JP2000217521A - Production of boiled rice capable of being preserved for long period and packed boiled rice - Google Patents
Production of boiled rice capable of being preserved for long period and packed boiled riceInfo
- Publication number
- JP2000217521A JP2000217521A JP11025904A JP2590499A JP2000217521A JP 2000217521 A JP2000217521 A JP 2000217521A JP 11025904 A JP11025904 A JP 11025904A JP 2590499 A JP2590499 A JP 2590499A JP 2000217521 A JP2000217521 A JP 2000217521A
- Authority
- JP
- Japan
- Prior art keywords
- rice
- adipic acid
- water
- cooked
- immersion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Cereal-Derived Products (AREA)
- Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、長期保存可能な米
飯の製造方法及び包装米飯に関し、詳しくは、喫食時の
香り及び食味が炊き立てのご飯と同等で、しかも、長期
保存可能な無菌状態の米飯を製造する方法及び該方法に
よって得られた米飯を包装した長期保存可能な包装米飯
に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing cooked rice that can be stored for a long period of time and a packaged cooked rice. The present invention relates to a method for producing cooked rice and a packaged cooked rice prepared by packaging the cooked rice obtained by the method.
【0002】[0002]
【従来の技術及び発明が解決しようとする課題】現在、
包装米飯と称する米飯商品類が市場に出回り、その販売
量は年々増加の一途を辿っている。この包装米飯の最大
の品質特性は、常温で長期間保存できることであるが、
その特性を達成するには、米穀中に存在する耐熱性芽胞
菌の殺菌又は静菌を行い、米飯を商業的無菌状態にする
必要がある。2. Description of the Related Art
Boiled rice products called wrapped boiled rice have appeared on the market, and the sales volume has been increasing year by year. The biggest quality characteristic of this packaged rice is that it can be stored at room temperature for a long time,
In order to achieve such properties, it is necessary to sterilize or sterilize the heat-resistant spores present in rice grains to make the cooked rice commercially sterile.
【0003】この耐熱性芽胞菌の殺菌方法として、レト
ルトパウチ内に米飯を充填した後、密閉して加熱殺菌す
る方法(特開昭56−72655号公報)、あるいは、
炊き水と浸漬米とを充填後にレトルト殺菌する方法(特
開昭62−51959号公報)等が開示されているが、
いずれも通常の炊飯行為とは異なる熱処理を行うため、
通常の炊飯米と比べて外観,香り,食味の何れも劣って
おり、炊き立てのご飯とは程遠い品質となっている。[0003] As a method for disinfecting the heat-resistant spore bacterium, a method of filling rice rice in a retort pouch and sealing and heat sterilizing it (Japanese Patent Application Laid-Open No. 56-72755), or
A method of retort sterilization after filling with cooking water and immersed rice (Japanese Patent Laid-Open No. 62-59959) and the like are disclosed.
In each case, heat treatment is different from normal rice cooking,
The appearance, aroma and taste are inferior to ordinary cooked rice, and the quality is far from freshly cooked rice.
【0004】一方、耐熱性菌の静菌方法としては、浸漬
水や炊き水に食用有機酸を添加して炊飯後の米飯のpH
を4.0〜4.8に調整することにより、炊飯時の加熱
で死滅できなかった耐熱芽胞菌の生育を抑止(静菌)す
る方法(特公平7−89879号公報)が開示されてい
る。On the other hand, as a bacteriostatic method for heat-resistant bacteria, an edible organic acid is added to immersion water or cooking water to adjust the pH of cooked rice after cooking.
(JP-B-7-89879) discloses a method of controlling (bacteriostatic) the growth of heat-resistant spores that could not be killed by heating during rice cooking by adjusting the pH to 4.0 to 4.8. .
【0005】また、レトルト殺菌とpH調整剤とを併用
する方法として、炊飯後の米飯のpHが5.0〜5.4
になるように炊き水にpH調整剤を添加し、耐熱性芽胞
菌の耐熱性をpH変動によって低下させることにより、
一般のレトルト殺菌(例えば120℃で20分)よりも
低い温度で商業的無菌状態を達成する方法が知られてい
る(特許第2692556号明細書)。しかしながら、
この方法においても、100℃以上で加熱することや、
炊き水にpH調整剤を添加することにより、食味・食感
を含む米飯の品質低下が生じていた。[0005] As a method of using retort sterilization and a pH adjuster in combination, the pH of cooked rice is adjusted to 5.0 to 5.4.
By adding a pH adjuster to the cooking water so that the heat resistance of the heat-resistant spore bacterium is reduced by pH fluctuation,
A method for achieving commercial sterility at a temperature lower than that of general retort sterilization (for example, at 120 ° C. for 20 minutes) is known (Japanese Patent No. 2692556). However,
Also in this method, heating at 100 ° C. or more,
By adding a pH adjuster to cooking water, the quality of cooked rice including taste and texture has been reduced.
【0006】さらに、通常の炊飯と同じ加熱処理を行っ
た場合でも、最終的な米飯のpHを4.8以下に抑える
ようなpH調整剤(静菌剤)の添加を行った米飯は、そ
のpH及びpH調整剤によりもたらされる酸味や酸臭を
有しているため、これも炊き立てのご飯の品質とは言い
難い。Further, even when the same heat treatment as that of ordinary rice cooking is performed, cooked rice to which a pH adjuster (bacteriostatic agent) has been added so as to suppress the final pH of cooked rice to 4.8 or less, Since it has a sourness and an acid odor caused by the pH and the pH adjuster, it is hard to say that this is the quality of freshly cooked rice.
【0007】そこで本発明は、常温で長期保存が可能で
あり、しかも、喫食時における食味や食感等が炊き立て
の米飯と同等の品質を得ることができる長期保存可能が
米飯の製造方法及び包装米飯を提供することを目的とし
ている。Therefore, the present invention relates to a method for producing cooked rice, which can be stored for a long time at room temperature, and can have the same quality as freshly cooked rice in terms of taste and texture during eating. The purpose is to provide packed rice.
【0008】[0008]
【課題を解決するための手段】上記目的を達成するた
め、本発明の長期保存可能な米飯の製造方法は、洗米し
た米をアジピン酸(HOOC(CH2)4COOH)を
含有する浸漬水、好ましくは、アジピン酸の濃度が0.
05〜1%であるアジピン酸含有浸漬水に浸漬した後、
該浸漬水を水切りした浸漬米を水洗し、該水洗した米を
容器に充填するとともに炊き水を加えて加熱処理するこ
とを特徴としている。In order to achieve the above object, the present invention provides a method for producing rice that can be stored for a long period of time, comprising the steps of: washing rice washed with immersion water containing adipic acid (HOOC (CH 2 ) 4 COOH); Preferably, the concentration of adipic acid is 0.1.
After immersion in an adipic acid-containing immersion water of 0.5 to 1%,
It is characterized in that the dipped rice from which the dipped water has been drained is washed with water, the washed rice is filled in a container, cooked water is added, and the rice is heated.
【0009】また、前記アジピン酸含有浸漬水のpH
を、ナトリウム,カリウム又はカルシウムのアジピン酸
塩及びアルカリの少なくとも一種により調整すること、
特に、前記アジピン酸塩を用いる場合は、そのpHを4
〜8に調整することを特徴としている。さらに、アジピ
ン酸含有浸漬水への米の浸漬時間は、少なくとも2分以
上で、通常の浸漬処理の時間までの範囲とすることが好
ましく、この浸漬の際に超音波処理を併用することも効
果的である。Further, the pH of the immersion water containing adipic acid is adjusted
Adjusting with at least one of sodium, potassium or calcium adipate and alkali;
In particular, when the adipate is used, its pH is adjusted to 4
It is characterized in that it is adjusted to 88. Further, the immersion time of rice in the adipic acid-containing immersion water is preferably at least 2 minutes or more and up to the time of normal immersion treatment, and it is also effective to use ultrasonic treatment together with this immersion. It is a target.
【0010】前記浸漬米の水洗は、5〜70℃の水を使
用して行うことが好ましく、この水洗の際にも、超音波
処理を併用することで効果的な水洗処理を行うことがで
きる。さらに、前記加熱処理は、通常行われている常圧
での炊飯処理で行うことが好ましく、必要に応じて具材
や調味料を加えることにより、調理米飯を製造すること
もできる。[0010] The water washing of the immersed rice is preferably carried out using water at 5 to 70 ° C, and in this water washing, an effective water washing treatment can be carried out by using ultrasonic treatment together. . Further, the heat treatment is preferably carried out in a usual rice cooking process under normal pressure, and cooked rice can be produced by adding ingredients and seasonings as necessary.
【0011】また、本発明の長期保存可能な包装米飯
は、上述の方法によって加熱処理した米飯を、ガスバリ
ア性フィルムで密封したものであって、特に、アジピン
酸含有量が0.07重量%以下であること、米飯のpH
が5〜8であることを特徴としている。[0011] The packaged cooked rice of the present invention which can be stored for a long time is a cooked rice cooked by the above-mentioned method, which is sealed with a gas barrier film. In particular, the content of adipic acid is 0.07% by weight or less. Is the pH of cooked rice
Is 5 to 8.
【0012】[0012]
【発明の実施の形態】図1は、本発明の長期保存可能な
米飯の製造方法を実施する標準的な工程を示すフローチ
ャートである。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS FIG. 1 is a flow chart showing standard steps for carrying out a method for producing cooked rice which can be stored for a long time according to the present invention.
【0013】まず、最初の洗米工程11は、通常の洗米
方法で行われるものであって、常法通り、水道水等の通
常の水を使用して通常の洗米処理を行えばよい。次の浸
漬工程12は、洗米工程11を終えた米をアジピン酸を
含む浸漬水(アジピン酸含有浸漬水)に浸漬する工程で
ある。この浸漬工程12で使用するアジピン酸含有浸漬
水におけるアジピン酸の濃度は、特に制限はないが、
0.05%未満ではアジピン酸を加えた効果、すなわ
ち、耐熱性芽胞菌の耐熱性を低下させる効果が十分に得
られないときがあり、1%を超えると、浸漬米からアジ
ピン酸を取り除くための水洗工程を長時間行わなければ
ならず、大量の水を消費することになるので、通常は、
0.05〜1%の範囲、好ましくは、0.1〜0.5%
の範囲が適当である。First, the first rice washing step 11 is carried out by a usual rice washing method, and a usual rice washing treatment may be carried out using ordinary water such as tap water as usual. The next immersion step 12 is a step of immersing the rice after the rice washing step 11 in immersion water containing adipic acid (adipic acid-containing immersion water). The concentration of adipic acid in the adipic acid-containing immersion water used in the immersion step 12 is not particularly limited,
If it is less than 0.05%, the effect of adding adipic acid, that is, the effect of lowering the heat resistance of heat-resistant spores may not be sufficiently obtained. Since the water washing process must be performed for a long time and consumes a large amount of water,
In the range of 0.05 to 1%, preferably 0.1 to 0.5%
Is appropriate.
【0014】また、浸漬工程12の時間は、アジピン酸
含有浸漬水におけるアジピン酸の濃度や処理温度にもよ
るが、2分未満では米へのアジピン酸の含浸が不十分と
なって耐熱性芽胞菌の耐熱性を低下させる効果が十分に
得られないときがあり、120分を超えると、米に必要
以上のアジピン酸が含浸してしまい、炊飯後の食味を低
下させることがあるので、通常は2〜120分の範囲、
好ましくは10〜90分の範囲が好適である。The duration of the immersion step 12 depends on the concentration of adipic acid in the adipic acid-containing immersion water and the treatment temperature, but if it is less than 2 minutes, the rice is insufficiently impregnated with adipic acid and heat-resistant spores are formed. The effect of reducing the heat resistance of the bacterium may not be sufficiently obtained, and if it exceeds 120 minutes, the rice may be impregnated with adipic acid more than necessary, which may lower the taste after cooking, so that it is usually used. Is in the range of 2 to 120 minutes,
Preferably, the range is 10 to 90 minutes.
【0015】さらに、アジピン酸含有浸漬水は、水道水
等の通常の水に適当量のアジピン酸を加えて溶解させた
ものであってもよいが、アジピン酸ナトリウム,アジピ
ン酸カリウム,アジピン酸カルシウムのようなアジピン
酸塩を使用あるいは併用してもよい。また、アジピン酸
と、これらのアジピン酸塩や水酸化ナトリウム,水酸化
カリウム,水酸化カルシウムのようなアルカリとを併用
することによってアジピン酸含有浸漬水のpHを適当な
範囲に調節することができる。Further, the immersion water containing adipic acid may be one obtained by adding an appropriate amount of adipic acid to ordinary water such as tap water and dissolving the same. However, sodium adipate, potassium adipate and calcium adipate may be used. May be used or used in combination. The pH of the adipic acid-containing immersion water can be adjusted to an appropriate range by using adipic acid in combination with these adipates and alkalis such as sodium hydroxide, potassium hydroxide and calcium hydroxide. .
【0016】アジピン酸含有浸漬水のpHは、アジピン
酸の濃度や処理温度等にもよるが、4〜8の範囲が適当
である。pHが低すぎたり、高すぎたりすると、耐熱性
低下効果が得られなくなったり、水洗工程の負担が増し
たり、炊飯後の米飯の食味が低下したりすることがあ
る。The pH of the immersion water containing adipic acid depends on the concentration of adipic acid and the treatment temperature, but is preferably in the range of 4 to 8. If the pH is too low or too high, the effect of lowering the heat resistance may not be obtained, the load of the washing step may increase, or the taste of cooked rice may decrease.
【0017】また、浸漬工程12における処理温度(水
温)は任意であり、温度が高い方が効果的ではあるが、
70℃を超えると米表層の澱粉の糊化が発生し、この糊
化がある程度以上進行すると水洗工程でアジピン酸を除
去するのが困難になる。一方、温度が低い場合、例えば
5℃未満になると、所定の効果を得るために長時間を要
するだけでなく、水に対するアジピン酸の溶解度が低い
ためにアジピン酸が析出するおそれもある。したがっ
て、処理温度は5〜70℃の範囲が適当であり、水を加
温したり冷却したりするエネルギーを考慮すると、通常
の水温に近い10〜30℃が最適である。The treatment temperature (water temperature) in the immersion step 12 is arbitrary, and a higher temperature is more effective.
If the temperature exceeds 70 ° C., gelatinization of the starch on the rice surface layer occurs. If the gelatinization proceeds to a certain extent, it becomes difficult to remove adipic acid in the washing step. On the other hand, when the temperature is low, for example, when the temperature is lower than 5 ° C., it takes not only a long time to obtain a predetermined effect, but also adipic acid may be precipitated due to low solubility of adipic acid in water. Therefore, the treatment temperature is suitably in the range of 5 to 70 ° C., and considering the energy for heating and cooling water, 10 to 30 ° C. which is close to the normal water temperature is optimal.
【0018】さらに、この浸漬工程12において超音波
処理を併用することにより、米の細部まで十分にアジピ
ン酸含有浸漬水を行き渡らせることができるので、耐熱
性芽胞菌の耐熱性を低下させる効果をより一層高めるこ
とができる。Furthermore, by using ultrasonic treatment in this immersion step 12, the adipic acid-containing immersion water can be sufficiently distributed to the details of rice, so that the effect of lowering the heat resistance of the heat-resistant spore bacterium can be obtained. It can be even higher.
【0019】上述のような浸漬工程12を終えた米(浸
漬米)は、水切り工程13を経て水洗工程14に入り、
浸漬米からアジピン酸含有浸漬水が取り除かれる。この
水洗工程14は、炊飯後の米飯にアジピン酸の影響が出
なくなる程度までにアジピン酸を除去するものであっ
て、水洗処理方法自体は、従来からの通常の方法で行う
ことができる。例えば、水道水等の通常の水に浸して適
宜撹拌したり、流水中に浸したり、シャワリングした
り、あるいは水中への浸漬と水切りとを交互に繰返した
りすることによって行うことができ、水中での超音波洗
浄も併用することができる。このときの温度も特に限定
はされるものではなく、温度を高くすればアジピン酸の
除去効率が向上するが、70℃を超えると前述のように
澱粉の糊化が発生してアジピン酸を十分に除去するのが
困難となり、一方、5℃未満では十分な水洗を行うのに
長時間を必要とするので、通常は5〜70℃、好ましく
は10〜30℃が適当である。After finishing the immersion step 12 as described above, the rice (immersed rice) enters a water washing step 14 through a draining step 13,
The immersion water containing adipic acid is removed from the immersed rice. The water washing step 14 is for removing adipic acid to such an extent that the effect of adipic acid does not appear on the cooked rice, and the water washing treatment itself can be performed by a conventional method. For example, immersion in ordinary water such as tap water and stirring as appropriate, immersion in running water, showering, or by alternately repeating immersion in water and draining, can be performed underwater Ultrasonic cleaning can also be used together. The temperature at this time is not particularly limited, and the higher the temperature, the higher the efficiency of adipic acid removal. However, when the temperature exceeds 70 ° C., gelatinization of starch occurs as described above, and However, if the temperature is lower than 5 ° C., it takes a long time to perform sufficient water washing, so that usually 5 to 70 ° C., preferably 10 to 30 ° C. is appropriate.
【0020】アジピン酸を除去するための水洗工程14
を終了した米(水洗米)は、充填工程15で所定量の炊
き水と共に適当な容器に充填された後、所定の加熱工程
16、即ち炊飯処理が行われる。この加熱工程16で使
用する容器は任意であるが、一食分を包装した包装米飯
を製造する場合は、所定の大きさの耐熱性プラスチック
トレイ(個食容器)を用いればよい。また、炊き水に
は、通常の水道水を使用することができ、炊き水と共に
適宜な具材や調味料を加えることにより、各種調理米飯
を得ることができる。Water washing step 14 for removing adipic acid
(Washed rice) is filled in a suitable container together with a predetermined amount of cooking water in a filling step 15, and then subjected to a predetermined heating step 16, that is, a rice cooking process. The container used in the heating step 16 is optional, but in the case of manufacturing a packaged rice packed with one serving, a heat-resistant plastic tray (individual serving container) having a predetermined size may be used. In addition, ordinary tap water can be used as the cooking water, and various cooked rice can be obtained by adding appropriate ingredients and seasonings together with the cooking water.
【0021】さらに、耐熱性プラスチックトレイの開口
を蒸気透過性及びバクテリアバリア性を有するフィルム
で覆っておくこともできる。また、加熱方法も任意であ
り、上述の個食容器を使用する場合は、通常、高温蒸気
を使用するが、釜等の金属製容器を使用して炊飯を行う
場合は、直火で加熱することもできる。Further, the opening of the heat-resistant plastic tray can be covered with a film having vapor permeability and bacterial barrier properties. In addition, the heating method is also optional. When the above-mentioned individual food container is used, high-temperature steam is usually used, but when rice is cooked using a metal container such as a kettle, heating is performed by direct heat. You can also.
【0022】加熱工程16で炊飯された米飯は、個食容
器のまま、あるいは適宜な容器に移し替えた後、密封工
程17においてガスバリア性フィルムで密封することに
より、製品として長期保存が可能な包装米飯が得られ
る。また、ガスバリア性フィルム内には、必要に応じて
脱酸素剤を封入してもよい。さらに、レトルトパウチの
ような包装形態を採用することもできる。The cooked rice cooked in the heating step 16 can be stored as an individual food container or transferred to an appropriate container, and then sealed in a sealing step 17 with a gas barrier film so that the product can be stored for a long period of time. Rice is obtained. Further, an oxygen scavenger may be enclosed in the gas barrier film as needed. Further, a packaging form such as a retort pouch can be adopted.
【0023】このようにして得られた包装米飯は、アジ
ピン酸含有浸漬水を使用した浸漬工程12におけるアジ
ピン酸の作用により、米穀中に存在する耐熱性芽胞菌の
耐熱性を低下させることができ、加熱工程16における
加熱で商業的無菌状態を達成することができるので、長
期保存が可能となり、電子レンジ等で加熱することによ
って喫食することができる。The packaged rice thus obtained can reduce the heat resistance of heat-resistant spores present in rice grains by the action of adipic acid in the immersion step 12 using immersion water containing adipic acid. Since a commercial sterile state can be achieved by heating in the heating step 16, long-term storage is possible, and the food can be eaten by heating in a microwave oven or the like.
【0024】このとき、上記包装米飯におけるアジピン
酸残存濃度は、0.07%以下になっていることが好ま
しく、特に、0.05%以下、さらに0.03%以下で
あることが好ましい。このアジピン酸残存濃度が0.0
7%以下であれば、通常の炊飯米との比較において、食
味の違いは識別可能ではあるが、実質的に同等であり、
0.05%以下であれば、通常の方法で炊飯した米飯と
識別できないほど、良好な食味である。At this time, the residual concentration of adipic acid in the wrapped rice is preferably 0.07% or less, particularly preferably 0.05% or less, and more preferably 0.03% or less. When the residual concentration of adipic acid is 0.0
If it is 7% or less, the difference in taste is identifiable in comparison with ordinary cooked rice, but it is substantially the same,
If it is 0.05% or less, the taste is so good that it cannot be distinguished from cooked rice in a usual manner.
【0025】また、炊飯後の米飯のpHは、5.0〜
8.0の範囲になるように設定すべきである。すなわ
ち、米飯のpHが5未満、あるいは8を超える場合は、
食味が低下して商品価値が損なわれることがある。さら
に、pHが5.2〜7.8の範囲内ならば、通常の炊飯
方法で炊飯した米飯と同等の食味が得られ、特に、pH
を5.5〜7.5の範囲にすることにより、通常の米飯
との識別が困難な良好な食味が得られる。The pH of the cooked rice is 5.0 to 5.0.
It should be set to be in the range of 8.0. That is, when the pH of cooked rice is less than 5 or more than 8,
Taste may be reduced and the commercial value may be impaired. Furthermore, if the pH is in the range of 5.2 to 7.8, the same taste as cooked rice cooked by a normal cooking method can be obtained.
Is in the range of 5.5 to 7.5, a good taste that is difficult to distinguish from ordinary cooked rice is obtained.
【0026】上述のようなアジピン酸残存濃度及びpH
範囲は、浸漬工程12や水洗工程14での処理条件を適
当に設定することにより、商業的無菌を達成できる程度
の耐熱性低下効果を失わずに容易に達成することができ
る。なお、米飯のpHは、米飯の9倍量の蒸留水を加え
て米飯を破砕し、その上澄みのpHを測定した値であ
る。Adipic acid residual concentration and pH as described above
The range can be easily attained by appropriately setting the treatment conditions in the immersion step 12 and the water washing step 14 without losing the heat resistance reducing effect to the extent that commercial sterility can be achieved. The pH of cooked rice is a value obtained by adding 9 times the amount of distilled water to cooked rice to crush the cooked rice and measuring the pH of the supernatant.
【0027】このようにして長期保存が可能な包装米飯
を製造することにより、製造ライン環境を無菌化するた
めのクリーンブースのような高価な設備を設ける必要が
なくなるので、設備コストの低減も図れる。By manufacturing packaged cooked rice that can be stored for a long period of time in this way, it is not necessary to provide expensive facilities such as a clean booth for sterilizing the production line environment, and thus it is possible to reduce equipment costs. .
【0028】[0028]
【実施例】実施例1 まず、アジピン酸含有浸漬水を使用して浸漬工程を行う
ことにより、耐熱性芽胞菌の耐熱性を低下させる効果を
検証した。あらかじめ加圧加熱殺菌した米の研ぎ汁に、
米穀から釣菌した極めて高い耐熱性を有する芽胞を懸濁
させて菌液とした。EXAMPLE 1 First, the effect of lowering the heat resistance of the heat-resistant spore bacterium was examined by performing the immersion step using immersion water containing adipic acid. To rice sharpening juice that has been pre-pressurized and heat sterilized,
Spores having extremely high heat resistance, picked from rice cereal, were suspended to obtain a bacterial solution.
【0029】そして、表1に示すように、アジピン酸処
理を行わなかったもの、すなわちアジピン酸を添加しな
い水(アジピン酸濃度0%)で浸漬処理を行ったもの
(実験番号1)をベースとし、実験番号11〜17、実
験番号21〜25及び実験番号31〜35の各種条件で
アジピン酸処理を施したものと比較した。なお、アジピ
ン酸処理は、菌液におけるアジピン酸の濃度が設定値に
なるように所定量のアジピン酸を加え、水酸化ナトリウ
ム水溶液でpHを7.0に調節して所定時間、所定温度
で放置することにより行い、続けて、この菌液6mlを
遠心分離(1回目)し、上澄みの5mlを捨て、新たな
殺菌済みの研ぎ汁を5ml加えて懸濁し、さらに2回目
の遠心分離を行い、上澄みの5mlを捨てて、新たな殺
菌済みの研ぎ汁5mlを加えて再懸濁させる水洗を模擬
した処理を行い、これを試料菌液とした。Then, as shown in Table 1, the base which was not subjected to the adipic acid treatment, that is, the one subjected to the immersion treatment in water (adipic acid concentration 0%) to which no adipic acid was added (Experiment No. 1) was used. , Experiment Nos. 11 to 17, Experiment Nos. 21 to 25 and Experiment Nos. 31 to 35 were compared with those treated with adipic acid under various conditions. The adipic acid treatment is performed by adding a predetermined amount of adipic acid so that the concentration of adipic acid in the bacterial solution becomes a set value, adjusting the pH to 7.0 with an aqueous sodium hydroxide solution, and leaving the mixture at a predetermined temperature for a predetermined time. Then, 6 ml of the bacterial solution was centrifuged (first time), 5 ml of the supernatant was discarded, 5 ml of fresh sterilized sharpening juice was added and suspended, and a second centrifugation was performed. 5 ml of the supernatant was discarded, and a treatment simulating washing with water in which 5 ml of freshly sterilized sharpening juice was added and resuspended was performed, and this was used as a sample bacterial solution.
【0030】各実験における比較は、アジピン酸処理を
行わなかった試料菌液及びアジピン酸処理を行った試料
菌液の一定量を100℃の温度に保ち、所定時間ごとの
残存菌数を測定し、得られたデータに基づいて生存曲線
を描き、D値(菌数を1/10にするのに必要な時間)
を求めることにより行った。その結果を表1に示す。な
お、この実験では、米の研ぎ汁を対象にしているが、実
際の米粒をアジピン酸含有浸漬水に浸漬し、その後に水
洗浄した場合にも、本実験で認められる芽胞の耐熱性低
下効果が得られることは明白である。なお、D値は、約
25(分)以下であれば実用的には十分である。In each experiment, a fixed amount of the sample bacterial solution without adipic acid treatment and a fixed amount of the sample bacterial solution with adipic acid treatment were maintained at a temperature of 100 ° C., and the number of remaining bacteria was measured at predetermined time intervals. Draw a survival curve based on the obtained data, and calculate the D value (the time required to reduce the number of bacteria to 1/10)
Was performed. Table 1 shows the results. In this experiment, rice sharpening juice was targeted, but the effect of reducing the heat resistance of spores observed in this experiment was also observed when actual rice grains were immersed in immersion water containing adipic acid and then washed with water. Is apparently obtained. The D value is practically sufficient if the value is about 25 (minutes) or less.
【0031】[0031]
【表1】 [Table 1]
【0032】実施例2 実施例1と同じ菌液を試料とし、表2に示す条件でアジ
ピン酸処理を行った後、実施例1と同じ方法で菌の生存
数を調べた。その結果を表2に示す。このことから、加
熱時のアジピン酸残存濃度を同一にした場合、すなわ
ち、炊飯後の米飯中に残留するアジピン酸の濃度を同一
にしようとした場合、比較的高濃度のアジピン酸含有浸
漬水で短時間処理したものの方が、低濃度で長時間処理
したものよりも、芽胞の耐熱性低下効果が大きいことと
がわかる。Example 2 The same bacterial solution as in Example 1 was used as a sample, treated with adipic acid under the conditions shown in Table 2, and the number of surviving bacteria was examined in the same manner as in Example 1. Table 2 shows the results. From this, when the concentration of residual adipic acid during heating is the same, that is, when it is attempted to make the concentration of adipic acid remaining in cooked rice the same, when immersion water containing adipic acid containing a relatively high concentration is used. It can be seen that those treated for a short time have a greater effect of lowering the heat resistance of the spores than those treated for a long time at a low concentration.
【0033】[0033]
【表2】 [Table 2]
【0034】実施例3 炊飯後の米飯中に残留するアジピン酸の濃度が米飯の品
質に与える影響を確認するため、常法により洗米した米
を表3に示す条件で炊飯した後、米飯中のアジピン酸濃
度の測定及び官能試験を行った。Example 3 In order to confirm the effect of the concentration of adipic acid remaining in cooked rice on the quality of cooked rice, rice washed by a conventional method was cooked under the conditions shown in Table 3 and then cooked. The measurement of adipic acid concentration and the sensory test were performed.
【0035】米飯中のアジピン酸濃度は、水洗を行うこ
とにより低下し、その量が0.07%以下になれば、十
分に良好な食味の米飯が得られることがわかった。It was found that the concentration of adipic acid in cooked rice was reduced by washing with water, and when the amount became 0.07% or less, cooked rice having a sufficiently good taste was obtained.
【0036】[0036]
【表3】 [Table 3]
【0037】実施例4 100kgのうるち米を常法により洗米・水切り(表面
付着の水を除去)を行った後、0.3%のアジピン酸水
溶液(熱水にアジピン酸を溶解させて高濃度のアジピン
酸水溶液を製作し、これを常温の水で希釈して0.3%
均一濃度の溶液としたもの。)30リットルに入れて1
時間浸漬した。浸漬水をザルを用いて水切りした後、水
を張った容器にザルごと浸漬米が水没するように漬込
み、上部から水を供給し、オーバーフローするような状
態で浸漬米を攪拌しつつ水洗いした。この際、必要に応
じて新水を張った容器に浸漬米を移し替え、水洗いを継
続した。Example 4 100 kg of glutinous rice was washed and drained (removing water adhering to the surface) by a conventional method, and then a 0.3% adipic acid aqueous solution (adipic acid was dissolved in hot water to obtain a high concentration Prepare an aqueous solution of adipic acid and dilute it with water at room temperature to 0.3%
A solution with a uniform concentration. ) 1 in 30 liters
Soaked for hours. After the immersion water was drained using a colander, the immersion rice was immersed in a container filled with water so that the immersion rice was submerged, water was supplied from above, and the immersion rice was washed with stirring while overflowing. At this time, the soaked rice was transferred to a container filled with fresh water as needed, and washing was continued with water.
【0038】米表面のアジピン酸を十分に洗い落として
水切りした浸漬米を、酸素バリア素材(EVOH)を含
むプラスチック成型容器に110g充填し、同時に、炊
き水として活性炭処理水を90ml充填した。次に、容
器上面を、一部に蒸気透過性フィルムを設けたフィルム
(一次フィルム)でシールした。その後、加熱装置(蒸
し機)に入れ、100℃で60分間炊飯した。炊飯終了
後、フィルム上面に残った蒸気の凝縮水を除去してか
ら、酸素バリア材(EVOH)を含むフィルム(二次フ
ィルム)でシールして包装米飯とした。110 g of immersed rice, which had been thoroughly washed out of adipic acid on the rice surface and drained, was charged into a plastic molded container containing an oxygen barrier material (EVOH), and at the same time, 90 ml of activated carbon treated water was charged as cooking water. Next, the upper surface of the container was sealed with a film (primary film) partially provided with a vapor-permeable film. Then, it put into the heating device (steamer) and cooked rice at 100 degreeC for 60 minutes. After the rice was cooked, the condensed water of the vapor remaining on the film upper surface was removed, and then sealed with a film (secondary film) containing an oxygen barrier material (EVOH) to obtain packed rice.
【0039】そして、一次フィルムと二次フィルムとの
間隙に脱酸素剤(商品名:エージレス)を封入した試料
1000食と、脱酸素剤を封入しない試料1000食と
をそれぞれ作成した。これらを、35℃の恒温室に2週
間保存した後、容器包装詰加圧加熱殺菌食品、いわゆる
レトルト食品の衛生試験法に準じて腐敗の状況を調べ
た。Then, a sample of 1000 meals in which an oxygen scavenger (trade name: Ageless) was sealed in the gap between the primary film and the secondary film, and a sample of 1,000 meals in which no oxygen scavenger was sealed were prepared. After storing these in a constant temperature room at 35 ° C. for 2 weeks, the state of spoilage was examined in accordance with the sanitary test method for pressurized and heat-sterilized foods in containers and packaging, so-called retort foods.
【0040】脱酸素剤を封入したものも、封入しなかっ
たものも、いずれも腐敗は一切認められなかった。した
がって、本実施例の包装米飯は、商業的無菌状態を達成
していたといえる。さらに、脱酸素剤を封入した方の米
飯は、酸味・酸臭をほとんど感じることがなく、炊き立
てご飯と同等の品質を有していた。また、この実施例に
おける米飯のpHは5.2であった。No decay was observed in either the case where the oxygen scavenger was sealed or the case where the oxygen scavenger was not sealed. Therefore, it can be said that the packed cooked rice of the present example achieved a commercial sterility state. Furthermore, the cooked rice in which the oxygen scavenger was sealed had almost no sourness or odor, and had the same quality as freshly cooked rice. The pH of cooked rice in this example was 5.2.
【0041】一方、対照実験区として、アジピン酸浸漬
処理は同様にして行ったが、その後の水洗工程を行わな
いで加熱処理した包装米飯を1000食作成し、同様に
35℃で2週間保存した。この対照実験区の米飯は、商
業的無菌状態は達成されたが、酸味・酸臭を有してお
り、品質的には、炊き立てのご飯に比べて劣っていた。
この場合の米飯のpHは4.5であった。On the other hand, as a control experimental group, adipic acid immersion treatment was performed in the same manner, but without the subsequent washing step, 1000 pieces of cooked cooked rice were prepared and similarly stored at 35 ° C. for 2 weeks. . The cooked rice in this control experimental plot achieved commercial sterility, but had sourness and odor, and was inferior in quality to freshly cooked rice.
In this case, the pH of the cooked rice was 4.5.
【0042】もう一つの対照実験区として、アジピン酸
浸漬を行わずに、水道水に浸漬しただけの米を用いて包
装米飯1000食を作成し、35℃で2週間保存した。
その結果、腐食が進んでいるものが2検体あり、商業的
無菌状態が達成されておらず、喫食には不適であった。In another control experiment group, 1,000 meals of packaged cooked rice were prepared using rice simply immersed in tap water without immersion in adipic acid, and stored at 35 ° C. for 2 weeks.
As a result, there were two specimens with advanced corrosion, commercial aseptic condition was not achieved, and it was not suitable for eating.
【0043】[0043]
【発明の効果】以上説明したように、本発明によれば、
米穀に付着している微生物の耐熱性を低下させることが
できるので、通常の炊飯条件、すなわち、100℃を超
す加熱を伴わない条件でも耐熱性芽胞菌を死滅させるこ
とができ、商業的無菌状態を達成できるとともに、米飯
の味や香りが炊き立てのご飯と同等の品質を有する包装
米飯を得ることができる。As described above, according to the present invention,
Since the heat resistance of microorganisms adhering to rice grains can be reduced, heat-resistant spores can be killed even under normal rice cooking conditions, that is, conditions without heating exceeding 100 ° C., and commercial sterile conditions can be achieved. And a packaged cooked rice having a taste and aroma of cooked rice having the same quality as freshly cooked rice can be obtained.
【図1】 本発明方法の一工程例を示すフローチャート
である。FIG. 1 is a flowchart showing one example of a process of the method of the present invention.
11…洗米工程、12…浸漬工程、13…水切り工程、
14…水洗工程、15…充填工程、16…加熱工程、1
7…密封工程11: rice washing process, 12: dipping process, 13: draining process,
14: washing step, 15: filling step, 16: heating step, 1
7 Sealing process
フロントページの続き (72)発明者 吉田 修 東京都港区西新橋1−16−7 日本酸素株 式会社内 Fターム(参考) 3E035 AA20 BA08 BC02 BD02 BD04 BD06 CA07 4B021 LA24 LP09 LW09 MQ05 4B023 LC08 LE11 LG01 LK04 LL01 LL05 LP03 LP05 LP10 LP18 LQ03 Continuation of the front page (72) Inventor Osamu Yoshida F-term within Nippon Sanso Co., Ltd. 1-16-7 Nishi-Shimbashi, Minato-ku, Tokyo 3E035 AA20 BA08 BC02 BD02 BD04 BD06 CA07 4B021 LA24 LP09 LW09 MQ05 4B023 LC08 LE11 LG01 LK04 LL01 LL05 LP03 LP05 LP10 LP18 LQ03
Claims (13)
漬した後、該浸漬水を水切りした浸漬米を水洗し、該水
洗した米を容器に充填するとともに炊き水を加えて加熱
処理することを特徴とする長期保存可能な米飯の製造方
法。After immersing the washed rice in immersion water containing adipic acid, the immersion water is drained, the immersed rice is washed with water, the washed rice is filled in a container, and cooked water is added to the rice for heat treatment. A method for producing cooked rice that can be stored for a long time.
の濃度が0.05〜1%であることを特徴とする請求項
1記載の長期保存可能な米飯の製造方法。2. The method according to claim 1, wherein the adipic acid-containing immersion water has a concentration of adipic acid of 0.05 to 1%.
トリウム,カリウム又はカルシウムのアジピン酸塩及び
アルカリの少なくとも一種により調整することを特徴と
する請求項1記載の長期保存可能な米飯の製造方法。3. The method for producing rice which can be stored for a long time according to claim 1, wherein the pH of the adipic acid-containing immersion water is adjusted by at least one of sodium, potassium or calcium adipic acid salt and alkali. .
リウム,カリウム又はカルシウムのアジピン酸塩を溶解
したものであり、そのpHが4〜8であることを特徴と
する請求項1記載の長期保存可能な米飯の製造方法。4. The long-term dipping water according to claim 1, wherein said adipic acid-containing immersion water is obtained by dissolving sodium, potassium or calcium adipic acid salt in water, and has a pH of 4 to 8. A method of producing storable cooked rice.
時間が2分以上でことを特徴とする請求項1記載の長期
保存可能な米飯の製造方法。5. The method according to claim 1, wherein the immersion time of the rice in the adipic acid-containing immersion water is 2 minutes or more.
る際に、超音波処理を併用することを特徴とする請求項
1記載の長期保存可能な米飯の製造方法。6. The method according to claim 1, wherein the rice is immersed in the adipic acid-containing immersion water together with ultrasonic treatment.
使用して行うことを特徴とする請求項1記載の長期保存
可能な米飯の製造方法。7. The method according to claim 1, wherein the washing of the soaked rice is carried out using water at a temperature of 5 to 70 ° C.
を併用することを特徴とする請求項1記載の長期保存可
能な米飯の製造方法。8. The method for producing cooked rice according to claim 1, wherein ultrasonic treatment is used when washing the soaked rice with water.
ることを特徴とする請求項1記載の長期保存可能な米飯
の製造方法。9. The method according to claim 1, wherein the heat treatment is a rice cooking process under normal pressure.
少なくともいずれか一方を加えることを特徴とする請求
項1記載の長期保存可能な米飯の製造方法。10. The method according to claim 1, wherein at least one of ingredients and seasonings is added together with the cooking water.
の製造方法によって加熱処理した米飯を、ガスバリア性
フィルムで密封したことを特徴とする包装米飯。11. A packaged cooked rice, wherein cooked rice cooked by the method according to any one of claims 1 to 10 is sealed with a gas barrier film.
7重量%以下であることを特徴とする請求項11記載の
包装米飯。12. The cooked rice having an adipic acid content of 0.0
The packaged rice according to claim 11, wherein the content is 7% by weight or less.
特徴とする請求項11記載の包装米飯。13. The packaged cooked rice according to claim 11, wherein the pH of the cooked rice is 5 to 8.
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