JP2000154493A5 - - Google Patents
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- JP2000154493A5 JP2000154493A5 JP1999325061A JP32506199A JP2000154493A5 JP 2000154493 A5 JP2000154493 A5 JP 2000154493A5 JP 1999325061 A JP1999325061 A JP 1999325061A JP 32506199 A JP32506199 A JP 32506199A JP 2000154493 A5 JP2000154493 A5 JP 2000154493A5
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- polymer
- ethylenically unsaturated
- paper substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920000642 polymer Polymers 0.000 description 12
- 239000000178 monomer Substances 0.000 description 10
- 239000000123 paper Substances 0.000 description 8
- 239000000758 substrate Substances 0.000 description 7
- 239000002253 acid Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 125000005907 alkyl ester group Chemical group 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- 239000011087 paperboard Substances 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 229920000126 Latex Polymers 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N 2-methyl-2-propenoic acid methyl ester Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
Description
【特許請求の範囲】
【請求項１】 ａ）１から１００重量部の、少なくとも１種の（メタ）アクリル酸のＣ１２からＣ４０アルキルエステル、ｂ）０から９９重量部の少なくとも１種のエチレン性不飽和モノマー、およびｃ）０から１５重量部の少なくとも１種のエチレン性不飽和酸含有モノマーまたはそれらの塩、を重合単位として有するポリマーを、紙基体に施用する事を含む、紙基体の改質方法。
【請求項２】 ポリマーが、重合単位として、
ａ）５から９５重量部の、少なくとも１種の（メタ）アクリル酸のＣ１２からＣ４０アルキルエステル、ｂ）４から９４重量部の少なくとも１種のエチレン性不飽和モノマー、およびｃ）１から１０重量部の少なくとも１種のエチレン性不飽和酸含有モノマーまたはそれらの塩、を含む、請求項１記載の方法。
【請求項３】 ポリマーが、重合単位として、
ａ）１０から９０重量部の、少なくとも１種の（メタ）アクリル酸のＣ１２からＣ４０アルキルエステル、ｂ）９から８９重量部の少なくとも１種のエチレン性不飽和モノマー、およびｃ）１から５重量部の少なくとも１種のエチレン性不飽和酸含有モノマーまたはそれらの塩、を含む、請求項１記載の方法。
【請求項４】 ポリマーがさらに架橋剤を含む、請求項１記載の方法。
【請求項５】 ポリマーがさらにフィラーを含む、請求項１記載の方法。
【請求項６】 紙基体が厚紙、板紙、波形板紙、クラフト紙、およびリームラップから選択される、請求項１記載の方法。
【請求項７】 ポリマーが５０から９９重量部のラテックスと混合され、この混合物が紙基体に施用される、請求項１記載の方法。
【請求項８】 ポリマーが、重合単位として、
ａ）５から９５重量部の、少なくとも１種の（メタ）アクリル酸のＣ１２からＣ４０アルキルエステル、ｂ）４から９４重量部の少なくとも１種のエチレン性不飽和モノマー、およびｃ）１から１０重量部の少なくとも１種のエチレン性不飽和酸含有モノマーまたはそれらの塩、を含む、請求項７記載の方法。
【請求項９】 ポリマーが、重合単位として、
ａ）１０から９０重量部の、少なくとも１種の（メタ）アクリル酸のＣ１２からＣ４０アルキルエステル、ｂ）９から８９重量部の少なくとも１種のエチレン性不飽和モノマー、およびｃ）１から５重量部の少なくとも１種のエチレン性不飽和酸含有モノマーまたはそれらの塩、を含む、請求項７記載の方法。
【請求項１０】 ポリマーがさらに架橋剤を含む、請求項７記載の方法。
【請求項１１】 ポリマーがさらにフィラーを含む、請求項７記載の方法。
【請求項１２】 ラテックスが、ブチルアクリレート／メチルメタアクリレート、ブチルアクリレート／スチレン、スチレン／ブタジエン、および酢酸ビニルラテックスからなる群から選択される、請求項７記載の方法。
【請求項１３】 紙基体が厚紙、板紙、波形板紙、クラフト紙、およびリームラップから選択される、請求項７記載の方法。
【請求項１４】 請求項１記載のポリマーで被覆された紙基体を含む物品。
【請求項１５】 請求項７記載のポリマーで被覆された紙基体を含む物品。
[Claims]
1. A a) 1 to 100 parts by weight of at least one (meth) C 40 alkyl esters of C 12 acrylic acid, b) at least one ethylenically unsaturated monomer of 0-99 parts by weight, And c) A method for modifying a paper substrate, which comprises applying a polymer having 0 to 15 parts by weight of at least one ethylenically unsaturated acid-containing monomer or a salt thereof as a polymerization unit to the paper substrate.
2. The polymer is used as a polymerization unit.
a) 5 to 95 parts by weight of at least one (meth) C 40 alkyl esters of C 12 acrylic acid, b) 4 from 94 parts by weight of at least one ethylenically unsaturated monomer, and c) from 1 The method according to claim 1, which comprises 10 parts by weight of at least one ethylenically unsaturated acid-containing monomer or a salt thereof.
3. The polymer is used as a polymerization unit.
a) 10 and 90 parts by weight of at least one (meth) C 40 alkyl esters of C 12 acrylic acid, b) 9 from 89 parts by weight of at least one ethylenically unsaturated monomer, and c) from 1 The method according to claim 1, which comprises 5 parts by weight of at least one ethylenically unsaturated acid-containing monomer or a salt thereof.
4. The method of claim 1, wherein the polymer further comprises a cross-linking agent.
5. The method of claim 1, wherein the polymer further comprises a filler.
6. The method of claim 1, wherein the paper substrate is selected from thick paper, paperboard, corrugated paperboard, kraft paper, and ream wrap.
7. The method of claim 1, wherein the polymer is mixed with 50 to 99 parts by weight of latex and the mixture is applied to a paper substrate.
8. The polymer is used as a polymerization unit.
a) 5 to 95 parts by weight of at least one (meth) C 40 alkyl esters of C 12 acrylic acid, b) 4 from 94 parts by weight of at least one ethylenically unsaturated monomer, and c) from 1 The method according to claim 7, which comprises 10 parts by weight of at least one ethylenically unsaturated acid-containing monomer or a salt thereof.
9. The polymer is used as a polymerization unit.
a) 10 and 90 parts by weight of at least one (meth) C 40 alkyl esters of C 12 acrylic acid, b) 9 from 89 parts by weight of at least one ethylenically unsaturated monomer, and c) from 1 The method according to claim 7, which comprises 5 parts by weight of at least one ethylenically unsaturated acid-containing monomer or a salt thereof.
10. The method of claim 7, wherein the polymer further comprises a cross-linking agent.
11. The method of claim 7, wherein the polymer further comprises a filler.
12. The method of claim 7, wherein the latex is selected from the group consisting of butyl acrylate / methyl methacrylate, butyl acrylate / styrene, styrene / butadiene, and vinyl acetate latex.
13. The method of claim 7, wherein the paper substrate is selected from cardboard, paperboard, corrugated paperboard, kraft paper, and ream wrap.
14. An article comprising a paper substrate coated with the polymer according to claim 1.
15. An article comprising a paper substrate coated with the polymer according to claim 7.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10865498P | 1998-11-16 | 1998-11-16 | |
| US60/108654 | 1998-11-16 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2000154493A JP2000154493A (en) | 2000-06-06 |
| JP2000154493A5 true JP2000154493A5 (en) | 2006-12-14 |
| JP4684380B2 JP4684380B2 (en) | 2011-05-18 |
Family
ID=22323385
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP32506199A Expired - Fee Related JP4684380B2 (en) | 1998-11-16 | 1999-11-16 | Method for modifying paper substrate |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1010807B1 (en) |
| JP (1) | JP4684380B2 (en) |
| CN (1) | CN1246525C (en) |
| AU (1) | AU5826599A (en) |
| BR (1) | BR9905626A (en) |
| DE (1) | DE69927775T2 (en) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6884468B1 (en) | 2003-10-27 | 2005-04-26 | Basf Ag | Method of making a paper coating using a blend of a vinyl aromatic-acrylic polymer dispersion with a vinyl aromatic-diene polymer dispersion |
| KR100563238B1 (en) | 2004-12-23 | 2006-03-21 | 하기룡 | Synthesis of acrylic warp size copolymers with stearyl methacrylate(sma)by miniemulsion polymerization |
| US20070232743A1 (en) * | 2006-03-30 | 2007-10-04 | Mario Laviolette | Method of forming a vapor impermeable, repulpable coating for a cellulosic substrate and a coating composition for the same |
| RU2518968C2 (en) * | 2008-11-07 | 2014-06-10 | Премиум Борд Финланд Ой | Paper or cardboard with coating, recyclable, and methods of their manufacture |
| CN102428135A (en) * | 2009-05-18 | 2012-04-25 | 汉高股份有限及两合公司 | Stabilized liquid adhesive concentrate |
| PT2714391E (en) * | 2011-05-30 | 2015-06-25 | Basf Se | Paper and cardboard packaging featuring a barrier coating comprising a polymer mixture |
| JP6028175B2 (en) * | 2013-04-26 | 2016-11-16 | 東洋インキＳｃホールディングス株式会社 | Coating agent for food packaging sheet and food packaging sheet. |
| JP6213290B2 (en) * | 2014-02-17 | 2017-10-18 | 王子ホールディングス株式会社 | Water and oil repellent paper and method for producing water and oil repellent paper |
| WO2016087597A1 (en) * | 2014-12-04 | 2016-06-09 | Basf Se | Paper or cardboard equipped with a barrier layer |
| US10988630B2 (en) | 2014-12-19 | 2021-04-27 | Certainteed Corporation | Coating compositions for building materials and coated building material substrates |
| CN105178116A (en) * | 2015-08-31 | 2015-12-23 | 福建省龙创工业设计有限公司 | Waterproof corrugated paperboard |
| JP6778041B2 (en) * | 2016-07-27 | 2020-10-28 | ライオン・スペシャリティ・ケミカルズ株式会社 | Water repellent for paper and paper manufacturing method |
| CN109844221A (en) * | 2016-08-09 | 2019-06-04 | 维实洛克Mwv有限责任公司 | The cardboard of oil resistant, grease resistance and moisture-proof |
| US10704200B2 (en) * | 2016-11-17 | 2020-07-07 | Westrock Mwv, Llc | Oil and grease resistant paperboard |
| WO2019006247A1 (en) | 2017-06-30 | 2019-01-03 | Certainteed Corporation | Vapor retarding building materials and methods for making them |
| JP7157349B2 (en) * | 2018-09-14 | 2022-10-20 | ダイキン工業株式会社 | Oil resistant agent for paper |
| MX2021010280A (en) | 2019-02-28 | 2022-07-21 | Topchim Nv | Polymeric coating formulation with hydrophobic side chains. |
| CN114008152A (en) * | 2019-02-28 | 2022-02-01 | 索理思比利时有限公司 | Polymer coating formulations with hydrophobic side chains |
| TW202106949A (en) * | 2019-05-28 | 2021-02-16 | 日商大金工業股份有限公司 | Oil-resistant agent composition for paper |
| CN112064407B (en) * | 2020-07-31 | 2022-04-05 | 安徽美盈森智谷科技有限公司 | Preparation process of recyclable hydrophobic corrugated board for processing packaging carton |
| CN113250006B (en) * | 2021-03-24 | 2022-11-29 | 宁波亚洲浆纸业有限公司 | Coating, coated paper, preparation method of coated paper and paper cup |
| JP7231873B2 (en) * | 2021-03-31 | 2023-03-02 | ダイキン工業株式会社 | Oil-resistant compounds containing hydrogen bonding sites |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05339101A (en) * | 1992-06-10 | 1993-12-21 | New Oji Paper Co Ltd | Adhesive sheet for preserving freshness of cut flower |
| US5763100A (en) * | 1993-05-10 | 1998-06-09 | International Paper Company | Recyclable acrylic coated paper stocks and related methods of manufacture |
| JPH07173799A (en) * | 1993-12-22 | 1995-07-11 | Mitsui Toatsu Chem Inc | Paper-coating composition and coated paper produced by coating with the composition |
| US5521266A (en) * | 1994-10-28 | 1996-05-28 | Rohm And Haas Company | Method for forming polymers |
| JP3517013B2 (en) * | 1995-03-06 | 2004-04-05 | 近代化學工業株式会社 | Moistureproofing agent and method for producing the same |
| US5539021A (en) * | 1995-06-05 | 1996-07-23 | The Dow Chemical Company | Process for preparing high internal phase ratio emulsions and latexes derived thereof |
| JPH09296390A (en) * | 1996-04-26 | 1997-11-18 | Oji Paper Co Ltd | Cast-coated paper |
| DE69811293T2 (en) * | 1997-06-20 | 2003-10-23 | Rohm & Haas | polymer compositions |
-
1999
- 1999-11-04 DE DE69927775T patent/DE69927775T2/en not_active Expired - Lifetime
- 1999-11-04 EP EP19990308765 patent/EP1010807B1/en not_active Expired - Lifetime
- 1999-11-04 AU AU58265/99A patent/AU5826599A/en not_active Abandoned
- 1999-11-12 BR BR9905626-7A patent/BR9905626A/en not_active IP Right Cessation
- 1999-11-16 CN CN 99123580 patent/CN1246525C/en not_active Expired - Fee Related
- 1999-11-16 JP JP32506199A patent/JP4684380B2/en not_active Expired - Fee Related
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