JP2000264690A - Pulverized volcanic glass-incorporated lightweight high- strength concrete and its production - Google Patents

Pulverized volcanic glass-incorporated lightweight high- strength concrete and its production

Info

Publication number
JP2000264690A
JP2000264690A JP7611699A JP7611699A JP2000264690A JP 2000264690 A JP2000264690 A JP 2000264690A JP 7611699 A JP7611699 A JP 7611699A JP 7611699 A JP7611699 A JP 7611699A JP 2000264690 A JP2000264690 A JP 2000264690A
Authority
JP
Japan
Prior art keywords
concrete
volcanic glass
strength
finely ground
particle size
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7611699A
Other languages
Japanese (ja)
Inventor
Kenichi Sodeyama
研一 袖山
Yoshitaka Jinno
好孝 神野
Harumi Morita
春美 森田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SPACER KOGYO KK
Kagoshima Prefecture
Original Assignee
SPACER KOGYO KK
Kagoshima Prefecture
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SPACER KOGYO KK, Kagoshima Prefecture filed Critical SPACER KOGYO KK
Priority to JP7611699A priority Critical patent/JP2000264690A/en
Publication of JP2000264690A publication Critical patent/JP2000264690A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/14Minerals of vulcanic origin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain the subject concrete with its lightweightness and high mechanical strength compatible with each other by packing voids among cement particles with pulverized volcanic glass having an average particle size of a specific value or lower. SOLUTION: This concrete is obtained by incorporating cement with pulverized volcanic glass <=15 μm in average particle size in the weight ratio of the latter to the former of 1.0-3.0 followed by adding water and a water reducing agent to the mixture and then kneading the resultant mixture followed by curing the mixture thus kneaded; wherein the pulverized volcanic glass is afforded with an appropriate particle size distribution through pulverization process, being excellent in fluidity, packing the voids among the cement particles, thereby forming the aimed dense concrete and obtaining the objective highly waterproof lightweight concrete with high compressive strength and flexural strength; the pulverized volcanic glass is made from not only silas, but also one of various kinds of volcanic rocks including obsidian, pitchstone and perlite. This concrete is suitably used as PC concrete, segment concrete, precast concrete or the like.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は微粉砕火山ガラス軽
量高強度コンクリートおよびその製造方法に関する。
The present invention relates to a finely ground volcanic glass lightweight high-strength concrete and a method for producing the same.

【0002】[0002]

【従来の技術および発明が解決しようとする課題】配合
された微粉砕火山ガラスは、アルミノ珪酸塩ガラスから
なり非常に微細で比表面積が大きく適度な粒度分布を持
つので、養生によって微粉砕火山ガラスはセメントと反
応して強固に結合するので、高強度が発現する。微粉砕
火山ガラスは、真比重が約2.4であり、セメントや一
般によく使用される珪砂の比重より小さいので、微粉砕
火山ガラスを適量配合することによって、軽量性を示
し、耐火性など優れた機能性を併せ持つ。
2. Description of the Related Art The finely ground volcanic glass compounded is made of aluminosilicate glass, is very fine, has a large specific surface area, and has an appropriate particle size distribution. Reacts with the cement to form a strong bond, thereby exhibiting high strength. Finely ground volcanic glass has a true specific gravity of about 2.4 and is smaller than the specific gravity of cement and silica sand, which is commonly used. Therefore, by adding an appropriate amount of finely ground volcanic glass, it exhibits lightness and excellent fire resistance. Combined functionality.

【0003】本発明のポイントは、平均粒径15μm以
下の微粉砕火山ガラスのセメントとの優れた反応性を利
用している点である。ここで、微粉砕火山ガラスの代わ
りに合成樹脂製のビーズを用いた場合には、このような
セメントとの反応性がないので、これら粒子とセメント
粒子との強固な結合が起こらず、高強度にならない。本
発明で用いた微粉砕火山ガラスは、粒径が小さいほど、
比表面積が大きくなり、セメントとの反応性も高くなる
ので、特に平均粒径10μm以下とした場合には、後述
する実施例1に見られるように、標準砂を用いたコンク
リートよりも約20%軽量化しているにもかかわらず、
圧縮強度と曲げ強度が著しく向上している。当然なが
ら、強度値をコンクリートのカサ比重で割った「比強
度」においては、比曲げ強度、比圧縮強度は、共に顕著
な強度向上を示した。
The point of the present invention is to utilize the excellent reactivity of finely ground volcanic glass having an average particle size of 15 μm or less with cement. Here, when synthetic resin beads are used in place of the finely ground volcanic glass, since there is no reactivity with such cement, strong bonding between these particles and cement particles does not occur, and high strength do not become. The finely ground volcanic glass used in the present invention, the smaller the particle size,
Since the specific surface area is increased and the reactivity with the cement is also increased, especially when the average particle diameter is 10 μm or less, as shown in Example 1 described later, about 20% compared to concrete using standard sand. Despite being lightweight,
Compressive strength and bending strength are significantly improved. As a matter of course, in the “specific strength” obtained by dividing the strength value by the bulk specific gravity of the concrete, both the specific bending strength and the specific compression strength showed a remarkable improvement in strength.

【0004】また、微粉砕火山ガラスを用いる場合、そ
の平均粒径が15μm以下で比表面積が大きいので、混
練時に多くの水を必要とする傾向にあるが、減水剤を適
量(対セメント比で約4%以下)加えることによって、
必要以上の水分を抑えることが可能となった。このこと
が、微粉砕火山ガラスを使いこなす上での重要な点であ
り、高強度を発現させるポイントとなっている。
In the case of using finely ground volcanic glass, since the average particle size is 15 μm or less and the specific surface area is large, a large amount of water tends to be required at the time of kneading. About 4% or less)
It became possible to suppress the moisture more than necessary. This is an important point in using finely ground volcanic glass, and is a point at which high strength is exhibited.

【0005】そこで、本発明においては微粉砕火山ガラ
スが有する流動性の高さやその他の諸性質を活用できる
用途としてコンクリート組成に含有することに着目して
鋭意研究を重ね、微粉砕火山ガラス軽量高強度コンクリ
ートを発明するに至ったものである。そして本発明は、
従来技術では困難であった軽量性と高強度を両立したコ
ンクリートの開発を目的としている。
Therefore, in the present invention, the inventors of the present invention focused on the fact that they are contained in concrete compositions as applications in which the high fluidity and other properties of the finely ground volcanic glass can be utilized, and have conducted extensive studies, and have studied the light weight of the finely ground volcanic glass. This led to the invention of high-strength concrete. And the present invention
The aim is to develop concrete that has both lightness and high strength, which were difficult with conventional technology.

【0006】[0006]

【課題を解決するための手段】本発明においては微粉砕
火山ガラスを組成中に包含した微粉砕火山ガラス軽量高
強度コンクリートを提供しようとするものであって、そ
の構成としては、請求項1に記載したように、セメント
粒子間の空隙に、平均粒径15μm以下に粉砕した火山
ガラス微粉体を流入充填させてなることを特徴としてい
る。
The object of the present invention is to provide a finely ground volcanic glass lightweight high-strength concrete containing finely ground volcanic glass in its composition. As described above, the method is characterized in that volcanic glass fine powder pulverized to an average particle size of 15 μm or less flows into and fills voids between cement particles.

【0007】上記構成の微粉砕火山ガラス軽量高強度コ
ンクリートによると、微粉砕火山ガラスは、粉砕工程に
より適度な粒度分布を持ち、流動性に優れており、セメ
ントの粒子間の空隙に流入されて空隙を充填させ、密実
なコンクリートとなり、圧縮強度、曲げ強度および防水
性の高い軽量なコンクリートとなり、PC矢板、セグメ
ント、プレキャスト板、ヒューム管等としての製品に広
く使用できる。
[0007] According to the finely ground volcanic glass lightweight high-strength concrete having the above structure, the finely ground volcanic glass has an appropriate particle size distribution due to the pulverizing process, has excellent fluidity, and is introduced into the voids between cement particles. By filling voids, it becomes dense concrete, and it becomes lightweight concrete with high compressive strength, bending strength and waterproofness, and can be widely used for products such as PC sheet pile, segment, precast board, fume pipe and the like.

【0008】また、上記した微粉砕火山ガラス軽量高強
度コンクリートを製造する方法としては、請求項2に記
載したように、セメントの重量1に対して、重量比1.
0〜3.0の割合で平均粒径15μm以下の火山ガラス
微粉砕体を加え、これに水と減水剤を加えて混練し、養
生させてコンクリートを製造することを特徴としてお
り、セメント粒子間に微粉砕火山ガラスを充填させるの
に好適な製造方法であり、セメント比1.0以下では、
高強度になるが、微粉砕火山ガラスの比重が約2.4で
あるため軽量化できない。セメント比3.0以上では、
高強度にならない。本発明に用いる微粉砕火山ガラス
は、標準砂より低比重なので、セメント比は上記1.0
〜3.0でも充分に軽量化できることになる。
[0008] As a method for producing the above-mentioned finely ground volcanic glass lightweight high-strength concrete, as described in claim 2, the weight ratio of cement to weight 1 is 1.
It is characterized by adding a finely ground volcanic glass having an average particle size of 15 μm or less at a ratio of 0 to 3.0, adding water and a water reducing agent thereto, kneading the mixture, and curing the mixture to produce concrete. It is a suitable production method for filling the finely ground volcanic glass with a cement ratio of 1.0 or less,
Although the strength is high, the weight cannot be reduced because the specific gravity of the finely ground volcanic glass is about 2.4. With a cement ratio of 3.0 or more,
Not high strength. The finely ground volcanic glass used in the present invention has a specific gravity lower than that of standard sand.
Even with a value of ~ 3.0, the weight can be reduced sufficiently.

【0009】上記微粉砕火山ガラスとしてはシラスのほ
か、黒曜岩、松脂岩、真珠岩などの種々の火山ガラス岩
の微粉砕体が対象となる。
The above-mentioned finely ground volcanic glass includes, in addition to shirasu, finely ground bodies of various volcanic glass rocks such as obsidian, pinestone, and perlite.

【0010】[0010]

【発明の実施の形態】次いで本発明の実施の形態とし
て、セメントと、微粉砕火山ガラスと、水および減水剤
についての配合例を以下の表1に示す。これらの配合例
に基づき何れの場合にも、混練後、養生させるもので、
養生後の微粉砕火山ガラス軽量高強度コンクリートの強
度については以下の表2に示す通りである。
BEST MODE FOR CARRYING OUT THE INVENTION Next, as an embodiment of the present invention, examples of blending of cement, finely ground volcanic glass, water and a water reducing agent are shown in Table 1 below. In any case based on these formulation examples, after kneading, it is to be cured,
The strength of the cured finely ground volcanic glass lightweight high-strength concrete after curing is as shown in Table 2 below.

【0011】<実施例および比較例>比較例は、JIS
R5201−1997の基本配合を参考にしている。
養生は、長期的強度を見るために、促進試験の手法を用
いた。具体的には、成形後1日湿気箱中、脱形後に70
℃の温水中で9.5日間養生した。
<Examples and Comparative Examples> Comparative examples are based on JIS.
Reference is made to the basic formulation of R5201-1997.
Curing used the accelerated test technique to see the long-term strength. Specifically, one day after molding, 70% after demolding
Cured in warm water at 9.5 days for 9.5 days.

【0012】[0012]

【表1】 [Table 1]

【0013】[0013]

【表2】 [Table 2]

【0014】「微粉砕火山ガラス」としては、南九州に
賦存するシラスを粉砕した微粉砕シラスを用いた。 養生方法(全て同じ条件): 成形後1日湿気箱中、脱
形後に70℃の温水中で9.5時間養生した。 * 上記の曲げ強度、圧縮強度は、平均値(3検体)で
ある。
As the "finely ground volcanic glass", finely ground shirasu obtained by crushing shirasu existing in Minamikyushu was used. Curing method (all under the same conditions): One day after molding, the specimen was cured in a moisture box, and after demolding, in hot water at 70 ° C. for 9.5 hours. * The above bending strength and compression strength are average values (3 samples).

【0015】軽量化率=(1−(微粉砕火山ガラスコン
クリートのカサ比重/標準砂コンクリートのカサ比重)
×100 比曲げ強度=各実施例の曲げ強度/各実施例のカサ比重 比圧縮強度=各実施例の圧縮強度/各実施例のカサ比重 微粉砕火山ガラスを含むコンクリートの特徴: 軽量、
高強度 曲げ強度、圧縮強度は、標準砂を用いたJIS規格試験
体より約20%軽量化(コンクリートのカサ比重で比較
して)しているにもかかわらず著しい高強度を示した。
セメントの反応性がよく、強固に結合することと、中実
体であるために、著しい高圧縮強度を示したと考えられ
る。比強度(曲げ強度、圧縮強度をカサ比重で割った
値)は、当然ながら著しく優れている。
Lightening rate = (1- (Kasa specific gravity of finely ground volcanic glass concrete / Kasa specific gravity of standard sand concrete))
× 100 Specific bending strength = Bending strength of each example / Kasa specific gravity of each example Specific compressive strength = Compression strength of each example / Kasa specific gravity of each example Characteristics of concrete including finely ground volcanic glass: Light weight,
High strength Flexural strength and compressive strength showed remarkably high strength despite being about 20% lighter (compared with the concrete specific gravity of concrete) than a JIS standard specimen using standard sand.
It is considered that the cement had good reactivity, was strongly bonded, and had a very high compressive strength because of its solid state. The specific strength (the value obtained by dividing the bending strength and the compressive strength by the bulk specific gravity) is, of course, extremely excellent.

【0016】[0016]

【発明の効果】以上のように本発明による微粉砕火山ガ
ラスを含む軽量高強度コンクリートによると、微粉砕火
山ガラスがセメントの粒子間の空隙内に流入して空隙を
充填させ、密実して圧縮強度および曲げ強度が高く、防
水性と軽量性を具有するコンクリートを提供でき、種々
の用途、例えばPC矢板、セグメント、プレキャスト、
ヒューム管等の製品として好適なコンクリートとなる。
As described above, according to the lightweight high-strength concrete containing the finely ground volcanic glass according to the present invention, the finely ground volcanic glass flows into the voids between the particles of cement to fill the voids and to be densely packed. Concrete having high compressive strength and bending strength, waterproofness and light weight can be provided, and can be used in various applications, for example, PC sheet pile, segment, precast,
It becomes a concrete suitable as a product such as a fume tube.

【0017】そして、本発明による微粉砕火山ガラスを
含有した軽量高強度コンクリートの製造方法によれば、
至極簡単でコストメリットをもたらす製造方法となる。
According to the method for producing a lightweight and high-strength concrete containing finely ground volcanic glass according to the present invention,
This is a very simple and cost-effective manufacturing method.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 神野 好孝 鹿児島県姶良郡隼人町小田1445番1 鹿児 島県工業技術センター内 (72)発明者 森田 春美 鹿児島県姶良郡隼人町小田1445番1 鹿児 島県工業技術センター内 ──────────────────────────────────────────────────続 き Continuing from the front page (72) Inventor Yoshitaka Jinno 1445-1 Oda, Hayato-cho, Aira-gun, Kagoshima Prefecture Inside the Kagoshima Industrial Technology Center (72) Harumi Morita 14445-1, Oda, Hayato-cho, Aira-gun, Kagoshima Kagoshima Prefectural Industrial Technology Center

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】セメント粒子間の空隙に、平均粒径15μ
m以下に粉砕した火山ガラス微粉体を流入充填させてな
ることを特徴とする微粉砕火山ガラス軽量高強度コンク
リート。
An average particle size of 15 μm is formed in a void between cement particles.
m. High-strength concrete of finely ground volcanic glass, characterized by being filled with volcanic glass fine powder pulverized to m or less.
【請求項2】セメントの重量1に対して、重量比1.0
〜3.0の割合で平均粒径15μm以下の火山ガラス微
粉砕体を加え、これに水と減水剤を加えて混練し、養生
させてコンクリートを製造することを特徴とする微粉砕
火山ガラス軽量高強度コンクリートの製造方法。
2. A weight ratio of 1.0 to 1 weight of cement.
A finely ground volcanic glass lightweight characterized by adding a finely ground volcanic glass having an average particle size of 15 μm or less at a ratio of ~ 3.0, adding water and a water reducing agent, kneading the mixture, and curing to produce concrete. Manufacturing method of high-strength concrete.
JP7611699A 1999-03-19 1999-03-19 Pulverized volcanic glass-incorporated lightweight high- strength concrete and its production Pending JP2000264690A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7611699A JP2000264690A (en) 1999-03-19 1999-03-19 Pulverized volcanic glass-incorporated lightweight high- strength concrete and its production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7611699A JP2000264690A (en) 1999-03-19 1999-03-19 Pulverized volcanic glass-incorporated lightweight high- strength concrete and its production

Publications (1)

Publication Number Publication Date
JP2000264690A true JP2000264690A (en) 2000-09-26

Family

ID=13595949

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7611699A Pending JP2000264690A (en) 1999-03-19 1999-03-19 Pulverized volcanic glass-incorporated lightweight high- strength concrete and its production

Country Status (1)

Country Link
JP (1) JP2000264690A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005007667A (en) * 2003-06-17 2005-01-13 Kagoshima Prefecture Shirasu concrete decorative material and its manufacturing method
CN112608099A (en) * 2020-12-11 2021-04-06 青岛理工大学 C50 steam-free curing concrete for coastal subway segments and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005007667A (en) * 2003-06-17 2005-01-13 Kagoshima Prefecture Shirasu concrete decorative material and its manufacturing method
JP4521497B2 (en) * 2003-06-17 2010-08-11 鹿児島県 Shirasu concrete decorative material and manufacturing method thereof
CN112608099A (en) * 2020-12-11 2021-04-06 青岛理工大学 C50 steam-free curing concrete for coastal subway segments and preparation method thereof

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