JP2000048803A - Organic electrolyte battery - Google Patents

Organic electrolyte battery

Info

Publication number
JP2000048803A
JP2000048803A JP10226530A JP22653098A JP2000048803A JP 2000048803 A JP2000048803 A JP 2000048803A JP 10226530 A JP10226530 A JP 10226530A JP 22653098 A JP22653098 A JP 22653098A JP 2000048803 A JP2000048803 A JP 2000048803A
Authority
JP
Japan
Prior art keywords
terminal
cover plate
nut
resin
battery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10226530A
Other languages
Japanese (ja)
Inventor
Takao Fukunaga
福永  孝夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Storage Battery Co Ltd
Original Assignee
Japan Storage Battery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Storage Battery Co Ltd filed Critical Japan Storage Battery Co Ltd
Priority to JP10226530A priority Critical patent/JP2000048803A/en
Publication of JP2000048803A publication Critical patent/JP2000048803A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Secondary Cells (AREA)
  • Connection Of Batteries Or Terminals (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

PROBLEM TO BE SOLVED: To secure insulating performance of a terminal, a nut and a cover plate, to endure fastening compressive force of the nut for fixing the terminal to the cover plate, and to hold sealing performance of the battery terminal part over a wide temperature range by using a polyphenylene sulfide resin for insulating packing. SOLUTION: A fluororubber-made O-ring 8 is inserted into a terminal 3, the terminal 3 is inserted into the through-hole of a cover plate 5, insulating packing 6 of a polyphenylene sulfide(PPS) resin is inserted into the terminal 3, and is fastened in torque of 50 kgf.cm by a nut 7 to be formed as a polar terminal. PPS resin-made insulating packing 6 is sandwiched by the terminal 3 and the cover plate 5 and the nut 7 and the cover plate 5, and can hold insulating performance and sealing performance of a battery in a shape capable of close contact. A PPS resin is a linear high polymer type PPS resin, having a molecular weight of 50,000 to 60,000, and particularly a high viscosity resin having melt viscosity not less than 7,000 is used to strengthen aseismatic property as well as to secure superhigh tenacity.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、有機電解質電池の
絶縁パッキングに関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an insulating packing for an organic electrolyte battery.

【0002】[0002]

【従来の技術】近年、ノート型パソコン等の携帯情報機
器、カメラ一体型VTR、液晶テレビ等のAV機器、そして
携帯電話などの移動通信機器、さらには電気自動車など
の動力源として用いられている電池に対して、大電流、
高出力の必要性の高まりから、より高エネルギー密度化
が要望されている。中でも、有機電解質電池はその要望
に応えられる電池として注目され、技術革新著しいもの
がある。
2. Description of the Related Art In recent years, portable information devices such as notebook computers, VTRs such as camera-integrated VTRs and liquid crystal televisions, and mobile communication devices such as mobile phones, and power sources for electric vehicles have been used. High current,
Due to the growing need for high output, higher energy density is demanded. Among them, an organic electrolyte battery is attracting attention as a battery that can meet the demand, and there is a remarkable technological innovation.

【0003】一般に、有機電解質電池では、正極活物質
にコバルト酸リチウム、ニッケル酸リチウム、マンガン
酸リチウムなど、負極に天然黒鉛、コークス、炭素繊維
や樹脂焼成炭素など、セパレータにはポリエチレン樹脂
やポリプロピレン樹脂製の微多孔膜など、電解液には六
フッ化燐酸リチウムや四フッ化ホウ酸リチウムなどの電
解質をエチレンカーボネート、プロピレンカーボネー
ト、ジエチルカーボネートなどの混合溶媒に溶かした有
機電解液が使用されている。前述の正極、負極、セパレ
ータ、電解液の収納にはステンレス、アルミ、鉄などの
金属製のケースが用いられている。
In general, in an organic electrolyte battery, lithium cobalt oxide, lithium nickel oxide, lithium manganate and the like are used as a positive electrode active material, natural graphite, coke, carbon fiber and resin-fired carbon are used as a negative electrode, and polyethylene resin and polypropylene resin are used as a separator. The electrolyte used is an organic electrolyte in which an electrolyte such as lithium hexafluorophosphate or lithium tetrafluoroborate is dissolved in a mixed solvent such as ethylene carbonate, propylene carbonate, or diethyl carbonate. . A metal case such as stainless steel, aluminum, or iron is used for storing the above-described positive electrode, negative electrode, separator, and electrolyte.

【0004】従って、金属ケースと、正極や負極の電流
を取り出す端子は絶縁パッキングを介して絶縁されてい
なければならず、そのパッキングには、有機電解液に安
定とされるポリプロピレン樹脂が用いられている。
[0004] Therefore, the metal case and the terminal for taking out the current of the positive electrode and the negative electrode must be insulated through an insulating packing, and the packing is made of a polypropylene resin which is stable in an organic electrolyte. I have.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、上記ポ
リプロピレン樹脂は、ガラス転移点が約−10℃であるこ
とから、低温から高温、例えば−30℃から+70℃に温度
が変化した場合、剛性が変化する。そのため、該ポリプ
ロピレン樹脂製のパッキングでは、広い範囲において端
子およびナットと蓋板とのシール性を保持することが困
難である。
However, since the glass transition point of the above polypropylene resin is about -10 ° C, the rigidity changes when the temperature changes from a low temperature to a high temperature, for example, from -30 ° C to + 70 ° C. I do. Therefore, it is difficult for the packing made of the polypropylene resin to maintain the sealing properties between the terminal and the nut and the cover plate over a wide range.

【0006】本発明は、このような課題に鑑みてなされ
たものであり、端子およびナットと蓋板との絶縁性を十
分に確保することができ、端子を蓋板に固定するための
ナットの締め付けによる圧縮力に耐えることができ、広
い温度範囲においても電池端子部のシール性を保持する
ことができる有機電解質電池を提供することを目的とす
る。
SUMMARY OF THE INVENTION The present invention has been made in view of such a problem, and can sufficiently secure insulation between a terminal and a nut and a cover plate, and a nut for fixing the terminal to the cover plate. An object of the present invention is to provide an organic electrolyte battery that can withstand a compressive force due to tightening and that can maintain the sealing property of a battery terminal portion even in a wide temperature range.

【0007】[0007]

【課題を解決するための手段】この目的を達成するため
の本発明に係る有機電解質電池は、貫通孔を有する蓋板
の該貫通孔に挿入される正極端子または負極端子が絶縁
パッキングを介してナットで蓋板に締結されてなる有機
電解質電池であって、前記絶縁パッキングにポリフェニ
レンサルファイド樹脂(以下PPS樹脂とする)を用いる
ものである。
According to the present invention, there is provided an organic electrolyte battery according to the present invention, wherein a positive electrode terminal or a negative electrode terminal inserted into a through-hole of a cover plate having a through-hole is provided via an insulating packing. An organic electrolyte battery fastened to a cover plate with a nut, wherein a polyphenylene sulfide resin (hereinafter, referred to as a PPS resin) is used for the insulating packing.

【0008】PPS樹脂は、高強度な絶縁体であり、ガラ
ス転移点が約90℃と高いため、広い温度範囲、例えば−
30℃から+70℃に温度が変化した場合においてもその剛
性が変化しないことから、絶縁パッキングにPPS樹脂を
使用することにより、広い温度範囲において端子および
ナットと蓋板との絶縁性を確保できるとともに、強力か
つ安定したシール性を得ることができる。
[0008] PPS resin is a high-strength insulator and has a high glass transition point of about 90 ° C.
The rigidity does not change even when the temperature changes from 30 ° C to + 70 ° C. By using PPS resin for the insulating packing, the insulation between the terminal and nut and the cover plate can be secured over a wide temperature range. Strong and stable sealing properties can be obtained.

【0009】上記PPS樹脂の分子量は、実用上、40000以
上60000以下であることが好ましい。
The PPS resin preferably has a molecular weight of 40,000 or more and 60,000 or less for practical use.

【0010】[0010]

【発明の実施の形態】以下、実施例とともに本発明の実
施形態について説明する。
Embodiments of the present invention will be described below with reference to examples.

【0011】図1は、幅100mm、高さ150mm、厚み50mm、
電池容量50Ahである長円筒型有機電解質電池の平面図お
よび縦断面図であり、図2は、正極活物質にコバルト酸
リチウム、負極に天然黒鉛、正極および負極のバインダ
ーとしてポリフッ化ビニリデン樹脂を用いた長円筒型有
機電解質電池における端子の組み立てを示す図である。
FIG. 1 shows a width of 100 mm, a height of 150 mm, a thickness of 50 mm,
Fig. 2 is a plan view and a vertical cross-sectional view of a long cylindrical organic electrolyte battery having a battery capacity of 50Ah.Fig. 2 uses lithium cobalt oxide as a positive electrode active material, natural graphite as a negative electrode, and polyvinylidene fluoride resin as a binder for the positive electrode and the negative electrode. FIG. 4 is a diagram showing the assembly of terminals in a long cylindrical organic electrolyte battery.

【0012】本実施例においては、正極と負極とをセパ
レータを介して長円型に巻回した電極群を電池ケース
(2)内に挿入し、正極および負極に取り付けたリード
と正極端子(3)および負極端子(4)とを超音波溶接に
て接続し、電解液を注液後、蓋板(5)でレーザー溶接
にて密封する。
In this embodiment, an electrode group in which a positive electrode and a negative electrode are wound in an oval shape with a separator interposed therebetween is inserted into a battery case (2), and a lead attached to the positive electrode and the negative electrode and a positive electrode terminal (3 ) And the negative electrode terminal (4) are connected by ultrasonic welding, and the electrolyte is injected, and then sealed with a lid plate (5) by laser welding.

【0013】正極端子および負極端子を蓋板に取り付け
る手順は、図2を用いて説明する。まず、正極端子(3)
および負極端子(4)にフッ素ゴムからなるOリング
(8)を挿入し、該両端子を蓋板(5)の貫通孔(9)に
各々入れ、ついで分子量50000、溶融粘度10000のPPS樹
脂からなる絶縁パッキング(6)を正極端子(3)および
負極端子(4)に挿入し、ナット(7)で締め付け、絶縁
パッキングを介してナットで締結された極端子とする。
ナットの締め付けトルクは50kgf・cmである。
The procedure for attaching the positive terminal and the negative terminal to the cover plate will be described with reference to FIG. First, the positive terminal (3)
Insert an O-ring (8) made of fluoro rubber into the negative electrode terminal (4) and insert both terminals into the through holes (9) of the lid plate (5). The insulating packing (6) is inserted into the positive terminal (3) and the negative terminal (4) and tightened with a nut (7) to form a pole terminal fastened with a nut via the insulating packing.
The tightening torque of the nut is 50 kgf · cm.

【0014】上記PPS樹脂からなる絶縁パッキングは、
図2(6)のごとく、端子と蓋板かつナットと蓋板で挟み
込み、密着することができる形状を有するものを用い
る。PPS樹脂による絶縁性と同時に電池のシール性を保
持することができるからである。
The insulating packing made of the PPS resin is as follows:
As shown in FIG. 2 (6), one having a shape that can be sandwiched and adhered between the terminal and the cover plate and between the nut and the cover plate is used. This is because the sealing properties of the battery can be maintained at the same time as the insulating properties of the PPS resin.

【0015】なお、該PPS樹脂は、架橋型、セミリニア
型、リニア高分子量型があり、自動車用などとしては耐
震性の点で分子量40000以上のリニア高分子量型が好ま
しい。さらに好ましくは、分子量50000から60000のリニ
ア高分子型PPS樹脂で、特に溶融粘度7000以上の高粘度
のものがよい。耐震性が強く、超高靱性を持つからであ
る。
The PPS resin includes a crosslinked type, a semi-linear type, and a linear high molecular weight type. For automobiles and the like, a linear high molecular weight type having a molecular weight of 40,000 or more is preferable from the viewpoint of earthquake resistance. More preferably, a high-molecular-weight PPS resin having a molecular weight of 50,000 to 60,000, particularly a high-viscosity resin having a melt viscosity of 7000 or more is preferable. This is because it has strong earthquake resistance and has super high toughness.

【0016】上記正極は、厚み0.03mmのアルミ箔の両面
にコバルト酸リチウムと導電材であるアセチレンブラッ
クおよびバインダーのポリフッ化ビニリデンを混合し、
ペースト状にしたものを被着させて作製した。
The above positive electrode is prepared by mixing lithium cobaltate, acetylene black as a conductive material and polyvinylidene fluoride as a binder on both sides of an aluminum foil having a thickness of 0.03 mm,
It was produced by applying a paste-like material.

【0017】上記負極は、厚み0.02mmの銅箔の両面に天
然黒鉛とバインダーのポリフッ化ビニリデンをペースト
状にしたものを被着させて作製した。
The above-mentioned negative electrode was produced by applying a paste of natural graphite and polyvinylidene fluoride as a binder on both surfaces of a copper foil having a thickness of 0.02 mm.

【0018】また、セパレータには、厚み0.040mmのポ
リエチレン樹脂製微多孔膜を使用した。
The separator used was a microporous polyethylene resin membrane having a thickness of 0.040 mm.

【0019】電解液には、エチレンカーボネートとジエ
チルカーボネートの混合溶媒中に六フッ化リン酸リチウ
ムを1モル/lの割合で溶解したものを用いた。
As the electrolytic solution, a solution prepared by dissolving lithium hexafluorophosphate at a ratio of 1 mol / l in a mixed solvent of ethylene carbonate and diethyl carbonate was used.

【0020】以上のようにして組み立てた有機電解質電
池(1)を電池Aとする。
The organic electrolyte battery (1) assembled as described above is referred to as a battery A.

【0021】比較例 絶縁パッキングにポリプロピレン樹脂を使用する他は上
述電池Aと同様にして組み立てた電池を電池Bとする。
Comparative Example A battery assembled in the same manner as the battery A except that a polypropylene resin was used for the insulating packing was designated as a battery B.

【0022】実験1 電池A、電池Bについて熱衝撃試験を行った。Experiment 1 A battery A and a battery B were subjected to a thermal shock test.

【0023】試験方法は、−30℃で2時間保持し、次に
+70℃で2時間保持する。これを1サイクルとして、100
サイクル実施した後、電解液の漏液を調べた。試験数量
はそれぞれ10個である。表1にその結果を示す。
The test method is to hold at -30 ° C for 2 hours and then at + 70 ° C for 2 hours. This is one cycle, 100
After the cycle was performed, the leakage of the electrolyte was examined. The test quantity is 10 pieces each. Table 1 shows the results.

【0024】試験結果より、本発明であるPPSの絶縁パ
ッキングを使用した電池Aは漏液が認められなかった。
これは、本発明におけるPPS樹脂は、ガラス転移点が90
℃であることから、−30℃から+70℃の温度範囲では剛
性が変化せず、ナットの締め付けによる圧縮力に十分耐
えることができ、端子およびナットと蓋板とのシール性
が保持できるためであり、広い温度範囲における使用に
耐えうることがわかる。一方、従来のポリプロピレン樹
脂の絶縁パッキングを使用した電池Bは、漏液が60%発
生した。これは、ポリプロピレン樹脂のガラス転移点が
−10℃であることから、−10℃以下では樹脂の剛性が変
化し、ナットの圧縮力に耐えることができず、端子およ
びナットと蓋板とのシール性が保持できなかったためと
考えられる。
From the test results, no leakage was observed in the battery A using the PPS insulating packing of the present invention.
This is because the PPS resin of the present invention has a glass transition point of 90.
Because the temperature is in ° C, the rigidity does not change in the temperature range of -30 ° C to + 70 ° C, it can sufficiently withstand the compressive force caused by tightening the nut, and the sealing property between the terminal and nut and the cover plate can be maintained. It can be seen that it can be used in a wide temperature range. On the other hand, the battery B using the conventional insulating packing made of polypropylene resin leaked 60%. This is because the glass transition point of polypropylene resin is −10 ° C., and at −10 ° C. or lower, the rigidity of the resin changes and cannot withstand the compressive force of the nut. It is considered that the sex was not maintained.

【0025】実験2 電池A、電池Bについて下記条件にて振動試験を行った。Experiment 2 A battery A and a battery B were subjected to a vibration test under the following conditions.

【0026】加速度 :10G 振動数 :11.7〜100Hz(15分/往復のリニアスイープ) 時間 :10時間 印可軸 :3軸 試験数量はそれぞれ10個である。表2にその結果を示
す。
Acceleration: 10 G Frequency: 11.7 to 100 Hz (15 minutes / reciprocal linear sweep) Time: 10 hours Applicable axis: 3 axes The test quantity is 10 pieces each. Table 2 shows the results.

【0027】試験結果より、本発明の絶縁パッキングを
使用した電池Aには漏液が認められなかった。これよ
り、該パッキングは、ナット(7)の締め付けによる圧
縮力に十分耐え、振動を加えても端子およびナットと蓋
板とのシール性が保持されており、耐震性に優れている
ことがわかる。一方、従来のポリプロピレン樹脂の絶縁
パッキングを使用した電池Bは、漏液が50%発生した。
このことから、ポリプロピレン樹脂の絶縁パッキングの
シール性は、振動に耐えうるものでないことがわかる。
From the test results, no leakage was observed in the battery A using the insulating packing of the present invention. From this, it can be seen that the packing sufficiently withstands the compressive force caused by the tightening of the nut (7), maintains the sealing properties between the terminal and the nut and the cover plate even when vibration is applied, and is excellent in earthquake resistance. . On the other hand, in the battery B using the conventional polypropylene resin insulating packing, 50% of the liquid leakage occurred.
From this, it is understood that the sealing property of the insulating packing of the polypropylene resin is not one that can withstand vibration.

【0028】なお、本実施例では、PPSの絶縁パッキン
グを使用する電池の形状を長円筒型としたが、角型、円
筒型など、形に制限なく適用可能である。
In the present embodiment, the shape of the battery using the PPS insulating packing is a long cylindrical shape, but the present invention can be applied to any shape such as a square shape or a cylindrical shape.

【0029】また、上記温度変化の際に振動が加わる場
合においても、本発明の絶縁パッキングによるシール性
は保持される。
Further, even when vibration is applied at the time of the temperature change, the sealing performance of the insulating packing of the present invention is maintained.

【0030】[0030]

【表1】 [Table 1]

【表2】 [Table 2]

【発明の効果】以上詳述したように、本発明の実施によ
り、広い温度範囲において端子およびナットと蓋板との
シール性を保持した有機電解質電池を提供することがで
きる。また、車載運用などで発生する振動条件下であっ
ても、十分なシール性を確保しうる有機電解質電池を提
供することができる。
As described above in detail, by implementing the present invention, it is possible to provide an organic electrolyte battery having a good sealing property between the terminal and the nut and the cover plate in a wide temperature range. Further, it is possible to provide an organic electrolyte battery capable of ensuring a sufficient sealing property even under vibration conditions generated in in-vehicle operation or the like.

【図面の簡単な説明】[Brief description of the drawings]

【図1】長円筒型有機電解質電池の平面図および縦断面
図。
FIG. 1 is a plan view and a longitudinal sectional view of a long cylindrical organic electrolyte battery.

【図2】長円筒型有機電解質電池における端子の組み立
てを示す図。
FIG. 2 is a view showing the assembly of terminals in a long cylindrical organic electrolyte battery.

【符号の説明】 1 長円筒型有機電解質電池 2 電池ケース 3 正極端子 4 負極端子 5 蓋板 6 絶縁パッキング 7 ナット 8 Oリング 9 貫通孔[Explanation of symbols] 1 Long cylindrical organic electrolyte battery 2 Battery case 3 Positive terminal 4 Negative terminal 5 Cover plate 6 Insulation packing 7 Nut 8 O-ring 9 Through hole

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】貫通孔(9)を有する蓋板(5)の該貫通孔
(9)に設けられている正極端子(3)または負極端子
(4)が、絶縁パッキング(6)を介してナット(7)で
蓋板に締結されてなる有機電解質電池(1)において、
前記絶縁パッキング(6)がポリフェニレンサルファイ
ド樹脂であることを特徴とする有機電解質電池。
A positive electrode terminal (3) or a negative electrode terminal (4) provided in a through-hole (9) of a cover plate (5) having a through-hole (9) is connected via an insulating packing (6). In the organic electrolyte battery (1) fastened to the cover plate with the nut (7),
An organic electrolyte battery, wherein the insulating packing (6) is a polyphenylene sulfide resin.
【請求項2】上記ポリフェニレンサルファイド樹脂の分
子量が40000以上60000以下であることを特徴とする有機
電解質電池。
2. An organic electrolyte battery, wherein the molecular weight of the polyphenylene sulfide resin is from 40,000 to 60,000.
JP10226530A 1998-07-27 1998-07-27 Organic electrolyte battery Pending JP2000048803A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10226530A JP2000048803A (en) 1998-07-27 1998-07-27 Organic electrolyte battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10226530A JP2000048803A (en) 1998-07-27 1998-07-27 Organic electrolyte battery

Publications (1)

Publication Number Publication Date
JP2000048803A true JP2000048803A (en) 2000-02-18

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP10226530A Pending JP2000048803A (en) 1998-07-27 1998-07-27 Organic electrolyte battery

Country Status (1)

Country Link
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