JP2000158585A5 - Manufacturing method of laminated metal plate and laminated metal plate - Google Patents

Manufacturing method of laminated metal plate and laminated metal plate Download PDF

Info

Publication number
JP2000158585A5
JP2000158585A5 JP1998340359A JP34035998A JP2000158585A5 JP 2000158585 A5 JP2000158585 A5 JP 2000158585A5 JP 1998340359 A JP1998340359 A JP 1998340359A JP 34035998 A JP34035998 A JP 34035998A JP 2000158585 A5 JP2000158585 A5 JP 2000158585A5
Authority
JP
Japan
Prior art keywords
metal plate
film
laminating
melting point
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1998340359A
Other languages
Japanese (ja)
Other versions
JP2000158585A (en
Filing date
Publication date
Application filed filed Critical
Priority to JP10340359A priority Critical patent/JP2000158585A/en
Priority claimed from JP10340359A external-priority patent/JP2000158585A/en
Publication of JP2000158585A publication Critical patent/JP2000158585A/en
Publication of JP2000158585A5 publication Critical patent/JP2000158585A5/en
Pending legal-status Critical Current

Links

Description

（６）前記（１）〜（５）において、フィルムが少なくとも２層以上から構成され、非ラミネート面とラミネート面を形成する各層の固有粘度差が０．０１〜０．５であることを特徴とするラミネート金属板の製造方法。
（７）二軸延伸ポリエステルフィルムを金属板の少なくとも片面にラミネートする際に、ラミネート開始時の金属板の温度Ｔ 0 をフィルムの融点Ｔ f 以上、ラミネートロールニップ出側の金属板の温度Ｔ 1 をフィルムの融点Ｔ f 以下にするとともに、更に下式で定義されるラミネートインデックスＫを１〜２０ｍｓｅｃの範囲内にしてラミネートすることを特徴とするラミネート金属板の製造方法。
Ｋ＝（Ｔ 0 −Ｔ f ）×ｔ／（Ｔ 0 −Ｔ 1 ）
但し、ｔ：ニップ時間
（８）二軸延伸ポリエステルフィルムを金属板の少なくとも片面にラミネートする際に、ラミネート開始時の金属板の温度Ｔ 0 をフィルムの融点Ｔ f 以上、ラミネートロールニップ出側の金属板の温度Ｔ 1 をフィルムの融点Ｔ f 以下にするとともに、更に下式で定義されるラミネートインデックスＫを１〜２０ｍｓｅｃの範囲内にしてラミネートして得られるラミネート金属板。
Ｋ＝（Ｔ 0 −Ｔ f ）×ｔ／（Ｔ 0 −Ｔ 1 ）
但し、ｔ：ニップ時間
（９）固体高分解能ＮＭＲによる構造解析における１、４位のベンゼン環炭素の緩和時間Ｔ１ρが１５０ｍｓｅｃ以上である二軸延伸ポリエステルフィルムを金属板の少なくとも片面にラミネートする際に、ラミネート開始時の金属板の温度Ｔ 0 をフィルムの融点Ｔ f 以上、ラミネートロールニップ出側の金属板の温度Ｔ 1 をフィルムの融点Ｔ f 以下にするとともに、更に下式で定義されるラミネートインデックスＫを１〜２０ｍｓｅｃの範囲内にしてラミネートして得られるラミネート金属板。
Ｋ＝（Ｔ 0 −Ｔ f ）×ｔ／（Ｔ 0 −Ｔ 1 ）
但し、ｔ：ニップ時間
(6) In the above (1) to (5), the film is composed of at least two layers, and the intrinsic viscosity difference between the layers forming the non-laminated surface and the laminated surface is 0.01 to 0.5. A method for manufacturing a laminated metal plate.
(7) When laminating a biaxially stretched polyester film on at least one side of a metal plate, the temperature T 0 of the metal plate at the start of laminating is equal to or higher than the melting point T f of the film, and the temperature T 1 of the metal plate on the exit side of the laminating roll nip. A method for producing a laminated metal plate, which comprises setting the temperature to T f or less of the melting point of the film and further setting the laminate index K defined by the following formula within the range of 1 to 20 msec.
K = (T 0 −T f ) × t / (T 0 −T 1 )
However, t: nip time
(8) When laminating a biaxially stretched polyester film on at least one side of a metal plate, the temperature T 0 of the metal plate at the start of laminating is equal to or higher than the melting point T f of the film, and the temperature T 1 of the metal plate on the exit side of the laminating roll nip. A laminated metal plate obtained by setting the temperature to T f or less of the melting point of the film and further setting the laminate index K defined by the following formula within the range of 1 to 20 msec.
K = (T 0 −T f ) × t / (T 0 −T 1 )
However, t: nip time
(9) When a biaxially stretched polyester film having a relaxation time T1ρ of benzene ring carbon at positions 1 and 4 in structural analysis by solid high-resolution NMR having a relaxation time T1ρ of 150 msec or more is laminated on at least one side of a metal plate, the metal at the start of lamination. The temperature T 0 of the plate is set to the melting point T f or more of the film, the temperature T 1 of the metal plate on the exit side of the laminate roll nip is set to the melting point T f or less of the film, and the laminate index K defined by the following formula is set to 1 to 20 msec. Laminated metal plate obtained by laminating within the range of.
K = (T 0 −T f ) × t / (T 0 −T 1 )
However, t: nip time

Claims (9)

固体高分解能ＮＭＲによる構造解析における１、４位のベンゼン環炭素の緩和時間Ｔ１ρが１５０ｍｓｅｃ以上である二軸延伸ポリエステルフィルムを金属板の少なくとも片面にラミネートする際に、ラミネート開始時の金属板の温度Ｔ0をフィルムの融点Ｔf以上、ラミネートロールニップ出側の金属板の温度Ｔ1をフィルムの融点Ｔf以下にするとともに、更に下式で定義されるラミネートインデックスＫを１〜２０ｍｓｅｃの範囲内にしてラミネートすることを特徴とするラミネート金属板の製造方法。
Ｋ＝（Ｔ0−Ｔf）×ｔ／（Ｔ0−Ｔ1）
但し、ｔ：ニップ時間When laminating a biaxially stretched polyester film having a relaxation time T1ρ of benzene ring carbon at positions 1 and 4 of 150 msec or more in structural analysis by solid high-resolution NMR on at least one side of the metal plate, the temperature of the metal plate at the start of lamination T 0 the film melting point T f or more, the laminate roll nip exit-side temperature T 1 of the metal plate while below the melting point T f of the film, further a range of 1~20msec laminate index K which is defined by the following formula A method for producing a laminated metal plate, characterized in that laminating.
K = (T 0 −T f ) × t / (T 0 −T 1 )
Where t: nip time ニップ時間ｔが０．００５〜０．０５ｓｅｃの範囲内であることを特徴とする請求項１に記載のラミネート金属板の製造方法。  The method for producing a laminated metal plate according to claim 1, wherein the nip time t is in the range of 0.005 to 0.05 sec. フィルムを構成するポリエステル単位の９０モル％以上がエチレンテレフタレート単位であることを特徴とする請求項１または請求項２に記載のラミネート金属板の製造方法。  The method for producing a laminated metal sheet according to claim 1 or 2, wherein 90 mol% or more of the polyester units constituting the film are ethylene terephthalate units. フィルムを構成するポリエステル単位の９５モル％以上がエチレンテレフタレート単位であることを特徴とする請求項１〜請求項３の何れかに記載のラミネート金属板の製造方法。  The method for producing a laminated metal sheet according to any one of claims 1 to 3, wherein 95 mol% or more of the polyester units constituting the film are ethylene terephthalate units. フィルムの面配向係数が０．１４以下であることを特徴とする請求項１〜請求項４のいずれかに記載のラミネート金属板の製造方法。  The method for producing a laminated metal plate according to any one of claims 1 to 4, wherein the plane orientation coefficient of the film is 0.14 or less. フィルムが少なくとも２層以上から構成され、非ラミネート面とラミネート面を形成する各層の固有粘度差が０．０１〜０．５であることを特徴とする請求項１〜請求項５の何れかに記載のラミネート金属板の製造方法。  6. The film according to claim 1, wherein the film is composed of at least two layers, and the intrinsic viscosity difference between each layer forming the non-laminated surface and the laminated surface is 0.01 to 0.5. The manufacturing method of the laminated metal plate of description. 二軸延伸ポリエステルフィルムを金属板の少なくとも片面にラミネートする際に、ラミネート開始時の金属板の温度ＴWhen laminating a biaxially stretched polyester film on at least one side of a metal plate, the temperature T of the metal plate at the start of lamination 00 をフィルムの融点ＴThe melting point T of the film ff 以上、ラミネートロールニップ出側の金属板の温度ＴThe temperature T of the metal plate on the exit side of the laminate roll nip 11 をフィルムの融点ＴThe melting point T of the film ff 以下にするとともに、更に下式で定義されるラミネートインデックスＫを１〜２０ｍｓｅｃの範囲内にしてラミネートすることを特徴とするラミネート金属板の製造方法。A method for producing a laminated metal plate, comprising: laminating with a laminate index K defined by the following formula within a range of 1 to 20 msec.
Ｋ＝（ＴK = (T 00 −Ｔ-T ff ）×ｔ／（Ｔ) × t / (T 00 −Ｔ-T 11 ）)
但し、ｔ：ニップ時間Where t: nip time 二軸延伸ポリエステルフィルムを金属板の少なくとも片面にラミネートする際に、ラミネート開始時の金属板の温度ＴWhen laminating a biaxially stretched polyester film on at least one side of a metal plate, the temperature T of the metal plate at the start of lamination 00 をフィルムの融点ＴThe melting point T of the film ff 以上、ラミネートロールニップ出側の金属板の温度ＴThe temperature T of the metal plate on the exit side of the laminate roll nip 11 をフィルムの融点ＴThe melting point T of the film ff 以下にするとともに、更に下式で定義されるラミネートインデックスＫを１〜２０ｍｓｅｃの範囲内にしてラミネートして得られるラミネート金属板。A laminated metal plate obtained by laminating the laminate index K defined by the following formula within the range of 1 to 20 msec.
Ｋ＝（ＴK = (T 00 −Ｔ-T ff ）×ｔ／（Ｔ) × t / (T 00 −Ｔ-T 11 ）)
但し、ｔ：ニップ時間Where t: nip time 固体高分解能ＮＭＲによる構造解析における１、４位のベンゼン環炭素の緩和時間Ｔ１ρが１５０ｍｓｅｃ以上である二軸延伸ポリエステルフィルムを金属板の少なくとも片面にラミネートする際に、ラミネート開始時の金属板の温度ＴWhen laminating a biaxially stretched polyester film having a relaxation time T1ρ of benzene ring carbon at positions 1 and 4 of 150 msec or more in structural analysis by solid high-resolution NMR on at least one side of the metal plate, the temperature of the metal plate at the start of lamination T 00 をフィルムの融点ＴThe melting point T of the film ff 以上、ラミネートロールニップ出側の金属板の温度ＴThe temperature T of the metal plate on the exit side of the laminate roll nip 11 をフィルムの融点ＴThe melting point T of the film ff 以下にするとともに、更に下式で定義されるラミネートインデックスＫを１〜２０ｍｓｅｃの範囲内にしてラミネートして得られるラミネート金属板。A laminated metal plate obtained by laminating the laminate index K defined by the following formula within the range of 1 to 20 msec.
Ｋ＝（ＴK = (T 00 −Ｔ-T ff ）×ｔ／（Ｔ) × t / (T 00 −Ｔ-T 11 ）)
但し、ｔ：ニップ時間Where t: nip time
JP10340359A 1998-11-30 1998-11-30 Manufacture of laminated plate Pending JP2000158585A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10340359A JP2000158585A (en) 1998-11-30 1998-11-30 Manufacture of laminated plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10340359A JP2000158585A (en) 1998-11-30 1998-11-30 Manufacture of laminated plate

Publications (2)

Publication Number Publication Date
JP2000158585A JP2000158585A (en) 2000-06-13
JP2000158585A5 true JP2000158585A5 (en) 2005-06-16

Family

ID=18336194

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10340359A Pending JP2000158585A (en) 1998-11-30 1998-11-30 Manufacture of laminated plate

Country Status (1)

Country Link
JP (1) JP2000158585A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002072346A1 (en) * 2001-03-14 2002-09-19 Jfe Steel Corporation Film-laminated metal sheet for container

Similar Documents

Publication Publication Date Title
US4734335A (en) Multilayer film formed of polyester and having a core layer suitable for thermoplastic embossing
US20110250468A1 (en) Metal Foil with Carrier
JP2630159B2 (en) Method for producing embossed decorative sheet
JP6678029B2 (en) Support substrate with circuit formation layer, support substrate with double-sided circuit formation layer, multilayer laminate, method for manufacturing multilayer printed wiring board, and multilayer printed wiring board
TW201029841A (en) Release film
JP2000158585A5 (en) Manufacturing method of laminated metal plate and laminated metal plate
US5137775A (en) Embossable laminates
WO2004028794A2 (en) Dimensionally stable laminate with removable web carrier and method of manufacture
JP2833484B2 (en) Decorative sheet
JP2007109694A (en) Process for producing one-side flexible metal laminated plate
JP2008526684A5 (en)
JP2002064258A (en) Method of manufacturing heat-resistant flexible board
JP4406728B2 (en) Laminated film for steel sheet
JPH08224849A (en) Manufacture of laminated sheet
JP2008074037A (en) Manufacturing process of heat-resistant flexible metal laminate
JPH01178445A (en) Composite light screening material
JP2002064259A (en) Method of manufacturing heat-resistant flexible board
JPS6027402A (en) Rolled steel foil
JPH0470139B2 (en)
JPS6217232Y2 (en)
JPH028751Y2 (en)
JPH01318289A (en) Manufacture of copper clad laminated board for multilayer printed board
JPS6032997Y2 (en) Composite with embossed pattern
JPH11245293A (en) Method for roughening surface of thermoplastic resin sheet
JPS60192624A (en) Manufacture of metallic plastic composite material