JP2001028390A - Sucking fixing carrying sheet - Google Patents

Sucking fixing carrying sheet

Info

Publication number
JP2001028390A
JP2001028390A JP19955599A JP19955599A JP2001028390A JP 2001028390 A JP2001028390 A JP 2001028390A JP 19955599 A JP19955599 A JP 19955599A JP 19955599 A JP19955599 A JP 19955599A JP 2001028390 A JP2001028390 A JP 2001028390A
Authority
JP
Japan
Prior art keywords
sheet
air permeability
porosity
porous
green sheet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP19955599A
Other languages
Japanese (ja)
Inventor
Takashi Wano
隆司 和野
Junichi Moriyama
順一 森山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nitto Denko Corp
Original Assignee
Nitto Denko Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nitto Denko Corp filed Critical Nitto Denko Corp
Priority to JP19955599A priority Critical patent/JP2001028390A/en
Publication of JP2001028390A publication Critical patent/JP2001028390A/en
Pending legal-status Critical Current

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Landscapes

  • Jigs For Machine Tools (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Laminated Bodies (AREA)
  • Container, Conveyance, Adherence, Positioning, Of Wafer (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a carrying sheet capable of sufficiently responding to a reduction in size and weight in a green sheet, without changing any facilities on the like of a manufacturing process, by using a porous carrying sheet whose surface to be a contact surface with a sheet to be sucked has a porosity and a roughness of respective specific values and moreover whose air permeability as a whole is a specific value. SOLUTION: A porous sheet 2 is used whose surface to be a contact surface with a green sheet 3 of a sheet to be sucked has a porosity of 40% or lower and has a roughness of 1 μm or lower. This prevents the green sheet 3 from coming in the pores in the sheet 2, when the green sheet 3 is sucked because the pores are very small and the occurrence of defects, such as uneven spots or flaws on the surface of the green sheet 3, because the surface of the sheet 2 is smooth. Furthermore, if air permeability in the direction of thickness of a sucking fixing carrying sheet 2 is set at 1 cm3/cm2/sec or lower, it is easy to conduct suction, fixation, and detachment of the green sheet 3 without affecting the cycle time of manufacturing process (time required to suck and detach the green sheet 3).

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、液晶用ガラス板、
半導体ウェハの切断吸着固定等に用いられる、あるいは
積層セラミックコンデンサーのグリーンシートの積層等
に用いられる吸着固定搬送用シートに関するものであ
る。
The present invention relates to a glass plate for a liquid crystal,
The present invention relates to a sheet for fixing and conveying by suction, which is used for cutting and fixing a semiconductor wafer or for stacking green sheets of a multilayer ceramic capacitor.

【0002】[0002]

【従来の技術】積層セラミックコンデンサーの製造工程
におけるグリーンシートの積層に際して、高分子多孔質
シートが吸着固定搬送用部材として採用されている。こ
のグリーンシート積層に際しての上記吸着固定搬送用部
材の使用方法は、例えば、つぎのようなものである。す
なわち、図1に示すように、吸引機1に取り付けた吸着
固定搬送用部材である高分子多孔質シート2を、キャリ
アフィルム4上のグリーンシート3に載置して、矢印方
向に吸引しながらグリーンシート3を吸引機1にて吸着
固定し搬送するというものである。この高分子多孔質シ
ートとしては、通気性、剛性およびクッション性等を考
慮して粘度平均分子量50万以上の超高分子量ポリエチ
レン(以下「UHMWPE」という)からなる多孔質シ
ートを使用することが提案されている(特開平8−16
9971号公報、特開平8−258198号公報、特開
平9−22935号公報参照)。
2. Description of the Related Art When laminating green sheets in a manufacturing process of a multilayer ceramic capacitor, a polymer porous sheet is employed as a member for adsorbing and fixing and conveying. The method of using the suction-fixing / conveying member for laminating the green sheets is, for example, as follows. That is, as shown in FIG. 1, a polymer porous sheet 2 which is a suction-fixing / conveying member attached to a suction device 1 is placed on a green sheet 3 on a carrier film 4, and is sucked in the direction of the arrow. The green sheet 3 is suction-fixed by the suction device 1 and transported. As this polymer porous sheet, it is proposed to use a porous sheet made of ultra-high molecular weight polyethylene having a viscosity average molecular weight of 500,000 or more (hereinafter referred to as "UHMWPE") in consideration of air permeability, rigidity, cushioning property and the like. (Japanese Patent Laid-Open No. 8-16)
9971, JP-A-8-258198, and JP-A-9-22935).

【0003】[0003]

【発明が解決しようとする課題】ところで、近年、上記
積層セラミックコンデンサーは高密度積層となり、これ
に伴いグリーンシート自体の厚みが薄くなって、数μm
タイプのものを積層する技術が必要不可欠となってい
る。このように、グリーンシートの厚みが薄くなり、こ
れに伴いグリーンシートの剛性も低下するためにその取
り扱いが困難となっている。すなわち、グリーンシート
を吸着固定搬送用部材である多孔質シートに吸着固定さ
せるときに多孔質シートの孔のなかに上記グリーンシー
トがもぐり込む等して、薄層のグリーンシートに凹凸や
傷等の欠陥が生じ、不良を招く要因となっている。
In recent years, the above-mentioned multilayer ceramic capacitor has become a high-density laminate, and accordingly the thickness of the green sheet itself has been reduced to several μm.
The technology of laminating types is indispensable. As described above, the thickness of the green sheet is reduced, and accordingly, the rigidity of the green sheet is reduced, so that it is difficult to handle the green sheet. That is, when the green sheet is adsorbed and fixed to the porous sheet serving as the adsorbing / fixing / transporting member, the above-mentioned green sheet penetrates into the holes of the porous sheet, and the thin green sheet has defects such as irregularities and scratches. Occurs, which is a factor of causing defects.

【0004】このような点から、従来から用いられてい
るUHMWPE製の多孔質シートからなる吸着固定搬送
用シートに関して、小さな孔径の多孔質体を用いること
によって上記問題に対応しようとしているが、下記のよ
うな問題があった。すなわち、上記小孔径の多孔質シー
トでは一般に通気性が低下するために、製造工程のタク
ト(グリーンシートの吸引、放出にかかる時間)が長く
なる、あるいはグリーンシートを吸着できない等の問題
がある。
[0004] From such a point, it has been attempted to address the above-mentioned problem by using a porous body having a small hole diameter with respect to a conventionally used adsorption-fixing / conveying sheet made of a porous sheet made of UHMWPE. There was such a problem. That is, the porous sheet having the small pore size generally has a problem that the air permeability is reduced, so that the tact time (time required for sucking and releasing the green sheet) in the manufacturing process becomes longer, or the green sheet cannot be adsorbed.

【0005】本発明は、このような事情に鑑みなされた
もので、従来からの製造工程の設備等をなんら変更する
ことなく、しかもグリーンシートの軽薄化にも充分対応
可能な吸着固定搬送用シートの提供をその目的とする。
SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned circumstances, and does not require any change in the conventional manufacturing process equipment and the like, and can sufficiently cope with the reduction of the thickness of the green sheet. The purpose is to provide.

【0006】[0006]

【課題を解決するための手段】上記の目的を達成するた
め、本発明の吸着固定搬送用シートは、下記の(A)お
よび(B)を備えた多孔質シートが被吸着部材との接触
面部を構成するようになっている吸着固定搬送用シート
であって、上記吸着固定搬送用シート全体の厚み方向の
通気度が1cm3 /cm2 /sec以上であるという構
成をとる。 (A)表面の開孔率が40%以下。 (B)表面粗さ(Ra)が1μm以下。
In order to achieve the above-mentioned object, the present invention provides a suction-fixing and conveying sheet comprising a porous sheet having the following (A) and (B): Wherein the air permeability in the thickness direction of the entire suction-fixed and conveyed sheet is 1 cm 3 / cm 2 / sec or more. (A) The porosity of the surface is 40% or less. (B) The surface roughness (Ra) is 1 μm or less.

【0007】すなわち、本発明者らは、従来からの製造
工程等を変更させることなく、薄厚のグリーンシートの
吸着固定搬送用部材として問題なく使用することのでき
る搬送用シートを得るために一連の研究を重ねた。その
結果、被吸着部材であるグリーンシートとの接触面部と
なる表面の開孔率が40%以下で、かつその表面粗さ
(Ra)が1μm以下の多孔質シートを用いると、グリ
ーンシート吸着時に孔径が微細なためグリーンシートが
もぐり込むことなく、また表面が平滑であるためにグリ
ーンシート表面に凹凸や傷等の欠陥が発生することがな
くなることを突き止めた。さらに、吸着固定搬送用シー
ト全体の厚み方向の通気度を1cm3 /cm2 /sec
以上に設定することにより、製造工程のタクト(グリー
ンシートの吸引、放出にかかる時間)に影響を与えるこ
となく吸着・固定・脱着が容易に行えることを見出し本
発明に到達した。
That is, the present inventors have made a series of attempts to obtain a transfer sheet which can be used as a member for adsorbing and fixing a thin green sheet without any change without changing the conventional manufacturing process. Repeated research. As a result, when a porous sheet having a porosity of 40% or less and a surface roughness (Ra) of 1 μm or less is used as a contact surface portion with a green sheet as a member to be sucked, when a green sheet is adsorbed, It has been found that the green sheet does not penetrate due to the fine pore size, and that the surface of the green sheet is free from defects such as irregularities and scratches due to its smooth surface. Furthermore, the air permeability in the thickness direction of the entire sheet for adsorption and fixing is set to 1 cm 3 / cm 2 / sec.
By setting as described above, it has been found that adsorption, fixing, and desorption can be easily performed without affecting the tact (time required for sucking and releasing the green sheet) in the manufacturing process, and reached the present invention.

【0008】さらに、上記多孔質シートの、被吸着部材
との接触面とは他面側に補強用となる他の多孔質シート
を積層した場合、良好な表面平滑性と通気性とともに、
吸着固定搬送用途として充分な高強度を確保することが
容易となる。
Further, when another porous sheet for reinforcement is laminated on the other surface side of the above-mentioned porous sheet from the contact surface with the member to be adsorbed, good surface smoothness and air permeability are obtained.
It is easy to secure a sufficiently high strength for suction fixed conveyance.

【0009】[0009]

【発明の実施の形態】つぎに、本発明の実施の形態につ
いて詳しく説明する。
Next, an embodiment of the present invention will be described in detail.

【0010】本発明の吸着固定搬送用シートは、被吸着
部材との接触面部となる表面の開孔率、表面粗さ(R
a)が特定の値を有する多孔質シートを用いて得られる
ものであり、しかも吸着固定搬送用シート全体の通気度
が特定の値を有するものである。なお、本発明の吸着固
定搬送用シートでは、前記(A)および(B)を備えた
多孔質シートが吸着固定搬送用シート全体を構成しても
よいし、この多孔質シートにさらに他の多孔質シートを
積層した多層構造であってもよい。
[0010] The sheet for suction and fixed conveyance according to the present invention has a porosity and a surface roughness (R) of a surface which is a contact surface portion with a member to be sucked.
a) is obtained by using a porous sheet having a specific value, and the air permeability of the entire sheet for adsorption and fixing has a specific value. In the adsorption-fixing / conveying sheet of the present invention, the porous sheet provided with the above (A) and (B) may constitute the entire adsorption-fixing / conveying sheet, or the porous sheet may further include another porous sheet. It may have a multilayer structure in which porous sheets are laminated.

【0011】上記多孔質シートの形成材料としては、特
に限定するものではないが、なかでも、耐摩耗性、耐衝
撃性、低摩擦係数という点からUHMWPEを用いるこ
とが好ましい。上記UHMWPEは、一般のポリエチレ
ン分子量(粘度法による測定値)が約10万以下である
のに対し、約50万以上の高分子量を示す点が特徴であ
る。
The material for forming the porous sheet is not particularly limited, but among them, UHMWPE is preferably used in terms of abrasion resistance, impact resistance, and low coefficient of friction. The UHMWPE is characterized in that it has a high molecular weight of about 500,000 or more, while the general polyethylene molecular weight (measured by a viscosity method) is about 100,000 or less.

【0012】そして、例えば、上記UHMWPEを用い
て多孔質シートを得るにおいて、特に焼結多孔質体で
は、その粒子径、粒子形状は重要な要因であり、またい
かに高密度に焼結させるかということもシートの孔径の
大きさに影響する。しかし、いずれの方法においても孔
径を小さくすることは、低気孔率、低通気性という特性
のシートしか得ることができない。一方、強度という点
では、低気孔率の方が適していると考えられるが、前述
のように、製造工程のタクトに影響し、かつスムーズに
グリーンシートを吸脱着させるには、適度な通気性が必
要となる。このような点から、本発明者らは、研究を重
ねた結果、シート全体の厚み方向の通気度の点で下記の
ような設定が必要であることを突き止めたのである。す
なわち、前記特定の多孔質シートが被吸着部材との接触
面を構成する吸着固定搬送用シート全体の厚み方向の通
気度が、1cm3 /cm2 /sec以上でなければなら
ず、特に好ましくは1.5cm3 /cm2 /sec以上
となる。そして、吸着固定搬送用シートとしての剛性を
有していれば通気度は高くても問題はないが、通常、3
0cm3 /cm2 /secが上限である。このように、
吸着固定搬送用シート全体の厚み方向の通気度を上記値
に設定するには、多孔質シートの気孔率を調整すること
により適宜に設定することができ、例えば、気孔率を2
0〜60%の範囲内、好ましくは30〜50%の範囲に
設定することにより調整することができる。
[0012] For example, in obtaining a porous sheet using the above UHMWPE, especially in a sintered porous body, its particle diameter and particle shape are important factors, and how to perform high density sintering. This also affects the size of the hole diameter of the sheet. However, in any of the methods, reducing the pore diameter can only obtain a sheet having characteristics of low porosity and low air permeability. On the other hand, in terms of strength, a low porosity is considered to be more suitable, but as mentioned above, it has an appropriate air permeability to affect the tact of the manufacturing process and to smoothly absorb and desorb the green sheet. Is required. From such a point, the present inventors have conducted studies and found that the following setting is necessary in terms of the air permeability in the thickness direction of the entire sheet. That is, the air permeability in the thickness direction of the entire suction-fixing and conveying sheet, in which the specific porous sheet forms a contact surface with the member to be sucked, must be 1 cm 3 / cm 2 / sec or more, and particularly preferably. 1.5 cm 3 / cm 2 / sec or more. Although there is no problem even if the air permeability is high as long as the sheet has the rigidity as the suction-fixing and conveying sheet, it is usually 3
0 cm 3 / cm 2 / sec is the upper limit. in this way,
In order to set the air permeability in the thickness direction of the entire sheet for adsorption and fixing to the above value, the air permeability can be appropriately set by adjusting the porosity of the porous sheet.
It can be adjusted by setting it in the range of 0 to 60%, preferably in the range of 30 to 50%.

【0013】本発明の吸着固定搬送用シートは、例え
ば、つぎのようにして得ることができる。すなわち、多
孔質シート形成材料として上記UHMWPEを用いた場
合は、まず、所定条件にて焼結多孔質体を作製する。つ
ぎに、この焼結多孔質体からシート状体を作製する。そ
して、上記シート状体に表面が平滑な材料を載置し、加
熱・加圧することにより、その表面の表面粗さ(Ra)
が所定の値となる表面が平滑なシート状体である吸着固
定搬送用シートを得ることができる。
[0013] The sheet for suction and fixed conveyance of the present invention can be obtained, for example, as follows. That is, when the above-described UHMWPE is used as a porous sheet forming material, first, a sintered porous body is prepared under predetermined conditions. Next, a sheet is produced from the sintered porous body. Then, a material having a smooth surface is placed on the sheet-like body and heated and pressurized so that the surface roughness (Ra) of the surface is increased.
Can be obtained as a sheet having a predetermined value.

【0014】上記焼結多孔質体の作製に関しては、所望
の気孔率、通気度および孔径を有するシート状体を得る
ことができる条件に適宜に設定される。その一例として
は、所望の大きさの少なくとも一つ以上の穴が形成され
た金型に、樹脂粉末を充填し、それを耐圧容器に入れ、
容器の中に水蒸気を封入して加温し、焼結多孔質体を作
製する。つぎに、この焼結多孔質体をさらに切削旋盤に
て切削することにより所望のシート状体を得ることがで
きる。
The preparation of the sintered porous body is appropriately set so that a sheet having a desired porosity, air permeability and pore size can be obtained. As an example, a mold in which at least one or more holes of a desired size are formed is filled with resin powder, and then put into a pressure-resistant container,
Water vapor is sealed in a container and heated to produce a sintered porous body. Next, the desired porous body can be obtained by further cutting the sintered porous body with a cutting lathe.

【0015】また、上記シート状体に載置する表面が平
滑な材料としては、特に限定するものではないが、例え
ば、ポリエチレンテレフタレートシート等の表面が平滑
な高分子シート、ステンレス材等の金属シート等があげ
られる。そして、表面が平滑な材料を載置しての加熱・
加圧条件は、特に限定するものではないが、例えば、温
度は120〜150℃、圧力は10g/cm2 〜100
kg/cm2 の範囲に設定することができる。
The material to be placed on the sheet is not particularly limited. For example, a polymer sheet having a smooth surface, such as a polyethylene terephthalate sheet, or a metal sheet, such as a stainless material, may be used. And the like. Then, heating and placing a material with a smooth surface
The pressing conditions are not particularly limited. For example, the temperature is 120 to 150 ° C., and the pressure is 10 g / cm 2 to 100.
It can be set in the range of kg / cm 2 .

【0016】このようにして得られる吸着固定搬送用シ
ートとしては、表面の開孔率が40%以下で、かつその
表面粗さ(Ra)が1μm以下でなければならない。な
お、表面粗さ(Ra)は0.1〜1μmが好ましく、特
に好ましくは表面粗さ(Ra)0.1〜0.5μmであ
る。すなわち、表面の開孔率が40%を超えると、吸着
固定時に吸着固定搬送用シートの穴にグリーンシートが
もぐり込んで凹凸状になるためグリーンシートの積層が
困難となったり、所定厚みの積層グリーンシートが得ら
れ難いという問題が生じるからである。さらに、表面粗
さが1μmを超えると、グリーンシート表面にダメージ
を与え欠陥を生じるからである。
The sheet for adsorption and fixing obtained in this manner must have a surface porosity of 40% or less and a surface roughness (Ra) of 1 μm or less. The surface roughness (Ra) is preferably from 0.1 to 1 μm, particularly preferably from 0.1 to 0.5 μm. That is, when the opening ratio of the surface exceeds 40%, the green sheet penetrates into the hole of the sheet for suction fixing and transporting during suction fixing and becomes uneven, so that lamination of the green sheet becomes difficult, or the laminated green sheet having a predetermined thickness is formed. This is because there is a problem that it is difficult to obtain a sheet. Further, if the surface roughness exceeds 1 μm, the surface of the green sheet is damaged and defects are generated.

【0017】そして、上記吸着固定搬送用シート全体の
厚み方向の通気度は、先に述べたように、1cm3 /c
2 /sec以上でなければならない。このように、シ
ート全体の厚み方向の通気度を上記値に設定するには、
多孔質シートの気孔率を所定の値、例えば、20〜60
%の範囲に設定することで調整することができる。上記
通気度が1cm3 /cm2 /sec未満のように小さ過
ぎると、製造工程のタクトに影響し、かつスムーズにグ
リーンシートを吸脱着させることが困難となる。
The air permeability in the thickness direction of the whole sheet for suction and fixing conveyance is 1 cm 3 / c as described above.
m 2 / sec or more. Thus, in order to set the air permeability in the thickness direction of the entire sheet to the above value,
The porosity of the porous sheet is set to a predetermined value, for example, 20 to 60.
It can be adjusted by setting it in the range of%. If the air permeability is too small, such as less than 1 cm 3 / cm 2 / sec, it will affect the tact time of the manufacturing process and make it difficult to smoothly adsorb and desorb the green sheet.

【0018】上記通気度に関係して、例えば、吸着固定
搬送用シートの気孔率は20〜60%の範囲に設定する
ことが好ましく、特に好ましくは30〜50%である。
Regarding the air permeability, for example, the porosity of the sheet for adsorption and fixing is preferably set in the range of 20 to 60%, particularly preferably 30 to 50%.

【0019】上記シート表面の開孔率は、例えば、つぎ
のようにして測定し算出することができる。すなわち、
走査型電子顕微鏡を用いてシートの表面を写真撮影する
(倍率20〜300倍)。そして、この写真をスキャナ
ーで読み込み、孔部と非孔部を2値化し、画像解析ソフ
ト(V10)(旭化成社製)を用いて開孔率を算出する
ことができる。
The porosity of the sheet surface can be measured and calculated as follows, for example. That is,
The surface of the sheet is photographed using a scanning electron microscope (magnification: 20 to 300 times). Then, the photograph is read by a scanner, the hole and the non-hole are binarized, and the aperture ratio can be calculated using image analysis software (V10) (manufactured by Asahi Kasei Corporation).

【0020】上記シート表面の表面粗さ(Ra)は、例
えば、つぎのようにして測定することができる。すなわ
ち、東京精密社製のサーフコム550A表面粗さ計を用
いて測定することができる。なお、この場合の測定条件
は、触針径250μmR、カットオフ値0.8、移動速
度0.3mm/秒、測定長4mmとする。
The surface roughness (Ra) of the sheet surface can be measured, for example, as follows. That is, it can be measured using a Surfcom 550A surface roughness meter manufactured by Tokyo Seimitsu Co., Ltd. The measurement conditions in this case are a stylus diameter of 250 μmR, a cutoff value of 0.8, a moving speed of 0.3 mm / sec, and a measurement length of 4 mm.

【0021】さらに、上記通気度に関しては、JIS
L 1096A法に準じ、フラジール試験機(TOYO
SEIKI社製)を用いて測定することができる。
Further, regarding the above-mentioned air permeability, JIS
L 1096A method, Frazier tester (TOYO
(Manufactured by SEIKI Co., Ltd.).

【0022】そして、シート全体の厚み方向の通気度を
上記所定の値に設定する場合には、前述のように、多孔
質シートの気孔率を調整することにより適宜に設定する
ことができるが、より好ましい態様として、上記のよう
にして作製した多孔質シート(シート状体)に、通気度
の高い他の多孔質体を積層させる方法があげられる。な
お、上記多孔質シートに、通気度の高い他の多孔質シー
トを積層させる際には、当然、上記多孔質シートの被吸
着部材との接触面とは他面側に積層させる必要がある。
このように多孔質シートに高通気度の他の多孔質シート
を積層することにより、上記多孔質シート表面は所定の
表面平滑性と孔径を有するとともに、シート全体として
は所定の通気度を有するようになり、しかも吸着固定搬
送用の用途として充分な高強度を確保することが容易と
なる。このような態様における上記通気度の高い多孔質
シートとしては、特に限定するものではないが、例え
ば、UHMWPEを用いた場合、このUHMWPEの特
徴である高粘度により、融点近傍での積層によっても多
孔質シートの孔が閉塞することなく融着させることがで
き好ましい。
When the air permeability in the thickness direction of the entire sheet is set to the above-mentioned predetermined value, it can be appropriately set by adjusting the porosity of the porous sheet as described above. As a more preferred embodiment, there is a method in which another porous body having high air permeability is laminated on the porous sheet (sheet-like body) produced as described above. When another porous sheet having high air permeability is laminated on the porous sheet, it is naturally necessary to laminate the porous sheet on the other surface side from the contact surface of the porous sheet with the member to be sucked.
By laminating another porous sheet with high air permeability on the porous sheet in this way, the surface of the porous sheet has a predetermined surface smoothness and a pore size, and the entire sheet has a predetermined air permeability. In addition, it is easy to secure a sufficiently high strength for use for suction fixed conveyance. The porous sheet having a high air permeability in such an embodiment is not particularly limited. For example, when UHMWPE is used, the porous sheet can be porous even by lamination near the melting point due to the high viscosity characteristic of this UHMWPE. It is preferable because it can be fused without closing the holes of the porous sheet.

【0023】上記多孔質シートの被吸着部材との接触面
とは他面側に他の多孔質体を積層させる方法としては、
例えば、両者ともUHMWPEを用いた場合は、温度1
30〜150℃、圧力1〜100kg/cm2 の条件で
1分〜12時間加熱・加圧する方法があげられる。
A method for laminating another porous body on the other surface side of the porous sheet from the contact surface with the member to be adsorbed is as follows.
For example, when both use UHMWPE, the temperature is 1
A method of heating and pressurizing at 30 to 150 ° C. under a pressure of 1 to 100 kg / cm 2 for 1 minute to 12 hours is exemplified.

【0024】つぎに、実施例について比較例と併せて説
明する。
Next, examples will be described together with comparative examples.

【0025】(1)単層タイプ(多孔質シートのみ)(1) Single layer type (porous sheet only)

【実施例1】内径500mm×高さ1000mmの金型
にUHMWPE粉末(分子量250万、融点136℃、
平均粒径40μm)を充填し、これを金属製耐圧容器に
入れ、容器内を30mmHgまで減圧した。この後、水
蒸気を導入し温度160℃×6気圧で5時間加熱した
後、徐冷して円柱状の焼結多孔質体を作製した。これ
を、旋盤にて切削し、厚み0.3mm、気孔率30%、
通気度10cm3 /cm2/sec、孔径30μmの白
色シートを得た。
EXAMPLE 1 UHMWPE powder (molecular weight 2.5 million, melting point 136 ° C.,
(Average particle size: 40 μm), and this was placed in a metal pressure-resistant container, and the pressure in the container was reduced to 30 mmHg. Thereafter, steam was introduced and heated at a temperature of 160 ° C. × 6 atm for 5 hours, and then gradually cooled to produce a columnar sintered porous body. This was cut with a lathe, thickness 0.3mm, porosity 30%,
A white sheet having an air permeability of 10 cm 3 / cm 2 / sec and a pore size of 30 μm was obtained.

【0026】つぎに、この白色シートの上面に、厚み
0.25mmのポリエチレンテレフタレート(PET)
シートを載置し、温度140℃、圧力50g/cm2
条件で1時間加熱・加圧することにより、PETシート
載置面の表面粗さ(Ra)が0.6μm、通気度5cm
3 /cm2 /secのシートを得た。
Next, a polyethylene terephthalate (PET) having a thickness of 0.25 mm is formed on the upper surface of the white sheet.
The sheet is placed and heated and pressurized for 1 hour at a temperature of 140 ° C. and a pressure of 50 g / cm 2 , so that the surface roughness (Ra) of the PET sheet placement surface is 0.6 μm and the air permeability is 5 cm.
A sheet of 3 / cm 2 / sec was obtained.

【0027】[0027]

【実施例2】内径500mm×高さ1000mmの金型
にUHMWPE粉末(分子量250万、融点136℃、
平均粒径40μm)を充填し、これを金属製耐圧容器に
入れ、容器内を30mmHgまで減圧した。この後、水
蒸気を導入し温度170℃×6気圧で12時間加熱した
後、徐冷して円柱状の焼結多孔質体を作製した。これ
を、旋盤にて切削し、厚み0.2mm、気孔率25%、
通気度6cm3 /cm2/sec、孔径10μmの白色
シートを得た。
Example 2 A UHMWPE powder (molecular weight 2.5 million, melting point 136 ° C.,
(Average particle size: 40 μm), and this was placed in a metal pressure-resistant container, and the pressure in the container was reduced to 30 mmHg. Thereafter, steam was introduced and heated at a temperature of 170 ° C. × 6 atm for 12 hours, and then gradually cooled to produce a columnar sintered porous body. This was cut with a lathe, thickness 0.2mm, porosity 25%,
A white sheet having an air permeability of 6 cm 3 / cm 2 / sec and a pore size of 10 μm was obtained.

【0028】つぎに、この白色シートの上面に、厚み
0.25mmのPETシートを載置し、温度130℃、
圧力20g/cm2 の条件で1時間加熱・加圧すること
により、PETシート載置面の表面粗さ(Ra)が1.
0μm、通気度2cm3 /cm 2 /secのシートを得
た。
Next, on the upper surface of the white sheet,
Place a 0.25 mm PET sheet, temperature 130 ° C,
Pressure 20g / cmTwoHeat and pressurize for 1 hour under the conditions of
As a result, the surface roughness (Ra) of the PET sheet mounting surface is 1.
0 μm, air permeability 2 cmThree/ Cm Two/ Sec sheet
Was.

【0029】[0029]

【実施例3】内径500mm×高さ1000mmの金型
にUHMWPE粉末(分子量250万、融点136℃、
平均粒径150μm)を充填し、これを金属製耐圧容器
に入れ、容器内を30mmHgまで減圧した。この後、
水蒸気を導入し温度140℃×4気圧で12時間加熱し
た後、徐冷して円柱状の焼結多孔質体を作製した。これ
を、旋盤にて切削し、厚み0.2mm、気孔率45%、
通気度20cm3 /cm2 /sec、孔径100μmの
白色シートを得た。
Example 3 UHMWPE powder (molecular weight 2.5 million, melting point 136 ° C.,
(Average particle size: 150 μm), which was placed in a metal pressure-resistant container, and the pressure in the container was reduced to 30 mmHg. After this,
After steam was introduced and heated at a temperature of 140 ° C. × 4 atm for 12 hours, it was gradually cooled to produce a cylindrical sintered porous body. This was cut with a lathe, thickness 0.2mm, porosity 45%,
A white sheet having an air permeability of 20 cm 3 / cm 2 / sec and a pore size of 100 μm was obtained.

【0030】つぎに、この白色シートの上面に、厚み
0.25mmのPETシートを載置し、温度140℃、
圧力50g/cm2 の条件で1時間加熱・加圧すること
により、PETシート載置面の表面粗さ(Ra)が1.
0μm、通気度15cm3 /cm2 /secのシートを
得た。
Next, a PET sheet having a thickness of 0.25 mm was placed on the upper surface of the white sheet.
By heating and pressurizing for 1 hour under the condition of a pressure of 50 g / cm 2 , the surface roughness (Ra) of the PET sheet mounting surface becomes 1.
A sheet having 0 μm and air permeability of 15 cm 3 / cm 2 / sec was obtained.

【0031】(2)積層タイプ(2) Laminated type

【実施例4】実施例1で用いたUHMWPE粉末に代え
て、平均粒径170μm、分子量500万のUHMWP
E粉末を用い、実施例1と同様にして、厚み1.5m
m、気孔率35%、通気度4cm3 /cm2 /sec、
孔径200μmのシートを得た。
Example 4 Instead of the UHMWPE powder used in Example 1, UHMWWP having an average particle size of 170 μm and a molecular weight of 5,000,000 was used.
Using E powder, as in Example 1, thickness 1.5 m
m, porosity 35%, air permeability 4 cm 3 / cm 2 / sec,
A sheet having a pore size of 200 μm was obtained.

【0032】つぎに、上記得られたシートと、前記実施
例1の加圧処理前の白色シートを重ね合わせ、小孔径の
シート(白色シート)側の表面に厚み0.25mmのP
ETシートを載置し、50g/cm2 の荷重をかけて1
40℃の乾燥機内で1時間加熱処理を行うことにより、
総厚み1.8mmの積層多孔質シートを得た。得られた
シート全体の通気度は、1.5cm3 /cm2 /sec
で、気孔率30%、小孔径側の表面粗さ(Ra)は0.
6μmであった。
Next, the above-obtained sheet and the white sheet before the pressure treatment in Example 1 were overlapped, and a 0.25 mm thick P
Place an ET sheet and apply a load of 50 g / cm 2 to
By performing a heat treatment in a dryer at 40 ° C. for 1 hour,
A laminated porous sheet having a total thickness of 1.8 mm was obtained. The air permeability of the entire obtained sheet is 1.5 cm 3 / cm 2 / sec
The porosity is 30%, and the surface roughness (Ra) on the small pore diameter side is 0.1.
It was 6 μm.

【0033】[0033]

【実施例5】実施例1で用いたUHMWPE粉末に代え
て、平均粒径170μm、分子量500万のUHMWP
E粉末を用い、実施例1と同様にして、厚み4mm、気
孔率45%、通気度5cm3 /cm2 /sec、孔径2
00μmのシートを得た。
Example 5 UHMWWP having an average particle size of 170 μm and a molecular weight of 5,000,000 was used in place of the UHMWPE powder used in Example 1.
Using E powder, as in Example 1, thickness 4 mm, porosity 45%, air permeability 5 cm 3 / cm 2 / sec, pore size 2
A sheet of 00 μm was obtained.

【0034】つぎに、上記得られたシートと、前記実施
例3の加圧処理前の白色シート(孔径100μm)を重
ね合わせ、小孔径のシート(白色シート)側の表面に厚
み0.25mmのポリエチレンシート(PET)を載置
し、50g/cm2 の荷重をかけて140℃の乾燥機内
で1時間加熱処理を行うことにより、総厚み4.2mm
の積層多孔質シートを得た。得られたシート全体の通気
度は、2cm3 /cm 2 /secで、気孔率40%、小
孔径側の表面粗さ(Ra)は1.0μmであった。
Next, the sheet obtained above and
The white sheet (pore diameter 100 μm) before the pressure treatment of Example 3 was weighed.
Thickness is applied to the surface of the small-diameter sheet (white sheet) side
Place a 0.25mm polyethylene sheet (PET)
And 50g / cmTwoWith a load of 140 ° C in the dryer
By heating for 1 hour at a total thickness of 4.2 mm
Was obtained. Ventilation of the entire sheet obtained
The degree is 2cmThree/ Cm Two/ Sec, porosity 40%, small
The surface roughness (Ra) on the pore diameter side was 1.0 μm.

【0035】[0035]

【実施例6】実施例1で用いたUHMWPE粉末に代え
て、平均粒径140μm、分子量400万のUHMWP
E粉末を用い、実施例1と同様にして、厚み1.8m
m、気孔率38%、通気度2cm3 /cm2 /sec、
孔径100μmのシートを得た。
Example 6 Instead of the UHMWPE powder used in Example 1, UHMWWP having an average particle size of 140 μm and a molecular weight of 4,000,000 was used.
1.8 m in thickness in the same manner as in Example 1 using E powder
m, porosity 38%, air permeability 2 cm 3 / cm 2 / sec,
A sheet having a pore size of 100 μm was obtained.

【0036】つぎに、上記得られたシートと、前記実施
例2の加圧処理前の白色シート(孔径10μm)を重ね
合わせ、小孔径のシート(白色シート)側の表面に厚み
0.25mmのポリエチレンシート(PET)を載置
し、50g/cm2 の荷重をかけて140℃の乾燥機内
で1時間加熱処理を行うことにより、総厚み2mmの積
層多孔質シートを得た。得られたシート全体の通気度
は、1.0cm3 /cm2/secで、気孔率30%、
小孔径側の表面粗さ(Ra)は0.6μmであった。
Next, the above-obtained sheet and the white sheet (pore size: 10 μm) before the pressure treatment in Example 2 were superimposed, and a 0.25 mm-thick sheet was placed on the surface of the sheet (white sheet) having a small hole diameter. A polyethylene sheet (PET) was placed and subjected to heat treatment in a dryer at 140 ° C. for 1 hour under a load of 50 g / cm 2 to obtain a laminated porous sheet having a total thickness of 2 mm. The air permeability of the entire sheet obtained was 1.0 cm 3 / cm 2 / sec, the porosity was 30%,
The surface roughness (Ra) on the small diameter side was 0.6 μm.

【0037】[0037]

【比較例1】上記実施例1と同様にして円柱状焼結体を
作製して旋盤にて切削することにより、厚み0.3m
m、気孔率30%、通気度10cm3 /cm2 /se
c、孔径30μm、表面粗さ(Ra)3μmの白色シー
トを得た。
[Comparative Example 1] A columnar sintered body was prepared in the same manner as in Example 1 and cut by a lathe to obtain a thickness of 0.3 m.
m, porosity 30%, air permeability 10 cm 3 / cm 2 / se
c, a white sheet having a pore size of 30 μm and a surface roughness (Ra) of 3 μm was obtained.

【0038】[0038]

【比較例2】UHMWPE粉末(分子量500万、融点
136℃、平均粒径170μm)を用い、上記実施例1
と同様にして円柱状焼結体を作製して旋盤にて切削する
ことにより、厚み1.8mm、気孔率35%、通気度3
cm3 /cm2 /sec、孔径200μmの白色シート
を得た。
Comparative Example 2 The above Example 1 was prepared using UHMWPE powder (molecular weight: 5,000,000, melting point: 136 ° C., average particle size: 170 μm).
A cylindrical sintered body was prepared in the same manner as described above, and was cut with a lathe to obtain a thickness of 1.8 mm, a porosity of 35%, and a permeability of 3
A white sheet having a size of cm 3 / cm 2 / sec and a pore size of 200 μm was obtained.

【0039】つぎに、この白色シートの上面に、厚み
0.25mmのPETシートを載置し、上記実施例1と
同様にして加熱加圧することにより、PETシート載置
面の表面粗さ(Ra)が1.0μm、気孔率35%、通
気度3cm3 /cm2 /secのシートを得た。
Next, a PET sheet having a thickness of 0.25 mm was placed on the upper surface of the white sheet, and heated and pressed in the same manner as in Example 1 to obtain a surface roughness (Ra) of the PET sheet placing surface. ) Of 1.0 μm, a porosity of 35%, and an air permeability of 3 cm 3 / cm 2 / sec.

【0040】[0040]

【比較例3】上記実施例1と同様にして円柱状の焼結多
孔質体を作製して旋盤にて切削することにより、厚み
1.8mm、気孔率30%、通気度0.3cm3 /cm
2 /sec、孔径30μmの白色シートを得た。
Comparative Example 3 A columnar sintered porous body was prepared in the same manner as in Example 1 and cut by a lathe to obtain a thickness of 1.8 mm, a porosity of 30%, and a permeability of 0.3 cm 3 /. cm
A white sheet having a pore size of 30 μm was obtained in 2 / sec.

【0041】つぎに、この白色シートの上面に、厚み
0.25mmのPETシートを載置し、上記実施例1と
同様にして加熱加圧することにより、PETシート載置
面の表面粗さ(Ra)が0.6μm、気孔率30%、通
気度0.3cm3 /cm2 /secのシートを得た。
Next, a PET sheet having a thickness of 0.25 mm was placed on the upper surface of the white sheet, and heated and pressed in the same manner as in Example 1 to obtain a surface roughness (Ra) of the PET sheet placing surface. ) Of 0.6 μm, a porosity of 30%, and an air permeability of 0.3 cm 3 / cm 2 / sec.

【0042】[0042]

【比較例4】UHMWPE粉末(分子量400万、融点
136℃、平均粒径150μm)を用い、上記実施例1
と同様にして円柱状焼結体を作製して旋盤にて切削する
ことにより、厚み0.3mm、気孔率38%、通気度
1.5cm3 /cm2 /sec、孔径100μmの白色
シートを得た。
Comparative Example 4 The above Example 1 was prepared using UHMWPE powder (molecular weight: 4,000,000, melting point: 136 ° C., average particle size: 150 μm).
A white sheet having a thickness of 0.3 mm, a porosity of 38%, a porosity of 1.5 cm 3 / cm 2 / sec, and a pore diameter of 100 μm was obtained by producing a columnar sintered body in the same manner as described above and cutting it with a lathe. Was.

【0043】つぎに、この白色シートの上面に、厚み
0.25mmのPETシートを載置し、温度130℃、
圧力20g/cm2 の条件で1時間加熱・加圧すること
により、PETシート載置面の表面粗さ(Ra)が1.
2μm、気孔率35%、通気度1.0cm3 /cm2
sec、孔径100μmのシートを得た。
Next, a PET sheet having a thickness of 0.25 mm was placed on the upper surface of the white sheet.
By heating and pressurizing for 1 hour under the condition of a pressure of 20 g / cm 2 , the surface roughness (Ra) of the PET sheet mounting surface becomes 1.
2 μm, porosity 35%, air permeability 1.0 cm 3 / cm 2 /
sec, and a sheet having a hole diameter of 100 μm was obtained.

【0044】[0044]

【比較例5】実施例1で用いたUHMWPE粉末に代え
て、平均粒径150μm、分子量400万のUHMWP
E粉末を用い、実施例1と同様にして、厚み0.3m
m、気孔率30%、通気度10cm3 /cm2 /se
c、孔径100μmのシートを得た。
Comparative Example 5 Instead of the UHMWPE powder used in Example 1, UHMWWP having an average particle size of 150 μm and a molecular weight of 4,000,000 was used.
Using E powder, a thickness of 0.3 m was obtained in the same manner as in Example 1.
m, porosity 30%, air permeability 10 cm 3 / cm 2 / se
c, a sheet having a hole diameter of 100 μm was obtained.

【0045】つぎに、実施例1で用いたUHMWPE粉
末を用い、実施例1と同様にして厚み3.0mm、気孔
率30%、通気度1cm3 /cm2 /sec、孔径30
μmのシートを得た。
Next, using the UHMWPE powder used in Example 1, a thickness of 3.0 mm, a porosity of 30%, an air permeability of 1 cm 3 / cm 2 / sec and a pore diameter of 30 were used in the same manner as in Example 1.
A μm sheet was obtained.

【0046】そして、上記得られた各シートを重ね合わ
せ、小孔径のシート(白色シート)側の表面に厚み0.
25mmのPETシートを載置し、50g/cm2 の荷
重をかけて140℃の乾燥機内で1時間加熱処理を行う
ことにより、総厚み3.2mmの積層多孔質シートを得
た。得られたシート全体の通気度は、0.8cm3 /c
2 /secで、気孔率28%、小孔径側の表面粗さ
(Ra)は1.0μmであった。
Then, the sheets obtained above are superposed on each other, and a sheet having a thickness of 0.
A 25 mm PET sheet was placed and subjected to a heat treatment in a dryer at 140 ° C. for 1 hour under a load of 50 g / cm 2 to obtain a laminated porous sheet having a total thickness of 3.2 mm. The air permeability of the obtained sheet is 0.8 cm 3 / c.
At m 2 / sec, the porosity was 28%, and the surface roughness (Ra) on the small-pore side was 1.0 μm.

【0047】[0047]

【比較例6】実施例1で用いたUHMWPE粉末に代え
て、平均粒径170μm、分子量500万のUHMWP
E粉末を用い、実施例1と同様にして、厚み0.3m
m、気孔率30%、通気度20cm3 /cm2 /se
c、孔径130μmのシートを得た。
Comparative Example 6 UHMWWP having an average particle size of 170 μm and a molecular weight of 5,000,000 was used in place of the UHMWPE powder used in Example 1.
Using E powder, a thickness of 0.3 m was obtained in the same manner as in Example 1.
m, porosity 30%, air permeability 20 cm 3 / cm 2 / se
c, A sheet having a pore size of 130 μm was obtained.

【0048】つぎに、実施例1で用いたUHMWPE粉
末に代えて、平均粒径140μm、分子量400万のU
HMWPE粉末を用い、実施例1と同様にして厚み2.
7mm、気孔率35%、通気度2cm3 /cm2 /se
c、孔径100μmのシートを得た。
Next, in place of the UHMWPE powder used in Example 1, U-U-M powder having an average particle diameter of 140 μm and a molecular weight of 4,000,000 was used.
Using HMWPE powder, the thickness was 2.
7 mm, porosity 35%, air permeability 2 cm 3 / cm 2 / se
c, a sheet having a hole diameter of 100 μm was obtained.

【0049】そして、上記得られた各シートを重ね合わ
せ、小孔径のシート(白色シート)側の表面に厚み0.
25mmのPETシートを載置し、100g/cm2
荷重をかけて140℃の乾燥機内で1時間加熱処理を行
うことにより、総厚み3mmの積層多孔質シートを得
た。得られたシート全体の通気度は、1.5cm3 /c
2 /secで、気孔率30%、小孔径側の表面粗さ
(Ra)は0.8μmであった。
Then, the obtained sheets are superimposed on each other, and a sheet having a thickness of 0.
A 25 mm PET sheet was placed and subjected to a heat treatment in a dryer at 140 ° C. for 1 hour under a load of 100 g / cm 2 to obtain a laminated porous sheet having a total thickness of 3 mm. The air permeability of the entire obtained sheet is 1.5 cm 3 / c.
At m 2 / sec, the porosity was 30%, and the surface roughness (Ra) on the small pore diameter side was 0.8 μm.

【0050】このようにして得られた各シートの上記各
物性(孔径、開孔率、通気度、表面粗さ)は下記に示す
測定法に従って測定した。さらに、各シートの引張強度
を下記に示す方法に従って測定した。これらの結果を後
記の表1に示す。
The physical properties (pore size, porosity, air permeability, surface roughness) of each sheet thus obtained were measured according to the following measuring methods. Further, the tensile strength of each sheet was measured according to the method described below. The results are shown in Table 1 below.

【0051】〔孔径および開孔率〕走査型電子顕微鏡を
用いてシートの表面を写真撮影した(倍率20〜300
倍)。この写真からシートの孔径を求めた。また、この
写真をスキャナーで読み込み、孔部と非孔部を2値化
し、画像解析ソフト(V10)(旭化成社製)により開
孔率を算出した。
[Pore Size and Porosity] The surface of the sheet was photographed using a scanning electron microscope (magnification: 20 to 300).
Times). The hole diameter of the sheet was determined from this photograph. Further, this photograph was read by a scanner, and the holes and non-holes were binarized, and the aperture ratio was calculated using image analysis software (V10) (manufactured by Asahi Kasei Corporation).

【0052】〔通気度〕JIS L 1096A法に準
じ、フラジール試験機(TOYOSEIKI社製)を用
いて測定した。
[Air permeability] Measured using a Frazier tester (manufactured by TOYOSEIKI) according to JIS L 1096A method.

【0053】〔表面粗さ(Ra)〕東京精密社製のサー
フコム550A表面粗さ計を用いて測定した。なお、測
定条件は、触針径250μmR、カットオフ値0.8、
移動速度0.3mm/秒、測定長4mmとした。
[Surface Roughness (Ra)] The surface roughness was measured using a Surfcom 550A surface roughness meter manufactured by Tokyo Seimitsu Co., Ltd. The measurement conditions were as follows: stylus diameter 250 μmR, cutoff value 0.8,
The moving speed was 0.3 mm / sec and the measurement length was 4 mm.

【0054】〔総合評価〕各シートを実際に吸着固定搬
送用シートとしてグリーンシートの搬送に用いた。すな
わち、図1に示すように、吸引機1に各吸着固定搬送用
シート(高分子多孔質シート)2を取り付け、キャリア
フィルム4上のグリーンシート3を吸引した後、排気・
加圧して脱着させた。その結果を上記引張強度の測定結
果とともに考慮して下記の基準に従って総合評価した。 ○:吸着固定搬送用シートとして用いた場合に、グリー
ンシート表面に損傷等が確認されず、また、吸引、排気
による剥離時間も短時間で作業性が良好であった。 △:吸着搬送した際にグリーンシート表面に損傷はなか
ったが、吸引・排気に時間を要した。 ×:吸着固定搬送用シートとして用いた場合に、グリー
ンシート表面に損傷等が確認され、吸引、排気による剥
離に時間がかかり、作業性に劣っていた。あるいは作業
は短時間でできるがグリーンシートの表面に損傷が確認
された。
[Comprehensive Evaluation] Each sheet was actually used for conveying a green sheet as a sheet for suction and fixed conveyance. That is, as shown in FIG. 1, each suction-fixing / conveying sheet (polymer porous sheet) 2 is attached to a suction machine 1, the green sheet 3 on the carrier film 4 is suctioned, and then the air
Pressurized for desorption. The results were comprehensively evaluated in accordance with the following criteria in consideration of the tensile strength measurement results. :: When used as a sheet for adsorption and fixation, no damage or the like was confirmed on the surface of the green sheet, and the peeling time by suction and exhaust was short, and workability was good. Δ: The surface of the green sheet was not damaged when the sheet was sucked and conveyed, but it took time for suction and exhaust. X: When used as a sheet for adsorption and fixing, damage and the like were confirmed on the surface of the green sheet, and it took time to peel off by suction and exhaust, resulting in poor workability. Alternatively, the work was completed in a short time, but damage was confirmed on the surface of the green sheet.

【0055】[0055]

【表1】 [Table 1]

【0056】上記表1の結果から、実施例品は、吸着固
定搬送用シートとして用いた場合、グリーンシート表面
に損傷等が確認されず、また、吸引、排気による剥離時
間も短時間で作業性が良好であった。このことから、グ
リーンシートの吸着固定搬送用シートとして非常に優れ
たものであることがわかる。これに対して、比較例1、
2品では、吸着固定搬送用シートとして用いた場合、グ
リーンシート表面に凹凸形状が確認され損傷が確認され
た。また、比較例3、5品では、グリーンシート表面に
損傷は確認されなかったが、吸引、排気による剥離に時
間がかかり、作業性に劣るものであった。さらに、比較
例4品は短時間で作業ができるがグリーンシートの表面
に損傷が確認された。さらに、比較例6品はグリーンシ
ートに損傷が確認され、作業にも時間を要した。
From the results shown in Table 1, when the product of the example was used as a sheet for adsorption and fixing, no damage or the like was observed on the surface of the green sheet, and the peeling time by suction and exhaust was short, and the workability was short. Was good. From this, it is understood that the sheet is very excellent as a sheet for fixing and conveying the green sheet. In contrast, Comparative Example 1,
In the case of the two products, when used as a sheet for adsorption and fixation, irregularities were confirmed on the surface of the green sheet, and damage was confirmed. In Comparative Examples 3 and 5, no damage was confirmed on the surface of the green sheet, but it took a long time to peel off by suction and exhaust, resulting in poor workability. Furthermore, although the work of Comparative Example 4 could be performed in a short time, damage was confirmed on the surface of the green sheet. Further, in the product of Comparative Example 6, damage was confirmed in the green sheet, and it took time for the operation.

【0057】[0057]

【発明の効果】以上のように、本発明の吸着固定搬送用
シートは、表面の開孔率が40%以下で、かつその表面
粗さ(Ra)が1μm以下の多孔質シートが被吸着部材
との接触面部を構成するようになっている。このよう
に、多孔質シート表面部の孔径が微細なためグリーンシ
ート吸着時にグリーンシートが孔にもぐり込んだりする
ことがなく、また表面が平滑であるためにグリーンシー
ト表面に凹凸や傷等の発生が防止できる。さらに、吸着
固定搬送用シート全体の厚み方向の通気度を1cm 3
cm2 /sec以上に設定することにより、製造工程の
タクト(グリーンシートの吸引、放出にかかる時間)に
影響を与えることなく吸着・固定・脱着が容易に行える
ようになる。
As described above, as described above, the present invention relates to
The sheet has a surface porosity of 40% or less and the surface
A porous sheet having a roughness (Ra) of 1 μm or less is a member to be adsorbed.
And a contact surface portion. like this
In addition, since the pore size of the porous sheet surface is very small,
Green sheet gets into holes when adsorbing heat
And the surface is smooth,
The occurrence of irregularities, scratches, and the like on the surface can be prevented. In addition, adsorption
The air permeability in the thickness direction of the entire fixed conveyance sheet is 1 cm. Three/
cmTwo/ Sec or more, the production process
Tact (time required to suck and release green sheet)
Adsorption, fixation, and desorption can be easily performed without affecting
Become like

【0058】さらに、上記多孔質シートの被吸着部材と
の接触面とは他面側に補強用となる他の多孔質体を積層
した場合、良好な表面平滑性と通気度とともに、吸着固
定搬送用途として充分な高強度を容易に確保することが
できる。
Further, when another porous body for reinforcement is laminated on the other side of the contact surface of the porous sheet with the member to be adsorbed, it has good surface smoothness and air permeability, as well as adsorption and fixed conveyance. Sufficient high strength for use can be easily secured.

【図面の簡単な説明】[Brief description of the drawings]

【図1】吸着固定搬送用部材(多孔質シート)を用いた
グリーンシートの吸着固定搬送工程を示す模式図であ
る。
FIG. 1 is a schematic diagram showing a process of adsorbing and fixing a green sheet using an adsorbing and fixing conveying member (porous sheet).

【符号の説明】[Explanation of symbols]

1 吸引機 2 高分子多孔質シート(吸着固定搬送用シート) 3 グリーンシート 4 キャリアフィルム DESCRIPTION OF SYMBOLS 1 Suction machine 2 Polymer porous sheet (sheet for adsorption fixed conveyance) 3 Green sheet 4 Carrier film

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 3C016 DA05 4F071 AA15 AA81 AH12 BA01 BB13 BC01 BC13 BC16 4F100 AK04 AK42 BA02 DJ00A DJ00B EJ17 EJ24 EJ42 GB41 JA08 JD02A JK01 JK14A JK15 YY00A 5F031 CA02 CA05 FA01 FA02 GA08 GA32 GA33 PA20  ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 3C016 DA05 4F071 AA15 AA81 AH12 BA01 BB13 BC01 BC13 BC16 4F100 AK04 AK42 BA02 DJ00A DJ00B EJ17 EJ24 EJ42 GB41 JA08 JD02A JK01 JK14A JK15 YY00A 5F031 CA02 GA05

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 下記の(A)および(B)を備えた多孔
質シートが被吸着部材との接触面部を構成するようにな
っている吸着固定搬送用シートであって、上記吸着固定
搬送用シート全体の厚み方向の通気度が1cm3 /cm
2 /sec以上であることを特徴とする吸着固定搬送用
シート。 (A)表面の開孔率が40%以下。 (B)表面粗さ(Ra)が1μm以下。
1. A sheet for suction and fixed conveyance, wherein a porous sheet having the following (A) and (B) constitutes a contact surface portion with a member to be sucked. The air permeability in the thickness direction of the entire sheet is 1 cm 3 / cm
2 / sec or more, the sheet for suction fixed conveyance. (A) The porosity of the surface is 40% or less. (B) The surface roughness (Ra) is 1 μm or less.
【請求項2】 上記多孔質シートの被吸着部材との接触
面とは他面側に、さらに他の多孔質シートが積層されて
なる請求項1記載の吸着固定搬送用シート。
2. The sheet according to claim 1, wherein another porous sheet is further laminated on the other surface of the porous sheet from the contact surface with the member to be adsorbed.
【請求項3】 吸引機の吸引面に取り付けられ、その吸
引力を利用して被吸着部材を吸着する請求項1または2
記載の吸着固定搬送用シート。
3. The suction member is attached to a suction surface of a suction machine, and uses the suction force to suck the member to be suctioned.
The sheet for fixing and conveying according to the above description.
JP19955599A 1999-07-13 1999-07-13 Sucking fixing carrying sheet Pending JP2001028390A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19955599A JP2001028390A (en) 1999-07-13 1999-07-13 Sucking fixing carrying sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP19955599A JP2001028390A (en) 1999-07-13 1999-07-13 Sucking fixing carrying sheet

Publications (1)

Publication Number Publication Date
JP2001028390A true JP2001028390A (en) 2001-01-30

Family

ID=16409782

Family Applications (1)

Application Number Title Priority Date Filing Date
JP19955599A Pending JP2001028390A (en) 1999-07-13 1999-07-13 Sucking fixing carrying sheet

Country Status (1)

Country Link
JP (1) JP2001028390A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
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JP2007229943A (en) * 2006-02-27 2007-09-13 Nitto Denko Corp Porous sheet manufacturing method and porous sheet obtained thereby
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Cited By (12)

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Publication number Priority date Publication date Assignee Title
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US7851058B2 (en) 2004-07-13 2010-12-14 Nitto Denko Corporation Sheet for suction and fixation, and method of producing the same
JP2007229943A (en) * 2006-02-27 2007-09-13 Nitto Denko Corp Porous sheet manufacturing method and porous sheet obtained thereby
JP2008036885A (en) * 2006-08-02 2008-02-21 Nitto Denko Corp Adsorbent film, its manufacturing method, adsorbent film with mold release film and its manufacturing method
CN103010742A (en) * 2011-09-22 2013-04-03 旭硝子株式会社 Glass substrate conveying method and method for forming glass substrate laminated body
CN103010742B (en) * 2011-09-22 2016-08-03 旭硝子株式会社 Carrying glass sheet method and glass substrate laminate forming method
CN104114358A (en) * 2012-02-17 2014-10-22 日东电工株式会社 Porous sheet for suction applications and replaceable surface layer used therein
CN104114358B (en) * 2012-02-17 2016-10-12 日东电工株式会社 The replacing surface layer used in absorption porous chips and absorption porous chips
JP2012162089A (en) * 2012-05-21 2012-08-30 Nitto Denko Corp Adsorption film and adsorption film with mold release film
KR20190121841A (en) 2017-05-09 2019-10-28 아사히 가세이 가부시키가이샤 Porous Sintered Sheet and Manufacturing Method Thereof
KR20200028973A (en) 2017-09-05 2020-03-17 아사히 가세이 가부시키가이샤 Porous sheet and manufacturing method thereof
WO2022021003A1 (en) * 2020-07-27 2022-02-03 重庆康佳光电技术研究院有限公司 Adapter plate, mass transfer method, and micro-led display

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