JP2000303082A - Method for slurrying organic waste and production of slurried fuel thereby - Google Patents
Method for slurrying organic waste and production of slurried fuel therebyInfo
- Publication number
- JP2000303082A JP2000303082A JP11154227A JP15422799A JP2000303082A JP 2000303082 A JP2000303082 A JP 2000303082A JP 11154227 A JP11154227 A JP 11154227A JP 15422799 A JP15422799 A JP 15422799A JP 2000303082 A JP2000303082 A JP 2000303082A
- Authority
- JP
- Japan
- Prior art keywords
- slurry
- fuel
- waste
- organic waste
- auxiliary fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Landscapes
- Processing Of Solid Wastes (AREA)
- Treatment Of Sludge (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、有機質廃棄物をス
ラリー化する方法とそれを使ったスラリー状燃料の製造
方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for slurrying organic waste and a method for producing a slurry fuel using the same.
【0002】[0002]
【従来の技術】生ゴミや下水汚泥のような有機質の廃棄
物は埋立て、海洋投棄、焼却等により処理されている
が、海洋投棄は禁止され、埋立地は枯渇し、もはや限界
状態である。今後、生ゴミ、下水汚泥の処理は、焼却と
再資源化に依存せざるを得ないのが実情である。焼却と
再資源化で最も大きな障害になっているのは、有機質汚
泥は含水率が約80%と高いにも係らず流動性がなく固
体状態であるということである。これは汚泥粒子がたん
ぱく質膜で覆われ、水分が膜内に閉じ込められた状態に
なっているためである。したがって通常の機械脱水では
脱水できず、単に細胞間の遊離水が脱水されるだけであ
る。このことが再資源化と焼却の最大の障壁となってい
るのである。細胞膜を破壊する方法として膨化処理があ
り、特許第2741565号には膨化処理で汚泥をスラ
リー状にして燃料にすることが記載されているが、膨化
処理は加熱、加圧した後、急激に減圧することで蛋白質
膜を破壊する方法であり、多大な設備投資を必要とし、
処理費も高くなる欠点がある。廃棄物の処理方法として
は有効な方法とは云いがたい。2. Description of the Related Art Organic wastes such as garbage and sewage sludge are disposed of by landfill, ocean dumping, incineration, etc. However, ocean dumping is prohibited, landfills are depleted, and are now in a marginal state. . In the future, the treatment of garbage and sewage sludge will have to rely on incineration and recycling. The biggest obstacle to incineration and recycling is that organic sludge is not fluid and is in a solid state despite its high water content of about 80%. This is because the sludge particles are covered with the protein film, and moisture is trapped in the film. Therefore, it cannot be dehydrated by ordinary mechanical dehydration, but merely dehydrates free water between cells. This is the biggest barrier to recycling and incineration. As a method for destroying the cell membrane, there is a swelling treatment. Japanese Patent No. 2741565 describes that sludge is formed into a slurry by the swelling treatment to be used as a fuel. This is a method of destroying the protein membrane by
There is a disadvantage that the processing cost is also high. This is not an effective method for treating waste.
【0003】[0003]
【発明が解決しようとする課題】本発明はかかる問題に
鑑みてなされたもので、その目的は、(1)加熱、加圧
は必要とせず、極めて簡単な方法で有機質廃棄物細胞膜
を破壊して、スラリー化できる方法を提供せんとするも
のである。また、(2)細胞膜を破壊してスラリー化し
てスラリー状の燃料にする新規な方法を提供せんとする
ものである。DISCLOSURE OF THE INVENTION The present invention has been made in view of the above problems, and has as its objects (1) a method of destroying a cell membrane of an organic waste by an extremely simple method without requiring heating and pressurization. Therefore, it is intended to provide a method capable of forming a slurry. Another object of the present invention is to provide (2) a novel method of breaking down a cell membrane to form a slurry to produce a slurry-like fuel.
【0004】[0004]
【課題を解決するための手段】本発明者は上記課題に関
して鋭意研究を行った結果、以下の知見を得た。すなわ
ち、(1)生ゴミ、汚泥等の有機質廃棄物を凍結して分
断磨砕すると細胞膜が破壊されて膜内の水分が流れ出て
スラリー化すること。そして、(2)有機質廃棄物を凍
結、分断磨砕してスラリー化したものに液体あるいは固
体粉末状の補助燃料を混合、分散させると優れたスラリ
ー状の燃料が得られること。以上の知見を得た。本発明
は以上の知見を基にになされたもので、次の構成からな
る。 (1)有機質廃棄物を凍結した後、分断磨砕することを
特徴とする有機質廃棄物のスラリー化方法。 (2)上記廃棄物が下水汚泥である請求項1に記載のス
ラリー化方法。 (3)上記廃棄物が生ゴミである請求項1に記載のスラ
リー化方法。 (4)有機質廃棄物を凍結、磨砕してスラリー化する工
程と、該スラリーに液体あるいは固体粉末状の補助燃料
を混合、分散させる工程を備えてなることを特徴とする
スラリー状燃料の製造方法。 (5)有機質廃棄物を凍結、磨砕してスラリー化する工
程と、該スラリーに液体あるいは固体粉末状の補助燃料
を混合、分散させる工程と、該スラリーに空気の泡を混
合分散させる工程を備えてなることを特徴とするスラリ
ー状燃料の製造方法。 (6)上記補助燃料が廃プラスチック油である請求項4
あるいは5に記載のスラリー状燃料。 (7)上記補助燃料が微粉砕した可燃性廃棄物である請
求項4あるいは5に記載のスラリー状燃料。 (8)上記補助燃料が可燃性廃棄物の炭化物粉末である
請求項4あるいは5に記載のスラリー状燃料。 (9)上記補助燃料が化石燃料である請求項4あるいは
5に記載のスラリー状燃料。Means for Solving the Problems The present inventors have conducted intensive studies on the above-mentioned problems, and have obtained the following findings. That is, (1) When an organic waste such as garbage and sludge is frozen and divided and ground, the cell membrane is destroyed and the water in the membrane flows out to form a slurry. (2) An excellent slurry-like fuel can be obtained by mixing and dispersing an auxiliary fuel in the form of a liquid or a solid powder into a slurry obtained by freezing, dividing and grinding the organic waste to form a slurry. The above findings were obtained. The present invention has been made based on the above findings, and has the following configuration. (1) A method for forming a slurry of organic waste, comprising freezing the organic waste and subjecting it to fragmentation and grinding. (2) The method according to claim 1, wherein the waste is sewage sludge. (3) The method according to claim 1, wherein the waste is garbage. (4) A process for producing a slurry-like fuel, comprising the steps of freezing and grinding organic waste to form a slurry, and mixing and dispersing a liquid or solid powdery auxiliary fuel with the slurry. Method. (5) a step of freezing and grinding organic waste to form a slurry, a step of mixing and dispersing a liquid or solid powdery auxiliary fuel with the slurry, and a step of mixing and dispersing air bubbles in the slurry. A method for producing a slurry-like fuel, comprising: (6) The auxiliary fuel is waste plastic oil.
Alternatively, the slurry fuel according to 5. (7) The slurry-like fuel according to claim 4 or 5, wherein the auxiliary fuel is finely pulverized combustible waste. (8) The slurry fuel according to claim 4 or 5, wherein the auxiliary fuel is a combustible waste carbide powder. (9) The slurry-like fuel according to claim 4 or 5, wherein the auxiliary fuel is a fossil fuel.
【0005】[0005]
【発明の実施の形態】本発明の凍結して分断磨砕とは、
細胞膜内の水分の凍結あるいは半凍結状態で高速粉砕し
て微粒子化することを意味する。微粒子化は実質氷点下
の温度でなされる。細胞膜が破壊された微粒子は解凍す
ると膜内の水分が外に流れ出てスラリー状となる。BEST MODE FOR CARRYING OUT THE INVENTION The freezing and fragmentation of the present invention is
This means that the water in the cell membrane is frozen or semi-frozen to form fine particles by high-speed pulverization. Micronization occurs at temperatures substantially below freezing. When the microparticles with the cell membrane destroyed are thawed, the water in the membrane flows out to form a slurry.
【0006】解凍したスラリーは、最高80%前後の水
分を含有し、それ自身でも燃料として利用できるが、発
熱量の変動が大きく発熱量が小さい場合が多いので、適
宜水分量を調整(減少)し、また発熱量を調整して使用
することが好ましい。発熱量の調整には、液体あるいは
固体粉末状の補助燃料を混合、分散させると良い。混合
の順序は、有機質廃棄物をいったん凍結磨砕してスラリ
ー化した後、混合しても良いし、あるいは凍結磨砕する
ときに同時に添加して一緒にスラリー化しても良い。The thawed slurry contains a maximum of about 80% of water and can be used as a fuel by itself. However, since the calorific value fluctuates greatly and the calorific value is often small, the amount of water is appropriately adjusted (reduced). In addition, it is preferable that the heat generation amount is adjusted for use. To adjust the calorific value, it is preferable to mix and disperse a liquid or solid powdery auxiliary fuel. The order of mixing may be such that the organic waste is once freeze-milled to form a slurry and then mixed, or may be added simultaneously with freeze-milling to form a slurry together.
【0007】補助燃料としては液体あるいは固体粉末状
のものが好ましい。液体系のものとしては石油、廃プラ
スチック油、廃油等が好ましいが、油系のものはスラリ
ーとは混合しがたいので、スラリーに界面活性剤を添加
してエマルジョン化するとよい。また超音波の照射もエ
マルジョン化には効果がある。固体粉末状の補助燃料と
しては微粉砕した可燃性廃棄物、あるいは微粉砕した可
燃性廃棄物の炭化物、石炭等の化石燃料の粉末が好まし
く、スラリーに混合分散させるに際して、必要に応じ
て、分散性を良くするために、界面活性剤を1〜数%添
加すれば良い。The auxiliary fuel is preferably in the form of a liquid or solid powder. As the liquid type, petroleum, waste plastic oil, waste oil and the like are preferable, but since the oil type is difficult to mix with the slurry, it is preferable to add a surfactant to the slurry to emulsify. Ultrasonic irradiation is also effective for emulsification. Pulverized combustible waste, or finely pulverized combustible waste carbide or fossil fuel powder such as coal is preferred as the solid powdered auxiliary fuel. In order to improve the property, a surfactant may be added in an amount of 1% to several%.
【0008】可燃性廃棄物とは、有機質、無機質の燃焼
可能な廃棄物全般をさす。無機質の可燃性廃棄物とは、
廃石炭、廃ピッチ、廃コークス等の石炭系廃棄物を指
す。有機質可燃性廃棄物とは、炭化水素系廃棄物全般を
さす。たとえば、焼酎、さけ、ビール等の各種アルコー
ル類の絞り粕、廃棄野菜、廃棄食品、廃棄パルプ、廃棄
木材、廃棄アルコール、廃プラスチック、廃油、おか
ら、食品加工残さ、家畜の内臓、血液、糞等である。こ
れらの廃棄物は粉体化可能のものは直接粉体化し、その
他のものはいったん炭化して粉砕、粉体化すると良い。The term "combustible waste" refers to all organic and inorganic combustible waste. What is inorganic combustible waste?
Refers to coal-based waste such as waste coal, waste pitch and waste coke. Organic combustible waste refers to all hydrocarbon waste. For example, shochu, salmon, beer and other various alcohols, waste vegetables, waste food, waste pulp, waste wood, waste alcohol, waste plastic, waste oil, okara, food processing residue, livestock offal, blood, feces And so on. As for these wastes, those which can be powdered are preferably directly powdered, and the others are preferably carbonized once, pulverized and powdered.
【0009】水分量の調節は、適宜加熱処理しても良い
し、機械脱水、あるいは吸水性のある廃棄物、たとえば
廃紙、おがくず等添加して調整しても良い。The amount of water may be adjusted by appropriate heat treatment or by mechanical dehydration or by adding water-absorbing waste such as waste paper and sawdust.
【0010】本発明のスラリー状燃料に微細な空気の泡
を混合すると、完全燃焼して黒鉛の発生を防止できる。
微細気泡は本出願人の出願にかかわる発明である次のよ
うに発明で発生させることができる。すなわち、スラリ
ー中で螺旋板を回転させることによって空気を吸引しな
がら強力な旋回流を発生させて空気を微細に分断して微
細な気泡を精製させ、混合撹拌によって気泡が分散した
スラリーを生成できる。気泡の大きさは10〜数百ミク
ロンの大きさまで自在に調整できる。When fine air bubbles are mixed with the slurry-like fuel of the present invention, the fuel is completely burnt and the generation of graphite can be prevented.
Fine bubbles can be generated in the invention as described below, which is an invention related to the present applicant's application. In other words, by rotating the spiral plate in the slurry, a strong swirling flow is generated while sucking air to generate a strong swirling flow, finely divide the air to purify fine bubbles, and generate a slurry in which bubbles are dispersed by mixing and stirring. . The size of the bubbles can be freely adjusted to a size of 10 to several hundred microns.
【0011】[0011]
【実施例】実施例によって本発明を説明する。 実施例1 スラリーの作製 原料の有機質廃棄物として機械脱水した下水汚泥1kg
を用意し、これを氷点下−30℃に凍結し、高速分断磨
砕機で微粒子化した後、解凍した。固形の汚泥はドロド
ロのスラリーになった。水分量は約80%であった。次
に60%まで乾燥脱水した後、廃プラスチック(ポリス
チレン)を油化して作った廃プラスチック油30%、界
面活性剤5%を添加、撹拌、混合して油と有機質スラリ
ーをエマルジョン化させてスラリー状の燃料を調製し
た。 燃焼テスト 次にこれをバーナーを使って燃焼テストした。黒煙を発
して燃焼した。発熱量は約7000Kcalであった。The present invention will be described by way of examples. Example 1 Preparation of slurry 1 kg of sewage sludge mechanically dewatered as organic waste as raw material
Was prepared, frozen at −30 ° C. below the freezing point, pulverized by a high-speed disintegrator, and then thawed. The solid sludge became a muddy slurry. The water content was about 80%. Next, after drying and dehydrating to 60%, 30% of waste plastic oil made by turning waste plastic (polystyrene) into oil and 5% of a surfactant are added, stirred and mixed to emulsify the oil and organic slurry to form a slurry. A fuel was prepared. Combustion test Next, this was subjected to a combustion test using a burner. Burned black smoke. The calorific value was about 7,000 Kcal.
【0012】 実施例2 原料: 1.有機質廃棄物として機械脱水した下水汚泥:800g 2.脱水した生ゴミ :200g 3.廃木材、廃プラスチックの炭化粉末 :300g 1,2,3の原料を混ぜ、−30℃に凍結した後、高速
分断磨機磨砕後、解凍した。ドロドロのスラリーが得ら
れた。次にスラリーに50〜100μの超マイクロ気泡
を混合分散させてこれをバーナーを使って燃焼テストし
た。黒鉛の発生はほとんどなかった。発熱量は5000
Kcalであった。Example 2 Raw Materials: 1. Sewage sludge mechanically dewatered as organic waste: 800 g 2. Dehydrated garbage: 200 g Waste wood, carbonized powder of waste plastic: 300 g The raw materials of 1, 2, and 3 were mixed, frozen at −30 ° C., crushed with a high-speed cutting and grinding machine, and then thawed. A muddy slurry was obtained. Next, 50 to 100 micro micro bubbles were mixed and dispersed in the slurry, and this was subjected to a combustion test using a burner. There was almost no generation of graphite. The calorific value is 5000
Kcal.
【0013】 実施例3 原料: 1.有機質廃棄物として機械脱水した下水汚泥:800g 2.重油 :100g 3.廃石炭粉末 :100g 1,2,3の原料に界面活性剤を少量混ぜ、−20℃に
凍結した後、高速分断磨機で磨砕後、解凍した。ドロド
ロのスラリーが得られた。次にこれをバーナーを使って
燃焼テストした。発熱量は4000Kcalであった。Example 3 Raw Materials: 1. Sewage sludge mechanically dewatered as organic waste: 800 g 2. Heavy oil: 100 g Waste coal powder: 100 g A small amount of a surfactant was mixed with the raw materials of 1, 2, 3 and frozen at -20 ° C, followed by grinding with a high-speed cutting and grinding machine, followed by thawing. A muddy slurry was obtained. Next, it was burned using a burner. The calorific value was 4000 Kcal.
【0014】[0014]
【発明の効果】本発明は以上詳記したように捨て場所に
困り処置に困っている汚泥等の有機質廃棄物を簡便な方
法でスラリー化と燃料化ができ、かつ燃料化したスラリ
ーは、 均一で高レベルの発熱量 安価で運搬、保管が容易 燃焼に際して黒煙の発生が少ない。 粉塵の発生がない。 脱水が不要 等の特徴を有し廃棄物の減量化と資源化に多大の貢献を
なすものである。According to the present invention, as described in detail above, an organic waste such as sludge which is in trouble in a dumping place and is in trouble can be slurried and converted into a fuel by a simple method. And high level of calorific value Inexpensive and easy to transport and store Low generation of black smoke during combustion. There is no generation of dust. It has features such as no need for dehydration and makes a great contribution to waste reduction and resource recycling.
Claims (9)
ことを特徴とする有機質廃棄物のスラリー化方法。1. A method for preparing a slurry of organic waste, comprising freezing the organic waste and subjecting it to fragmentation and grinding.
載の液状化方法。2. The liquefaction method according to claim 1, wherein the waste is sewage sludge.
の液状化方法。3. The liquefaction method according to claim 1, wherein the waste is garbage.
する工程と、該スラリーに液体あるいは固体粉末状の補
助燃料を混合、分散させる工程を備えてなることを特徴
とするスラリー状燃料の製造方法。4. A slurry-like fuel comprising a step of freezing and grinding an organic waste to form a slurry, and a step of mixing and dispersing a liquid or solid powdery auxiliary fuel with the slurry. Manufacturing method.
する工程と、該スラリーに液体あるいは固体粉末状の補
助燃料を混合、分散させる工程と、該スラリーに空気の
泡を混合分散させる工程を備えてなることを特徴とする
スラリー状燃料の製造方法。5. A process for freezing and grinding organic waste to form a slurry, a process for mixing and dispersing a liquid or solid powdery auxiliary fuel with the slurry, and a process for mixing and dispersing air bubbles in the slurry. A method for producing a slurry-like fuel, comprising a step.
求項4あるいは5に記載のスラリー状燃料。6. A slurry fuel according to claim 4, wherein said auxiliary fuel is waste plastic oil.
ある請求項4あるいは5に記載のスラリー状燃料。7. The slurry fuel according to claim 4, wherein the auxiliary fuel is finely pulverized combustible waste.
である請求項4あるいは5に記載のスラリー状燃料。8. The slurry fuel according to claim 4, wherein the auxiliary fuel is a combustible waste carbide powder.
るいは5に記載のスラリー状燃料。9. The slurry fuel according to claim 4, wherein the auxiliary fuel is a fossil fuel.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11154227A JP2000303082A (en) | 1999-04-21 | 1999-04-21 | Method for slurrying organic waste and production of slurried fuel thereby |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11154227A JP2000303082A (en) | 1999-04-21 | 1999-04-21 | Method for slurrying organic waste and production of slurried fuel thereby |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2000303082A true JP2000303082A (en) | 2000-10-31 |
Family
ID=15579641
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11154227A Pending JP2000303082A (en) | 1999-04-21 | 1999-04-21 | Method for slurrying organic waste and production of slurried fuel thereby |
Country Status (1)
Country | Link |
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JP (1) | JP2000303082A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100665566B1 (en) * | 2000-01-05 | 2007-01-09 | 주식회사 케이티 | Interferometric wavelength convert with fiber optical loop mirror |
-
1999
- 1999-04-21 JP JP11154227A patent/JP2000303082A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100665566B1 (en) * | 2000-01-05 | 2007-01-09 | 주식회사 케이티 | Interferometric wavelength convert with fiber optical loop mirror |
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