JP2000128669A - Antifouling sanitary ware - Google Patents
Antifouling sanitary wareInfo
- Publication number
- JP2000128669A JP2000128669A JP10319806A JP31980698A JP2000128669A JP 2000128669 A JP2000128669 A JP 2000128669A JP 10319806 A JP10319806 A JP 10319806A JP 31980698 A JP31980698 A JP 31980698A JP 2000128669 A JP2000128669 A JP 2000128669A
- Authority
- JP
- Japan
- Prior art keywords
- component
- metal oxide
- sanitary ware
- mgo
- metal oxides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Sanitary Device For Flush Toilet (AREA)
- Glass Compositions (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、大便器、小便器、
便器のサナ、便器タンク、洗面台の洗面器、手洗い器等
の衛生陶器に関する。TECHNICAL FIELD The present invention relates to a toilet bowl, a urinal,
The present invention relates to sanitary ware such as toilet sana, toilet tanks, wash basins, and hand basins.
【０００２】[0002]
【従来の技術】衛生陶器の表面を衛生的に清浄に保つこ
と、及び長期に亘って美観を高く保つことは、衛生陶器
が一般的に生活用品として広く使用されていることから
必要とされる特性である。古くより一般家庭において、
衛生陶器表面を衛生的に清浄に保ち、美観を高く保つた
めの方法として、界面活性剤、酸、アルカリ等の洗剤を
タワシやブラシに付けて強く陶磁器表面をこすり、洗剤
による化学的な汚れ除去と、タワシやブラシでこするこ
とによる物理的除去を併用する方法が採られてきた。2. Description of the Related Art It is necessary to keep sanitary ware surfaces sanitary clean and to maintain high aesthetics over a long period of time, because sanitary ware is generally widely used as a living article. It is a characteristic. In old households,
As a method of keeping the sanitary ware surface clean and hygienic, a detergent such as a surfactant, acid, or alkali can be attached to a scourer or brush to rub the surface of the porcelain strongly and remove chemical stains with the detergent. And physical removal by scrubbing with a scourer or brush have been employed.
【０００３】[0003]
【発明が解決しようとする課題】しかしながら、この方
法によれば、汚れが付着する度に、タワシやブラシでこ
するという労働が要求される。特に、老齢者において、
かかる労働が毎回要求されるのは大変である。また、と
りわけ、衛生陶器のうち、大便器、小便器、便器のサナ
の洗浄に関しては、使用者にとって、できれば、清掃頻
度がより低くなってほしいという願望は強いものがあ
る。さらに、近年上記界面活性剤が含有される家庭排水
の垂れ流しによる河川の汚染が問題となっている。そこ
で、本発明の目的は、界面活性剤を使用せず、かつタワ
シやブラシで強くこすらなくても、衛生陶器表面の汚れ
を、流水程度で簡単に除去できるようにした衛生陶器を
提供することを目的とする。However, according to this method, labor for scrubbing with a scourer or a brush is required every time dirt adheres. Especially in the elderly,
It is difficult to require such labor every time. In particular, among sanitary wares, there is a strong desire for users to reduce the frequency of cleaning, if possible, of toilet bowls, urinals, and toilet sana. Furthermore, in recent years, there has been a problem of river pollution due to the drainage of household wastewater containing the surfactant. Therefore, an object of the present invention is to provide a sanitary ware which is capable of easily removing dirt on the surface of the sanitary ware with running water without using a surfactant and without rubbing strongly with a scourer or a brush. With the goal.
【０００４】[0004]
【課題を解決するための手段】本発明では、上記課題を
解決すべく、陶器素地表面に釉薬層が被覆されており、
前記釉薬層は少なくともガラス状の成分を含み、前記ガ
ラス状の成分は少なくともＳｉＯ2成分とＡｌ2Ｏ3成分
と２価金属酸化物成分とアルカリ金属酸化物成分を含
み、前記ＳｉＯ2成分の重量はガラス成分の合計重量に
対して５５〜８０％であり、前記Ａｌ2Ｏ3成分の重量は
ガラス成分の合計重量に対して５〜１３％であり、前記
２価金属酸化物成分の重量はガラス成分の合計重量に対
して１１〜２８％であり、前記アルカリ金属酸化物成分
の重量はガラス成分の合計重量に対して１〜７％であ
り、かつ前記２価金属酸化物成分は少なくともＭｇＯ成
分とＣａＯ成分とＺｎＯ成分を含んでなる便器におい
て、前記ＭｇＯ成分の量が前記２価金属酸化物成分の合
計量に対して１０〜３０モル％であることを特徴とする
防汚性衛生陶器を提供する。According to the present invention, in order to solve the above-mentioned problems, a glaze layer is coated on the surface of a ceramic body,
The glaze layer contains at least a glassy component, and the glassy component contains at least a SiO 2 component, an Al 2 O 3 component, a divalent metal oxide component, and an alkali metal oxide component, and the weight of the SiO 2 component Is 55 to 80% with respect to the total weight of the glass component, the weight of the Al 2 O 3 component is 5 to 13% with respect to the total weight of the glass component, and the weight of the divalent metal oxide component is The weight of the alkali metal oxide component is 1 to 7% with respect to the total weight of the glass component, and the divalent metal oxide component is at least MgO. A toilet bowl comprising a component, a CaO component, and a ZnO component, wherein the amount of the MgO component is 10 to 30 mol% based on the total amount of the divalent metal oxide component. Provide That.
【０００５】釉薬中のＭｇＯ成分の量が、釉薬中の２価
金属酸化物成分の合計量に対して１０モル％以上にする
ことにより、おそらく基材表面の表面電荷状態が変化す
るために、使用環境下において汚れが付着しにくくな
る。特に大便器、小便器、便器のサナにおいては、使用
環境であるｐＨ７〜９における表面のゼータ電位が−２
０ｍＶ〜−６０ｍＶ、より好ましくは−３０ｍＶ〜−５
０ｍＶ程度になると、おそらく付着汚れ表面の有するゼ
ータ電位と同符号かつ同程度になるために、その効果が
顕著になる。代表的な汚れ成分であるタンパク質、尿
石、大腸菌等は一般にマイナスに帯電していることが知
られており、例えば、大腸菌のｐＨ７〜９におけるゼー
タ電位は−４０ｍＶ前後であったことから、基材表面の
ゼータ電位がマイナスであり、かつ、その値が−４０ｍ
Ｖに近いものほど汚れにくいと考えられる。[0005] If the amount of the MgO component in the glaze is at least 10 mol% with respect to the total amount of the divalent metal oxide components in the glaze, the surface charge state of the substrate surface will probably change, Dirt is less likely to adhere in the use environment. In particular, in toilet bowls, urinals, and toilet sana, the zeta potential of the surface at pH 7 to 9, which is the use environment, is -2.
0 mV to -60 mV, more preferably -30 mV to -5
At about 0 mV, the effect is remarkable because it is probably the same sign and the same as the zeta potential of the adhered dirt surface. It is known that proteins, urine stones, Escherichia coli, etc., which are typical stain components, are generally negatively charged. For example, since the zeta potential of Escherichia coli at pH 7 to 9 was around -40 mV, The material surface has a negative zeta potential and the value is -40 m
It is considered that the one closer to V is less likely to be stained.
【０００６】さらに、釉薬のＭｇＯ成分の量が、釉薬中
の２価金属酸化物成分の合計量に対して３０モル％を超
えると、１１００〜１２００℃の陶器の最適焼成温度に
おいて、釉薬層の表面平滑性が充分でなく、優れた表面
光沢性が得られない。Further, when the amount of the MgO component in the glaze exceeds 30 mol% with respect to the total amount of the divalent metal oxide components in the glaze, at an optimum firing temperature of the ceramic of 1100 to 1200 ° C., The surface smoothness is not sufficient, and excellent surface gloss cannot be obtained.
【０００７】[0007]
【発明の実施の形態】本発明における衛生陶器とは、大
便器、小便器、便器のサナ、便器タンク、洗面台の洗面
器、手洗い器等をいう。本発明における釉薬層を形成す
る釉薬は、ガラス成分を主成分とするが、他に酸化鉄、
酸化コバルト等の着色顔料、酸化錫、ケイ酸ジルコン等
の乳濁剤、未溶解のシリカ成分等が含まれていてもよ
い。釉薬中のガラス成分は、ＳｉＯ2成分とＡｌ2Ｏ3成
分と２価金属酸化物成分とアルカリ金属酸化物成分を主
成分とするが、他にＴｉＯ2、Ｖ2Ｏ5、Ａｇ2Ｏ、Ｃｕ2
Ｏ等が含有されていてもよい。上記アルカリ金属酸化物
成分には、Ｎａ2Ｏ、Ｋ2Ｏ、Ｌｉ2Ｏ等が利用できる。
上記２価金属酸化物成分には、ＭｇＯ、ＣａＯ、ＳｒＯ
等のアルカリ土類金属酸化物、ＺｎＯ、ＣｕＯ等が利用
できる。BEST MODE FOR CARRYING OUT THE INVENTION The sanitary ware in the present invention refers to toilet bowls, urinals, toilet bowl sana, toilet tanks, wash basins, hand washers, and the like. The glaze for forming the glaze layer in the present invention has a glass component as a main component.
A coloring pigment such as cobalt oxide, an emulsifier such as tin oxide and zircon silicate, and an undissolved silica component may be contained. The glass component in the glaze is mainly composed of a SiO 2 component, an Al 2 O 3 component, a divalent metal oxide component, and an alkali metal oxide component, but in addition to TiO 2 , V 2 O 5 , Ag 2 O, Cu 2
O and the like may be contained. As the alkali metal oxide component, Na 2 O, K 2 O, Li 2 O and the like can be used.
The divalent metal oxide component includes MgO, CaO, SrO
And alkaline earth metal oxides such as ZnO, CuO and the like.
【０００８】[0008]
【実施例】（比較例１）Example (Comparative Example 1)
【０００９】[0009]
【表１】 [Table 1]
【００１０】表１の組成から成る釉薬基材（２価の金属
酸化物成分、すなわちＣａＯ、ＭｇＯ、ＺｎＯの重量は
ガラス成分の合計重量に対して２０重量％であり、その
組成比は、それぞれ６６ｍｏｌ％、９ｍｏｌ％、２５ｍ
ｏｌ％である）２ｋｇと水１ｋｇ及び球石４ｋｇを、容
積６リットルの陶器製ポット中に入れ、ボールミルによ
り約１８時間粉砕した。レーザー回折式粒度分布計を用
いて、粉砕後に得られた釉薬スラリーの粒径を測定した
ところ、１０μｍ以下が６５％、５０％平均粒径（Ｄ５
０）が６．２μｍであった。A glaze substrate having the composition shown in Table 1 (the weight of the divalent metal oxide component, ie, CaO, MgO, and ZnO is 20% by weight based on the total weight of the glass component, and the composition ratio is 66mol%, 9mol%, 25m
2 kg), 1 kg of water and 4 kg of cobblestone were placed in a 6-liter pottery pot and ground by a ball mill for about 18 hours. The particle size of the glaze slurry obtained after pulverization was measured using a laser diffraction type particle size distribution analyzer.
0) was 6.2 μm.
【００１１】次に、ケイ砂、長石、粘土等を原料として
調製した衛生陶器素地泥漿を用いて、品番：ＣＳ９７１
Ｂに相当する洋風大便器の成形体を作製し、上記の如く
して得られた釉薬に糊剤としてカルボキシメチルセルロ
ース（ＣＭＣ）を添加した後、成形体にスプレーコーテ
ィング法により塗布し、１１００〜１２００℃で焼成す
ることにより試験用サンプルを得た。なお、得られた試
験用サンプルの釉薬色はパステルアイボリー（色番：＃
ＳＣ１）である。このサンプルを用いて、尿石付着試験
を行った。Next, using a sanitary ware body slurry prepared from silica sand, feldspar, clay and the like as a raw material, a product number: CS971
A molded body of a Western-style toilet bowl corresponding to B was prepared, carboxymethylcellulose (CMC) was added as a glue to the glaze obtained as described above, and then applied to the molded body by a spray coating method. A test sample was obtained by baking at ℃. The glaze color of the obtained test sample was pastel ivory (color number: #
SC1). Using this sample, a urolith adhesion test was performed.
【００１２】尿石付着試験は、初めに、人間より採取し
た尿を蒸留水で２倍に希釈し、この希釈尿約２リットル
を上記サンプル大便器のボール内に入れ、座面を密閉し
て常温で一週間放置した。希釈直後及び大便器ボール内
で一週間放置した後の尿を２５℃においてｐＨ測定（堀
場製作所製ｐＨメーターＭ−１２使用）したところ、そ
れぞれ６．５、８．５であった。In the urinary stone adhesion test, first, urine collected from a human is diluted twice with distilled water, and about 2 liters of the diluted urine is placed in the bowl of the sample toilet bowl, and the seat surface is sealed. It was left at room temperature for one week. The pH of urine immediately after dilution and after standing for one week in a toilet bowl was measured at 25 ° C. (using a pH meter M-12 manufactured by Horiba, Ltd.), and it was 6.5 and 8.5, respectively.
【００１３】次に、ボール内の希釈尿を捨て、約１２リ
ットルの水道水（通常の便器タンクによる洗浄水量に相
当する）でボール内を流水洗浄し、室温で乾燥させた。
その後、ヘルステック製歯垢染色ジェル「ＤＥＮＴＣＬ
ＵＢ」を蒸留水で希釈した溶液をボール内にスプレー
し、赤色の強弱で尿石付着量を評価した。この歯垢染色
ジェルを用いると、尿石付着の多い部分は強く赤色に染
まり、尿石の無い部分には色が着かない。そのため、目
視により尿石付着量を評価することが可能である。 そ
の結果、ボール内の希釈尿喫水部及び浸漬部が強く赤色
に染まり、大量の尿石が付着していることが分かった。Next, the diluted urine in the bowl was discarded, the bowl was washed with running water of about 12 liters of tap water (corresponding to the amount of washing water in a normal toilet tank), and dried at room temperature.
Then, Dental plaque dye gel "DENTCL" made by Healthtech
A solution obtained by diluting "UB" with distilled water was sprayed into a ball, and the adhesion amount of urinary stone was evaluated based on the intensity of the red color. When this plaque-stained gel is used, a portion having a large amount of urinary stones is strongly dyed red, and a portion having no urolith is not colored. Therefore, it is possible to visually evaluate the attached amount of urinary stone. As a result, it was found that the diluted urine draft part and the immersion part in the ball were strongly stained red, and that a large amount of urine stones had adhered.
【００１４】（実施例１）比較例１で調製した釉薬組成
に対して、ＭｇＯ成分が多くなるように調合した釉薬基
材（２価の金属酸化物、すなわちＣａＯ、ＭｇＯ、Ｚｎ
Ｏの重量はガラス成分の合計重量に対して２０重量％で
あり、その組成比は、それぞれ４５ｍｏｌ％、２２ｍｏ
ｌ％、３３ｍｏｌ％である）２ｋｇと水１ｋｇ及び球石
４ｋｇを、容積６リットルの陶器製ポット中に入れ、ボ
ールミルにより約１６時間粉砕した。レーザー回折式粒
度分布計を用いて、粉砕後に得られた釉薬スラリーの粒
径を測定したところ、１０μｍ以下が６４％、５０％平
均粒径（Ｄ５０）が６．３μｍであった。(Example 1) A glaze base material (a divalent metal oxide, ie, CaO, MgO, Zn) prepared so that the MgO component is increased with respect to the glaze composition prepared in Comparative Example 1.
The weight of O is 20% by weight with respect to the total weight of the glass components, and the composition ratio thereof is 45 mol% and 22 mo, respectively.
2 kg, 1 kg of water, and 4 kg of cobblestone were placed in a 6-liter pottery pot and ground by a ball mill for about 16 hours. When the particle size of the glaze slurry obtained after the pulverization was measured using a laser diffraction type particle size distribution meter, it was 64% for 10 μm or less, and the 50% average particle size (D50) was 6.3 μm.
【００１５】次に、ケイ砂、長石、粘土等を原料として
調製した衛生陶器素地泥漿を用いて、品番：ＣＳ９７１
Ｂに相当する洋風大便器の成形体を作製し、上記の如く
して得られた釉薬に糊剤としてカルボキシメチルセルロ
ース（ＣＭＣ）を添加した後、成形体にスプレーコーテ
ィング法により塗布し、１１００〜１２００℃で焼成す
ることにより試験用サンプルを得た。なお、得られた試
験用サンプルの釉薬色はパステルアイボリー（色番：＃
ＳＣ１）相当である。このサンプルを用いて、比較例１
と同様に尿石付着試験を行った。比較例１と同一の希釈
尿を使用し、室温で一週間放置した後（希釈尿のｐＨ
は、初期６．５、一週間放置後８．５）、ボール内に歯
垢染色シェルの希釈溶液をスプレーしたところ、希釈尿
喫水部及び浸漬部は薄く赤色に染まったが、比較例１の
サンプルと比較すると明らかにその色が薄かった。従っ
て、比較例１のサンプルよりも尿石付着量が少ないこと
が分かった。[0015] Next, using the sanitary ware body slurry prepared from silica sand, feldspar, clay and the like as a raw material, product number: CS971
A molded product of a Western-style toilet bowl corresponding to B was prepared, and carboxymethylcellulose (CMC) was added as a glue to the glaze obtained as described above, and then applied to the molded product by a spray coating method. A test sample was obtained by baking at ℃. The glaze color of the obtained test sample was pastel ivory (color number: #
SC1). Using this sample, Comparative Example 1
A urinary stone adhesion test was performed in the same manner as described above. After using the same diluted urine as in Comparative Example 1 and allowing it to stand at room temperature for one week (pH of diluted urine)
In the initial stage, 6.5, after standing for one week 8.5), when the diluted solution of the plaque stained shell was sprayed into the ball, the diluted urine draft portion and the immersion portion were stained red lightly. The color was clearly lighter than the sample. Therefore, it was found that the urine stone adhesion amount was smaller than that of the sample of Comparative Example 1.
【００１６】[0016]
【発明の効果】本発明によれば、表面に付着した汚れ
を、流水程度で簡単に除去できるようにした衛生陶器を
提供することができる。According to the present invention, it is possible to provide a sanitary ware in which dirt attached to the surface can be easily removed with only running water.
フロントページの続き (72)発明者 伊藤 正昭 福岡県北九州市小倉北区中島２丁目１番１ 号 東陶機器株式会社内 (72)発明者 林 浩一 福岡県北九州市小倉北区中島２丁目１番１ 号 東陶機器株式会社内 (72)発明者 安藤 正美 福岡県北九州市小倉北区中島２丁目１番１ 号 東陶機器株式会社内 (72)発明者 川上 克博 福岡県北九州市小倉北区中島２丁目１番１ 号 東陶機器株式会社内 (72)発明者 堀内 智 福岡県北九州市小倉北区中島２丁目１番１ 号 東陶機器株式会社内 Ｆターム(参考） 2D039 AA01 AA04 AD00 BA03 DB04 4G062 AA08 AA09 AA15 BB01 DA06 DA07 DB03 DB04 DC01 DD01 DE01 DE02 DE03 DE04 DF01 EA01 EA02 EA03 EA10 EB01 EB02 EB03 EC01 EC02 EC03 ED01 ED02 ED03 ED04 EE01 EE02 EE03 EE04 EF01 EG01 FA01 FA10 FB01 FC01 FD01 FE01 FF01 FG01 FH01 FJ01 FK01 FL01 GA01 GA10 GB01 GC01 GD01 GE01 HH01 HH03 HH05 HH07 HH09 HH11 HH13 HH15 HH17 HH20 JJ01 JJ03 JJ05 JJ07 JJ10 KK01 KK03 KK05 KK07 KK10 MM07 NN40 PP01 PP02 PP05 Continuing from the front page (72) Inventor Masaaki Ito 2-1-1 Nakajima, Kokurakita-ku, Kitakyushu-shi, Fukuoka Tochiki Kiki Co., Ltd. (72) Inventor Koichi Hayashi 2-1-1 Nakajima, Kokurakita-ku, Kitakyushu-shi, Fukuoka No. 1 Toto Kiki Co., Ltd. (72) Masami Ando 2-1-1 Nakajima, Kokurakita-ku, Kitakyushu-shi, Fukuoka Prefecture Tochi Kiki Co., Ltd. (72) Katsuhiro Kawakami Nakajima, Kokurakita-ku, Kitakyushu-shi, Fukuoka 2-1-1 1-1 Totoki Equipment Co., Ltd. (72) Inventor Satoshi Horiuchi 2-1-1 Nakajima, Kokurakita-ku, Kitakyushu-shi, Fukuoka F-term in Totoki Equipment Co., Ltd. 2D039 AA01 AA04 AD00 BA03 DB04 4G062 AA08 AA09 AA15 BB01 DA06 DA07 DB03 DB04 DC01 DD01 DE01 DE02 DE03 DE04 DF01 EA01 EA02 EA03 EA10 EB01 EB02 EB03 EC01 EC02 EC03 ED01 ED02 ED03 ED04 EE01 EE02 EE03 FE01 F01 FE01 FA01 FE01 GB01 GC01 GD01 GE01 HH01 HH03 HH05 HH07 HH09 HH11 HH13 HH15 HH17 HH20 JJ01 JJ03 JJ05 JJ07 JJ10 KK01 KK03 KK05 KK07 KK10 MM07 NN40 PP01 PP02 PP05
Claims (1)
り、前記釉薬層は少なくともガラス状の成分を含み、前
記ガラス状の成分は少なくともＳｉＯ2成分とＡｌ2Ｏ3
成分と２価金属酸化物成分とアルカリ金属酸化物成分を
含み、前記ＳｉＯ2成分の重量はガラス成分の合計重量
に対して５５〜８０％であり、前記Ａｌ2Ｏ3成分の重量
はガラス成分の合計重量に対して５〜１３％であり、前
記２価金属酸化物成分の重量はガラス成分の合計重量に
対して１１〜２８％であり、前記アルカリ金属酸化物成
分の重量はガラス成分の合計重量に対して１〜７％であ
り、かつ前記２価金属酸化物成分は少なくともＭｇＯ成
分とＣａＯ成分とＺｎＯ成分を含んでなる衛生陶器にお
いて、前記ＭｇＯ成分の量が前記２価金属酸化物成分の
合計量に対して１０〜３０モル％であることを特徴とす
る防汚性衛生陶器。1. A ceramic substrate having a glaze layer coated on a surface thereof, wherein the glaze layer includes at least a glassy component, and the glassy component includes at least a SiO 2 component and an Al 2 O 3 component.
Component, a divalent metal oxide component and an alkali metal oxide component, wherein the weight of the SiO 2 component is 55 to 80% based on the total weight of the glass component, and the weight of the Al 2 O 3 component is And the weight of the divalent metal oxide component is 11 to 28% with respect to the total weight of the glass component, and the weight of the alkali metal oxide component is A sanitary ware which is 1 to 7% based on the total weight and wherein the divalent metal oxide component contains at least an MgO component, a CaO component and a ZnO component, wherein the amount of the MgO component is An antifouling sanitary ware, which is 10 to 30 mol% based on the total amount of the components.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10319806A JP2000128669A (en) | 1998-10-21 | 1998-10-21 | Antifouling sanitary ware |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10319806A JP2000128669A (en) | 1998-10-21 | 1998-10-21 | Antifouling sanitary ware |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000128669A true JP2000128669A (en) | 2000-05-09 |
Family
ID=18114411
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10319806A Pending JP2000128669A (en) | 1998-10-21 | 1998-10-21 | Antifouling sanitary ware |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000128669A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1904417A4 (en) * | 2005-06-06 | 2008-12-03 | American Standard Int Inc | Antimicrobial glaze and acid resistant procelain for enameled steel products |
| JP2011246290A (en) * | 2010-05-21 | 2011-12-08 | Ohara Inc | Glass substrate |
| CN113912293A (en) * | 2021-08-24 | 2022-01-11 | 福建良瓷科技有限公司 | Formula and glazing method of special temmoku glaze for sanitary ceramics |
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|---|---|---|---|---|
| JPH03224922A (en) * | 1990-01-30 | 1991-10-03 | Nippon Soda Co Ltd | Pollution-preventing/deodorizing method for toilet bowl |
| JPH05124942A (en) * | 1991-05-06 | 1993-05-21 | Colgate Palmolive Co | Tooth sordes detecting composition |
| JPH05255055A (en) * | 1992-01-17 | 1993-10-05 | Colgate Palmolive Co | Pet chew product having oral care property |
| WO1996023412A1 (en) * | 1995-02-02 | 1996-08-08 | Toto Ltd. | Process for producing antibacterial glaze, antibacterial member, and process for producing the member |
| JPH0956625A (en) * | 1995-01-10 | 1997-03-04 | Toto Ltd | Kitchen and sanitary space member and manufacture therefor |
| JPH10203943A (en) * | 1997-01-24 | 1998-08-04 | G C:Kk | Cleaning material for removable prosthesis and retaining device in oral cavity |
-
1998
- 1998-10-21 JP JP10319806A patent/JP2000128669A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03224922A (en) * | 1990-01-30 | 1991-10-03 | Nippon Soda Co Ltd | Pollution-preventing/deodorizing method for toilet bowl |
| JPH05124942A (en) * | 1991-05-06 | 1993-05-21 | Colgate Palmolive Co | Tooth sordes detecting composition |
| JPH05255055A (en) * | 1992-01-17 | 1993-10-05 | Colgate Palmolive Co | Pet chew product having oral care property |
| JPH0956625A (en) * | 1995-01-10 | 1997-03-04 | Toto Ltd | Kitchen and sanitary space member and manufacture therefor |
| WO1996023412A1 (en) * | 1995-02-02 | 1996-08-08 | Toto Ltd. | Process for producing antibacterial glaze, antibacterial member, and process for producing the member |
| JPH10203943A (en) * | 1997-01-24 | 1998-08-04 | G C:Kk | Cleaning material for removable prosthesis and retaining device in oral cavity |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1904417A4 (en) * | 2005-06-06 | 2008-12-03 | American Standard Int Inc | Antimicrobial glaze and acid resistant procelain for enameled steel products |
| JP2011246290A (en) * | 2010-05-21 | 2011-12-08 | Ohara Inc | Glass substrate |
| CN113912293A (en) * | 2021-08-24 | 2022-01-11 | 福建良瓷科技有限公司 | Formula and glazing method of special temmoku glaze for sanitary ceramics |
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