JP2001032129A - Production of cellulose acetate slub yarn - Google Patents

Production of cellulose acetate slub yarn

Info

Publication number
JP2001032129A
JP2001032129A JP11199044A JP19904499A JP2001032129A JP 2001032129 A JP2001032129 A JP 2001032129A JP 11199044 A JP11199044 A JP 11199044A JP 19904499 A JP19904499 A JP 19904499A JP 2001032129 A JP2001032129 A JP 2001032129A
Authority
JP
Japan
Prior art keywords
take
roller
yarn
cellulose acetate
grooved
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11199044A
Other languages
Japanese (ja)
Inventor
Hiroyuki Kono
裕之 河野
Takeshi Tamura
武志 田村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Rayon Co Ltd
Original Assignee
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd
Priority to JP11199044A priority Critical patent/JP2001032129A/en
Publication of JP2001032129A publication Critical patent/JP2001032129A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To obtain a cellulose acetate slub yarn in high spinning stability while preventing the breakage of yarn on a grooved take-up roll in the production of a cellulose acetate slub yarn using a grooved take-up roll. SOLUTION: A cellulose acetate slub yarn is produced by intermittently varying the take-up speed in the dry spinning of a cellulose acetate fiber using a grooved take-up roll having grooves on a part of the circumferential direction of the roll. The friction coefficient between the surface of the take-up roll and the fiber is set to <=0.5.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、セルロースアセテ
ート太細糸の製造方法に関する。
[0001] The present invention relates to a method for producing a cellulose acetate thick and thin yarn.

【0002】[0002]

【従来の技術】従来より、繊維の長手方向に繊度差のあ
る太細糸については、ポリエステル繊維を中心に数多く
提案されている。一般にポリエステル繊維において繊維
の長手方向に繊度差を形成させるには、ポリエステル未
延伸糸を特定条件下で不完全な延伸を行い、ネッキング
現象を生じせしめることを基本とする技術が用いられ、
数多くの提案があり、かつ実用化されている。
2. Description of the Related Art Conventionally, many thick and thin yarns having a difference in fineness in the longitudinal direction of fibers have been proposed, mainly polyester fibers. Generally, in order to form a difference in fineness in the longitudinal direction of the polyester fiber, a technique based on incompletely stretching a polyester undrawn yarn under specific conditions to cause a necking phenomenon is used,
There are many proposals and they have been put to practical use.

【0003】一方、セルロースアセテート繊維は紡糸原
液を加熱雰囲気中に吐出する乾式紡糸により製造される
ことから、紡糸ノズルから紡糸原液が吐出されると瞬時
に大部分の溶剤が蒸発し、繊維形成がなされるため、ポ
リエステル繊維等のような未延伸糸という中間体は存在
せず、従ってネッキング現象を基本とした技術での太細
糸の製造は困難である。これに対し、セルロースアセテ
ート繊維の乾式紡糸における引き取りローラーを溝付き
引き取りローラーとし、引き取り速度を間欠的に低速化
して太繊度部を形成し糸の長手方向に繊度差のある太細
糸を得る方法が特公平3−9203号公報で提案されて
いる。
[0003] On the other hand, since cellulose acetate fibers are produced by dry spinning in which a spinning dope is discharged into a heated atmosphere, most of the solvent evaporates instantly when the spinning dope is discharged from a spinning nozzle, resulting in fiber formation. Therefore, there is no intermediate such as an undrawn yarn such as polyester fiber, and it is difficult to produce a thick and thin yarn by a technique based on the necking phenomenon. On the other hand, a method in which the take-off roller in dry spinning of cellulose acetate fiber is a grooved take-off roller, the take-off speed is intermittently reduced to form a thick fine portion, and a thick fine yarn having a fineness difference in the longitudinal direction of the yarn is obtained. Has been proposed in Japanese Patent Publication No. 3-9203.

【0004】しかしながら、この方法においては、布帛
としたときに繊細なスラブ状の外観を呈するセルロース
アセテート太細糸が得られるものの、溝付き引き取りロ
ーラー上での糸切れが生じ易く、紡糸安定性に欠けると
いう問題がある。
[0004] However, in this method, although a cellulose acetate thick and thin yarn having a delicate slab-like appearance when obtained as a fabric is obtained, yarn breakage easily occurs on a grooved take-off roller and spinning stability is reduced. There is a problem of chipping.

【0005】[0005]

【発明が解決しようとする課題】本発明の目的は、溝付
き引き取りローラーを用いたセルロースアセテート太細
糸の製造方法における溝付き引き取りローラー上での糸
切れを防止し、セルロースアセテート太細糸を紡糸安定
性よく得ることにある。
SUMMARY OF THE INVENTION It is an object of the present invention to provide a method for producing a cellulose acetate thick and thin thread using a grooved take-off roller, which prevents yarn breakage on the grooved take-off roller and reduces the cellulose acetate thick and thin thread. The object is to obtain good spinning stability.

【0006】[0006]

【課題を解決するための手段】本発明は、セルロースア
セテート繊維の乾式紡糸において、吐出後の引き取りに
当たりローラー円周方向の一部に溝を設けた溝付き引き
取りローラーを用い、引き取り速度を間欠的に変化させ
て太細糸を製造するに際し、引き取りローラー表面の繊
維との摩擦係数を0.5以下とすることを特徴とするセ
ルロースアセテート太細糸の製造方法、にある。
According to the present invention, in dry spinning of cellulose acetate fiber, a take-off roller having a groove in a part of a circumferential direction of the roller is used for taking-out after discharging, and a take-up speed is intermittently controlled. Wherein the coefficient of friction with the fiber on the surface of the take-off roller is adjusted to 0.5 or less when producing a thick and thin yarn.

【0007】[0007]

【発明の実施の形態】一般にセルロースアセテート繊維
の乾式紡糸は、セルロースアセテートフレークをアセト
ン、塩化メチレン/メタノール混合物等の溶剤に溶解し
て紡糸原液を調製し、この紡糸原液を小孔径の紡糸ノズ
ルから加熱空気中に吐出し、溶剤を蒸発させて糸状体を
形成させるとともに、この糸状体を引き取って完全な糸
の形態にする工程をとり、糸の繊度は、紡糸原液濃度が
一定の場合、紡糸原液の吐出量と引き取り速度により決
定される。従い、紡糸原液吐出線速度が一定の場合に
は、引き取り速度が低速のときには太繊度、高速のとき
には細繊度の糸が得られる。
DESCRIPTION OF THE PREFERRED EMBODIMENTS In general, dry spinning of cellulose acetate fibers is performed by dissolving cellulose acetate flakes in a solvent such as acetone, a methylene chloride / methanol mixture or the like to prepare a spinning dope, and spinning the spinning dope from a spinning nozzle having a small pore diameter. It is discharged into heated air to evaporate the solvent to form a filament, and the filament is taken out to form a complete thread. It is determined by the discharge amount of the stock solution and the take-up speed. Accordingly, when the spinning stock solution discharge linear speed is constant, a yarn with a fine fineness can be obtained when the take-up speed is low, and a fine fineness can be obtained when the take-up speed is high.

【0008】本発明においては、乾式紡糸における吐出
後の糸状体の引き取りを、引き取りローラーとしてロー
ラー円周方向の一部に糸状体が落ち込むに十分な溝を設
けた溝付き引き取りローラーを用い、引き取り速度を間
欠的に低速化し、太繊度部を間欠的に形成させて太細糸
を製造するものである。
[0008] In the present invention, the take-off of the filament after ejection in dry spinning is performed by using a take-up roller having a groove provided with a groove sufficient to drop the filament into a part of the circumferential direction of the roller. The speed is reduced intermittently, and a thick fineness portion is formed intermittently to produce a thick and thin yarn.

【0009】本発明におけるセルロースアセテート太細
糸の製造方法を図1及び図2で更に説明すると、図1は
本発明のセルロースアセテート太細糸を具体的に製造す
る装置の例の概略図であり、1は紡糸ノズル、2は加熱
筒、3は油剤付与装置、4はトラバースガイド、5は溝
付き引き取りローラー、6は巻き取り装置を表す。紡糸
での引き取り速度を間欠的にかつランダムに変化させる
には、引き取り速度を高速にする或いは低速にすればよ
いが、製糸安定性の点で低速にする手段を用いることが
好ましい。引き取り速度を低速にするためには、溝付き
引き取りローラーを用いることが好ましく、例えば溝付
き引き取りローラー5として、図2(イは正面図、ロは
側面図)に示すような溝付き引き取りローラーを用い
る。
The method for producing a cellulose acetate thick thread according to the present invention will be further described with reference to FIGS. 1 and 2. FIG. 1 is a schematic view of an example of an apparatus for specifically producing the cellulose acetate thick thread according to the present invention. Reference numeral 1 denotes a spinning nozzle, 2 denotes a heating cylinder, 3 denotes an oil applying device, 4 denotes a traverse guide, 5 denotes a grooved take-up roller, and 6 denotes a winding device. In order to intermittently and randomly change the take-up speed in spinning, the take-up speed may be increased or decreased. However, it is preferable to use a means for decreasing the take-up speed in terms of yarn production stability. In order to reduce the take-up speed, it is preferable to use a grooved take-up roller. For example, as the grooved take-up roller 5, a grooved take-up roller as shown in FIG. 2 (a is a front view, and b is a side view) is shown. Used.

【0010】図2に示す溝付き引き取りローラーは、直
径Dなるローラーの一部円周方向に深さ(D
)なる深さの溝を角度θで設けてなる。図1におけ
るトラバースガイド4は、引き取りローラー5の溝を中
心として左右に移動し得るものであり、トラバースガイ
ド4の移動手段はランダムな周期で往復し得るものであ
れば機械式、電気式等のいずれの方式であってもよい。
[0010] grooved take-up roller shown in FIG. 2, the depth in the portion circumferentially of the diameter D 0 becomes roller of (D 0 -
A groove having a depth of D 1 ) is provided at an angle θ. The traverse guide 4 in FIG. 1 can move left and right around the groove of the take-up roller 5, and the moving means of the traverse guide 4 may be a mechanical type, an electric type, or the like as long as it can reciprocate at a random cycle. Either method may be used.

【0011】図1において、紡糸ノズル1から吐出し、
加熱筒2で脱溶剤されて形成された糸状体は、油剤供給
装置3を経て溝付き引き取りローラー5で引き取られ、
巻き取り装置6で巻き取られるが、溝付き引き取りロー
ラー5での引き取りの際、トラバースガイド4の左右の
移動に対応して、溝付き引き取りローラー5上の糸の位
置が左右にトラバースし、糸が一時的に溝付き引き取り
ローラー5の溝に落ち込んだ状態で引き取られたり、ま
た溝付き引き取りローラー5の溝のない面にある状態で
引き取られたりする動作を生じる。
In FIG. 1, discharge from a spinning nozzle 1 is performed.
The thread formed by removing the solvent in the heating cylinder 2 is taken off by the grooved take-off roller 5 via the oil agent supply device 3,
The yarn is wound by the winding device 6, but when the grooved take-up roller 5 takes up the yarn, the position of the yarn on the grooved take-up roller 5 traverses left and right in accordance with the left and right movement of the traverse guide 4. Is temporarily dropped into the groove of the grooved take-off roller 5 or is taken on a groove-free surface of the grooved take-up roller 5.

【0012】溝付き引き取りローラー5の溝部分での表
面速度は溝のないローラー面の部分よりも低速となるた
め、糸状体が溝に落ち込んでいる間に太繊度糸が形成さ
れることになり、糸状体が溝に落ち込んでいない状態で
は細繊度糸が形成される。また、この溝の深さは、糸の
細繊度部と太繊度部の繊度差と明確に対応し、溝が深く
なるに従い繊度差は大きくなる。従って、溝付き引き取
りローラー5における溝の深さと長さによって繊度差と
太繊度部の長さが設定される。
Since the surface speed of the grooved take-off roller 5 at the groove portion is lower than that at the portion of the roller surface having no groove, a thick fine yarn is formed while the filamentary material falls into the groove. On the other hand, in a state where the thread is not dropped into the groove, a fine yarn is formed. Further, the depth of the groove clearly corresponds to the fineness difference between the fine fineness portion and the thick fineness portion of the yarn, and the fineness difference increases as the groove becomes deeper. Therefore, the fineness difference and the length of the large fineness portion are set according to the depth and length of the groove in the grooved take-off roller 5.

【0013】しかしながら、溝付き引き取りローラー5
の溝が極度に深い場合は、トラバースガイド4の移動に
もかかわらず、一旦糸状体が溝の中に落ちると、溝から
糸を脱出させることが困難となるため、本発明方法の場
合は、溝は引き取りローラー5の全周に亘ることなく、
ローラー面上の溝部の一部は必ず溝のないローラー面と
同一表面をなすようにすることが好ましい。
However, the grooved take-up roller 5
Is extremely deep, it is difficult for the thread to escape from the groove once the thread has fallen into the groove despite the movement of the traverse guide 4, so in the case of the method of the present invention, The groove does not cover the entire circumference of the take-up roller 5,
It is preferable that a part of the groove on the roller surface always forms the same surface as the roller surface having no groove.

【0014】本発明方法においては、溝付き引き取りロ
ーラーの表面の繊維との摩擦係数を0.5以下とするこ
とを必須とする。溝付き引き取りローラーの表面の繊維
との摩擦係数が0.5以下であるときには、溝付き引き
取りローラー上で溝のない面から溝部へ、また溝部から
溝のない面へのトラバースガイドによる糸状体の移動が
極めてスムースに行われ、ローラーへの巻き付きがな
く、巻き付きに起因する糸切れを防止してセルロースア
セテート太細糸を紡糸安定性よく得ることができる。
In the method of the present invention, it is essential that the coefficient of friction between the grooved take-up roller and the fiber on the surface is 0.5 or less. When the coefficient of friction with the fiber on the surface of the grooved take-off roller is 0.5 or less, the thread-like body is traversed on the grooved take-up roller from a groove-free surface to a groove portion and from a groove portion to a groove-free surface by a traverse guide. The movement is extremely smooth, there is no winding around the roller, and the yarn breakage due to the winding can be prevented, and the cellulose acetate thick and thin yarn can be obtained with good spinning stability.

【0015】摩擦係数は、走行速度25m/分、初期張
力(T)13gで、直径40mmの金属面の円柱上に
接触角180°で試料糸を接触走行させたときの走行糸
張力(T)を測定し、次式により算出される。 摩擦係数=(T−T)/(T+T
The coefficient of friction is as follows: the running yarn tension (T 1 ) when the sample yarn was caused to contact and run at a contact angle of 180 ° on a cylinder of a metal surface having a diameter of 40 mm at a running speed of 25 m / min and an initial tension (T 1 ) of 13 g. 2 ) is measured and calculated by the following equation. Coefficient of friction = (T 1 −T 2 ) / (T 1 + T 2 )

【0016】溝付き引き取りローラー表面の摩擦係数が
0.5を超える場合、例えばローラー表面が鏡面加工さ
れているような場合は、引きき取りローラー上での糸の
移動が摩擦抵抗により糸の張力変動が起こり、変動時の
弛みによりローラーへの巻き付きが生じて糸切れが発生
し易くなる。
When the friction coefficient of the grooved take-up roller surface exceeds 0.5, for example, when the roller surface is mirror-finished, the movement of the yarn on the take-up roller is caused by the frictional resistance and the yarn tension. Fluctuation occurs, and loosening at the time of fluctuation causes wrapping around the roller, and yarn breakage easily occurs.

【0017】溝付き引き取りローラー表面の摩擦抵抗を
小さくし繊維との摩擦係数を下げる手段としては、特に
限定はなくフッ素樹脂加工等も用いられるが、0.3以
下の摩擦係数が容易に得られる梨地加工が好ましく用い
られる。また、摩擦係数を下げるローラー表面は、糸が
接触する面で、ローラー表面の溝のない面、溝部の底面
であり、更には溝部側面であることが好ましい。
The means for reducing the frictional resistance of the grooved take-off roller surface and the coefficient of friction with the fiber is not particularly limited, and a fluororesin processing or the like is used, but a friction coefficient of 0.3 or less can be easily obtained. A satin finish is preferably used. The surface of the roller that lowers the coefficient of friction is the surface with which the yarn is in contact, the surface of the roller surface without grooves, the bottom surface of the groove, and more preferably the side surface of the groove.

【0018】[0018]

【実施例】以下、本発明を実施例により具体的に説明す
る。
The present invention will be described below in more detail with reference to examples.

【0019】(実施例1〜3)平均酢化度61.3%の
セルロ−ストリアセテ−トフレークを塩化メチレンとメ
タノールの混合溶剤に溶解し、固形分濃度21.9重量
%に調製した紡糸原液を、乾式紡糸装置にて孔径30μ
m、孔数20個の紡糸ノズルから温度45℃の加熱雰囲
気中に吐出して糸賦型した後、最大深さ53mm、溝部
の角度135°の溝を有し、ローラー表面に表1に示す
各種の表面粗さ(R)の梨地加工を施した直径212
mm、ローラー回転数460rpmの溝付き引き取りロ
ーラーにより、溝付き引き取りローラー上のトラバース
ガイド移動周期(片道)0.15〜1.5秒、引き取り
速度150〜300m/分の条件で引き取り、巻き取っ
て84dtex/20fの太細糸をそれぞれ得た。
(Examples 1 to 3) Cellulose triacetate flakes having an average acetylation degree of 61.3% were dissolved in a mixed solvent of methylene chloride and methanol to prepare a spinning dope having a solid concentration of 21.9% by weight. , Dry spinning device, pore size 30μ
m, after spinning from a spinning nozzle having 20 holes into a heating atmosphere at a temperature of 45 ° C., and forming the yarn, a groove having a maximum depth of 53 mm and a groove angle of 135 ° is provided on the roller surface as shown in Table 1. Diameter 212 with satin finish of various surface roughness (R Z )
mm, a traverse guide moving cycle (one way) on the grooved take-off roller is 0.15 to 1.5 seconds, and a take-up speed is 150 to 300 m / min by a grooved take-off roller having a roller rotation number of 460 rpm. 84 dtex / 20f thick and thin yarns were obtained.

【0020】得られた太細糸は、いずれも糸の状態で長
さが5〜20cm、太さが細繊度部の1.9〜2倍の太
繊度部と平均81.2〜81.7dtexの細繊度部と
を有していた。表1に溝付き引き取りローラー表面の摩
擦係数、糸切れ状況を示したが、いずれも紡糸安定性は
極めて良好であった。
Each of the obtained thick and thin yarns has a length of 5 to 20 cm in the form of a yarn, a thickness of 1.9 to 2 times the thickness of the fine size, and an average of 81.2 to 81.7 dtex. And a fine fineness portion. Table 1 shows the coefficient of friction and the state of thread breakage on the grooved take-off roller surface, and all showed extremely good spinning stability.

【0021】(比較例1)実施例1において、溝付き引
き取りローラーをローラー表面に表1に示す表面粗さ
(R)の鏡面加工を施した溝付き引き取りローラーに
代えた以外は、実施例1と同様にして84dtex/2
0fの太細糸を得た。得られた太細糸は、糸の状態で長
さが5〜20cm、太さが細繊度部の1.9〜2倍の太
繊度部と平均81.2dtexの細繊度部を有してお
り、表1に用いた溝付き引き取りローラー表面の摩擦係
数、糸切れ状況を示したが、糸切れが多く紡糸安定性は
極めて不良であった。
Comparative Example 1 The procedure of Example 1 was repeated, except that the grooved take-off roller was replaced with a grooved take-up roller having a mirror-finished surface roughness (R Z ) shown in Table 1 on the roller surface. 84dtex / 2 as in 1
0f thick thread was obtained. The obtained thick fine yarn has a length of 5 to 20 cm in the state of a thread, a thick fineness portion whose thickness is 1.9 to 2 times the fine fineness portion, and a fine fineness portion with an average of 81.2 dtex. Table 1 shows the coefficient of friction and the state of thread breakage on the surface of the grooved take-off roller used. The thread breakage was large and the spinning stability was extremely poor.

【0022】[0022]

【表1】 [Table 1]

【0023】[0023]

【発明の効果】本発明方法によれば、溝付き引き取りロ
ーラーを用いるセルロースアセテート太細糸の製造にお
いて、溝付き引き取りローラー上での糸切れを防止する
ことができるので、衣料用途に好適なセルロースアセテ
ート太細糸を紡糸安定性よく得ることができ、生産性の
向上に大いに寄与し得るものである。
According to the method of the present invention, in the production of cellulose acetate thick and thin yarn using a grooved take-off roller, thread breakage on the grooved take-off roller can be prevented, so that cellulose suitable for use in clothing can be used. Acetate thick and thin yarn can be obtained with good spinning stability, and can greatly contribute to improvement in productivity.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明のセルロースアセテート太細糸を製造す
る装置の例の概略図である。
FIG. 1 is a schematic view of an example of an apparatus for producing the cellulose acetate thick and thin yarn of the present invention.

【図2】図1における溝付き引き取りローラーの概略図
であって、イは正面図、ロは側面図である。
FIG. 2 is a schematic view of a grooved take-off roller in FIG. 1, wherein A is a front view and B is a side view.

【符号の説明】[Explanation of symbols]

1 紡糸ノズル 2 加熱筒 3 油剤供給装置 4 トラバースガイド 5 溝付き引き取りローラー 6 巻き取り装置 REFERENCE SIGNS LIST 1 spinning nozzle 2 heating cylinder 3 oil supply device 4 traverse guide 5 grooved take-up roller 6 take-up device

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 セルロースアセテート繊維の乾式紡糸に
おいて、吐出後の引き取りに当たりローラー円周方向の
一部に溝を設けた溝付き引き取りローラーを用い、引き
取り速度を間欠的に変化させて太細糸を製造するに際
し、引き取りローラー表面の繊維との摩擦係数を0.5
以下とすることを特徴とするセルロースアセテート太細
糸の製造方法。
Claims: 1. In dry spinning of cellulose acetate fiber, a take-off roller having a groove in a part of a roller circumferential direction is used for taking-out after discharge, and a take-up speed is changed intermittently to form a thick yarn. In manufacturing, the coefficient of friction with the fiber on the surface of the take-off roller is 0.5
A method for producing a cellulose acetate thick and thin yarn, characterized by the following.
JP11199044A 1999-07-13 1999-07-13 Production of cellulose acetate slub yarn Pending JP2001032129A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11199044A JP2001032129A (en) 1999-07-13 1999-07-13 Production of cellulose acetate slub yarn

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11199044A JP2001032129A (en) 1999-07-13 1999-07-13 Production of cellulose acetate slub yarn

Publications (1)

Publication Number Publication Date
JP2001032129A true JP2001032129A (en) 2001-02-06

Family

ID=16401190

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11199044A Pending JP2001032129A (en) 1999-07-13 1999-07-13 Production of cellulose acetate slub yarn

Country Status (1)

Country Link
JP (1) JP2001032129A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008291389A (en) * 2007-05-24 2008-12-04 Mitsubishi Rayon Co Ltd Spinning method for cellulose acetate fiber
CN114635211A (en) * 2020-12-16 2022-06-17 滨州亚光家纺有限公司 Manufacturing method of hollow slub yarn

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008291389A (en) * 2007-05-24 2008-12-04 Mitsubishi Rayon Co Ltd Spinning method for cellulose acetate fiber
CN114635211A (en) * 2020-12-16 2022-06-17 滨州亚光家纺有限公司 Manufacturing method of hollow slub yarn

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