JP2000212868A - Nonwoven fabric, its formation, and cushion body and sheet for vehicle using the same nonwoven fabric - Google Patents

Nonwoven fabric, its formation, and cushion body and sheet for vehicle using the same nonwoven fabric

Info

Publication number
JP2000212868A
JP2000212868A JP642199A JP642199A JP2000212868A JP 2000212868 A JP2000212868 A JP 2000212868A JP 642199 A JP642199 A JP 642199A JP 642199 A JP642199 A JP 642199A JP 2000212868 A JP2000212868 A JP 2000212868A
Authority
JP
Japan
Prior art keywords
fiber
softening point
nonwoven fabric
heat treatment
forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP642199A
Other languages
Japanese (ja)
Inventor
Hiroaki Miura
宏明 三浦
Hitoshi Ito
仁 伊藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissan Motor Co Ltd
Original Assignee
Nissan Motor Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Motor Co Ltd filed Critical Nissan Motor Co Ltd
Priority to JP642199A priority Critical patent/JP2000212868A/en
Publication of JP2000212868A publication Critical patent/JP2000212868A/en
Withdrawn legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To obtain a nonwoven fabric capable of recycling, especially improved in fatigue resistance and provide a forming method of the nonwoven fabric and obtain a cushion material made of fibers and a sheet for vehicles using the nonwoven fabric enabling lightening of the raw materials. SOLUTION: This method for forming a nonwoven fabric comprises steps for carrying out thermoforming (heat treatment A) of a fiber polymer composed of a main fiber (fiber A), a binder fiber having high softening point (fiber B) and a binder fiber having low softening point (fiber C) at a temperature lower than the softening point of the fiber A and not lower than the softening point of the fiber B and thermoforming (heat treatment B) accompanied by compression at a temperature lower than the softening point of the fiber C having a softening point not higher than the softening point of the fiber B. The nonwoven fabric obtained by the above method is subjected to thermoforming (forming C) in the shape of finally formed cushion body at a temperature not lower than the softening point of the fiber C and lower by at least 30 deg.C than the softening point of the fiber B to provide the objective cushion body and sheet for vehicles.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、例えば自動車等の
車両用シートに適用され、リサイクルが可能で、特にヘ
タリが改善された追加成形可能な不織布及びその成形方
法、並びに該不織布を用いたクッション体及び車両用シ
ートに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is applicable to, for example, a vehicle seat such as an automobile, and is recyclable, and particularly has an improved settling, a nonwoven fabric which can be additionally molded, a method of molding the same, and a cushion using the nonwoven fabric. The present invention relates to a body and a vehicle seat.

【0002】[0002]

【従来の技術】従来より、車両用シートのクッション
材、寝具用マット材及び座布団等のクッション材にはポ
リウレタン(PU)フォームが使用されてきた。しかし
ながら、ポリウレタン材料は燃焼時に含窒素系のガスが
発生し、また、製造時にフロンガスが使用されるため、
環境保護の立場から問題点が指摘され始めている。
2. Description of the Related Art Conventionally, polyurethane (PU) foam has been used as a cushion material for vehicle seats, a mat material for bedding, and a cushion material such as a cushion. However, polyurethane materials generate nitrogen-containing gas during combustion, and because fluorocarbon gas is used during production,
Problems have begun to be pointed out from the standpoint of environmental protection.

【0003】そこで、ポリウレタンフォーム材料の代替
材料として、ポリエチレンテレフタレート(PET)を
用いたクッション材等が、特開昭57−35047号公
報に開示されている。このような低融点ポリエステル繊
維を接着成分としたポリエステル繊維を用いたクッショ
ン材は、過酷な条件で使用される車両用座席に用いた場
合、ヘタリが生じやすく、継続使用が困難であり、更
に、リサイクルを考慮した具体的な提案もない。
A cushioning material using polyethylene terephthalate (PET) is disclosed in Japanese Patent Application Laid-Open No. 57-35047 as an alternative material to the polyurethane foam material. A cushioning material using a polyester fiber having such a low-melting-point polyester fiber as an adhesive component, when used in a vehicle seat used under severe conditions, tends to cause settling, and is difficult to continuously use. There is no specific proposal considering recycling.

【0004】ヘタリが生じにくくする手段として、ポリ
エステル短繊維にウレタン系バインダーを用いたもの
(特開平4−84906号公報)や、ポリエステル短繊
維にポリアミド系バインダーを用いたもの(特開平4−
309398号公報)や、芳香族ポリアミド(アラミ
ド)繊維にポリフェニルサルファイド(PPS)繊維を
バインダーとして使用したもの(特開平2−26975
号公報)等が開示されているが、このようなウレタン系
バインダー、ポリアミド系バインダーやPPSを用いた
ものは、リサイクルすることができない。
As means for reducing the occurrence of settling, a method using a urethane-based binder for polyester short fibers (Japanese Patent Application Laid-Open No. 4-84906) and a method using a polyamide-based binder for polyester short fibers (Japanese Patent Application Laid-Open No. 4-84906).
No. 309398) and those using a polyphenylsulfide (PPS) fiber as a binder for an aromatic polyamide (aramid) fiber (JP-A-2-26975).
JP-A No. 2000-214, etc., but those using such a urethane-based binder, polyamide-based binder or PPS cannot be recycled.

【0005】一方、自動車等の車両においては、繊維ク
ッション材を用いると、ウレタンクッション材に比較し
て、低密度化が可能となるため、材料の軽量化を図るこ
とができ、自動車の燃費向上のための大きな課題の1つ
となっている。
On the other hand, in a vehicle such as an automobile, when a fiber cushion material is used, the density can be reduced as compared with the urethane cushion material, so that the material can be reduced in weight and the fuel efficiency of the automobile can be improved. Is one of the major issues for

【0006】[0006]

【発明が解決しようとする課題】本発明の目的は、上述
の従来技術の問題点を解決し、リサイクルが可能で、特
に、耐ヘタリ性を改善した不織布及びその成形方法、並
びに材料の軽量化を図ることも可能となる、該不織布を
用いた繊維製クッション材及び車両用シートを提供する
ことである。
SUMMARY OF THE INVENTION It is an object of the present invention to solve the above-mentioned problems of the prior art and to make it possible to recycle, in particular, to improve non-woven fabric with improved settling resistance, a method of molding the same, and to reduce the weight of the material. It is another object of the present invention to provide a fiber cushion material and a vehicle seat using the nonwoven fabric, which can also achieve the following.

【0007】[0007]

【課題を解決するための手段】本発明者らは、上記課題
を解決するため研究した結果、不織布の成形時に、最終
的に得られる不織布の厚さが圧縮厚さより厚くなるよう
な圧縮を伴う熱処理を行うことにより、ヘタリが改善さ
れた不織布が提供され、更に、不織布を構成する繊維中
のバインダー繊維を2種類混合することにより、ヘタリ
性が改善された不織布を再度成形できることを見出し、
本発明に到った。
Means for Solving the Problems The inventors of the present invention have studied to solve the above-mentioned problems, and as a result, when forming a nonwoven fabric, a compression is performed so that the thickness of the finally obtained nonwoven fabric is larger than the compression thickness. By performing the heat treatment, a nonwoven fabric with improved settling is provided.Furthermore, by mixing two types of binder fibers in the fibers constituting the nonwoven fabric, it has been found that a nonwoven fabric with improved settling can be formed again.
The present invention has been made.

【0008】請求項1記載の不織布の成形方法は、主体
繊維(繊維A)、高軟化点バインダー繊維(繊維B)及
び低軟化点バインダー繊維(繊維C)により構成される
繊維重合体を、繊維Aの軟化点未満かつ繊維Bの軟化点
以上の温度で熱成形(熱処理A)し、次いで繊維Bの軟
化点より低い軟化点である繊維Cの軟化点未満の温度で
圧縮を伴う熱成形(熱処理B)を行う工程を有すること
を特徴とする。
The method of forming a nonwoven fabric according to the first aspect of the present invention is characterized in that a fiber polymer composed of a main fiber (fiber A), a binder fiber having a high softening point (fiber B) and a binder fiber having a low softening point (fiber C) is used. Thermoforming (heat treatment A) at a temperature below the softening point of A and above the softening point of fiber B, followed by thermoforming with compression at a temperature below the softening point of fiber C, which is a softening point lower than the softening point of fiber B ( A step of performing a heat treatment B).

【0009】請求項2記載の不織布の成形方法は、請求
項1記載の不織布の成形方法において、繊維集合体はポ
リエステルを主成分とし、繊維Aを0〜90重量%と、
繊維Aより少なくとも20℃は軟化点の低い成分を全部
まはた一部含む繊維Bを5〜95重量%と、繊維Bより
少なくとも50℃は軟化点の低い成分を全部または一部
含む繊維Cを5〜95重量%とから構成されることを特
徴とする。
According to a second aspect of the present invention, there is provided a method of forming a non-woven fabric according to the first aspect, wherein the fiber aggregate has polyester as a main component and the fiber A has 0 to 90% by weight.
5 to 95% by weight of fiber B containing all or a part of a component having a low softening point at least 20 ° C. lower than fiber A, and fiber C containing all or a part of a component having a softening point lower than fiber B at least 50 ° C. From 5 to 95% by weight.

【0010】請求項3記載の不織布の成形方法は、請求
項2記載の不織布の成形方法において、繊維Aは繊度
0.5〜10000デニールで繊維長30〜100mm
であり、繊維Bは繊維径1〜10000デニールで繊維
長30〜100mmであり、繊維Cは繊維径1〜100
00デニールで繊維長30〜100mmであることを特
徴とする。
According to a third aspect of the present invention, there is provided a method of forming a nonwoven fabric according to the second aspect, wherein the fiber A has a fineness of 0.5 to 10,000 denier and a fiber length of 30 to 100 mm.
The fiber B has a fiber diameter of 1 to 10,000 denier and a fiber length of 30 to 100 mm, and the fiber C has a fiber diameter of 1 to 100
It is characterized by having a denier of 00 and a fiber length of 30 to 100 mm.

【0011】請求項4記載の不織布の成形方法は、請求
項1〜3いずれかの項記載の不織布の成形方法におい
て、得られる不織布が熱処理Bで圧縮された厚さの10
5%以上の厚さになることを特徴とする。
In a fourth aspect of the present invention, there is provided the method of forming a nonwoven fabric according to any one of the first to third aspects, wherein the obtained nonwoven fabric has a thickness of 10% which is compressed by the heat treatment B.
The thickness is 5% or more.

【0012】請求項5記載の不織布の成形方法は、請求
項1〜3いずれかの項記載の不織布の成形方法におい
て、得られる不織布が熱処理Bで圧縮された厚さの30
0%以上の厚さになることを特徴とする。
[0012] According to a fifth aspect of the present invention, there is provided the method of forming a nonwoven fabric according to any one of the first to third aspects, wherein the obtained nonwoven fabric has a thickness of 30% compressed by the heat treatment B.
It is characterized by having a thickness of 0% or more.

【0013】請求項6記載の不織布の成形方法は、請求
項1〜5いずれかの項記載の熱処理Aにおいて、繊維A
の軟化点の少なくとも20℃以下かつ繊維Bの軟化点以
上の温度で熱成形を行なうことを特徴とする。
According to a sixth aspect of the present invention, there is provided a method of forming a nonwoven fabric, comprising the steps of:
The thermoforming is carried out at a temperature of at least 20 ° C. of the softening point and at least the softening point of the fiber B.

【0014】請求項7記載の不織布の成形方法は、請求
項1〜6いずれかの項記載の熱処理Bにおいて、繊維C
の軟化点の少なくとも20℃以下の温度で圧縮を伴う熱
成形を行なうことを特徴とする。
According to a seventh aspect of the present invention, there is provided a method for forming a nonwoven fabric, comprising the steps of:
Thermoforming with compression at a temperature of at least 20 ° C. below the softening point.

【0015】請求項8記載の不織布の成形方法は、請求
項1〜7いずれかの項記載の熱処理Bにおいて、雰囲気
温度が30℃以上であることを特徴とする。
According to an eighth aspect of the present invention, there is provided a method for forming a nonwoven fabric, wherein the atmosphere temperature is 30 ° C. or more in the heat treatment B according to any one of the first to seventh aspects.

【0016】請求項9記載の不織布の成形方法は、請求
項1〜7いずれかの項記載の熱処理Bにおいて、雰囲気
温度が60℃以上であることを特徴とする。
The method for forming a nonwoven fabric according to the ninth aspect is characterized in that, in the heat treatment B according to any one of the first to seventh aspects, the ambient temperature is 60 ° C. or higher.

【0017】請求項10記載の不織布の成形方法は、請
求項1〜9いずれかの項記載の不織布の成形方法におい
て、熱処理時に、不織布に対して加湿若しくは蒸気を付
加し、又は加湿若しくは蒸気雰囲気中で熱処理すること
を特徴とする。
In a tenth aspect of the present invention, there is provided the method of forming a nonwoven fabric according to any one of the first to ninth aspects, wherein humidification or steam is added to the nonwoven fabric during the heat treatment, or a humidified or steam atmosphere is added. It is characterized in that heat treatment is performed in the inside.

【0018】請求項11記載の不織布は、請求項1〜1
0いずれかの項記載の成形方法により成形される。
The nonwoven fabric according to the eleventh aspect is the nonwoven fabric according to the first to eleventh aspects.
The molding is performed by the molding method described in any one of the above items.

【0019】請求項12記載のクッション体は、請求項
11記載の不織布を、繊維Cの軟化点以上かつ繊維Bの
軟化点より少なくとも30℃低い温度で最終成形クッシ
ョン体の形状に熱成形(成形C)することにより得られ
る。
A cushion body according to a twelfth aspect is obtained by thermoforming (molding) the nonwoven fabric according to the eleventh aspect at a temperature higher than the softening point of the fiber C and at least 30 ° C. lower than the softening point of the fiber B. C).

【0020】請求項13記載のクッション体は、請求項
11記載の不織布を、繊維Cの軟化点以上かつ繊維Bの
軟化点より少なくとも60℃低い温度で最終成形クッシ
ョン体の形状に熱成形(成形C)することにより得られ
る。
The cushion body according to the thirteenth aspect is obtained by thermoforming (molding) the nonwoven fabric according to the eleventh aspect at a temperature higher than the softening point of the fiber C and at least 60 ° C. lower than the softening point of the fiber B. C).

【0021】請求項14記載のクッション体は、請求項
12又は13記載のクッション体において、成形時にク
ッション体に対して加湿若しくは蒸気を付加し、又は加
湿若しくは蒸気雰囲気中で成形することを特徴とする。
According to a fourteenth aspect of the present invention, there is provided the cushion body according to the twelfth or thirteenth aspect, wherein humidification or steam is added to the cushion body during molding, or molding is performed in a humidified or steam atmosphere. I do.

【0022】請求項15記載の車両用シートは、請求項
12〜14いずれかの項記載のクッション体を一部また
は全部に用いて製造される。
A vehicle seat according to a fifteenth aspect is manufactured using the cushion body according to any one of the twelfth to fourteenth aspects in part or in whole.

【0023】本発明の不織布の成形方法に用いる繊維集
合体は、主体繊維(繊維A)、高融点バインダー繊維
(繊維B)及び低融点バインダー繊維(繊維C)により
構成される。このような構成とすることにより再度の形
成を可能とすることができる。具体的には、このような
繊維体とすることによって、開繊によるリサイクルを容
易とすることができるのである。
The fiber aggregate used in the method for forming a nonwoven fabric of the present invention is composed of a main fiber (fiber A), a high melting point binder fiber (fiber B) and a low melting point binder fiber (fiber C). With such a configuration, re-formation can be performed. Specifically, by using such a fibrous body, recycling by fiber opening can be facilitated.

【0024】不織布とする繊維集合体は、ポリエステル
を主成分とする必要がある。合成繊維中でもポリエステ
ルが適しているのは、最終成形品、例えばクッション材
の成形を熱成形で行うという点から熱可塑性の合成繊維
である必要があり、更に、流通量が多くかつ安価であ
り、機械的強度の点からも好適だからである。本発明で
使用することができるポリエステルとは、例えばポリエ
チレンテレフタレート(PET)、ポリブチレンテレフ
タレート(PBT)、ポリエチレンナフタレート(PE
N)、ポリブチレンナフタレート(PBN)、ポリエチ
レンイソフタレート(PEI)、ポリブチレンイソフタ
レート(PBI)、ポリεカプローラクトン(PCL)
等のほか、PETのエチレングリコール成分を他の異な
るグリコール成分で置換したもの(例えばポリヘキサメ
チレンフタサート(PHT))、またはテレフタル酸成
分を他の異なる2塩基酸成分で置換したもの(ポリヘキ
サメチレンイソフタレート(PHI)、ポリヘキサメチ
レンナフタレート(PHN))等がある。また、これら
ポリエステルを構成単位とした共重合ポリエステル、例
えばPBTとポリテトラメチレングリコール(PTM
G)とのブロック共重合体、PETとPEIとの共重合
体、PBTとPBIとの共重合体、PBTとPCLとの
共重合体等の、主たる繰返し単位がポリエステルからな
る共重合体も用いることができる。
It is necessary that the fiber aggregate to be a nonwoven fabric contains polyester as a main component. Among the synthetic fibers, polyester is suitable for the final molded product, for example, it is necessary to be a thermoplastic synthetic fiber in that the molding of the cushion material is performed by thermoforming, and furthermore, the circulation amount is large and inexpensive, This is because it is preferable from the viewpoint of mechanical strength. Examples of the polyester that can be used in the present invention include polyethylene terephthalate (PET), polybutylene terephthalate (PBT), and polyethylene naphthalate (PE).
N), polybutylene naphthalate (PBN), polyethylene isophthalate (PEI), polybutylene isophthalate (PBI), poly ε-caprolactone (PCL)
And the like, in which the ethylene glycol component of PET is replaced by another different glycol component (for example, polyhexamethylene phthalate (PHT)), or the terephthalic acid component is replaced by another different dibasic acid component (polyhexaethylene). Methylene isophthalate (PHI), polyhexamethylene naphthalate (PHN)) and the like. Further, copolymerized polyesters containing these polyesters as constituent units, for example, PBT and polytetramethylene glycol (PTM)
A copolymer having a main repeating unit made of polyester, such as a block copolymer with G), a copolymer of PET and PEI, a copolymer of PBT and PBI, and a copolymer of PBT and PCL are also used. be able to.

【0025】上記繊維集合体は、繊維Aを0〜90重量
%と、繊維Aより少なくとも20℃は軟化点の低い成分
を全部または一部含む繊維Bを5〜95重量%と、繊維
Bより少なくとも50℃は軟化点の低い成分を全部また
は一部含む繊維Cを5〜95重量%とから構成される。
The above fiber assembly contains 0 to 90% by weight of fiber A, 5 to 95% by weight of fiber B containing all or a part of a component having a lower softening point at least 20 ° C. than fiber A, and 5% to 95% by weight of fiber B. At least 50 ° C. comprises 5-95% by weight of fiber C containing all or a part of a component having a low softening point.

【0026】繊維Aはポリエステルを主成分とする繊維
で、上記したようなものが使用でき、繊維集合体中に0
〜90重量%の割合で配合される。繊維Aを90重量%
を超えて配合すると、最終成形品、例えばクッション体
の形状を維持することが困難となり、目的を達成できな
い。
The fiber A is a fiber containing polyester as a main component, and the above-mentioned fibers can be used.
It is blended at a ratio of about 90% by weight. 90% by weight of fiber A
If the amount exceeds the range, it becomes difficult to maintain the shape of the final molded product, for example, the cushion body, and the object cannot be achieved.

【0027】繊維Bは、前記繊維Aより少なくとも20
℃は軟化点の低い成分を全部または一部含む繊維で、繊
維集合体中に5〜95重量%の割合で配合される。繊維
Bを配合し、熱処理Bを行なうことにより、最終成形
品、例えばクッション体に耐ヘタリ性を付与できる。
Fiber B is at least 20 times greater than fiber A
C is a fiber containing all or a part of a component having a low softening point, and is blended in a fiber aggregate at a ratio of 5 to 95% by weight. By blending the fiber B and performing the heat treatment B, the final molded article, for example, the cushion body can be provided with set resistance.

【0028】繊維Bの繊維集合体中の含量が5重量%未
満では、ヘタリ改善の効果が充分に得られず、95重量
%を超えると、繊維Cの配合量が不充分になり、シート
形状に成形できない。また、繊維Aより少なくとも20
℃は軟化点を低い成分を全部または一部含むものである
が、繊維Aより少なくとも20℃は軟化点の低い成分と
は、例えば繊維AがPET,PEN等からなる場合、P
BT,PCL,PBI等やこれらからなる共重合体等が
ある。一部含むとは、繊維Bの断面形状が芯鞘型やサイ
ドバイサイド型等2種以上の成分又は分子量等の異なる
成分からなる樹脂の複合繊維等からなることを意味す
る。軟化点を少なくとも20℃低くするのは、これより
軟化点が高くなると繊維Aの軟化が始まる恐れがあるか
らである。
If the content of the fiber B in the fiber aggregate is less than 5% by weight, the effect of improving the settling cannot be sufficiently obtained, and if it exceeds 95% by weight, the compounding amount of the fiber C becomes insufficient and the sheet shape becomes insufficient. Cannot be molded. In addition, at least 20
C. contains all or a part of the component having a low softening point. The component having a softening point at least 20 ° C. lower than that of the fiber A is, for example, P when the fiber A is made of PET, PEN, or the like.
Examples include BT, PCL, PBI, and the like, and copolymers composed of these. The term “partially included” means that the cross-sectional shape of the fiber B is a composite fiber of a resin composed of two or more kinds of components such as a core-sheath type and a side-by-side type, or components having different molecular weights. The softening point is lowered by at least 20 ° C., because if the softening point is higher than this, the fiber A may start to soften.

【0029】また、同時に繊維Cは、繊維Bより少なく
とも50℃は軟化点の低い成分を全部または一部含む繊
維で、繊維集合体中に5〜95重量%の割合で配合され
る。この繊維Cは、耐ヘタリ性能を付与した不繊布を、
最終成形品、例えばクッション体に成形するために必要
である。繊維集合体中に低融点バインダーを含むこと
で、一度高温で成形して耐ヘタリ性能を付与した後に、
低温で再形成を行うことが可能となる。バインダー繊維
は、通常1種類を含有すれば繊維同士の接合が可能であ
るため最終成形品、例えばクッション体の形状に成形し
得るが、本発明では低融点バインダーを含むことによ
り、耐ヘタリ性不織布に対する再度の成形を、耐ヘタリ
性能を失うことなく行うことを可能とすることができ
る。
At the same time, the fiber C is a fiber containing all or a part of a component having a softening point lower than that of the fiber B by at least 50 ° C., and is blended in a fiber aggregate at a ratio of 5 to 95% by weight. This fiber C is a non-woven cloth having a set resistance performance,
It is necessary for molding into a final molded article, for example, a cushion body. By including a low melting point binder in the fiber assembly, after once molding at high temperature and imparting anti-settling performance,
Reforming can be performed at a low temperature. The binder fiber can be formed into a final molded product, for example, a cushion body because the fiber can be bonded to each other if it contains one type of binder fiber. Can be performed again without losing the anti-settling performance.

【0030】繊維Cの繊維集合体中の含量が5重量%未
満ではクッション体として成形が困難になり、95重量
%を超えると、バインダー繊維の配合量が大となるた
め、クッション自体が硬くなってしまう他、繊維Bの配
合量が減ってしまうため、十分な耐ヘタリ効果が得られ
ない。また、繊維Bより少なくとも50℃は軟化点を低
い成分を全部または一部含むものであるが、繊維Bより
少なくとも50℃は軟化点の低い成分とは、例えば繊維
BがPBTからなる場合、PET,PEIの共重合体、
PET,PCLの共重合体等がある。一部含むとは、繊
維Bと同様に繊維Cの断面形状が芯鞘型やサイドバイサ
イド型等2種以上の成分又は分子量の異なる成分からな
る樹脂の複合繊維からなることを意味する。軟化点を少
なくとも50℃低くするのは、熱処理Bにおいて、耐ヘ
タリ効果を付与する際に必要な軟化点の差である。これ
より軟化点が高くなると、耐ヘタリ効果が有効に発揮さ
れない。
If the content of the fiber C in the fiber assembly is less than 5% by weight, it becomes difficult to form the cushion as a cushion, and if it exceeds 95% by weight, the amount of the binder fiber increases and the cushion itself becomes hard. In addition, since the amount of the fiber B is reduced, a sufficient anti-settling effect cannot be obtained. Further, at least 50 ° C. lower than the fiber B contains all or a part of a component having a softening point lower than the fiber B. The component having a softening point lower than the fiber B by at least 50 ° C. is, for example, PET, PEI when the fiber B is made of PBT. A copolymer of
There are copolymers of PET and PCL. The term “partially included” means that the fiber C has a cross-sectional shape of a resin composite fiber composed of two or more components such as a core-sheath type or a side-by-side type or a component having a different molecular weight, like the fiber B. The reason for lowering the softening point by at least 50 ° C. is a difference in the softening point necessary for imparting the anti-settling effect in the heat treatment B. If the softening point is higher than this, the anti-settling effect is not effectively exhibited.

【0031】また、繊維集合体は、繊維Aが繊度0.5
〜10000デニールで繊維長30〜100mmであ
り、繊維Bが繊維径1〜10000デニールで繊維長3
0〜100mmであり、繊維Cが繊維径1〜10000
デニールで繊維長30〜100mmであって、最終成形
品の密度が0.01〜0.3g/cm3 になるように構
成される。
In the fiber assembly, the fiber A has a fineness of 0.5
The fiber B has a fiber length of 30 to 100 mm and a fiber diameter of 1 to 10,000 denier and a fiber length of 3 to 10,000 denier.
0 to 100 mm, and the fiber C has a fiber diameter of 1 to 10,000.
It is configured such that the denier is 30 to 100 mm in fiber length and the density of the final molded product is 0.01 to 0.3 g / cm 3 .

【0032】繊維Aの繊度は0.5デニール以上である
あることが好ましく、これはこれより細い繊維の製造は
困難であり、繊維の安定供給が難しく、更にコスト増加
を伴うため適当ではなく、また、他の繊維Bと混ざりに
くくなり、均一な繊維集合体を得るのが困難になる。一
方、繊維Aの繊度は10000デニール以下でなくては
ならず、これはこれより太い繊維は繊維接合点が著しく
減少し、十分な剛性を得るのに不適となり、また、本成
形による効果が得られにくくなる。
The fineness of the fiber A is preferably 0.5 denier or more, which is not suitable because it is difficult to produce finer fibers, it is difficult to supply fibers stably, and the cost is increased. Moreover, it becomes difficult to mix with other fibers B, and it becomes difficult to obtain a uniform fiber aggregate. On the other hand, the fineness of the fiber A must be 10000 denier or less, which means that the thicker fiber has a significantly reduced fiber joining point, becomes unsuitable for obtaining sufficient rigidity, and has the effect of the main molding. It becomes difficult to be.

【0033】その繊維長は30〜100mmの範囲であ
ることが、繊維集合体の機械的強度の点から必要であ
る。繊維長が30mm未満の繊維は不織布の製造に劣
り、100mmを超える繊維は繊維集合体中で均一に分
散させることが難しく、高品質での安定性を求めるには
十分な材料とはならない。
It is necessary that the fiber length is in the range of 30 to 100 mm from the viewpoint of the mechanical strength of the fiber assembly. Fibers having a fiber length of less than 30 mm are inferior to the production of nonwoven fabrics, and fibers having a fiber length of more than 100 mm are difficult to disperse uniformly in a fiber aggregate, and are not a sufficient material for seeking high-quality stability.

【0034】バインダー繊維(繊維B,C)には、繊度
1〜10000デニール、繊維長30〜100mmの繊
維を用いる。1デニール未満の繊度のバインダー繊維は
一般的でなくコストが高くなり、更に加熱成形時にバイ
ンダー繊維自体にヘタリが生じ、また繊維Aと混ざりに
くくなり、均一な繊維集合体を得るが困難になる。一
方、10000デニールを超えると、太い繊維を用いる
ことにより、相対的に繊維本数が減少するため繊維接合
点が著しく減少し、形状維持が困難になるからである。
As the binder fibers (fibers B and C), fibers having a fineness of 1 to 10,000 denier and a fiber length of 30 to 100 mm are used. Binder fibers having a fineness of less than 1 denier are uncommon and costly. Further, the binder fibers themselves are settled during heat molding, are hardly mixed with the fiber A, and it is difficult to obtain a uniform fiber aggregate. On the other hand, if it exceeds 10,000 denier, the number of fibers is relatively reduced due to the use of thick fibers, so that the number of fiber joints is significantly reduced, and it becomes difficult to maintain the shape.

【0035】バインダー繊維の繊維長は3〜100mm
の範囲であることが、繊維集合体の機械的強度の点から
必要である。繊維長が30mm未満の繊維は不織布の製
造に劣り、100mmを超える繊維は繊維集合体中で均
一に分散させることが難しく、高品質での安定性を求め
るには十分な材料とはならない。
The fiber length of the binder fiber is 3 to 100 mm
Is necessary in terms of the mechanical strength of the fiber assembly. Fibers having a fiber length of less than 30 mm are inferior to the production of nonwoven fabrics, and fibers having a fiber length of more than 100 mm are difficult to disperse uniformly in a fiber aggregate, and are not a sufficient material for seeking high-quality stability.

【0036】上記繊維集合体の熱成形は、まず、繊維A
の軟化点未満かつ繊維Bの軟化点以上の温度で熱成形
(熱処理A)し、さらに繊維Cの軟化点未満の温度で圧
縮を伴う熱成形(熱処理B)を行なう。これにより得ら
れる不織布が圧縮された厚さより大きいことが必要であ
る。熱処理Aでは、不織布に含まれる2種のバインダー
繊維を両方共融解させ、繊維同士を接着し不織布とす
る。熱処理Bは、得られる不織布の耐ヘタリ性を向上さ
せるために必要で、この操作により低ヘタリ性の不織布
を提供することが可能となる。
In the thermoforming of the fiber assembly, first, the fiber A
Thermoforming (heat treatment A) at a temperature lower than the softening point of the fiber B and higher than the softening point of the fiber B, and thermoforming with heat compression (heat treatment B) at a temperature lower than the softening point of the fiber C. It is necessary that the resulting nonwoven is larger than the compressed thickness. In heat treatment A, the two types of binder fibers contained in the nonwoven fabric are both melted, and the fibers are bonded to each other to form a nonwoven fabric. Heat treatment B is necessary to improve the set resistance of the obtained nonwoven fabric, and this operation makes it possible to provide a low set nonwoven fabric.

【0037】熱処理Aにおいては、好ましくは、繊維A
の軟化点の少なくとも20℃以下かつ繊維Bの軟化点以
上の温度で熱成形する。繊維Aの軟化点以上では繊維A
まで軟化してしまい、最終成形品、例えばクッション材
としての形状繊維が不可能になる。一方、繊維Bの軟化
点未満では繊維Cのみの融解しか起こらないため、接合
が不十分になるばかりでなく、後の熱処理B、成形Cに
おいて十分な耐ヘタリ効果が得られない。
In the heat treatment A, preferably, the fiber A
Thermoforming at a temperature of at least 20 ° C. or lower and a softening point of the fiber B or higher. Above the softening point of fiber A, fiber A
Until the final molded product, for example, a shaped fiber as a cushion material, becomes impossible. On the other hand, if the fiber B is less than the softening point, only the fiber C alone melts, so that not only the joining becomes insufficient, but also the heat treatment B and the forming C afterwards cannot obtain a sufficient anti-settling effect.

【0038】熱処理Bにおいては、好ましくは、繊維C
の軟化点の少なくとも20℃以下の温度で圧縮を伴う成
形を行なう。熱処理Bは圧縮を伴う成形で耐ヘタリ性を
付与するものである。ここで繊維Cの軟化点以上で圧縮
を行なうと圧縮された厚さに成形されてしまい、耐ヘタ
リ性能が向上されない。また、繊維Cの軟化点の20℃
以下で成形を行なうことが好ましいのは、それ以上の温
度では繊維Cの融解が始まってしまい、成形されてしま
うためである。さらにまた、熱処理Bを行なう雰囲気温
度は、30℃以上で行なわなければ耐ヘタリ効果を得ら
れにくい。望ましくは雰囲気温度60℃以上で熱処理B
を行うことで、処理時間の短縮も可能となる。
In the heat treatment B, preferably, the fibers C
Molding with compression is performed at a temperature of at least 20 ° C. below the softening point of The heat treatment B is for imparting settling resistance by molding with compression. Here, if compression is performed at a temperature higher than the softening point of the fiber C, the fiber C is formed into a compressed thickness, and the anti-settling performance is not improved. In addition, the softening point of the fiber C is 20 ° C.
The reason why the molding is preferably performed below is that at a higher temperature, the melting of the fiber C starts and the fiber C is molded. Furthermore, unless the ambient temperature at which the heat treatment B is performed is 30 ° C. or higher, it is difficult to obtain the anti-settling effect. Desirably heat treatment B at an ambient temperature of 60 ° C. or more
, The processing time can be reduced.

【0039】また、本発明の不織布の成形方法において
は、得られる不織布が、熱処理Bで圧縮された厚さの1
05%以上の厚さにならなくてはならない。105%未
満では耐ヘタリ性の改善効果が得られないため好ましく
ない。好ましくは熱処理Bで得られる不織布が、圧縮時
の300%以上となる成形を行なうことで、へタリ改善
の効果を増進できる。
Further, in the method for forming a nonwoven fabric of the present invention, the obtained nonwoven fabric has a thickness of 1% compressed by the heat treatment B.
Must be at least 05% thick. If it is less than 105%, the effect of improving the set resistance is not obtained, which is not preferable. Preferably, the nonwoven fabric obtained by the heat treatment B is shaped so as to be 300% or more at the time of compression, whereby the effect of improving settling can be enhanced.

【0040】好ましくは、上記熱成形は、不織布に対し
て加湿若しくは蒸気を付加し、又は加湿若しくは蒸気雰
囲気中で行なう。このようにすることにより、熱処理、
耐ヘタリ効果の付与を短時間で効率的に行なうことがで
きる。また処理時間が同じ場合には、耐ヘタリ効果がよ
り良好に得られ、圧縮永久歪み率がさらに改善される。
Preferably, the thermoforming is performed by humidifying or adding steam to the nonwoven fabric, or in a humidifying or steam atmosphere. By doing so, heat treatment,
The anti-settling effect can be efficiently provided in a short time. When the treatment time is the same, the anti-settling effect is more excellently obtained, and the compression set is further improved.

【0041】次いで、不織布を熱成形して最終成形品、
例えばクッション体を得るための成形(C)は、繊維C
の軟化点以上かつ繊維Bの軟化点より少なくとも30℃
低い温度で最終成形品の形状に成形されなければならな
い。繊維Cの軟化点以上でないと繊維Cが融解せず、最
終成形品、例えばクッション体に成形できない。また、
繊維Bの軟化点より少なくとも30℃は低い温度でない
と、繊維Bの軟化が始まるばかりでなく、耐ヘタリ効果
が失われる。好ましくは繊維Bの軟化点の少なくとも6
0℃は低い温度で成形Cを行なうことで、耐ヘタリ効果
を維持したまま成形を行なうことができる。
Next, the non-woven fabric is thermoformed to obtain a final molded product.
For example, molding (C) for obtaining a cushion body is performed using fibers C
Above the softening point and at least 30 ° C. below the softening point of the fiber B
It must be formed into the shape of the final molded article at low temperatures. If the softening point is not higher than the softening point of the fiber C, the fiber C does not melt and cannot be formed into a final molded product, for example, a cushion body. Also,
Unless the temperature is at least 30 ° C. lower than the softening point of the fiber B, not only the softening of the fiber B starts but also the anti-settling effect is lost. Preferably at least 6 of the softening point of fiber B
By performing the forming C at a low temperature of 0 ° C., the forming can be performed while maintaining the anti-settling effect.

【0042】得られる最終成形品の見かけ密度は、0.
01〜0.3g/cm3 である。この範囲とすることに
より、クッション体としての繊維の凝集性と硬さを成り
立たせることができる。見かけ密度の測定は、クッショ
ン体の重量を測定し、見かけ体積を定規により測定して
算出した。
The apparent density of the final molded article obtained is 0.
01 to 0.3 g / cm 3 . By setting it in this range, the cohesiveness and hardness of the fiber as the cushion body can be satisfied. The apparent density was calculated by measuring the weight of the cushion body and measuring the apparent volume with a ruler.

【0043】また、クッション体を車両用シートとして
用いる場合は、表皮材としてポリエステル製のものを用
いれば、クッションを含めて100%ポリエステル製と
なるので、リサイクル上も有利である。
When the cushion body is used as a vehicle seat, if the skin material is made of polyester, it is made of 100% polyester including the cushion, which is advantageous in recycling.

【0044】また、上記成形Cにおいては、クッション
材に対して加湿若しくは蒸気を付加し、又は加湿若しく
は蒸気雰囲気中で成形することで、さらに耐ヘタリ性能
を改善することができる。
In the above-mentioned molding C, humidification or steam is added to the cushion material, or molding is performed in a humidified or steam atmosphere, whereby the anti-settling performance can be further improved.

【0045】このように、本発明の不織布を用いたクッ
ション材及びクッション材の車両用部品は、耐ヘタリ性
能を向上させることができ、また、自動車等の車両に用
いられる場合の乗り心地も改善され、さらに、製品のリ
サイクル性の点からも繊維集合体を用いることで容易な
リサイクルが可能となる。
As described above, the cushion material using the nonwoven fabric of the present invention and the vehicular component of the cushion material can improve the settling resistance and also improve the ride comfort when used in vehicles such as automobiles. Further, from the viewpoint of the recyclability of the product, the use of the fiber aggregate enables easy recycling.

【0046】[0046]

【発明の実施の形態】次に、本発明の好適例を図面に基
いて説明する。図1、 2は成形室の略体断面図で、図1
は本発明の熱成形方法、図2は従来の熱成形方法をそれ
ぞれ示すものである。図1に示すように、本発明におけ
る成形では、熱処理A室10及び熱処理B室11の2室
を備え、熱処理B室に圧縮用コンベア16を備えてい
る。熱処理A室及び熱処理B室は、ともに、それぞれ送
気管18及び排気管19を備える。各成形室内の移送用
コンベア12の移送部は、金網13と多数の孔14とか
らなり、送気管18から成形室に圧送された空気が成形
室上部から下部へと流れるようになっている。熱処理B
室11の圧縮用コンベア16も移送用コンベアと同様
に、移送部が金網13と多数の孔14からなっている。
Next, a preferred embodiment of the present invention will be described with reference to the drawings. 1 and 2 are schematic sectional views of the molding chamber.
2 shows a thermoforming method of the present invention, and FIG. 2 shows a conventional thermoforming method. As shown in FIG. 1, in the forming in the present invention, two chambers of a heat treatment chamber A 10 and a heat treatment chamber B 11 are provided, and a compression conveyor 16 is provided in the heat treatment chamber B. Both the heat treatment chamber A and the heat treatment chamber B have an air supply pipe 18 and an exhaust pipe 19, respectively. The transfer section of the transfer conveyor 12 in each molding chamber includes a wire mesh 13 and a large number of holes 14, so that the air fed from the air supply pipe 18 to the molding chamber flows from the upper part of the molding chamber to the lower part. Heat treatment B
The transfer section of the compression conveyor 16 of the chamber 11 also includes a wire net 13 and a large number of holes 14 similarly to the transfer conveyor.

【0047】図2は従来の熱成形方法の熱成形室で、成
形室は1室であり、移送用コンベア12と成形用ローラ
ー15とを有する。
FIG. 2 shows a thermoforming chamber according to a conventional thermoforming method. The thermoforming chamber has one chamber, and has a transfer conveyor 12 and a forming roller 15.

【0048】次に図1を参照しながら、本発明の不織布
を成形する方法について説明する。熱処理A室に移送用
コンベア14で繊維集合体1を移送し、送気管18よ
り、繊維B及びCの軟化点以上の熱風、好ましくは更に
蒸気、例えば230℃の熱風を吹き込み、該熱風は熱処
理A室上部より繊維集合体を通過し、移送用コンベアの
金網13の孔14を通過して、熱処理A室下部から排気
管19を介して室外へと排出される。成形用ローラー1
5により予備成形が行われ、熱処理Aを通過した不織布
2が得られる。
Next, a method for forming the nonwoven fabric of the present invention will be described with reference to FIG. The fiber assembly 1 is transferred to the heat treatment room A by the transfer conveyor 14, and hot air having a temperature equal to or higher than the softening point of the fibers B and C, preferably steam, for example, hot air of 230 ° C. is blown from the air supply pipe 18; It passes through the fiber assembly from the upper part of the room A, passes through the holes 14 of the wire mesh 13 of the transfer conveyor, and is discharged from the lower part of the heat treatment room A to the outside through the exhaust pipe 19. Forming roller 1
5, the non-woven fabric 2 having passed through the heat treatment A is obtained.

【0049】次いでこの不織布は、熱処理B室11へと
移送され、繊維Cの軟化点以下の熱風、好ましくは更に
蒸気、例えば70℃の熱風、蒸気を吹き込み、これによ
り加熱された不織布2が、圧縮成形用ローラー16によ
り圧縮され、自らの反発力により圧縮された厚さより大
きな厚さヘと回復して不織布3が得られる。圧縮後の回
復量のコントロールは、熱処理A終了後の不織布の厚
み、熱処理B室の温度、熱処理Bでの圧縮厚さ及び熱処
理Bの処理時間等で調節できる。
Next, the nonwoven fabric is transferred to the heat treatment B chamber 11 and blows hot air having a softening point of the fiber C or lower, preferably steam, for example, hot air or steam at 70 ° C., thereby heating the nonwoven fabric 2. The nonwoven fabric 3 is obtained by being compressed by the compression molding roller 16 and recovering to a thickness larger than the thickness compressed by its own repulsive force. The amount of recovery after compression can be controlled by adjusting the thickness of the nonwoven fabric after heat treatment A, the temperature of the heat treatment B chamber, the compression thickness in heat treatment B, the treatment time of heat treatment B, and the like.

【0050】このようにして熱処理B後に得られた不織
布3を用いて、最終成形品、例えばクッション体を成形
する方法を図3〜5を用いて説明する。図3〜5は、成
形型の略体断面図で、図3は型開き成形前状態、図4は
型閉じ成形中状態、また、図5は型開き成形後状態をそ
れぞれ示すものである。図3〜5に示すように、本発明
に用いる成形型は、型閉じにより最終成形品容積になっ
ているキヤビティーを形成する成形面31と41を各々
有する上型30と下型40とを備えている。なお、上型
30は下型40に対し、図示しない支軸を介して移動可
能(図3中、矢印参照)に取り付けられており、その移
動によって型閉じ及び型開きすることができる。
A method of forming a final molded product, for example, a cushion body, using the nonwoven fabric 3 obtained after the heat treatment B will be described with reference to FIGS. 3 to 5 are schematic cross-sectional views of the mold. FIG. 3 shows a state before the mold is opened, FIG. 4 shows a state during the mold closing, and FIG. 5 shows a state after the mold is opened. As shown in FIGS. 3 to 5, the molding die used in the present invention includes an upper die 30 and a lower die 40 each having molding surfaces 31 and 41 for forming cavities having a final molded product volume by closing the die. ing. The upper mold 30 is attached to the lower mold 40 via a support shaft (not shown) so as to be movable (see the arrow in FIG. 3), and the mold can be closed and opened by the movement.

【0051】上型30は、下面開口の箱型形状をなす上
型本体32と、その本体下面を覆いかつ成形面31を形
成する上部加圧部材33とからなる。上部加圧部材33
は多数の孔34を有するパンチングメタルによって形成
されている。上型本体32と上型加圧部材33とにより
形成される上型30内のチヤンバー35には、送気管3
6が連結されている。下型40は、上面開口の箱型形状
をなす下型本体42とその本体上面を覆いかつ成形面4
1を形成する下部加圧部材43とからなる。下部加圧部
材43は前記上部加圧部材43と同様に、多数の孔44
を有するパンチングメタルによって形成されている。下
型本体42と下型加圧部材43とによって形成される下
型40内のチヤンバー45には、排気管46が連結され
ている。
The upper die 30 comprises an upper die body 32 having a box shape with a lower surface opening, and an upper pressing member 33 which covers the lower surface of the main body and forms a molding surface 31. Upper pressing member 33
Is formed of a punching metal having many holes 34. The chamber 35 in the upper die 30 formed by the upper die main body 32 and the upper die pressing member 33 has an air supply pipe 3
6 are connected. The lower mold 40 has a box-shaped lower mold body 42 having an upper surface opening, and a molding surface 4 that covers the upper surface of the body.
1 and a lower pressurizing member 43 forming the first pressurizing member 43. The lower pressing member 43 has a large number of holes 44 similarly to the upper pressing member 43.
It is formed of a punching metal having An exhaust pipe 46 is connected to a chamber 45 in the lower die 40 formed by the lower die body 42 and the lower die pressing member 43.

【0052】次に、上記成形型を用いてクッション体を
成形する場合について説明する。図3に示されるように
型開きした成形型の下型40の成形面41に、複数の不
織布3を積層状に、例えば不織布の厚みが50mmの
時、最終成形品の一般部になる部分に4枚、端部になる
部分に6枚配置する。
Next, a case where a cushion body is formed by using the above-mentioned mold will be described. As shown in FIG. 3, a plurality of nonwoven fabrics 3 are laminated on the molding surface 41 of the lower mold 40 that is opened as shown in FIG. 3. For example, when the thickness of the nonwoven fabric is 50 mm, Four sheets and six sheets are arranged at the end portions.

【0053】次に、図4に示されるように下型40に上
型30を型閉じする。そして、上型30の送気管36か
ら、例えば165℃の熱風及び好ましくは蒸気をチヤン
バー35に圧送する。上型30の上部チヤンバー35に
導入された熱風は、上型加圧部材33の孔34からキヤ
ビティーに噴出して、最終成形品の厚みに圧縮された不
織布4を加熱する。
Next, as shown in FIG. 4, the upper mold 30 is closed with the lower mold 40. Then, for example, hot air at 165 ° C. and preferably steam are pressure-fed to the chamber 35 from the air supply pipe 36 of the upper die 30. The hot air introduced into the upper chamber 35 of the upper mold 30 blows out from the hole 34 of the upper mold pressing member 33 into the cavity, and heats the nonwoven fabric 4 compressed to the thickness of the final molded product.

【0054】前記不織布4を通過した熱風は、下型40
の下部加圧部材43の孔44から下部チヤンバー45に
入り、排気管46を通じて外部に排出される。これによ
り、上型30と下型40の両チヤンバー35及び45は
熱気室となり、不織布4を加熱する。加熱は、所定時
間、例えば成形型内温度120〜130℃で15分間の
加熱圧縮を行なう。この加熱圧縮により、不繊布3が、
クッション体5の形状に成形される。
The hot air that has passed through the nonwoven fabric 4
The lower chamber 45 enters the lower chamber 45 through the hole 44 of the lower pressure member 43 and is discharged to the outside through the exhaust pipe 46. Thus, the chambers 35 and 45 of the upper mold 30 and the lower mold 40 become hot air chambers, and heat the nonwoven fabric 4. The heating is performed by heating and compressing for a predetermined time, for example, 15 minutes at a temperature in the mold of 120 to 130 ° C. By this heating and compression, the nonwoven fabric 3
It is formed into the shape of the cushion body 5.

【0055】次に、図5では成形終了後、型開きを行な
い、クッション材2が最終成形型のクッション体5に成
形されていることを示している。
Next, FIG. 5 shows that after the molding is completed, the mold is opened, and the cushion material 2 is molded into the cushion body 5 of the final molding die.

【0056】図6では、本成形により得られたクッショ
ン体5を用いて、自動車用シートクッション6を作製し
た例を示す。
FIG. 6 shows an example in which an automobile seat cushion 6 is manufactured using the cushion body 5 obtained by the main molding.

【0057】本発明は上記実施の形態及び下記実施例に
限定されるものではなく、本発明の要旨を逸脱しない範
囲における変更が可能である。例えば前記実施の形態
は、熱処理Bにおいて不織布の厚み方向に対して、厚み
50%になるように加熱圧縮を行なったが、圧縮がかか
る方向ならば、幅方向に対して成形を行なうことも可能
であり、また、これらの組合せによる成形も可能であ
る。
The present invention is not limited to the above-described embodiment and the following examples, but can be modified without departing from the gist of the present invention. For example, in the above-described embodiment, the heat compression is performed so that the thickness becomes 50% with respect to the thickness direction of the nonwoven fabric in the heat treatment B. However, if the compression direction is applied, the molding can be performed in the width direction. Further, molding by a combination of these is also possible.

【0058】また、型に投入または設置する不織布3は
積層体の形状をしたものに限らず、本熱処理A,Bを施
した物であれば、玉綿状、ブロック状等の形状のものを
使用することも可能である。さらにまた、処理時間の短
縮のために、繊維集合体1をあらかじめ成形室内温度付
近まで余熱したものを、成形室に投入することも有効で
ある。
The non-woven fabric 3 to be put or placed in the mold is not limited to the shape of the laminate, but any of the shapes subjected to the main heat treatments A and B, such as cotton, block, etc. It is also possible to use. Furthermore, in order to shorten the processing time, it is also effective to pre-heat the fiber assembly 1 to around the temperature of the molding chamber and to put it into the molding chamber.

【0059】[0059]

【実施例】本発明を次の実施例及び比較例により説明す
る。
The present invention will be described with reference to the following examples and comparative examples.

【実施例1】最終成形品(クッション体)の平均見かけ
密度が0.025g/cm3 となるようにするため、繊
維Aとして繊度6デニールで繊維長50mmのH38F
(日本エステル(株)製)を80重量%、繊維Bとして
繊度2デニールで繊維長50mmのCF31(日本エス
テル(株)製)を10重量%、繊維Cとして繊度2デニ
ールで繊維長50mmの4080(日本エステル(株)
製)を10重量%を用いて構成された繊維集合体を作製
し、図1に示すように、熱処理Aを熱処理A室内温度2
30℃、処理時間10分、湿度雰囲気DRYで行ない、
ついで熱処理Bを熱処理B室内温度70℃、処理時間1
5分、湿度雰囲気50%R.H.で圧縮厚さ25mmと
して行なって、厚み50mm、平均見かけ密度0.01
25g/m2 の不織布を得た。次に図3に示すように、
得られた厚み50mmの不織布を、一般部に4枚、端部
に6枚積層したものに対して、成形Cを雰囲気温度16
5℃で行ない、平均見かけ密度0.025g/cm3
クッション体を得た。
Example 1 In order to make the average apparent density of the final molded product (cushion body) 0.025 g / cm 3 , H38F having a fineness of 6 denier and a fiber length of 50 mm was used as the fiber A.
80% by weight (manufactured by Nippon Ester Co., Ltd.), 10% by weight of CF31 (manufactured by Nippon Ester Co., Ltd.) having a fiber length of 2 denier and 50 mm in fiber length, and 4080 having a fiber length of 2 denier and 50 mm in fiber length as fiber C. (Nippon Ester Co., Ltd.
Was produced using 10% by weight of a heat treatment A, and as shown in FIG.
30 ° C., processing time 10 minutes, humidity atmosphere DRY,
Then, the heat treatment B was performed at a temperature of 70 ° C. in the heat treatment B room and a treatment time of 1 hour.
5 minutes, humidity 50% R. H. Compressed thickness 25 mm, thickness 50 mm, average apparent density 0.01
A nonwoven fabric of 25 g / m 2 was obtained. Next, as shown in FIG.
The obtained non-woven fabric having a thickness of 50 mm was laminated on four sheets in the general part and six pieces in the end part.
Performed at 5 ° C. to obtain a cushion body having an average apparent density of 0.025 g / cm 3 .

【0060】[0060]

【実施例2】構成繊維の割合を繊維Aを90重量%、繊
維Bを5重量%、繊維Cを5重量%とし、熱処理Bの処
理時間を20分とした以外は実施例1と全く同じにし
て、クッション体を得た。
Example 2 Exactly the same as Example 1 except that the ratio of the constituent fibers was 90% by weight of fiber A, 5% by weight of fiber B, 5% by weight of fiber C, and the treatment time of heat treatment B was 20 minutes. To obtain a cushion body.

【0061】[0061]

【実施例3】繊維Cとして7080(日本エステル
(株)製)を用い、繊維B−C間の軟化点差を60℃と
し、成形Cの温度を215℃とした以外は実施例1と全
く同じにして、クッション体を得た。
Example 3 Exactly the same as Example 1 except that 7080 (manufactured by Nippon Ester Co., Ltd.) was used as fiber C, the softening point difference between fibers B and C was 60 ° C., and the temperature of molding C was 215 ° C. To obtain a cushion body.

【0062】[0062]

【実施例4】繊維Bとして2080(日本エステル
(株)製)を用い、繊維A−B間の軟化点差を45℃と
し、繊維B−C間の軟化点差を95℃とした以外は実施
例1と全く同じにして、クッション体を得た。
Example 4 Example 8 was repeated except that 2080 (manufactured by Nippon Ester Co., Ltd.) was used as the fiber B, the softening point difference between the fibers A and B was 45 ° C., and the softening point difference between the fibers B and C was 95 ° C. A cushion body was obtained in exactly the same manner as in 1.

【0063】[0063]

【実施例5】繊維Bとして7080(日本エステル
(株)製)を用い、繊維A−B間の軟化点差を90℃と
し、繊維B−C間の軟化点差を50℃とし、また熱処理
Aの処理温度を215℃とした以外は実施例1と全く同
じにして、クッション体を得た。
Example 5 7080 (manufactured by Nippon Ester Co., Ltd.) was used as fiber B, the softening point difference between fibers AB was 90 ° C., the softening point difference between fibers B and C was 50 ° C. A cushion body was obtained in exactly the same manner as in Example 1 except that the treatment temperature was 215 ° C.

【0064】[0064]

【実施例6】熱処理Bの圧縮厚さを47mmとし、熱処理
Bにおける圧縮後の回復率を105%とし、熱処理Bの
処理時間を20分とした以外は実施例1と全く同じにし
て、クッション体を得た。
Example 6 Cushioning was performed in exactly the same manner as in Example 1 except that the compression thickness of heat treatment B was 47 mm, the recovery rate after compression in heat treatment B was 105%, and the processing time of heat treatment B was 20 minutes. I got a body.

【0065】[0065]

【実施例7】熱処理Bの圧縮厚さを16mmとし、熱処理
Bにおける圧縮後の回復率を300%とし、熱処理Bの
熱処理Bの処理時間を10分とした以外は実施例1と全
く同じにして、クッション体を得た。
Example 7 Except that the compression thickness of the heat treatment B was 16 mm, the recovery rate after compression in the heat treatment B was 300%, and the processing time of the heat treatment B of the heat treatment B was 10 minutes, the same as in Example 1 To obtain a cushion body.

【0066】[0066]

【実施例8】熱処理Bの熱処理B室内温度を90℃と
し、熱処理Bの処理時間を10分とした以外は実施例1
と全く同じにして、クッション体を得た。
Example 8 Example 1 was repeated except that the temperature in the heat treatment B room was set to 90 ° C. and the processing time for the heat treatment B was set to 10 minutes.
A cushion body was obtained in exactly the same manner as described above.

【0067】[0067]

【実施例9】熱処理Bの熱処理B室内温度を30℃と
し、熱処理Bの処理時間を20分とした以外は実施例1と
全く同じにして、クッション体を得た。
Example 9 A cushion body was obtained in exactly the same manner as in Example 1 except that the temperature of the heat treatment B in the heat treatment B was 30 ° C., and the treatment time of the heat treatment B was 20 minutes.

【0068】[0068]

【実施例10】熱処理Bの熱処理B室内湿度をDRYと
し、熱処理Bの処理時間を分とした以外は実施例1と全
く同じにして、クッション体を得た。
Example 10 A cushion body was obtained in exactly the same manner as in Example 1, except that the humidity of the heat treatment B in the heat treatment B was set to DRY, and the treatment time of the heat treatment B was set to minutes.

【0069】[0069]

【実施例11】熱処理Aの熱処理A室内湿度を50%
R.H.とし、熱処理Bの処理時間を10分とした以外
は実施例1と全く同じにして、クッション体を得た。
Embodiment 11 Heat treatment A room humidity of heat treatment A is 50%
R. H. The cushion body was obtained in exactly the same manner as in Example 1 except that the processing time of the heat treatment B was changed to 10 minutes.

【0070】[0070]

【実施例12】成形Cのクッション体成形型内温度を繊
維Bの軟化点より30℃低い190℃とした以外は実施
例1と全く同じにして、クッション体を得た。
Example 12 A cushion body was obtained in exactly the same manner as in Example 1 except that the temperature in the mold for the cushion body of Form C was 190 ° C., which was 30 ° C. lower than the softening point of the fiber B.

【0071】[0071]

【実施例13】最終成形品(クッション体)の密度を
0.01g/cm3 とするため、熱処理Bの処理時間を
5分とし、平均見かけ密度0.005g/m2 の不織布
を得た以外は実施例1と全く同じにして、クッション体
を得た。
Example 13 In order to set the density of the final molded article (cushion body) to 0.01 g / cm 3 , the processing time of the heat treatment B was set to 5 minutes, and a nonwoven fabric having an average apparent density of 0.005 g / m 2 was obtained. In the same manner as in Example 1, a cushion body was obtained.

【0072】[0072]

【実施例14】最終成形品(クッション体)の密度を
0.3g/cm3 とするため、熱処理Bの処理時間を3
0分とし、平均見かけ密度0.15g/m2 の不織布を
得た以外は実施例1と全く同じにして、クッション体を
得た。
Embodiment 14 In order to set the density of the final molded product (cushion body) to 0.3 g / cm 3 , the processing time of the heat treatment B was set to 3 hours.
A cushion body was obtained in exactly the same manner as in Example 1 except that the nonwoven fabric had an average apparent density of 0.15 g / m 2 at 0 minutes.

【0073】[0073]

【比較例1】従来の一般熱成形品として、図2に示す様
に、熱処理Aのみにて厚み50mmの不織布を得、熱処
理Bを行なわず、成形Cを行いクッション体とした以外
は実施例1と全く同じにして、クッション体を得た。
Comparative Example 1 As a conventional general thermoformed product, as shown in FIG. 2, a non-woven fabric having a thickness of 50 mm was obtained only by heat treatment A, and a heat treatment B was not performed. A cushion body was obtained in exactly the same manner as in 1.

【0074】[0074]

【比較例2】繊維Cを2080(日本エステル(株)
製)とし、繊維B−C間の軟化点差を15℃とし、成形
Cのクッション体成形型内温度を205℃とした以外は
実施例1と全く同じにして、クッション体を得た。
Comparative Example 2 Fiber C was converted to 2080 (Nippon Ester Co., Ltd.)
A cushion body was obtained in exactly the same manner as in Example 1 except that the softening point difference between the fibers B and C was set to 15 ° C., and the temperature in the cushion body forming die of Form C was set to 205 ° C.

【0075】[0075]

【比較例3】熱処理Bの圧縮厚さを50mmとし、熱処
理Bにおける圧縮後の回復率を100%とした以外は実施例
1と全く同じにして、クッション体を得た。
Comparative Example 3 A cushion body was obtained in exactly the same manner as in Example 1 except that the compression thickness of heat treatment B was 50 mm, and the recovery rate after compression in heat treatment B was 100%.

【0076】[0076]

【比較例4】熱処理Bの熱処理B室内温度を110℃と
し、処理時間を10分とした以外は実施例1と全く同じ
にして、クッション体を得た。
Comparative Example 4 A cushion body was obtained in exactly the same manner as in Example 1 except that the temperature of the heat treatment B in the heat treatment B was set to 110 ° C. and the treatment time was set to 10 minutes.

【0077】[0077]

【比較例5】成形Cのクッション体成形型内温度を繊維
Bの軟化点より5℃低い215℃とした以外は実施例1
と全く同じにして、クッション体を得た。
Comparative Example 5 Example 1 except that the temperature in the mold for the cushion body of Form C was set to 215 ° C., which is 5 ° C. lower than the softening point of the fiber B.
A cushion body was obtained in exactly the same manner as described above.

【0078】(試験例)上記の実施例1〜14及び比較
例1〜5で得られたクッション体について、圧縮永久歪
み試験をJIS−K6382の圧縮永久歪み試験方法に
より行なって、圧縮永久歪み率の測定をした。これらの
試験結果を表1に示す。
(Test Example) A compression set test was performed on the cushion bodies obtained in Examples 1 to 14 and Comparative Examples 1 to 5 in accordance with the compression set test method of JIS-K6382. Was measured. Table 1 shows the test results.

【0079】[0079]

【表1】 [Table 1]

【0080】表1に示す結果において、従来成形方法に
よって得られた比較例1の成形品の圧縮永久歪み率30
%以上のものは×で示し、本成形方法の効果がないもの
と判断した。圧縮永久歪み率が改善された15%以上3
0%以下のものを○、著しく改善された15%未満のも
のを◎で示した。表1より、実施例で作製したクッショ
ン体は、圧縮永久歪み率の値が改善されたことがわか
る。また、表1より比較例では、クッション体として得
ることができなかったか、また、歪み率の値が従来品程
度にしかならなかった。
The results shown in Table 1 show that the compression set of the molded article of Comparative Example 1 obtained by the conventional molding method was 30%.
% Or more were indicated by x, and it was judged that the present molding method had no effect. 15% or more with improved compression set 3
Those with 0% or less are marked with ○, and those with significantly improved less than 15% are marked with ◎. Table 1 shows that the cushion bodies manufactured in the examples have improved compression set values. Further, from Table 1, in the comparative example, it could not be obtained as a cushion body, and the value of the strain rate was only about the same as the conventional product.

【0081】[0081]

【発明の効果】本発明の成形方法により製造された不織
布及び該不織布を用いたクッション体と車両用シートは
特に圧縮永久歪み率が改善され、また、リサイクル性も
向上することができる。
As described above, the nonwoven fabric produced by the molding method of the present invention, and the cushion body and the vehicle seat using the nonwoven fabric can have particularly improved compression set and recyclability.

【図面の簡単な説明】[Brief description of the drawings]

【図1】 本発明に係る熱処理方法を示す側断面図であ
る。
FIG. 1 is a side sectional view showing a heat treatment method according to the present invention.

【図2】 従来の一般熱処理方法を示す側断面図であ
る。
FIG. 2 is a side sectional view showing a conventional general heat treatment method.

【図3】 本発明に係るクッション体の成形方法を示す
側断面図である。
FIG. 3 is a side sectional view showing a method of forming a cushion body according to the present invention.

【図4】 本発明に係るクッション体の成形方法を示す
側断面図である。
FIG. 4 is a side sectional view showing a method for forming a cushion body according to the present invention.

【図5】 本発明に係るクッション体の成形方法を示す
側断面図である。
FIG. 5 is a side sectional view showing a method for forming a cushion body according to the present invention.

【図6】 本発明の車両用シートの一例を示す斜視図で
ある。
FIG. 6 is a perspective view showing an example of a vehicle seat according to the present invention.

【符号の説明】[Explanation of symbols]

1 繊維集合体 2 熱処理Aを終えた不織布 3 熱処理Bを終えた不織布 4 従来熱処理を終えた不織布 5 成形Cを行われている不織布 6 成形Cを終えたクッション体 7 クッション体を用いた車両用シート 10 熱処理A室 11 熱処理B室 12 室内移送用コンベア 13 コンベア上金網 14 コンベア上孔 15 成形用ローラー 16 圧縮成形用ローラー 17 室外移送用コンベア 18 送気管 19 排気管 20 従来成形室 30 上型 31 上型成形面 32 上型本体 33 上部加圧部材 34 上型成形面孔 35 上型チヤンバー 36 送気管 40 下型 41 下型成形面 42 下型本体 43 下型加圧部材 44 下型成形面孔 45 下型チヤンバー 46 排気管 DESCRIPTION OF SYMBOLS 1 Fiber aggregate 2 Non-woven fabric which completed heat treatment A 3 Non-woven fabric which completed heat treatment B 4 Non-woven fabric which completed conventional heat treatment 5 Non-woven fabric which had been formed C 6 Cushion body which completed C formation 7 For vehicles using a cushion body Sheet 10 Heat treatment room A 11 Heat treatment room B 12 Indoor transfer conveyor 13 Conveyor upper wire net 14 Conveyor upper hole 15 Forming roller 16 Compression forming roller 17 Outside transfer conveyor 18 Air supply pipe 19 Exhaust pipe 20 Conventional forming chamber 30 Upper mold 31 Upper die forming surface 32 Upper die main body 33 Upper pressing member 34 Upper die forming surface hole 35 Upper die chamber 36 Air supply pipe 40 Lower die 41 Lower die forming surface 42 Lower die main body 43 Lower die pressing member 44 Lower die forming surface hole 45 Lower Type chamber 46 Exhaust pipe

Claims (15)

【特許請求の範囲】[Claims] 【請求項1】 主体繊維(繊維A)、高軟化点バインダ
ー繊維(繊維B)および低軟化点バインダー繊維(繊維
C)により構成される繊維重合体を、繊維Aの軟化点未
満かつ繊維Bの軟化点以上の温度で熱成形(熱処理A)
し、次いで繊維Bの軟化点より低い軟化点である繊維C
の軟化点未満の温度で圧縮を伴う熱成形(熱処理B)を
行う工程を有することを特徴とする不織布の成形方法。
1. A fiber polymer comprising a main fiber (fiber A), a high softening point binder fiber (fiber B) and a low softening point binder fiber (fiber C) is mixed with a fiber polymer having a softening point lower than that of fiber A and Thermoforming at a temperature above the softening point (heat treatment A)
And then a fiber C having a softening point lower than that of the fiber B
A process of performing thermoforming with compression (heat treatment B) at a temperature lower than the softening point of the nonwoven fabric.
【請求項2】 請求項1記載の不織布の成形方法におい
て、繊維集合体はポリエステルを主成分とし、繊維Aを
0〜90重量%と、繊維Aより少なくとも20℃は軟化
点の低い成分を全部または一部含む繊維Bを5〜95重
量%と、繊維Bより少なくとも50℃は軟化点の低い成
分を全部または一部含む繊維Cを5〜95重量%とから
構成されることを特徴とする不織布の成形方法。
2. The method for forming a nonwoven fabric according to claim 1, wherein the fiber aggregate is mainly composed of polyester, the fiber A is contained in an amount of 0 to 90% by weight, and all components having a softening point lower than that of the fiber A by at least 20 ° C. Alternatively, the fiber C is characterized by comprising 5 to 95% by weight of the fiber B partially containing the fiber B and 5 to 95% by weight of the fiber C containing all or a part of the component having a softening point lower by at least 50 ° C. than the fiber B. Nonwoven fabric molding method.
【請求項3】 請求項2記載の不織布の成形方法におい
て、繊維Aは繊度0.5〜10000デニールで繊維長
30〜100mmであり、繊維Bは繊維径1〜1000
0デニールで繊維長30〜100mmであり、繊維Cは
繊維径1〜10000デニールで繊維長30〜100m
mであることを特徴とする不織布の成形方法。
3. The method for forming a nonwoven fabric according to claim 2, wherein the fiber A has a fineness of 0.5 to 10,000 denier and a fiber length of 30 to 100 mm, and the fiber B has a fiber diameter of 1 to 1000.
The fiber length is 30 to 100 mm with 0 denier and the fiber length is 30 to 100 m with the fiber diameter of 1 to 10000 denier.
m.
【請求項4】 請求項1〜3いずれかの項記載の不織布
の成形方法において、得られる不織布が熱処理Bで圧縮
された厚さの105%以上の厚さになることを特徴とす
る不織布の成形方法。
4. The method for forming a nonwoven fabric according to claim 1, wherein the obtained nonwoven fabric has a thickness of 105% or more of the thickness compressed by the heat treatment B. Molding method.
【請求項5】 請求項1〜3いずれかの項記載の不織布
の成形方法において、得られる不織布が熱処理Bで圧縮
された厚さの300%以上の厚さになることを特徴とす
る不織布の成形方法。
5. The method for forming a nonwoven fabric according to claim 1, wherein the obtained nonwoven fabric has a thickness of 300% or more of the thickness compressed by the heat treatment B. Molding method.
【請求項6】 請求項1〜5いずれかの項記載の熱処理
Aにおいて、繊維Aの軟化点の少なくとも20℃以下か
つ繊維Bの軟化点以上の温度で熱成形を行なうことを特
徴とする不織布の成形方法。
6. The non-woven fabric according to claim 1, wherein thermoforming is performed at a temperature of at least 20 ° C. of the softening point of the fiber A and at least the softening point of the fiber B. Molding method.
【請求項7】 請求項1〜6いずれかの項記載の熱処理
Bにおいて、繊維Cの軟化点の少なくとも20℃以下の
温度で圧縮を伴う熱成形を行なうことを特徴とする不織
布の成形方法。
7. The method for forming a nonwoven fabric according to any one of claims 1 to 6, wherein thermoforming accompanied by compression is performed at a temperature of at least 20 ° C. or less of the softening point of the fiber C.
【請求項8】 請求項1〜7いずれかの項記載の熱処理
Bにおいて、雰囲気温度が30℃以上であることを特徴
とする不織布の成形方法。
8. The method for forming a nonwoven fabric according to claim 1, wherein the atmosphere temperature is 30 ° C. or higher.
【請求項9】 請求項1〜7いずれかの項記載の熱処理
Bにおいて、雰囲気温度が60℃以上であることを特徴
とする不織布の成形方法。
9. The method for forming a nonwoven fabric according to claim 1, wherein the atmosphere temperature is 60 ° C. or higher.
【請求項10】 請求項1〜9いずれかの項記載の不織
布の成形方法において、熱処理時に、不織布に対して加
湿若しくは蒸気を付加し、又は加湿若しくは蒸気雰囲気
中で熱処理することを特徴とする不織布の成形方法。
10. The method for forming a nonwoven fabric according to any one of claims 1 to 9, wherein humidification or steam is added to the nonwoven fabric during heat treatment, or heat treatment is performed in a humidified or steam atmosphere. Nonwoven fabric molding method.
【請求項11】 請求項1〜10いずれかの項記載の成
形方法により成形された不織布。
11. A non-woven fabric formed by the forming method according to claim 1.
【請求項12】 請求項11記載の不織布を、繊維Cの
軟化点以上かつ繊維Bの軟化点より少なくとも30℃低
い温度で最終成形クッション体の形状に熱成形(成形
C)することにより得られるクッション体。
12. The non-woven fabric according to claim 11, which is obtained by thermoforming (molding C) into a final molded cushion at a temperature higher than the softening point of the fiber C and at least 30 ° C. lower than the softening point of the fiber B. Cushion body.
【請求項13】 請求項11記載の不織布を、繊維Cの
軟化点以上かつ繊維Bの軟化点より少なくとも60℃低
い温度で最終成形クッション体の形状に熱成形(成形
C)することにより得られるクッション体。
13. A non-woven fabric according to claim 11, which is obtained by thermoforming (forming C) into a final molded cushion at a temperature higher than the softening point of the fiber C and at least 60 ° C. lower than the softening point of the fiber B. Cushion body.
【請求項14】 請求項12又は13記載のクッション
体において、成形時にクッション体に対して加湿若しく
は蒸気を付加し、又は加湿若しくは蒸気雰囲気中で成形
することを特徴とするクッション体。
14. The cushion body according to claim 12, wherein humidification or steam is added to the cushion body during molding, or molding is performed in a humidified or steam atmosphere.
【請求項15】 請求項12〜14いずれかの項記載の
クッション体を一部または全部に用いて製造される車両
用シート。
15. A vehicle seat manufactured by partially or entirely using the cushion body according to any one of claims 12 to 14.
JP642199A 1999-01-13 1999-01-13 Nonwoven fabric, its formation, and cushion body and sheet for vehicle using the same nonwoven fabric Withdrawn JP2000212868A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP642199A JP2000212868A (en) 1999-01-13 1999-01-13 Nonwoven fabric, its formation, and cushion body and sheet for vehicle using the same nonwoven fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP642199A JP2000212868A (en) 1999-01-13 1999-01-13 Nonwoven fabric, its formation, and cushion body and sheet for vehicle using the same nonwoven fabric

Publications (1)

Publication Number Publication Date
JP2000212868A true JP2000212868A (en) 2000-08-02

Family

ID=11637918

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP2000212868A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006522239A (en) * 2003-03-31 2006-09-28 キシミド・エル・エル・シー Abrasion-resistant composite material containing binder resin activated at the processing site
JP2007070745A (en) * 2005-09-05 2007-03-22 Unitika Ltd Method for forming carpet
JP2008179920A (en) * 2007-01-25 2008-08-07 Kuraray Kuraflex Co Ltd Smooth lightweight board material
JP2009536269A (en) * 2006-05-10 2009-10-08 コルボント ベスローテン フェンノートシャップ Non-woven fabric, tufted non-woven fabric, and product containing the material

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006522239A (en) * 2003-03-31 2006-09-28 キシミド・エル・エル・シー Abrasion-resistant composite material containing binder resin activated at the processing site
JP2007070745A (en) * 2005-09-05 2007-03-22 Unitika Ltd Method for forming carpet
JP2009536269A (en) * 2006-05-10 2009-10-08 コルボント ベスローテン フェンノートシャップ Non-woven fabric, tufted non-woven fabric, and product containing the material
JP2008179920A (en) * 2007-01-25 2008-08-07 Kuraray Kuraflex Co Ltd Smooth lightweight board material

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