JP2000007520A - Antimicrobial cosmetic - Google Patents
Antimicrobial cosmeticInfo
- Publication number
- JP2000007520A JP2000007520A JP17609598A JP17609598A JP2000007520A JP 2000007520 A JP2000007520 A JP 2000007520A JP 17609598 A JP17609598 A JP 17609598A JP 17609598 A JP17609598 A JP 17609598A JP 2000007520 A JP2000007520 A JP 2000007520A
- Authority
- JP
- Japan
- Prior art keywords
- antibacterial
- zeolite
- cosmetic
- cosmetics
- antimicrobial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】この発明は抗菌性化粧料に関
し、より詳しくは抗菌性ゼオライトを用いた基礎化粧品
などに利用される抗菌性化粧料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an antibacterial cosmetic, and more particularly, to an antibacterial cosmetic used for basic cosmetics using an antibacterial zeolite.
【０００２】[0002]
【従来の技術】一般に、化粧品は微生物を成育可能な水
や栄養分を含んでおり、その使用の度に化粧品を取りだ
して使用するため、大気中に遊離する微生物が開栓され
た化粧品に混入したり、手や指先と接触させた化粧品が
容器内へ戻されることより、手や指先等の表面に付着し
た微生物が混入する可能性が高い。2. Description of the Related Art In general, cosmetics contain water and nutrients capable of growing microorganisms. Since the cosmetics are taken out and used each time the cosmetics are used, microorganisms released into the atmosphere are mixed into the opened cosmetics. Or, the cosmetics that have been brought into contact with the hand or fingertip are returned into the container, so that there is a high possibility that microorganisms adhering to the surface of the hand or fingertip may be mixed.
【０００３】また、一般に化粧品の１回当たりの使用量
は、容器内に充填された量に比較して少ないため、消費
者が化粧品を使用し始めてから使用し終わるまでに化粧
品を取り出す頻度が極めて高く、使いきるまでに長時間
を経過することが多い。[0003] In addition, since the amount of cosmetics used per serving is generally smaller than the amount filled in a container, the frequency with which consumers take out cosmetics from the start of using cosmetics to the end of using the cosmetics is extremely high. They are expensive and often take a long time to run out.
【０００４】したがって、化粧品はカビや細菌などの微
生物により使用中に変質し易いという問題があり、クリ
ーム、乳液、化粧水などの基礎化粧品に抗菌効果を付与
し保存性を高めるために、防腐剤を加えることが試みら
れている。[0004] Therefore, cosmetics have a problem that they are easily degraded during use by microorganisms such as molds and bacteria. In order to impart an antibacterial effect to basic cosmetics such as creams, milky lotions and lotions and to improve the preservability, preservatives are used. Has been attempted.
【０００５】現在、知られている化粧品用防腐剤として
は、カチオン活性剤、フェノール類、ソルビン酸塩、サ
リチル酸塩、デヒドロ酢酸塩等の有機系防腐剤がある
が、これらを規定量添加してもカビや酵母の発生を防止
するには充分ではなく、添加量を多くしたり、顕著な効
果を示すものを使用したりすると皮膚刺激の問題を生じ
ることもある。At present, known preservatives for cosmetics include cationic preservatives, organic preservatives such as phenols, sorbates, salicylates, dehydroacetates, etc. However, it is not enough to prevent the generation of mold and yeast, and if the amount of addition is large or a substance having a remarkable effect is used, a problem of skin irritation may occur.
【０００６】また、化粧品中で発生しやすい、大腸菌や
緑膿菌等は、耐性菌ができやすいため、規定量添加して
も腐敗を生じることもある。[0006] Escherichia coli, Pseudomonas aeruginosa and the like, which are liable to occur in cosmetics, are liable to form resistant bacteria.
【０００７】一方、抗菌性ゼオライトを有機系防腐剤の
代替材料として頭髪化粧品に利用する技術が知られてい
る（特開昭６０−１７４７００７号公報）。On the other hand, there is known a technique in which an antibacterial zeolite is used in hair cosmetics as a substitute for an organic preservative (Japanese Patent Application Laid-Open No. Sho 60-1747007).
【０００８】[0008]
【発明が解決しようとする課題】しかし、有機系防腐剤
の代替材料として抗菌性ゼオライトを化粧品に配合する
と、経時的に再凝集や沈殿を生じ、これに伴って抗菌作
用の低下がみられるので、実際の使用に充分に耐える抗
菌性化粧料は得られなかった。However, when an antibacterial zeolite is added to cosmetics as a substitute for an organic preservative, re-agglomeration or precipitation occurs with the passage of time, and the antibacterial action is reduced with this. However, an antibacterial cosmetic which can sufficiently withstand actual use was not obtained.
【０００９】また、金属担持ゼオライトは微粒子化する
（特に粒径１．０μｍ以下に微粒子化する）と金属イオ
ンを担持し難くなって不安定化し、そのために抗菌作用
が低下するという問題もあった。Further, when the metal-supported zeolite is formed into fine particles (particularly, when the particle size is reduced to 1.0 μm or less), it becomes difficult to carry metal ions and the metal ions become unstable, and therefore, there is a problem that the antibacterial action is reduced. .
【００１０】そこで、この発明の課題は、金属担持ゼオ
ライトを用いて、カビ、酵母、大腸菌及び緑膿菌等など
の微生物に対して充分に発育防止効果を有する抗菌性化
粧料を提供することである。Accordingly, an object of the present invention is to provide an antibacterial cosmetic having a sufficient growth inhibitory effect against microorganisms such as mold, yeast, Escherichia coli and Pseudomonas aeruginosa using a metal-supported zeolite. is there.
【００１１】上記課題をより詳細に説明すると、この発
明の課題は、基礎化粧料などの化粧料中の抗菌性ゼオラ
イトに再凝集や沈殿起こさせず、経時的に抗菌作用の安
定した抗菌性化粧料とすることであり、特に化粧料中に
配合した粒径１．０μｍ以下の微粒子状の抗菌性ゼオラ
イトの抗菌作用を向上させると共に、抗菌作用を経時的
に安定させ、保存性に優れた抗菌性化粧料を提供するこ
とである。The object of the present invention will be described in more detail. An object of the present invention is to provide an antibacterial cosmetic having a stable antibacterial action over time without causing re-aggregation or precipitation of the antibacterial zeolite in cosmetics such as basic cosmetics. In particular, the antibacterial action of fine-particle antibacterial zeolite having a particle size of 1.0 μm or less incorporated in cosmetics is improved, and the antibacterial action is stabilized with time, and the antibacterial agent has excellent storage stability. Is to provide sexual cosmetics.
【００１２】[0012]
【課題を解決するための手段】上記の課題を解決するた
めに、本願の発明では、微粒子状の抗菌性ゼオライト
０．０００１〜１０重量％、２価以上の多価アルコール
もしくは糖類または両者併用した混合物１〜５０重量
％、有機酸もしくはその塩類または両者併用した混合物
０．１〜５０重量％および水を必須成分として含有する
抗菌性化粧料としたのである。In order to solve the above-mentioned problems, in the present invention, 0.0001 to 10% by weight of fine-particle antibacterial zeolite, a dihydric or higher polyhydric alcohol or a saccharide, or both of them are used. An antibacterial cosmetic containing 1 to 50% by weight of a mixture, 0.1 to 50% by weight of an organic acid or a salt thereof or a mixture of both, and water as essential components.
【００１３】上記抗菌性ゼオライトは、金属を担持した
粒径１．０μｍ以下の抗菌性ゼオライトを採用できる。
上記抗菌性化粧料は、乳化組成物（水−油エマルジョ
ン）や水溶液からなる抗菌性化粧料も含むものである。The antimicrobial zeolite may be a metal-supported antimicrobial zeolite having a particle size of 1.0 μm or less.
The antibacterial cosmetic includes an antibacterial cosmetic comprising an emulsified composition (water-oil emulsion) or an aqueous solution.
【００１４】この発明における特定の抗菌性金属イオン
を含有する微粒子状ゼオライトは、極微量でカビ、酵
母、細菌を問わず微生物全般に効果があり、そのものが
再凝集、沈殿を生じてしまうことにより抗菌作用が低下
する。The finely divided zeolite containing a specific antibacterial metal ion in the present invention is effective in a very small amount on microorganisms irrespective of molds, yeasts and bacteria, and causes reaggregation and sedimentation. Antibacterial activity is reduced.
【００１５】そして、この発明では、化粧料の必須成分
として微粒子状ゼオライトと共に分子内に水酸基が２個
以上、好ましくは分子内に水酸基が３個以上の多価アル
コールもしくは糖類と、有機酸またはその塩類を配合す
ることによって微粒子状ゼオライトの分散状態の経時変
化が極めて少ない抗菌性化粧料になり、微粒子状ゼオラ
イトの再凝集や沈殿が生じない抗菌性化粧料になる。In the present invention, a polyhydric alcohol or saccharide having two or more hydroxyl groups in the molecule, preferably three or more hydroxyl groups in the molecule together with the fine particle zeolite as an essential component of the cosmetic, and an organic acid or its organic acid. By blending the salts, an antibacterial cosmetic having an extremely small change in the dispersion state of the fine-particle zeolite over time can be obtained, and an antibacterial cosmetic without re-aggregation or precipitation of the fine-particle zeolite can be obtained.
【００１６】[0016]
【発明の実施の形態】この発明に用いる抗菌性ゼオライ
トは、下記の一般式（Ａ）で示される抗菌性の金属イオ
ンを担持したアルミノケイ酸塩からなるものである。な
お、銀を担持したものは銀ゼオライトとも称される。BEST MODE FOR CARRYING OUT THE INVENTION The antibacterial zeolite used in the present invention comprises an aluminosilicate supporting an antibacterial metal ion represented by the following general formula (A). In addition, what carried silver is also called silver zeolite.
【００１７】 （Ａ） ＭＸ2 ／ｎＯ・Ａｌ2 Ｏ3 ・ＹＳｉＯ2 ・ＺＨ2 Ｏ （式中、Ｍは銀イオン、銅イオン等の金属イオンを示
し、ｎは０〜６の整数であり、Ｘ、Ｙ、Ｚは各成分のモ
ル比を示す。） 抗菌性ゼオライトの粒子径は、小さいほど分散性がよ
く、かつ抗菌性も優れていて好ましく、この発明で所要
の抗菌性を得るための好ましい粒径は、１．０μｍ以
下、より好ましくは０．５μｍ以下である。(A) MX 2 /nO.Al 2 O 3 .YSiO 2 .ZH 2 O (wherein M represents a metal ion such as a silver ion or a copper ion, and n is an integer of 0 to 6, X, Y, and Z indicate the molar ratio of each component.) The smaller the particle size of the antibacterial zeolite, the better the dispersibility and the better the antibacterial property. The preferred particle size is 1.0 μm or less, more preferably 0.5 μm or less.
【００１８】化粧料中の微粒子状ゼオライトの配合量
は、０．０００１〜５０重量％が適当である。なぜな
ら、０．０００１重量％未満の配合割合では、化粧料に
所期した抗菌性を確実に発揮させることが困難になり、
５０重量％を越える配合割合では、抗菌性が安定しなく
なり好ましくないからである。The amount of the fine particle zeolite in the cosmetic is suitably from 0.0001 to 50% by weight. This is because, if the content is less than 0.0001% by weight, it is difficult to ensure that the desired antibacterial property of the cosmetic is exhibited.
If the compounding ratio exceeds 50% by weight, the antibacterial properties become unstable, which is not preferable.
【００１９】この発明に用いる多価アルコールは、下記
の（Ｂ）に例示されるような分子内に水酸基が２以上有
するグリコールなど、または水酸基が３個以上の糖アル
コールなどの多価アルコールである。またこの発明に用
いる糖類は、下記の（Ｂ）に例示されるような単糖類、
二糖類などのオリゴ糖の他、多糖類であってもよい。The polyhydric alcohol used in the present invention is a polyhydric alcohol such as a glycol having two or more hydroxyl groups in a molecule or a sugar alcohol having three or more hydroxyl groups as exemplified in the following (B). . Further, the saccharide used in the present invention is a monosaccharide as exemplified in the following (B),
In addition to oligosaccharides such as disaccharides, polysaccharides may be used.
【００２０】（Ｂ） エチレングリコール、ジエチレン
グリコール、トリエチレングリコール、ポリエチレング
リコール、プロピレングリコール、ポリプロピレングリ
コール、グリセリン、ジグリセリン、ポリグリセリン、
イソプレングリコール、１，３−ブチレングリコール、
ソルビトール、マンニトール、ブドウ糖、ショ糖、果
糖、キシリット、乳糖、マルトース、マルチトール、ト
レハロース等である。(B) ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, polypropylene glycol, glycerin, diglycerin, polyglycerin,
Isoprene glycol, 1,3-butylene glycol,
Sorbitol, mannitol, glucose, sucrose, fructose, xylit, lactose, maltose, maltitol, trehalose and the like.
【００２１】上述したような多価アルコールまたは糖類
のこの発明における配合量は、１〜５０重量％が適当で
ある。なぜなら、１重量％未満の少量では、抗菌性ゼオ
ライトを配合した化粧料に所期した抗菌性を安定して発
揮させることが困難であり、５０重量％を越えて配合す
ると、化粧料の肌触りなどの使用感が悪化して好ましく
ないからである。The amount of the polyhydric alcohol or saccharide as described above in the present invention is suitably 1 to 50% by weight. If the amount is less than 1% by weight, it is difficult to stably exhibit the desired antibacterial property of the cosmetic containing the antibacterial zeolite. This is because the feeling of use is deteriorated, which is not preferable.
【００２２】この発明に用いる有機酸またはその塩類
は、下記の（Ｃ）に示されるものである。The organic acids or salts thereof used in the present invention are those shown in the following (C).
【００２３】（Ｃ） クエン酸、乳酸、グリコール酸、
酒石酸、リンゴ酸等、およびこれらの塩類等であり、こ
のような有機酸もしくはその塩類または両者併用した混
合物の化粧料中の配合量は、０．０１〜５０重量％が適
当である。なぜなら、０．０１重量％未満の少量では、
抗菌性ゼオライトを配合した化粧料に所期した抗菌性を
安定して発揮させることが困難になり、５０重量％を越
えて配合すると、化粧料の肌触りなどの使用感が悪化し
て好ましくないからである。(C) citric acid, lactic acid, glycolic acid,
Tartaric acid, malic acid and the like, and salts thereof, and the like, and the amount of such an organic acid or a salt thereof or a mixture thereof in a cosmetic is suitably 0.01 to 50% by weight. Because, in a small amount less than 0.01% by weight,
It is difficult to stably exhibit the desired antibacterial properties of the cosmetics containing the antibacterial zeolite, and if the amount exceeds 50% by weight, the feeling of use of the cosmetics, such as the feel of the cosmetics, deteriorates. It is.
【００２４】因みに、基礎化粧料等の化粧料に単独で微
粒子状ゼオライトを配合すると、再凝集や沈殿を生じ、
そのことによって抗菌作用が低下した。By the way, when fine-particle zeolite is blended alone with cosmetics such as basic cosmetics, re-aggregation or precipitation occurs,
This reduced the antimicrobial activity.
【００２５】しかしながら、この発明においては、微粒
子状ゼオライトに対して、２価以上の多価アルコールも
しくは糖類または両者併用した混合物、および有機酸も
しくはその塩類または両者併用した混合物を配合するこ
とにより、再凝集や沈殿を生じることなく、抗菌作用が
持続することが認められた。However, in the present invention, the fine particles of zeolite are mixed with a polyhydric alcohol or saccharide having a valency of 2 or more, or a mixture of both, and an organic acid or a salt thereof, or a mixture of both to recycle. It was confirmed that the antibacterial action was continued without aggregation or precipitation.
【００２６】そして、単独で微粒子状ゼオライトを配合
するよりも、微粒子状ゼオライトと多価アルコール又は
糖類と有機酸又はその塩類を併用した方がさらに高い抗
菌作用を得ることができた。Further, a higher antibacterial effect could be obtained when the fine particle zeolite and the polyhydric alcohol or saccharide and the organic acid or salts thereof were used in combination than when the fine particle zeolite was blended alone.
【００２７】この発明は、特に水を多く含有する系や外
相が水相である系に有用であり、特に水−油のエマルジ
ョンや水溶液状の化粧料に適用できるものである。すな
わち、この発明は、例えば化粧水、乳液、クリーム等の
皮膚化粧料、クレンジングジェル等の洗浄化粧料として
提供できるものである。The present invention is particularly useful for a system containing a large amount of water or a system in which the external phase is an aqueous phase, and is particularly applicable to a water-oil emulsion or aqueous cosmetic. That is, the present invention can be provided, for example, as skin cosmetics such as lotions, emulsions and creams, and cleaning cosmetics such as cleansing gels.
【００２８】[0028]
【実施例および比較例】〔実施例１、比較例１〜３〕表
１に示す配合割合（重量％）で実施例と比較例中（２）
〜（４）の各成分を順次（１）に添加し、均一に混合し
分散させて化粧料用乳化組成物を調製した。なお、実施
例１および比較例１、２で使用した銀担持ゼオライト
（Ａ）は粒子径が１．０μｍ以下であり、比較例３で使
用している銀担持ゼオライト（Ｓ）は、平均粒度１．８
μｍ（２．５〜１．０μｍ）のものを使用した。[Examples and Comparative Examples] [Example 1, Comparative Examples 1 to 3] (2) in Examples and Comparative Examples at the blending ratio (% by weight) shown in Table 1
The components (1) to (4) were sequentially added to (1), uniformly mixed and dispersed to prepare an emulsified composition for cosmetics. The silver-supported zeolite (A) used in Example 1 and Comparative Examples 1 and 2 had a particle size of 1.0 μm or less, and the silver-supported zeolite (S) used in Comparative Example 3 had an average particle size of 1 μm. .8
μm (2.5 to 1.0 μm) was used.
【００２９】[0029]
【表１】 [Table 1]
【００３０】実施例および比較例に対し、これらの抗菌
活性の経時的変化を以下の試験方法で評価した。これら
の結果は、表２に示した。The changes over time in the antibacterial activity of the Examples and Comparative Examples were evaluated by the following test methods. These results are shown in Table 2.
【００３１】＜抗菌活性の評価試験＞細菌として大腸菌
(Escherichia coli)、黄色ブドウ球菌(Staphylococcus
aureus）および緑膿菌(Pseudomonas aeruginosa)を用
い、真菌としてカンジダ(Candida albicans)、黒カビ(A
spergillus niger）を用い、細菌は１０6 個、真菌は１
ｇ当たり１０5 個を植菌し、３７℃及び２５℃でそれぞ
れ培養して、２週間後の生菌数を測定した。細菌につい
ては死減した場合、真菌については生菌数が１／１００
０以下となった場合に抗菌活性が充分であると判断し
た。<Evaluation test of antibacterial activity> Escherichia coli as a bacterium
(Escherichia coli), Staphylococcus
aureus) and Pseudomonas aeruginosa, and as fungi Candida albicans and black mold (A
spergillus niger), 10 6 bacteria and 1 fungus
10 5 cells per g were inoculated and cultured at 37 ° C. and 25 ° C., respectively, and the number of viable cells after 2 weeks was measured. When bacteria are killed, the viable count is 1/100 for fungi.
When it was 0 or less, it was judged that the antibacterial activity was sufficient.
【００３２】評価試料については、実施例と比較例を用
い、それぞれ調製直後試料と４０℃、２ヶ月間保管した
試料を用いた。表２における評価結果は、充分な抗菌活
性の認められた場合を〇印、１種または２種の菌にのみ
抗菌活性が認められた場合を△印、全く認められなかっ
た場合を×印で示した。For the evaluation samples, the examples and comparative examples were used, and the samples immediately after preparation and the samples stored at 40 ° C. for 2 months were used. The evaluation results in Table 2 are indicated by a triangle when sufficient antibacterial activity was observed, a white triangle when antibacterial activity was observed only for one or two types of bacteria, and a cross when no antibacterial activity was observed. Indicated.
【００３３】[0033]
【表２】 [Table 2]
【００３４】表２において明らかなように、実施例１に
おいては４０℃、２ヶ月間保管後でも充分な抗菌活性が
認められたのに対し、比較例においては、一部の菌に対
しては抗菌活性の認められたものもあったが、比較例３
では、４０℃、２ヶ月後で全く抗菌活性が認められなか
った。As is clear from Table 2, in Example 1, sufficient antibacterial activity was observed even after storage at 40 ° C. for 2 months, while in Comparative Example, some bacteria were inhibited. Some antibacterial activities were observed, but Comparative Example 3
Did not show any antibacterial activity after 2 months at 40 ° C.
【００３５】〔実施例２〜４〕（化粧用乳液の処方） 表３に示す配合割合（重量％）で実施例２〜４の油相成
分（４）〜（８）を混合し加熱溶解して７５℃に保っ
た。一方、表３の材料（１）〜（３）と（９）の水相成
分を混合し、加熱溶解後、材料（１０）を分散させて７
５℃とし、これに前記の油相を攪拌しながら添加して乳
化した。これを冷却後、４０℃にて材料（１１）、（１
２）を添加し混合して化粧品の乳液を得た。[Examples 2 to 4] (Formulation of cosmetic emulsion) The oil phase components (4) to (8) of Examples 2 to 4 were mixed at the mixing ratio (% by weight) shown in Table 3 and dissolved by heating. And kept at 75 ° C. On the other hand, the materials (1) to (3) in Table 3 and the aqueous phase component of (9) were mixed and dissolved by heating.
The temperature was adjusted to 5 ° C., and the above oil phase was added thereto with stirring to emulsify. After cooling, at 40 ° C., materials (11), (1)
2) was added and mixed to obtain a cosmetic emulsion.
【００３６】[0036]
【表３】 [Table 3]
【００３７】〔実施例５〜７〕（化粧用クリームの処
方） 表４に示す配合割合（重量％）で、実施例５〜７の油相
成分（４）〜（９）を混合し加熱溶解して７５℃に保っ
た。一方、表４の材料（１）〜（３）、（１０）の水相
成分を混合し、加熱溶解後、材料（１１）を分散させて
７５℃とし、これを前記の油相を攪拌しながら添加して
乳化した。これを冷却後、４０℃にて（１２）、（１
３）を添加し混合して化粧品のクリームを得た。[Examples 5 to 7] (Formulation of cosmetic cream) The oil phase components (4) to (9) of Examples 5 to 7 were mixed at the mixing ratio (% by weight) shown in Table 4 and dissolved by heating. And kept at 75 ° C. On the other hand, the aqueous phase components of materials (1) to (3) and (10) in Table 4 were mixed and dissolved by heating. Then, the material (11) was dispersed to 75 ° C., and the oil phase was stirred. While adding, emulsified. After cooling, at 40 ° C. (12), (1)
3) was added and mixed to obtain a cosmetic cream.
【００３８】[0038]
【表４】 [Table 4]
【００３９】実施例２〜７についても、実施例１と全く
同様にして抗菌活性の評価試験を行なったが、４０℃で
２ヶ月保管した試料について充分な抗菌活性が認められ
た。With respect to Examples 2 to 7, the evaluation test of the antibacterial activity was carried out in exactly the same manner as in Example 1. The sample stored at 40 ° C. for 2 months showed sufficient antibacterial activity.
【００４０】[0040]
【発明の効果】この発明は、以上説明したように、微粒
子状の抗菌性ゼオライト、２価以上の多価アルコールも
しくは糖類または両者併用した混合物、有機酸もしくは
その塩類または両者併用した混合物および水を必須成分
としてそれぞれ所定量含有する抗菌性化粧料としたの
で、カビ、酵母、大腸菌及び緑膿菌等の微生物に対して
も充分に発育防止効果を有し、化粧品の保存性を顕著に
高めることができる抗菌性化粧料となる。According to the present invention, as described above, the present invention relates to the use of fine particles of an antibacterial zeolite, a dihydric or higher polyhydric alcohol or a saccharide or a mixture of both, an organic acid or a salt thereof or a mixture of both and water. As antibacterial cosmetics containing predetermined amounts as essential components, each has a sufficient growth inhibitory effect against microorganisms such as mold, yeast, Escherichia coli and Pseudomonas aeruginosa, and significantly enhances the preservability of cosmetics. It becomes an antibacterial cosmetic that can be used.
【００４１】また、化粧料中の抗菌性ゼオライトが再凝
集や沈殿せず、経時的に抗菌作用が安定した抗菌性化粧
料となり、特に化粧料中に微粒子状の（１．０μｍ以
下）抗菌性ゼオライトを配合したものでも優れた抗菌性
が安定的に作用し、保存性に優れた抗菌性化粧料となる
利点がある。Further, the antibacterial zeolite in the cosmetic does not re-aggregate or precipitate and becomes an antibacterial cosmetic having a stable antibacterial action over time. Even in the case where zeolite is blended, the excellent antibacterial property works stably, and there is an advantage that it becomes an antibacterial cosmetic having excellent storage stability.
───────────────────────────────────────────────────── フロントページの続き Ｆターム(参考） 4C083 AB441 AB442 AC022 AC072 AC111 AC112 AC122 AC132 AC242 AC302 AC352 AC392 AC402 AD112 AD191 AD332 AD352 CC05 DD31 EE03 EE10 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4C083 AB441 AB442 AC022 AC072 AC111 AC112 AC122 AC132 AC242 AC302 AC352 AC392 AC402 AD112 AD191 AD332 AD352 CC05 DD31 EE03 EE10
Claims (2)
１〜１０重量％、２価以上の多価アルコールもしくは糖
類または両者併用した混合物１〜５０重量％、有機酸も
しくはその塩類または両者併用した混合物０．１〜５０
重量％および水を必須成分として含有する抗菌性化粧
料。1. A fine-particle antibacterial zeolite 0.000
1 to 10% by weight, 1 to 50% by weight of a dihydric or higher polyhydric alcohol or saccharide or a mixture of both, 0.1 to 50 of an organic acid or a salt thereof or a mixture of both
An antibacterial cosmetic containing weight% and water as essential components.
径１．０μｍ以下の抗菌性ゼオライトである請求項１記
載の抗菌性化粧料。2. The antibacterial cosmetic according to claim 1, wherein the antibacterial zeolite is a metal-supported antibacterial zeolite having a particle size of 1.0 μm or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17609598A JP3836980B2 (en) | 1998-06-23 | 1998-06-23 | Antibacterial cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17609598A JP3836980B2 (en) | 1998-06-23 | 1998-06-23 | Antibacterial cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000007520A true JP2000007520A (en) | 2000-01-11 |
| JP3836980B2 JP3836980B2 (en) | 2006-10-25 |
Family
ID=16007619
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17609598A Expired - Lifetime JP3836980B2 (en) | 1998-06-23 | 1998-06-23 | Antibacterial cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3836980B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002030365A1 (en) * | 2000-10-06 | 2002-04-18 | Kabushiki Kaisha Sangi | Antibacterial resin |
| JP2012072134A (en) * | 2010-09-03 | 2012-04-12 | Taiki:Kk | Silver ion production liquid for antibacterial use, silver ion antibacterial liquid produced from the liquid, and production method for producing the antibacterial liquid |
| WO2018167990A1 (en) * | 2017-03-17 | 2018-09-20 | 東洋エアゾール工業株式会社 | Warming composition and aerosol formulation including same |
-
1998
- 1998-06-23 JP JP17609598A patent/JP3836980B2/en not_active Expired - Lifetime
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002030365A1 (en) * | 2000-10-06 | 2002-04-18 | Kabushiki Kaisha Sangi | Antibacterial resin |
| JPWO2002030365A1 (en) * | 2000-10-06 | 2004-02-19 | 株式会社サンギ | Antibacterial resin |
| JP2012072134A (en) * | 2010-09-03 | 2012-04-12 | Taiki:Kk | Silver ion production liquid for antibacterial use, silver ion antibacterial liquid produced from the liquid, and production method for producing the antibacterial liquid |
| WO2018167990A1 (en) * | 2017-03-17 | 2018-09-20 | 東洋エアゾール工業株式会社 | Warming composition and aerosol formulation including same |
| KR20190124313A (en) * | 2017-03-17 | 2019-11-04 | 도요 에어로졸 고교 가부시키가이샤 | Warm composition and aerosol formulations comprising the same |
| CN110520098A (en) * | 2017-03-17 | 2019-11-29 | 东洋喷雾工业株式会社 | Warming composition and aerosol preparation containing the warming composition |
| JPWO2018167990A1 (en) * | 2017-03-17 | 2020-01-16 | 東洋エアゾール工業株式会社 | Warming composition and aerosol preparation containing the same |
| KR102241381B1 (en) * | 2017-03-17 | 2021-04-15 | 도요 에어로졸 고교 가부시키가이샤 | Warm sensation composition and aerosol formulation comprising the same |
| US11642552B2 (en) | 2017-03-17 | 2023-05-09 | Toyo Aerosol Industry Co., Ltd. | Warming composition and aerosol formulation including same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3836980B2 (en) | 2006-10-25 |
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