JP2000231916A - Apparatus and method for welding lead-acid battery electrode plate group - Google Patents

Apparatus and method for welding lead-acid battery electrode plate group

Info

Publication number
JP2000231916A
JP2000231916A JP11032100A JP3210099A JP2000231916A JP 2000231916 A JP2000231916 A JP 2000231916A JP 11032100 A JP11032100 A JP 11032100A JP 3210099 A JP3210099 A JP 3210099A JP 2000231916 A JP2000231916 A JP 2000231916A
Authority
JP
Japan
Prior art keywords
lead
mold
electrode plate
laminate
positive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
JP11032100A
Other languages
Japanese (ja)
Inventor
Shigetaka Kitamori
茂孝 北森
Masatoshi Miyatsuka
政敏 宮塚
Takumi Yamana
匠 山名
Toshihiro Kuroda
敏裕 黒田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Corp
Original Assignee
Shin Kobe Electric Machinery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shin Kobe Electric Machinery Co Ltd filed Critical Shin Kobe Electric Machinery Co Ltd
Priority to JP11032100A priority Critical patent/JP2000231916A/en
Publication of JP2000231916A publication Critical patent/JP2000231916A/en
Abandoned legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

PROBLEM TO BE SOLVED: To provide an apparatus for welding a lead-acid battery electrode plate group of energy saving, with less oxidizing scum, less lead mist, less effect to environment with a stable operation. SOLUTION: This apparatus for welding a lead-acid battery plate group has a process for coating a solid flux on a positive electrode tab part 4 and a negative electrode tab part by forming a layered product by alternately laminating a positive electrode plate 1 and a negative electrode plate 3 through a separator 2; a process for making a molton metal 7 of the lead alloy one the recessed part 9 of the mold 6 by induction heating by pressing after a solid lead or lead alloy on a recessed part 9 of a mold 6, disposing; and a process for cooling and solidifying by inverting and inserting the layered product into the recessed part 9 of the mold 6.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、キャスト・オン・
ストラップ方式による鉛蓄電池用極板群の溶接装置及び
溶接方法の改良に関するものである。
[0001] The present invention relates to a cast-on
The present invention relates to an improvement in a welding apparatus and a welding method for a lead storage battery electrode group using a strap method.

【0002】[0002]

【従来の技術】キャスト・オン・ストラップ方式によ
る、従来から用いられていた鉛蓄電池用極板群溶接装置
の工程図を図2に示す。すなわち、正極板1と負極板3と
をセパレータ2を介して交互に重ねて積層して積層体を
組み(図3)、正極耳部4及び負極耳部5に液体状のフラ
ックスを塗着した後に乾燥させる。一方、図4に示すよ
うに鉛又は鉛合金を溶解させて溶湯7を作製し、該溶湯7
を加熱した鋳型6の窪み部9に供給し、溶湯7の液面を鋳
型6の高さで擦り切って、溶湯7の高さを揃えた後、前記
積層体を逆さにし、同じ極性の耳同士を前記鉛合金の溶
湯7が満たされた窪み部9に挿入して冷却・凝固させる。
その後、積層体を鋳型6から取り出すことによって、同
じ極性の極板どうしがストラップ8によって電気的に接
続される(図5)。この溶接方式は、一般的にキャスト
・オン・ストラップ方式呼ばれており、密閉型鉛蓄電池
や自動車用鉛蓄電池などの、大量に生産される電池に適
した生産方式であることから広く一般に使用されてい
る。
2. Description of the Related Art FIG. 2 shows a process diagram of a conventionally used lead-acid battery electrode group welding apparatus using a cast-on-strap method. That is, the positive electrode plate 1 and the negative electrode plate 3 were alternately stacked and laminated via the separator 2 to form a laminate (FIG. 3), and the positive electrode lug 4 and the negative electrode lug 5 were coated with a liquid flux. After drying. On the other hand, as shown in FIG.
Is supplied to the recess 9 of the heated mold 6, and the liquid surface of the molten metal 7 is rubbed with the height of the mold 6 so that the height of the molten metal 7 is uniform. These are inserted into the depression 9 filled with the molten metal 7 of the lead alloy and cooled and solidified.
Thereafter, by taking out the laminate from the mold 6, the plates having the same polarity are electrically connected by the strap 8 (FIG. 5). This welding method is generally called a cast-on-strap method and is widely used because it is a production method suitable for batteries produced in large quantities, such as sealed lead-acid batteries and automotive lead-acid batteries. ing.

【0003】しかしながら、従来から使用されていた図
2に示されるキャスト・オン・ストラップ方式による極
板群の溶接方式は、以下に示すような問題点が認められ
た。
[0003] However, the following problems have been recognized in the conventional welding method of the electrode plate group by the cast-on-strap method shown in FIG.

【0004】(1)極板群の溶接に際して、常に大量の
鉛合金を溶解させて溶湯7として保持しておく必要があ
り、溶湯7を加熱・保持するために多くのエネルギーを
必要とすること。
(1) It is necessary to always melt a large amount of lead alloy and hold it as molten metal 7 when welding the electrode group, and it requires a lot of energy to heat and hold molten metal 7. .

【0005】(2)大量の溶湯7を保持しておく必要が
あり、溶湯7の表面から鉛のミストが大気中に飛散する
ため、環境に悪影響を及ぼすこと。
(2) It is necessary to hold a large amount of molten metal 7, and lead mist scatters from the surface of molten metal 7 into the atmosphere, which adversely affects the environment.

【0006】(3)大気中の酸素によって保持されてい
る溶湯7の表面の鉛が酸化されるため、大量の酸化カス
が生成されること。また前記した摺り切り工程(図1)
においても、大量の酸化カスが発生すること。
(3) Since lead on the surface of the molten metal 7 held by oxygen in the atmosphere is oxidized, a large amount of oxidized scum is generated. In addition, the above-mentioned grinding step (FIG. 1)
, A large amount of oxidized gas is generated.

【0007】(4)鉛合金の溶湯7を鋳型6の窪み部9に
供給するためには、鉛合金の凝固点以上の温度に供給ポ
ンプや配管を、あらかじめ加熱しておく必要がある。そ
して、ポンプや配管内に鉛合金やその酸化カスが詰まる
場合があり、安定した稼動ができないこと。
(4) In order to supply the molten metal 7 of the lead alloy to the depression 9 of the mold 6, it is necessary to previously heat the supply pump and the pipe to a temperature higher than the solidification point of the lead alloy. In addition, the lead alloy or its oxidized gas may be clogged in the pump or the piping, and stable operation cannot be performed.

【0008】(5)鋳型6や、鋳型6の窪み部9に供給さ
れる溶湯の温度にバラツキが生じやすいこと。
(5) The temperature of the molten metal supplied to the mold 6 and the depression 9 of the mold 6 is likely to vary.

【0009】一方、誘導炉を用いて、あらかじめ鋳型6
を加熱しておく方法が特開平6−290770号公報や特開平8
−255608号公報などで開示されている。これらの方法
は、溶湯7を供給した後、誘導加熱によって鋳型6を加熱
し、溶融状態を維持しようとするものである。これらの
方法を用いると、前記の問題点のうち、鋳型6の温度に
バラツキは抑えられるものの、その他(1)〜(4)の
問題点は解決されない。
On the other hand, using an induction furnace,
The method of heating is described in JP-A-6-290770 and JP-A-8-290770.
-255608. In these methods, after the molten metal 7 is supplied, the mold 6 is heated by induction heating to maintain a molten state. When these methods are used, among the above-mentioned problems, the variation in the temperature of the mold 6 can be suppressed, but the other problems (1) to (4) cannot be solved.

【0010】[0010]

【発明が解決しようとする課題】本発明の目的は、省エ
ネルギーであり、酸化カスが少なく、鉛のミストの飛散
による環境への影響が少なく、安定した稼動が可能な鉛
蓄電池用極板群の溶接装置を提供することである。
SUMMARY OF THE INVENTION An object of the present invention is to provide an electrode group for a lead-acid battery which is energy-saving, has little oxidizing residue, has little influence on the environment due to scattering of lead mist, and can operate stably. It is to provide a welding device.

【0011】[0011]

【課題を解決するための手段】上記した課題を解決する
ために、第一の発明では、耳部を有する正極板と負極板
とをセパレータを介して交互に積層して積層体を形成
し、前記積層体の正極耳部と負極耳部にフラックス塗着
する手段と、固体の鉛又は鉛合金を鋳型の窪み部に設置
し、プレスした後、誘導加熱によって鉛又は鉛合金製の
溶湯を作製する手段と、前記積層体を逆さにして、前記
正極耳部及び負極耳部を前記溶湯が満たされた鋳型の窪
み部に挿入した後、冷却・凝固させる手段とを有するこ
とを特徴とする溶接装置に関するものである。
In order to solve the above-mentioned problems, in the first invention, a positive electrode plate having ears and a negative electrode plate are alternately laminated via a separator to form a laminate, Means for applying flux to the positive and negative ears of the laminate, and placing solid lead or a lead alloy in the recess of the mold, pressing and then producing a molten metal made of lead or lead alloy by induction heating And means for inverting the laminate, inserting the positive and negative electrode ears into the recesses of the mold filled with the molten metal, and then cooling and solidifying. It concerns the device.

【0012】第二の発明は、前記積層体の正極耳部と負
極耳部に塗着するフラックスは、ペースト状フラックス
を用いる物であることを特徴とする溶接装置に関するも
のである。
[0012] The second invention relates to a welding apparatus, wherein the flux applied to the positive and negative electrode lugs of the laminate uses a paste-like flux.

【0013】第三の発明は、耳部を有する正極板と負極
板とをセパレータを介して交互に積層して積層体を形成
し、前記積層体の正極耳部と負極耳部にフラックス塗着
する手段と、固体の鉛又は鉛合金を鋳型の窪み部に設置
し、プレスした後、誘導加熱によって鉛又は鉛合金製の
溶湯を作製する手段と、前記積層体を逆さにして、前記
正極耳部及び負極耳部を前記溶湯が満たされた鋳型の窪
み部に挿入した後、冷却・凝固させる手段とを有するこ
とを特徴とする、溶接方法に関するものである。
According to a third aspect of the invention, a positive electrode plate and a negative electrode plate each having a lug are alternately laminated with a separator interposed therebetween to form a laminate, and a flux is applied to the positive lug and the negative lug of the laminate. Means for placing solid lead or a lead alloy in a recess of a mold, pressing, and then producing a molten metal made of lead or lead alloy by induction heating, and inverting the laminate to form the positive electrode lug. And a means for cooling and solidifying after inserting the metal part and the negative electrode lug into the hollow part of the mold filled with the molten metal.

【0014】第四の発明は、前記積層体の正極耳部と負
極耳部に塗着するフラックスは、ペースト状フラックス
を用いる物であることを特徴とする、溶接方法に関する
ものである。
A fourth aspect of the present invention relates to a welding method, wherein the flux applied to the positive and negative electrode lugs of the laminate uses a paste-like flux.

【0015】[0015]

【発明の実施の形態】本発明の一実施例を以下に示す。
本発明に関するキャスト・オン・ストラップ方式によ
る、12V-5Ahの密閉型鉛蓄電池用極板群溶接装置の工程
図を図1に示す。すなわち、w38mm×h68mm×t3mmの正極
板1が3枚と、w38mm×h70mm×t2.5mmの負極板3が4枚と
をセパレータ2を介して交互に積層して積層体を作製
し、正極耳部4及び負極耳部5にペースト状のフラックス
を塗着する。今回、フラックスとしてタイトリ社製のタ
イトリペースト(商品名)を用いた。したがって、本発
明を用いるとフラックスの乾燥工程が不要になるという
特長がある。
DESCRIPTION OF THE PREFERRED EMBODIMENTS One embodiment of the present invention will be described below.
FIG. 1 shows a process diagram of a 12V-5Ah closed type lead-acid battery electrode group welding apparatus using a cast-on-strap method according to the present invention. That is, three positive electrode plates 1 of w38 mm × h68 mm × t3 mm and four negative electrode plates 3 of w38 mm × h70 mm × t2.5 mm are alternately laminated with the separator 2 interposed therebetween to produce a laminate. A paste-like flux is applied to the part 4 and the negative electrode ear part 5. This time, Titori paste (trade name) manufactured by Titori was used as the flux. Therefore, there is an advantage that the use of the present invention eliminates the need for a flux drying step.

【0016】そして、ロール状に巻いた鉛合金を一定の
寸法(約10g)で切りとって、鋳型6の窪み部9に供給し
て設置した後に400kgf/cm2の圧力でプレスする。なお、
プレスする理由は、鉛合金と鋳型6の窪み部9との接触面
積を増加させ、後述する誘導加熱時の熱伝導を容易に
し、溶湯7の温度のバラツキを少なくするためである。
窪み部9に鉛合金のブロックの入った鋳型6を、富士電波
工機(株)社製の誘導炉(周波数30kHz、出力30kW、加
熱時間10秒)を用いて誘導加熱して、鋳型6の窪み部9に
設置した鉛合金を溶解させて450±10℃の溶湯7を作製す
る。なお、周波数を30kHzとした理由は、作業者が騒音
として感じない領域であるためである。この方法を用い
ると、鋳型6と溶湯7の温度をほぼ一定にすることができ
る。
Then, the lead alloy wound into a roll is cut into a predetermined size (about 10 g), supplied to the recess 9 of the mold 6 and installed, and then pressed at a pressure of 400 kgf / cm 2 . In addition,
The reason for pressing is to increase the contact area between the lead alloy and the concave portion 9 of the mold 6, facilitate heat conduction during induction heating described later, and reduce the temperature variation of the molten metal 7.
The mold 6 having the lead alloy block in the recess 9 is induction-heated using an induction furnace (frequency 30 kHz, output 30 kW, heating time 10 seconds) manufactured by Fuji Denki Koki Co., Ltd. The lead alloy placed in the depression 9 is melted to produce a molten metal 7 at 450 ± 10 ° C. The reason why the frequency is set to 30 kHz is that it is an area where the worker does not feel noise. By using this method, the temperatures of the mold 6 and the molten metal 7 can be made substantially constant.

【0017】次に、前記積層体を逆さにして、正極耳部
4及び負極耳部5のそれぞれを前記鉛合金の溶湯7が満た
された窪み部9に挿入(図4)した後に、鋳型6に下部か
ら水を噴射して冷却する(図なし)。前記鉛合金の溶湯
7を冷却・凝固させた後、前記積層体を鋳型6から取り出
すことによって、同じ極性の極板どうしがストラップ8
によって電気的に接続される(図5)。
Next, the laminate is turned upside down and the positive electrode lug is
After inserting each of the negative electrode ear 4 and the negative electrode ear 5 into the hollow part 9 filled with the molten metal 7 of the lead alloy (FIG. 4), water is injected into the mold 6 from below to cool it (not shown). Molten lead alloy
After cooling and solidifying 7, the laminate is taken out of the mold 6 so that the plates having the same polarity can be strapped together.
(See FIG. 5).

【0018】本発明を用いると、以下に示す効果があ
る。
The use of the present invention has the following effects.

【0019】(1)鉛合金の溶湯7をあらかじめ作製
し、保持しておく必要がない。したがって、省エネルギ
ーであるとともに、鉛合金の酸化カスがほとんど生成さ
れず、鉛のミストも少ないため環境への影響がほとんど
ない。
(1) There is no need to prepare and hold the lead alloy melt 7 in advance. Therefore, it is not only energy-saving, but also hardly generates oxide scum of the lead alloy and little mist of lead, so that there is almost no influence on the environment.

【0020】(2)鋳型6の窪み部9へ鉛合金を固形の状
態で供給できるため、溶湯7をポンプで供給する場合に
比べて供給量が安定する。その結果、溶融後に摺り切り
工程が不要となり、摺り切り時に発生する酸化カスを皆
無にすることができる。さらに、鉛合金の溶湯7を供給
するためのポンプやパイプ及びそれらの加熱装置が不要
となる。
(2) Since the lead alloy can be supplied to the recess 9 of the mold 6 in a solid state, the supply amount is more stable than when the molten metal 7 is supplied by a pump. As a result, there is no need for a grinding step after melting, and it is possible to eliminate any oxidized residue generated during grinding. Further, a pump and a pipe for supplying the molten metal 7 of the lead alloy and a heating device thereof are not required.

【0021】(3)鉛合金を鋳型6の窪み部9に供給して
設置した後にプレスすることにより、鉛合金と鋳型6の
窪み部9との接触面積を増加させ、溶湯7温度のバラツキ
を少なくできる。
(3) The contact area between the lead alloy and the recess 9 of the mold 6 is increased by supplying the lead alloy to the recess 9 of the mold 6 and then pressing the same, thereby reducing the temperature variation of the molten metal 7. Can be reduced.

【0022】(4)ペースト状のフラックスを使用して
いるため、乾燥工程が不要となる。
(4) Since a paste-like flux is used, a drying step is not required.

【0023】[0023]

【発明の効果】上述したように、本発明に係る鉛蓄電池
用極板群の溶接装置を用いると、省エネルギーであり、
酸化カスが少なく、鉛のミストが少ないため環境への影
響が少なく、安定した稼動が可能な鉛蓄電池用極板群の
溶接装置が提供できる点で優れている。
As described above, the use of the lead-acid battery electrode group welding apparatus according to the present invention can save energy.
The present invention is excellent in that it can provide a welding device for a lead-acid battery electrode group that can be operated stably because it has a small amount of oxidized gas and little mist of lead.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の鉛蓄電池用極板群溶接装置の工程図で
ある。
FIG. 1 is a process diagram of a lead-acid battery electrode group welding apparatus of the present invention.

【図2】従来の鉛蓄電池用極板群溶接装置の工程図であ
る。
FIG. 2 is a process diagram of a conventional lead plate battery electrode group welding apparatus.

【図3】正極板、セパレータ及び負極板の積層体の概略
図である。
FIG. 3 is a schematic view of a laminate of a positive electrode plate, a separator, and a negative electrode plate.

【図4】溶接中の積層体の概略図である。FIG. 4 is a schematic view of a laminate during welding.

【図5】溶接後の積層体の概略図である。FIG. 5 is a schematic view of a laminated body after welding.

【符号の説明】[Explanation of symbols]

1:正極板、 2:セパレータ、 3:負極板、 4:正極耳
部、5:負極耳部、 6:鋳型、 7:溶湯、 8:ストラッ
プ、 9:窪み部。
1: Positive plate, 2: Separator, 3: Negative plate, 4: Positive ear, 5: Negative ear, 6: Mold, 7: Molten, 8: Strap, 9: Depressed part.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 黒田 敏裕 茨城県下館市大字下江連1250番地 日立化 成工業株式会社結城工場内 Fターム(参考) 5H022 AA01 BB01 BB03 BB14 BB17 BB30 CC19 EE10  ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Toshihiro Kuroda 1250 Shimoedori, Shimodate-shi, Ibaraki Pref.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】耳部を有する正極板と負極板とをセパレー
タを介して交互に積層して積層体を形成し、前記積層体
の正極耳部と負極耳部にフラックス塗着する手段と、固
体の鉛又は鉛合金を鋳型の窪み部に設置し、プレスした
後、誘導加熱によって鉛又は鉛合金製の溶湯を作製する
手段と、前記積層体を逆さにして、前記正極耳部及び負
極耳部を前記溶湯が満たされた鋳型の窪み部に挿入した
後、冷却・凝固させる手段とを有することを特徴とする
鉛蓄電池用極板群の溶接装置。
1. A means for alternately laminating a positive electrode plate having a lug and a negative electrode plate via a separator to form a laminate, and applying flux to the positive lug and the negative lug of the laminate. After placing solid lead or lead alloy in the recess of the mold and pressing it, a means for producing a molten metal made of lead or lead alloy by induction heating, and inverting the laminate to form the positive and negative electrode lugs And a means for cooling and solidifying after the part is inserted into the hollow part of the mold filled with the molten metal.
【請求項2】前記積層体の正極耳部と負極耳部に塗着す
るフラックスは、ペースト状フラックスを用いる物であ
ることを特徴とする請求項1記載の鉛蓄電池用極板群の
溶接装置。
2. A lead-acid battery electrode plate welding apparatus according to claim 1, wherein the flux applied to the positive and negative electrode lugs of the laminated body uses a paste-like flux. .
【請求項3】耳部を有する正極板と負極板とをセパレー
タを介して交互に積層して積層体を形成し、前記積層体
の正極耳部と負極耳部にフラックス塗着する手段と、固
体の鉛又は鉛合金を鋳型の窪み部に設置し、プレスした
後、誘導加熱によって鉛又は鉛合金製の溶湯を作製する
手段と、前記積層体を逆さにして、前記正極耳部及び負
極耳部を前記溶湯が満たされた鋳型の窪み部に挿入した
後、冷却・凝固させる手段とを有することを特徴とする
鉛蓄電池用極板群の溶接方法。
3. A means for forming a laminate by alternately laminating a positive electrode plate having a lug and a negative electrode plate with a separator interposed therebetween, and applying flux to the positive lug and the negative lug of the laminate. After placing solid lead or lead alloy in the recess of the mold and pressing it, a means for producing a molten metal made of lead or lead alloy by induction heating, and inverting the laminate to form the positive and negative electrode lugs And a means for cooling and solidifying after the part is inserted into the hollow part of the mold filled with the molten metal.
【請求項4】前記積層体の正極耳部と負極耳部に塗着す
るフラックスは、ペースト状フラックスを用いる物であ
ることを特徴とする請求項3記載の鉛蓄電池用極板群の
溶接方法。
4. The method for welding a lead-acid battery electrode group according to claim 3, wherein the flux applied to the positive and negative electrode lugs of the laminate uses a paste-like flux. .
JP11032100A 1999-02-10 1999-02-10 Apparatus and method for welding lead-acid battery electrode plate group Abandoned JP2000231916A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11032100A JP2000231916A (en) 1999-02-10 1999-02-10 Apparatus and method for welding lead-acid battery electrode plate group

Publications (1)

Publication Number Publication Date
JP2000231916A true JP2000231916A (en) 2000-08-22

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014109315A1 (en) * 2013-01-08 2014-07-17 新神戸電機株式会社 Method for manufacturing electrode plate group for lead-acid battery
KR101576745B1 (en) 2014-08-29 2015-12-11 주식회사 신화아이티 Manufacturing method and(of) electrode for battery
CN113161629A (en) * 2020-09-25 2021-07-23 蚌埠睿德新能源科技有限公司 Polar plate connecting method of lead-acid storage battery

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014109315A1 (en) * 2013-01-08 2014-07-17 新神戸電機株式会社 Method for manufacturing electrode plate group for lead-acid battery
JPWO2014109315A1 (en) * 2013-01-08 2017-01-19 日立化成株式会社 Manufacturing method of electrode plate group for lead acid battery
KR101576745B1 (en) 2014-08-29 2015-12-11 주식회사 신화아이티 Manufacturing method and(of) electrode for battery
CN113161629A (en) * 2020-09-25 2021-07-23 蚌埠睿德新能源科技有限公司 Polar plate connecting method of lead-acid storage battery

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