JP2000218356A - Rapid heating method of light metal injection molding die, and light metal injection molding method - Google Patents

Rapid heating method of light metal injection molding die, and light metal injection molding method

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Publication number
JP2000218356A
JP2000218356A JP11023987A JP2398799A JP2000218356A JP 2000218356 A JP2000218356 A JP 2000218356A JP 11023987 A JP11023987 A JP 11023987A JP 2398799 A JP2398799 A JP 2398799A JP 2000218356 A JP2000218356 A JP 2000218356A
Authority
JP
Japan
Prior art keywords
mold
temperature
cavity surface
injection molding
light metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11023987A
Other languages
Japanese (ja)
Other versions
JP3393079B2 (en
Inventor
Kengo Takeya
健吾 武谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Steel Works Ltd
Original Assignee
Japan Steel Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Steel Works Ltd filed Critical Japan Steel Works Ltd
Priority to JP02398799A priority Critical patent/JP3393079B2/en
Publication of JP2000218356A publication Critical patent/JP2000218356A/en
Application granted granted Critical
Publication of JP3393079B2 publication Critical patent/JP3393079B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a heating method of a light metal injection molding die, and a light metal injection molding method, for reducing occurrence ratio of molding failures due to the temperature of a molding die. SOLUTION: Just before a molten metal is injected, a coil 3 for induction heating is inserted between a fixed die 1 and a movable die 2 which are in a die opening condition, and a current is applied under a condition that the coil 3 is brought into close contact with cavity surfaces 4 of the fixed die 1 and the movable die 2. Thereby, an eddy current is generated in a die 5, so as to rise the temperature of the cavity surfaces 4 only to a given temperature in a short time.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、軽金属射出成形用
金型の急速加熱方法および該方法を用いた軽金属射出成
形方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for rapidly heating a light metal injection molding die and a method for light metal injection molding using the method.

【0002】[0002]

【従来の技術】マグネシウム合金あるいはアルミニウム
合金などの軽金属を射出成形する方法として、ダイカス
ト法、チクソモールディング法が挙げられる。両方法と
も、所定の溶融状態にまで加熱された溶湯を金型キャビ
ティ内に高速で充填して成形品を得るものである。溶湯
温度は合金の種類によっても異なるがおよそ600℃程
度であり、他方、金型のキャビティ表面は約150℃〜
250℃とされている。従って、溶湯と金型キャビティ
表面の温度差は極めて大きなものとなり、金型キャビテ
ィ内に流入した溶湯は数ms〜数十msという短時間の
内に凝固し流動を停止する。そして、溶湯がキャビティ
を充填完了する前に凝固、流動停止した場合には、充填
不良あるいはウエルドなどの成形欠陥が発生する。従っ
て、このような成形欠陥を抑制するためには、溶湯の凝
固時間を長くすること、すなわち溶湯と金型のキャビテ
ィ表面との温度差を小さくすることが重要であり、その
一つの方法として金型のキャビティ表面の温度を上げる
ことが有効である。
2. Description of the Related Art Injection molding of light metals such as magnesium alloys and aluminum alloys includes a die casting method and a thixomolding method. In both methods, a molten metal heated to a predetermined molten state is filled into a mold cavity at a high speed to obtain a molded product. The temperature of the molten metal varies depending on the type of alloy, but is about 600 ° C., while the cavity surface of the mold is about 150 ° C.
250 ° C. Therefore, the temperature difference between the molten metal and the surface of the mold cavity becomes extremely large, and the molten metal flowing into the mold cavity solidifies in a short time of several ms to several tens of ms and stops flowing. If the molten metal solidifies and stops flowing before the cavity is completely filled, molding defects such as poor filling or welding occur. Therefore, in order to suppress such molding defects, it is important to increase the solidification time of the molten metal, that is, to reduce the temperature difference between the molten metal and the cavity surface of the mold. It is effective to raise the temperature of the cavity surface of the mold.

【0003】金型のキャビティの加熱方法は、主に以下
の二つの方法が挙げられる。一つは、金型内部に電気ヒ
ータと温度測定用の熱電対を内蔵するものであり、熱電
対による温度測定結果と設定温度との差からPID制御
などによりヒータ操作量を決定して、任意の電圧あるい
は時間、ヒータに通電することによって金型を設定温度
とする。もう一つは、金型内部に流路を設置して、その
中を150℃〜300℃に加熱された熱媒体油を循環さ
せることによって金型を一定の温度に保持する。なお、
これらの金型加熱方法は、金型のキャビティのみならず
主型をも含む金型全体を一定の温度に保持している。
[0003] There are mainly two methods for heating the cavity of a mold. One is to incorporate an electric heater and a thermocouple for temperature measurement inside the mold, and determine the heater operation amount by PID control or the like from the difference between the temperature measurement result by the thermocouple and the set temperature, and By energizing the heater for the voltage or time, the mold is set to the set temperature. The other is to maintain the mold at a constant temperature by installing a flow path inside the mold and circulating a heating medium oil heated to 150 ° C. to 300 ° C. therein. In addition,
In these mold heating methods, not only the mold cavity but also the entire mold including the main mold is maintained at a constant temperature.

【0004】上述したように金型のキャビティ表面の温
度を上げることは、成形欠陥を抑制する上で有効な手段
である。凝固解析により、金型のキャビティ内での溶湯
の凝固時間を計算した結果を図3に示す。この図によれ
ば、金型のキャビティ表面の温度を350℃〜400℃
まで上げることによつて、溶湯の凝固時間は現状よりも
1.5〜3倍長くなる。従って、キャビティ表面の温度
を上げれば、凝固時間が長くなり、成形欠陥の発生率を
減少させることができる。さらに、凝固時間が長くなる
と、同一の成形品をより小さな射出率で成形することが
でき、より低い射出速度あるいは小型の成形機で成形す
ることができる。
[0004] As described above, increasing the temperature of the cavity surface of the mold is an effective means for suppressing molding defects. FIG. 3 shows the result of calculating the solidification time of the molten metal in the cavity of the mold by the solidification analysis. According to this figure, the temperature of the cavity surface of the mold is 350 ° C. to 400 ° C.
The solidification time of the molten metal becomes 1.5 to 3 times longer than the current state. Therefore, if the temperature of the cavity surface is increased, the solidification time is prolonged, and the incidence of molding defects can be reduced. Further, when the solidification time is longer, the same molded product can be molded with a smaller injection rate, and can be molded with a lower injection speed or a small molding machine.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、上述し
た加熱方法で金型温度を350℃〜400℃まで上げる
と、次のような弊害を生じる。 (a)金型の摺動部分のかじり、または焼付き(スライ
ドコア、エジェクタピンなど) (b)キャビティ表面の離型剤のはじき (c)突き出し時の成形品の変形 上記(a)は金型全体を高温度にすることによって生じ
るものであり、金型の温度むらに起因した摺動部品間の
熱膨張差により発生する。(b)は水溶性の離型剤をキ
ャビティ表面に塗布した時に、離型剤がキャビティ表面
に液膜を形成することなく瞬時に沸騰、蒸発してしま
い、離型剤を有効に塗布することができない現象であ
る。この結果、成形品はキャビティ表面から離型不能と
なり、変形などの欠陥が発生する。(b)はマグネシウ
ム合金あるいはアルミニウム合金などの軽金属が高温度
での強度に乏しいので、突き出し時に成形品が変形す
る。
However, when the mold temperature is increased from 350 ° C. to 400 ° C. by the above-described heating method, the following adverse effects occur. (A) Galling or seizure of the sliding part of the mold (slide core, ejector pin, etc.) (b) Repelling of the release agent on the cavity surface (c) Deformation of the molded product at the time of protruding This is caused by raising the temperature of the entire mold, and is caused by a difference in thermal expansion between sliding parts due to uneven temperature of the mold. (B) is that when a water-soluble release agent is applied to the cavity surface, the release agent boils and evaporates instantly without forming a liquid film on the cavity surface, and the release agent is effectively applied. Is a phenomenon that cannot be done. As a result, the molded product cannot be released from the cavity surface, and defects such as deformation occur. In (b), since a light metal such as a magnesium alloy or an aluminum alloy has a low strength at a high temperature, the molded product is deformed when protruding.

【0006】本発明は、上述した問題点を解決するため
になされたものであって、成形金型の金型温度による成
形品の欠陥の発生率を低くすることができる軽金属射出
成形金型の加熱方法および軽金属射出成形方法を提供す
ることを課題とする。
SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and an object of the present invention is to provide a light metal injection molding die capable of reducing the incidence of defects in a molded product due to the temperature of the molding die. It is an object to provide a heating method and a light metal injection molding method.

【0007】[0007]

【課題を解決するための手段】上記の問題点を克服する
ためには、金型全体の温度を従来の技術で述べたように
上げるのではなく、溶湯と直接接触する金型のキャビテ
ィ表面の温度のみを上げることが必要となる。すなわ
ち、溶湯の射出直前に金型のキャビティ表面を所定の温
度にまで上昇させ、射出充填後の冷却時間中に突き出し
可能な温度まで表面を冷却すれば、上記問題点を克服で
きる。具体的には、溶湯の射出直前に型開き状態にある
固定型と可動型の間に誘導加熱用のコイルを挿入して、
そのコイルを固定型と可動型のキャビティ表面に近接さ
せた状態で通電する。これによって、金型内に渦電流を
発生させ、キャビティ表面の温度を短時間で上昇させ
る。
In order to overcome the above-mentioned problems, the temperature of the whole cavity of the mold is brought into direct contact with the molten metal, instead of raising the temperature of the whole mold as described in the prior art. Only the temperature needs to be increased. That is, the above problem can be overcome by raising the cavity surface of the mold to a predetermined temperature immediately before injection of the molten metal and cooling the surface to a temperature at which the mold can protrude during the cooling time after injection filling. Specifically, a coil for induction heating is inserted between the fixed mold and the movable mold that are in the mold open state just before the injection of the molten metal,
The coil is energized in a state where it is brought close to the surfaces of the fixed and movable cavities. As a result, an eddy current is generated in the mold, and the temperature of the cavity surface is increased in a short time.

【0008】[0008]

【発明の実施の形態】本発明の実施の形態を実施例に基
づき図面を参照して説明する。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the present invention will be described based on embodiments with reference to the drawings.

【0009】図1に示すように、金型5のキャビティ表
面4の温度調節に用いられる装置は、金型5のキャビテ
ィ表面4を直接加熱するために使用する誘導加熱用電源
6、コイル3、このコイル3を移動させる図示しないエ
アシリンダ等と、金型5のキャビティ表面4を予熱、冷
却するために使用する熱媒体油温度調節器7、切換用電
磁弁8等から構成される。
As shown in FIG. 1, an apparatus used for controlling the temperature of the cavity surface 4 of the mold 5 includes an induction heating power source 6, a coil 3, and a power supply used for directly heating the cavity surface 4 of the mold 5. An air cylinder or the like (not shown) for moving the coil 3, a heat medium oil temperature controller 7 used for preheating and cooling the cavity surface 4 of the mold 5, a switching electromagnetic valve 8, and the like.

【0010】次に、軽金属射出成形用金型の急速加熱方
法および該方法を用いた軽金属射出成形方法について、
図1の(a)〜(d)に基づき、図2のフローチャート
を参照して説明する。 (a)熱媒体油の循環を開始し、金型5のキャビティ表
面4の温度が、200℃程度の時に、離型剤噴霧装置1
2からキャビティ表面4に向けて離型剤を噴霧する(ス
テップS1)。 (b)その後、溶湯の射出直前に、型開き状態にある固
定型1と可動型2の間に誘導加熱用のコイル3を挿入し
(ステップS2)、キャビティ表面4に近接する位置で
固定する。そして、このコイル3に誘導加熱用電源6か
ら適当な周波数の交流電流を通電し金型5内部に渦電流
を発生させて、キャビティ表面4から0〜5mm浸透し
た位置を直接加熱する(ステップS3)。この時、キャ
ビティ表面4から1mmの深さの位置に熱電対9を設置
しておき、その測定値が350℃〜400℃に上昇する
まで1〜30秒程度加熱する。加熱完了後速やかにコイ
ル3を金型5外ヘ移動させる(ステップS4,S5)。 (c)次いで、型閉じ、型締め、射出、保圧動作を行う
(ステップS6,S7)。保圧動作完了後の冷却工程中
に、金型5に内設された流路10に200℃程度の熱媒
体油を循環させてキャビテイ表面4および成形品11を
冷却する(ステップS8)。 (d)そして、前記した熱電対9による温度指示値が、
150℃〜250℃程度に低下したところで型を開き、
成形品11の突き出し動作を行い(ステップS9)、熱
媒体油の循環を停止して金型5の冷却を停止する(ステ
ップS10)。 以上の動作を繰り返して、キャビテイ表面4の温度を制
御しながら成形を行う。
Next, a rapid heating method for a light metal injection mold and a light metal injection molding method using the method will be described.
This will be described with reference to the flowchart of FIG. 2 based on (a) to (d) of FIG. (A) When the circulation of the heating medium oil is started and the temperature of the cavity surface 4 of the mold 5 is about 200 ° C., the release agent spraying device 1
A mold release agent is sprayed from 2 toward the cavity surface 4 (step S1). (B) Then, immediately before the injection of the molten metal, the coil 3 for induction heating is inserted between the fixed mold 1 and the movable mold 2 in the mold open state (step S2), and fixed at a position close to the cavity surface 4. . Then, an AC current having an appropriate frequency is applied to the coil 3 from the induction heating power supply 6 to generate an eddy current inside the mold 5 and directly heats a position which has penetrated 0 to 5 mm from the cavity surface 4 (step S3). ). At this time, a thermocouple 9 is placed at a depth of 1 mm from the cavity surface 4 and heating is performed for about 1 to 30 seconds until the measured value rises to 350 ° C to 400 ° C. Immediately after the completion of the heating, the coil 3 is moved out of the mold 5 (Steps S4 and S5). (C) Next, mold closing, mold closing, injection, and pressure holding operations are performed (steps S6 and S7). During the cooling step after completion of the pressure-holding operation, heat medium oil at about 200 ° C. is circulated through the flow path 10 provided in the mold 5 to cool the cavity surface 4 and the molded product 11 (Step S8). (D) Then, the temperature indication value by the thermocouple 9 is:
When the temperature drops to about 150 ° C to 250 ° C, open the mold,
The projecting operation of the molded article 11 is performed (step S9), and the circulation of the heat medium oil is stopped to stop the cooling of the mold 5 (step S10). By repeating the above operation, molding is performed while controlling the temperature of the cavity surface 4.

【0011】型締力450Tonの軽金属射出成形機に
て、マグネシウム合金のAZ91Dを使用してパソコン
ケースを従来の金型加熱方法(金型温度220℃)で成
形したところ、オーバフロー側に充填不良による成形欠
陥が多数発生し、この時の不良率は約50%であった。
そこで、本発明の方法で、射出直前の金型5のキャビテ
ィ表面4の温度を350℃にし成形したところ、充填不
良が改善されて、成形欠陥が減少し、不良率は5%に減
少した。
When a personal computer case was molded using a magnesium alloy AZ91D by a conventional mold heating method (mold temperature of 220 ° C.) using a light metal injection molding machine having a mold clamping force of 450 Ton, the overflow side caused a defective filling. Many molding defects occurred, and the defect rate at this time was about 50%.
Then, when the temperature of the cavity surface 4 of the mold 5 immediately before injection was adjusted to 350 ° C. by the method of the present invention, molding defects were improved, molding defects were reduced, and the defect rate was reduced to 5%.

【0012】上記実施例では、金型の予熱は、金型内に
熱媒体油を循環することによって行っているが、カート
リッジヒータを埋設することによって行ってもよい。ま
た、上記実施例では、金型の冷却は、上記熱媒体油によ
って行っているが、金型内に冷却水あるいは冷却ガスな
どを循環することによって行ってもよい。金型の予熱に
カートリッジヒータを使用する場合は、金型内に熱媒体
油又は冷却水若しくは冷却ガスなどを循環することによ
って行う。なお、金型内に冷却水あるいは冷却ガスなど
を循環する場合、別途、金型内に冷却回路を設ける必要
がある。すなわち、金型の予熱手段と冷却手段は、同一
の場合と別個の場合がある。
In the above embodiment, the preheating of the mold is performed by circulating the heat medium oil in the mold, but may be performed by burying a cartridge heater. Further, in the above embodiment, the mold is cooled by the heat medium oil, but may be cooled by circulating cooling water or cooling gas in the mold. When a cartridge heater is used for preheating the mold, it is performed by circulating heat medium oil, cooling water, cooling gas, or the like in the mold. When circulating cooling water or cooling gas in the mold, it is necessary to separately provide a cooling circuit in the mold. That is, the mold preheating means and the cooling means may be the same or separate.

【0013】[0013]

【発明の効果】本発明の方法は、上述したように構成さ
れているので、次のような効果を得ることができる。 (a)溶湯を射出する直前の金型のキャビティ表面の温
度が高いために、溶湯の凝固時間が長くなり、成形欠陥
の発生率を低くすることができる。 (b)金型全体の温度は、200℃程度に維持できるの
で各部は摺動可能であり、離型剤を噴霧する時のキャビ
ティ表面の温度も200℃程度であるから、離型剤のは
じきの問題も生じない。 (c)離型剤を有効に塗布できることに加え、金型に具
備された冷却回路により成形品の取り出し温度を低くで
きるため、成形品の突き出しによる変形などの問題も解
消する。 (d)金型温度を上げることによる弊害を防ぎながら、
金型のキャビティ表面のみを加熱することによって、成
形欠陥を大幅に低減できる。 (e)射出速度を低下させることができるので、バリが
低減し、後加工が容易となる。さらに、従来まで大型の
成形機を使用しなければ成形できなかった製品を小型の
成形機で成形できるようになり、コストが削減できる。
Since the method of the present invention is configured as described above, the following effects can be obtained. (A) Since the temperature of the cavity surface of the mold immediately before the injection of the molten metal is high, the solidification time of the molten metal is prolonged, and the incidence of molding defects can be reduced. (B) Since the temperature of the entire mold can be maintained at about 200 ° C., each part can be slid, and the temperature of the cavity surface when spraying the release agent is also about 200 ° C. No problem arises. (C) In addition to being able to effectively apply the release agent, the cooling circuit provided in the mold can lower the temperature at which the molded product is taken out, thereby eliminating problems such as deformation due to protrusion of the molded product. (D) While preventing the adverse effects of increasing the mold temperature,
By heating only the cavity surface of the mold, molding defects can be significantly reduced. (E) Since the injection speed can be reduced, burrs are reduced and post-processing is facilitated. Further, a product which could not be molded unless a large molding machine was used until now can be molded by a small molding machine, and costs can be reduced.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の方法を実施する装置の動作図である。FIG. 1 is an operation diagram of an apparatus for implementing a method of the present invention.

【図2】図1に示される装置の動作を説明するためのフ
ローチャートである。
FIG. 2 is a flowchart for explaining the operation of the device shown in FIG.

【図3】金型温度と成形品の凝固時間の関係を示す図で
ある。
FIG. 3 is a diagram showing a relationship between a mold temperature and a solidification time of a molded product.

【符号の説明】[Explanation of symbols]

1 固定型 2 可動型 3 コイル 4 キャビティ表面 5 金型 6 誘導加熱用電源 7 熱媒体油温度調節器 8 切換用電磁弁 9 熱電対 10 流路 11 成形品 12 離型剤噴霧装置 DESCRIPTION OF SYMBOLS 1 Fixed type 2 Movable type 3 Coil 4 Cavity surface 5 Die 6 Induction heating power supply 7 Heat medium oil temperature controller 8 Switching electromagnetic valve 9 Thermocouple 10 Channel 11 Molded product 12 Mold spray agent

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 溶湯の射出直前に型開き状態にある固定
型(1)と可動型(2)の間に誘導加熱用のコイル
(3)を挿入し、該コイル(3)を固定型(1)と可動
型(2)のキャビティ表面(4)に近接させた状態で通
電することによって、金型(5)内に渦電流を発生さ
せ、キャビティ表面(4)だけを短時間に所定の温度に
昇温することを特徴とする軽金属射出成形用金型の急速
加熱方法。
1. A coil (3) for induction heating is inserted between a fixed mold (1) and a movable mold (2) which are in a mold open state immediately before injection of molten metal, and the coil (3) is fixed ( An electric current is generated in the mold (5) by energizing in a state in which the cavity surface (4) of the movable die (1) and the movable die (2) are brought close to each other. A method for rapidly heating a light metal injection molding die, wherein the temperature is raised to a temperature.
【請求項2】 金型(5)内に設けた予熱手段でキャビ
ティ表面(4)を予熱し、キャビティ表面(4)に離型
剤を噴霧した後、溶湯の射出直前に型開き状態にある固
定型(1)と可動型(2)の間に誘導加熱用のコイル
(3)を挿入し、該コイル(3)を固定型(1)と可動
型(2)のキャビティ表面(4)に近接させた状態で通
電することによって、金型(5)内に渦電流を発生さ
せ、キャビティ表面(4)だけを短時間に所定の温度に
昇温した後、コイル(3)を金型外へ移動させて型閉じ
し、溶湯を射出、保圧後、金型(5)内に設けた冷却手
段でキャビティ表面(4)を所定温度まで冷却した後、
金型(5)を開いて成形品(11)を突き出すことを特
徴とする軽金属射出成形方法。
2. A cavity surface (4) is preheated by a preheating means provided in a mold (5), and after a mold release agent is sprayed on the cavity surface (4), the mold is in an open state immediately before injection of molten metal. A coil (3) for induction heating is inserted between the fixed mold (1) and the movable mold (2), and the coil (3) is placed on the cavity surface (4) of the fixed mold (1) and the movable mold (2). By energizing in the proximity state, an eddy current is generated in the mold (5), and only the cavity surface (4) is heated to a predetermined temperature in a short time, and then the coil (3) is removed from the mold. After the mold is closed, the molten metal is injected and the pressure is maintained, the cavity surface (4) is cooled to a predetermined temperature by cooling means provided in the mold (5).
A light metal injection molding method characterized in that a mold (5) is opened and a molded product (11) is protruded.
【請求項3】 前記キャビティ表面(4)の温度を、予
熱時より冷却時の方が低くなるように前記冷却手段で制
御することを特徴とする請求項2記載の軽金属射出成形
方法。
3. The light metal injection molding method according to claim 2, wherein the temperature of the cavity surface (4) is controlled by the cooling means so as to be lower during cooling than during preheating.
JP02398799A 1999-02-01 1999-02-01 Light metal injection molding method Expired - Lifetime JP3393079B2 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005051571A1 (en) * 2003-11-26 2005-06-09 Price, James, Cairns Casting of metal artefacts
JP2010284714A (en) * 2009-06-15 2010-12-24 Fuji Denki Thermosystems Kk Method and apparatus for heating mold
KR20180137007A (en) * 2016-04-26 2018-12-26 록툴 METHOD AND APPARATUS FOR DIE CASTING METAL ALLOY

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201119835A (en) 2009-12-10 2011-06-16 Quanta Comp Inc Pre-heat apparatus, injection molding with the same, and method of pre-heating injection molding

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005051571A1 (en) * 2003-11-26 2005-06-09 Price, James, Cairns Casting of metal artefacts
EA009004B1 (en) * 2003-11-26 2007-10-26 Мэри Томас Гиллс Рэффл Process and apparatus for casting of metal artefacts
JP2010284714A (en) * 2009-06-15 2010-12-24 Fuji Denki Thermosystems Kk Method and apparatus for heating mold
KR20180137007A (en) * 2016-04-26 2018-12-26 록툴 METHOD AND APPARATUS FOR DIE CASTING METAL ALLOY
KR102352445B1 (en) * 2016-04-26 2022-01-17 록툴 Die casting method and apparatus for metal alloy

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