JP2000034800A - Soft foamed fiber plate and its manufacture - Google Patents

Soft foamed fiber plate and its manufacture

Info

Publication number
JP2000034800A
JP2000034800A JP20175498A JP20175498A JP2000034800A JP 2000034800 A JP2000034800 A JP 2000034800A JP 20175498 A JP20175498 A JP 20175498A JP 20175498 A JP20175498 A JP 20175498A JP 2000034800 A JP2000034800 A JP 2000034800A
Authority
JP
Japan
Prior art keywords
fiberboard
foaming
based thermoplastic
foaming agent
thermoplastic resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP20175498A
Other languages
Japanese (ja)
Inventor
Mitsugi Kuramochi
貢 倉持
Tatsumi Ota
達見 太田
Hiroshi Nachi
博司 名知
Takeshi Okazawa
岳 岡澤
Hiroichi Sugiyama
博一 杉山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shimizu Construction Co Ltd
Shimizu Corp
Original Assignee
Shimizu Construction Co Ltd
Shimizu Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shimizu Construction Co Ltd, Shimizu Corp filed Critical Shimizu Construction Co Ltd
Priority to JP20175498A priority Critical patent/JP2000034800A/en
Publication of JP2000034800A publication Critical patent/JP2000034800A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide a soft foamed fiber plate with a lighter weight which resolves VOC problems and improves in temperature retaining performance and sound absorbing characteristic. SOLUTION: A soft foamed fiber plate 1 which is formed of wood fibers 2 and polyolefin based thermoplastic resin cullets 3 as raw materials in a foaming and molding method using physical foaming agent is manufactured by mixing the wood fibers 2 crushed into rod chips with resin foaming body for foaming mold in an extrusion foaming method using the physical foaming agent and cutting into specified forms. In this case, the wood fibers 2 and the polyolefin based thermoplastic resin cullets 3 are obtained by recycling industrial waste including wood frames and cured films of glasses or others, resulting in pollution issues and cost related problems to be improved.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、軟質繊維板に関
し、特に断熱、遮音特性に優れVOC問題を解決した軽
量の軟質発泡繊維板に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a soft fiberboard, and more particularly to a lightweight soft foamed fiberboard having excellent heat insulation and sound insulation properties and solving the VOC problem.

【0002】[0002]

【従来の技術】最近の木質系材料は、一般に図4に示す
ように、木材繊維20を原料にし、これに耐水剤と接着
剤21を加えて成形した繊維板22を中心にしている。
繊維板22は、そのかさ比重で区分されており、0.4
kg/lのものは軟質繊維板といわれている。この軟質
繊維板は、主として保温あるいは吸音用として使用され
るほか、畳床用として使用されている。しかし、現状の
軟質繊維板は、かさ比重0.4kg/l、熱伝導率が
0.55W/m・Kとポリスチレンフォーム等の有機系
発泡保温剤と比較して、重量も熱伝導率も10倍程度劣
っており、保温性能は必ずしも高くない。又、接着剤か
ら発生するホルムアルデヒド等の揮発性有機物質(VO
C)が、人体に悪影響を与えることが指摘され、問題視
される事態が現実に発生している。
2. Description of the Related Art As shown in FIG. 4, recent wood-based materials generally include a fiberboard 22 formed by using a wood fiber 20 as a raw material and adding a water resistant agent and an adhesive 21 thereto.
The fiberboard 22 is classified by its bulk specific gravity,
Those with a weight of kg / l are called soft fiberboard. This soft fiber board is mainly used for heat insulation or sound absorption, and is also used for tatami floors. However, the current soft fiber board has a bulk specific gravity of 0.4 kg / l, a thermal conductivity of 0.55 W / m · K, and a weight and a thermal conductivity of 10 5 compared to an organic foamed heat insulator such as polystyrene foam. It is inferior by a factor of two, and the heat retention performance is not always high. In addition, volatile organic substances such as formaldehyde generated from the adhesive (VO)
It has been pointed out that C) has an adverse effect on the human body, and a problematic situation has actually occurred.

【0003】こうしたシックビルディング症候群が発生
した背景としては、有機系高分子材料の開発・普及や快
適な住環境を目指し建物の気密性を進歩させてきた状況
が挙げられるものの、上記のように問題視される状況下
では、人に優しい内装材をキャッチフレーズにした健康
住宅の販売を始めとして、改めて地球環境問題が建築業
界にもクローズアップされている。そして、現状の軟質
繊維板が上述のようにバインダーとして接着剤を使用し
ていることからVOC問題とは無関係でなく、改善策を
追求しなければならない。
The background of the occurrence of such sick building syndrome includes the development and spread of organic polymer materials and the improvement of the airtightness of buildings with the aim of providing a comfortable living environment. Under such circumstances, global environmental issues have been highlighted again in the construction industry, starting with the sale of healthy homes that use human-friendly interior materials as a catchphrase. Since the current soft fiberboard uses an adhesive as a binder as described above, it is not irrelevant to the VOC problem and an improvement measure must be pursued.

【0004】一方、リサイクル法の施行により、産業界
ではリサイクルの推進が活発になってきており、地球環
境問題としても温暖化、ダイオキシンの発生防止の観点
から、産業廃棄物の焼却処分も自由にならない状況下に
ある。従って、軟質繊維板を含む内装仕上材や仕上用下
地材についてもリサイクルの推進を図る段階に至ってい
る。
On the other hand, with the enforcement of the Recycling Law, recycling is being promoted in the industrial world, and from the viewpoint of preventing global warming and the generation of dioxins, incineration of industrial waste is also free. Under no circumstances. Therefore, it has reached the stage of promoting recycling of interior finishing materials including soft fiber boards and finishing base materials.

【0005】[0005]

【発明が解決しようとする課題】本発明は、VOC問題
を解決し保温性能と吸音特性とを向上させて軽量化を図
った軟質発泡繊維板を提供しょうとするものである。
SUMMARY OF THE INVENTION An object of the present invention is to provide a flexible foamed fiberboard which solves the VOC problem, improves the heat insulation performance and the sound absorption characteristics, and reduces the weight.

【0006】[0006]

【課題を解決するための手段】本発明による軟質発泡繊
維板は、木質繊維及びポリオレフィン系熱可塑性樹脂カ
レットを原材料にし物理的発泡剤を用いて発泡成形する
ものであり、その製造は棒状チップに粉砕した木質繊維
を樹脂発泡体と混合して、物理的発泡剤を使用する押出
発泡法で発泡成形させてから、所定形状に切り出して行
うものである。
The flexible foamed fiberboard according to the present invention is made of wood fiber and a polyolefin-based thermoplastic resin cullet as raw materials and is foam-formed using a physical foaming agent. The method is performed by mixing crushed wood fibers with a resin foam, subjecting the mixture to foam molding by an extrusion foaming method using a physical foaming agent, and then cutting out to a predetermined shape.

【0007】[0007]

【発明の実施の形態】本発明による軟質発泡繊維板1
は、図1に示すように、木質繊維2とポリオレフィン系
熱可塑性樹脂カレット3とを原材料として用いており、
これに物理的発泡剤5を添加して発泡させることで、加
工するための素材7を成形している。素材7は、所定の
寸法に切り出すことで床用下地材や吸音パネルの芯材7
として適宜加工されて最終的に商品化されている。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A flexible foamed fiberboard 1 according to the present invention.
As shown in FIG. 1, wood fiber 2 and polyolefin-based thermoplastic resin cullet 3 are used as raw materials,
The material 7 to be processed is formed by adding the physical foaming agent 5 and foaming. The material 7 is cut into a predetermined size to obtain a floor base material or a core material 7 for a sound absorbing panel.
It is appropriately processed and finally commercialized.

【0008】木質繊維2は、主として熱帯材から得られ
るが、産業廃棄物や都市ごみから選別された合板型枠の
残材、木工場の削りカス等の木材廃棄物の再利用材を含
めて採用することができる。木質繊維2の原料として
は、上記木材を絶乾の見かけ比重0.8kg/l、粒径
1〜3mm、長さ3〜5mm程度の棒状チップに粉砕し
たものを用いる。
The wood fibers 2 are mainly obtained from tropical materials, but include recycled materials of wood wastes such as plywood form materials selected from industrial waste and municipal waste, and shavings from wood factories. Can be adopted. The raw material of the wood fiber 2 is obtained by pulverizing the above wood into rod-shaped chips having an apparent specific gravity of 0.8 kg / l, a particle diameter of 1 to 3 mm, and a length of about 3 to 5 mm.

【0009】もう一方の原料であるポリオレフィン系熱
可塑性樹脂カレット3としては、ポリエチレン、ポリプ
ロピレン、塩化ビニール等の熱可塑性樹脂を使用してお
り、これに蒸発型発泡剤を添加して発泡倍率5〜20倍
程度に発泡させた樹脂発泡体4として製造工程を形成し
ている。
As the other raw material, the polyolefin-based thermoplastic resin cullet 3, a thermoplastic resin such as polyethylene, polypropylene, vinyl chloride or the like is used. The manufacturing process is formed as a resin foam 4 foamed about 20 times.

【0010】ポリオレフィン系熱可塑性樹脂も又、産業
廃棄物を再利用することで対応できる。即ち、建物の新
築現場からは、ガラス、サッシ等の養生フイルムとして
用いたポリオレフィン系熱可塑性樹脂の成型品が廃棄さ
れるので、これを分別して置いて樹脂発泡体4の原料と
して使用できるからである。なお、蒸発型発泡剤とは、
別名物理的発泡剤5とも称されるものであり、飽和炭化
水素系、フッ素系及び塩素系等の常温では50〜100
℃で気体になる炭化水素を用いている。
[0010] Polyolefin-based thermoplastic resins can also be handled by reusing industrial waste. That is, since a molded product of a polyolefin-based thermoplastic resin used as a curing film such as a glass and a sash is discarded from a new construction site of a building, the molded product can be separated and used as a raw material of the resin foam 4. is there. In addition, the evaporation type foaming agent is
Also known as a physical blowing agent 5, which is 50 to 100 at room temperature such as a saturated hydrocarbon type, a fluorine type and a chlorine type.
Uses hydrocarbons that become gas at ° C.

【0011】軟質発泡繊維板1は、床用下地材や吸音パ
ネルの芯材として商品化されるものであるから、その用
途に応じて曲げ強度や靱性を調整している。例えば、床
用下地材や吸音パネルの芯材の用に軽量を主眼にする場
合には、その配合を、容積比で木質繊維:樹脂発泡体=
1:0.5〜2とし、木質繊維+樹脂発泡体:空気=
1:5〜20の範囲で発泡させることで製造している。
この他にも、破壊までの強度や剛性が必要な場合には、
樹脂発泡体の発泡倍率を下げて曲げ強度を上げたり、薄
板で変形能力を必要とする場合には、木質繊維に対する
樹脂発泡体の配合比を上げて靱性を上げることで対処す
るという具合に、商品であるボードへの様々な要求に対
しても、その配合を変えることで対応可能である。
Since the flexible foamed fiberboard 1 is commercialized as a base material for a floor or a core material of a sound absorbing panel, the bending strength and the toughness are adjusted according to the use. For example, in the case where the main purpose is to reduce the weight of the base material for floors or the core material of the sound-absorbing panel, the composition is determined by volume ratio of wood fiber: resin foam =
1: 0.5 to 2, wood fiber + resin foam: air =
It is manufactured by foaming in the range of 1: 5 to 20.
In addition to this, when strength and rigidity to failure are required,
If the expansion ratio of the resin foam is lowered to increase the bending strength, or if the deformability is required in a thin plate, it will be dealt with by increasing the compounding ratio of the resin foam to the wood fiber to increase the toughness, It is possible to respond to various demands for commercial boards by changing the composition.

【0012】次に、本発明による軟質発泡繊維板の製造
方法を図1、2に基づいて説明する。図1は、製造工程
の前段を説明するための概要図である。軟質発泡繊維板
1の製造は、第1に、ポリオレフィン系熱可塑性樹脂3
を原料に物理的発泡剤5を添加して5〜20倍程度に発
泡させて樹脂発泡体4を製造することから始まる。この
段階で、商品化される用途に対応して、押し出す加工素
材7の剛性、曲げ強度や靱性を所定の値にするために添
加率と発泡率とを調整している。第2の製造工程は、樹
脂発泡体4を溶融釜8に移して充分に溶融し、溶融状態
の樹脂発泡体4の中に、見かけ比重0.8kg/l、粒
径1〜3mm、長さ3〜5mm程度の棒状チップに粉砕
した木質繊維2を混入して攪拌することで、均一な混合
体6を製造する工程である。この工程においても、木質
繊維と樹脂発泡体との混入割合を容積比で調整し所定の
特性を保有するように調整している。
Next, a method for producing a flexible foamed fiberboard according to the present invention will be described with reference to FIGS. FIG. 1 is a schematic diagram for explaining the first stage of the manufacturing process. First, the production of the flexible foamed fiberboard 1 is performed by using a polyolefin-based thermoplastic resin 3.
Is started by producing a resin foam 4 by adding a physical foaming agent 5 to the raw material and foaming it by about 5 to 20 times. At this stage, the addition ratio and the foaming ratio are adjusted in order to set the rigidity, bending strength and toughness of the extruded material 7 to predetermined values according to the application to be commercialized. In the second manufacturing process, the resin foam 4 is transferred to the melting pot 8 and sufficiently melted, and the apparent specific gravity is 0.8 kg / l, the particle size is 1 to 3 mm, and the length is in the molten resin foam 4. This is a step of producing a uniform mixture 6 by mixing and agitating the crushed wood fiber 2 into a rod-shaped chip of about 3 to 5 mm. Also in this step, the mixing ratio of the wood fiber and the resin foam is adjusted by the volume ratio so as to maintain predetermined characteristics.

【0013】図2に示す製造工程後半の第3の製造工程
では、上記の均一な混合体6を高圧押出機9に投入し、
空気10を供給しながら高圧を加えて、混合体6の中に
空気を圧入する比率を調整している。次いで所定の加圧
後に、混合体6を高圧押出機9のダイ11を通して大気
中に連続的に押し出し商品として加工するための素材7
を押し出している。第4の製造工程は、発泡素材7を要
求性能の異なる製造ゴット毎に整理し、切削加工機12
に導入して切り出し加工を行い、所定の商品13に仕上
げるものである。
In a third manufacturing step in the latter half of the manufacturing step shown in FIG. 2, the uniform mixture 6 is charged into a high-pressure extruder 9,
While supplying air 10, high pressure is applied to adjust the ratio of pressurizing air into the mixture 6. Then, after a predetermined pressurization, the raw material 7 for continuously extruding the mixture 6 through the die 11 of the high-pressure extruder 9 into the atmosphere and processing it as a product.
Is extruded. In the fourth manufacturing process, the foaming material 7 is arranged for each manufacturing got having different required performance, and the cutting machine 12 is used.
, And cut out to finish a predetermined product 13.

【0014】本発明による軟質発泡繊維板1は、特性面
においても以下のような優れた性能を備えている。 かさ比重が、0.1〜0.2kg/lの範囲で、軽量
化が達成されている。 熱伝導率が、0.10〜0.30W/m・Kの範囲
で、優れた保温性能を有している。 繊維板内部の空気含有量が増加したので、吸音特性が
向上している。 樹脂発泡体の発泡倍率、木質繊維と樹脂発泡体との添
加率及び空気の含有率を制御して、商品の用途に合わせ
た、剛性、靱性、曲げ強度を繊維板に付与できる。
The flexible foamed fiberboard 1 according to the present invention also has the following excellent properties in terms of characteristics. Weight reduction is achieved when the bulk specific gravity is in the range of 0.1 to 0.2 kg / l. When the thermal conductivity is in the range of 0.10 to 0.30 W / m · K, it has excellent heat retention performance. Since the air content inside the fiberboard has increased, the sound absorption characteristics have been improved. By controlling the expansion ratio of the resin foam, the addition ratio of the wood fiber and the resin foam, and the content of air, rigidity, toughness, and flexural strength suitable for the use of the product can be imparted to the fiberboard.

【0015】[0015]

【発明の効果】本発明による軟質発泡繊維板は、木質繊
維及びポリオレフィン系熱可塑性樹脂カレットを原材料
にし物理的発泡剤を用いて発泡成形するものであり、そ
の製造は棒状チップに粉砕した木質繊維を樹脂発泡体と
混合して、物理的発泡剤を使用する押出発泡法で発泡成
形させてから、所定形状に切り出して行うものであるか
ら、以下の効果を発揮できる。 住宅の床下地に使用すると、床暖房の熱効率が上が
り、光熱費の節約と省エネルギーになる。 作業現場
で用いる囲い板の芯材として使用すれば、軽量で吸音性
能の高い 仮設材になる。 木質系産業廃棄物を焼却せずに再利用できるので、C
O2等の環境問題とコスト面の改善を図れる。 養生フィルムを再利用できるので、産業廃棄物の減容
化とコストダウンが図れる。 改修・解体現場から回収し軟質発泡繊維板として再生
できるので、数回のリサイクルが可能になる。
The flexible foamed fiberboard according to the present invention is made by foaming a wood fiber and a polyolefin-based thermoplastic resin cullet as raw materials using a physical foaming agent. Is mixed with a resin foam, foamed by an extrusion foaming method using a physical foaming agent, and then cut out into a predetermined shape, so that the following effects can be exhibited. When used as a flooring in a house, the thermal efficiency of floor heating increases, saving on energy costs and saving energy. If used as the core material of the shroud used at the work site, it becomes a temporary material that is lightweight and has high sound absorption performance. Since wood-based industrial waste can be reused without incineration, C
Environmental problems such as O2 and cost can be improved. Since the curing film can be reused, industrial waste can be reduced in volume and cost. Since it can be recovered from renovation and demolition sites and regenerated as soft foamed fiberboard, it can be recycled several times.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明による軟質発泡繊維板FIG. 1 is a flexible foamed fiberboard according to the present invention.

【図2】軟質発泡繊維板の前段の製造工程FIG. 2 is a manufacturing process of a first stage of a flexible foamed fiberboard;

【図3】軟質発泡繊維板の後段の製造工程FIG. 3 is a manufacturing process at a later stage of a flexible foamed fiber board;

【図4】従来の軟質繊維板FIG. 4 is a conventional soft fiberboard.

【符号の説明】[Explanation of symbols]

1 軟質発泡繊維板 20
木材繊維 2 木質繊維 21
接着剤 3 ポリオレフィン系熱可塑性樹脂カレット 22
繊維板 4 樹脂発泡体 5 物理的発泡剤 6 混合体 7 発泡素材 8 溶融釜 9 高圧押出機 10 空気 11 高圧押出機のダイ 12 切削加工機 13 商品
1 Flexible foam fiberboard 20
Wood fiber 2 Wood fiber 21
Adhesive 3 Polyolefin-based thermoplastic resin cullet 22
Fiberboard 4 Resin foam 5 Physical foaming agent 6 Mixture 7 Foam material 8 Melting pot 9 High pressure extruder 10 Air 11 High pressure extruder die 12 Cutting machine 13 Product

───────────────────────────────────────────────────── フロントページの続き (72)発明者 名知 博司 東京都港区芝浦一丁目2番3号 清水建設 株式会社内 (72)発明者 岡澤 岳 東京都港区芝浦一丁目2番3号 清水建設 株式会社内 (72)発明者 杉山 博一 東京都港区芝浦一丁目2番3号 清水建設 株式会社内 Fターム(参考) 2E001 AA02 AB02 AC01 AD01 BA03 BA05 2E162 BA06 CD01 FC03 4F074 AA02L AA16L AA17L AA24L AA35L AE01 AE04 BA31 BA35 BA42 BA53 CA22 CC03X CC22X DA02 DA07 DA32 DA57 DA58  ──────────────────────────────────────────────────続 き Continuing on the front page (72) Hiroshi Nachi, 1-3-2 Shibaura, Minato-ku, Tokyo Shimizu Corporation Inside (72) Takeshi Okazawa 1-2-3, Shibaura, Minato-ku, Tokyo Shimizu Corporation (72) Inventor Hirokazu Sugiyama 1-3-2 Shibaura, Minato-ku, Tokyo Shimizu Corporation F-term (reference) 2E001 AA02 AB02 AC01 AD01 BA03 BA05 2E162 BA06 CD01 FC03 4F074 AA02L AA16L AA17L AA24L AA35L AE01 AE04 BA31 BA35 BA42 BA53 CA22 CC03X CC22X DA02 DA07 DA32 DA57 DA58

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 木質繊維及びポリオレフィン系熱可塑性
樹脂カレットを原材料にし物理的発泡剤を用いて発泡成
形する軟質発泡繊維板。
1. A flexible foamed fiberboard which is made of wood fiber and cullet of a polyolefin-based thermoplastic resin as raw materials and foam-formed using a physical foaming agent.
【請求項2】 木質繊維が木質廃材であることを特徴と
する請求項1に記載の軟質発泡繊維板。
2. The flexible foamed fiberboard according to claim 1, wherein the wood fiber is wood waste material.
【請求項3】 ポリオレフィン系熱可塑性樹脂カレット
が養生フィルムの廃材であることを特徴とする請求項1
に記載の軟質発泡繊維板。
3. The cullet of a polyolefin-based thermoplastic resin is a waste material of a cured film.
4. The flexible foamed fiberboard according to item 1.
【請求項4】 棒状チップに粉砕した木質繊維を樹脂発
泡体と混合して、押出発泡法で発泡成形させてから、所
定形状に切り出しする軟質発泡繊維板の製造方法。
4. A method for producing a flexible foamed fiberboard in which wood fibers crushed into rod-shaped chips are mixed with a resin foam, foamed by extrusion foaming, and then cut into a predetermined shape.
【請求項5】 樹脂発泡体は、ポリオレフィン系熱可塑
性樹脂カレットに蒸発型発泡剤を添加して発泡させて成
ることを特徴とする請求項4に記載の軟質発泡繊維板の
製造方法。
5. The method for producing a flexible foamed fiberboard according to claim 4, wherein the resin foam is formed by adding an evaporating foaming agent to a polyolefin-based thermoplastic resin cullet and foaming.
【請求項6】 蒸発型発泡剤が物理的発泡剤であること
を特徴とする請求項5に記載の軟質発泡繊維板の製造方
法。
6. The method according to claim 5, wherein the evaporative foaming agent is a physical foaming agent.
JP20175498A 1998-07-16 1998-07-16 Soft foamed fiber plate and its manufacture Pending JP2000034800A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20175498A JP2000034800A (en) 1998-07-16 1998-07-16 Soft foamed fiber plate and its manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20175498A JP2000034800A (en) 1998-07-16 1998-07-16 Soft foamed fiber plate and its manufacture

Publications (1)

Publication Number Publication Date
JP2000034800A true JP2000034800A (en) 2000-02-02

Family

ID=16446392

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20175498A Pending JP2000034800A (en) 1998-07-16 1998-07-16 Soft foamed fiber plate and its manufacture

Country Status (1)

Country Link
JP (1) JP2000034800A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1657375A1 (en) * 2004-11-16 2006-05-17 Kronotec Ag Insulating plate
JP2006522247A (en) * 2003-03-31 2006-09-28 ファン デン ドンケル コーネリス Column protection assembly
JP2007056176A (en) * 2005-08-26 2007-03-08 Daicel Polymer Ltd Fiber reinforced foamable resin composition and foamed molding therefrom
JP2007308583A (en) * 2006-05-18 2007-11-29 Sekisui Chem Co Ltd Sound absorbing material

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006522247A (en) * 2003-03-31 2006-09-28 ファン デン ドンケル コーネリス Column protection assembly
EP1657375A1 (en) * 2004-11-16 2006-05-17 Kronotec Ag Insulating plate
US7998442B2 (en) 2004-11-16 2011-08-16 Kronotec Ag Sound insulating board
JP2007056176A (en) * 2005-08-26 2007-03-08 Daicel Polymer Ltd Fiber reinforced foamable resin composition and foamed molding therefrom
JP2007308583A (en) * 2006-05-18 2007-11-29 Sekisui Chem Co Ltd Sound absorbing material

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