JP2000355533A - Product for bathing use - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a product for bathing use capable of satisfying playful mind and giving amusing or pleasure feeling to everyone taking a bath by providing a plurality of chipped bath preparations and a plurality of the corresponding containers for the preparations. SOLUTION: This product for bathing use is obtained by providing (A) a plurality of chipped bath preparations 1a-1c and (B) a plurality of the corresponding containers 2a-2c for the preparations each consisting mainly of pref. a water- soluble base material (e.g. pullulan). The component B is desirably arranged so as to be in layers or in an engagedly manner. The shape of the component A may have a plant body shape, flower-like shape, petaloid shape or the like, and the component B may be in a polyhedral shape, spherical shape, columnar shape or the like. The components A and B may each contain any of perfumes, coloring agents, inorganic salts, organic acids, moisturizers, moisture absorbents, saccharides, higher fatty acids, oils, surfactants, foaming agents, physiologically active substances, enzymes, and crude drugs.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to bath products.
More specifically, the present invention relates to a bath product comprising a plurality of small bath agents and a plurality of storage bodies capable of storing the same.

[0002]

2. Description of the Related Art Bath preparations are classified into forms such as powders, granules, tablets, soft capsules and liquids. Normally, bath preparations contain active ingredients of hot springs, and exert various effects such as a heat retention effect, a blood circulation promoting effect, a fatigue recovery effect, a beautiful skin effect, and a cleansing skin. In addition,
The function of the bath agent is described in, for example, JP-A-4-24381.
No. 8 and Japanese Patent Application Laid-Open No. 9-24951, etc., in order to increase the enjoyment of bathing, bath salts are stored in soft capsules with popular characters. There has been proposed a bath agent in which a bonus that attracts the interest of people is enclosed. Further, examples of bath agents that give a bather an auditory enjoyment include bath agents that generate gas such as carbon dioxide gas, and bath agents that incorporate an aromatic agent that imparts an olfactory enjoyment. However, although these conventional bath agents provide bathers with a certain level of fun and fun of bathing, they are not simple baths and have unexpected surprises for bathers.

[0003]

DISCLOSURE OF THE INVENTION The present invention relates to a bath preparation which can provide a bather with unexpected surprises, and can provide the bather with a playfulness, fun and enjoyment of bathing. It is an object to provide a new bath product.

[0004]

Means for Solving the Problems The present inventors have solved the above-mentioned problems by providing a plurality of small bath additives and a bath product comprising a plurality of storage bodies capable of storing the same. I do. By making the bath product of the present invention water-floating or non-water-floating, the bath product can be varied. The flake-shaped bath agent stored in the bath product of the present invention can be made to be a water-floating or non-water-floating type, or a color, a shape, a fragrance, and the like can be diversified to provide a more varied bath product. . Further, when each of the plurality of containers is formed of a water-soluble base material having a different dissolution rate in hot water, at a predetermined time interval, the small-sized bath agent is discharged from the containers in the hot water. To the visual,
It can be an olfactory or aurally interesting bath product. Further, when an effective ingredient usually used for a bath agent is blended with the above-mentioned small bath agent, there is also a merit that the original effect of the bath agent can be expected.

[0005]

DETAILED DESCRIPTION OF THE INVENTION A plurality of flaky bath agents of the present invention;
A part of a base material constituting a bath product provided with a plurality of storage bodies capable of storing the same (hereinafter, simply referred to as “bath product of the present invention” unless otherwise specified) is a part thereof. Alternatively, a water-insoluble substrate such as plastic, wood, paper, or cloth can be used for the whole, but it is usually preferable to use a water-soluble substrate for a part or the whole thereof. Such water-soluble bases include, for example, natural and synthetic water-soluble compounds such as pullulan, carrageenan, agar, gelatin, polyvinyl alcohol, polyvinyl acetate partial oxide, polyvinyl alcohol partial butyrate, and vinylpyrrolidone-vinyl acetate copolymer. A polymer can be used as appropriate.
These water-soluble polymers can be used alone or in appropriate combination of two or more kinds. By appropriately selecting the type of the water-soluble base material, processing conditions, and the like, the time during which the bath product of the present invention dissolves in hot water and the time during which the components are released into the hot water can be arbitrarily controlled.

In the present invention, of the water-soluble polymers, biodegradable pullulan can be used more preferably. Pullulan is maltotriose, a kind of trisaccharide, is α-
A water-soluble polysaccharide having a molecular weight of about 10,000 to 1,000,000 polymerized by 1,6 bonds and, for example, a microorganism having a pullulan-producing ability such as Aureobasidium pullulans or Aureobasidium fermentans is used as a glucose, Culture in a nutrient medium using saccharides such as fructose, sucrose, maltose, and partially decomposed starch as a carbon source, remove cells from the culture by filtration, etc., and if necessary, concentrate, separate, precipitate, etc. It can be prepared by removing the body and then purifying, drying and pulverizing. As a method for preparing pullulan, for example, JP-B-51-3636
No. 0, JP-B-51-42199, JP-B-54
No. 14,678, JP-A-6-65302, and the like, and the pullulan obtained by these methods can be suitably used in the present invention. Also, "PI20" sold by Hayashibara Shoji Co., Ltd.,
Purified or partially purified pullulan products such as "PF20" and "Trigluco-A" can be used in the present invention without special processing.

In the present invention, the pullulan itself,
Alternatively, the water-soluble derivatives thereof can be used alone or in combination of two or more. The water-soluble derivative of pullulan can be produced by chemically reacting pullulan with an appropriate reagent. Pullulan and water-soluble derivatives are safe substances widely used in the fields of food, cosmetics, pharmaceuticals and the like. Specific examples of the water-soluble derivative of pullulan include an esterified product and an etherified product of pullulan. More specifically, carboxylic acid ester, phosphoric acid ester, alkyl ether, carboxymethyl ether, aminoalkyl ether, hydroxypropyl ether and the like of pullulan can be mentioned. As a method for preparing a water-soluble derivative of pullulan, for example, Japanese Patent Publication No. 52-22029 and Japanese Patent Publication No. 52-78286
And the methods described in JP-A-53-58589. Generally, the water-soluble derivative of pullulan, the water solubility decreases as the degree of substitution of the substituent to be introduced increases, by adjusting the degree of substitution,
It has the advantage that the rate of dissolution in water can be adjusted arbitrarily.

[0008] The water-soluble base material is usually used in the form of a small bath agent or a container in the bath product of the present invention.
In terms of anhydride, about 1 to 99 w / w% (hereinafter, “w / w%” is abbreviated as “%” unless otherwise specified), preferably about 20 to 99%, more preferably About 30
To 99%, more preferably about 40 to 99%. By appropriately adjusting the blending amount of pullulan and / or its water-soluble derivative, or by appropriately selecting the type of water-soluble derivative of pullulan, or by appropriately selecting molding processing conditions, The dissolution rate, dissolution time, and specific gravity of the agent and the container in hot water can be arbitrarily adjusted. Usually 3 to 600 seconds, preferably 10 to
The range is 300 seconds, more preferably 30 to 300 seconds. It is also possible to mix one or more components of a commonly used bath agent into the water-soluble base material itself.

The plurality of containers in the bath product of the present invention may be formed of the same kind of water-soluble base material, or may be formed using water-soluble base materials having different dissolution rates in hot water. Good. When the container is formed using a water-soluble base material having a different dissolution rate in hot water, the small-sized bath agent stored in the container is automatically and sequentially placed in the hot water at a predetermined time interval. It can be released, resulting in a more varied bath product. The shape of the container is formed in a multilayer polyhedron shape, multilayer spherical shape, multilayer cylindrical shape, multilayer cone shape, multilayer rod shape, or the like. The individual storage bodies may have the same shape or different shapes. Further, when the plurality of containers are fitted and arranged in another layer, and a small piece of bath agent is filled between the containers, the small portion of the inside of the container is filled with the small piece of bath agent. It may or may not be filled, but it is preferable to make it hollow to give the bath product of the present invention greater buoyancy. When the container and the flaky bath agent are formed using a water-soluble base material having a different water solubility, the various flaky bath agents spread on the surface of the bath at a predetermined time interval during use, and The bather, while enjoying the small tubules visually, olfactory or visually, while imagining the next released small tub bath, You can enjoy the flaky bath agent. In addition, various tangible objects including processed products such as plants, leaves, flowers, and petals can be stored in the plurality of storage bodies, in addition to the small bath preparation. Further, regarding the base material constituting the strip-shaped bath agent of the present invention, all may be formed of the same type of base material or different types of base materials. In the latter case, for example, in the case of forming individual small-sized bath agents with different water-soluble base materials each having a different dissolution rate in hot water, small flakes prepared with a water-soluble base material having a high dissolution rate in hot water are used. After the bath agent first dissolves in hot water and disappears, or almost in parallel with this, the small-sized bath agent prepared from a water-soluble base material that dissolves in water secondarily dissolves in hot water. , Disappears. Therefore, the bather can sufficiently enjoy a wide variety of bathing agents that change visually, audibly, or olfactoryly in a single bathing.

The components which can be incorporated into the bath product of the present invention will be described in detail.
Organic acid salts, humectants, enzymes, bioactive substances, extracts, crude drugs, sugars, higher fatty acids, higher alcohols,
One or more components selected from esters, oils, surfactants, vitamins and foaming agents can be mentioned.
These components can be used alone or in combination of two or more.

In the above components, the sugars include glucose,
Fructose, trehalose, isomerized sugar, honey, maple syrup, maltose, isomaltose, sucrose, lactose, lactose, palatinose, neotrehalose, maltotriose, panose, raffinose, glucosyl trehalose, lactose sucrose,
One kind of sugar such as isomaltooligosaccharide, soybean oligosaccharide, fructooligosaccharide, lactose fructose oligosaccharide, starch syrup, cyclodextrin, and sugar alcohol such as erythritol, xylitol, sorbitol, maltitol, lactitol, palatinit, and reduced starch decomposed product Alternatively, two or more types are appropriately selected.

Among the above-mentioned saccharides, α, α-, α, β-, and β, β-trehalose, which have particularly excellent moisturizing effects on the skin and beautiful skin effects, can be suitably used. (Hereinafter, unless otherwise noted, trehalose is simply α, α
-, Α, β- or β, β-trehalose, or a mixture of two or more thereof. ). Among the trehaloses, α, α-trehalose includes, for example, trehalose obtained by extracting from yeast described in JP-A-7-246097, and JP-A-58-21695.
, Α-α-trehalose from maltose by the phosphorylase method described in
Α, α- by starch enzymatic saccharification described in 170977 and JP-A-7-213283.
Various trehaloses such as trehalose can be appropriately employed.
The use of commercially available high-purity α, α-trehalose hydrous crystals, high-purity α, α-trehalose anhydrous crystals, or the like can also be employed as appropriate. For example, high-purity α, α-trehalose hydrated crystal (registered trademark “Trehaose”) sold by Hayashibara Corporation can be advantageously used as inexpensive high-quality trehalose.

[0015] Trehalose also has a function of stabilizing various components to be added to the flaky bath agent in the bath product of the present invention. The amount of trehalose is usually
About 0.1 to 99%, preferably about 1 to 90%, more preferably about 10 to 80%, more preferably about 1 to 90%, in terms of an anhydride, of the small bath agent contained in the bath product of the present invention. Desirably, it is desirable that the content be in the range of about 30 to 70%. However, the amount of trehalose is determined by the size (total weight) of the flaky bath agent contained in the bath product of the present invention.
Can be set appropriately according to the conditions.

The vitamins that can be incorporated in the bath product of the present invention include vitamin A, vitamin B, vitamin C, vitamin D, vitamin E, vitamin F, vitamin K, vitamin P, and vitamin U. , Carnitine, ferulic acid, γ-oryzanol, lipoic acid and their derivatives, or one or more of them.

[0015] Among the above vitamins, L-ascorbic acid has the effects of whitening and whitening skin, preventing skin weakening, preventing petechiae, preventing ecchymosis and promoting blood circulation. Can be suitably used. As long as L-ascorbic acid can be used in the bath product of the present invention, its origin and properties are not limited.
Not only L-ascorbic acid obtained by natural or organic synthesis, but also JP-B-48-38158, JP-B-58-5920, JP-A-58-198498, JP-A-3-139288, Kaihei 3-135
L-ascorbic acid derivatives disclosed in Japanese Patent Application No. 992 and Japanese Patent Application No. 10-101855 can be used. Of these L-ascorbic acid derivatives, JP-A-3-139288 and JP-A-3-1359
Α-Glycosyl ascorbic acid disclosed in JP-A-92-92 can be advantageously used as stable L-ascorbic acid. α-Glycosyl ascorbic acid has excellent heat resistance, light resistance and high solubility in water, as compared with L-ascorbic acid, and thus can be suitably used for the bath product of the present invention.

The amount of L-ascorbic acid and a derivative thereof to be added to the bath product of the present invention is usually about 0.5 as an anhydride, based on the flake-form bath agent stored in the bath product of the present invention. 001 to 70%, preferably about 0.01
It is preferably in the range of about 50%, more preferably about 0.1% to 30%, and even more preferably about 1% to 20%. However, the amount of L-ascorbic acid and its derivative can be appropriately set according to the size (total weight) of the small-sized bath agent contained in the bath product of the present invention.

Hesperidin can also be suitably used as another vitamin which can be added to the bath product of the present invention. Hesperidin has an effect of alleviating or relieving skin whitening and whitening, moisturizing the skin, preventing skin weakness, preventing petechiae, preventing ecchymosis, promoting blood circulation, recovering from fatigue, chilling, and stiff shoulders. The origin and properties of the hesperidin used for this purpose are not limited as long as it can be used in the bath product of the present invention. Such hesperidin is of course naturally derived, and for example, α-glycosyl hesperidin described in JP-A-3-7593 is significantly improved in water solubility as compared with hesperidin. In the present invention, it can be suitably used. α-Glycosyl hesperidin can be suitably used in the present invention because it has advantages of higher stability and higher solubility in water than hesperidin. When hesperidin and / or α-glycosyl hesperidin are used in combination with L-ascorbic acid, an excellent effect of mutually enhancing the biological activities of both is exerted.

The amount of hesperidin and α-glycosyl hesperidin to be incorporated in the bath product of the present invention is usually about 0.001 in terms of an anhydride, based on the flaky bath agent contained in the bath product of the present invention. To 70%, preferably about 0.01 to 50%, more preferably about 0.1 to 50%.
It is preferably in the range of about 30%, more preferably about 1-20%. However, the amount of L-ascorbic acid and its derivative can be appropriately set according to the size (total weight) of the small-sized bath agent contained in the bath product of the present invention.

Other vitamins that can be added to the bath product of the present invention include rutin. Rutin is excellent for skin whitening and whitening, moisturizing the skin, preventing skin weakening, preventing petechiae, preventing ecchymosis, promoting blood circulation, relieving fatigue, chilling, stiff shoulders, etc. It works.

The origin and properties of rutin used for this purpose are not limited as long as it can be used in the present invention.
Such rutin, of course, is of natural origin,
For example, JP-A-3-27293 and JP-A-3-27293
Α-Glycosyl described in 115292
Since rutin has higher stability than rutin and has significantly improved water solubility, it can be suitably blended with the bath product of the present invention. Rutin and / or α-
The combination of glycosyl rutin and L-ascorbic acid is
An excellent effect of mutually enhancing both physiological activities can be expected.

The compounding amount of rutin and α-glycosyl rutin which can be added to the bath product of the present invention is usually about 0. 001 to 70%, preferably about 0.01
It is preferably in the range of about 50%, more preferably about 0.1% to 30%, and even more preferably about 1% to 20%. However, the amount of L-ascorbic acid and its derivative can be appropriately set according to the size (total weight) of the small-sized bath agent contained in the bath product of the present invention.

Colorants that can be incorporated into the bath product of the present invention include natural pigments such as carotene, chlorophyll, and riboflavin, and blue # 1, blue # 2, yellow # 4, yellow # 202- (1), and green No. 201, green No. 204, etc., and these colorants are usually used in an amount of about 0.0001 to 0.001 in terms of anhydride with respect to the flaky bath agent contained in the bath product of the present invention. 5%, preferably about 0.001 to 5%.

Similarly, examples of the fragrance include natural fragrances such as citrus fragrances and herbs, and synthetic fragrances. Usually, anhydrous fragrances are used for the flaky bath preparations stored in the bath product of the present invention. It is blended at a ratio of about 0.0001 to 5%, preferably about 0.001 to 5% in terms of a product.

Examples of the inorganic / organic acid salts include sodium hydrogen carbonate, sodium carbonate, potassium carbonate, magnesium carbonate, sodium hydrogen carbonate, sodium percarbonate, heavy magnesium carbonate, hot water, borax, sodium chloride, sodium sulfate, and the like. Potassium sulfide, sodium sulfide, calcium oxide, potassium nitrate, sodium nitrate,
Calcium nitrate, iron sulfite, aluminum sulfate, metasilicic acid, anhydrous silicic acid, neutral clay, sodium thiosulfate, benzoic acid, sodium polyphosphate, potassium soap, calcium hydrogen phosphate, sodium salicylate, sodium sesquicarbonate, potassium bromide, chloride Potassium, ammonium chloride, iron sulfate, slaked lime, artificial callus salts, potassium permanganate,
Sodium phosphate, sodium hyposulfite, calcium thiosulfate, sodium hydroxide, mica powder, inorganic salts such as sulfur, and succinic acid, malic acid, citric acid, tartaric acid,
Examples thereof include inorganic acid salts such as organic acids such as fumaric acid. These inorganic / organic acid salts may be used alone or in combination of two or more, usually in an amount of about 1 to 70%, preferably 5 to 5%, in terms of anhydride, with respect to the flaky bath agent contained in the bath product of the present invention. -50%, more preferably 5-40%
It is blended in the range. Further, among the inorganic / organic acid salts, one or more carbonates such as sodium hydrogen carbonate, sodium carbonate, potassium carbonate, magnesium carbonate, sodium percarbonate, heavy magnesium carbonate, sodium hydrogen carbonate, and / or succinic acid , Malic acid, citric acid, tartaric acid,
When one or more organic acids such as fumaric acid are used, the bath product of the present invention can be a foamable bath product.

Examples of humectants include glycerin, propylene, glycol, sodium lactate, sodium pyrrolidonecarboxylate, polyethylene glycol, carboxymethylcellulose, dextrin, guar gum, quince seed gum, carrageenan, alginic acid, arabinogalactan gum, serine, chitosan , Maltotil, galactosamine, lactic acid culture, urea, aquaizer E
Components selected from J, pectin, soluble collagen, elastin, sodium hyaluronate, chondroitin sulfate, aspartic acid and the like can be mentioned. These components can be used alone or in combination of two or more. These humectants are usually used in an amount of about 0.
0001 to 40%, desirably about 0.001 to 3
0%, more preferably, about 0.01 to 20%.

Examples of the foaming agent include sodium bicarbonate, potassium bicarbonate, sodium carbonate, potassium carbonate, calcium carbonate, magnesium carbonate, sodium sesquicarbonate, sodium chloride, potassium chloride, ammonium chloride, slaked lime, calcium hydroxide, water Sodium oxide, titanium oxide, calcium oxide, magnesium oxide,
Examples thereof include components selected from inorganic salts such as potassium nitrate, sodium nitrate, calcium nitrate, borax, aluminum sulfate, sodium sulfate, magnesium sulfate, calcium thiosulfate, calcium hydrogen phosphate, and sodium phosphate. These components can be used alone or in combination of two or more. These foaming agents are usually used in an amount of about 0.0001 to 40%, preferably about 0.001 to 30%, more preferably about 0.001 to 40% in terms of an anhydride, based on the flaky bath agent contained in the bath product of the present invention. Is blended at a ratio of about 0.01 to 20%. The foaming agent imparts visual and auditory enjoyment to the bath product of the present invention.

Examples of the enzymes include proteolytic enzymes, cellulases, polysaccharide synthases, dextranase, pectin degrading enzymes, naringinase, catalase, urokinase, lipolytic enzymes, amylolytic enzymes, pancreatin, lysozyme chloride and the like. Can be. These enzymes are usually used in an amount of about 0.0001 to 40%, preferably about 0.001 to 30%, more preferably about 0.0001 to 40% in terms of an anhydride, based on the small-sized bath agent contained in the bath product of the present invention. Is blended at a ratio of about 0.01 to 20%.

Examples of physiologically active substances, extracts and crude drugs include hormones, saponins, naringin, glycosylated naringin, antibiotics, bactericides, turmeric extracts, kakiniku extracts, ginseng extracts, nanten extracts, karin extracts,
Chlorella extract, Aloe extract, Propolis extract, Genoko ginger extract, Citrus extract, Eucalyptus extract, Ende extract, Dokudami extract, Button extract,
One or two or more selected from licorice extract, peonies extract, loquat extract, daisy, elephantwood, lingonberry, aloe, eye, pafia, mugwort, chimpanzee, chamomile, touki, carrot, capsicum, safflower, mint and the like are used as appropriate.

The higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid,
One or more of oleic acid, linoleic acid, linolenic acid, lanolinic acid, isostearic acid and the like are appropriately used.

As the higher alcohol, one or more of lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, cholesterol, 2-hexyldecanol and the like are appropriately used.

As the esters, cetyl octoate,
One or more of myristyl lactate, cetyl lactate, myristyl myristate, isopropyl palmitate, isopropyl adipate, butyl stearate, decyl oleate, cholesterol isostearate and the like are appropriately used.

As the oils, one or more kinds of sugar oils, silicone oils and the like are appropriately used.

As the surfactant, one or more of a nonionic surfactant, an anionic surfactant, an amphoteric surfactant and the like are appropriately used.

As a method for producing the bath product of the present invention, an appropriate base material is formed by a method such as adhesive processing, compression molding, pressure molding, mold molding, spreading method, nonwoven fabric processing method, and spinning method. can do. The thickness of the strip-shaped bath agent stored by the bath product of the present invention, and the thickness of the storage body constituting the bath product of the present invention are usually about 0.1 to 10 mm, preferably about 0.3 to 5 mm, more preferably about 0.5 to
3 mm. When each of the storage bodies is fitted and arranged in layers, the gap between the storage bodies is usually 0 to 100.
mm, preferably 0 to 50 mm, more preferably 0 mm
３０30 mm. In addition, the volume of each container is about 1 to 5
It is formed so as to be 00 cm ³ , preferably about 10 to 300 cm ³ , more preferably about 20 to 100 cm ³ . The number of containers in the bath product of the present invention is usually 2
~ 50, preferably 2-20, more preferably
A range of 2 to 10, more preferably 3 to 5, is suitable.

The shape of the small-sized bath agent containing the bath product of the present invention may be a plant, flower, petal, leaf or stem, star, polyhedron, sphere, cone, rod. ,
Examples include scaly, sheet, flake, briquette, laminate, and popular character shapes that are visually appealing. The size of the flaky bath agent,
What is necessary is just a size which can be stored in the storage body in the bath product of the present invention, and usually, the surface area is 0.01 to 100 cm ² ,
Preferably, 0.1 to 50 cm ² , more preferably, 1
２０20 cm ² are preferred. These flake-shaped bath agents can be produced by, for example, binding, punching, compression molding, pressure molding, mold molding, spreading, nonwoven fabric processing, spinning, and the like. In the case where such a small-sized bath agent is made water-floating, the compression, pressurizing conditions and the like are appropriately adjusted so that the specific gravity of the finally obtained small-sized bath agent during processing is usually less than 1. Select and mold. Further, in order to enhance the buoyancy of the bath product of the present invention, air, oxygen,
Higher buoyancy can be imparted to the bath product of the present invention by encapsulating an inert gas or gas-filled capsule or the like under normal or pressurized conditions, or by hollow molding a small bath agent. The flake-shaped bath agent may be stored in a storage body in a process until the bath product of the present invention is completed. The number of flake-shaped bath agents containing the bath product of the present invention is usually 3 to
1000 pieces, preferably 10-600 pieces, more preferably 50-300 pieces, even more preferably
A range of 30 to 100 pieces is preferred.

When the container in the bath product of the present invention is, for example, a container having a water-floating quintuple structure composed of a water-soluble base material, when the container is floated on a hot water surface, the quintuple The first outermost part of the structural housing, that is, the first outermost housing that comes into contact with the hot water first melts and is housed in the gap between the first and second housings. Is released and dissolved in hot water. Next, the second container dissolves, and the second piece-like bath agent stored in the gap between the second and third containers is released and dissolved in the hot water. . Hereinafter, in accordance with this procedure, the third and fourth small-sized bath agents filled in the gaps between the plurality of storage bodies in the bath product of the present invention are sequentially released and dissolved in the hot water. It is.

When the bath product of the present invention is floated on hot water, it can be visually and olfactoryly sensed that the flake-shaped bath agent having the same or different color and shape spreads over the bath surface with time and dissolves. In addition to having an objective or auditory enjoyment, the effect of the active ingredient added to the flaky bath preparation has the following effects: whitening and whitening of the skin, moisturizing the skin, preventing weakening of the skin, petechiae Prevention, ecchymosis prevention, blood circulation promotion,
It is effective in relieving fatigue, relieving chills, stiff shoulders, etc.

When the bath product of the present invention is composed of a water-soluble base material and is made non-water-floating, when it is immersed in hot water, the bath product of the present invention can be removed from the bath product of the present invention with the passage of time. The agent is released intermittently or continuously in hot water. At this time, if the flake-form bath agent is water-floating, it rises from the bottom of the tub toward the surface of the bath, so that the bather can change the shape, color and floating of the flake-form bath agent. Can be visually enjoyed. The shape of the bath product of the present invention, of interest to bathers, volcanic shape, conical shape, spherical shape, polyhedral shape, cylindrical shape, cylindrical shape, three-dimensional shape such as rod shape, or
If formed into a popular character shape, the small-sized bath agent released into the hot water from the bath product of the present invention can be made more interesting.

As described above, when the base material of the bath product of the present invention is composed of a water-soluble base material, the water content increases over time.
This bath product is characterized in that the flake-like bath agent is automatically released into the hot water, and is finally completely dissolved in the hot water and disappears. Therefore, the bather can enjoy the bath product of the present invention that changes with time visually, olfactoryly, or audibly while immersed in the hot water. In addition, the bather can enjoy the visualized, olfactory, or auditory sensation of the continuously released flaky bathing agent in a relaxed state, while effectively mixing the flaky bathing agent of the present invention. Skin whitening and whitening due to ingredients and warm bath effect, moisturizing skin,
It is possible to simultaneously enjoy the effects of cleansing the skin, preventing skin weakness, preventing petechiae, preventing ecchymosis, promoting blood circulation, relieving fatigue, relieving or relieving stiffness, stiff shoulders, and the like.

Hereinafter, the present invention will be described with reference to experimental examples.

[0041]

[Experimental example] <Panel test> Using the bath products prepared by the methods of Examples 1 to 4, 50 healthy men and women, 25
Names (ages 18 to 50) were bathed, and a questionnaire survey was conducted on the feeling of use. The results are shown in Table 1.

[0042]

[Table 1]

As is clear from the results shown in Table 1, the bath product of the present invention can be said to be an excellent bath product that gives bathers pleasure in bathing, fun, and satisfaction.

Hereinafter, the present invention will be described in more detail with reference to Examples.

[0045]

Example 1 Pullulan acetate (substitution degree: about 1.5) 4
0 parts by weight, trehalose 20 parts by weight, L-ascorbic acid 10 parts by weight, α-glycosyl rutin 10 parts by weight, rose flavor 5 parts by weight, sodium carbonate 2 parts by weight, purified water 25
Parts by weight and then rolled to a thickness of about 1 mm at a roll pressure of 75 kg / cm ² by a known method, and then using a rose petal (about 2 cm × about 1 cm) punching die. This was punched out to obtain a small bath agent. on the other hand,
One side of the bottom is about 3 cm, about 7 cm or about 10 cm as a water-soluble storage body for storing the small bath agent.
A three-layered rod having a star shape and a height of about 3 cm, about 7 cm and about 10 cm was obtained by molding. The thickness of each container was about 1.5 mm. The upper portion of each of the storage bodies is opened, and the insides of the storage bodies are sequentially filled with the petals of the rose petal-like small bath agent, and the openings are closed with a pullulan film (thickness 0.5 mm). A bath product was obtained. FIG. 1 shows a cross-sectional view of this product. FIG.
Among them, 1 (a), 1 (b) and 1 (c) mean small-sized bath agents, and 2 (a), 2 (b) and 2 (c) mean containers.

When this product is floated on a hot water surface, the outermost container dissolves in hot water, then the second and third containers dissolve sequentially, and a petal-like bath agent for rose petals is dissolved. It spreads almost concentrically on the surface of the hot water, and the fragrance of roses stands all over the bathroom, so that bathers can enjoy the atmosphere of a rose garden visually and smell. In addition, the various active ingredients contained in this product are dissolved in hot water, and these active ingredients and the effect of the warm bath are exerted, resulting in whitening and whitening of the skin, moisturizing the skin, cleansing the skin, Excellent effects such as prevention of weakness, prevention of petechiae, prevention of ecchymosis, warming effect, promotion of blood circulation, recovery from fatigue, relieving or relieving coldness, stiff shoulders and the like are exhibited.

[0047]

Example 2 Pullulan acetate (degree of substitution: about 1.5) 5
0 parts by weight, 30 parts by weight of trehalose, 10 parts by weight of L-ascorbic acid, 6 parts by weight of α-glycosyl hesperidin, 3 parts by weight of jasmine flavor, 0.2 parts by weight of Blue No. 1,
20 parts by weight of purified water are mixed, then coated on a polyester film, dried at 45 ° C., peeled from the polyester film, and cut into a jasmine flower shape (about 1 cm × about 1.3 cm) using a punching die. And punched out to obtain a flake bath agent of the present invention. On the other hand, using pullulan acetate (degree of substitution about 1.0), a diameter of about 15 cm,
A water-soluble container (about 2 m thick) having a columnar shape with a height of about 1.5 cm and a partition plate that divides the interior into six equal parts at an angle of 60 degrees.
m) was obtained by casting. Inside this water-soluble container,
The flower-shaped flake bath agent was filled. Separately, a water-soluble container manufactured in the same manner as described above except that pullulan was used in place of the pullulan acetate (substitution degree: about 1.5) was used for the petal-shaped bath of rose petals obtained in Example 1. The agent was stored. The water-soluble container is bound using a binder so that the water-soluble container is located below the water-soluble container, and the upper opening is formed to a thickness of 2 mm.
The film was occluded with a 0.2 mm pullulan acetate (degree of substitution: about 1.5) film to obtain a bath product of the present invention. FIG. 2 shows a side view of this product. In FIG. 2, 1 (a) and 1 (b) denote a small flake bath agent, 2 (a) and 2 (b) denote a container, and 3 denotes a partition plate.

This product floats in a state of sinking below the surface of the water. First, the water-soluble container of the upper layer, which has a high dissolution rate, is dissolved in hot water, and the petals of a rose petal-like small piece-like bath agent are concentrically formed. The jasmine flower-shaped flake-shaped bath agent filled in the lower layer of the water-soluble container floats and dissolves substantially concentrically on the surface of the water. The bather floats and dissolves in the hot water, and can enjoy the small-sized bath preparations having different colors, fragrances, and shapes visually and olfactory over time. Next, the various active ingredients blended in the flaky bath agent are dissolved in hot water, and these active ingredients and the warm bath effect are exerted, skin whitening and whitening, skin whitening and whitening, Excellent effects such as moisturizing the skin, purifying the skin, preventing skin weakness, preventing petechiae, preventing ecchymosis, warming effect, promoting blood circulation, recovering from fatigue, relieving or relieving coldness, stiff shoulders, etc. Is done.

[0049]

Example 3 Pullulan phosphate (degree of substitution: about 1.2)
35 parts by weight, trehalose 30 parts by weight, L-ascorbic acid 5 parts by weight, α-glycosyl hesperidin 10 parts by weight, α-glycosyl rutin 1 part by weight, rosemary flavor 4 parts by weight, Green 201 No. 1 part by weight, purified water 20 The weight parts were mixed, and then tablet-formed into a star-shaped hollow body (major axis: about 1 cm, thickness: about 1 mm) by a known method to obtain a flake-shaped bath agent. On the other hand, using polyvinyl alcohol,
Approximately conical volcano-shaped water-soluble container (diameter of bottom is about 12c)
m, height of about 12 cm, thickness of 5 mm) and a similar volcanic type water-soluble storage body (bottom diameter of about 7 cm, height of about 6 cm, thickness of 4 mm), and a double-structured storage body. Obtained by compression molding. On top of these two water-soluble containers,
An opening having a diameter of 3 cm is provided, the star-shaped bath salt agent is placed in the outer container, and the petal-shaped rose petal bath rose obtained by the method of Example 1 is placed in the inner container. The agent was filled, and each opening of these containers was closed with a pull-run film having a thickness of 1 mm. The specific gravity of this product was about 1.5. In FIG. 3, 1 (a) and 1 (b) denote a small flake bath agent, 2 (a) and 2 (b) denote a container, and 4 denotes a bubble.

When this product is submerged in the bathtub, air inside the container is blown out as bubbles from the opening provided in the upper part of the volcano-type structure, and the star-shaped and rose petal-shaped flake-shaped bath agent is discharged. Is released into the hot water at regular intervals. Therefore, the bather can fully enjoy the fragrance of the flowers standing in the bathroom while visually enjoying the product. Furthermore, various active ingredients blended in the flaky bath agent are dissolved in hot water, and these active ingredients and the effect of the hot bath are exerted.
Skin whitening and whitening, skin whitening and whitening, moisturizing skin, cleansing skin, preventing skin weakness,
Excellent effects such as prevention of petechiae, prevention of ecchymosis, warming effect, promotion of blood circulation, recovery from fatigue, relieving or relieving coldness, stiff shoulders and the like are exhibited.

[0051]

Example 4 Three types of small-sized bath agents were prepared by the methods of Examples 1 to 3, and these small-sized bath agents were prepared using pullulan phosphate (substitution degree: about 1.5). The capsules were individually housed in capsules (diameter 2 cm) for filling the bath bath. On the other hand, hemispherical bodies having diameters of about 18 cm, 12 cm, 7 cm and 2 cm were obtained by casting using pullulan phosphate (degree of substitution about 1.6). The thickness of each of these semi-spherical bodies was about 1 mm. These hemispherical bodies were sequentially superimposed, and a gap between them was filled with a plurality of the above-mentioned three types of capsules for filling small-sized bath agents. This semi-finished product was separately prepared, and both were bound using a binder to obtain a bath product of the present invention. In order to impart buoyancy to the bath product of the present invention, the innermost water-soluble container was hollow. In FIG. 4, 1 (a), 1 (b) and 1 (c) denote the flaky bath preparations as 2 (a), 2 (b), 2 (c) and 2
(D) indicates a housing, 4 indicates a bubble, and 5 indicates a cavity.

When this product consisting of a quadruple-structured container is floated on a hot water surface, the outermost container is first dissolved in hot water, and a plurality of pieces filled with the strip-shaped bath agent obtained by the method of Example 1 are used. These spherical capsules float on the surface of the molten metal, and then these spherical capsules are dissolved, and the above-mentioned small-sized bath agent is released to the surface of the molten metal and spreads over the entire surface. Hereinafter, in the same manner, the small-sized bath preparations obtained by the methods of Example 2 and Example 3 are released onto the surface of the molten metal in this order at predetermined time intervals and spread over the entire surface. Therefore, the bather visually enjoys the three types of small-sized bath agents having different colors, shapes, and dissolution rates sequentially released from the storage body at fixed time intervals, while standing in the bathroom. You can enjoy the scent smell. In addition, various active ingredients blended in this product are dissolved in hot water, and the whitening and whitening of skin, whitening and whitening of skin, moisturizing skin, Excellent effects such as cleansing of the skin, prevention of skin weakness, prevention of petechiae, prevention of ecchymosis, warming effect, promotion of blood circulation, recovery from fatigue, relieving or relieving coldness, stiff shoulders and the like are exhibited.

[0053]

As described above, the bath product of the present invention comprises:
It is a bath product provided with a plurality of storage bodies capable of storing a plurality of small bath agents. The bather can visually, olfactory, or audibly enjoy the bath product that changes over time and / or the small-sized bath agent having a different color, shape, and aroma emitted from the bath product. Furthermore,
Skin whitening and whitening, skin whitening and whitening, skin moisturizing, skin cleansing, skin weakening, produced by the medicinal ingredients and the warm bath effect blended in the flaky bath preparation. Excellent effects such as prevention, prevention of petechiae, prevention of ecchymosis, warming effect, promotion of blood circulation, recovery from fatigue, chilling, stiff shoulder and the like can be enjoyed.

As described above, the bath product of the present invention not only provides the bather with the enjoyment and comfort of bathing, which were lacking in the conventional bath preparations and bath products, but also has the original function of the bath preparation. It can be said to be an ideal bath product that can be played. The bath product of the present invention is a very significant invention as a bath product for refreshing the mind and body in a stressful modern society.

[Brief description of the drawings]

FIG. 1 is a cross-sectional view of a bath product of Example 1 of the present invention.

FIG. 2 is a side view of the bath product of Example 2 of the present invention.

FIG. 3 is a diagram showing a state when the bath product of Example 3 of the present invention is used in hot water.

FIG. 4 is a sectional view of a bath product of Example 4 of the present invention.

[Explanation of symbols]

 1 (a) Small flake bath agent 1 (b) Small flake bath agent 1 (c) Small flake bath agent 2 (a) Container 2 (b) Container 2 (c) Container 2 (d) Container Body 3 Partition plate 4 Bubbles 5 Cavity 6 Capsule for filling small flakes

Continued on front page F-term (reference) 3E014 PA10 PC01 PC07 PC08 PC16 PF10 3E068 AA22 AA35 AB10 AC09 BB02 BB08 CC21 CE05 CE20 EE15 EE32 EE40 4C083 AA111 AB271 AB312 AC231 AC241 AC792 AD191 AD212 AD392 AD471 AD642 BB01 BB21 BB11 BB11 DD21 BB11 DD21 EE06 EE07 EE42 FF06

Claims (10)

[Claims] 1. A bath product comprising a plurality of small bath agents and a plurality of storage bodies capable of storing the same. 2. The bath product according to claim 1, wherein the plurality of small bath agents and the container are mainly composed of a water-soluble base material. 3. The bath product according to claim 1, wherein the plurality of storage bodies are arranged in a layered or fitted state. 4. The bath product according to claim 1, wherein the shape of the container is a polyhedral shape, a spherical shape, a cylindrical shape, a conical shape, a rod shape or a capsule shape. 5. The bath product according to claim 1, wherein each of the plurality of small bath agents and the storage body is formed of a water-soluble base material having a different dissolution rate in hot water. . 6. The bath product according to claim 1, wherein the plurality of small-sized bath agents comprises two or more types of small-sized bath agents. 7. The shape of a plurality of small bath agents may be plant-like, flower-like, petal-like, leaf-like, stem-like, star-like, polyhedral-like, spherical, granular, conical, rod-like, scale-like, and sheet-like. Shape, flake shape, briquette shape, laminate shape, polyhedral shape, spherical shape,
7. The bath product according to claim 1, wherein the bath product has a cylindrical shape, a conical shape, a rod shape or a capsule shape. 8. The method according to claim 8, wherein the plurality of small bath agents and the container contain a fragrance, a coloring agent, an inorganic salt, an organic acid, a humectant, a humectant, a saccharide, a higher fatty acid, an oil, a surfactant, a foaming agent, The bath product according to any one of claims 1 to 7, comprising one or more components selected from a physiologically active substance, an enzyme, and a crude drug. 9. The bath product according to claim 1, which is floating or non-floating in hot water. 10. The method according to claim 1, wherein the plurality of flake-like bath agents are floating or non-floating in hot water.
Bath products as described.