JP2001110458A - Method for inspecting short circuit of battery abd apparatus for inspecting short circuit of battery - Google Patents

Method for inspecting short circuit of battery abd apparatus for inspecting short circuit of battery

Info

Publication number
JP2001110458A
JP2001110458A JP28556299A JP28556299A JP2001110458A JP 2001110458 A JP2001110458 A JP 2001110458A JP 28556299 A JP28556299 A JP 28556299A JP 28556299 A JP28556299 A JP 28556299A JP 2001110458 A JP2001110458 A JP 2001110458A
Authority
JP
Japan
Prior art keywords
battery
electrode plate
short
voltage
short circuit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP28556299A
Other languages
Japanese (ja)
Inventor
Michio Kurematsu
道男 榑松
Muneyoshi Noda
宗良 野田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP28556299A priority Critical patent/JP2001110458A/en
Publication of JP2001110458A publication Critical patent/JP2001110458A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/36Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
    • G01R31/385Arrangements for measuring battery or accumulator variables
    • G01R31/3865Arrangements for measuring battery or accumulator variables related to manufacture, e.g. testing after manufacture
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/50Testing of electric apparatus, lines, cables or components for short-circuits, continuity, leakage current or incorrect line connections
    • G01R31/52Testing for short-circuits, leakage current or ground faults

Abstract

PROBLEM TO BE SOLVED: To decrease errors of judgement in inspection of short circuit in the manufacturing steps of a battery. SOLUTION: Voltage is applied between a positive electrode and a negative electrode of a battery in which liquid has not yet been injected, where the battery comprises groups of electrode plates formed of a positive plate, a negative plate, and a separator. The difference in potential between the positive electrode and the negative electrode is measured, after voltage is stopped to be applied for conducting inspecting of short circuit.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は電池の短絡検査方法
とその装置に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method and an apparatus for detecting a short circuit of a battery.

【0002】[0002]

【従来の技術】電池は正極板と負極板とがセパレータに
より隔離されていることが電池の機能を維持する上で重
要であり、正極板と負極板との短絡を検出する短絡検査
が電池の製造工程において行われている。このような短
絡検査方法として正極板と負極板間の絶縁抵抗を測定
し、抵抗値によって短絡の有無を判定する方法がある。
実際の製造工程においては未注液の電池の端子間に数百
Vから数十kVの比較的高電圧を印加し、その際に流れ
る電流値を測定することによって間接的に絶縁抵抗を測
定する方法が一般的に行われており、この場合にはその
電流値の高低で短絡の有無を判定していた。
2. Description of the Related Art In a battery, it is important to maintain the function of the battery that a positive electrode plate and a negative electrode plate are separated by a separator, and a short-circuit test for detecting a short circuit between the positive electrode plate and the negative electrode plate is performed on the battery. It is performed in the manufacturing process. As such a short-circuit inspection method, there is a method of measuring the insulation resistance between the positive electrode plate and the negative electrode plate and determining the presence or absence of a short-circuit based on the resistance value.
In the actual manufacturing process, a relatively high voltage of several hundreds of volts to several tens of kV is applied between the terminals of an unfilled battery, and the current flowing at that time is measured to measure the insulation resistance indirectly. The method is generally performed, and in this case, the presence or absence of a short circuit is determined based on the level of the current value.

【0003】電池、特に大規模通信バックアップ用途の
数十Ah〜数千Ahの大容量の電池では極板の対向面積
の総和は非常に大きく電池製造時に極板やセパレータが
大気中の水分を吸収しやすい。さらに大きな電池体積も
あいまって特にセルの中心部分まで一旦吸収された水分
は容易に電池外に蒸発しない。このような大気中の水分
を吸収したセルは絶縁抵抗が低下し、前記したような短
絡検査では短絡の無い電池も短絡と誤判定してしまうこ
とがあった。例えば図5は擬似的に短絡させた未注液電
池および短絡の無い未注液電池に300Vの直流電圧を
印加し、その際に流れる電流値と雰囲気湿度との関係を
示した図である。図5のように雰囲気湿度が高くなる程
電流値が増大することがわかる。特に雰囲気湿度が80
RH%程度になると短絡がある電池との電流の差が小さ
くなるためその判定が困難である。また、例として短絡
の有無を判定する電流値を60mAに設定した場合、雰
囲気湿度が70RH%付近を超えて高くなると短絡がな
い電池でも短絡が有ると誤判定してしまうことになる。
このように従来の電池の短絡検査方法では大気中の湿度
の影響を大変受けやすかった。
[0003] In a battery, especially a large-capacity battery of several tens Ah to several thousand Ah used for large-scale communication backup, the sum of the facing areas of the electrode plates is very large, and the electrode plates and the separator absorb the moisture in the air during battery production. It's easy to do. In addition to the large battery volume, the water once absorbed, especially to the center of the cell, does not easily evaporate out of the battery. Such a cell that has absorbed moisture in the air has a low insulation resistance, and a battery without a short circuit may be erroneously determined as a short circuit in the short circuit test as described above. For example, FIG. 5 is a diagram showing the relationship between the current value flowing at that time and the ambient humidity when a DC voltage of 300 V is applied to an uninjected battery that has been pseudo-short-circuited and an uninjected battery that has no short circuit. As can be seen from FIG. 5, the current value increases as the atmospheric humidity increases. Especially the atmospheric humidity is 80
At about RH%, it is difficult to determine the difference between the short-circuited battery and the current, because the difference is small. Further, as an example, when the current value for judging the presence or absence of a short circuit is set to 60 mA, when the ambient humidity becomes higher than around 70 RH%, a battery having no short circuit will be erroneously determined to have a short circuit.
As described above, the conventional battery short-circuit inspection method is very susceptible to the influence of atmospheric humidity.

【0004】[0004]

【発明が解決しようとする課題】本発明は前記したよう
な大気中の湿度の影響を抑制した精度の良い電池の短絡
検査方法とその装置を得ることを目的とする。
SUMMARY OF THE INVENTION It is an object of the present invention to provide a method and an apparatus for inspecting a short-circuit of a battery with high accuracy, which suppress the influence of humidity in the atmosphere as described above.

【0005】[0005]

【課題を解決するための手段】前記した課題を解決する
ために本発明の請求項1記載に係る発明は正極板,負極
板およびセパレータから構成されたセルを備えた未注液
電池の短絡検査方法において、正極板と負極板間に電圧
を印加した後の前記正極板と前記負極板間の電位差を測
定し、この電位差によって短絡の有無を判定することと
した。
According to a first aspect of the present invention, there is provided a short-circuit test for an unfilled battery provided with a cell comprising a positive electrode plate, a negative electrode plate and a separator. In the method, a potential difference between the positive electrode plate and the negative electrode plate after applying a voltage between the positive electrode plate and the negative electrode plate is measured, and the presence or absence of a short circuit is determined based on the potential difference.

【0006】また、本発明の請求項2記載に係る発明は
請求項1記載の電池の短絡検査方法において、セルあた
りの正極板と負極板の対向する面積の総和は2000c
2以上とした。
According to a second aspect of the present invention, there is provided the battery short-circuit inspection method according to the first aspect, wherein the sum of the opposed areas of the positive electrode plate and the negative electrode plate per cell is 2,000 c.
m 2 or more.

【0007】また、本発明の請求項3記載に係る発明は
請求項1もしくは請求項2記載の電池の短絡検査方法に
おいて未注液電池は鉛蓄電池とし、セパレータは繊維を
主体した。
According to a third aspect of the present invention, in the battery short-circuit inspection method according to the first or second aspect, the non-injected battery is a lead storage battery and the separator is mainly made of fiber.

【0008】さらに、本発明の請求項4記載に係る発明
は請求項3記載の電池の短絡検査方法において正極板お
よび負極板が未化成状態であることとした。
Further, in the invention according to claim 4 of the present invention, in the battery short-circuit inspection method according to claim 3, the positive electrode plate and the negative electrode plate are in an unformed state.

【0009】また、本発明の請求項5記載に係る発明は
第1の所定時間電池端子間に電圧を印加する電圧発生器
と、電圧印加終了から第2の所定時間経過時の電池端子
間電圧を測定する電圧測定器と、第1および第2の所定
時間を計測するタイマーと、電圧測定器で測定された電
圧と所定の判定電圧とを比較して短絡の有無を判定する
判定器とを備えた電池の短絡検査装置とした。
According to a fifth aspect of the present invention, there is provided a voltage generator for applying a voltage between battery terminals for a first predetermined time, and a voltage between the battery terminals after a lapse of a second predetermined time from the end of the voltage application. , A timer that measures the first and second predetermined times, and a determiner that determines whether there is a short circuit by comparing the voltage measured by the voltmeter with a predetermined determination voltage. The battery was equipped with a short-circuit inspection device.

【0010】[0010]

【発明の実施の形態】本発明の一実施の形態を図1を用
いて説明する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS One embodiment of the present invention will be described with reference to FIG.

【0011】図1に示したように電池1に電圧発生器2
が接続されており、電池1の正極端子と負極端子に一定
の電圧(V1)が印加される。ここで電池1には正極板
と負極板とがセパレータを介して積層されたセルが収納
されている(正極板,負極板,セパレータおよびセルと
もに図示せず)。電圧の印加時間はタイマー3によって
制御され、ある所定時間(t1)後には電圧の印加が終
了する。印加終了後、再びタイマー3によって次の所定
時間(t2)後に電池1の端子間の電位差(電圧、V2
が電圧測定器4によって測定される。この電位差V2
判定器5で所定の判定電圧VRと比較され短絡の有無を
判定するものである。すなわちV2≧VR(もしくはV2
>VR)の場合には短絡無しと判定し、若しV2<V
R(もしくはV 2≦VR)の場合には短絡有りと判定す
る。この判定はコンデンサーの原理を用いたもので、正
極端子と負極端子間に電圧を印加することにより静電容
量に基づいて電荷がチャージされ、これらの端子間に電
位差が発生する。この時正極板と負極板の短絡抵抗が小
さい程、両極の電位はより等しくなり、電荷はチャージ
されにくく電位差(V2)は零に近づく。これとは逆に
短絡していなければチャージされ、これら極板間に比較
的大きな電位差(V2)が生ずる。この電位差(V2)の
値により、短絡の有無を判定するものである。この電位
差(V2)は図2に示したように時間経過による電荷の
放電にともなって低下していくので電位差(V 2)を測
定するタイミングは厳密に規定する必要がある。ここで
電池1は当然未注液状態で検査を行う必要があることは
言うまでもない。また電池1としては未化成状態の鉛蓄
電池に適用することが最も好ましい。未化成状態の鉛蓄
電池は正極活物質および負極活物質がともに塩基性硫酸
鉛および硫酸鉛そしてごく少量の金属鉛の混合物であ
り、セルが多少吸湿しても電池端子間に大きな電位差を
発生させることがないからである。また、未化成活物質
は化成活物質と比較して電子伝導度が低く、電流検知に
よる従来の短絡検査方法では短絡の検知が困難である。
さらに本発明の電池短絡検査方法はガラス繊維セパレー
タ等のマットセパレータを用いた電池に適用することが
好ましい。マットセパレータは比表面積が大きく、湿度
の影響を受けやすく、本発明での課題が顕著となるから
である。それ以外のセパレータ、例えばゲル電解質を採
用した鉛蓄電池に用いられるような枠体をセパレータと
して用いた場合には、正極板と負極板との間にマットセ
パレータのような吸湿体が存在しないので従来からの短
絡検査方法でも大気中の湿度の影響をそれ程受けない。
また本発明の短絡検査方法はセル当たりの正極板と負極
板との対向面積の総和が2000cm2を超えるような
大容量の電池に適用することが好ましい。特にこのよう
な対向面積の総和が大きい電池はセル体積当たりの吸湿
能も高く、大気中の湿度の増加によってより容易に吸湿
し短絡検査における誤判定の危険性を増大させるからで
ある。また大容量の電池は当然体積も大きく、セルの中
心部まで水分が吸湿した場合、電池を低湿度の雰囲気下
に移動させてもセル中心部の水分を殆ど除去できなくな
るため、本発明の課題はより顕著になる。また、このよ
うな対向面積の総和が2000cm2を超える電池は静
電容量が大きくなることから、電圧印加を終了した後の
電位差(V2)の時間変化はより緩やかとなり、タイマ
ー3や電圧測定器4の精度が短絡判定に及ぼす影響をよ
り少なくすることができる。
As shown in FIG. 1, a battery 1 has a voltage generator 2
Is connected, and is fixed to the positive terminal and the negative terminal of the battery 1.
Voltage (V1) Is applied. Here, the battery 1 has a positive electrode plate
And a cell in which a negative electrode plate and a negative electrode plate are stacked via a separator
(Positive electrode plate, negative electrode plate, separator and cell
Also not shown). The voltage application time depends on timer 3.
Controlled for a predetermined time (t1) After that, the voltage application ends.
Complete. After the application is completed, the next predetermined time is again set by the timer 3.
Time (tTwo) After that, the potential difference between the terminals of the battery 1 (voltage, VTwo)
Is measured by the voltmeter 4. This potential difference VTwoIs
A predetermined judgment voltage VRTo determine if there is a short circuit
It is to judge. That is, VTwo≧ VR(Or VTwo
> VR)), It is determined that there is no short circuit,Two<V
R(Or V Two≤VRIn the case of), it is determined that there is a short circuit.
You. This judgment is based on the principle of the capacitor,
Capacitance is obtained by applying a voltage between the pole terminal and the negative terminal.
The charge is charged based on the amount, and the charge is applied between these terminals.
A difference occurs. At this time, the short-circuit resistance between the positive and negative plates is small.
In short, the potential of both poles becomes more equal and the charge is charged
Potential difference (VTwo) Approaches zero. On the contrary
Charged if not short-circuited and compared between these plates
Large potential difference (VTwo) Occurs. This potential difference (VTwo)of
The presence or absence of a short circuit is determined based on the value. This potential
Difference (VTwo) Indicates the change in electric charge over time as shown in FIG.
The potential difference (V Two)
It is necessary to strictly define the timing to determine. here
The fact that the battery 1 needs to be inspected without liquid
Needless to say. As the battery 1, unleaded lead storage
Most preferably, it is applied to batteries. Unformed lead storage
In batteries, both the positive and negative electrode active materials are basic sulfuric acid.
Mixture of lead and lead sulphate and very small amounts of metallic lead.
Large potential difference between battery terminals even if the cell absorbs some moisture.
This is because they do not occur. In addition, non-chemical activated material
Has a lower electronic conductivity than chemical active materials,
It is difficult to detect a short circuit by the conventional short circuit inspection method.
Further, the battery short-circuit inspection method of the present invention is a glass fiber separator.
It can be applied to batteries using mat separators such as
preferable. The mat separator has a large specific surface area and humidity
Because the subject of the present invention becomes remarkable.
It is. Use other separators, such as gel electrolyte.
A frame such as that used in lead-acid batteries used
When used as a mat, the mat
There is no hygroscopic material like parator
The influence of atmospheric humidity is not so large even in the case of the fault detection method.
In addition, the short-circuit inspection method of the present invention employs a positive electrode plate and a negative electrode per cell.
2000cm total area facing the plateTwoMore than
It is preferable to apply to a large capacity battery. Especially like this
Batteries with a large sum of the opposing areas absorb moisture per cell volume
High performance, more easily absorbs moisture due to increased atmospheric humidity
The risk of misjudgment in short-circuit inspection increases.
is there. Large-capacity batteries naturally have large volumes,
If moisture has absorbed into the core, place the battery in a low-humidity atmosphere.
Can hardly remove the water at the center of the cell.
Therefore, the problem of the present invention becomes more remarkable. Also this
The total sum of the facing areas is 2000cmTwoBatteries that exceed
Since the capacitance becomes large,
Potential difference (VTwo) Time change becomes more gradual and the timer
-3 and the accuracy of the voltage measurement device 4 affect short circuit judgment.
Can be reduced.

【0012】[0012]

【実施例】次に本発明の実施例についての性能比較を説
明する。
Next, the performance comparison of the embodiment of the present invention will be described.

【0013】(本発明例)まず、短絡検査を行う電池を
用意した。電池Aは公称電圧,定格容量が、2V100
0Ah(10時間率)相当の密閉形鉛蓄電池を用いた。
正極板はPbO2を主成分の活物質とするもので、幅1
40mm、高さ400mm、厚さ5.5mmのものを1
5枚、負極板はPbを主成分の活物質とするもので幅1
40mm、高さ400mm、厚さ3.0mmのものを1
6枚用い、幅140mm、高さ405mm、厚さ4.8
mmのガラス繊維製のセパレータを用い、1個の電池を
構成した。次に電池Bは電池Aと正極板,負極板および
セパレータの寸法,枚数は全く同じであるが、活物質は
いずれも未化成状態である。未化成状態の活物質は定法
に従い、鉛粉(鉛と一酸化鉛,鉛丹等の鉛酸化物との混
合粉)を水と希硫酸とで混練したペーストを鉛合金製の
格子体に塗着し、40℃から60℃程度の温度条件下で
熟成乾燥されたものを用いた。この未化成活物質は正極
板,負極板ともに塩基性硫酸鉛(一般には3塩基性硫酸
鉛),硫酸鉛および金属鉛の混合物である。これら電池
Aおよび電池Bの正極板と負極板との対向面積の総和は
いずれも16800cm2である。これらの電池Aおよ
び電池Bについてそれぞれ100個ずつ準備した。な
お、それぞれの100個中50個は活物質の破片を正極
板と負極板との間に介在させて擬似的な短絡電池を作製
した。これら電池の端子間に直流100Vの電圧(実施
の形態におけるV1)を5秒間(実施の形態における
1)印加した。この電圧を取り除いた1秒後(実施の
形態におけるt2)に、正極端子と負極端子間の電位差
(V2)を測定した。
(Example of the present invention) First, a battery to be subjected to a short-circuit test was prepared. Battery A has a nominal voltage and rated capacity of 2V100
A sealed lead-acid battery equivalent to 0 Ah (10 hour rate) was used.
The positive electrode plate has PbO 2 as the main active material and has a width of 1
40 mm, height 400 mm, thickness 5.5 mm
Five negative plates are composed of Pb as the main active material and have a width of 1
40 mm, height 400 mm, thickness 3.0 mm
Using 6 sheets, width 140mm, height 405mm, thickness 4.8
A single battery was formed using a glass fiber separator of mm. Next, battery B has the same dimensions and number of positive plates, negative plates, and separators as battery A, but the active material is not yet formed. For the unformed active material, apply a paste obtained by kneading lead powder (mixed powder of lead and lead oxides such as lead monoxide and lead oxide) with water and dilute sulfuric acid to a lead alloy lattice according to a standard method. And then aged and dried under a temperature condition of about 40 ° C to 60 ° C. The unformed active material is a mixture of basic lead sulfate (generally tribasic lead sulfate), lead sulfate, and metallic lead for both the positive electrode plate and the negative electrode plate. The total sum of the opposing areas of the positive electrode plate and the negative electrode plate of these batteries A and B is 16800 cm 2 . For each of these batteries A and B, 100 batteries were prepared. In addition, 50 out of 100 pieces each had a fragment of the active material interposed between the positive electrode plate and the negative electrode plate to produce a pseudo short-circuit battery. A voltage of 100 V DC (V 1 in the embodiment) was applied between the terminals of these batteries for 5 seconds (t 1 in the embodiment). One second after removing this voltage (t 2 in the embodiment), the potential difference (V 2 ) between the positive terminal and the negative terminal was measured.

【0014】(従来例)前記する本発明例と同じ構成の
電池Aおよび電池Bを用い正極端子と負極端子の間に3
00Vの電圧を印加し、この時に正極端子−負極端子間
に流れる電流値を測定した。
(Conventional example) A battery A and a battery B having the same configuration as the above-mentioned present invention are used, and 3 is connected between the positive terminal and the negative terminal.
A voltage of 00 V was applied, and the value of the current flowing between the positive electrode terminal and the negative electrode terminal at this time was measured.

【0015】(短絡検査の比較1)以上の本発明例と従
来例の構成で短絡検査を行った。検査雰囲気の温度は2
5℃、湿度は30〜100RH%の範囲で変化させ、こ
の時の誤判定率を調査した。その結果を図3に示す。誤
判定率は擬似的な短絡を発生させなかった電池で短絡有
りと判定されたもの(以下、第1の誤判定)の率および
擬似的な短絡を発生させた電池について短絡検査で短絡
無しと判定された電池(以下、第2の誤判定)の率をそ
れぞれ調査した。
(Comparison 1 of Short-Circuit Inspection) A short-circuit inspection was conducted with the above-described examples of the present invention and the conventional example. Inspection atmosphere temperature is 2
5 ° C. and humidity were changed in the range of 30 to 100 RH%, and the erroneous determination rate at this time was investigated. The result is shown in FIG. The misjudgment rate is the rate of batteries that did not cause a pseudo short circuit and was judged as having a short circuit (hereinafter, the first misjudgment), and the short circuit test determined that there was no short circuit for the battery that caused a pseudo short circuit. The rate of the batteries (hereinafter referred to as “second erroneous determination”) was examined.

【0016】その結果第2の誤判定率については従来例
および本発明例ともに0%であった。一方、第1の誤判
定率については図3に示したように本発明例は従来例と
比較して極めて低く抑制されている。とりわけ、未化成
極板で構成される電池Bについては誤判定率は0%であ
った。ここで従来例については電池Aおよび電池Bとも
に湿度の増加にしたがって第1の誤判定率が急激に上昇
した。ここで未化成極板を用いた電池Bが化成極板を用
いた電池Aよりも第1の誤判定率に及ぼす湿度の影響度
が大きい。これは未化成活物質と化成活物質における吸
湿性の差によるものと推測される。
As a result, the second misjudgment rate was 0% in both the conventional example and the present invention. On the other hand, as shown in FIG. 3, the first erroneous determination rate is extremely low in the example of the present invention as compared with the conventional example. In particular, the erroneous determination rate was 0% for the battery B composed of an unformed electrode plate. Here, in the conventional example, the first erroneous determination rate sharply increased as the humidity increased in both the battery A and the battery B. Here, the influence of humidity on the first erroneous determination rate of the battery B using the unformed electrode plate is larger than that of the battery A using the formed electrode plate. This is presumed to be due to the difference in hygroscopicity between the unchemically activated material and the chemically activated material.

【0017】(短絡検査の比較2)正極板および負極板
とも未化成状態の極板で構成される電池Bに関して極板
面積とセル構成枚数を変化させてそれぞれ異なる正極板
と負極板の対向面積の総和を有する電池を用意し、25
℃,90RH%の雰囲気下で前述した本発明例と従来例
の短絡検査方法により短絡検査を行い前述した第1の誤
判定率の調査を行った。その結果を図4に示す。図4の
結果から対向面積の総和が2000cm2以下の電池に
ついては本発明例,従来例ともに第1の誤判定率は0%
であった。対向面積の総和が2000cm2を超えて大
きくなると従来例の検査方法では第1の誤判定率が上昇
してゆく。他方、本発明例の検査方法では第1の誤判定
率は極めて低く抑制されていることが確認できた。
(Comparison 2 of short-circuit inspection) In the battery B composed of an unformed electrode plate for both the positive electrode plate and the negative electrode plate, the area of the positive electrode plate and the facing area of the negative electrode plate which are different by changing the electrode plate area and the number of cells constituting the battery B Prepare a battery having the sum of
In an atmosphere of 90 ° C. and 90 RH%, short-circuit inspection was performed by the above-described short-circuit inspection method of the present invention and the conventional example, and the above-mentioned first erroneous determination rate was investigated. FIG. 4 shows the results. From the results shown in FIG. 4, the first erroneous determination rate is 0% in both the present invention example and the conventional example for the battery having a total facing area of 2000 cm 2 or less.
Met. When the sum of the opposing areas exceeds 2000 cm 2 , the first erroneous determination rate increases in the conventional inspection method. On the other hand, it was confirmed that the first erroneous determination rate was extremely low in the inspection method of the example of the present invention.

【0018】[0018]

【発明の効果】本発明の電池の短絡検査方法によれば雰
囲気湿度や電池のサイズに影響されず安定して判定精度
の高い短絡検査を行うことができ、工業上極めて有用な
ものである。
According to the battery short-circuit inspection method of the present invention, a short-circuit inspection with high determination accuracy can be stably performed without being affected by the atmospheric humidity and the size of the battery, and is extremely useful in industry.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明例による電池の短絡検査装置を示す図FIG. 1 is a diagram showing a battery short-circuit inspection device according to an embodiment of the present invention.

【図2】本発明例の電池短絡検査における端子間電位差
の時間変化を示す図
FIG. 2 is a diagram showing a time change of a potential difference between terminals in a battery short-circuit test according to an example of the present invention.

【図3】本発明例および従来例の電池短絡検査における
誤判定率と雰囲気湿度との関係を示す図
FIG. 3 is a diagram showing the relationship between the erroneous determination rate and the atmospheric humidity in the battery short-circuit test of the present invention example and the conventional example.

【図4】本発明例および従来例の電池短絡検査における
誤判定率と電池の正極板と負極板の対向面積の総和との
関係を示す図
FIG. 4 is a diagram showing the relationship between the erroneous determination rate in the battery short-circuit test according to the present invention and the conventional example and the total sum of the facing areas of the positive and negative plates of the battery.

【図5】従来例の電池短絡検査における電流と雰囲気湿
度との関係を示す図
FIG. 5 is a diagram showing a relationship between current and ambient humidity in a conventional battery short-circuit test.

【符号の説明】[Explanation of symbols]

1 電池 2 電圧発生器 3 タイマー 4 電圧測定器 5 判定器 DESCRIPTION OF SYMBOLS 1 Battery 2 Voltage generator 3 Timer 4 Voltage measuring device 5 Judgment device

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 正極板,負極板およびセパレータから構
成されたセルを備えた未注液電池の短絡検査方法であっ
て、前記正極板と前記負極板間に電圧を印加した後の前
記正極板と前記負極板間の電位差を測定することを特徴
とする電池の短絡検査方法。
1. A method for inspecting a short circuit of an uninjected battery provided with a cell composed of a positive electrode plate, a negative electrode plate, and a separator, wherein the positive electrode plate after applying a voltage between the positive electrode plate and the negative electrode plate And measuring the potential difference between the battery and the negative electrode plate.
【請求項2】 セルあたりの正極板と負極板の対向する
面積の総和は2000cm2以上であることを特徴とす
る請求項1に記載の電池の短絡検査方法。
2. The battery short-circuit inspection method according to claim 1, wherein the total sum of the opposed areas of the positive electrode plate and the negative electrode plate per cell is 2000 cm 2 or more.
【請求項3】 未注液電池は鉛蓄電池とし、セパレータ
は繊維を主体とするマットセパレータとしたことを特徴
とする請求項1もしくは請求項2のいずれか1項に記載
の電池の短絡検査方法。
3. The battery short-circuit inspection method according to claim 1, wherein the unfilled battery is a lead storage battery, and the separator is a mat separator mainly composed of fibers. .
【請求項4】 正極板および負極板が化成されていない
状態であることを特徴とする請求項3に記載の電池の短
絡検査方法。
4. The method according to claim 3, wherein the positive electrode plate and the negative electrode plate are not formed.
【請求項5】 電池の短絡検査装置であって、第1の所
定時間電池端子間に電圧を印加する電圧発生器と、電圧
印加終了から第2の所定時間経過時の電池端子間電圧を
測定する電圧測定器と、前記第1の所定時間および第2
の所定時間を計測するタイマーと、電圧測定器で測定さ
れた電圧と所定の判定電圧とを比較して短絡の有無を判
定する判定器とを備えた電池の短絡検査装置。
5. A battery short-circuit inspection device, comprising: a voltage generator for applying a voltage between battery terminals for a first predetermined time; and measuring a voltage between battery terminals when a second predetermined time has elapsed from the end of the voltage application. The first predetermined time and the second
A battery short-circuit inspection device comprising: a timer for measuring a predetermined time; and a determiner for comparing the voltage measured by the voltmeter with a predetermined determination voltage to determine the presence or absence of a short circuit.
JP28556299A 1999-10-06 1999-10-06 Method for inspecting short circuit of battery abd apparatus for inspecting short circuit of battery Pending JP2001110458A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP28556299A JP2001110458A (en) 1999-10-06 1999-10-06 Method for inspecting short circuit of battery abd apparatus for inspecting short circuit of battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28556299A JP2001110458A (en) 1999-10-06 1999-10-06 Method for inspecting short circuit of battery abd apparatus for inspecting short circuit of battery

Publications (1)

Publication Number Publication Date
JP2001110458A true JP2001110458A (en) 2001-04-20

Family

ID=17693168

Family Applications (1)

Application Number Title Priority Date Filing Date
JP28556299A Pending JP2001110458A (en) 1999-10-06 1999-10-06 Method for inspecting short circuit of battery abd apparatus for inspecting short circuit of battery

Country Status (1)

Country Link
JP (1) JP2001110458A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007035288A (en) * 2005-07-22 2007-02-08 Furukawa Battery Co Ltd:The Inspection method of lead accumulator
CN103135059A (en) * 2011-11-30 2013-06-05 海洋王照明科技股份有限公司 Battery short-circuiting circuit and battery short circuit testing method
DE102019104879A1 (en) 2018-03-06 2019-09-12 Toyota Jidosha Kabushiki Kaisha Method for testing a solid-state battery, method for producing a solid-state battery, and method for producing a battery pack
KR20190106692A (en) 2018-03-06 2019-09-18 도요타 지도샤(주) Method for testing all solid state battery, method for producing all solid state battery, and method for producing battery pack
DE102019209906A1 (en) 2018-07-06 2020-01-09 Toyota Jidosha Kabushiki Kaisha SHORT-CIRCUIT TEST METHOD FOR SOLID-BODY BATTERY ARRANGEMENT, CLAMPING DEVICE USED FOR THIS, SHORT-CIRCUIT KIT, AND METHOD FOR PRODUCING A SOLID-BATTERY
US10753978B2 (en) 2018-04-27 2020-08-25 Toyota Jidosha Kabushiki Kaisha Method for testing all solid state battery, method for producing all solid state battery, and method for producing battery pack
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007035288A (en) * 2005-07-22 2007-02-08 Furukawa Battery Co Ltd:The Inspection method of lead accumulator
JP4557829B2 (en) * 2005-07-22 2010-10-06 古河電池株式会社 Inspection method of lead acid battery
CN103135059A (en) * 2011-11-30 2013-06-05 海洋王照明科技股份有限公司 Battery short-circuiting circuit and battery short circuit testing method
DE102019104879A1 (en) 2018-03-06 2019-09-12 Toyota Jidosha Kabushiki Kaisha Method for testing a solid-state battery, method for producing a solid-state battery, and method for producing a battery pack
KR20190106692A (en) 2018-03-06 2019-09-18 도요타 지도샤(주) Method for testing all solid state battery, method for producing all solid state battery, and method for producing battery pack
US10985413B2 (en) 2018-03-06 2021-04-20 Toyota Jidosha Kabushiki Kaisha Method for testing all solid state battery, method for producing all solid state battery, and method for producing battery pack
DE102019104879B4 (en) 2018-03-06 2024-03-28 Toyota Jidosha Kabushiki Kaisha Method for testing a solid-state battery, method for manufacturing a solid-state battery and method for manufacturing a battery pack
US10753978B2 (en) 2018-04-27 2020-08-25 Toyota Jidosha Kabushiki Kaisha Method for testing all solid state battery, method for producing all solid state battery, and method for producing battery pack
DE102019209906A1 (en) 2018-07-06 2020-01-09 Toyota Jidosha Kabushiki Kaisha SHORT-CIRCUIT TEST METHOD FOR SOLID-BODY BATTERY ARRANGEMENT, CLAMPING DEVICE USED FOR THIS, SHORT-CIRCUIT KIT, AND METHOD FOR PRODUCING A SOLID-BATTERY
US11125776B2 (en) 2018-07-06 2021-09-21 Toyota Jidosha Kabushiki Kaisha Short circuit inspection method for all-solid-state battery assembly, restraint jig used therefor, kit for short circuit inspection, and method for manufacturing all-solid-state battery
CN112219126A (en) * 2018-11-21 2021-01-12 株式会社Lg化学 Clamp extrusion type extrusion short circuit inspection method
CN112219126B (en) * 2018-11-21 2023-09-05 株式会社Lg新能源 Clamp extrusion type extrusion short circuit inspection method

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