KR920012219A - Water-soluble dispersant in plastics with reduced content of formaldehyde - Google Patents

Water-soluble dispersant in plastics with reduced content of formaldehyde Download PDF

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KR920012219A
KR920012219A KR1019910023657A KR910023657A KR920012219A KR 920012219 A KR920012219 A KR 920012219A KR 1019910023657 A KR1019910023657 A KR 1019910023657A KR 910023657 A KR910023657 A KR 910023657A KR 920012219 A KR920012219 A KR 920012219A
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water
ethylene
vinyl
polymer
dispersant
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KR1019910023657A
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KR950006531B1 (en
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브린크 게르하르트
알폰스비러 콘라드
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한스 쉬타하, 에리히 프란크
워커-헤미 게엠베하
에리히 프란크
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/024—Emulsion paints including aerosols characterised by the additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/006—Removal of residual monomers by chemical reaction, e.g. scavenging
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02—Processes; Apparatus
    • B27K3/15—Impregnating involving polymerisation including use of polymer-containing impregnating agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/24—Homopolymers or copolymers of amides or imides
    • C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide

Abstract

내용 없음No content

Description

포름알데히드의 감소함량을 가진 플라스틱의 수용성 분산제Water-soluble dispersant in plastics with reduced content of formaldehyde

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (9)

아크릴산에스테르, 메타그릴산에스테르, 비닐에스테르, 올레핀, 비닐 할라이드, 비닐 방향족화합물 및 에틸렌기를 가진 불포화카르복실산 및 아미드로 구성되는 그룹에서 하나 또는 그 이상의 모노머의 폴리머를 기준으로하여 30∼70wt%의 고형분함량을 가지며, 그 폴리머의 전체중량을 기준으로 하여 에킬렌기를 가진 불포화 카르복실산의 N-알킬아미드 및/또는 N-알콕시알키아미드 0∼10wt%의 함량을 구성하되, 그 폴리머를 기준으로하여 히드로겐피옥시드, 유기퍼옥시드 퍼보레이트, 퍼카르보네이트, 퍼설페이트 및 퍼포스페이트로 구성되는 그룹에서 하나 또는 그이상의 퍼옥시화합물 0.05∼10.0wt%를 포함함을 특징으로하는 플라스틱의 수용성분산제.30 to 70 wt% of the polymer of one or more monomers in the group consisting of acrylic acid esters, methacrylic acid esters, vinyl esters, olefins, vinyl halides, vinyl aromatic compounds and unsaturated carboxylic acids and amides having ethylene groups 0 to 10 wt% of N-alkylamides and / or N-alkoxyalkyamides of unsaturated carboxylic acids having a solid content and based on the total weight of the polymer and having an ethylene group, based on the polymer A water-soluble dispersant for plastics, comprising 0.05 to 10.0 wt% of one or more peroxy compounds in the group consisting of hydrogen pioxide, organic peroxide perborate, percarbonate, persulfate and perphosphate . 제1항에 있어서, N-메틸롤아크릴아미드 함량 또는 N-메틸롤메타크릴아미드함량을 선택적으로 가진 비닐 아세테이트 호모폴리며, 비닐아세테이트-에틸렌코폴리머, 비닐아세테이트-에틸렌-N-메틸롤(메타)아크릴 아미드 테르폴리머, 비닐콜로리드-비닐 아세테이트-에틸렌-N-메틸론(메타)아크릴아미드코폴리머, 비닐 콜로리드-에틸렌코폴리머, 비닐클로리드-에틸렌-N-메틸롤(메타)아크릴아미드 테르폴리머, 알킬아크릴레이트-N-메틸롤(메타)아크릴아미드 코폴리머, 비닐아세테이트-에틸렌-아크릴레이트 코폴리머 또는 비닐 아세테이트-아크릴레이트 코폴리머의 수용성분산제를 사용함을 특징으로 하는 상기 플라스틱 수용성분산제.A vinyl acetate homopoly with optionally an N-methylol acrylamide content or an N-methylol methacrylamide content, vinyl acetate-ethylene copolymer, vinyl acetate-ethylene-N-methylol (meth Acrylamide terpolymer, vinyl chloride-vinyl acetate-ethylene-N-methylone (meth) acrylamide copolymer, vinyl chloride-ethylene copolymer, vinyl chloride-ethylene-N-methylol (meth) acrylamide The water-soluble dispersant for plastics, characterized by using a water-soluble dispersant of a terpolymer, alkyl acrylate-N-methylol (meth) acrylamide copolymer, vinyl acetate-ethylene-acrylate copolymer, or vinyl acetate-acrylate copolymer. 제1항 또는 제2항에 있어서, 수용성퍼옥시화합물을 사용함을 특징으로 하는 상기 플라스틱의 수용성분산제.The water-soluble dispersant for plastics according to claim 1 or 2, wherein a water-soluble peroxy compound is used. 제1항, 제2항 또는 제3항 중 어느 한항에 있어서, 히드로겐 퍼옥시드는 퍼옥시화합물로 사용함을 특징으로 하는 상기 플라스틱의 수용성 분산제.The water-soluble dispersant of any one of claims 1, 2, or 3, wherein the hydrogen peroxide is used as a peroxy compound. 제1항, 제2항, 제3항 또는 제4항중 어느 한 항에 있어서, 상기 분산제에는 상기 폴리머를 기준으로 하여 퍼옥시화합물 0.5∼5.0wt%를 포함함을특징으로하는 상기 플라스틱의 수용성 분산제.The water-soluble dispersant according to any one of claims 1, 2, 3 or 4, wherein the dispersant comprises 0.5 to 5.0 wt% of a peroxy compound based on the polymer. . 포름 알데히드의 감소함량을가진 플라스틱의 수용성분산제를 제조하는 방법에 있어서, 폴리머를 기준으로 하여 히드로겐 퍼옥시드, 유기퍼옥시드, 퍼보레이트 퍼카보네이트, 퍼설페이트 및 퍼 포스페이트로 구성하는 그룹에서 하나 또는 그이상의 퍼옥시화합물 0.05∼10.0wt%를 아크릴산에스테르, 메타크릴산에스테르, 비닐에스테르, 올레핀, 비닐할라이드, 비닐방향족화합물 및 에틸렌기를 가진 불포화카르복실산 및 그 아미드로 구성되는 그룹에서 하나 또는 그 이상의 포노머의 폴리머를 기재로하여 그 폴리머의 총중량을 기준으로하여 에틸렌기를 가진 불포화카르복실산의 N-알킬아미드 및/또는 N-알콕시알킬아미드 0∼10wt%함량을 가진 수용성분산제에 그 중합이 완료된후에 첨가시킴을 특징으로하는 상기 방법.A process for preparing a water-soluble dispersant for plastics having a reduced content of formaldehyde, wherein the polymer is selected from the group consisting of hydrogen peroxide, organic peroxide, perborate percarbonate, persulfate and perphosphate based on polymers. 0.05 to 10.0 wt% or more of the peroxy compound is selected from the group consisting of acrylic acid ester, methacrylic acid ester, vinyl ester, olefin, vinyl halide, vinyl aromatic compound and unsaturated carboxylic acid having an ethylene group and amide thereof. After completion of the polymerization in a water-soluble dispersant having 0 to 10 wt% of N-alkylamide and / or N-alkoxyalkylamide of an unsaturated carboxylic acid having an ethylene group based on the total weight of the polymer based on the polymer of the mer Said method, characterized in that the addition. 제6항에 있어서, 상기 퍼옥시화합물은 수용액 또는 에멀죤에서 첨가시킴을 특징으로하는 상기 방법.The method as claimed in claim 6, wherein the peroxy compound is added in an aqueous solution or an emulsion. 바인더, 코팅제, 침지제(impregnating agant)또는 접착제로서 전항의 청구범위중 어느한 항의 플라스틱 분산제의 사용.Use of the plastic dispersant of any of the preceding claims as a binder, coating, impregnating agant or adhesive. 부직포를 결합 또는 코팅하는 상기 청구범위 1항 내지 제7항중 어느 한항의 플라스틱 분산제의 사용.Use of the plastic dispersant of any one of the preceding claims to bond or coat a nonwoven fabric. ※ 참고사항 ： 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019910023657A 1990-12-20 1991-12-20 Aqueous polymer dispersions with reduced amount of formaldehyde KR950006531B1 (en)

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Application Number Priority Date Filing Date Title
DE????P4040959.7 1990-12-20
DEP4040959.7 1990-12-20
DE4040959A DE4040959C1 (en) 1990-12-20 1990-12-20

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KR950006531B1 KR950006531B1 (en) 1995-06-16

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US (1) US5331024A (en)
EP (1) EP0492378B2 (en)
JP (1) JPH06179797A (en)
KR (1) KR950006531B1 (en)
CA (1) CA2058230A1 (en)
DE (2) DE4040959C1 (en)
ES (1) ES2077784T3 (en)
FI (1) FI104557B (en)

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EP0492378B1 (en) 1995-09-27
DE4040959C1 (en) 1992-03-12
US5331024A (en) 1994-07-19
ES2077784T3 (en) 1995-12-01
EP0492378B2 (en) 2000-10-25
EP0492378A2 (en) 1992-07-01
KR950006531B1 (en) 1995-06-16
FI915994A (en) 1992-06-21
EP0492378A3 (en) 1992-12-23
FI104557B (en) 2000-02-29
DE59106592D1 (en) 1995-11-02
JPH06179797A (en) 1994-06-28
CA2058230A1 (en) 1992-06-21
FI915994A0 (en) 1991-12-19

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