JP2000256088A - Production of coated fertilizer and its apparatus - Google Patents

Production of coated fertilizer and its apparatus

Info

Publication number
JP2000256088A
JP2000256088A JP11064522A JP6452299A JP2000256088A JP 2000256088 A JP2000256088 A JP 2000256088A JP 11064522 A JP11064522 A JP 11064522A JP 6452299 A JP6452299 A JP 6452299A JP 2000256088 A JP2000256088 A JP 2000256088A
Authority
JP
Japan
Prior art keywords
fertilizer
coating
gas
coated fertilizer
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP11064522A
Other languages
Japanese (ja)
Other versions
JP2000256088A5 (en
Inventor
Shigeo Yokoyama
茂雄 横山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP11064522A priority Critical patent/JP2000256088A/en
Publication of JP2000256088A publication Critical patent/JP2000256088A/en
Publication of JP2000256088A5 publication Critical patent/JP2000256088A5/ja
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/30Layered or coated, e.g. dust-preventing coatings
    • C05G5/37Layered or coated, e.g. dust-preventing coatings layered or coated with a polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/20Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
    • Y02P60/21Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Details Or Accessories Of Spraying Plant Or Apparatus (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Fertilizers (AREA)

Abstract

PROBLEM TO BE SOLVED: To inexpensively and stably produce a time interval elution type coated fertilizer reduced in initial suppression down to a satisfactory level on an industrial scale by disposing a dust removing device having performance of a removal rate above a specific value between a gas outlet from a coating device and a gas cooling condenser disposed in a circulation system for gas and removing the dust used for drying. SOLUTION: The performance of the dust removing device is >=95% in the removal rate of 1 to 10-micron particles and >=99.5% in the removal rate of 10 to 100-micron particles. The coated fertilizer is produced by using the device for coating the fertilizer surface with a polymer solution and reintroducing the gas used for drying discharged from the coating device into the coating device. Not only the shape of the particles of the fertilizer but the dust derived from the particles of the fertilizer exert a significant influence on the initial elution of the coated fertilizer and the dust removing device is built into the gas circulation system for solvent drying. The dust removing device is a bag filter, an electrostatic precipitator, etc. The material that exerts the significant influence on the elution is the water-soluble particles of 1 to 100 microns.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、良好な品質の被覆
肥料を製造する方法およびその装置に関するものであ
る。さらに詳しくは、初期の肥料成分の溶出が抑制され
た被覆肥料を製造するために好適な方法およびその装置
に関するものである。
[0001] The present invention relates to a method and an apparatus for producing a coated fertilizer of good quality. More specifically, the present invention relates to a method and an apparatus suitable for producing a coated fertilizer in which elution of an initial fertilizer component is suppressed.

【0002】[0002]

【従来の技術】肥料をポリマーで被覆する方法として
は、例えば、特公昭54−3104号や特公昭56−8
9号に記載のように、ポリマー溶液を肥料粒子にスプレ
ーすると同時に、転動または噴流状態にある肥料粒子に
高速の熱風流を当て瞬間的に乾燥させる方法などが知ら
れている。また、近年では被覆肥料の溶出パターンに対
する要求は多様化しており、従来から、ある期間に対し
て溶出率がほぼ直線的に増加するリニアタイプや、これ
よりも初期の溶出率が高いレギュラータイプばかりでな
く、初期の溶出率が抑制されたシグモイドタイプが、作
物の栄養吸収パターンと肥料の溶出がほぼ一致すること
から好まれて使用されるようになってきている。これら
のシグモイド型肥料を作る方法としては、例えば、特公
平5−29634号、特開平9−132493号に開示
されている。
2. Description of the Related Art As a method of coating a fertilizer with a polymer, for example, Japanese Patent Publication No. 54-3104 and Japanese Patent Publication No. 56-8
As described in No. 9, there is known a method in which a polymer solution is sprayed on fertilizer particles, and at the same time, a high-speed hot air flow is applied to the rolling or jetting fertilizer particles to instantaneously dry the fertilizer particles. In recent years, the requirements for the elution pattern of coated fertilizers have diversified. Conventionally, only the linear type, in which the elution rate increases almost linearly over a certain period, and the regular type, in which the initial elution rate is higher than this, Rather, the sigmoid type in which the initial dissolution rate is suppressed has been favorably used because the nutrient absorption pattern of the crop and the dissolution of the fertilizer almost coincide with each other. Methods for producing these sigmoid fertilizers are disclosed, for example, in Japanese Patent Publication No. Hei 5-29634 and Japanese Patent Application Laid-Open No. Hei 9-132493.

【0003】また、さらに育苗箱による全量基肥施肥法
などの極度に集約された施肥・栽培法に使用される肥料
としては、施用後肥料成分を溶出させない期間もしくは
溶出を極度に抑制された期間と、一定期間経過後速やか
な溶出を行う期間とを有する、いわゆる時限溶出型のも
のが求められている。この全量基肥施肥法とは、栽培期
間中に必要な肥料の全量もしくはその大部分を育苗開始
時に、上記時限溶出型の被覆肥料として育苗箱に施用す
るものであり、時限溶出型被覆肥料の溶出は、育苗期間
中においては極度に溶出が抑制され、育苗期間終了後
(本圃に移植後)に速やかに溶出を開始するのものが必
要である。このような時限溶出型被覆肥料を用いること
により、育苗期間中に溶出する肥料による濃度障害を起
こすことなく、また、本圃において必要な肥料分を速や
かに吸収することができる。さらに種子または種籾から
発根した根は、成長とともに時限溶出型被覆肥料と接触
し、ついには根で肥料を抱える状態になり、成長した苗
を本圃に移植する際には、根は肥料を抱えて移植され
る。このため根が接触している該肥料から肥料分を直接
吸収することが可能となり、施肥肥料の吸収効率を大幅
に向上させることが可能になった。
[0003] Further, fertilizers used for extremely concentrated fertilization and cultivation methods such as a total basal fertilization method using a nursery box include a period during which fertilizer components are not eluted after application or a period during which elution is extremely suppressed. There is a demand for a so-called timed elution type having a period in which rapid elution is performed after a certain period of time. The total amount fertilizer application method is to apply the entire amount or most of the fertilizer required during the cultivation period to the nursery box as the above-mentioned time-eluting type coated fertilizer at the start of the seedling raising, and dissolve the time-eluting type coated fertilizer. It is necessary that the elution is extremely suppressed during the seedling raising period, and the elution begun immediately after the seedling raising period is completed (after transplantation in this field). By using such a time-eluting type coated fertilizer, it is possible to quickly absorb the fertilizer required in this field without causing a concentration disorder due to the fertilizer eluted during the seedling raising period. Furthermore, the roots that have emerged from the seeds or seeds come into contact with the time-eluting type coated fertilizer as they grow, and eventually become fertilized by the roots.When the grown seedlings are transplanted to this field, the roots carry the fertilizer. To be transplanted. Therefore, it is possible to directly absorb the fertilizer from the fertilizer with which the root is in contact, and it is possible to greatly improve the absorption efficiency of the fertilizer.

【0004】しかし、このような施肥法を実現させるた
めには、時限溶出型被覆肥料は作物の育苗期間中に肥料
の溶出による濃度障害を起こさせないことが前提にな
り、初期溶出抑制期間中の溶出率を極めて低く抑えられ
たものが必要であり、従来のリニア型やレギュラー型溶
出パターンの被覆肥料に比べて厳密な溶出制御が要求さ
れる。これらの時限溶出型被覆肥料を製造する基本的な
被膜組成や製造方法としては、特開平4−202078
号、特開平4−202079号および特開平6−876
84号に開示されている。また、さらに初期溶出抑制期
間中の溶出率を抑える好ましい装置や製造方法として
は、特開平10−118557号、特開平10−156
166号および特開平10−156167号に開示され
ている。
[0004] However, in order to realize such a fertilization method, it is premised that the time-eluting type coated fertilizer does not cause concentration disturbance due to elution of the fertilizer during the seedling raising period of the crop. It is necessary that the dissolution rate is extremely low, and stricter dissolution control is required compared to the conventional linear or regular type dissolution pattern coated fertilizer. The basic coating composition and production method for producing these time-eluting coated fertilizers are described in JP-A-4-202078.
JP-A-4-202079 and JP-A-6-876
No. 84. Further, as preferable devices and production methods for further suppressing the dissolution rate during the initial dissolution suppression period, JP-A-10-118557 and JP-A-10-156 are known.
166 and JP-A-10-156167.

【0005】被覆肥料を製造する方法および装置につい
て、前述の特許公報があるが、ガスの循環系を含めた被
覆肥料の製造装置に関しては、特公昭56−38255
号に被覆装置、サイクロン、冷却器、ブロワー、空気加
熱器等からなる例示が開示されている程度である。しか
し、これらの方法のみでは、時限溶出型の溶出を示す被
膜組成であっても、これらを大量に生産しようとした場
合には、初期抑制期間中の溶出率を薄い皮膜で満足すべ
きレベルにまで低減されたものを安定的に生産すること
は困難であった。
[0005] A method and an apparatus for producing a coated fertilizer are described in the above-mentioned patent gazette, but an apparatus for producing a coated fertilizer including a gas circulation system is disclosed in JP-B-56-38255.
No. 4,867,059 discloses an example including a coating device, a cyclone, a cooler, a blower, an air heater, and the like. However, with these methods alone, even if the coating composition shows a time-eluting type elution, if it is intended to produce these in large quantities, the elution rate during the initial suppression period will be at a level that is satisfactory with a thin film. It has been difficult to stably produce the reduced amount.

【0006】[0006]

【発明が解決しようとする課題】本発明は、育苗時全量
基肥施肥法に使用される時限溶出型被覆肥料を、大量か
つ安定的に生産する方法およびその装置を提供すること
を目的とする。被覆肥料の初期の溶出を抑制するために
は、一般的に肥料の粒子に均一な厚みのポリマーの被膜
を形成させることが重要である。このためには、肥料粒
子の形状ができるだけ凹凸の少ない丸みのあるものを使
用し、ポリマーを薄い濃度で何回も重ね塗りするような
方法をとることが好ましい。
SUMMARY OF THE INVENTION It is an object of the present invention to provide a method and an apparatus for producing a large amount and stably of a time-eluting coated fertilizer used in a total fertilizer application method for raising seedlings. In order to suppress the initial dissolution of the coated fertilizer, it is generally important to form a polymer film having a uniform thickness on the fertilizer particles. For this purpose, it is preferable to use a method in which the shape of the fertilizer particles is as round as possible with as few irregularities as possible, and the polymer is repeatedly applied at a low concentration many times.

【0007】しかし、肥料の粒子の形状には限界があ
り、凹凸を全くなくすることは困難であり、また、重ね
塗りすることは被覆肥料の生産性を犠牲にしなければな
らないとの問題点があった。また、被膜の厚みを増すこ
とも、被覆肥料の初期溶出を抑制する方法として有効な
手段であるが、被膜を厚くすることは、肥料の有効成分
含有率を低下させるだけではなく、高価な被膜を多く使
用しなければならなく、経済的にも不利となる。初期抑
制を満足できるレベルにまで低減された時限溶出型被覆
肥料を、安価かつ工業的規模で安定に生産する装置の開
発が望まれていた。
However, there is a problem in that the shape of the fertilizer particles is limited, it is difficult to eliminate the irregularities at all, and it is necessary to sacrifice the productivity of the coated fertilizer in recoating. there were. Increasing the thickness of the coating is also an effective means of suppressing the initial elution of the coated fertilizer, but thickening the coating not only reduces the active ingredient content of the fertilizer, but also increases the cost of the coating. Must be used a lot, which is economically disadvantageous. It has been desired to develop an apparatus for stably producing a time-eluting coated fertilizer reduced to a level that can satisfy the initial control at a low cost on an industrial scale.

【0008】[0008]

【課題を解決するための手段】本発明者は、被覆肥料の
初期溶出を抑制する被覆肥料の製造方法およびその装置
について鋭意検討を行った結果、肥料の粒子の形状ばか
りでなく、肥料の粒子に由来する粉塵が被覆肥料の初期
溶出に大きな影響を与えていることを発見し、溶媒乾燥
用のガスの循環系に粉塵除去装置を組み込む本発明を完
成するに至った。すなわち、本発明の被覆肥料の製造方
法は、ポリマーの溶液を肥料の表面に吹き付け乾燥させ
ることにより肥料表面をポリマーで被覆する被覆装置を
用い、被覆装置から排出する乾燥に使用したガスをガス
の循環系より被覆装置に再導入して被覆肥料を製造する
方法において、被覆装置からのガス出口と前記ガスの循
環系に設けたガスの冷却凝縮器との間に、1〜10ミク
ロン粒子の除去率が95%以上、かつ、10〜100ミ
クロン粒子の除去率が99.5%以上の性能を有する粉
塵除去装置を設けて、乾燥に使用したガスの粉塵を除去
することを特徴とする。
Means for Solving the Problems The present inventors have conducted intensive studies on a method and an apparatus for producing a coated fertilizer which suppresses the initial elution of the coated fertilizer. It has been found that dust derived from ash has a great influence on the initial elution of the coated fertilizer, and the present invention has been completed in which a dust removal device is incorporated in a gas circulation system for solvent drying. That is, the method for producing a coated fertilizer of the present invention uses a coating device that coats the surface of the fertilizer with a polymer by spraying a solution of the polymer onto the surface of the fertilizer and drying the gas used for drying discharged from the coating device. In a method of producing a coated fertilizer by re-introducing into a coating device from a circulation system, removing 1 to 10 micron particles between a gas outlet from the coating device and a gas cooling condenser provided in the gas circulation system. A dust removing device having a performance of 95% or more and a removal rate of 10 to 100 micron particles of 99.5% or more is provided to remove gas dust used for drying.

【0009】また、本発明の被覆肥料の製造装置は、ポ
リマー溶液を肥料の表面に吹き付け乾燥させることによ
り肥料表面をポリマーで被覆する装置と、被覆装置から
排出する乾燥に使用したガスを被覆装置に再導入するた
めのガスの循環系とを含む被覆肥料の製造装置であっ
て、被覆装置からのガス出口と前記ガスの循環系に設け
たガスの冷却凝縮器との間に、1〜10ミクロン粒子の
除去効率が95%以上、かつ、10〜100ミクロン粒
子の除去効率が99.5%以上の性能を有する粉塵除去
装置を設けたことを特徴とする。そして、前記ガスの循
環系は、ガス循環ブロワー、熱風発生装置を含むもので
ある。被覆される肥料は、被覆装置で被覆された後冷却
され、製品となる。
[0009] The apparatus for producing a coated fertilizer of the present invention comprises an apparatus for coating the surface of a fertilizer with a polymer by spraying and drying a polymer solution on the surface of the fertilizer, and an apparatus for coating a gas used for drying discharged from the coating apparatus. And a gas circulating system for reintroducing the gas into the coated fertilizer, wherein a gas outlet and a gas cooling condenser provided in the gas circulating system have a 1-10 A dust removing device having a performance of removing micron particles of 95% or more and a removing efficiency of 10 to 100 micron particles of 99.5% or more is provided. The gas circulation system includes a gas circulation blower and a hot air generator. The fertilizer to be coated is cooled after being coated with the coating device, and becomes a product.

【0010】本発明において、乾燥用のガスはガス循環
ブロワーで送風され、熱風発生装置で加温されて被覆装
置に入り、被覆装置を出た有機溶媒を含むガスは、粉塵
除去装置で除塵され、冷却凝縮器で有機溶剤が液化分離
され、ガス循環ブロワーに戻る。溶剤乾燥に使用するガ
スは、通常空気が使用され、大気汚染防止、溶剤のロス
の減少を考慮すると、循環使用することが効率的であ
る。被覆液は被覆液調整槽で被覆材を有機溶剤で溶解お
よび/または分散させたものであり、調整槽または中間
槽から送液ポンプで被覆装置に送られる。
In the present invention, the gas for drying is blown by a gas circulation blower, heated by a hot air generator and enters the coating device, and the gas containing the organic solvent exiting the coating device is removed by a dust removing device. Then, the organic solvent is liquefied and separated in the cooling condenser and returned to the gas circulation blower. Air is usually used as the gas used for drying the solvent, and it is efficient to circulate the gas in consideration of preventing air pollution and reducing loss of the solvent. The coating liquid is obtained by dissolving and / or dispersing a coating material in an organic solvent in a coating liquid adjusting tank, and is sent from the adjusting tank or the intermediate tank to the coating apparatus by a liquid sending pump.

【0011】また、これらの装置の順番は、必ずしもこ
の順でなくてもよいが、粉塵による装置の汚染などを考
慮すると、粉塵除去装置は被覆装置のすぐ後に設けるこ
とが好ましい。本発明者の研究では、被覆操作中に被覆
装置から発生する粉塵は、被覆し始めに多く、被覆率が
増加するに従って粉塵の発生は少なくなり、肥料の表面
が完全に覆われると、粉塵の発生はほとんど無くなる。
このため被覆装置内で発生する粉塵のみでは肥料の初期
溶出に大きな影響を与えることはない。
The order of these devices does not necessarily have to be in this order, but in consideration of the contamination of the device by dust and the like, the dust removing device is preferably provided immediately after the coating device. In the study of the present inventor, the dust generated from the coating apparatus during the coating operation is large at the beginning of coating, and the generation of dust decreases as the coating rate increases, and when the surface of the fertilizer is completely covered, the dust is generated. The occurrence is almost eliminated.
Therefore, dust alone generated in the coating apparatus does not significantly affect the initial elution of the fertilizer.

【0012】肥料を乾燥させるための熱風を循環使用す
る装置において、粉塵除去装置がない場合もしくはこの
効率が低い場合には、循環するガス中に微細粉塵が含ま
れ、この微細粉塵は、循環システム内の多くの機器・装
置によるトラップ、蓄積、放出効果により、定常的に被
覆装置内に運ばれるため、被覆操作期間中あまり変動し
ていなく、被覆し始めから被覆終了時まで常に被覆肥料
の被膜に取り込まれるために、肥料の初期溶出に大きな
影響を与える。したがって、循環ガス中の粉塵を効率よ
く捕集することが重大になってくる。
[0012] In a device that uses hot air for drying fertilizer in a circulating manner, if there is no dust removal device or if the efficiency is low, the circulating gas contains fine dust. Because of the trapping, accumulation and release effects of many devices and equipment in the yard, it is constantly transported into the coating equipment, so it does not fluctuate much during the coating operation, and it is always coated from the start of coating to the end of coating. It has a great effect on the initial elution of fertilizers because it is taken up in the soil. Therefore, it becomes important to efficiently collect dust in the circulating gas.

【0013】本発明の被覆肥料の製造装置の構成を、以
下に詳細に説明する。本発明で使用する被覆装置は、従
来から知られている被覆装置を使用することができる。
具体的には転動型、流動層型、噴流層型のなどを使用す
ることが可能であり、被膜を瞬間的に乾燥できる点で噴
流層型被覆装置が好ましい。また、噴流層の内部に噴流
のためのガイド管を有しているものが特に好ましい。
The construction of the apparatus for producing coated fertilizer of the present invention will be described in detail below. As the coating device used in the present invention, a conventionally known coating device can be used.
Specifically, a tumbling type, a fluidized bed type, a spouted bed type, or the like can be used, and a spouted bed type coating apparatus is preferable in that a coating film can be instantaneously dried. Further, those having a guide tube for a jet flow inside the spouted bed are particularly preferable.

【0014】本発明で使用する粉塵除去装置としては、
バクフィルター、電気集塵機などの除去装置を用いるこ
とができる。粉塵の除去性能としては、1〜10ミクロ
ン粒子の除去率が95%以上、かつ、10〜100ミク
ロン粒子の除去効率99.5%以上の性能を有すること
が必要である。100ミクロンを越える粒子は、循環系
で大部分が沈降し、配管や循環系にある装置を汚染する
ことはあっても、再び被覆装置に戻ることは極めて稀で
ある。また、1ミクロン未満の粒子は、粉塵の発生その
ものが少ないばかりでなく、被覆の厚みに比較して粒径
が小さく影響は少ない。除塵装置を設置しない場合、溶
出に大きな影響を与えるのは1〜100ミクロンの水溶
性の粒子が主体であり、これらを効率よく除去する装置
が好ましい。
The dust removing device used in the present invention includes:
A removing device such as a tap filter or an electric dust collector can be used. It is necessary for the dust removal performance to have a removal rate of 1 to 10 micron particles of 95% or more and a removal efficiency of 10 to 100 micron particles of 99.5% or more. Particles larger than 100 microns settle down largely in the circulation and contaminate the piping and equipment in the circulation, but very rarely return to the coating equipment. In addition, particles having a particle diameter of less than 1 micron not only generate less dust, but also have a smaller particle size and less influence than the thickness of the coating. When a dust removing device is not installed, water-soluble particles having a size of 1 to 100 microns mainly affect elution, and a device for efficiently removing these particles is preferable.

【0015】このような装置としては、先にも述べたよ
うにバクフィルター、電気集塵機などがあげられる。一
般のサイクロンでは、10ミクロン以下の粒子の除去効
率が低く、また、マルチサイクロンなどの小さな粒子の
除去効率が高いものでも、10ミクロン程度粒子の除去
効率が80%程度であり、本発明に使用するには、さら
に小さな粒子の除去効率の高いものが必要である。ま
た、比較的大きな粒子の除去効率の高いサイクロンと、
小さな粒子の除去効率の高い電気集塵機とを組み合わせ
て使用することが好ましい。さらに、除塵装置として
は、装置の簡便さ、1ミクロン以上の粒子の除去効率の
高さなどの点から、バグフィルターが特に好ましい。サ
イクロンと電気集塵機の組み合わせおよびバグフィルタ
ーを使用した場合には、100ミクロン以上の粒子も同
時に除去可能であり、装置の汚染が少ないメリットも有
する。
Examples of such an apparatus include a back filter and an electric dust collector as described above. A general cyclone has a low removal efficiency of particles of 10 microns or less, and a high removal efficiency of small particles such as a multicyclone has a removal efficiency of approximately 80% of particles of approximately 10 microns. In order to achieve this, it is necessary to have a smaller particle removal efficiency. In addition, a cyclone with high removal efficiency for relatively large particles,
It is preferable to use in combination with an electrostatic precipitator having a high efficiency of removing small particles. Further, as the dust removing device, a bag filter is particularly preferable in terms of simplicity of the device and high removal efficiency of particles of 1 micron or more. When a combination of a cyclone and an electrostatic precipitator and a bag filter are used, particles having a size of 100 microns or more can be removed at the same time, and there is an advantage that contamination of the apparatus is reduced.

【0016】また、運転条件としては、循環ガス中の溶
剤が凝縮しないような温度で運転することが好ましい。
溶剤が凝縮すると、粉塵が装置の壁面に固着し、装置か
らの排出が困難になったり、バグフィルターの場合に
は、圧力損失が異常に大きくなることがある。本発明で
使用するガス循環ブロワーとしては、所定の送風量、吐
出圧力を満たせば、従来から知られれている装置を使用
することができる。例えば、ターボファン型遠心送風
機、可動翼型回転圧縮機、ルーツ式送風機、ナッシュポ
ンプなどがあげられる。
As the operating conditions, it is preferable to operate at a temperature at which the solvent in the circulating gas does not condense.
When the solvent condenses, dust adheres to the wall surface of the device, which makes it difficult to discharge from the device. In the case of a bag filter, the pressure loss may be abnormally large. As the gas circulation blower used in the present invention, a conventionally known device can be used as long as a predetermined air blowing amount and discharge pressure are satisfied. For example, a turbofan centrifugal blower, a movable blade type rotary compressor, a roots blower, a Nash pump, and the like can be given.

【0017】本発明で使用する熱風発生装置としては、
ガスを所定の温度にまで加熱することができれば、従来
から知られている通常の気体用熱交換機を使用すること
ができる。例えば、フィン付き多管式で、管外にガス、
管内に加圧蒸気を流す形式の熱交換機を使用することが
できる。本発明で使用する冷却凝縮器としては、有機溶
剤を含むガスを所定の温度にまで冷却することができる
性能を持つものであれば、従来から知られている通常の
冷却凝縮器を使用することができる。例えば、熱風発生
装置と同様なフィン付き多管式で管内に冷却水を流す形
式の熱交換機を使用することができる。
The hot air generator used in the present invention includes:
As long as the gas can be heated to a predetermined temperature, a conventionally known ordinary gas heat exchanger can be used. For example, multi-tube type with fins, gas outside the tube,
A heat exchanger of a type in which pressurized steam flows through the pipe can be used. As the cooling condenser used in the present invention, a conventionally known ordinary cooling condenser may be used as long as it has a performance capable of cooling a gas containing an organic solvent to a predetermined temperature. Can be. For example, it is possible to use a finned multi-tubular heat exchanger similar to the hot air generator, in which cooling water flows through the pipes.

【0018】本発明で使用する被覆液調整槽は、ポリマ
ーを使用する溶剤に溶解させることおよび無機粉体を溶
剤に分散させることができる装置であることが必要であ
り、撹拌装置および加熱装置が付いた槽が好ましい。本
発明で使用する送液ポンプとしては、ポリマーを含む液
を被覆装置内のスプレーノズルから噴霧できる送液圧力
と所定の送液能力を持つものであれば、従来から知られ
ている通常の送液ポンプを使用することができる。例え
ば、プランジャーポンプ、ギヤポンプ、スクリューポン
プ等を使用することができる。
The coating liquid adjusting tank used in the present invention needs to be a device capable of dissolving a polymer in a solvent and dispersing an inorganic powder in the solvent, and a stirring device and a heating device are required. A fitted tank is preferred. As the liquid sending pump used in the present invention, a conventionally known ordinary sending pump can be used as long as it has a sending pressure capable of spraying a liquid containing a polymer from a spray nozzle in a coating apparatus and a predetermined sending ability. A liquid pump can be used. For example, a plunger pump, a gear pump, a screw pump, and the like can be used.

【0019】本発明において、これらの装置で循環用の
ガスが流れる順としては、熱風発生装置で加熱されたガ
スが被覆装置に入り、被覆装置を出た溶媒を含むガスが
冷却凝縮器に入る順が必須であり、ガス循環ブロワーお
よび粉塵除去装置は、これらの装置間のいずれかに設置
される。被覆装置で発生した粉塵が他の装置を汚染し、
冷却、加熱効率を低減することを防止するため、粉塵除
去装置は被覆装置のすぐ後に設置されることが好まし
い。また、溶剤にブロワーの腐食や高温によるブロワー
の腐食を低減するため、ガス循環ブロワーは冷却凝縮器
と熱風発生装置の間に設置することが好ましい。これら
の理由により、特に好ましい順としては、熱風発生装置
で加熱されたガスはすぐに被覆装置に入り、被覆装置を
出た溶剤を含むガスはすぐに粉塵除去装置に入り、その
後に冷却凝縮装置を経て、ガス循環ブロワーで加圧され
熱風発生装置に戻る順である。
In the present invention, the order in which the gas for circulation flows in these devices is such that the gas heated by the hot air generator enters the coating device, and the gas containing the solvent exiting the coating device enters the cooling condenser. The order is essential, and the gas circulation blower and the dust removal device are installed somewhere between these devices. Dust generated by the coating equipment contaminates other equipment,
In order to prevent the cooling and heating efficiency from being reduced, the dust removing device is preferably installed immediately after the coating device. Further, in order to reduce the corrosion of the blower by the solvent and the corrosion of the blower due to the high temperature, it is preferable to install the gas circulation blower between the cooling condenser and the hot air generator. For these reasons, in a particularly preferred order, the gas heated by the hot-air generator immediately enters the coating device, the gas containing the solvent leaving the coating device immediately enters the dust removal device, and then the cooling condensing device. , And pressurized by the gas circulation blower to return to the hot air generator.

【0020】また、被覆肥料の初期溶出を安定的に低減
された肥料を製造するには、上記の装置の被覆装置の後
に、製品被覆肥料と破砕された肥料粒子や大きな粉塵お
よび被覆中に発生した大きな肥料の固まりなどを分離す
るための篩等を設けることが好ましい。このような篩等
としては、被膜を傷つけない形式のものであれば、いか
なる形式のものでもよいが、通常、連続型振動篩が使用
される。また、連続型振動篩の上段目開きは、被覆前の
肥料の目開きよりも僅かに大きくすることが好ましく、
また、下段目開きは、被覆前の肥料と同じ程度が好まし
い。上段目開きをやや大きくするのは、被覆による肥料
粒子の太りを顧慮したものである。
Further, in order to produce a fertilizer in which the initial elution of the coated fertilizer is stably reduced, the product coated fertilizer and the crushed fertilizer particles, large dust, and dust generated in the coating after the coating device of the above device. It is preferable to provide a sieve or the like for separating a large lump of fertilizer or the like. As such a sieve or the like, any type may be used as long as it does not damage the coating, but a continuous vibrating sieve is usually used. Also, the upper opening of the continuous vibrating sieve is preferably slightly larger than the opening of the fertilizer before coating,
Further, it is preferable that the size of the lower opening is the same as that of the fertilizer before coating. The reason for making the upper opening slightly larger is to take into account the thickening of fertilizer particles due to coating.

【0021】[0021]

【発明の実施の形態】以下、本発明の被覆肥料の製造装
置の実施例と、該製造装置による被覆肥料の製造方法の
実施例、および得られた被覆肥料の評価について示す
が、本発明は、以下の実施例に限定されるものではな
い。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, an example of a coated fertilizer manufacturing apparatus of the present invention, an example of a method of manufacturing a coated fertilizer by the manufacturing apparatus, and evaluation of the obtained coated fertilizer will be described. However, the present invention is not limited to the following embodiments.

【実施例1】1)被覆肥料の製造装置 本発明の被覆肥料の製造装置を図1に示す。図1におい
て、1は塔径400mm、高さ3mの噴流塔であり、原
肥投入口および被覆物排出口を有する。2はバグフィル
ターであり、内部に内径200mm、長さ2m、1ミク
ロンの微粒子除去能力99.5%のフィルター3本を内
蔵している。3は有効伝熱面積56平方mのフィンチュ
ーブ式冷却凝縮器である。4は600N立方m/hr、
0.35atmの送風能力のルーツ型ブロワーである。
5は有効伝熱面積7.5平方mのフィンチューブ式熱風
発生装置である。6は内径800mm、高さ700mm
の撹拌器の被覆液調整槽であり、撹拌装置と加熱のため
のスチームジャケットおよび温度調節器がついている。
7は2.5L/minのプランジャー型送液ポンプであ
る。8はスプレーノズル、9は120mm径のガイド
管、10は振動篩である。なお、図1において、cwは
冷却水、solは凝縮した有機溶剤、stは蒸気、dr
は凝縮水を示す。
Example 1 1) Apparatus for producing coated fertilizer FIG. 1 shows an apparatus for producing coated fertilizer of the present invention. In FIG. 1, reference numeral 1 denotes a jet tower having a tower diameter of 400 mm and a height of 3 m, which has an inlet for raw manure and an outlet for coated material. Reference numeral 2 denotes a bag filter, which contains three filters having an inner diameter of 200 mm, a length of 2 m, and a micron removing capability of 99.5%. 3 is a fin tube type cooling condenser having an effective heat transfer area of 56 square meters. 4 is 600N cubic m / hr,
It is a roots-type blower with a blowing capacity of 0.35 atm.
Reference numeral 5 denotes a fin tube type hot air generator having an effective heat transfer area of 7.5 square meters. 6 is 800mm inside diameter, 700mm height
This is a coating liquid adjustment tank of a stirrer, which is equipped with a stirrer, a steam jacket for heating, and a temperature controller.
Reference numeral 7 denotes a 2.5 L / min plunger type liquid feed pump. Reference numeral 8 denotes a spray nozzle, 9 denotes a guide tube having a diameter of 120 mm, and 10 denotes a vibrating sieve. In FIG. 1, cw is cooling water, sol is a condensed organic solvent, st is steam, dr
Indicates condensed water.

【0022】2)被覆肥料の製造方法(野菜全量基肥セ
ル育苗用NP肥料) 上記の被覆肥料の製造装置を使用し、下記の操作により
被覆粒状肥料を製造した。パークロルエチレン414k
gを被覆液調整槽に投入し、ジャケットにスチームを通
じ120℃に加温する。この槽に撹拌機を起動し、タル
ク14.4kgを投入する。5分後、ポリエチレン〔商
品名 サンテックM2270、旭化成工業(株)製〕1
9.8kg、ポリエチレングリコールモノメチルエーテ
ル〔商品名ユニオックスM2000、日本油脂(株)
製〕1.8kgを投入し、120℃に加温溶解させる。
肥料投入前にブロワーを起動させ、70℃の熱風を噴流
塔、バクフィルターを含む系に約1時間循環させ、噴流
塔、バグフィルターを余熱する。
2) Production method of coated fertilizer (NP fertilizer for growing all-vegetable basal cell seedlings) Using the above-mentioned apparatus for producing coated fertilizer, coated granular fertilizer was produced by the following operation. Parkroll ethylene 414k
g was put into a coating liquid adjusting tank, and heated to 120 ° C. through steam in a jacket. A stirrer is started in this tank, and 14.4 kg of talc is charged. After 5 minutes, polyethylene [trade name: Suntech M2270, manufactured by Asahi Kasei Corporation] 1
9.8 kg, polyethylene glycol monomethyl ether [trade name UNIOX M2000, NOF Corporation]
1.8 kg, and heated and dissolved at 120 ° C.
Activate the blower before feeding the fertilizer, circulate the hot air of 70 ° C through the system including the jet tower and back filter for about 1 hour, and preheat the jet tower and bag filter.

【0023】ブロワーの送風量を450N立方m/hr
とし、窒素29%および苦溶性リン3%を含む粒状肥料
〔商品名 くみあい燐硝安2903、旭化成工業(株)
製〕を、2.3mmから3.4mmに篩粉したもの30
kgを噴流塔に徐々に投入し、肥料を噴流状態にする。
投入口を閉じ、熱風発生装置出口の熱風温度を140℃
に昇温させ、噴流塔内の肥料の温度が65℃になった時
点で送液ポンプを起動し、3.3kg/minの送液速
度で被覆液を送りスプレーを開始した。噴流塔内肥料の
温度は、スプレー開始直後やや低下したものの、ほぼ6
5℃で一定であった。13分間スプレーした後、送液ポ
ンプを停止し、熱風を冷風に切り替えた。噴流塔内の肥
料の温度が40℃以下になったならば、ブロワーを停止
し、できた被覆肥料を噴流塔下部の排出バルブより抜き
出した。この被覆肥料を、2.3mmと4mmの篩で篩
粉し、中間の粒度のものを製品とした。2バッチ目から
は余熱時間を10分とした以外は、同様な操作で被覆を
繰り返し、合計10バッチを生産した。製品被覆肥料の
収量は、各バッチとも約33kgであり、被覆物を切断
し、被膜の重量を測定したところ、各バッチともに被覆
肥料に含まれる被膜の割合は10.3重量%であった。
また、篩上および篩下の被覆肥料は、全バッチ平均でバ
ッチ当たり0.3kgであった。
The blower blow rate is 450N cubic m / hr.
And a granular fertilizer containing 29% of nitrogen and 3% of insoluble phosphorus [trade name: Kumiai Phosphorus Nitan 2903, Asahi Kasei Corporation]
Manufactured from 2.3 mm to 3.4 mm 30
kg is gradually injected into the spout tower, and the fertilizer is spouted.
Close the inlet and set the hot air temperature at the hot air generator outlet to 140 ° C.
When the temperature of the fertilizer in the jet tower reached 65 ° C., the liquid feed pump was started, and the coating liquid was fed at a liquid feed rate of 3.3 kg / min to start spraying. Although the temperature of the fertilizer in the spout tower decreased slightly immediately after the start of spraying, it was almost 6
It was constant at 5 ° C. After spraying for 13 minutes, the liquid sending pump was stopped, and the hot air was switched to cold air. When the temperature of the fertilizer in the spout tower became 40 ° C. or lower, the blower was stopped, and the resulting coated fertilizer was withdrawn from the discharge valve at the bottom of the spout tower. The coated fertilizer was sieved with a 2.3 mm and 4 mm sieve to obtain a product having an intermediate particle size. Coating was repeated by the same operation except that the residual heat time was changed to 10 minutes from the second batch, thereby producing a total of 10 batches. The yield of the product-coated fertilizer was about 33 kg for each batch, and the coating was cut and the weight of the coating was measured. As a result, the ratio of the coating contained in the coating fertilizer for each batch was 10.3% by weight.
The on-screen and under-screen coated fertilizer was 0.3 kg per batch on average for all batches.

【0024】3)被覆肥料の評価 製造した被覆肥料の溶出率を測定した。ポリ瓶に被覆肥
料5.00gをポリエチレンのネットに詰めて入れる。
この瓶に蒸留水200mlを加え、25℃のインキュウ
ベーターに所定の日数放置する。所定の日数になったな
らば、ポリエチレンネットを取り出し、水洗し、残りの
液と併せて500mlとし、水中の硝酸態窒素およびア
ンモニア態窒素を肥料分析法に基づき分析する。ポリエ
チレンネットは再び、ポリ瓶に入れ、蒸留水200ml
を加え、25℃で放置する。この操作を繰り返す。測定
結果を表1にまとめて示す。また、篩上および篩上の被
覆肥料の30日目の溶出率は8〜40%であり、製品の
溶出率に比較して著しく高かった。野菜全量基肥セル育
苗用NP肥料に重要なのは、30日目の溶出率が低いこ
とであり、通常、この溶出率が1%を越えると、育苗期
間中に根痛みが激しくなる。本実施例では30日目の溶
出率が全て1%以下であり、要求される性能を満たす被
覆肥料を安定的に生産できた。
3) Evaluation of coated fertilizer The dissolution rate of the manufactured coated fertilizer was measured. A plastic bottle is filled with 5.00 g of the coated fertilizer in a polyethylene net.
200 ml of distilled water is added to the bottle, and the bottle is left in an incubator at 25 ° C. for a predetermined number of days. When the predetermined number of days has been reached, the polyethylene net is taken out, washed with water, made up to 500 ml in total with the remaining liquid, and the nitrate nitrogen and ammonia nitrogen in the water are analyzed based on the fertilizer analysis method. Put the polyethylene net into a plastic bottle again, and add 200 ml of distilled water.
And left at 25 ° C. Repeat this operation. Table 1 summarizes the measurement results. The elution rate of the on-screen and the coated fertilizer on the 30th day was 8 to 40%, which was significantly higher than the elution rate of the product. What is important for the NP fertilizer for raising whole-cell-based fertilizer cells for seedlings is that the elution rate on the 30th day is low. Usually, when the elution rate exceeds 1%, the root pain becomes severe during the seedling raising period. In this example, the elution rates on the 30th day were all 1% or less, and a coated fertilizer satisfying the required performance could be stably produced.

【0025】[0025]

【表1】 [Table 1]

【0026】[0026]

【実施例2】1)被覆肥料の製造装置 図1に示す前記実施例1の被覆肥料の製造装置におい
て、噴流塔内のガイド管を取り外した以外は、実施例1
と同様にして被覆肥料の製造装置とした。 2)被覆肥料の製造方法(水稲全量苗箱施肥用尿素肥
料) 実施例1の翌日、上記の被覆肥料の製造装置を使用し、
下記の操作により被覆粒状肥料を製造した。パークロル
エチレン414kgを被覆液調整槽に投入し、ジャケッ
トにスチームを通じ120℃に加温する。この槽に撹拌
機を起動し、タルク14.8kgとシリコーン処理デン
プン〔商品名 ミニパックS、ニッカ(株)製〕2.1
6kgを投入する。5分後、ポリエチレン〔商品名 サ
ンテックM2270、旭化成工業(株)製〕19.1k
gを投入し、120℃に加温溶解させる。肥料投入前に
ブロワーを起動させ、70℃の熱風を噴流塔、バクフィ
ルターを含む系に約1時間循環させ、噴流塔、バグフィ
ルターを余熱する。
Embodiment 2 1) Apparatus for producing coated fertilizer Example 1 of the apparatus for producing coated fertilizer of Example 1 shown in FIG. 1 except that a guide pipe in a jet tower was removed.
In the same manner as in the above, an apparatus for producing a coated fertilizer was prepared. 2) Production method of coated fertilizer (urea fertilizer for application of whole rice seedling box fertilizer) On the day after Example 1, using the above-mentioned production apparatus for coated fertilizer,
A coated granular fertilizer was produced by the following operation. 414 kg of perchlor ethylene is charged into a coating solution adjusting tank, and heated to 120 ° C. through steam in a jacket. A stirrer was started in this tank, and 14.8 kg of talc and silicone-treated starch (trade name: Minipack S, manufactured by Nikka Co., Ltd.) 2.1
Input 6kg. After 5 minutes, polyethylene (trade name: Suntech M2270, manufactured by Asahi Kasei Corporation) 19.1k
g, and the mixture is heated and dissolved at 120 ° C. Activate the blower before feeding the fertilizer, circulate the hot air of 70 ° C through the system including the jet tower and back filter for about 1 hour, and preheat the jet tower and bag filter.

【0027】ブロワーの送風量を450N立方m/hr
とし、尿素肥料〔商品名 くみあい大粒尿素、三井化学
(株)製〕を2.3mmから3.4mmに篩粉したもの
30kgを噴流塔に徐々に投入し、肥料を噴流状態にす
る。投入口を閉じ、熱風発生装置出口の熱風温度を14
5℃に昇温させ、噴流塔内の肥料の温度が70℃になっ
た時点で送液ポンプを起動し、3.3kg/minの送
液速度で被覆液を送り、スプレーを開始した。噴流塔内
肥料の温度は、スプレー開始直後やや低下したものの、
ほぼ70℃で一定であった。13.6分間スプレーした
後、送液ポンプを停止し、熱風を冷風に切り替えた。噴
流塔内の肥料の温度が50℃以下になったならば、ブロ
ワーを停止し、できた被覆肥料を噴流塔下部の排出バル
ブより抜き出した。2バッチ目からは余熱時間を10分
とした以外は、同様な操作で被覆を繰り返し、合計10
バッチを生産した。被覆肥料の収量は、各バッチともに
33.5kgであり、被覆物を切断し、被膜の重量を測
定したところ、各バッチともに被覆肥料中に含まれる被
膜の割合は10.7重量%であった。また、実施例1、
2終了後、バグフィルターに捕集されていた粉塵払い出
し重量を測定したところ、0.95kgあった。
[0027] The blower blow rate is 450N cubic m / hr.
Then, 30 kg of urea fertilizer (trade name: Kumiai large-grain urea, manufactured by Mitsui Chemicals, Inc.) sieved from 2.3 mm to 3.4 mm is gradually charged into the jet tower to make the fertilizer into a jet state. Close the inlet and set the hot air temperature at the hot air generator outlet to 14
The temperature was raised to 5 ° C., and when the temperature of the fertilizer in the jet tower reached 70 ° C., the liquid sending pump was started, and the coating liquid was sent at a liquid sending rate of 3.3 kg / min, and spraying was started. The temperature of the fertilizer in the spout tower decreased slightly immediately after the start of spraying,
It was constant at approximately 70 ° C. After spraying for 13.6 minutes, the liquid feed pump was stopped, and the hot air was switched to cold air. When the temperature of the fertilizer in the spout tower became 50 ° C. or less, the blower was stopped, and the resulting coated fertilizer was withdrawn from the discharge valve at the bottom of the spout tower. From the second batch, coating was repeated by the same operation except that the residual heat time was set to 10 minutes, and a total of 10
Batch produced. The yield of the coated fertilizer was 33.5 kg for each batch, and the coating was cut and the weight of the coating was measured. As a result, the ratio of the coating contained in the coated fertilizer for each batch was 10.7% by weight. . Example 1,
After the completion of Step 2, the weight of the dust discharged from the bag filter was measured and found to be 0.95 kg.

【0028】3)被覆肥料の評価 実施例1と同様な操作により、被覆肥料中の尿素成分溶
出率を測定した。測定結果を表2にまとめて示す。水稲
全量苗箱施肥用肥料に要求される重要な性能の一つは、
30日目の溶出率が低いことであり、通常、この溶出率
が3%を越えると育苗期間中に苗の徒長、黄変化などの
障害が現れるようになる。さらに、溶出率が高くなると
苗が枯死する。本実施例では30日目の溶出率が全て3
%以下であり、要求される性能を満たす肥料を安定的に
生産できた。
3) Evaluation of coated fertilizer The dissolution rate of urea component in the coated fertilizer was measured by the same operation as in Example 1. Table 2 summarizes the measurement results. One of the important performance requirements for fertilizer for rice seedling box fertilizer application is
The elution rate on the 30th day is low. Usually, when the elution rate exceeds 3%, disorders such as seedling growth and yellowing appear during the seedling raising period. Furthermore, when the elution rate increases, the seedlings die. In this example, the elution rate on day 30 was all 3
% Or less, and could stably produce fertilizers satisfying the required performance.

【0029】[0029]

【表2】 [Table 2]

【0030】[0030]

【比較例1】1)被覆肥料の製造装置 実施例1の被覆肥料の製造装置において、バグフィルタ
ーを取り外し、替わりに直径0.3mの単純接直径の線
入り口型サイクロン11を設置した以外は、実施例1と
同様にして被覆肥料の製造装置とした。その装置を図2
に示す。 2)被覆肥料の製造方法 実施例1と同じ肥料、同じ被覆液を使用し同様な操作に
より(バグフィルターはないが余熱時間は1バッチ目は
1時間とした)、被覆肥料を合計10バッチを生産し
た。被覆後の篩粉は行わなかった。被覆物の重量は、各
バッチともに33kgであり、被覆物を切断し、被膜の
重量を測定したところ、各バッチともに肥料に対して1
0重量%の被膜がついていた。 3)被覆肥料の評価 実施例1と同様な操作により、被覆肥料中の窒素成分の
溶出率を測定した。測定結果をまとめて表3に示す。本
比較例では7バッチ目より、30日目の溶出率が高くな
り、1%を越えたものになった。
[Comparative Example 1] 1) Apparatus for producing coated fertilizer In the apparatus for producing coated fertilizer of Example 1, except that a bag filter was removed and a line entrance type cyclone 11 having a simple tangent diameter of 0.3 m was installed instead. In the same manner as in Example 1, an apparatus for producing a coated fertilizer was obtained. Fig. 2
Shown in 2) Manufacturing method of coated fertilizer By using the same fertilizer and the same coating liquid as in Example 1 and performing the same operation (there is no bag filter but the remaining heat time is 1 hour for the first batch), a total of 10 batches of coated fertilizer are used. Produced. No sieve flour was applied after coating. The weight of the coating was 33 kg for each batch, and the coating was cut and the weight of the coating was measured.
There was a coating of 0% by weight. 3) Evaluation of coated fertilizer The dissolution rate of the nitrogen component in the coated fertilizer was measured by the same operation as in Example 1. Table 3 summarizes the measurement results. In this comparative example, the elution rate on the 30th day was higher than that of the 7th batch and exceeded 1%.

【0031】[0031]

【表3】 [Table 3]

【0032】[0032]

【比較例2】1)被覆肥料の製造装置 比較例1の被覆肥料の製造装置において、噴流塔内のガ
イド管を取り外した以外は、比較例1と同様にして被覆
肥料の製造装置とした。 2)被覆肥料の製造方法 比較例1の翌日、実施例2と同じ肥料、同じ被覆液を使
用し、同様な操作により(余熱時間1時間とした)、被
覆肥料を合計10バッチを生産した。被覆物の重量は、
各バッチともに33.6kgであり、被覆物を切断し、
被膜の重量を測定したところ、各バッチともに肥料に対
して12重量%の被膜がついていた。比較例1、2終了
後、サイクロンに捕集されていた粉塵の重量を測定した
ところ、0.7kgであった。 3)被覆肥料の評価 実施例2と同様な操作により、被覆肥料中の尿素成分の
溶出率を測定した。測定結果をまとめて表4に示す。本
比較例では、ほとんどののバッチで30日目の溶出率が
3%を越えたものになった。また、30日間の溶出率の
バラツキも大きかった。
Comparative Example 2 1) Apparatus for producing coated fertilizer The apparatus for producing coated fertilizer of Comparative Example 1 was replaced with the apparatus for producing coated fertilizer in the same manner as Comparative Example 1 except that the guide tube in the jet tower was removed. 2) Manufacturing method of coated fertilizer On the next day of Comparative Example 1, the same fertilizer and the same coating liquid as those in Example 2 were used, and the same operation (remaining heating time was set to 1 hour) produced a total of 10 batches of coated fertilizer. The weight of the coating is
Each batch weighs 33.6 kg, cuts the coating,
When the weight of the coating was measured, each batch had a coating of 12% by weight based on the fertilizer. After the completion of Comparative Examples 1 and 2, the weight of the dust collected in the cyclone was measured and found to be 0.7 kg. 3) Evaluation of coated fertilizer The dissolution rate of the urea component in the coated fertilizer was measured by the same operation as in Example 2. Table 4 summarizes the measurement results. In this comparative example, the elution rate on the 30th day exceeded 3% in most of the batches. In addition, the dispersion of the elution rate for 30 days was large.

【0033】[0033]

【表4】 [Table 4]

【0034】[0034]

【発明の効果】本発明の噴流塔のガスの出口とガス冷却
器との間に、高性能の粉塵除去装置を設けた装置を使用
することにより、初期溶出抑制期間の溶出率が低減され
た時限溶出型被覆肥料を大量かつ安定的に生産すること
が可能である。また、同時に粉塵による装置の汚染を防
止することも可能である。
According to the present invention, by using a device provided with a high-performance dust removing device between the gas outlet of the jet tower and the gas cooler of the present invention, the dissolution rate during the initial dissolution suppression period is reduced. It is possible to stably produce a large amount of time-dissolving coated fertilizer. At the same time, it is possible to prevent contamination of the device by dust.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施例1に示す被覆肥料の製造装置の
説明図である。
FIG. 1 is an explanatory diagram of an apparatus for producing a coated fertilizer shown in Example 1 of the present invention.

【図2】比較例1に示す被覆肥料の製造装置の説明図で
ある。
FIG. 2 is an explanatory diagram of an apparatus for producing a coated fertilizer shown in Comparative Example 1.

【符号の説明】[Explanation of symbols]

1 噴流塔型被覆装置 2 バグフィルター 3 フィンチューブ式冷却凝縮器 4 ルーツ型ブロワー 5 フィンチューブ式熱風発生装置 6 攪拌機付き被覆液調整槽 7 プランジャー式送液ポンプ 8 スプレーノズル 9 ガイド管 10 振動篩 11 サイクロン cw 冷却水 sol 凝縮した有機溶剤 st 蒸気 dr 凝縮水 DESCRIPTION OF SYMBOLS 1 Spout tower type coating apparatus 2 Bag filter 3 Fin tube type cooling condenser 4 Roots type blower 5 Fin tube type hot air generator 6 Coating liquid adjustment tank with a stirrer 7 Plunger type liquid sending pump 8 Spray nozzle 9 Guide pipe 10 Vibrating sieve 11 cyclone cw cooling water sol condensed organic solvent st steam dr condensed water

フロントページの続き Fターム(参考) 4D073 AA01 BB03 CA12 DC19 DC22 4D075 AA04 BB18Z BB24Y BB33Y CA50 DA11 DB32 DC50 EA07 EB01 EB13 4H061 AA02 AA03 DD04 EE35 FF08 FF15 GG15 GG19 GG47 GG51 HH02 LL15 LL30 Continued on front page F term (reference) 4D073 AA01 BB03 CA12 DC19 DC22 4D075 AA04 BB18Z BB24Y BB33Y CA50 DA11 DB32 DC50 EA07 EB01 EB13 4H061 AA02 AA03 DD04 EE35 FF08 FF15 GG15 GG19 GG47 GG51 H

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 ポリマー溶液を肥料の表面に吹き付け乾
燥させることにより肥料表面をポリマーで被覆する被覆
装置を用い、被覆装置から排出する乾燥に使用したガス
をガスの循環系より被覆装置に再導入して被覆肥料を製
造する方法において、被覆装置からのガス出口と前記ガ
スの循環系に設けたガスの冷却凝縮器との間に、1〜1
0ミクロン粒子の除去率が95%以上、かつ、10〜1
00ミクロン粒子の除去率が99.5%以上の性能を有
する粉塵除去装置を設けて、乾燥に使用したガスの粉塵
を除去することを特徴とする被覆肥料の製造方法。
1. A coating apparatus for coating a surface of a fertilizer with a polymer by spraying and drying a polymer solution on a surface of a fertilizer, and reusing gas used for drying discharged from the coating apparatus into the coating apparatus from a gas circulation system. And producing a coated fertilizer, wherein between a gas outlet from the coating device and a gas cooling condenser provided in the gas circulation system, 1 to 1
The removal rate of 0 micron particles is 95% or more and 10 to 1
A method for producing a coated fertilizer, comprising: providing a dust removing device having a performance of removing a 00 micron particle of 99.5% or more to remove dust of gas used for drying.
【請求項2】 ポリマー溶液を肥料の表面に吹き付け乾
燥させることにより肥料表面をポリマーで被覆する被覆
装置と、被覆装置から排出する乾燥に使用したガスを被
覆装置に再導入するためのガスの循環系とを含む被覆肥
料の製造装置において、被覆装置からのガス出口と前記
ガスの循環系に設けたガスの冷却凝縮器との間に、1〜
10ミクロン粒子の除去効率が95%以上、かつ、10
〜100ミクロン粒子の除去効率が99.5%以上の性
能を有する粉塵除去装置を設けたことを特徴とする被覆
肥料の製造装置。
2. A coating apparatus for coating a fertilizer surface with a polymer by spraying and drying a polymer solution on a surface of a fertilizer, and a gas circulation for re-introducing a gas used for drying discharged from the coating apparatus to the coating apparatus. System for producing a coated fertilizer including a system, between a gas outlet from the coating device and a gas cooling condenser provided in the gas circulation system,
The removal efficiency of 10 micron particles is 95% or more and 10
An apparatus for producing a coated fertilizer, comprising a dust removing apparatus having a performance of removing particles having a particle size of from 100 to 100 microns of 99.5% or more.
【請求項3】 ガスの循環系がガス循環ブロワー、熱風
発生装置を含むことを特徴とする請求項2記載の被覆肥
料の製造装置。
3. The apparatus for producing coated fertilizer according to claim 2, wherein the gas circulation system includes a gas circulation blower and a hot air generator.
【請求項4】 粉塵除去装置がバグフィルターであるこ
とを特徴とする請求項2記載の被覆肥料の製造装置。
4. The apparatus for producing coated fertilizer according to claim 2, wherein the dust removing device is a bag filter.
【請求項5】 被覆後の肥料をさらに分級し粉末などを
除去する装置を設けたことを特徴とする請求項2記載の
被覆肥料の製造装置。
5. The apparatus for producing coated fertilizer according to claim 2, further comprising an apparatus for further classifying the coated fertilizer to remove powder and the like.
JP11064522A 1999-03-11 1999-03-11 Production of coated fertilizer and its apparatus Withdrawn JP2000256088A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11064522A JP2000256088A (en) 1999-03-11 1999-03-11 Production of coated fertilizer and its apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11064522A JP2000256088A (en) 1999-03-11 1999-03-11 Production of coated fertilizer and its apparatus

Publications (2)

Publication Number Publication Date
JP2000256088A true JP2000256088A (en) 2000-09-19
JP2000256088A5 JP2000256088A5 (en) 2006-04-06

Family

ID=13260644

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11064522A Withdrawn JP2000256088A (en) 1999-03-11 1999-03-11 Production of coated fertilizer and its apparatus

Country Status (1)

Country Link
JP (1) JP2000256088A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675881A (en) * 2018-07-27 2018-10-19 遵义大兴复肥有限责任公司 Processing unit (plant) for making fertilizer

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675881A (en) * 2018-07-27 2018-10-19 遵义大兴复肥有限责任公司 Processing unit (plant) for making fertilizer
CN108675881B (en) * 2018-07-27 2023-09-19 遵义大兴复肥有限责任公司 A processingequipment for making fertilizer

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