JP2000197701A - Manufacture of functional physiologically activated negative ion air produced by using coral - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a manufacturing method of functional physiologically activated negative ion air free from harmful substances produced by using coral. SOLUTION: A burning means 1 burns weathered coral powder at a temperature of 100 to 1000 deg.C to form calcium carbide (CaCO3) 2 of coral, and a dissociation means 3 dissociates the calcium carbide (CaCO3) 2 of coral from the burning means 1 by a minute external force into calcium ions (Ca2+) 5 and carbonic acid ions (CO32-) 6. A water reaction means 7 reacts upon the above carbonic acid ions 6 with the water (H2O) in the air to obtain bicarbonate (H2CO3) 8 of buffer base-physiological function activated ions and hydroxyl ions (OH) 9 of physiologically activated ions-negative ions.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention generally relates to a method for producing negative ion air, and more particularly to a method for producing functionally active negative ion air. More particularly, the present invention relates to a method for producing functional physiologically active negative ion air generated using calcined coral powder.

[0002]

2. Description of the Related Art From here to [0016], a description of a patent application "functional physiologically active negative ion air generated using weathered coral" filed on Dec. 24, 1998 by the present applicant is described. It is almost the same as the text of the specification, but is described again here because the application is different. Thus, air ions include positive ions and negative ions. Positive ion air is abundant in urban spaces and polluted air, and in many places migraine, autonomic imbalance, insomnia, depression, anxiety,
Although neurosis and sympathetic nervous activity excitement occur, it is said that there is a feeling of exhilaration, deep sleep, an increase in parasympathetic nervous activity, an increase in learning effect, etc. in the space of negative ion air. Such air ions are produced by a Leonard effect, a corona discharge effect, an electron discharge method, tourmaline adsorption fiber, or the like.

[0003] When a water droplet is split into small water droplets by a strong external force, there is a method in which the water droplet itself is ionized by the Leonard effect into positive ions, and the air around the water droplet is negatively ionized.
When raw water is contaminated, it has the disadvantage of spraying bacteria and the like into the air. The corona discharge method is
Although a high voltage is applied to the negative electrode to generate positive and negative ions by plasma, there is a problem in that ozone and nitrogen oxide harmful to the human body are generated as by-products.
The electron emission type is similar to the corona discharge effect, and has no positive electrode and emits an electron beam into the air.

[0004]

The physiologically good effects of negative ions include the suppression of excited sympathetic nervous activity, the increased vagal activity, and the sleep action by promoting the secretion of substances in the brain, which are common in the frail elderly and hypertension. , Fatigue recovery, analgesic,
Diuretic action is known, and many such negative ion air generating methods and the like have been introduced. Thus, ozone and nitrogen oxide harmful to the human body are mixed in the negative ions by the corona discharge method described above. In addition, negative ions generated by water droplet splitting by high-speed fan injection based on the Leonard effect have disadvantages such as the complexity of the structure of the method and the risk of contamination of raw water.

It is also necessary to consider that the negative ions existing in the natural world, especially near the waterfall, in the forest, and the so-called negative ions that are artificially created are different. APKrueger
Has expressed air ions by four molecular formulas.
(International Journal of Bioneterology, vol.16, n
o.4, pp313-322, 1972). That is, the cation is H ⁺ (H
_{2 O) n (H 3 O} ) + (H 2 O) n, the negative ions are _{^{O 2 + (H 2 O)}} n, OH - (H 2 O) n
And divided. Here, (H ₂ O) _n is a water ion cluster, and H ⁻ , O ₂ ⁻ , OH ^{−, and the} like are derived from the dissociation of water ions, and are so-called air ions. It is considered that the corona discharge or the forced water droplet splitting method was used as the ion dissociation method.

The method of creating active ionic air by splitting water droplets using the Leonard effect that does not generate ozone, a substance harmful to the human body, and the physiological activity of its negative ions are as follows:
These are disclosed in JP-A-4-141179 (production of anions and an apparatus therefor) and JP-A-8-308914 (active air with high humidity). However, although the negative ions created by these methods are described as bioactive, they do not provide any mechanism for causing biological or physiological activities as described by APKrueger.

[0007]

SUMMARY OF THE INVENTION In view of the above technical problems, a method for producing a functional physiologically active negative ion air generated by using weathered coral according to the present invention has been described. It produces a substance that plays an important role in maintaining the acid-base equilibrium of blood, ie, negative ion air that activates physiological functions. Although this section is usually brief, it is considered that the present invention is difficult to understand because it is an unprecedented breakthrough. So, the related technology is also described in detail below.

In order to achieve the above object, a method for producing a functional physiologically active negative ion air generated by using weathered coral according to the present invention comprises the steps of applying pressure and frictional force to calcium carbonate, water and air by weathered coral powder. It is intended to produce functional physiologically active negative ion air by applying a fine external force such as vibration force or vibration force.

The operation and manufacturing method will be described below.
Bell. First, the calcium carbonate contained in weathered coral powder
More CaCO_Three ← → Ca^2- + CO_Three ^2- (formula
Dissolved into calcium ion and calcium carbonate as in 1)
Let go. In an aqueous solution, between the water molecules and hydrogen ions,
H_TwoO ← → H⁺ + OH^- (Equation 2)
Always holds true. External motions such as pressure, frictional force and vibration
Due to the energy, water molecules form a water cluster structure,
Ion cluster complex with multiple molecules of water molecules
As (H_TwoO) (H_TwoO)_n ← → H⁺(H_TwoO)
_n + OH⁺(H _TwoO)_n (Equation 3) This
Here, (H_TwoO)_n Is called a physiologically active negative ion.

As shown in the formula 1, when the generated carbon dioxide gas is dissolved in an aqueous solution, it is reversibly integrated with H ₂ O to form carbon dioxide (H ₂ C).
O ₃ ), which is reversibly dissociated as an acid into a hydrogen ion (H ⁺ ) and a bicarbonate ion (HCO ₃ ⁺ ) as shown in (Formula 4). Here, CO ₂ and H ₂ CO ₃ are put together,
Dissociated carbonate HCO ₃ ⁺ is defined as bound carbonate, ie, a functionally active ion. CO ₂ + H ₂ O ← → H ₂ CO ₃
← → HCO ₃ ⁺ + H ⁺ (Equation 4)

[0011] Dissociation of the second stage of carbonic acid, HCO ₃ ⁺ becomes an acid, is carried out as ^{_{HCO 3 + ← → H + CO}} 3 2+ ( Equation 5). With the above ion configuration, the thermal dissociation constant (Kl) of the first stage of carbonic acid is Kl =
[(H ⁺ ) (HCO ₃ ⁺ )] / [CO ₂ )] pH = p
Kl + log [(HCO ₃ ⁺ )] / [(CO ₂ )]
(Equation 6)

When H ⁺ increases due to the addition of a mountain to the aqueous solution, OH ⁺ decreases. If alkali is added and OH ⁺ increases, H ⁺ decreases and equilibrates in that state. The concentration (pH value) of a physiological aqueous solution of the human body is -log [H
⁺ ] Or pK + log {[HCO ₃ ⁺ ] / [CO
₂ ]｝, for example, the average pH value of blood is about 7.4.

In order to constantly maintain the pH value in a living body, the living body is provided with various pH buffer systems. The main buffer system in blood and interstitial fluid is CO ₂ + H ₂ O
← → HCO ₃ ^{++ By} saying that it is a H ⁺ system,
Food intake and substances biological functional homeostasis by metabolism, i.e. acid - base equilibrium ^{_{properties, HCO 3 +, H +,}} CO 2, O
It is called a functional bioactive ion because it is regulated by an ion called H ⁺ . It is an object of the present invention to generate such functional physiologically active negative ions in the air to maintain the homeostasis of the human body.

The present invention uses weathered coral powder as a means for generating functional physiologically active ions. Weathered coral powder contains about 35 to 45% of calcium carbonate. When calcium carbonate (CaCO ₃ ) is subjected to minute external force (pressure, friction, etc.) of water, calcium ions (Ca ²⁺ )
And dissociate with carbonate ions (CO ₃ ⁺ ), and carbonate ions become water (H
When reacted with O ₂ ), bicarbonate (HCO ₃ ), which is a bioactive ion, and negative ion (O,
H ^-) is generated.

The generation of such negative ions (OH ⁻ ) is caused by reducing the number of hydrogen ions (H ⁻ ) dissociated from water ions, and thereby the number of negative ions, which are biologically active ions and biologically active ions, is reduced in the air. To increase. If this reaction takes place in a liquid, the liquid becomes alkaline. It can be seen that the increase amount and the rate of the functional physiologically active negative ion depend on the mixing ratio of impurities, minute external force, and the amount of water (humidity) in calcium carbonate.

In the present invention, calcium carbonate, which has been detected from weathered coral powder, is calcined at 120 to 1000 ° C. to increase the purity and to be granulated. Examples of the minute external force include passive frictional force and pressure, and ultrasonic vibration.

Hereinafter, a specific configuration of the method for producing a functional physiologically active negative ion air generated using coral according to the present invention will be described in detail. First, the configuration of the invention described in claim 1 of the present invention will be described. According to the present invention, first, a sintering means sinters weathered coral powder to form coral calcium carbonate (CaCO2).
₃ ) Create.

Next, the dissociation means separates the coral calcium carbonate (CaCO ₃ ) from the above-mentioned firing means into calcium ions (Ca ²⁺ ) and carbonate ions (CO ₃ ² ) by a fine external force (pressure, wind force, frictional force, etc.). ^- ) Dissociate with. The moisture-reactive means, moisture (H ₂ O) is reacted warm衝塩groups in the air above the carbonate ions - physiology bicarbonate are active ion (H ₂
CO ₃ ) and hydroxyl ion (OH ⁻ ) which is a physiologically active ion-negative ion are obtained.

Next, the configuration of the invention according to claim 2 of the method for producing a functional physiologically active negative ion air generated by using coral according to the present invention will be described. According to the present invention, the weathered coral is fired at 100 to 1000 ° C., reacts with air and water, and comprises moisture-containing negative ion air (OH ⁻ (H ₂ O) n).

[0020]

BEST MODE FOR CARRYING OUT THE INVENTION A general embodiment of a method for producing functional physiologically active negative ion air generated using coral according to the present invention will be described below. The firing means fires the weathered coral powder at 100 to 1,000 ° C. to produce coral calcium carbonate (CaCO ₃ ). Next, the dissociation means converts the coral calcium carbonate (CaCO ₃ ) from the above-mentioned baking means into calcium ions (Ca ²⁺ ) and carbonate ions (CO ₃
Dissociate in ^2- ).

Then, the water reaction means reacts the carbonate ion with water (H ₂ O) in the air to form a warming base—bicarbonate (H ₂ CO ₃ ), which is a physiologically active ion, and physiological activity. Hydroxide ion (OH ⁻ ) which is an ion-negative ion is obtained.

[0022]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The method for producing a physiologically active negative ion air generated by using coral according to the present invention will be described in detail with reference to the accompanying drawings using specific embodiments. First, as shown in the block diagram shown in FIG. 1, weathering coral powder is fired at 100 to 1,000 ° C. by firing means 1 to produce coral calcium carbonate (CaCO ₃ ) 2.

Next, in the dissociation means 3, the coral calcium carbonate (CaCO ₃ ) 2 from the sintering means 1 is subjected to minute external force (pressure, wind force, frictional force, etc.) 4 (the piston 4a in FIG. Are dissociated by calcium ions (Ca ²⁺ ) 5 and carbonate ions (CO ₃ ^2- ) 6 by the spray button 4b in FIG. 4 and the ultrasonic transmitter 4c in FIG.

Then, the above-mentioned carbonate ion 6 is reacted with water (H ₂ O) in the air by the water reaction means 7 to thereby form bicarbonate (H ₂ CO ₃ ) which is a warming base-physiologically active ion. 8 and bioactive ions - hydroxyl ions are negative ions I (OH ^-)
Get 9. The hydroxide ions (OH ^-), or negative if the ion I is by generating lots, will reduce the dissociated hydrogen ions from water molecule (H ^+), negative ions are physiology active ions in the air The number increases.

FIGS. 2 to 4 show specific embodiments of the apparatus for performing the method for producing negative ion air of the present invention. First, FIG.
Is of the piston type. This is to put the coral calcium carbonate 2 fired as described above in a cylinder S, drive a piston P in the cylinder S up and down by the rod R, and inject the negative ions I from an injection port O. is there. FIG. 3 shows a spray type. For this, the calcined coral calcium carbonate 2 and the compressed gas G are put into the spray can C as described above, and the spray button B is pressed to eject the negative ions I. Alternatively, without the compressed gas G, the spray button B is pressed to inject the negative ions I at that pressure. 4 is an ultrasonic type. This means that the coral calcium carbonate 2 and the ultrasonic transmitter U fired as described above are put in the housing H, and the calcium carbonate water dropped through the valve V is
The ultrasonic transmitter U vibrates to generate negative ions I, and the fan F injects the negative ions from the injection port O.

The test data of the above are shown below.
Tables 1, 2, and 3 show data on the number of negative ions in coral calcium water, and are shown in FIGS. 5, 6, 7, 8, 9, 10, 1.
1, 12, and 13 are data on which the data is based.

[0027]

[Table 1]

[0028]

[Table 2]

[0029]

[Table 3]

Tables 4, 5, and 6 show data on the number of negative ions of coral calcium PW (powder).
4,15,16,17,18,19,20,21,22
Is the data on which it is based.

[0031]

[Table 4]

[0032]

[Table 5]

[0033]

[Table 6]

[0034]

As described above, the functional physiologically active negative ion air generated by using the weathered coral according to the present invention solves the above-mentioned problems and produces a great effect as shown in the above data. Was. It also had a deodorizing effect.

[Brief description of the drawings]

FIG. 1 is a block diagram showing one embodiment of a method for producing a functional physiologically active negative ion air generated using weathered coral according to the present invention.

FIG. 2 is a partial cross-sectional side view of an embodiment of a piston type apparatus used in a method for producing a functional physiologically active negative ion air generated using weathered coral according to the present invention.

3 shows a side sectional view of the spray-type embodiment of FIG.

FIG. 4 shows a side sectional view of the ultrasonic embodiment of FIG. 2;

FIG. 5 is a bar graph showing a part of the data of Table 1.

FIG. 6 shows another bar of the data of Table 1 and a bar graph thereof.

FIG. 7 is a bar graph of yet another portion of the data of Table 1.

FIG. 8 is a bar graph showing a part of the data of Table 2.

FIG. 9 is another bar chart of another portion of the data of Table 2.

FIG. 10 is a bar graph of yet another portion of the data of Table 2.

FIG. 11 is a bar graph showing a part of the data of Table 3.

FIG. 12 is another bar graph of another part of the data of Table 3.

FIG. 13 is a bar graph of yet another portion of the data of Table 3.

FIG. 14 is a line graph showing a part of the data shown in Table 4;

FIG. 15 shows another part of the data of Table 4 showing a line graph thereof.

FIG. 16 shows yet another portion of the data of Table 4 showing a line graph thereof.

FIG. 17 is a line graph showing a part of the data shown in Table 5;

18 is another line of the data of Table 5 showing a line graph thereof. FIG.

FIG. 19 shows yet another portion of the data of Table 5 showing a line graph thereof.

FIG. 20 is a line graph showing a part of the data shown in Table 6;

FIG. 21 shows another portion of the data of Table 6 showing a line graph thereof.

FIG. 22 is a line graph of yet another portion of the data of Table 6.

[Description of Signs] 1 Means for baking weathered coral powder 2 Coral calcium carbonate 3 Fine external force 4 Dissociation means 5 Calcium ion 6 Carbonate 7 Moisture reaction means 8 Bicarbonate 9 Hydroxide ion

Claims (2)

[Claims] Claims 1. A weathered coral powder is fired by firing means to form coral calcium carbonate (CaCO ₃ ), and said coral calcium carbonate (CaCO ₃ ) is subjected to a fine external force (pressure, wind force, frictional force, etc.) by dissociation means. Calcium ion (Ca ²⁺ )
Is dissociated with carbonate ions (CO ₃ ²⁻ ), and the carbonate ions are reacted with water (H ₂ O) in the air by a water reaction means to form a warming base—bicarbonate (H ₂ O), which is a physiologically active ion ₂ CO ₃₎ and the physiologically active ions - hydroxyl ions are negative ions (OH ^-)
A method for producing functional physiologically active negative ion air generated using weathered coral, comprising: Wherein the _{^{- ((H 2 O) n}} OH), in which more made wherein weathering corals, calcined at 100 to 1000 ° C., reacted with air and water, the water with negative ions air A method for producing a functional physiologically active negative ion air generated using the weathered coral according to claim 1.