JP2001003547A - Unslippery resin molded board - Google Patents
Unslippery resin molded boardInfo
- Publication number
- JP2001003547A JP2001003547A JP11180283A JP18028399A JP2001003547A JP 2001003547 A JP2001003547 A JP 2001003547A JP 11180283 A JP11180283 A JP 11180283A JP 18028399 A JP18028399 A JP 18028399A JP 2001003547 A JP2001003547 A JP 2001003547A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- pattern
- slip
- resin molded
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Bathtubs, Showers, And Their Attachments (AREA)
- Residential Or Office Buildings (AREA)
- Floor Finish (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、浴室やシャワーユ
ニット等の洗い場床等に好適に用いられる難滑り性樹脂
成形板(表面が滑りにくい樹脂成形板)に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a non-slip resin molded plate (a resin molded plate with a non-slip surface) which is suitably used for a washing floor such as a bathroom or a shower unit.
【0002】[0002]
【従来の技術】浴室やシャワーユニット等の洗い場床の
滑りを防止する方法としては、例えば、軟質アクリル樹
脂発泡体層を被覆した滑り止めシートを敷材本体の接床
部下面に貼り合わせて一体化した滑りにくい敷材を敷く
方法(特開平8−117125号公報)や、洗い場床表
面に滑り止めパターン(多数の凹部)を散在させ、各々
の凹部を円弧状に凹ませて吸盤効果を与える方法(特開
平9−203227号公報)等が知られている。2. Description of the Related Art As a method for preventing the floor of a washing room such as a bathroom or a shower unit from slipping, for example, a non-slip sheet coated with a soft acrylic resin foam layer is attached to the lower surface of a floor portion of a flooring material body and integrated. (Japanese Patent Laid-Open Publication No. HEI 8-117125), a method of laying a non-slip pattern (a large number of recesses) on the floor of a washing place, and making each recess in an arc shape to give a sucker effect. A method (Japanese Patent Application Laid-Open No. 9-203227) and the like are known.
【0003】[0003]
【発明が解決しようとする課題】しかし、上記特開平8
−117125号公報に開示の敷材を敷く方法では、長
らく使用する間に敷材に汚れが付着しヌルヌルして滑り
易くなる問題がある。また、前記特開平9−20322
7号公報に開示の洗い場床表面に滑り止めパターンを散
在させる方法では、長らく使用する間に同様に凹部隙間
に汚れが付着しヌルヌルして滑り易くなり、また、多数
の凹部を有するパターンであるので清掃性の問題があ
る。本発明は、敷材を敷いたり、板表面に多数の凹部を
形成させたりの必要もなく、表面が平坦であっても滑り
にくく、更に清掃性の容易な樹脂成形板を提供すること
を目的とする。However, Japanese Patent Application Laid-open No.
In the method of laying the laying material disclosed in Japanese Patent Publication No. -117125, there is a problem that the laying material becomes dirty during use for a long time and becomes slippery. In addition, Japanese Patent Application Laid-Open No.
In the method disclosed in Japanese Patent Publication No. 7-131, in which a non-slip pattern is scattered on the floor of a washing place, dirt is similarly adhered to a concave gap during use for a long time to make it slippery and slippery, and a pattern having a large number of concave parts. So there is a problem of cleanability. An object of the present invention is to provide a resin molded plate which does not need to lay a laying material or form a large number of concave portions on the plate surface, does not slip even on a flat surface, and is easy to clean. And
【0004】[0004]
【課題を解決するための手段】本発明者らは、樹脂成形
板の表面層を構成する樹脂として特定の樹脂を用いれ
ば、上記目的が達成できることを見出し、本発明を完成
した。すなわち、本発明は、下記(1)〜(3)の難滑
り性樹脂成形板である。 (1)表面樹脂層と強化樹脂板とからなる樹脂成形板で
あって、前記表面樹脂層の床滑り抵抗係数は3.8以上
である難滑り性樹脂成形板。 (2)表面樹脂層には繊維が含まれている、上記(1)
の難滑り性樹脂成形板。 (3)表面樹脂層と強化樹脂板とのあいだに、更に模様
層が形成されている、上記(2)又は(3)の難滑り性
樹脂成形板。 (4)表面樹脂が、イソシアネート系樹脂にポリエステ
ルポリオールを反応して得られる熱硬化樹脂あるいは不
飽和ポリエステル樹脂にビニルエステル樹脂を反応して
得られる熱硬化樹脂である、上記(1)〜(3)のいず
れかの難滑り性樹脂成形板。Means for Solving the Problems The present inventors have found that the above object can be achieved by using a specific resin as the resin constituting the surface layer of the resin molded plate, and completed the present invention. That is, the present invention relates to the following non-slip resin molded plate (1) to (3). (1) A resin molded plate comprising a surface resin layer and a reinforced resin plate, wherein the floor resin layer has a floor slip resistance coefficient of 3.8 or more. (2) The above (1), wherein the surface resin layer contains fibers.
Non-slip resin molded plate. (3) The non-slip resin molded plate according to the above (2) or (3), wherein a pattern layer is further formed between the surface resin layer and the reinforced resin plate. (4) The above (1) to (3), wherein the surface resin is a thermosetting resin obtained by reacting a polyester polyol with an isocyanate-based resin or a thermosetting resin obtained by reacting a vinyl ester resin with an unsaturated polyester resin. ) Any of the non-slip resin molded plates.
【0005】ここで、難滑り性樹脂成形板の床滑り抵抗
係数はJIS−A 1407に規定する方法「床の滑り
試験方法(振子形)」(滑り片はステンレス鋼SUS3
04)で測定した値とする。床滑り抵抗係数は高いほど
滑りにくく好ましいが、本発明においては、通常、3.
8〜10程度の範囲の難滑り性樹脂成形板が得られる。[0005] Here, the floor slip resistance coefficient of the non-slip resin molded plate is a method specified in JIS-A 1407, "Method of testing the floor slip (pendulum type)" (the sliding piece is made of stainless steel SUS3).
04). The higher the coefficient of floor slip resistance is, the more difficult it is to slip.
A non-slip resin molded plate in the range of about 8 to 10 is obtained.
【0006】本発明で用いられる表面樹脂の好ましいも
のは、ゴム様の柔軟性を持つイソシアネート系樹脂にト
ルエン等の有機溶媒に溶かしたポリエステルポリオール
を適量加え、反応して得られる樹脂(熱硬化樹脂)や、
不飽和ポリエステル樹脂にビニルエステル樹脂等のゴム
系相溶加剤を加え、反応させた樹脂(熱硬化樹脂)であ
る。A preferable surface resin used in the present invention is a resin (thermosetting resin) obtained by adding an appropriate amount of a polyester polyol dissolved in an organic solvent such as toluene to an isocyanate resin having rubber-like flexibility and reacting. )
A resin (thermosetting resin) obtained by adding a rubber-based additive such as a vinyl ester resin to an unsaturated polyester resin and reacting the same.
【0007】表面樹脂層に表面の強度を上げるため繊維
を含ませることもできる。その場合の繊維としては、ガ
ラス繊維、アルミナ繊維、シリカ繊維等の無機質繊維、
あるいはポリエステル繊維、ナイロン繊維等の有機繊維
が用いられ、これらは織布であっても不織布であっても
よい。中でも、模様の美感を損なわない点や経済性の点
で、ガラス繊維の不織布が好ましい。ここで、使用する
繊維の目付量は好ましくは20〜50g/平方メート
ル、更に好ましくは30〜40g/平方メートル程度で
ある。The surface resin layer may contain fibers for increasing the surface strength. In that case, the fibers include glass fibers, alumina fibers, inorganic fibers such as silica fibers,
Alternatively, organic fibers such as polyester fibers and nylon fibers are used, and these may be woven or non-woven fabrics. Among them, a glass fiber nonwoven fabric is preferable from the viewpoint of not impairing the beauty of the pattern and the economic efficiency. Here, the basis weight of the fiber used is preferably about 20 to 50 g / m 2, more preferably about 30 to 40 g / m 2.
【0008】用いられる強化樹脂板としては、代表的な
ものは繊維強化樹脂板(FRP)があり、繊維としては
ガラス繊維、アルミナ繊維、シリカ繊維等の無機質繊
維、あるいはポリエステル繊維、ナイロン繊維等の有機
繊維が用いられ、これらは織布であっても不織布であっ
てもよい。強化樹脂板に用いられる樹脂としては、例え
ば、不飽和ポリエステル樹脂やジシクロペンタジエン樹
脂等の熱硬化性樹脂がある。シートモールディングコン
パウンド(SMC)、バルクモールディングコンパウン
ド(BMC)等の熱硬化性繊維強化材料を用いて強化樹
脂板を製造することもできる。As a reinforced resin plate to be used, a typical one is a fiber reinforced resin plate (FRP), and as a fiber, inorganic fibers such as glass fiber, alumina fiber, silica fiber, etc., or polyester fiber, nylon fiber, etc. Organic fibers are used, which may be woven or non-woven. Examples of the resin used for the reinforced resin plate include a thermosetting resin such as an unsaturated polyester resin and a dicyclopentadiene resin. A reinforced resin plate can also be manufactured using a thermosetting fiber reinforced material such as a sheet molding compound (SMC) or a bulk molding compound (BMC).
【0009】模様層に用いられる模様としては、インキ
が好ましく用いられ、前記表面樹脂に可溶なものから選
ぶ。そのようなインキとしては、顔料又は染料を不飽和
ポリエステル系樹脂、アクリル系樹脂、硝化綿(ニトロ
セルロース)系樹脂等に混合したものがある。インキの
ほかにも、雲母(マイカ)等の天然鉱物の粉砕物、金属
等の無機物の粉砕物を模様として用いることもできる。
なお、ここで模様とは、花柄模様、幾何学的模様等、い
ろいろな模様があり得るが、無模様又は単色模様であっ
てもよい。As the pattern used for the pattern layer, ink is preferably used and is selected from those soluble in the surface resin. As such an ink, there is an ink obtained by mixing a pigment or a dye with an unsaturated polyester resin, an acrylic resin, a nitrified cotton (nitrocellulose) resin, or the like. In addition to the ink, a pulverized product of a natural mineral such as mica (mica) or a pulverized product of an inorganic substance such as a metal can also be used as the pattern.
Here, the pattern may be various patterns such as a floral pattern and a geometric pattern, but may be a non-pattern or a monochromatic pattern.
【0010】[0010]
【作用】強化樹脂板の表面側は、イソシアネート系樹脂
にポリエステルポリオールを反応して得られる熱硬化樹
脂や、不飽和ポリエステル樹脂にビニルエステル樹脂を
反応して得られる熱硬化樹脂等の、ゴム様性状をもつ表
面樹脂又は繊維含有面樹脂であるので、従来の樹脂板よ
りも高い床滑り抵抗係数を有する。The surface side of the reinforced resin plate is a rubber-like resin such as a thermosetting resin obtained by reacting a polyester polyol with an isocyanate resin or a thermosetting resin obtained by reacting a vinyl ester resin with an unsaturated polyester resin. Since it is a surface resin having properties or a fiber-containing surface resin, it has a higher floor slip resistance coefficient than a conventional resin plate.
【0011】[0011]
【発明の実施の形態】以下、本発明の実施の形態につい
て、添付図面を参照しながら更に具体的に説明する。図
1は、本発明に係る一実施例の難滑り性樹脂成形板であ
る。繊維2に表面樹脂1を含浸させ、硬化させ、強化樹
脂板(繊維強化樹脂板)5と接着して一体となった難滑
り性樹脂成形板である。Embodiments of the present invention will be described below more specifically with reference to the accompanying drawings. FIG. 1 is a non-slip resin molded plate according to one embodiment of the present invention. This is a hard-slip resin molded plate in which the fibers 2 are impregnated with the surface resin 1, cured, adhered to a reinforced resin plate (fiber reinforced resin plate) 5 and integrated.
【0012】図2は、本発明に係る他の実施例の難滑り
性樹脂成形板である。表面樹脂1含有繊維層と強化樹脂
板5とのあいだに、更に模様層(3と4)が形成されて
いる。なお、図1及び図2では、難滑り性樹脂成形板の
表面は平坦な例であるが、表面を凹凸形状としてもよ
い。FIG. 2 shows a non-slip resin molded plate according to another embodiment of the present invention. Pattern layers (3 and 4) are further formed between the fiber layer containing the surface resin 1 and the reinforced resin plate 5. In FIGS. 1 and 2, the surface of the non-slip resin molded plate is a flat example, but the surface may have an uneven shape.
【0013】本発明に係る難滑り性樹脂成形板の製造
は、模様付き樹脂成形板の場合、例えば、以下に示すよ
うな方法で製造できる(図3参照)。片面に模様3が施
されたフィルムを用意し、その模様面の上に繊維(ガラ
ス繊維不織布等)2を重ね、この上に、イソシアネート
系樹脂にポリエステルポリオールを反応して得られる未
硬化熱硬化性樹脂、あるいは不飽和ポリエステル樹脂に
ビニルエステル樹脂等のゴム系相溶加剤を加え、反応さ
せた未硬化熱硬化性樹脂を載置し、これを均一の厚さに
延伸し、これを硬化炉内にて重合が約80%進行するま
で保持する。ここで、重合が約80%進行するまで保持
する理由は、前記フィルムを剥がすことができ、表面樹
脂が含浸した繊維層の片面に模様3が転写された表面樹
脂含有繊維層が得られるからである。重合が約80%進
行すれば、これを適当な大きさに切断し、前記フィルム
を剥がし、除去する。[0013] In the case of a resin molded plate with a pattern, the method of manufacturing the resin molded plate having low slipperiness according to the present invention can be carried out, for example, by the following method (see FIG. 3). A film having a pattern 3 on one side is prepared, and a fiber (glass fiber nonwoven fabric or the like) 2 is overlaid on the pattern side, and an uncured thermosetting obtained by reacting a polyester polyol with an isocyanate-based resin thereon. A rubber-based additive such as vinyl ester resin is added to a reactive resin or unsaturated polyester resin, and the reacted uncured thermosetting resin is placed, stretched to a uniform thickness, and cured. Hold in the furnace until polymerization progresses about 80%. Here, the reason why the polymerization is maintained until the polymerization proceeds about 80% is that the film can be peeled off, and a surface resin-containing fiber layer in which the pattern 3 is transferred to one surface of the fiber layer impregnated with the surface resin is obtained. is there. When the polymerization proceeds about 80%, it is cut into a suitable size, the film is peeled off and removed.
【0014】次に、これを模様面を上にして表面用型7
の上に載置し、この上にシートモールディングコンパウ
ンド(SMC)等の熱硬化性繊維強化材料を重ね、裏面
用型9を締めて加圧、加熱し、成形する。冷後脱型する
と、片面模様付きの樹脂成形板が得られる。Next, this is placed on the surface mold 7 with the pattern surface facing up.
, And a thermosetting fiber reinforced material such as a sheet molding compound (SMC) is stacked thereon, and the back mold 9 is tightened, pressed, heated, and molded. When the mold is released after cooling, a resin molded plate with a single-sided pattern is obtained.
【0015】[0015]
【実施例】実施例1 図3に難滑り性樹脂成形板の製造手順を示した。フィル
ム片面に、表面樹脂1に可溶なインキで模様3が施され
た厚さ50μmの印刷フィルム6(ベースフィルムはポ
リエステルフィルム6a)を用意し、図3Aのようにそ
の模様面の上に目付量35g/平方メートルのガラス繊
維不織布2を重ね、この上に、透明未硬化のポリエステ
ル系樹脂(日立化成工業(株)製、商品名:ユーポール
6039T)とイソシアネート系樹脂(住友バイエルウ
レタン(株)、商品名:SUMIDUR N75)の混
合物(混合比は重量で81:29)を載置し、バーコー
ター法により樹脂を膜厚0.3mmに均一に延伸、脱泡
した。EXAMPLE 1 FIG. 3 shows the procedure for producing a non-slip resin molded plate. On one surface of the film, a printing film 6 (base film is a polyester film 6a) having a thickness of 50 μm, on which a pattern 3 is applied with an ink soluble in the surface resin 1, is prepared, and as shown in FIG. A glass fiber nonwoven fabric 2 having an amount of 35 g / m 2 is overlaid, and a transparent uncured polyester resin (manufactured by Hitachi Chemical Co., Ltd., trade name: EUPOL 6039T) and an isocyanate resin (Sumitomo Bayer Urethane Co., Ltd.) A mixture (trade name: SUMIDUR N75) (mixing ratio: 81:29 by weight) was placed, and the resin was uniformly stretched to a thickness of 0.3 mm by a bar coater method and defoamed.
【0016】これを40℃硬化炉内にて重合が約80%
進むまで(約30分間)保持した。その後、適当な大き
さに切断し、剥離によりベースフィルム6aを除去し
た。The polymerization is reduced to about 80% in a 40 ° C. curing oven.
Hold until advanced (about 30 minutes). Thereafter, the base film 6a was cut into an appropriate size, and the base film 6a was removed by peeling.
【0017】次に、図3Bに示すように模様3がある面
を上にして表面用型7の上に載置し、この上にシートモ
ールディングコンパウンド(SMC)8を重ね、裏面用
型9を締めて加圧(100kg/平方センチメート
ル)、加熱(表面用型:150℃、裏面用型:145
℃)し、成形した。脱型し、図3Dに示すような片面模
様付きの樹脂成形板が得られた。得られた樹脂成形板の
床滑り抵抗係数をJIS−A1407に規定する方法で
測定すると、4.0であった。Next, as shown in FIG. 3B, the pattern 3 is placed on the front mold 7 with the surface on which the pattern 3 is present, and a sheet molding compound (SMC) 8 is stacked thereon, and the back mold 9 is placed. Tighten and pressurize (100 kg / square centimeter), heat (front type: 150 ° C, back type: 145)
C) and molded. The mold was released, and a resin molded plate with a single-sided pattern as shown in FIG. 3D was obtained. The floor slip resistance coefficient of the obtained resin molded plate was 4.0 as measured by the method specified in JIS-A1407.
【0018】[0018]
【発明の効果】本発明の難滑り性樹脂成形板は、板表面
に多数の凹部を形成させることなく、また敷材不要で、
滑りにくい。清掃性も容易である。表面樹脂層に繊維が
含まれているものでは、板表面も補強されているので、
板表面に凹凸を設けることもできる。表面樹脂層と強化
樹脂板とのあいだに、更に模様層が形成されているもの
は、美感があり、意匠性も高い。本発明の難滑り性樹脂
成形板は、浴室の床等の滑りやすい環境の床材として好
適である。According to the present invention, the non-slip resin molded plate of the present invention does not need to form a large number of recesses on the plate surface, and does not require a laying material.
Not slippery. Easy to clean. If the surface resin layer contains fibers, the board surface is also reinforced,
Irregularities can also be provided on the plate surface. One in which a pattern layer is further formed between the surface resin layer and the reinforced resin plate has a beautiful appearance and high design. The non-slip resin molded plate of the present invention is suitable as a floor material in a slippery environment such as a bathroom floor.
【図1】本発明に係る難滑り性樹脂成形板の断面略図で
ある。FIG. 1 is a schematic sectional view of a non-slip resin molded plate according to the present invention.
【図2】本発明に係る模様付き難滑り性樹脂成形板の断
面略図である。FIG. 2 is a schematic cross-sectional view of a patterned hard-to-slip resin molded plate according to the present invention.
【図3】本発明に係る模様付き難滑り性樹脂成形板を製
造する手順の説明図である。FIG. 3 is an explanatory diagram of a procedure for manufacturing a patterned hard-to-slip resin molded plate according to the present invention.
1:表面樹脂 2:ガラス繊維不織布 3:模様 4:接着材樹脂 5:強化樹脂板(繊維強化樹脂板) 6:印刷フィルム 6a:ベースフィルム(ポリエ
ステルフィルム) 7:表面型 8:シートモールディングコ
ンパウンド(SMC) 9:裏面型1: Surface resin 2: Glass fiber non-woven fabric 3: Pattern 4: Adhesive resin 5: Reinforced resin plate (fiber reinforced resin plate) 6: Printing film 6a: Base film (polyester film) 7: Surface type 8: Sheet molding compound ( SMC) 9: Back type
───────────────────────────────────────────────────── フロントページの続き (72)発明者 高田 賢治 富山県富山市一本木1010番地 日立化成ユ ニット株式会社内 Fターム(参考) 2D032 GA00 2E025 BA01 BC02 ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Kenji Takada 1010 Ippongi, Toyama City, Toyama Prefecture Hitachi Chemical Unit Co., Ltd. F-term (reference) 2D032 GA00 2E025 BA01 BC02
Claims (4)
形板であって、前記表面樹脂層の床滑り抵抗係数は3.
8以上である難滑り性樹脂成形板。1. A resin molded plate comprising a surface resin layer and a reinforced resin plate, wherein the surface resin layer has a floor slip resistance coefficient of 3.
Non-slip resin molded plate of 8 or more.
項1の難滑り性樹脂成形板。2. The non-slip resin molded plate according to claim 1, wherein the surface resin layer contains fibers.
に模様層が形成されている、請求項2又は3の難滑り性
樹脂成形板。3. The non-slip resin molded plate according to claim 2, wherein a pattern layer is further formed between the surface resin layer and the reinforced resin plate.
エステルポリオールを反応して得られる熱硬化樹脂ある
いは不飽和ポリエステル樹脂にビニルエステル樹脂を反
応して得られる熱硬化樹脂である、請求項1〜3のいず
れかの難滑り性樹脂成形板。4. A thermosetting resin obtained by reacting a polyester polyol with an isocyanate-based resin or a thermosetting resin obtained by reacting a vinyl ester resin with an unsaturated polyester resin. Non-slip resin molded plate of any of the above.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11180283A JP2001003547A (en) | 1999-06-25 | 1999-06-25 | Unslippery resin molded board |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11180283A JP2001003547A (en) | 1999-06-25 | 1999-06-25 | Unslippery resin molded board |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2001003547A true JP2001003547A (en) | 2001-01-09 |
Family
ID=16080517
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11180283A Pending JP2001003547A (en) | 1999-06-25 | 1999-06-25 | Unslippery resin molded board |
Country Status (1)
Country | Link |
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JP (1) | JP2001003547A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005105707A (en) * | 2003-09-30 | 2005-04-21 | Arisawa Mfg Co Ltd | Hydrophilic pasting decorated material |
JP2009264060A (en) * | 2008-04-28 | 2009-11-12 | Glass Cube:Kk | Light floor system, set for light floor, and construction method of light floor |
-
1999
- 1999-06-25 JP JP11180283A patent/JP2001003547A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005105707A (en) * | 2003-09-30 | 2005-04-21 | Arisawa Mfg Co Ltd | Hydrophilic pasting decorated material |
JP2009264060A (en) * | 2008-04-28 | 2009-11-12 | Glass Cube:Kk | Light floor system, set for light floor, and construction method of light floor |
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