JP2001065020A - Slime removing tool - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a small-sized slime removing tool with excellent safety or handleability without causing a problem of chlorine odor or corrosion, retaining proper solubility and capable of being easily set in slime generating parts of various forms. SOLUTION: A slime removing composition containing an enclosure compound consisting of a non-bleaching powder antibacterial agent such as 5-chloro-2- methyl-4-isothiazoline-3-on or the like or the non-bleaching powder antibacterial agent and a multilayer phosphate compound; and a specified base material such as calcium sulfate, acetoacetate-o-toluidide, sorbitol or the like is pressure molded to provide a small-sized slime removing agent consisting of tablets having a maximum length of 30 mm or less. This slime removing agent is housed in a water permeable vessel consisting of a nonwoven fabric or porous resin film, preferably, a water permeable vessel having a locking means such as adhesive tape.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a kitchen sink, a drain in a bathroom, and a garbage container for a kitchen (commonly known as a triangle corner).
The present invention relates to a slime removing tool provided at a place where slime is generated by a metabolite such as bacteria or mold, such as a garbage container or a garbage container, for removing slime and preventing the occurrence of slime.

[0002]

2. Description of the Related Art The main components of slime, such as kitchen sinks and bathroom drains, kitchen garbage containers and garbage containers, are ingredients,
Surfactants, soaps, human scales and the like serve as nutrients for bacteria, and are polysaccharides and mold hyphae secreted from the bacteria at that time.

[0003] As a method for removing such a slime component,
Oxidizing agents are widely used for commercially available slime removal, among which a method of chemically decomposing and removing slime using a chlorine bleaching powder or an aqueous solution of sodium hypochlorite, and a method of disinfecting bacteria and mold are used. ing. Further, in many cases, similar effects are obtained by using sodium percarbonate powder or hydrogen peroxide solution generally used as a non-chlorine oxidizing agent.

[0004]

However, in the above-mentioned bleaching powder-based slime remover and aqueous sodium hypochlorite solution, the active ingredient hypochlorous acid-based substance has a strong oxidizing power, and And the metal in the surrounding area may be corroded and generates toxic chlorine gas.
In particular, when reacting with an acidic substance such as vinegar, a dangerous state occurs in which the generation amount of chlorine gas is significantly increased. In addition, in the case of a drug containing trichloroisocyanuric acid as an active ingredient, when reacting with an alkaline or sodium hypochlorite-based detergent,
Attention must be paid to the fact that high concentrations produce explosive nitrogen trichloride gas.

Further, sodium percarbonate, which is a non-chlorine oxidizing agent, has high solubility and dissolves quickly when it comes into contact with water. The oxidizing power of aqueous hydrogen peroxide is weaker than that of hypochlorous acid-based substances, and it has the disadvantage that it decomposes slime in a short contact and cannot kill bacteria or mold that cause slime. An object of the present invention is to provide a small-sized slimming tool which does not have the above-mentioned danger, is excellent in safety and handleability, maintains appropriate solubility, and can be easily installed in a slime-generating portion of various shapes. Is to do.

[0006]

Means for Solving the Problems The present inventors have conducted intensive studies to solve the above-mentioned problems, and as a result, they have identified a non-bleachable antibacterial agent, particularly an clathrate compound comprising an antibacterial agent and a multimolecular host compound. A small tablet of a pressed product of a slime control composition containing the base material of the present invention does not have the above-mentioned danger, is excellent in safety and handleability, retains appropriate solubility, and has a slime control effect. It has been found that it can be easily installed on objects having various forms of slime control, and the present invention has been completed.

That is, the present invention relates to an inclusion compound comprising an antibacterial agent such as 5-chloro-2-methyl-4-isothiazolin-3-one and a multimolecular host compound such as tetrakisphenol, and an organic iodine. Non-bleachable antibacterial agents such as antibacterial agents, calcium hydrogen phosphate dihydrate, tricalcium phosphate anhydride, magnesium hydrogen phosphate trihydrate, magnesium hydrogen phosphate octahydrate, lactose, vanillin, calcium citrate 4 Hydrate, calcium sulfate dihydrate, calcium sulfate hemihydrate, acetoacetic anilide, acetoacetic acid-o
-Toluidide, acetoacetic acid-p-toluidide, acetoacetic acid-o-anisidide, sorbitol, glycerin monofatty acid ester, alkyl sorbitan ester (H
LB14 or less), a base composition comprising one or more compounds selected from sucrose fatty acid esters (HLB14 or less), and a base material comprising a compound, and the like. The present invention relates to a slime-removing device, characterized in that one or more slime-controlling agents comprising tablets are stored in a water-permeable container.

[0008] The present invention also provides a slime-removing device and a water-permeable container, wherein the water-permeable container of the slime-removing device is a bag of a nonwoven fabric or a resin film having a hole.
The slime-removing tool, which is provided with a locking means, or the locking means is provided with an adhesive portion or a container provided on the container.
The present invention relates to the slimming tool described above, comprising a placing portion provided between two tablet storing portions.

Further, the present invention provides a method for preparing the above-mentioned calcium sulfate.
Wherein the pentahydrate is β-type calcium sulfate hemihydrate, and the slime-removing device or the slime-controlling agent is a C ₁₄ -C such as stearic acid or lauric acid as a dissolution regulator.
_The present invention relates to a slimming device characterized by being a small tablet containing ₂₄ saturated fatty acids.

[0010]

BEST MODE FOR CARRYING OUT THE INVENTION As the non-bleachable antibacterial agent in the present invention, any one can be used as long as it does not generate chlorine gas by reacting with an acidic substance or the like at the time of use. And compounds known as general fungicides or antibacterial agents, and natural oils known to have antibacterial activity. As the fungicide or antibacterial agent, for example, 5-chloro-2-
Methyl-4-isothiazolin-3-one, 2-methyl-
4-isothiazolin-3-one, 4,5-dichloro-3
-N-octyl-isothiazolin-3-one, 1,2-
Benzisothiazolin-3-one, 2-methoxycarbonylbenzimidazole, 2,3,5,6-tetrachloro-4-methanesulfonylpyridine, 2-thiocyanomethibenzothiazole, 2,2-dithio-bis- (pyridine- 1-oxide), 3,3,4,4-tetrahydrothiophene-1,1-dioxide, 4,5-dichloro-1,2-dithiolan-3-one, 5-chloro-4-
Phenyl-1,2-dithiolan-3-one, N-methylpyrrolidone, phenyl- (2-cyano-2-chlorovinyl) sulfone, methylenebisthiocyanate, 2-bromo-2-nitropropane-1,3-diol, 2,2-
Dibromo-2-ethanol, 2-bromo-4'-hydroxyacetophenone, dibromonitrilepropionamide, 2-bromo-2-bromomethylglutarnitrile,
Sodium percarbonate, potassium persulfate, sodium perborate, orthophenylphenol, diphenyl, 2-isopropyl-5-methylphenol, parachloromethaxylenol, n-butyl parahydroxybenzoate, ethyl parahydroxybenzoate, parahydroxybenzoic acid Methyl, benzalkonium chloride, benzethonium chloride, chlorohexidine hydrochloride, chlorohexidine gluconate, 2-
Pyridinethiol-1-oxide, 2-pyridinethiol-1-oxide zinc salt, 2-pyridinethiol-1
-Oxide sodium, N, N'-hexamethylenebis (4-carbamoyl-1-decylpyridinium bromide), 4,4 '-(tetramethylenediamino) bis (1
-Decylpyridinium bromide) and the like.

Examples of natural oils include cineol, hinokitiol, menthol, terpineol, borneol, nopol, citral, citronellal, citronellol, geraniol, linalool, dimethyloctanol, thymol and the like.

Further, as the non-bleachable antibacterial agent in the present invention, an iodine antibacterial agent can be exemplified, and among them, a solid antibacterial agent is particularly preferable. Examples of solid iodine antibacterial agents include 2,3,3-triiodoallyl alcohols, 2,3,3-triiodoallyl ethers, 2,3,3-triiodoallylazoles, and 3-iodo. -2-propargylbutylcarbamic acid, 4-chlorophenyl (3-iodopropargyl) formal, iodopropargylazoles, diiodo-para-trisulfone, popidone iodine, benzyliodoacetate and paranitrobenzyliodoacetate. Can be.

These non-bleachable antibacterial agents may be used alone or
A mixture of more than one species can be used. Further, these non-bleached powder antibacterial agents can be used as guest compounds of a multimolecular host compound, and can be used after forming an inclusion compound.

In the present invention, the base material used together with the non-bleachable antibacterial agent is calcium hydrogen phosphate dihydrate, tricalcium phosphate anhydride, magnesium hydrogen phosphate trihydrate, magnesium hydrogen phosphate octahydrate, lactose. , Vanillin,
Calcium citrate tetrahydrate, calcium sulfate dihydrate, calcium sulfate hemihydrate, acetoacetic anilide, acetoacetic-o-toluidide, acetoacetic-p-
Nonionic surfactants such as toluidide, acetoacetic acid-o-anisidide, sorbitol, alkyl sorbitan ester (HLB14 or less), glycerin mono fatty acid ester, and sucrose fatty acid ester (HLB14 or less) are used alone. Or two or more kinds can be used in combination, but it can be determined in consideration of the impact on tableting properties when formed under pressure, solubility in water, disintegration, and stability of antibacterial agents. desirable.

The substrate is preferably a neutral solid substance which does not increase the generation of chlorine gas when mixed with a commercially available cleaning agent containing hypochlorous acid. In addition, especially when an inclusion compound is used as the non-bleachable antibacterial agent, sorbitol, lactose, acetoacetic acid-o-
Toluidide and calcium sulfate hydrate are preferred. Furthermore, when calcium sulfate is used as the base material, calcium sulfate hemihydrate is preferred from the viewpoint that moldability and solubility can be easily controlled, and among calcium sulfate hemihydrate, Β-type ones produced by normal-pressure calcination are preferred over α-type ones produced by pressure-sintering because they are less likely to lose their shape due to water absorption. When .pentahydrate is used, it is more preferable to use it in combination with lactose from the viewpoint of controlling the moldability and solubility.

In the present invention, the term "multimolecular host compound" refers to a compound which forms a crystalline complex (inclusion compound) having an interaction with an antibacterial agent serving as a guest by an intermolecular force such as hydrogen bond and having a regular arrangement. The compound is not particularly limited as long as it has the above properties, and examples thereof include the following compounds. (1) Tetrakisphenols (2) 1,1,6,6-tetraphenyl-2,4-hexadiyne-1,6-diol (3) 1,6-bis (2-chlorophenyl) -1,6 −
Diphenylhexane-2,4-diyne-1,6-diol (4) 1,1,4,4-tetraphenyl-2-butyne-
1,4-diol (5) 2,5-bis (2,4, dimethylphenyl) hydroquinone (6) 1,1-bis (2,4, dimethylphenyl) -2
-Propyn-1-ol (7) 1,1,2,2-tetraphenylethane-1,2
-Diol (8) 1,1'-bi-2-naphthol (9) 9,10-diphenyl-9,10-dihydroxyanthracene (10) 1,1,6,6-tetra (2,4-dimethylphenyl) -2,4-hexadiyne-1,6-diol (11) 9,10-bis (4-methylphenyl) -9,
10-dihydroxyanthracene (12) 1,1-bis (4-hydroxyphenyl) cyclohexane (13) N, N, N ', N'-tetrakis (cyclohexyl)-(1,1'-biphenyl) -2-2' -Dicarboxamide (14) 4,4'-sulfonylbisphenol (15) 4,4'-butylidenebis (3-methyl-6-
tert-butylphenol) (16) 2,2'-methylenebis (4-methyl-6-t
tert-butylphenol) (17) 4,4'-thiobis (4-chlorophenol) (18) 2,2'-methylenebis (4-chlorophenol) (19) deoxycholic acid (20) cholic acid (21) α, α, α ′, α′-tetraphenyl-1,
1'-biphenyl-2,2'-dimethanol (22) t-butylhydroquinone (23) 2,5-di-tert-butylhydroquinone (24) granular corn starch (25) 1,4-diazabicyclo- (2, 2,2) -octane

The tetrakisphenols in the above-mentioned multimolecular host compound include, for example, 1,1,2,2-
Tetrakis (4-hydroxyphenyl) ethane, 1,
1,2,2-tetrakis (3-fluoro-4-hydroxyphenyl) ethane, 1,1,2,2-tetrakis (3
-Chloro-4-hydroxyphenyl) ethane, 1,1,
2,2-tetrakis (3-methyl-4-hydroxyphenyl) ethane, 1,1,2,2-tetrakis (3-methoxy-4-hydroxyphenyl) ethane, 1,1,2,2
2-tetrakis (3,5-dimethyl-4-hydroxyphenyl) ethane, 1,1,3,3-tetrakis (4-hydroxyphenyl) propane, 1,1,3,3-tetrakis (3-fluoro-4- (Hydroxyphenyl) propane, 1,1,3,3-tetrakis (3-chloro-4-hydroxyphenyl) propane, 1,1,3,3-tetrakis (3-methyl-4-hydroxyphenyl) propane, 1,1 , 3,3-tetrakis (3-methoxy-4-
(Hydroxyphenyl) propane, 1,1,3,3-tetrakis (3,5-dimethyl-4-hydroxyphenyl)
Propane, 1,1,4,4-tetrakis (4-hydroxyphenyl) butane, 1,1,4,4-tetrakis (3
-Fluoro-4-hydroxyphenyl) butane, 1,
1,4,4-tetrakis (3-chloro-4-hydroxyphenyl) butane, 1,1,4,4-tetrakis (3-
Methyl-4-hydroxyphenyl) butane, 1,1,
4,4-tetrakis (3-methoxy-4-hydroxyphenyl) butane, 1,1,4,4-tetrakis (3,5
-Dimethyl-4-hydroxyphenyl) butane, 1,
1,5,5-tetrakis (4-hydroxyphenyl) pentane, 1,1,5,5-tetrakis (3-fluoro-
4-hydroxyphenyl) pentane, 1,1,5,5-
Tetrakis (3-chloro-4-hydroxyphenyl) pentane, 1,1,5,5-tetrakis (3-methyl-4
-Hydroxyphenyl) pentane, 1,1,5,5-tetrakis (3-methoxy-4-hydroxyphenyl) pentane, 1,1,5,5-tetrakis (3,5-dimethyl-4-hydroxyphenyl) pentane and the like Tetrakis (hydroxyphenyl) alkanes can be specifically exemplified.

The clathrate compound used in the present invention is usually
A non-bleachable antibacterial agent to be a guest and a host compound,
In some cases, at room temperature to 1 in the presence of water or an organic solvent.
It can be easily obtained by stirring and reacting at 00 ° C. for several minutes to several hours.

In the present invention, the mixing ratio of the non-bleachable antibacterial agent to the base material is arbitrary between 1 to 99 parts by weight of the non-bleachable antibacterial agent and 99 to 1 part by weight of the base material because of various usage conditions. The mixing ratio can be varied, but preferably 5 to 20 parts by weight of a non-exposed powder antibacterial agent,
0 parts by weight. When an inclusion compound is used as the non-bleachable powder antibacterial agent, a mixing ratio of 2 to 30 parts by weight of the inclusion compound and 98 to 70 parts by weight of the base material is preferable.

The slime control agent of the present invention can be obtained by press-molding a slime control composition containing a non-bleachable antibacterial agent and a base material.
If necessary, a lubricant such as calcium stearate, magnesium stearate, sodium stearate, sodium benzoate, orthoboric acid or the like may be added to the whole slime control agent 10
A binder such as hydroxypropylcellulose, sodium alginate, polyvinyl alcohol, or polyvinylpyrrolidone is used in an amount of 0.1 to 5 parts by weight based on 0 parts by weight, and 1 to 15 parts by weight based on 100 parts by weight of the total slime control agent. By adding in the ratio of parts, pressure molding can be facilitated.

Addition of a C ₁₄ -C ₂₄ saturated fatty acid such as stearic acid for the purpose of imparting lubricity during molding and at the same time improving the stability of the agent in water (the ability to prevent swelling and collapse). Can be. In particular, when calcium sulfate is used as a base material, it is preferable to add a C ₁₄ -C ₂₄ saturated fatty acid as a dissolution regulator. The amount of the C ₁₄ -C ₂₄ saturated fatty acid to be added is 1 to 10 with respect to 100 parts by weight of the whole slime control agent.
Used in parts by weight. Although 10 parts by weight or more can be added, the dissolution rate becomes slow. Although the saturated fatty acids C ₁₄ -C ₂₄ can include stearic acid and lauric acid Specifically, metal salts of saturated fatty acids of C ₁₄ -C ₂₄ such as calcium stearate as the lubricant is If used in a proportion of 1 part by weight or more with respect to 100 parts by weight of the whole slime control agent, the moldability may be impaired,
It is not suitable for use as a dissolution regulator. Further, depending on the purpose, corrosion inhibitors such as alkylthiourea-based and triazole-based can be added to suppress corrosion of metal parts such as piping. Also, by adding diatomaceous earth, sulphate clay and the like, an antistatic effect can be imparted during molding.

A surfactant can be added to the small slime control agent of the present invention for the purpose of spreading the antibacterial agent dissolved in water to a wide range. Surfactants include anionic surfactants, cationic surfactants, amphoteric surfactants,
Various known surfactants such as a nonionic surfactant can be used.

It is also possible to add a deodorant or an odorant to deodorize and mask the odor of drainage pipes and garbage, and to remove bitter components to prevent accidental eating due to small tablets. It is also possible to add an unpleasant taste component such as a hot and pungent component.

The slime-controlling agent comprising a tablet according to the present invention can be in the form of various known tablets, but it is disc-shaped in view of ease of press molding and easy installation in a narrow place. , Drop square, oval, flat sphere,
A shape such as a sphere is preferably selected. The size of the longest part is 30 mm or less, preferably 20 mm or less, and particularly preferably 15 mm or less so that it can be installed in a narrow container such as various drainage pipes or kitchen trash receptacles.

The slimming tool of the present invention has a maximum length of 30
mm is contained in a water-permeable container in order to prevent the small slime control agent composed of a tablet having a size of less than 1 mm from flowing out when the product is further miniaturized by dissolution. Even if the container is made of a material that has an appropriate water permeability, it can be used even if the container is made of a material that has a proper water permeability. A storage container made of a bag such as a nonwoven fabric or a resin film having pores is preferably used.

For the water-permeable container, various well-known materials such as a thread, a string, a metal wire, a resin stopper, an adhesive tape, etc. are provided for installing the container in a drainage control unit such as a waste container in a kitchen or the like. It is preferable that the locking means is provided with a locking means, such as an adhesive tape portion, as shown in FIG. FIG. 1 shows a slime removing tool of the present invention having an adhesive portion Q on one surface of a container C made of a nonwoven fabric in which a tablet T is stored.
FIG. 3 is a schematic vertical sectional view showing a state where the garbage receiving container (commonly called a triangular corner) W is locked inside a wall surface of the kitchen through the adhesive portion Q. Also, as shown in FIG.
Between them, a water-permeable container C provided with a mounting portion R in which the tablet T does not exist, and the mounting portion R is placed on the upper end of the periphery of a garbage receiving container W (commonly called a triangular corner) W in the kitchen to make it slimy. Can be controlled.

[0027]

EXAMPLES The present invention will be described below with reference to Examples and Comparative Examples.
Although described more specifically, the technical scope of the present invention is not limited to these examples. Examples and Comparative Examples (Preparation of Samples) From the respective mixtures having the compounding ratios shown in Table 1, each sample consisting of a cylindrical molded product having a diameter of 10 mm was prepared by pressure molding. In Table 1, “TEP · CMI” is 2 mol of 5-chloro- as an antibacterial agent serving as a guest compound.
Inclusion compound obtained by reaction of 2-methyl-4-isothiazolin-3-one with 1 mol of 1,1,2,2-tetrakis (4-hydroxyphenyl) ethane as a polymolecular host compound "Bronopol" represents the antimicrobial agent 2-bromo-2-nitropropane-1,3-diol, "TIAA" represents 2,3,3-triiodoallyl alcohol, and "HPC" represents the binder hydroxy. Represents propylcellulose.

[0028]

[Table 1]

(Tabletting / Disintegration Test) The sample was tableted at a tableting pressure of 1 t / cm ² with a rotary tableting machine (P-22, a small high-speed tableting machine manufactured by Hata Kikai Seisakusho, Ltd.) equipped with a 10 mm mold. ,
When a "tabletability" test was conducted for body cracking, capping, lubricity, adhesion, and the like, the tabletability of all samples was evaluated as "O", and there was no tableting failure. . Further, one tablet of the molded product of each of these samples was placed in a 200 ml polycup, 200 ml of distilled water was added, and the collapsed state of the molded product after standing at room temperature for 24 hours was observed.
None of the samples collapsed.

(Dissolution Test) One tablet is placed in a commercially available storage case for removing slime, and a commercially available pipette washer having a diameter of 18 cm and a height of 58 cm (washing water amount: 14.75 L, washing water temperature: 35 to 40 ° C., washing) (Water contact time: 3 minutes, washing interval: 6.6 minutes / time) At a position of 25 to 29 cm in water depth, the entire storage case was hung with a string and continuously washed to measure the dissolution rate. The numerical values in Table 1 represent the time until the molded product is completely dissolved.

(Performance test) One tablet (molded product) was placed in a nonwoven bag having a side of 20 mm and fixed with double-sided tape at four diagonal lines above the trash removal basket in the drain of a general household kitchen. did. In addition, the same sample as the above was fixed with three-sided tape to three places at the middle part and one place at the bottom of the wall of the kitchen garbage receiving container (commonly called a triangular corner) of the kitchen sink. The kitchen in which the chemicals were installed was used as usual, and after one week, the odor (rot odor of garbage) and the degree of adhesion of slime were visually observed. In addition, the case where the medicine was used without setting was used as a control. Table 1 shows the results. As can be seen from Table 1, when the small slime control agent of the present invention was installed, the spoilage odor of the garbage was small and the amount of slime adhered after one week was large in each case when the small slime control agent of the present invention was installed. Decreased to.

(Chlorine gas generation test when mixed with hypochlorous acid-based cleaning agent) A 1 g sample was put into a 100 ml beaker, 100 ml of distilled water was added, and the pH of the dissolved solution was measured with a pH meter. The following were used as a measure for generating chlorine gas by mixing with a commercially available hypochlorous acid-based cleaning agent. The results are shown in Table 1 as "danger of chlorine-based detergent". As can be seen from Table 1, all of the samples of the examples were evaluated as “○”, and it was found that there was no fear of generating chlorine gas.

(Disintegration test of clathrate when clathrate is used: dissolution test of antibacterial agent from clathrate) To see the effect of the base material on the stability of the clathrate, A disintegration test of the contact compound was performed. 1 g of each base material shown in Table 2 and 98 g of distilled water were put into a 200 ml beaker, stirred with a magnetic stirrer for 3 hours, and dissolved to a saturated state, and then 1 g of the above TEP was included as an inclusion compound.
-CMI was added, the mixture was stirred with a magnetic stirrer for 24 hours, and then the solution was filtered through a 0.2 µ membrane filter to measure the amount of the antibacterial agent eluted in the clathrate compound. As a blank, water with no added base material was used. Table 2 shows the results. In Table 2, "degree of clathration disintegration (%)" means the dissolution ratio of the antibacterial agent from the clathrate compound. And, as can be seen from Table 2, the base material used in the present invention had the same degree of clathrate disintegration as the blank, but the polyethylene glycol used for comparison degraded the clathrate compound at a high rate. From this point of view, the base material used in the present invention was found to be excellent also from the viewpoint of the degree of inclusion disintegration.

[0034]

[Table 2]

[0035]

According to the present invention, the slime-removing device of the present invention does not contain a chemical that promotes the generation of chlorine by reacting with a chlorine-generating agent or a chlorine-generating agent. It is safe and easy to handle because it has no problem of chlorine odor and corrosion, and it is small and easy to use because of its small size.For example, complex shapes such as kitchen sinks, bathroom drains, kitchen garbage containers, etc. It can be easily installed in places,
Since the active ingredient can be more stably eluted, it is easily installed in places where slime is generated by metabolites such as germs and molds, to remove slime and prevent the generation of slime, and also to reduce garbage etc. It is possible to suppress a bad smell caused by decay.

[Brief description of the drawings]

FIG. 1 is a schematic vertical cross-sectional view of a case where a slimming implement of the present invention is applied to a garbage receiving container in a kitchen.

FIG. 2 is a schematic perspective view when a slimming tool of another embodiment of the present invention is applied to a garbage receiving container in a kitchen.

[Explanation of symbols]

 T Tablet (slime control agent) C Slime control agent storage container Q Container sticking part S Tablet storage portion of slime control agent storage container R Placement of slime control agent storage container W Kitchen garbage container (commonly called triangular corner)

──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. ⁷ Identification symbol FI theme coat ゛ (Reference) A01N 43/80 102 A01N 43/80 102 A61L 2/16 A61L 2/16 Z 2/26 2/26 Z C11D 3/48 C11D 3/48 (72) Inventor Eiji Takemura 2-2-1 Otemachi, Chiyoda-ku, Tokyo F-term in Nippon Soda Co., Ltd. 2D061 AA01 AA02 AB06 AB10 3B117 AA06 AA08 4C058 AA02 AA06 BB07 JJ02 JJ22 4H003 AB45 BA17 BA21 CA08 DA08 DA13 DB01 EA24 EB03 EB04 EB07 EB09 EB12 EB21 EB41 EB42 FA01 FA32 FA34 4H011 AA05 DA03 DB09 DC11

Claims (13)

[Claims] 1. A slime-controlling composition containing a non-bleached powder-type germicide and a base material, which is subjected to pressure molding to have a maximum length of 30 mm.
A slime-removing device characterized in that one or more slime-controlling agents comprising the following tablets are contained in a water-permeable container. 2. The slimming tool according to claim 1, wherein the water-permeable container is a nonwoven fabric or a bag of a resin film having holes. 3. The slimming tool according to claim 1, wherein the water-permeable container is provided with locking means. 4. The slimming tool according to claim 3, wherein the locking means is an adhesive portion provided on the container. 5. The slimming tool according to claim 2, wherein the locking means is a mounting portion provided between the two tablet storage portions of the container. 6. The slime-removing tool according to claim 1, wherein the non-bleachable antibacterial agent is an inclusion compound comprising an antibacterial agent and a multimolecular host compound. 7. The slimming tool according to claim 6, wherein the multimolecular host compound is one or more compounds selected from the following compounds (1) to (25). (1) Tetrakisphenols (2) 1,1,6,6-tetraphenyl-2,4-hexadiyne-1,6-diol (3) 1,6-bis (2-chlorophenyl) -1,6 −
Diphenylhexane-2,4-diyne-1,6-diol (4) 1,1,4,4-tetraphenyl-2-butyne-
1,4-diol (5) 2,5-bis (2,4, dimethylphenyl) hydroquinone (6) 1,1-bis (2,4, dimethylphenyl) -2
-Propyn-1-ol (7) 1,1,2,2-tetraphenylethane-1,2
-Diol (8) 1,1'-bi-2-naphthol (9) 9,10-diphenyl-9,10-dihydroxyanthracene (10) 1,1,6,6-tetra (2,4-dimethylphenyl) -2,4-hexadiyne-1,6-diol (11) 9,10-bis (4-methylphenyl) -9,
10-dihydroxyanthracene (12) 1,1-bis (4-hydroxyphenyl) cyclohexane (13) N, N, N ', N'-tetrakis (cyclohexyl)-(1,1'-biphenyl) -2-2' -Dicarboxamide (14) 4,4'-sulfonylbisphenol (15) 4,4'-butylidenebis (3-methyl-6-
tert-butylphenol) (16) 2,2'-methylenebis (4-methyl-6-t
tert-butylphenol) (17) 4,4'-thiobis (4-chlorophenol) (18) 2,2'-methylenebis (4-chlorophenol) (19) deoxycholic acid (20) cholic acid (21) α, α, α ′, α′-tetraphenyl-1,
1'-biphenyl-2,2'-dimethanol (22) t-butylhydroquinone (23) 2,5-di-tert-butylhydroquinone (24) granular corn starch (25) 1,4-diazabicyclo- (2, 2,2) -octane 8. The method according to claim 8, wherein the non-bleachable antibacterial agent is 5-chloro-2.
The slimming tool according to claim 6 or 7, wherein the tool is -methyl-4-isothiazolin-3-one. 9. The slime-removing device according to claim 1, wherein the non-bleachable antibacterial agent is an organic iodine antibacterial agent. 10. A substrate comprising calcium hydrogen phosphate dihydrate, tricalcium phosphate anhydride, magnesium hydrogen phosphate
Hydrate, magnesium hydrogen phosphate octahydrate, lactose, vanillin, calcium citrate tetrahydrate, calcium sulfate dihydrate, calcium sulfate hemihydrate, acetoacetic anilide, acetoacetate-o-toluidide , Acetoacetic acid-p-
Claims: One or more compounds selected from toluidide, acetoacetic acid-o-anisidide, sorbitol, glycerin monofatty acid ester, alkyl sorbitan ester (HLB14 or less), and sucrose fatty acid ester (HLB14 or less). Item 10. A slimming tool according to any one of Items 1 to 9. 11. The tool according to claim 10, wherein the calcium sulfate hemihydrate is β-type calcium sulfate hemihydrate. 12. The slime-removing device according to claim 1, wherein the slime-controlling composition contains a C ₁₄ -C ₂₄ saturated fatty acid as a dissolution regulator. 13. The C ₁₄ -C ₂₄ saturated fatty acid is stearic acid or lauric acid.
The slime removal tool described.