JP2000199173A - Woven fabric for organic substance decomposing photocatalyst - Google Patents
Woven fabric for organic substance decomposing photocatalystInfo
- Publication number
- JP2000199173A JP2000199173A JP37202698A JP37202698A JP2000199173A JP 2000199173 A JP2000199173 A JP 2000199173A JP 37202698 A JP37202698 A JP 37202698A JP 37202698 A JP37202698 A JP 37202698A JP 2000199173 A JP2000199173 A JP 2000199173A
- Authority
- JP
- Japan
- Prior art keywords
- woven fabric
- coating material
- photocatalyst
- glass
- titanium dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002759 woven fabric Substances 0.000 title claims abstract description 47
- 239000011941 photocatalyst Substances 0.000 title claims abstract description 24
- 239000000126 substance Substances 0.000 title claims description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 65
- 239000000463 material Substances 0.000 claims abstract description 34
- 239000011248 coating agent Substances 0.000 claims abstract description 33
- 238000000576 coating method Methods 0.000 claims abstract description 33
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 20
- 239000011521 glass Substances 0.000 claims abstract description 9
- 238000001035 drying Methods 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 239000013078 crystal Substances 0.000 claims description 10
- HFLAMWCKUFHSAZ-UHFFFAOYSA-N niobium dioxide Chemical compound O=[Nb]=O HFLAMWCKUFHSAZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000005416 organic matter Substances 0.000 claims description 8
- DZKDPOPGYFUOGI-UHFFFAOYSA-N tungsten(iv) oxide Chemical compound O=[W]=O DZKDPOPGYFUOGI-UHFFFAOYSA-N 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 claims description 6
- 229910001111 Fine metal Inorganic materials 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 4
- 238000009941 weaving Methods 0.000 claims description 4
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 claims description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 3
- DUSBUJMVTRZABV-UHFFFAOYSA-M [O-2].O[Nb+4].[O-2] Chemical compound [O-2].O[Nb+4].[O-2] DUSBUJMVTRZABV-UHFFFAOYSA-M 0.000 claims description 3
- DLINORNFHVEIFE-UHFFFAOYSA-N hydrogen peroxide;zinc Chemical compound [Zn].OO DLINORNFHVEIFE-UHFFFAOYSA-N 0.000 claims description 3
- 239000005355 lead glass Substances 0.000 claims description 3
- 239000005297 pyrex Substances 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000007921 spray Substances 0.000 abstract description 4
- 239000004744 fabric Substances 0.000 description 12
- 239000000853 adhesive Substances 0.000 description 9
- 230000001070 adhesive effect Effects 0.000 description 9
- 239000010419 fine particle Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 4
- 238000013032 photocatalytic reaction Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 101150042008 ACO4 gene Proteins 0.000 description 1
- 102100032566 Carbonic anhydrase-related protein 10 Human genes 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 101100321669 Fagopyrum esculentum FA02 gene Proteins 0.000 description 1
- 101000867836 Homo sapiens Carbonic anhydrase-related protein 10 Proteins 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Catalysts (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
【０００１】[0001]
【発明に属する技術分野】本発明は排ガスの処理、廃水
処理、浄水処理などの環境浄化手段として用いられる有
機物分解光触媒に適用するための有機物分解用の織布に
関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a woven fabric for decomposing organic substances, which is applied to an organic substance decomposing photocatalyst used as an environmental purification means such as exhaust gas treatment, wastewater treatment, and water purification treatment.
【０００２】[0002]
【従来の技術】有機物分解光触媒は、例えば酸化チタン
等の半導体物質に光を照射することで、該半導体物質に
強い還元作用をもつ電子と強い酸化作用をもつ正孔を生
成し、この半導体に接触した分子種（有機物）を酸化還
元作用により分解する技術に係る。こうした光触媒技術
については、従来様々な提案がなされており、例えば特
開平９−２５３５０５号や特開平６−１３４４７６号に
示す光触媒材料が提案されている。また本出願の発明者
においても特願平１０−２４３８１３号、特願平１０−
３５２０１８号に示す提案を行っている。2. Description of the Related Art An organic substance decomposition photocatalyst irradiates a semiconductor substance such as titanium oxide with light, thereby generating electrons having a strong reducing action and holes having a strong oxidizing action on the semiconductor substance, and producing the semiconductor substance. The present invention relates to a technique for decomposing molecular species (organic substances) in contact with each other by redox action. Conventionally, various proposals have been made for such photocatalyst technology, and for example, photocatalyst materials disclosed in JP-A-9-253505 and JP-A-6-134476 have been proposed. In addition, the inventors of the present application also disclosed in Japanese Patent Application Nos.
No. 352018 is proposed.
【０００３】[0003]
【発明が解決しようとする課題】ところで、出願人は上
記出願を行った後においても、様々な材料について有機
物分解能に関する実験と実証を行っており、広い分野に
応用することのできる光触媒材料の開発に取り組んでい
るところである。By the way, the applicant has conducted experiments and demonstrations on the resolution of organic substances for various materials even after filing the above-mentioned application, and has developed a photocatalyst material applicable to a wide range of fields. We are working on.
【０００４】そうした中で、出願人は光触媒用に用意さ
れた光源ばかりでなく、通常の太陽光や室内光を利用
し、様々な分野に応用することのできる光触媒材料を提
供することを目的とし、本願発明を行なうに至ったもの
である。[0004] Under such circumstances, the applicant has aimed to provide a photocatalyst material that can be applied to various fields using not only a light source prepared for a photocatalyst but also ordinary sunlight or room light. Thus, the present invention has been accomplished.
【０００５】[0005]
【課題を解決するための手段】上記目的を達成するた
め、本発明は石英ガラス、鉛ガラス、ソーダガラス、パ
イレックスなどからなる透明糸状物質を縦糸、横糸に用
いて織成してなる織布の片面側に、酸化チタン、酸化亜
鉛、二酸化タングステン、二酸化ニオブ、酸化ケイ素な
どからなる金属結晶微粒子を含む塗材を塗布し、乾燥し
た後、これを高温処理することで、片面側に二酸化チタ
ン、二酸化亜鉛、三酸化タングステン、三酸化ニオブ、
二酸化ケイ素などからなる有機物分解光触媒物質を焼成
することとした有機物分解光触媒用の織布としたもので
ある。In order to achieve the above object, the present invention relates to a woven fabric formed by weaving a transparent thread-like substance made of quartz glass, lead glass, soda glass, Pyrex or the like for warp and weft yarns. A coating material containing metal crystal fine particles made of titanium oxide, zinc oxide, tungsten dioxide, niobium dioxide, silicon oxide, etc. is applied to the coating material, dried, and then subjected to a high temperature treatment, so that titanium dioxide and zinc dioxide are applied to one side. , Tungsten trioxide, niobium trioxide,
This is a woven fabric for an organic substance decomposing photocatalyst in which an organic substance decomposing photocatalyst substance made of silicon dioxide or the like is calcined.
【０００６】また本発明は透明糸状物質を織成してなる
織布の片面側に金属結晶微粒子を含む塗材を塗布し、乾
燥した後、これを高温処理する工程を少なくとも３回か
ら５回繰り返すこととしたものである。Further, the present invention comprises repeating a step of applying a coating material containing fine metal crystal particles on one side of a woven fabric formed by weaving a transparent thread-like substance, drying the coating material, and then subjecting the coating material to a high-temperature treatment at least three to five times. It is what it was.
【０００７】また本発明は片面側に金属結晶微粒子を含
む塗材を塗布し、乾燥した織布を高温処理する工程にあ
って、処理温度を４５０℃〜６５０℃としてなる有機物
分解光触媒用の織布としたものである。The present invention is also directed to a step of applying a coating material containing metal crystal fine particles on one side and treating the dried woven fabric at a high temperature, wherein the treatment temperature is 450 ° C. to 650 ° C. It is a cloth.
【０００８】[0008]
【発明の実施の形態】出願人は先に提案した特願平１０
−３５２０１８号において、表面に二酸化チタン層を備
えた有機物分解光触媒用の糸を用いて織成された織布の
提案を行ったところである。出願人はこうして形成され
た織布を壁用のクロスとして壁パネルの片面に接着剤で
貼着し、該織布の壁用クロス等としての用途の実験を行
ったところ、織布に対して照射される光により光触媒反
応が生じ、壁パネルから織布が離脱し易いことが判明し
た。すなわち、織布に照射される光により織布の糸の表
面に形成された二酸化チタン層が光触媒反応を起こし、
接着剤を構成する有機物質が分解され、接着剤の接着力
を低下させることに基づくものと認められるためであ
る。出願人は、こうした不具合を克服するため、この種
の織布において使用可能な無機系の接着剤を探したとこ
ろであるが、接着力のある無機系の接着剤は全くと言っ
ていいほど存在せず、対応に苦慮していたところであ
る。DESCRIPTION OF THE PREFERRED EMBODIMENTS The applicant has filed Japanese Patent Application No.
In Japanese Patent Application No. 352018, a woven fabric woven using a yarn for organic matter decomposition photocatalyst having a titanium dioxide layer on the surface has been proposed. The applicant applied the woven fabric thus formed as a cloth for a wall to one surface of a wall panel with an adhesive, and conducted an experiment on the use of the woven cloth as a cloth for a wall. It was found that a photocatalytic reaction was caused by the irradiated light, and the woven fabric was easily detached from the wall panel. That is, the titanium dioxide layer formed on the surface of the yarn of the woven fabric by the light irradiated on the woven fabric causes a photocatalytic reaction,
This is because it is recognized that the organic substance constituting the adhesive is decomposed to reduce the adhesive strength of the adhesive. The applicant has sought an inorganic adhesive that can be used in this kind of woven fabric in order to overcome such a problem, but almost no inorganic adhesive having adhesive strength exists. I was struggling to respond.
【０００９】そのような中で出願人は、ガラスクロスの
片面側にのみ、こうした二酸化チタン層等を形成するべ
く試行錯誤を行ったところ、以下の実施形態に係る有機
物分解光触媒用の織布を完成するに至ったところであ
る。先ず、本実施形態においては、石英ガラス、鉛ガラ
ス、ソーダガラス、パイレックスなどからなる透明糸状
物質（１００〜５００ミクロン程度）を縦糸及び横糸に
用いて図１に示す織布１、すなわちガラスクロスを形成
し、その片面側に金属結晶微粒子を含む塗材２を塗布す
るようにする。実施形態において金属結晶微粒子はチタ
ニアゾルが用いられ、塗材２は図１に示すようにトレイ
３中に貯留される。Under such circumstances, the applicant conducted trial and error to form such a titanium dioxide layer or the like only on one side of the glass cloth, and found that a woven fabric for an organic matter decomposing photocatalyst according to the following embodiment was formed. It has just been completed. First, in the present embodiment, the woven fabric 1 shown in FIG. 1, that is, the glass cloth is used by using a transparent thread-like substance (about 100 to 500 microns) made of quartz glass, lead glass, soda glass, Pyrex, or the like for the warp and the weft. Then, the coating material 2 containing the metal crystal fine particles is applied to one surface side thereof. In the embodiment, titania sol is used as the metal crystal fine particles, and the coating material 2 is stored in a tray 3 as shown in FIG.
【００１０】塗材２は、界面活性剤を添加してなる溶液
中にチタニアゾルを２〜５％程度配合し、撹拌して形成
させる。また、チタニアゾルは有機チタネートやチタン
塩を加水分解したり、微粒子の二酸化チタンを水やアル
コールなどの溶媒に懸濁することによって得られる。こ
うしてトレイ３中に貯留される塗材２は、塗布ローラ４
を用いて織布１の片面側に塗布される（図１参照）。さ
らに、塗材２の織布１への塗布は、図２に示すようにス
プレーガン５を用いて、織布１の片面側に塗布すること
としてもよい。こうして塗材２の塗布が片側面全体に行
われた織布１は、塗材２の自然乾燥が行われる。乾燥時
間は１０分〜３０分程度とし、こうして乾燥が行われる
と織布１は、片側面に付着されたチタニアゾルが乾燥さ
れてチタニアゲルとなる。The coating material 2 is formed by mixing about 2 to 5% of titania sol in a solution containing a surfactant and stirring. The titania sol is obtained by hydrolyzing an organic titanate or a titanium salt, or by suspending fine particles of titanium dioxide in a solvent such as water or alcohol. The coating material 2 stored in the tray 3 in this manner is
Is applied to one side of the woven fabric 1 (see FIG. 1). Further, the coating material 2 may be applied to the woven fabric 1 by using a spray gun 5 as shown in FIG. In the woven fabric 1 on which the coating material 2 is applied on one side as a whole, the coating material 2 is naturally dried. The drying time is about 10 minutes to 30 minutes. When the drying is performed in this manner, the woven fabric 1 is dried from the titania sol attached to one side surface to form a titania gel.
【００１１】こうして図３に示すように塗布工程並びに
乾燥工程を経た織布１は、次に処理温定４５０℃〜６５
０℃程度に加熱された高温炉中に供給され、図３に示す
加熱工程へと移行される。加熱時間は３０分程度が適当
とされ、こうして高温処理された織布１は、片側面に塗
布されたチタニアゲルが二酸化チタン（Ｔｉｏ２）に変
化し、図４に示すように織布１の片側面に二酸化チタン
層６が焼成されることとなる。上記塗布工程並びに乾燥
工程、さらに加熱工程は、図３に示すように通常３〜５
回程度繰り返され、これにより、徐々に二酸化チタン層
６の層圧並びに塗布量が増大する。こうした二酸化チタ
ン層６は図４のＡ部に示すように、織布１を構成する糸
の表面において斑状に付着された層状をなし、ガラスク
ロスからなる織布１に対して外光が適度に透過可能とさ
れる。なお、織布１の片側面における二酸化チタン層６
の層圧を増大させたり、また外表面における斑状の二酸
化チタン層６の面積を増加させる場合は、上記塗布工程
あるいは乾燥工程の繰り返し回数を増加させる方法や塗
材２中における界面活性剤について、よりエマルション
性の高いものを選択する方法がある。As shown in FIG. 3, the woven fabric 1 which has been subjected to the coating step and the drying step is processed at a processing temperature of 450 ° C. to 65 ° C.
It is supplied into a high-temperature furnace heated to about 0 ° C., and is shifted to a heating step shown in FIG. The heating time is suitably about 30 minutes. In the woven fabric 1 thus treated at a high temperature, the titania gel applied to one side is changed into titanium dioxide (TiO2), and as shown in FIG. Then, the titanium dioxide layer 6 is fired. As shown in FIG. 3, the coating step, the drying step, and the heating step are usually performed in 3 to 5 times.
This is repeated about once, whereby the layer pressure and coating amount of the titanium dioxide layer 6 gradually increase. As shown in part A of FIG. 4, the titanium dioxide layer 6 has a layered shape attached to the surface of the yarn constituting the woven fabric 1 in a patchy manner, and external light is appropriately applied to the woven fabric 1 made of glass cloth. It can be transmitted. The titanium dioxide layer 6 on one side of the woven fabric 1
In order to increase the layer pressure of, or to increase the area of the patchy titanium dioxide layer 6 on the outer surface, a method of increasing the number of repetitions of the coating step or the drying step and the surfactant in the coating material 2 There is a method of selecting one having a higher emulsion property.
【００１２】すなわち、このようにして片側面に二酸化
チタン層６を備えた織布１は、端部からはもちろん、二
酸化チタン層６を備えていない裏面からも外光を透過す
ることができ、紫外線照射ランプなど特別に用意された
照明の光や太陽光、室内光でも二酸化チタン層６の部分
において光触媒現象を発生させることができる。つまり
この現象はガラスクロスからなる織布１内に透過された
光γがエネルギとなって、二酸化チタン層６の部分に電
子と正孔が生成される酸化還元作用が発生し、こうして
形成される織布１は様々な用途に使用することが可能と
される。例えばカーテン用のクロスとして使用すること
により、太陽光が織布１の主として裏面側に照射され、
より活発な光触媒反応を得ることができる。また、片側
面だけに二酸化チタン層６が備えられるため、二酸化チ
タン層６を備えていない裏面側に接着剤（有機系）を塗
布して壁やパネルに貼着しても、裏面側には有機物質を
分解する光触媒反応が生じないため、接着剤成分が分解
されることもない。したがって、壁用クロス、天井クロ
ス、傷口用の密閉シールなどに用いるのに好適とされ
る。That is, the woven fabric 1 provided with the titanium dioxide layer 6 on one side in this way can transmit external light not only from the end but also from the back surface not provided with the titanium dioxide layer 6. Photocatalytic phenomena can be generated in the titanium dioxide layer 6 even with specially prepared illumination light such as an ultraviolet irradiation lamp, sunlight, or indoor light. That is, in this phenomenon, light γ transmitted through the woven fabric 1 made of glass cloth becomes energy, and an oxidation-reduction action occurs in which electrons and holes are generated in the portion of the titanium dioxide layer 6, which is formed in this manner. The woven fabric 1 can be used for various applications. For example, by using as a cloth for curtains, sunlight is mainly irradiated on the back side of the woven fabric 1,
A more vigorous photocatalytic reaction can be obtained. In addition, since the titanium dioxide layer 6 is provided only on one side, even if an adhesive (organic) is applied to the back side not having the titanium dioxide layer 6 and attached to a wall or panel, the back side may be provided. Since the photocatalytic reaction for decomposing the organic substance does not occur, the adhesive component is not decomposed. Therefore, it is suitable for use as a wall cloth, a ceiling cloth, a hermetic seal for a wound, and the like.
【００１３】[0013]
【実施例】上記実施例においては、塗材２中に含まれる
金属結晶微粒子をチタニアゲル（酸化チタン）に例をと
って説明したが、塗材中に含有する材料としては、この
他にも酸化亜鉛、二酸化タングステン、二酸化ニオブ、
酸化ケイ素など、様々な金属結晶微粒子を選択すること
ができる。こうした物質からなる塗材を片側面に塗布し
てなる織布１は、前記実施形態のように、高温炉中に供
給することで有機物分解光触媒物質として焼成されるこ
ととなる。すなわち、酸化亜鉛は燃焼により二酸化亜鉛
に、二酸化タングステンは燃焼により三酸化タングステ
ンに、二酸化ニオブは燃焼により三酸化ニオブに、酸化
ケイ素は燃焼により二酸化ケイ素に変換されることとな
る。こうして変換され、焼成された有機物分解光触媒物
質層にあっては、前記二酸化チタン層６と同様に光触媒
が行われるため、こうして形成される織布にあっても前
記実施形態と同様な用途に使用することが可能となる。[Embodiment] In the above embodiment, the metal crystal fine particles contained in the coating material 2 have been described by taking titania gel (titanium oxide) as an example. Zinc, tungsten dioxide, niobium dioxide,
Various metal crystal fine particles such as silicon oxide can be selected. The woven fabric 1 obtained by applying a coating material made of such a substance to one side is supplied to a high-temperature furnace and fired as an organic matter decomposing photocatalytic substance as in the above-described embodiment. That is, zinc oxide is converted to zinc dioxide by combustion, tungsten dioxide is converted to tungsten trioxide by combustion, niobium dioxide is converted to niobium trioxide by combustion, and silicon oxide is converted to silicon dioxide by combustion. The photocatalyst layer converted and fired in the organic matter is photocatalyzed in the same manner as the titanium dioxide layer 6, so that the woven fabric thus formed can be used for the same applications as in the above embodiment. It is possible to do.
【発明の効果】以上のように、本発明によれば光触媒用
に用意された光源ばかりでなく、通常の太陽光や室内光
を利用し、様々な分野に応用することのできる光触媒材
料を提供することができるという効果がある。As described above, according to the present invention, not only a light source prepared for a photocatalyst but also a photocatalyst material which can be applied to various fields by using ordinary sunlight or indoor light is provided. There is an effect that can be.
【図１】 有機物分解光触媒用の織布を製造するため、
塗材をローラにより塗布する斜視図である。FIG. 1 In order to produce a woven fabric for an organic matter decomposition photocatalyst,
It is a perspective view which applies a coating material with a roller.
【図２】 有機物分解光触媒用の織布を製造するため、
塗材をスプレーガンにより塗布する状態を示す図であ
る。FIG. 2 To produce a woven fabric for an organic matter decomposition photocatalyst,
It is a figure showing the state where a coating material is applied with a spray gun.
【図３】 有機物分解光触媒用の織布の製造工程を示す
ブロック図である。FIG. 3 is a block diagram showing a manufacturing process of a woven fabric for an organic matter decomposition photocatalyst.
【図４】 製造される織布を拡大して示す図である。FIG. 4 is an enlarged view showing a woven fabric to be manufactured.
１ 織布 ２ 塗材 ３ トレイ ４ 塗布ローラ ５ スプレーガン ６ 二酸化チタン層 DESCRIPTION OF SYMBOLS 1 Woven cloth 2 Coating material 3 Tray 4 Coating roller 5 Spray gun 6 Titanium dioxide layer
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｂ０１Ｊ 23/20 Ｂ０１Ｊ 23/30 Ａ 23/30 32/00 32/00 35/02 Ｊ 35/02 35/06 Ｋ 35/06 Ｃ０２Ｆ 1/72 １０１ Ｃ０２Ｆ 1/72 １０１ Ｂ０１Ｄ 53/36 Ｇ Ｊ Ｆターム(参考） 4D048 AA17 AB03 BA06Y BA07X BA12X BA16Y BA24Y BA27Y BA41X BB08 CC06 EA01 4D050 AA01 AA12 AB07 BB01 BC06 BC09 4G069 AA01 AA03 BA02A BA04A BA04B BA14A BA14B BA48A BA48C BB04A BB04B BC35A BC55A BC60A CA02 CA04 CA05 CA10 CA15 CA17 CA19 DA06 EA09 FA02 FB08 FB23 FB34 4L031 AB32 BA09 CA00 CA08 DA00──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) B01J 23/20 B01J 23/30 A 23/30 32/00 32/00 35/02 J 35/02 35 / 06 K 35/06 C02F 1/72 101 C02F 1/72 101 B01D 53/36 G J F term (reference) 4D048 AA17 AB03 BA06Y BA07X BA12X BA16Y BA24Y BA27Y BA41X BB08 CC06 EA01 4D050 AA01 AA12 AB07 BB01 BC06 ACO4 BA04A BA04B BA14A BA14B BA48A BA48C BB04A BB04B BC35A BC55A BC60A CA02 CA04 CA05 CA10 CA15 CA17 CA19 DA06 EA09 FA02 FB08 FB23 FB34 4L031 AB32 BA09 CA00 CA08 DA00
Claims (3)
パイレックスなどからなる透明糸状物質を縦糸、横糸に
用いて織成してなる織布の片面側に、酸化チタン、酸化
亜鉛、二酸化タングステン、二酸化ニオブ、酸化ケイ素
などからなる金属結晶微粒子を含む塗材を塗布し、乾燥
した後、これを高温処理することで、片面側に二酸化チ
タン、二酸化亜鉛、三酸化タングステン、三酸化ニオ
ブ、二酸化ケイ素などからなる有機物分解光触媒物質を
焼成することとした有機物分解光触媒用の織布。1. A quartz glass, a lead glass, a soda glass,
On one side of a woven fabric made by weaving a transparent thread material such as Pyrex for warp and weft, a coating material containing fine metal crystal particles made of titanium oxide, zinc oxide, tungsten dioxide, niobium dioxide, silicon oxide, etc. is applied. After drying, this is treated at a high temperature, so that an organic substance decomposing photocatalyst composed of titanium dioxide, zinc dioxide, tungsten trioxide, niobium trioxide, silicon dioxide, etc. is calcined on one side, for an organic substance decomposing photocatalyst. Woven fabric.
してなる織布の片面側に金属結晶微粒子を含む塗材を塗
布し、乾燥した後、これを高温処理する工程を少なくと
も３回から５回繰り返すこととしてなる有機物分解光触
媒用の織布。2. The method according to claim 1, wherein a coating material containing fine metal crystal particles is applied to one side of a woven fabric formed by weaving a transparent thread-like substance, dried, and then subjected to a high-temperature treatment at least three to five times. Woven fabric for organic matter decomposing photocatalyst to be repeated.
粒子を含む塗材を塗布し、乾燥した織布を高温処理する
工程にあって、処理温度を４５０℃〜６５０℃としてな
る有機物分解光触媒用の織布。3. The organic matter-decomposing photocatalyst according to claim 1, wherein a coating material containing fine metal crystal particles is applied to one side, and the dried woven fabric is treated at a high temperature, wherein the treatment temperature is 450 ° C. to 650 ° C. Woven fabric.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP37202698A JP2000199173A (en) | 1998-12-28 | 1998-12-28 | Woven fabric for organic substance decomposing photocatalyst |
| EP19990121482 EP1008565A1 (en) | 1998-12-11 | 1999-10-28 | Process for the preparation of thread, string, rope or woven fabric with photocatalyst for decomposing organic compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP37202698A JP2000199173A (en) | 1998-12-28 | 1998-12-28 | Woven fabric for organic substance decomposing photocatalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000199173A true JP2000199173A (en) | 2000-07-18 |
Family
ID=18499721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP37202698A Pending JP2000199173A (en) | 1998-12-11 | 1998-12-28 | Woven fabric for organic substance decomposing photocatalyst |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000199173A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005144383A (en) * | 2003-11-18 | 2005-06-09 | Koto Seishoku Kk | Photocatalyst-processed sheet |
| JP2017075420A (en) * | 2015-10-14 | 2017-04-20 | 住化エンバイロメンタルサイエンス株式会社 | Allergen-reducing composition for fiber |
| RU2824859C1 (en) * | 2023-11-28 | 2024-08-14 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Томский государственный университет" | Method of producing fibrous filtering-sorbent material coated with nano-sized titanium dioxide and fibrous filtering-sorbent material |
-
1998
- 1998-12-28 JP JP37202698A patent/JP2000199173A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005144383A (en) * | 2003-11-18 | 2005-06-09 | Koto Seishoku Kk | Photocatalyst-processed sheet |
| JP2017075420A (en) * | 2015-10-14 | 2017-04-20 | 住化エンバイロメンタルサイエンス株式会社 | Allergen-reducing composition for fiber |
| RU2824859C1 (en) * | 2023-11-28 | 2024-08-14 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Томский государственный университет" | Method of producing fibrous filtering-sorbent material coated with nano-sized titanium dioxide and fibrous filtering-sorbent material |
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