
膜の防湿性を高める事に有効であり、ソルビトールの添
加は皮膜に塑性能を保持させる事に有効である。ソルビ
トールは従来より可塑剤としての用途で使用されてい
る。[0010] In the coating composition of the present invention, the addition of a sucrose fatty acid ester is essential. Also,
For the purpose of further improving the function of the coating composition of the present invention, sorbitol or maltodextrin is further added. The addition of a sucrose fatty acid ester is effective in increasing the moisture resistance of the film, and the addition of sorbitol is effective in maintaining the plastic performance of the film. Sorbitol has been conventionally used for plasticizer applications.
【００１１】ショ糖脂肪酸エステルとしては、ラウリン
酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレ
イン酸、リノール酸などの高級脂肪酸エステル及びそれ
らの混合物、牛脂、ラノリン、ヤシ油、ヒマシ油、サン
フラワー油及びそれらの硬化油などの混合脂肪酸のエス
テル等が挙げられ、それらのうちモノエステル含量が８
０％以下のものが好ましく、より好ましくは４０〜８０
％のものであり、最も好ましくは５０〜７５％のもので
ある。Examples of the sucrose fatty acid esters include higher fatty acid esters such as lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid and linoleic acid, and mixtures thereof, tallow, lanolin, coconut oil, castor oil and sunflower oil. And esters of mixed fatty acids such as hardened oil thereof, among which the monoester content is 8%.
It is preferably 0% or less, more preferably 40 to 80%.
%, Most preferably 50-75%.
【００１２】また、ショ糖脂肪酸エステルは、そのＨＬ
Ｂが７以上のものが好ましく、特に好ましくはＨＬＢ１
１〜１６のものである。具体的には、例えば三菱化学
（株）製のリョートーシュガーエステルS-1170（モノエ
ステル含量５５％、ＨＬＢ１１）、S-1670（モノエステ
ル含量７５％、ＨＬＢ16）、P-1570（モノエステル含量
７０％、ＨＬＢ１５）等が挙げられるが、これらに限定
されるものではない。ショ糖脂肪酸エステルの使用量は
前記コーティング用組成物の全固形分中の１〜２０重量
％が適当であり、特に好ましくは３〜１２重量％であ
る。Further, sucrose fatty acid esters have their HL
B is preferably 7 or more, particularly preferably HLB1
1 to 16. Specifically, for example, Ryoto Sugar Ester S-1170 (monoester content 55%, HLB11), S-1670 (monoester content 75%, HLB16), P-1570 (monoester content) manufactured by Mitsubishi Chemical Corporation 70%, HLB15) and the like, but are not limited thereto. The amount of the sucrose fatty acid ester to be used is suitably from 1 to 20% by weight, particularly preferably from 3 to 12% by weight, based on the total solid content of the coating composition.
【００１３】本発明のコーティング用組成物において
は、ショ糖脂肪酸エステルに加えて、ソルビトール又は
マルトデキストリンもしくはこれらの混合物を加えても
よく、これらの使用量は前記コーティング剤の全固形分
中１〜３０重量％が適当であり、特に好ましくは１０〜
２５重量％である。In the coating composition of the present invention, sorbitol or maltodextrin or a mixture thereof may be added in addition to the sucrose fatty acid ester, and the amount of these used is 1 to 3 in the total solid content of the coating agent. 30% by weight is suitable, and particularly preferably 10 to 10% by weight.
25% by weight.
【００１４】マルトデキストリンは、デンプンを希酸又
はアミラーゼで分解して生じる低分子デキストリンであ
り、Ｄ−グルコースの重合度（以下、ＤＥレンジという
こともある）の異なる種々の商品が存在するが、使用で
きるマルトデキストリンの重合度は特に制限されるもの
ではない。Maltodextrin is a low-molecular-weight dextrin produced by decomposing starch with a dilute acid or amylase. There are various products having different degrees of polymerization of D-glucose (hereinafter sometimes referred to as DE range). The degree of polymerization of maltodextrin that can be used is not particularly limited.
【００１５】本組成物の調製方法としては、精製水にシ
ョ糖脂肪酸エステル単独、又はショ糖脂肪酸エステルと
ソルビトール及びマルトデキストリンの一方又は双方と
の混合物を溶解又は分散し、これに大豆由来のヘミセル
ロースを溶解させる方法、或いは添加する該ヘミセルロ
ースを予めエタノールに分散させたものを混合溶解させ
る方法等が挙げられる。しかし、ヘミセルロース、ショ
糖脂肪酸エステル、ソルビトール、マルトデキストリ
ン、水及び必要に応じてエタノールを組成物中に所定の
割合で均一に含まれるように調整することができる方法
である限り、上記方法以外の調製方法も採用することが
できる。The composition is prepared by dissolving or dispersing sucrose fatty acid ester alone or a mixture of sucrose fatty acid ester and one or both of sorbitol and maltodextrin in purified water, and adding soybean-derived hemicellulose thereto. Or a method in which the hemicellulose to be added is dispersed in ethanol in advance and mixed and dissolved. However, as long as the method can be adjusted so that hemicellulose, sucrose fatty acid ester, sorbitol, maltodextrin, water and, if necessary, ethanol are uniformly contained in the composition at a predetermined ratio, a method other than the above method is used. Preparation methods can also be employed.
【００１６】本発明の組成物には、必要に応じて着色
料、香料、顔料等の助剤を本発明の目的に影響を与えな
い程度に添加することもできる。本発明の組成物を被コ
ーティング物にコーティングする方法としては、従来公
知のコーティング装置、例えばパンコーティング装置、
流動層造粒コーティング装置、遠心流動型造粒コーティ
ング装置、複合型造粒コーティング装置、ドラムタイプ
コーティング装置等を用いて該組成物を被コーティング
物上にスプレーコーティングする方法が採用できる。Auxiliary agents such as coloring agents, fragrances and pigments can be added to the composition of the present invention, if necessary, to such an extent that the purpose of the present invention is not affected. As a method of coating the composition to be coated with the composition of the present invention, a conventionally known coating apparatus, for example, a pan coating apparatus,
A method in which the composition is spray-coated on an object to be coated using a fluidized bed granulation coating apparatus, a centrifugal fluidized granulation coating apparatus, a composite granulation coating apparatus, a drum type coating apparatus, or the like can be employed.
【００１７】[0017]
【実施例】以下、実施例によって本発明を詳細に説明す
るが、本発明はこれらの実施例に限定されるものではな
い。EXAMPLES Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited to these examples.
【００１８】 実施例１ （コーティング液組成） 水溶性ヘミセルロース〔商品名「ヘミロース」不二製油（株）製〕 ９．０部 ショ糖脂肪酸エステル〔商品名「リョートーシュガーエステルＳ−１１７０」 三菱化学（株）製〕 １．０部 マルトデキストリン〔「ＭＡＬＴＲＩＮ」Grain Processing Corp.製〕 １．０部 エタノール １０．０部 精製水 ７９．０部Example 1 (Composition of coating liquid) Water-soluble hemicellulose (trade name “Hemirose” manufactured by Fuji Oil Co., Ltd.) 9.0 parts Sucrose fatty acid ester [trade name “Ryoto Sugar Ester S-1170” Mitsubishi Chemical Corporation 1.0 part Maltodextrin [“MALTRIN” manufactured by Grain Processing Corp.] 1.0 part Ethanol 10.0 parts Purified water 79.0 parts
【００１９】（コーティング方法）通気式パンコーティ
ング装置〔フロイント産業（株）製、（モデルＨＣ−ｍ
ｉｎｉ）〕を使用し、乳糖及び結晶性セルロース〔商品
名「アビセルＦＤ−１０１」旭化成工業（株）製〕より
なる三角錠1000ｇに上記組成のコーティング液195ｇを
スプレーコーティングした。コーティング操作中、錠剤
同士の付着、コーティング膜の剥離も見られず平滑な被
覆表面を有する錠剤が得られた。またコーティング錠の
摩損試験を行った結果、皮膜の損傷もなく良好であっ
た。(Coating method) Ventilation type pan coating apparatus [Freund Sangyo Co., Ltd., Model HC-m
ini)], 1000 g of a triangular tablet made of lactose and crystalline cellulose [trade name “Avicel FD-101” manufactured by Asahi Kasei Kogyo Co., Ltd.] was spray-coated with 195 g of a coating solution having the above composition. During the coating operation, there was no adhesion between tablets and no peeling of the coating film was observed, and tablets having a smooth coated surface were obtained. In addition, as a result of performing an abrasion test on the coated tablet, the coating tablet was good without any damage to the film.
【００２０】 実施例２ （コーティング液組成） 水溶性ヘミセルロース〔商品名「ヘミロース」不二製油（株）製〕 ９．０部 ショ糖脂肪酸エステル〔商品名「リョートーシュガーエステルＳ−１１７０」 三菱化学（株）製〕 ０．５部 エタノール １０．０部 精製水 ８０．５部Example 2 (Coating liquid composition) Water-soluble hemicellulose (trade name “Hemirose” manufactured by Fuji Oil Co., Ltd.) 9.0 parts Sucrose fatty acid ester [trade name “Ryoto Sugar Ester S-1170” Mitsubishi Chemical Corporation Ltd.] 0.5 parts Ethanol 10.0 parts Purified water 80.5 parts
【００２１】（コーティング方法）実施例１と同様のコ
ーティング装置により、乳糖及び結晶セルロース（「ア
ビセルＦＤ−１０１」）よりなる三角錠1000ｇに上記コ
ーティング液195 ｇをスプレーコーティングした。コー
ティング操作中、錠剤同士の付着、コーティング膜の剥
離も見られず平滑な被覆表面を有する錠剤が得られた。
またコーティング錠の摩損試験を行った結果、皮膜の損
傷もなく良好であった。(Coating method) Using a coating apparatus similar to that in Example 1, 195 g of the above coating solution was spray-coated on 1000 g of a triangular tablet made of lactose and crystalline cellulose (Avicel FD-101). During the coating operation, there was no adhesion between tablets and no peeling of the coating film was observed, and tablets having a smooth coated surface were obtained.
In addition, as a result of performing an abrasion test on the coated tablet, the coating tablet was good without any damage to the film.
【００２２】 実施例３ （コーティング液組成） 水溶性ヘミセルロース〔商品名「ヘミロース」不二製油（株）製〕 ９．０部 ショ糖脂肪酸エステル〔商品名「リョートーシュガーエステルＳ−１１７０」 三菱化学（株）製〕 ０．５部 マルトデキストリン〔「ＭＡＬＴＲＩＮ」Grain Processing Corp.製〕 ０．５部 エタノール １０．０部 精製水 ８０．０部Example 3 (Composition of coating liquid) Water-soluble hemicellulose (trade name “Hemirose” manufactured by Fuji Oil Co., Ltd.) 9.0 parts Sucrose fatty acid ester [trade name “Ryoto Sugar Ester S-1170” Mitsubishi Chemical Corporation 0.5 parts maltodextrin [“MALTRIN” Grain Processing Corp.] 0.5 parts ethanol 10.0 parts purified water 80.0 parts
【００２３】（コーティング方法）実施例１と同様のコ
ーティング装置により、乳糖及び結晶セルロース「アビ
セルＦＤ−１０１」よりなる三角錠1500ｇに上記コーテ
ィング液500 ｇをスプレーコーティングした。コーティ
ング操作中、錠剤同士の付着、コーティング膜の剥離も
見られず平滑な被覆表面を有する錠剤が得られた。また
コーティング錠の摩損試験を行った結果、皮膜の損傷も
なく良好であった。(Coating Method) Using the same coating apparatus as in Example 1, 1500 g of a triangular tablet comprising lactose and crystalline cellulose "Avicel FD-101" was spray-coated with 500 g of the above coating solution. During the coating operation, there was no adhesion between tablets and no peeling of the coating film was observed, and tablets having a smooth coated surface were obtained. In addition, as a result of performing an abrasion test on the coated tablet, the coating tablet was good without any damage to the film.
【００２４】 実施例４ （コーティング液組成） 水溶性ヘミセルロース〔商品名「ヘミロース」不二製油（株）製〕 ９．０部 ショ糖脂肪酸エステル〔商品名「リョートーシュガーエステルＳ−１１７０」 三菱化学（株）製〕 ０．５部 ソルビトール ０．５部 マルトデキストリン〔「ＭＡＬＴＲＩＮ」Grain Processing Corp.製〕 ０．５部 エタノール １０．０部 精製水 ７９．５部Example 4 (Composition of coating liquid) Water-soluble hemicellulose (trade name “Hemirose” manufactured by Fuji Oil Co., Ltd.) 9.0 parts Sucrose fatty acid ester [trade name “Ryoto Sugar Ester S-1170” Mitsubishi Chemical Corporation 0.5 part Sorbitol 0.5 part Maltodextrin [manufactured by “MALTRIN” Grain Processing Corp.] 0.5 part Ethanol 10.0 parts Purified water 79.5 parts
【００２５】（コーティング方法）実施例１と同様のコ
ーティング装置により、乳糖及び結晶セルロース「アビ
セルＦＤ−１０１」よりなる三角錠1000ｇに上記コーテ
ィング液600 ｇをスプレーコーティングした。コーティ
ング操作中、錠剤同士の付着、コーティング膜の剥離も
見られず平滑な被覆表面を有する錠剤が得られた。また
コーティング錠の摩損試験を行った結果、皮膜の損傷も
なく良好であった。(Coating method) Using a coating apparatus similar to that of Example 1, 1000 g of a triangular tablet comprising lactose and crystalline cellulose "Avicel FD-101" was spray-coated with 600 g of the above coating solution. During the coating operation, there was no adhesion between tablets and no peeling of the coating film was observed, and tablets having a smooth coated surface were obtained. In addition, as a result of performing an abrasion test on the coated tablet, the coating tablet was good without any damage to the film.
【００２６】 実施例５ （コーティング液組成） 水溶性ヘミセルロース〔商品名「ヘミロース」不二製油（株）製〕 ９．０部 ショ糖脂肪酸エステル〔商品名「リョートーシュガーエステルＳ−１１７０」 三菱化学（株）製〕 ０．５部 マルトデキストリン〔「ＭＡＬＴＲＩＮ」Grain Processing Corp.製〕 ０．５部 エタノール １０．０部 精製水 ８０．０部 青色色素 微量Example 5 (Composition of coating liquid) Water-soluble hemicellulose [trade name "Hemirose" manufactured by Fuji Oil Co., Ltd.] 9.0 parts Sucrose fatty acid ester [trade name "Ryoto Sugar Ester S-1170" Mitsubishi Chemical Corporation 0.5 parts Maltodextrin [manufactured by “MALTRIN” Grain Processing Corp.] 0.5 parts Ethanol 10.0 parts Purified water 80.0 parts Blue dye trace
【００２７】（コーティング方法）複合型造粒コーティ
ング装置である「スパイラー」〔（モデル ＳＦＣ−ｍ
ｉｎｉ）フロイント産業（株）製〕実施例１と同様のコ
ーティング装置を使用し、白糖及びデンプンよりなる球
形顆粒1000ｇに上記コーティング液を1000ｇスプレーコ
ーティングした。コーティング操作中、顆粒同士の付
着、団粒の発生も見られず平滑かつ均一な被覆表面の顆
粒が得られた。(Coating method) "Spilar" [(Model SFC-m)
ini) (manufactured by Freund Corporation) Using the same coating apparatus as in Example 1, 1000 g of the spherical granules composed of sucrose and starch were spray-coated with 1000 g of the above coating solution. During the coating operation, no adhesion of granules or generation of aggregates was observed, and granules having a smooth and uniform coated surface were obtained.
【００２８】 実施例６ （コーティング液組成） 水溶性ヘミセルロース〔商品名「ヘミロース」不二製油（株）製〕 ５．０部 ショ糖脂肪酸エステル〔商品名「リョートーシュガーエステルＳ−１１７０」 三菱化学（株）製〕 ０．５部 マルトデキストリン〔「ＭＡＬＴＲＩＮ」Grain Processing Corp.製〕 ０．５部 エタノール ５．０部 精製水 ８９．０部 青色色素 微量Example 6 (Composition of coating liquid) Water-soluble hemicellulose [trade name "Hemirose" manufactured by Fuji Oil Co., Ltd.] 5.0 parts Sucrose fatty acid ester [trade name "Ryoto Sugar Ester S-1170" Mitsubishi Chemical Corporation 0.5 part Maltodextrin [manufactured by “MALTRIN” Grain Processing Corp.] 0.5 part Ethanol 5.0 parts Purified water 89.0 parts Blue pigment trace
【００２９】（コーティング方法）実施例５と同様のコ
ーティング装置により、乳糖・デンプン混合造粒物１ｋ
ｇに対し、上記コーティング液600gをスプレーコーティ
ングした。コーティング操作中再造粒、団粒の発生等無
くコーティング物を得ることができた。(Coating method) Using the same coating apparatus as in Example 5, lactose / starch mixed granules 1 k
Then, 600 g of the above-mentioned coating solution was spray-coated on g. A coating product could be obtained without any re-granulation or aggregation during the coating operation.
【００３０】 比較例１ （コーティング液組成） 水溶性ヘミセルロース〔商品名「ヘミロース」不二製油（株）製〕 ９．０部 グリセリン １．０部 エタノール １０．０部 精製水 ８０．０部Comparative Example 1 (Composition of coating liquid) Water-soluble hemicellulose (trade name “Hemirose” manufactured by Fuji Oil Co., Ltd.) 9.0 parts Glycerin 1.0 part Ethanol 10.0 parts Purified water 80.0 parts
【００３１】（コーティング）実施例１と同様のコーテ
ィング装置を使用し、乳糖及び結晶セルロース〔「アビ
セルＦＤ−１０１」旭化成工業（株）製〕よりなる三角
錠350 ｇに上記コーティング液をスプレーコーティング
した。コーティング操作中錠剤表面がベタつき、皮膜の
剥離が確認された。スプレー速度を下げて粘着性が出な
いようにしてコーティング操作を行ったところ、平滑な
被覆表面の錠剤が得られたがベタついた感触のコーティ
ング物であった。またコーティング錠の摩損試験を行っ
た結果、皮膜の損傷もなく良好であった。(Coating) Using the same coating apparatus as in Example 1, 350 g of a triangular tablet made of lactose and crystalline cellulose ("Avicel FD-101" manufactured by Asahi Kasei Corporation) was spray-coated with the above coating solution. . During the coating operation, the tablet surface was sticky, and peeling of the film was confirmed. When the coating operation was carried out by lowering the spraying speed so as not to cause stickiness, tablets having a smooth coated surface were obtained, but the coating was sticky to the touch. In addition, as a result of performing an abrasion test on the coated tablet, the coating tablet was good without any damage to the film.
【００３２】 比較例２ （コーティング液組成） 水溶性ヘミセルロース〔商品名「ヘミロース」不二製油（株）製〕 ９．０部 ソルビトール １．０部 マルトデキストリン〔「ＭＡＬＴＲＩＮ」Grain Processing Corp.製〕 １．０部 エタノール １０．０部 精製水 ７９．０部Comparative Example 2 (Composition of coating liquid) Water-soluble hemicellulose (trade name “Hemirose” manufactured by Fuji Oil Co., Ltd.) 9.0 parts Sorbitol 1.0 part Maltodextrin [“MALTRIN” manufactured by Grain Processing Corp.] 1 0.0 parts Ethanol 10.0 parts Purified water 79.0 parts
【００３３】（コーティング）実施例１と同様のコーテ
ィング装置により、乳糖及び結晶セルロース〔「アビセ
ル−１０１」旭化成（株）製〕よりなる三角錠1000g に
上記コーティング液600 ｇをスプレーコーティングし
た。コーティング操作中、目立った錠剤同士の付着等は
確認されなかったが、得られた錠剤は表面の荒れた状態
であった。スプレー速度を下げて表面荒れが発生しない
様にコーティング操作を行ったところ、平滑な被覆表面
の錠剤が得られた。またコーティング錠の摩損試験を行
った結果、被服の損傷もなく良好であった。(Coating) Using a coating apparatus similar to that used in Example 1, 1000 g of a triangular tablet made of lactose and crystalline cellulose (“Avicel-101” manufactured by Asahi Kasei Corporation) was spray-coated with 600 g of the above coating solution. During the coating operation, no noticeable adhesion of the tablets was observed, but the obtained tablets had a rough surface. When the coating operation was performed by lowering the spray speed so as not to cause surface roughness, tablets having a smooth coated surface were obtained. In addition, as a result of an abrasion test of the coated tablet, the coating was good without any damage to the clothing.
【００３４】 比較例３ （コーティング液組成） 水溶性ヘミセルロース〔商品名「ヘミロース」不二製油（株）製〕 ５．０部 グリセリン ０．５部 エタノール ５．０部 精製水 ８９．５部Comparative Example 3 (Coating liquid composition) Water-soluble hemicellulose [trade name “Hemirose” manufactured by Fuji Oil Co., Ltd.] 5.0 parts Glycerin 0.5 parts Ethanol 5.0 parts Purified water 89.5 parts
【００３５】（コーティング方法）実施例５と同様のコ
ーティング装置により、白糖及びデンプンよりなる球形
顆粒1000g に上記コーティング液を実施例５と同一条件
でスプレーコーティングした。コーティング作業中顆粒
同士の付着が顕著であった。(Coating Method) Using the same coating apparatus as in Example 5, 1000 g of spherical granules composed of sucrose and starch were spray-coated with the coating solution under the same conditions as in Example 5. Adhesion between the granules was remarkable during the coating operation.
【００３６】実施例７ （保存安定性試験）実施例１〜６及び比較例１〜３のコ
ーティング物をガラス瓶に入れ、蓋をしない状態で４０
℃、相対湿度７５％の恒温恒湿器中に１ヶ月間保存し
た。保存後の外観変化の判定は目視により確認を行っ
た。結果を表１に示す。Example 7 (Storage stability test) The coatings of Examples 1 to 6 and Comparative Examples 1 to 3 were put in a glass bottle and placed in a state without a lid.
The sample was stored in a thermo-hygrostat at 75 ° C. and a relative humidity of 75% for one month. The change in appearance after storage was visually confirmed. Table 1 shows the results.
【００３７】[0037]
【表１】 [Table 1]
【００３８】[0038]
【発明の効果】以上の実施例及び比較例より明らかなよ
うに、本発明の組成物を用いることにより、従来用いら
れている食品用水溶性コーティング組成物の問題点が解
消され、従来用いられている可塑剤を用いなくても成膜
性、強度共に良好なコーティング物が得ることができ
る。またコーティング操作中の錠剤或いは顆粒同士の付
着、コーティング皮膜の剥離等の障害も回避することが
でき、成膜性、作業性、皮膜性能の何れも十分満足する
物性を有した皮膜を得ることができる。As is clear from the above Examples and Comparative Examples, the use of the composition of the present invention solves the problems of the conventionally used water-soluble coating compositions for foods, and A coating having good film formability and strength can be obtained without using a plasticizer. Further, it is possible to avoid obstacles such as adhesion of tablets or granules during the coating operation and peeling of the coating film, and to obtain a film having physical properties that are sufficiently satisfactory in all of film forming property, workability, and film performance. it can.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 前田 裕一 大阪府泉佐野市住吉町１番地 不二製油株 式会社阪南事業所内 Ｆターム(参考） 4B035 LE01 LE07 LG18 LG19 LG21 LG26 LK14 LP26 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Yuichi Maeda 1 Sumiyoshicho, Izumisano-shi, Osaka Fuji Oil Co., Ltd. Hannan Works F-term (reference) 4B035 LE01 LE07 LG18 LG19 LG21 LG26 LK14 LP26
Claims (2)
肪酸エステル単独又は、ショ糖脂肪酸エステルとソルビ
トール及びデキストリンより選ばれる少なくとも１種と
の混合物を加えてなる食品用水溶性コーティング用組成
物。1. A water-soluble coating composition for food, comprising sucrose fatty acid ester alone or a mixture of sucrose fatty acid ester and at least one selected from sorbitol and dextrin to soybean-derived hemicellulose.
上である請求項１記載の食品用水溶性コーティング用組
成物。2. The water-soluble coating composition for food according to claim 1, wherein the sucrose fatty acid ester has an HLB value of 7 or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29618399A JP3957932B2 (en) | 1999-10-19 | 1999-10-19 | Water-soluble coating composition for food |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29618399A JP3957932B2 (en) | 1999-10-19 | 1999-10-19 | Water-soluble coating composition for food |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2001112421A true JP2001112421A (en) | 2001-04-24 |
| JP3957932B2 JP3957932B2 (en) | 2007-08-15 |
Family
ID=17830250
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29618399A Expired - Lifetime JP3957932B2 (en) | 1999-10-19 | 1999-10-19 | Water-soluble coating composition for food |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3957932B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003095982A (en) * | 2001-09-27 | 2003-04-03 | Mitsubishi-Kagaku Foods Corp | Improver for feeling on tongue of sorbitol tablet molding |
| WO2006017787A2 (en) * | 2004-08-06 | 2006-02-16 | Grain Processing Corporation | Tablet coating composition |
| JP2013162753A (en) * | 2012-02-09 | 2013-08-22 | Fuji Oil Co Ltd | Loosening improving agent for cereal processed food |
| JP2019526287A (en) * | 2016-09-07 | 2019-09-19 | エイチワイ カンパニー，リミテッド | Method for producing functional coffee containing peanut sprout extract and functional coffee by the production method |
| JP2020002012A (en) * | 2018-06-25 | 2020-01-09 | 日本酢ビ・ポバール株式会社 | Coating composition as well as oral solid preparation and method for producing the same |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101880033B1 (en) * | 2016-08-29 | 2018-07-20 | 충남태안영농조합법인 | Manufacturing method of a bean using an edible bug |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04325058A (en) * | 1991-04-25 | 1992-11-13 | Fuji Oil Co Ltd | Coating agent |
| JPH05287097A (en) * | 1992-04-06 | 1993-11-02 | Daicel Chem Ind Ltd | Surface treatment, coated polymer film and production of the same |
| JPH0779712A (en) * | 1993-09-17 | 1995-03-28 | Sanei Gen F F I Inc | Preparation containing water-soluble hemicellulose |
| JPH07101883A (en) * | 1993-10-01 | 1995-04-18 | Sanei Gen F F I Inc | Preparation containing water-soluble hemicellulose |
| JPH0799929A (en) * | 1993-10-01 | 1995-04-18 | Sanei Gen F F I Inc | Preparation containing water-soluble hemicellulose |
| JPH0970285A (en) * | 1995-09-05 | 1997-03-18 | Freunt Ind Co Ltd | Coating method and coating material obtained thereby |
-
1999
- 1999-10-19 JP JP29618399A patent/JP3957932B2/en not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04325058A (en) * | 1991-04-25 | 1992-11-13 | Fuji Oil Co Ltd | Coating agent |
| JPH05287097A (en) * | 1992-04-06 | 1993-11-02 | Daicel Chem Ind Ltd | Surface treatment, coated polymer film and production of the same |
| JPH0779712A (en) * | 1993-09-17 | 1995-03-28 | Sanei Gen F F I Inc | Preparation containing water-soluble hemicellulose |
| JPH07101883A (en) * | 1993-10-01 | 1995-04-18 | Sanei Gen F F I Inc | Preparation containing water-soluble hemicellulose |
| JPH0799929A (en) * | 1993-10-01 | 1995-04-18 | Sanei Gen F F I Inc | Preparation containing water-soluble hemicellulose |
| JPH0970285A (en) * | 1995-09-05 | 1997-03-18 | Freunt Ind Co Ltd | Coating method and coating material obtained thereby |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003095982A (en) * | 2001-09-27 | 2003-04-03 | Mitsubishi-Kagaku Foods Corp | Improver for feeling on tongue of sorbitol tablet molding |
| WO2006017787A2 (en) * | 2004-08-06 | 2006-02-16 | Grain Processing Corporation | Tablet coating composition |
| WO2006017787A3 (en) * | 2004-08-06 | 2006-05-18 | Grain Processing Corp | Tablet coating composition |
| JP2013162753A (en) * | 2012-02-09 | 2013-08-22 | Fuji Oil Co Ltd | Loosening improving agent for cereal processed food |
| JP2019526287A (en) * | 2016-09-07 | 2019-09-19 | エイチワイ カンパニー，リミテッド | Method for producing functional coffee containing peanut sprout extract and functional coffee by the production method |
| JP2020002012A (en) * | 2018-06-25 | 2020-01-09 | 日本酢ビ・ポバール株式会社 | Coating composition as well as oral solid preparation and method for producing the same |
| CN112261953A (en) * | 2018-06-25 | 2021-01-22 | 日本瓦姆&珀巴尔株式会社 | Coating composition, oral solid preparation and process for producing the same |
| JP7189689B2 (en) | 2018-06-25 | 2022-12-14 | 日本酢ビ・ポバール株式会社 | Coating composition and oral solid dosage form and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3957932B2 (en) | 2007-08-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0523120B2 (en) | Film-forming product intended for coating solid forms | |
| KR101145013B1 (en) | Film-forming starchy composition | |
| EP0133827B1 (en) | Film forming compositions for the coating of solid forms of pharmaceutical or food products and coated products of these compositions so obtained | |
| DE69219303T3 (en) | Film coatings and coating compositions based on cellulosic polymers and lactose | |
| DE60127674T2 (en) | USE OF AN ACETYLATED PRE-GARNISHED STARCH WITH A HIGH AMYLOSE AMOUNT | |
| EP2060189B1 (en) | Adsorbate containing additive | |
| KR20010101907A (en) | Edible coating composition | |
| US20110002986A1 (en) | Stable Shellac Enteric Coating Formulation for Nutraceutical and Pharmaceutical Dosage Forms | |
| CN102421423A (en) | Enhanced moisture barrier immediate release film coating systems and substrates coated therewith | |
| TW200413524A (en) | Decolorized yeast cell wall fraction, or decolorization acid-treated yeast cell wall fraction | |
| JP4027611B2 (en) | Film coating agent | |
| KR102287342B1 (en) | Immediate release film coatings containing medium chain glycerides and substrates coated therewith | |
| JP2001112421A (en) | Water-soluble coating composition for food | |
| WO2012120364A2 (en) | Novel immediate release film coating compositions | |
| CN110777022B (en) | Coated biological enzyme particle and preparation method thereof | |
| EP3860849A1 (en) | Smooth high solids film coating composition comprising water soluble cellulose ether, process for preparing the same | |
| JP3634339B2 (en) | Composition for glazing oily confectionery, glazing method and glazed oily confectionery | |
| JP2003093000A (en) | Enteric coat for food, enteric food and method for producing the same | |
| WO2009024992A2 (en) | Film coating compositions based on tribasic calcium phosphate | |
| CN110973126A (en) | Azoxystrobin emulsion and preparation method thereof | |
| KR20230055872A (en) | Film-coating composition having natural substances | |
| JPS63269970A (en) | Method for carrying out antizymic and moisture-proofing coating of food and chemical | |
| CN105521493A (en) | Film coating premixing auxiliary material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20050614 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20051117 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20060904 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20070116 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20070315 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20070508 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20070509 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 3957932 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100518 Year of fee payment: 3 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110518 Year of fee payment: 4 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110518 Year of fee payment: 4 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120518 Year of fee payment: 5 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130518 Year of fee payment: 6 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140518 Year of fee payment: 7 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313115 |
|
| R360 | Written notification for declining of transfer of rights |
Free format text: JAPANESE INTERMEDIATE CODE: R360 |
|
| R360 | Written notification for declining of transfer of rights |
Free format text: JAPANESE INTERMEDIATE CODE: R360 |
|
| R371 | Transfer withdrawn |
Free format text: JAPANESE INTERMEDIATE CODE: R371 |
|
| S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313115 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| EXPY | Cancellation because of completion of term |