JP2000319349A - Foamable flame retardant composition - Google Patents
Foamable flame retardant compositionInfo
- Publication number
- JP2000319349A JP2000319349A JP11164281A JP16428199A JP2000319349A JP 2000319349 A JP2000319349 A JP 2000319349A JP 11164281 A JP11164281 A JP 11164281A JP 16428199 A JP16428199 A JP 16428199A JP 2000319349 A JP2000319349 A JP 2000319349A
- Authority
- JP
- Japan
- Prior art keywords
- inorganic compound
- foamable
- aqueous film
- forming inorganic
- polyol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、軽量、クッション
性、耐熱性、断熱性、耐候性、耐薬品性に優れ、輸送機
器、土木建築、生活用品、衣料・装身具、スポーツ・レ
ジャー、産業用機器、通信等のあらゆる分野で有用な発
泡性難燃組成物に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is excellent in light weight, cushioning property, heat resistance, heat insulating property, weather resistance and chemical resistance, and is used for transportation equipment, civil engineering construction, daily necessities, clothing and accessories, sports and leisure, and industrial use. The present invention relates to a foamable flame-retardant composition useful in all fields such as equipment and communication.
【０００２】[0002]
【従来の技術】従来より、ポリウレタンフォームは建築
材料をはじめ生活用品全般の幅広い分野で使われている
が、可燃性なため一度着火してしまうと炎が伝播しやす
い欠点があり、建築現場での施工中の火災が報告されて
いる。そのため、このままでは難燃性が要求される建築
材料には適用できず、難燃化の方法として難燃剤の添加
する方法やイソシアヌレート変性した難燃性ポリウレタ
ンフォームが知られている。2. Description of the Related Art Conventionally, polyurethane foam has been used in a wide range of fields such as building materials and daily necessities. However, since it is flammable, once ignited, there is a drawback that a flame easily propagates. A fire was reported during construction. Therefore, it cannot be applied to building materials that require flame retardancy as it is, and a method of adding a flame retardant or a flame-retardant polyurethane foam modified with isocyanurate is known as a method of flame retardation.
【０００３】[0003]
【発明が解決しようとする課題】しかし、難燃剤の添加
による方法では充分に硬質ウレタンフォームの難燃性が
高められず、特に建築材料の分野では使用が困難なもの
であった。また、イソシアヌレート変性した難燃性ポリ
ウレタンフォームは難燃性を高められたものの燃焼時に
煙を伴い発生する青酸ガス、一酸化炭素等の有毒ガスの
問題が改善されているものではなっかた。However, the method of adding a flame retardant does not sufficiently increase the flame retardancy of a rigid urethane foam, and has been difficult to use especially in the field of building materials. In addition, although the isocyanurate-modified flame-retardant polyurethane foam has improved flame retardancy, the problem of toxic gas such as hydrocyanic acid gas and carbon monoxide generated with smoke during combustion has not been improved.
【０００４】本発明は、上記の問題点に鑑みてなされた
ものでその目的とするところは、従来の難燃化法に比
べ、極めて優れた難燃効果を有し、しかも、有害ガスを
伴う煙の発生を低減する発泡性難燃性組成物を提供しよ
うとするものである。SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned problems, and has as its object the purpose of the present invention is to have an extremely excellent flame-retardant effect as compared with the conventional flame-retarding method, and furthermore, it is accompanied by a harmful gas. It is an object of the present invention to provide a foamable flame-retardant composition that reduces the generation of smoke.
【０００５】[0005]
【課題を解決するための手段】発明者は、特許第２０２
８２０３号及び特許第２０１５６９４号として特許さ
れ、また、特願平８−７３２１２号で開示されている水
性造膜性無機化合物の耐火性、断熱性及び特願平１０−
３７７９５０号で開示した有機物に水性造膜性無機化合
物を含浸炭化処理した活性炭が有害ガスの吸着効果に優
れる事等を種々検討を行ったところ、上記目的を達成し
うることを見出し本発明に到達したものである。Means for Solving the Problems The inventor of the present invention has a patent No. 202
No. 8203 and Japanese Patent No. 20156944, and the fire resistance, heat insulation and water solubility of the aqueous film-forming inorganic compound disclosed in Japanese Patent Application No. 8-73212.
Various studies have been made on the fact that activated carbon obtained by impregnating and carbonizing an organic substance with an aqueous film-forming inorganic compound disclosed in 377950 is excellent in the effect of adsorbing harmful gases, and found that the above object can be achieved. It was done.
【０００６】すなわち、本発明の要旨は、イソシアネー
ト，ポリオール等を混合発泡形成させる発泡性組成物に
おいて、水性造膜性無機化合物及び有機物に水性造膜性
無機化合物を含浸炭化処理した活性炭を必須成分として
含有することを特徴とする発泡性難燃組成物にある。That is, the gist of the present invention is to provide a foamable composition in which isocyanate and polyol are mixed and foamed to form an activated carbon obtained by impregnating and carbonizing an aqueous film-forming inorganic compound and an organic substance with an aqueous film-forming inorganic compound. As a foamable flame-retardant composition.
【０００７】建築材料分野で使用される発泡性組成物と
してはポリウレタンフォームが知られているが、この作
業工程はＡ液としてポリオール等に発泡剤、製泡剤、触
媒等を混合し、Ｂ液としてトルエンジイソシアネート
（ＴＤＩ）等をＡ液に添加混合し、充填個所に注入し発
泡させるものである。[0007] Polyurethane foam is known as a foamable composition used in the field of building materials. In this work step, a foaming agent, a foaming agent, a catalyst, etc. are mixed with a polyol as a liquid A, and a liquid B is mixed. In this method, toluene diisocyanate (TDI) or the like is added to and mixed with the solution A, and the mixture is injected into a filling portion and foamed.
【０００８】本発明で使用されるイソシアネートは、一
般に使われているものが使用できる。例えば、トルエン
ジイソシアネート（ＴＤＩ）、ジフェニルメタンジイソ
シアネート（ＭＤＩ）、ジイソシアネートとしては、
１，６−ヘキサメレンジイソシアネート（ＨＤＩ）、
２，２，４−トリメチル−ヘキサメチレンジイソシアネ
ート（ＴＭＤＩ）、４，４’ジシクロヘキシルメタンジ
イソシアネート（ＨＭＤＩ）、ｍ−キシレンジイソシア
ネート（ＸＤＩ）、テトラメチルキシレンジイソシアネ
ート（ＴＭＸＤＩ）、イソフォロンジイソシアネート
（ＩＰＤＩ）、リシンジイソシアネート（ＬＤＩ）、多
官能イソシアネートとしては、ジメチルトリフェニルメ
タン−テトライソシアネート、トリフェニルメタン−ト
リイソシアネート、トリス（イソシアネートフェニル）
−チオフォスフェート、変性イソシアネートとしては、
変性ＴＤＩとして、ウレタン変性ＴＤＩ、アロファネー
ト変性ＴＤＩ、ビウレット変性ＴＤＩ、ＭＤＩと変性Ｔ
ＤＩとの混合物、イソシアヌレート変性体、クルードＴ
ＤＩ、変性ＭＤＩとしては、ウレタン変性ＭＤＩ、カル
ボジイミド変性ＭＤＩ、ウレトニミン変性ＭＤＩ、アシ
ル尿素ジイソシアネートやＴＤＩ／ＭＤＩの混合物、そ
の他の変性イソシアネート等が挙げられる。As the isocyanate used in the present invention, those generally used can be used. For example, as toluene diisocyanate (TDI), diphenylmethane diisocyanate (MDI), and diisocyanate,
1,6-hexamylene diisocyanate (HDI),
2,2,4-trimethyl-hexamethylene diisocyanate (TMDI), 4,4'dicyclohexylmethane diisocyanate (HMDI), m-xylene diisocyanate (XDI), tetramethyl xylene diisocyanate (TMXDI), isophorone diisocyanate (IPDI), lysine Diisocyanate (LDI) and polyfunctional isocyanates include dimethyltriphenylmethane-tetraisocyanate, triphenylmethane-triisocyanate, tris (isocyanatephenyl)
-Thiophosphate, modified isocyanate,
As modified TDI, urethane modified TDI, allophanate modified TDI, biuret modified TDI, MDI and modified TDI
Mixture with DI, modified isocyanurate, crude T
Examples of DI and modified MDI include urethane-modified MDI, carbodiimide-modified MDI, uretonimine-modified MDI, acylurea diisocyanate, a mixture of TDI / MDI, and other modified isocyanates.
【０００９】また、ポリオールも一般に使われているも
のが使用できる。例えば、エポキサイド付加ポリエーテ
ルポリオール、変性ポリエーテルポリオールとしては、
グラフトポリオール、ポリ尿素分散ポリオール、ＰＨＤ
ポリオール、アミン変性ポリオール、ポリテトラメチレ
ンエーテルグリコール（ＰＴＭＥＧ）、ポリエステルポ
リオールとしては、汎用ポリエステルポリオール、ポリ
カプロラクトンポリオール、芳香族ポリエステルポリオ
ール、ポリカーボネートポリオール等が挙げられる。As the polyol, those generally used can be used. For example, as epoxide-added polyether polyol, modified polyether polyol,
Graft polyol, polyurea-dispersed polyol, PHD
Examples of the polyol, amine-modified polyol, polytetramethylene ether glycol (PTMEG), and polyester polyol include general-purpose polyester polyol, polycaprolactone polyol, aromatic polyester polyol, and polycarbonate polyol.
【００１０】さらに、発泡剤、製泡剤、触媒等も例示は
しないが、一般に使われているものを使用でき、これら
の使用量は、目的の発泡生成物の密度に応じ適宜選択す
れば良い。Further, although a foaming agent, a foaming agent, a catalyst and the like are not illustrated, generally used ones can be used, and the amounts of these may be appropriately selected according to the density of the desired foamed product. .
【００１１】水性造膜性無機化合物は、特許第２０２８
２０３号及び特許第２０１５６９４号として特許され、
また、特願平８−７３２１２号で開示されており、優れ
た耐火性、断熱性を有しているが、硼素を含むものを使
用するのが好ましい。An aqueous film-forming inorganic compound is disclosed in Japanese Patent No. 2028.
No. 203 and Patent No. 2015694,
Further, it is disclosed in Japanese Patent Application No. 8-73212 and has excellent fire resistance and heat insulation properties, but it is preferable to use one containing boron.
【００１２】有機物に水性造膜性無機化合物を含浸炭化
処理した活性炭（以下、水性造膜性無機化合物含浸活性
炭という）は、特願平１０−３７７９５０号で開示した
もので、上記の水性造膜性無機化合物の特性を持つ上に
優れた有害ガスの吸着効果も有するので微粉体として使
用することが好ましい。Activated carbon obtained by impregnating and carbonizing an organic substance with an aqueous film-forming inorganic compound (hereinafter referred to as activated carbon impregnated with an aqueous film-forming inorganic compound) is disclosed in Japanese Patent Application No. 10-377950. It is preferably used as a fine powder because it has the properties of a toxic inorganic compound and also has an excellent harmful gas adsorption effect.
【００１３】[0013]
【発明の実施の形態】以下に本発明の実施の形態を説明
するが、本発明は、一般に使用されるＡ液，Ｂ液の２液
混合のポリウレタンフォームに適用可能で下記の実施の
形態に限定されるものではない。DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the present invention will be described below. However, the present invention is applicable to commonly used two-component polyurethane foams of Solution A and Solution B, and is applicable to the following embodiments. It is not limited.
【００１４】本実施形態で使用するポリウレタンフォー
ムは、商品名：フォームライトＨＭ−１０７５，ポリウ
レタン化成（株）製造で、予めＡ液，Ｂ液の２液に処方
されたものを使用した。Ａ液（ポリオール）１００重量
部に水性造膜性無機化合物５０重量部及び水性造膜性無
機化合物含浸活性炭２５重量部を混合したものに、Ｂ液
（ポリイソシアネート）１００重量部をＢ液として、液
温２０℃で混合し１０秒撹拌し発泡を行った。また、Ｂ
液（ポリイソシアネート）に水性造膜性無機化合物及び
水性造膜性無機化合物含浸活性炭をに混合させたものに
Ａ液（ポリオール）を混合して発泡させた場合、発泡す
るがフォームの均一性においてはＡ液（ポリオール）に
水性造膜性無機化合物及び水性造膜性無機化合物含浸活
性炭を混合しＢ液（ポリイソシアネート）と混合発泡し
た方が好ましい結果が得られた。得られた発泡体をバー
ナーにより着火したが発泡体の発する炎は小さく延焼し
なかった。また、発煙量及び刺激臭もごくわずかであっ
た。さらに、バーナーの火を消すと発泡体の発する炎は
数秒で鎮火した。The polyurethane foam used in the present embodiment was manufactured by Formlite HM-1075, manufactured by Polyurethane Chemical Co., Ltd., and was previously formulated into two liquids, liquid A and liquid B. 100 parts by weight of liquid A (polyol) mixed with 50 parts by weight of an aqueous film-forming inorganic compound and 25 parts by weight of activated carbon impregnated with an aqueous film-forming inorganic compound, and 100 parts by weight of liquid B (polyisocyanate) as liquid B The mixture was mixed at a liquid temperature of 20 ° C. and stirred for 10 seconds to foam. Also, B
When a liquid (polyisocyanate) mixed with an aqueous film-forming inorganic compound and activated carbon impregnated with an aqueous film-forming inorganic compound is mixed with liquid A (polyol) and foamed, foaming occurs but the uniformity of the foam is increased. A preferable result was obtained by mixing the aqueous film-forming inorganic compound and the activated carbon impregnated with the aqueous film-forming inorganic compound with the liquid A (polyol) and foaming the mixture with the liquid B (polyisocyanate). The obtained foam was ignited by a burner, but the flame generated by the foam was small and did not spread. In addition, the amount of smoke and the irritating odor were very small. In addition, when the burner was extinguished, the foam emitted a flame in a few seconds.
【０００１４】これは、一般のポリウレタンフォームの
燃焼が、化合物の発火に伴い熱分解し、可燃性の気体を
発生することにより、さらに燃焼部分が広がり、新たに
化合物を熱分解するというサイクルで行われていると考
えられているが、水性造膜性無機化合物の優れた耐火性
及び断熱性により熱分解を抑制し可燃性の気体の発生を
抑え、水性造膜性無機化合物含浸活性炭により炭化膜層
が出来やすく、燃焼部の広がりを防ぐ効果と活性炭の優
れた吸着効果により有害ガスを伴う煙の発生を低減する
ものと思われ、本発明の発泡性難燃組成物は難燃効果と
煙の低減に効果があることがわかる。[00014] This is a cycle in which the combustion of general polyurethane foam is thermally decomposed with the ignition of the compound to generate a flammable gas, so that the combustion portion is further expanded and the compound is newly pyrolyzed. It is thought that the excellent fire resistance and heat insulation of the aqueous film-forming inorganic compound suppresses thermal decomposition and suppresses the generation of flammable gas, and the carbonized film is formed by activated carbon impregnated with the aqueous film-forming inorganic compound. It is thought that the foamable flame-retardant composition of the present invention has a flame-retardant effect and a smoke formation due to the effect of preventing the spread of the combustion part and the excellent adsorption effect of the activated carbon. It can be seen that there is an effect on the reduction of
【００１５】[0015]
【発明の効果】本発明によれば、従来の難燃化法に比
べ、極めて優れた難燃効果を有し、しかも、有害ガスを
伴う煙の発生を低減する発泡性難燃性組成物を提供でき
る。よって、本発明の組成物から得られるウレタンフォ
ームは、建築材料の分野では極めて有用なものである。According to the present invention, there is provided a foamable flame-retardant composition which has an extremely excellent flame-retardant effect as compared with the conventional flame-retardant method, and further reduces the generation of smoke accompanied by harmful gases. Can be provided. Therefore, the urethane foam obtained from the composition of the present invention is extremely useful in the field of building materials.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ０８Ｌ 75/08 Ｃ０８Ｌ 75/08 //(Ｃ０８Ｇ 18/48 101:00） Ｆターム(参考） 4F074 AA78 AC02 AC33 BA01 BA31 CA11 CA12 CA13 CA23 CC25X DA18 DA32 DA36 DA38 DA47 DA59 4J002 CK021 DK006 FD136 GC00 GL00 GN00 4J034 DA01 DB03 DB07 DF01 DF02 DF12 DG02 DG06 DG14 DQ01 HA01 HA07 HA09 HB03 HB06 HB07 HB08 HB09 HB15 HC03 HC09 HC12 HC17 HC22 HC25 HC26 HC34 HC35 HC44 HC46 HC52 HC61 HC64 HC65 HC67 HC71 HC73 MA01 MA03 QB17 RA03 RA10 RA15 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C08L 75/08 C08L 75/08 // (C08G 18/48 101: 00) F-term (Reference) 4F074 AA78 AC02 AC33 BA01 BA31 CA11 CA12 CA13 CA23 CC25X DA18 DA32 DA36 DA38 DA47 DA59 4J002 CK021 DK006 FD136 GC00 GL00 GN00 4J034 DA01 DB03 DB07 DF01 DF02 DF12 DG02 DG06 DG14 DQ01 HA01 HA07 HA09 HB03 HCBHC HCB HCB HC HC HC HC44 HC46 HC52 HC61 HC64 HC65 HC67 HC71 HC73 MA01 MA03 QB17 RA03 RA10 RA15
Claims (1)
泡形成させる発泡性組成物において、水性造膜性無機化
合物及び有機物に水性造膜性無機化合物を含浸炭化処理
した活性炭を必須成分として含有することを特徴とする
発泡性難燃組成物。1. A foamable composition for forming and foaming a mixture of isocyanate, polyol and the like, characterized in that it contains, as an essential component, an activated carbon obtained by impregnating and carbonizing an aqueous film-forming inorganic compound with an aqueous film-forming inorganic compound. Foamable flame retardant composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11164281A JP2000319349A (en) | 1999-05-07 | 1999-05-07 | Foamable flame retardant composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11164281A JP2000319349A (en) | 1999-05-07 | 1999-05-07 | Foamable flame retardant composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000319349A true JP2000319349A (en) | 2000-11-21 |
Family
ID=15790124
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11164281A Pending JP2000319349A (en) | 1999-05-07 | 1999-05-07 | Foamable flame retardant composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000319349A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003000806A2 (en) * | 2001-06-22 | 2003-01-03 | Hiroshi Kokuta | Aqueous film forming inorganic composition, inorganic foam, thermally insulating composite and method for production thereof |
-
1999
- 1999-05-07 JP JP11164281A patent/JP2000319349A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003000806A2 (en) * | 2001-06-22 | 2003-01-03 | Hiroshi Kokuta | Aqueous film forming inorganic composition, inorganic foam, thermally insulating composite and method for production thereof |
| WO2003000806A3 (en) * | 2001-06-22 | 2003-03-13 | Hiroshi Kokuta | Aqueous film forming inorganic composition, inorganic foam, thermally insulating composite and method for production thereof |
| JPWO2003000806A1 (en) * | 2001-06-22 | 2004-10-07 | 博 穀田 | Aqueous film-forming inorganic composition, inorganic foam, heat-insulating composite, and methods for producing them |
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